JPH0443557A - Hybrid battery - Google Patents
Hybrid batteryInfo
- Publication number
- JPH0443557A JPH0443557A JP14814190A JP14814190A JPH0443557A JP H0443557 A JPH0443557 A JP H0443557A JP 14814190 A JP14814190 A JP 14814190A JP 14814190 A JP14814190 A JP 14814190A JP H0443557 A JPH0443557 A JP H0443557A
- Authority
- JP
- Japan
- Prior art keywords
- active material
- battery
- double layer
- layer capacitor
- positive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000007773 negative electrode material Substances 0.000 claims abstract description 9
- 239000007774 positive electrode material Substances 0.000 claims abstract description 8
- -1 polypropylene Polymers 0.000 claims abstract description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 3
- 239000004917 carbon fiber Substances 0.000 claims abstract description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000003792 electrolyte Substances 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910000733 Li alloy Inorganic materials 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011149 active material Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 239000001989 lithium alloy Substances 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 239000007772 electrode material Substances 0.000 claims 1
- 229910002804 graphite Inorganic materials 0.000 claims 1
- 239000010439 graphite Substances 0.000 claims 1
- 230000002687 intercalation Effects 0.000 claims 1
- 238000009830 intercalation Methods 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 208000028659 discharge Diseases 0.000 abstract description 14
- 239000003990 capacitor Substances 0.000 abstract description 11
- 239000004743 Polypropylene Substances 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 229920001155 polypropylene Polymers 0.000 abstract description 3
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011888 foil Substances 0.000 abstract description 2
- 239000005486 organic electrolyte Substances 0.000 abstract description 2
- 239000010935 stainless steel Substances 0.000 abstract description 2
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 239000012982 microporous membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は電気二重層キャパシタの分極性電極と電池の正
極並びに負極を一体化したバイブリフト電池に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a vibelift battery in which the polarizable electrode of an electric double layer capacitor and the positive and negative electrodes of the battery are integrated.
従来技術とその問題点
従来の電気二重層キャパシタは、活性炭電極表面への電
解液からのイオンの物質的吸着による電気二重層に蓄積
された電荷を利用することから、瞬時の大電流放電は可
能であるが電気容量は極めて小さい。Conventional technology and its problems Conventional electric double layer capacitors are capable of instantaneous large current discharge because they utilize the charge accumulated in the electric double layer due to the physical adsorption of ions from the electrolyte onto the surface of the activated carbon electrode. However, the electrical capacity is extremely small.
一方、電池は電気化学反応を伴うため、特に電解液に有
機溶媒を用いる電池においては、電極界面の抵抗が大き
く、大電流放電ができないという欠点があった。On the other hand, since batteries involve electrochemical reactions, they have the drawback that, particularly in batteries that use organic solvents for the electrolyte, the resistance at the electrode interface is large and large current discharge is not possible.
発明の目的
本発明は上記従来の問題点に鑑みなされたものであり、
大電流負荷で放電したときの放電々圧の低下が少ない、
長時間にわたって安定した電圧を維持することができる
ハイブリット電池を提供することを目的とするものであ
る。Purpose of the Invention The present invention has been made in view of the above-mentioned conventional problems.
There is little drop in discharge voltage when discharging with a large current load.
The object of the present invention is to provide a hybrid battery that can maintain a stable voltage for a long period of time.
実施例
以下、本発明−の詳細について一実施例により説明する
。EXAMPLE Hereinafter, the present invention will be explained in detail by way of an example.
第１図は本発明のハイブリット電池の断面図、第２図は
従来の電池の断面図、第３図は本発明の電池と従来の電
池の放電特性比較図である。FIG. 1 is a sectional view of the hybrid battery of the present invention, FIG. 2 is a sectional view of a conventional battery, and FIG. 3 is a comparison diagram of the discharge characteristics of the battery of the present invention and the conventional battery.
