JPH04180029A - Connecting structural body for circuit - Google Patents

Connecting structural body for circuit

Info

Publication number
JPH04180029A
JPH04180029A JP2309275A JP30927590A JPH04180029A JP H04180029 A JPH04180029 A JP H04180029A JP 2309275 A JP2309275 A JP 2309275A JP 30927590 A JP30927590 A JP 30927590A JP H04180029 A JPH04180029 A JP H04180029A
Authority
JP
Japan
Prior art keywords
particles
conductive
connection
solder
circuit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2309275A
Other languages
Japanese (ja)
Inventor
Katsuma Endo
甲午 遠藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
Original Assignee
Seiko Epson Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Epson Corp filed Critical Seiko Epson Corp
Priority to JP2309275A priority Critical patent/JPH04180029A/en
Publication of JPH04180029A publication Critical patent/JPH04180029A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
    • H05K3/321Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/36Assembling printed circuits with other printed circuits
    • H05K3/361Assembling flexible printed circuits with other printed circuits

Abstract

PURPOSE:To widen the margin of a press welding operation and to improve the reliability of connection by allowing >=2 kinds of conductive particles, such as solder particles, and particles formed by applying metal plating on a plastic nuclear material to coexist in an anisotropically conductive adhesive layer. CONSTITUTION:The solder particles 6 which are the conductive particles and the particles 7 which are formed by applying the metal plating of Ni or Au, etc., on the plastic nuclear material and are the conductive particles are made to coexist in the anisotropically conductive adhesive layer 5. The connection of the relatively high reliability at about <=200 deg.C is obtd. by the solder particles 6 and the connection of the high reliability is obtd. at a relatively high temp. of about >=180 deg.C by the particles 7 formed by applying the metal plating of the Ni or Au, etc., on the plastic nuclear material.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は信頼性に優れた微細回路の接続構造体に関する
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a highly reliable microcircuit connection structure.

(従来の技術) 従来より液晶パネルへの半導体あるいは半導体部品の接
続あるいは光センサーへの集積回路類の接続、さらには
各種回路基板への表面実装部品の接続などのように接続
端子が相対峙して細かいピッチでならんでいる場合の接
続方法として、半田付けや導電ペーストによる方法が広
く用いられている。しかし、これらの方法は導電性接続
部材を導電回路部のみに限定して形成しなければならな
いので、窩密度、高精細化の進む微細回路の接続に困難
をきたしてきた。第2図、および第3図はは従来の回路
の接続構造体の一例を示すものである。第2図において
21はTAEテープ材料、22は回路基板たるTABテ
ープ上に形成された接続回路たる銅箔パターン、23は
液晶パネル、24は液晶パネル上の接続回路たるIT○
よりなる電極パターン、25は異方導電性接着剤層、2
6.27は導電性粒子を示す、26の導電性粒子は第2
図においては半田微粒子である、また27は高分子重合
体からなる核材上に形成された制電性金属薄膜層により
実質的に被覆された導電性粒子である。
(Prior art) Conventionally, connection terminals are used to face each other, such as connecting semiconductors or semiconductor components to liquid crystal panels, connecting integrated circuits to optical sensors, and connecting surface mount components to various circuit boards. Soldering or conductive paste is widely used as a connection method when the wires are lined up at a fine pitch. However, in these methods, the conductive connecting member must be formed only in the conductive circuit portion, which has caused difficulty in connecting fine circuits with increasing hole density and high definition. FIGS. 2 and 3 show an example of a conventional circuit connection structure. In FIG. 2, 21 is a TAE tape material, 22 is a copper foil pattern that is a connection circuit formed on the TAB tape that is a circuit board, 23 is a liquid crystal panel, and 24 is an IT○ that is a connection circuit on the liquid crystal panel.
25 is an anisotropic conductive adhesive layer, 2
6.27 indicates conductive particles, 26 conductive particles are the second
In the figure, numerals 27 are solder fine particles, and 27 are conductive particles substantially covered with an antistatic metal thin film layer formed on a core material made of a high molecular weight polymer.

(発明が解決しようとする1llflJしかし、従来の
回路の接続構造体は第2図および第3図より明らかなよ
うに幾多の問題点を有するものであった・ まず、従来の回路の接続構造体においては、TABテー
プ21の銅箔パターン22と液晶パネル23の上の電極
パターン24の間に挟持される異方導電性接着剤層25
の中の導電性粒子26は半田粒子であるため、異方導電
性接着剤層をTABテープと液晶パネルの間に挟持し、
ヒーターツールにてTABテープを液晶パネルに加熱し
ながら押し付けるとTABテープと液晶パネルは接着剤
層が硬化することによって、TABテープと液晶パネル
は接合されるが、この詩、温度が高すぎると接着剤の硬
化は進展し単なる接合という意味での強度は向上するが
導電性粒子たる半田粒子が共晶金属よりできているため
融点というものが存在しこの半田粒子は一度溶けてしま
うためTABテープの銅箔パターンと液晶パネルの電極
パターンとの導通接続の信頼性という意味では接続信頼
性は低減するものであった。
(1llfllJ that the invention attempts to solve) However, the conventional circuit connection structure has many problems as is clear from FIGS. 2 and 3. First, the conventional circuit connection structure , an anisotropic conductive adhesive layer 25 sandwiched between a copper foil pattern 22 of a TAB tape 21 and an electrode pattern 24 on a liquid crystal panel 23.
Since the conductive particles 26 inside are solder particles, an anisotropic conductive adhesive layer is sandwiched between the TAB tape and the liquid crystal panel.
When you press the TAB tape against the LCD panel while heating it with a heater tool, the adhesive layer will harden and the TAB tape and LCD panel will be joined together. The hardening of the agent progresses and the strength in the sense of mere bonding improves, but since the solder particles, which are conductive particles, are made of eutectic metal, there is a melting point, and the solder particles melt once, so the TAB tape's strength increases. The connection reliability was reduced in terms of the reliability of the conductive connection between the copper foil pattern and the electrode pattern of the liquid crystal panel.

さらに、第3図においては、導電性粒子が高分子重合体
からなる核材上に形成された制電性金属薄膜層により実
質的に被覆されたものであるため、高温高圧側の高エネ
ルギーサイドでの圧着ツールによる圧着では比較的半田
による導電性粒子に比べると導通接続の信頼性は保たれ
るものの低温低圧側の低エネルギーサイドでの圧着ツー
ルによる圧着では導通接続の信頼性はきわめて阻害され
る。
Furthermore, in FIG. 3, since the conductive particles are substantially covered with an antistatic metal thin film layer formed on a core material made of a polymer, the high energy side on the high temperature and high pressure side Although crimping with a crimping tool at low temperatures maintains the reliability of conductive connections compared to conductive particles using solder, crimping with crimping tools at low temperature, low voltage, and low energy sides significantly impairs the reliability of conductive connections. Ru.

そこで、本発明は従来のこのような欠点を解決し相対峙
して形成された接続回路の接続の信頼性を向上させるこ
とを目的とする。
SUMMARY OF THE INVENTION Therefore, an object of the present invention is to solve these conventional drawbacks and improve the reliability of connections between connection circuits formed oppositely.

(課題を解決するための手段) 本発明による回路の接続構造体は、相対峙して形成され
た接続用回路のうち少なくとも一方の接続用回路は液晶
パネル上に形成され他の一方の接続用回路は他の電子部
品上に形成され、上記接続用回路の間に絶縁性接着剤中
に導電性微粒子を介在させた異方導電性接着剤層を有し
上記導電性粒子は1個の異方導電性接着剤層中に鉛・錫
合金を主体とする半田微粒子と、Ni微粒子あるいはプ
ラスチック核材に金属メッキを施した粒子等の非低融点
金属を導電物質とした微粒子の2種以上の導電性粒子よ
り構成されることを特徴とする。
(Means for Solving the Problems) In the circuit connection structure according to the present invention, at least one of the connection circuits formed facing each other is formed on a liquid crystal panel, and the other connection circuit is formed on a liquid crystal panel. The circuit is formed on another electronic component, and between the connecting circuits there is an anisotropically conductive adhesive layer in which conductive particles are interposed in an insulating adhesive. The conductive adhesive layer contains two or more types of solder fine particles mainly made of a lead-tin alloy, and fine particles whose conductive material is a non-low melting point metal such as Ni fine particles or particles of plastic core material plated with metal. It is characterized by being composed of conductive particles.