ここで１は負極集電体、２は分極性電極、３は負極活物
質層、４は電解質層、５は正極集電体、６は正極活物質
層、７は封口体である。Here, 1 is a negative electrode current collector, 2 is a polarizable electrode, 3 is a negative electrode active material layer, 4 is an electrolyte layer, 5 is a positive electrode current collector, 6 is a positive electrode active material layer, and 7 is a sealing body.
負極集電体、正極集電体はステンレス箔からなり、分極
性電極は活性炭又は炭素繊維からなる電気二重層キャパ
シタ、負極活物質層はグラファイト化カーボンからなり
、電解質層はポリプロピレンの微孔膜と有機電解液から
なり、正極活物質層はバナジウム酸化物よりなる。封口
体は変性ポリプロピレンである。The negative electrode current collector and positive electrode current collector are made of stainless steel foil, the polarizable electrode is an electric double layer capacitor made of activated carbon or carbon fiber, the negative electrode active material layer is made of graphitized carbon, and the electrolyte layer is a microporous membrane of polypropylene. It is made of an organic electrolyte, and the positive electrode active material layer is made of vanadium oxide. The sealing body is modified polypropylene.
電池構成は、電極面積が１００ｃｊ、分極性電極の厚み
は５０ｕｍ、正極活物質層の厚みは４５μｍ、負極活物
質層の厚みは３０ａｍであり、分極性電極の外側に活物
質層を配した。又、電解質層の厚みは２５μｍで電解液
にはプロピレンカーボネートとジメトキシエタンの混合
溶媒に過塩素酸リチウムを溶解したものを用いた。The battery configuration had an electrode area of 100 cj, a polarizable electrode thickness of 50 um, a positive electrode active material layer thickness of 45 μm, and a negative electrode active material layer thickness of 30 am, with the active material layer disposed outside the polarizable electrode. The thickness of the electrolyte layer was 25 μm, and the electrolytic solution used was a mixture of propylene carbonate and dimethoxyethane in which lithium perchlorate was dissolved.
集電体の周囲を封口材でシールレ電池を密封した。The Schiele battery was sealed around the current collector with a sealant.
尚、正極活物質は上記実施例のほか、マンガン、チタン
、コバルト、ニッケル、ニオブ等の酸化物を用いてもよ
い。In addition to the above embodiments, oxides of manganese, titanium, cobalt, nickel, niobium, etc. may be used as the positive electrode active material.
又、負極活物質もＷＯ，、ＭｏＯ，等の眉間化合物ある
いはリチウム又はリチウム合金の粉末を用いることがで
きる。Further, as the negative electrode active material, a compound such as WO, MoO, etc., or a powder of lithium or a lithium alloy can be used.
比較のため、分極性電極を有しない従来の電池（第２同
）を用いて、本発明の電池と同負荷条件で放電したとき
の、放電特性の比較図を第３図に示した。尚、従来の電
池は、分極性電極が無いほかは、電極面積、正極、負極
活物質層の厚み等、同じとした。第３図より、放電初期
に大電流を必要とする負荷の場合、電気二重層キャパシ
タが放電初期の大電流負荷を負担するので、放電々圧の
落ち込みが少ない。For comparison, FIG. 3 shows a comparative diagram of discharge characteristics when a conventional battery (No. 2) without polarizable electrodes was discharged under the same load conditions as the battery of the present invention. Note that the conventional batteries had the same electrode area, the thickness of the positive electrode, the negative electrode active material layer, etc., except that they did not have polarizable electrodes. From FIG. 3, in the case of a load that requires a large current in the early stage of discharge, the electric double layer capacitor bears the large current load in the early stage of discharge, so that there is little drop in the discharge voltage.
又、定常電流での放電は、電池電極が負担するので、電
気二重層キャパシタに較べて長時間にわたって、安定し
た電圧を維持することができる。このように、１個の電
池で電気二重層キャパシタと電池の特性が得られるので
、従来のように電気二重層キャパシタと電池を個々に接
続する必要がなく、機器の小型軽量化ができる。Furthermore, since the battery electrode bears the burden of discharging at a steady current, a stable voltage can be maintained for a longer period of time compared to an electric double layer capacitor. In this way, since the characteristics of an electric double layer capacitor and a battery can be obtained with one battery, there is no need to connect the electric double layer capacitor and the battery individually as in the past, and the device can be made smaller and lighter.