(実施例) 以下に、本発明の実施例を図面を用いて説明する。第1
図は回路の接続構造体における要部断面図を示す。第1
図において、1はTABテープ、2は回路基板たるTA
Bテープ上に形成された接続回路たる導箔パターン、3
は液晶パネル、4は液晶パネル上の接続回路たるITO
よりなる電極パターン、5は異方導電性接着剤層、6は
導電性粒子のうちの半田微粒子、7は同じく導電性粒子
のうちのNi微粒子あるいはプラスチック核材に金属メ
ッキを施した粒子等の非低融点金属を導電物質とした微
粒子をしめす。導電性粒子は2種以上の導電性粒子より
構成されている。
(Example) Examples of the present invention will be described below with reference to the drawings. 1st
The figure shows a sectional view of a main part of a circuit connection structure. 1st
In the figure, 1 is TAB tape, 2 is TA which is a circuit board.
B A conductive foil pattern as a connection circuit formed on the tape, 3
is the liquid crystal panel, and 4 is the ITO connection circuit on the liquid crystal panel.
5 is an anisotropic conductive adhesive layer, 6 is a solder fine particle among the conductive particles, and 7 is also a Ni fine particle among the conductive particles, or a particle made of metal plating on a plastic core material, etc. Indicates fine particles made of a non-low melting point metal as a conductive substance. The conductive particles are composed of two or more types of conductive particles.

一般に半田微粒子はいわゆる合金であり、融点というも
のを有する。半田微粒子の融点はその合金成分がいかな
るものであれ一般には200°C前後である。一方、異
方導電性接着剤の硬化は】60’Cを越えたところから
発現するものが多く170から190°Cという範囲内
で圧着作業する事が多い。このように圧着作業の温度と
半田の融点がかなり近いため、圧着作業のばらつきによ
っては部分的に、圧着作業の温度が半田の融点をこえる
可能性がありうる。他方、半田微粒子は基本成分として
鉛と錫を含んでいるが、液晶パネルの一般的な電極パタ
ーンがITOからできているため、そしてITOの成分
がインジウムと錫の酸化物からできておりITOの遊離
金属たるインジウムと錫はそれぞれ半田の成分金属たる
鉛と錫との間に200℃以下で共晶点をもつため、むし
ろ200°C以下においては微視的に半田微粒子と液晶
パネルの電極パターンたるITOのあいだに冶金学的結
合を持った部位が存在することとなり導通接続の信頼性
は向上することとなる。さらにTABテープの鈍箔パタ
ーンは一般には錫メッキが施されており、この錫メッキ
も上述する半田微粒子の構成成分と微視的に合金をつく
り、はんだ微粒子との接続信頼性を向上させることがで
きる。このように半田微粒子は200°C以下で比較的
信頼性の高い接続を得ることができる。
Generally, solder particles are a so-called alloy and have a melting point. The melting point of fine solder particles is generally around 200°C, regardless of the alloy components. On the other hand, the curing of anisotropically conductive adhesives often occurs at temperatures above 60'C, and crimping is often carried out within the range of 170 to 190°C. As the temperature of the crimping operation and the melting point of the solder are quite close to each other, the temperature of the crimping operation may partially exceed the melting point of the solder depending on variations in the crimping operation. On the other hand, solder fine particles contain lead and tin as basic components, but because the general electrode pattern of liquid crystal panels is made of ITO, and the components of ITO are made of indium and tin oxides, ITO Indium and tin, which are free metals, have a eutectic point between lead and tin, which are component metals of solder, at temperatures below 200°C. The reliability of the conductive connection is improved because there is a metallurgically bonded portion between the ITO barrels. Furthermore, the dull foil pattern of TAB tape is generally tin-plated, and this tin plating also microscopically forms an alloy with the components of the solder particles mentioned above, improving the connection reliability with the solder particles. can. In this way, solder particles can provide a relatively reliable connection at temperatures below 200°C.

他方、プラスチック核材にNiあるいはAu等の金属メ
ッキを施した粒子を導電性粒子とする場合。TABテー
プの銅箔パターンと液晶パネルの電極パターンとの導通
はあくまでなんらかの結合によるのではなく、単に接触
によるものである。
On the other hand, when the conductive particles are particles in which a plastic core material is plated with a metal such as Ni or Au. The conduction between the copper foil pattern of the TAB tape and the electrode pattern of the liquid crystal panel is not due to any kind of bonding, but simply due to contact.