発明の効果
上記した如く、本発明は大電流負荷で放電したときの放
電々圧の低下が少ない、長時間にわたって安定した電圧
を維持することができるハイブリット電池を提供するこ
とが出来るので、その工業的価値は極めて大である。Effects of the Invention As described above, the present invention can provide a hybrid battery that can maintain a stable voltage for a long period of time with little drop in discharge voltage when discharging under a large current load. The value is extremely high.
第１図は本発明の一実施例を示した電池の断面図、第２
図は従来の電池の断面図、第３図は本発明と従来の電池
の放電特性比較図である。
１・・・負極集電体 ２・・・分極性電極３・・
・負極活物質層 ４・・・電解質層５・・・正極集
電体 ６・・・正極活物質層７・・・封口体FIG. 1 is a cross-sectional view of a battery showing one embodiment of the present invention, and FIG.
The figure is a sectional view of a conventional battery, and FIG. 3 is a comparison diagram of the discharge characteristics of the present invention and the conventional battery. 1... Negative electrode current collector 2... Polarizable electrode 3...
・Negative electrode active material layer 4... Electrolyte layer 5... Positive electrode current collector 6... Positive electrode active material layer 7... Sealing body
Claims (4)
質を一体化した正極と、前記の分極性電極と負極活物質
を一体化した負極と、これら正・負極間に電解質層を有
することを特徴とするハイブリット電池。(1) A positive electrode that integrates a polarizable electrode made of activated carbon or carbon fiber and a positive electrode active material, a negative electrode that integrates the polarizable electrode and negative electrode active material, and an electrolyte layer between these positive and negative electrodes. A hybrid battery featuring
のハイブリット電池。(2) The hybrid battery according to claim 1, wherein the active material is disposed outside the polarizable electrode.
バルト、ニッケル、ニオブの酸化物から選ばれた少なく
とも一種からなる請求項１記載のハイブリット電池。(3) The hybrid battery according to claim 1, wherein the positive electrode active material comprises at least one selected from oxides of manganese, vanadium, titanium, cobalt, nickel, and niobium.
２等の層間化合物もしくはリチウム又はリチウム合金か
ら選ばれた少なくとも一種からなる請求項１記載のハイ
ブリット電池。(4) Negative electrode active material is graphite, WO_2, MoO_
2. The hybrid battery according to claim 1, comprising at least one selected from intercalation compounds such as No. 2, lithium, and lithium alloys.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14814190A JP2541342B2 (en) | 1990-06-06 | 1990-06-06 | Hybrid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14814190A JP2541342B2 (en) | 1990-06-06 | 1990-06-06 | Hybrid battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0443557A true JPH0443557A (en) | 1992-02-13 |
| JP2541342B2 JP2541342B2 (en) | 1996-10-09 |
Family
ID=15446190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14814190A Expired - Lifetime JP2541342B2 (en) | 1990-06-06 | 1990-06-06 | Hybrid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2541342B2 (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0700583A1 (en) * | 1994-02-28 | 1996-03-13 | Motorola, Inc. | Electrical energy storage device and method of charging and discharging same |
| JPH08162374A (en) * | 1994-11-30 | 1996-06-21 | Aisin Seiki Co Ltd | Electrical energy storage body |
| US5739804A (en) * | 1994-03-16 | 1998-04-14 | Kabushiki Kaisha Toshiba | Display device |
| JP2001351688A (en) * | 2000-06-07 | 2001-12-21 | Fdk Corp | Complex element of cell and capacitor |
| EP1665446A1 (en) * | 2003-09-18 | 2006-06-07 | Commonwealth Scientific And Industrial Research Organisation | High performance energy storage devices |
| JP2006172775A (en) * | 2004-12-14 | 2006-06-29 | Hitachi Ltd | Energy storage device, its module and automobile using it |