従って、圧着エネルギーが小さい場合導電性粒子とTA
Bテープあるいは液晶パネルの電極パターンとの導通接
続の信頼性は低いものとなってしまう。反面、圧着エネ
ルギーが大きい場合、導電性粒が溶けてTABテープの
銅箔パターンや液晶パネルの電極パターンとの導通の信
頼性が低下するような事がなく接着剤の硬化を十分進行
させ導通接続の信頼性を低下させずに清ませることがで
きる。このように、プラスチック核材にNiあるいはA
u等の金属メッキを施した粒子を導電性粒子とする場合
、180°C以上の比較的高温で信頼性の高い接続を得
ることができる。
Therefore, when the crimping energy is small, the conductive particles and TA
The reliability of the conductive connection with the B tape or the electrode pattern of the liquid crystal panel becomes low. On the other hand, if the pressure bonding energy is large, the conductive grains will not melt and the reliability of the conduction with the TAB tape's copper foil pattern or the LCD panel's electrode pattern will not deteriorate, and the adhesive will sufficiently harden and a conductive connection will be achieved. can be cleaned without reducing reliability. In this way, Ni or A can be added to the plastic core material.
When particles plated with metal such as U are used as conductive particles, a highly reliable connection can be obtained at a relatively high temperature of 180° C. or higher.

以上説明したように、プラスチック核材にNiあるいは
Au等の金属メッキを施した粒子と半田微粒子による導
電性粒子では高温と低温に於て信頼性の高さがことなる
。したがって、本発明のように、プラスチック核材にN
iあるいはAu等の金属メッキを施した粒子と半田微粒
子による導電性粒子との2種類の導電性粒子を一つの異
方導電性接着剤の中に混在させておけば圧着作業の条件
が多少ばらついても、高温と低温に於てそれぞれ別の導
電性粒子が信頼性の保持に寄与し、より広い範囲で信頼
性を確保することができる。その結果、圧着作業の条件
に対する許容限界を広くすることができる。それによっ
て、接続コストの低減をはかることができる。さらに、
圧着作業の条件に対する許容限界を広くすることができ
れば、周辺構造の多様化を可能とすることができ、周辺
構造のコストダウンにも寄与することができる。
As explained above, particles made of a plastic core material plated with metal such as Ni or Au and conductive particles made of solder particles have different reliability at high and low temperatures. Therefore, as in the present invention, N is added to the plastic core material.
If two types of conductive particles, particles plated with metal such as i or Au and conductive particles made of solder fine particles, are mixed in one anisotropic conductive adhesive, the conditions of the crimping work will vary somewhat. However, different conductive particles contribute to maintaining reliability at high and low temperatures, making it possible to ensure reliability over a wider range. As a result, it is possible to widen the allowable limits for the conditions of the crimping operation. Thereby, connection costs can be reduced. moreover,
If the allowable limits for the conditions of the crimping operation can be widened, it is possible to diversify the peripheral structures, and this can also contribute to reducing the cost of the peripheral structures.

さらに、接続の信頼性そのものをも向上させることがで
きる。その結果、このような回路の接続構造をした製品
の使用範囲をひろげることができ、製品の応用範囲を広
げ、活用技術の範囲を広げることによって、本発明によ
る回路の接続構造の技術のコストを低減させることを可
能としている。
Furthermore, the reliability of the connection itself can be improved. As a result, the range of use of products with such a circuit connection structure can be expanded, and the cost of the circuit connection structure technology according to the present invention can be reduced by expanding the application range of the product and the range of utilization technology. It is possible to reduce the

さらに、製品の応用範囲を広げ、活用技術の範囲を広げ
ることによって、製品の付加価値を付けることが可能と
なってくる。
Furthermore, by expanding the range of applications of products and the range of technologies utilized, it becomes possible to add value to products.