| JP2008047452A (en) * | 2006-08-18 | 2008-02-28 | Shin Kobe Electric Mach Co Ltd | Paste type electrode plate and its manufacturing method |
| FR2927472A1 (en) * | 2008-02-11 | 2009-08-14 | Commissariat Energie Atomique | HYBRID SYSTEM FOR STORING ELECTRIC ENERGY WITH BIPOLAR ELECTRODES |
| US9203116B2 (en) | 2006-12-12 | 2015-12-01 | Commonwealth Scientific And Industrial Research Organisation | Energy storage device |
| US9666860B2 (en) | 2007-03-20 | 2017-05-30 | Commonwealth Scientific And Industrial Research Organisation | Optimised energy storage device having capacitor material on lead based negative electrode |
| US9812703B2 (en) | 2010-12-21 | 2017-11-07 | Commonwealth Scientific And Industrial Research Organisation | Electrode and electrical storage device for lead-acid system |
-
1990
- 1990-06-06 JP JP14814190A patent/JP2541342B2/en not_active Expired - Lifetime
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0700583A1 (en) * | 1994-02-28 | 1996-03-13 | Motorola, Inc. | Electrical energy storage device and method of charging and discharging same |
| EP0700583A4 (en) * | 1994-02-28 | 1996-09-11 | Motorola Inc | Electrical energy storage device and method of charging and discharging same |
| US5739804A (en) * | 1994-03-16 | 1998-04-14 | Kabushiki Kaisha Toshiba | Display device |
| JPH08162374A (en) * | 1994-11-30 | 1996-06-21 | Aisin Seiki Co Ltd | Electrical energy storage body |
| JP2001351688A (en) * | 2000-06-07 | 2001-12-21 | Fdk Corp | Complex element of cell and capacitor |
| EP1665446A4 (en) * | 2003-09-18 | 2007-09-26 | Commw Scient Ind Res Org | High performance energy storage devices |
| JP2007506230A (en) * | 2003-09-18 | 2007-03-15 | コモンウエルス サイエンティフィック アンド インダストリアル リサーチ オーガナイゼーション | High performance energy storage device |
| EP1665446A1 (en) * | 2003-09-18 | 2006-06-07 | Commonwealth Scientific And Industrial Research Organisation | High performance energy storage devices |
| EP2290737A3 (en) * | 2003-09-18 | 2011-07-20 | Commonwealth Scientific and Industrial Research Organisation | High performance energy storage devices |
| EP2273602A3 (en) * | 2003-09-18 | 2011-07-20 | Commonwealth Scientific and Industrial Research Organisation | High performance energy storage devices |
| JP2011181513A (en) * | 2003-09-18 | 2011-09-15 | Commonwealth Scientific & Industrial Research Organisation | High performance energy storage device |
| JP2006172775A (en) * | 2004-12-14 | 2006-06-29 | Hitachi Ltd | Energy storage device, its module and automobile using it |
| JP2008047452A (en) * | 2006-08-18 | 2008-02-28 | Shin Kobe Electric Mach Co Ltd | Paste type electrode plate and its manufacturing method |
| US9203116B2 (en) | 2006-12-12 | 2015-12-01 | Commonwealth Scientific And Industrial Research Organisation | Energy storage device |
| US9666860B2 (en) | 2007-03-20 | 2017-05-30 | Commonwealth Scientific And Industrial Research Organisation | Optimised energy storage device having capacitor material on lead based negative electrode |
| FR2927472A1 (en) * | 2008-02-11 | 2009-08-14 | Commissariat Energie Atomique | HYBRID SYSTEM FOR STORING ELECTRIC ENERGY WITH BIPOLAR ELECTRODES |
| WO2009101047A1 (en) * | 2008-02-11 | 2009-08-20 | Commissariat A L'energie Atomique | Hybrid electric energy storage system with bipolar electrodes |
| US9812703B2 (en) | 2010-12-21 | 2017-11-07 | Commonwealth Scientific And Industrial Research Organisation | Electrode and electrical storage device for lead-acid system |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2541342B2 (en) | 1996-10-09 |
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