(発明の効果) 本発明は以上説明したように、1個の異方導電性接着剤
層中に鉛・錫合金を主体とする半田微粒子と、Ni微粒
子あるいはプラスチック核材に金属メッキを施した粒子
等の非低融点金属を導電物質とした微粒子の2種以上の
導電性粒子を混在させることのより、圧着作業のマージ
ンを広げ、信頼性を向上させる効果がある。
(Effects of the Invention) As explained above, the present invention has metal plating applied to solder fine particles mainly composed of lead-tin alloy and Ni fine particles or plastic core material in one anisotropic conductive adhesive layer. By mixing two or more types of conductive particles, such as fine particles made of non-low melting point metal as a conductive substance, the margin of the crimping operation is widened and the reliability is improved.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図   本発明の実施例における回路の接続構造体
の要部断面図。 第2図   従来の実施例における回路の接続構造体の
要部断面図 I   TABテープ 2  銅箔パターン 3  液晶パネル 4  電極パターン 5  異方導電性接着剤層 6  半田微粒子 7  プラスチック核材に金属メッキを施した導電性粒
子 21  TABテープ 22 銅箔パターン 23 液晶パネル 24 電極パターン 25 異方導電性接着剤層 26 半田微粒子 以  上 出願人 セイコーエプソン株式会社 代理人弁理士 銘木喜三部(化1名)
FIG. 1 is a sectional view of a main part of a circuit connection structure in an embodiment of the present invention. FIG. 2 Cross-sectional view of main parts of a circuit connection structure in a conventional example I TAB tape 2 Copper foil pattern 3 Liquid crystal panel 4 Electrode pattern 5 Anisotropically conductive adhesive layer 6 Solder particles 7 Metal plating on plastic core material Applied conductive particles 21 TAB tape 22 Copper foil pattern 23 Liquid crystal panel 24 Electrode pattern 25 Anisotropic conductive adhesive layer 26 Solder particles or more Applicant Seiko Epson Corporation Representative Patent Attorney Kizobe Meiki (1 person)

Claims (1)

【特許請求の範囲】[Claims] 相対峙して形成された接続用回路のうち少なくとも一方
の接続用回路は液晶パネル上に形成され、他の一方の接
続用回路は他の電子部品上に形成され、上記接続用回路
の間に絶縁性接着剤中に導電性微粒子を介在させた異方
導電性接着剤層を有し、上記導電性粒子は1個の異方導
電性接着剤層中に鉛・錫合金を主体とする半田微粒子と
、Ni微粒子あるいはプラスチック核材に金属メッキを
施した粒子等の非低融点金属を導電物質とした微粒子の
2種以上の導電性粒子より構成されることを特徴とする
回路の接続構造体。
At least one of the connection circuits formed facing each other is formed on the liquid crystal panel, the other connection circuit is formed on another electronic component, and there is no space between the connection circuits. It has an anisotropic conductive adhesive layer in which conductive fine particles are interposed in an insulating adhesive, and the conductive particles are solder mainly composed of a lead-tin alloy in one anisotropic conductive adhesive layer. A circuit connection structure characterized by being composed of two or more types of conductive particles: fine particles and fine particles whose conductive substance is a non-low melting point metal such as Ni fine particles or particles obtained by metal plating a plastic core material. .
JP2309275A 1990-11-15 1990-11-15 Connecting structural body for circuit Pending JPH04180029A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2309275A JPH04180029A (en) 1990-11-15 1990-11-15 Connecting structural body for circuit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2309275A JPH04180029A (en) 1990-11-15 1990-11-15 Connecting structural body for circuit

Publications (1)

Publication Number Publication Date
JPH04180029A true JPH04180029A (en) 1992-06-26

Family

ID=17991038

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2309275A Pending JPH04180029A (en) 1990-11-15 1990-11-15 Connecting structural body for circuit

Country Status (1)

Country Link
JP (1) JPH04180029A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995032449A1 (en) * 1994-05-20 1995-11-30 Seiko Epson Corporation Structure of conductive connecting portions, and liquid crystal display and electronic printer provided with the same
WO2014046093A1 (en) * 2012-09-24 2014-03-27 デクセリアルズ株式会社 Anisotropic conductive adhesive
WO2015056754A1 (en) * 2013-10-17 2015-04-23 デクセリアルズ株式会社 Anisotropic conductive adhesive and connection structure

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995032449A1 (en) * 1994-05-20 1995-11-30 Seiko Epson Corporation Structure of conductive connecting portions, and liquid crystal display and electronic printer provided with the same
WO2014046093A1 (en) * 2012-09-24 2014-03-27 デクセリアルズ株式会社 Anisotropic conductive adhesive
JP2014065766A (en) * 2012-09-24 2014-04-17 Dexerials Corp Anisotropic conductive adhesive
CN104662118A (en) * 2012-09-24 2015-05-27 迪睿合电子材料有限公司 Anisotropic conductive adhesive
EP2899245A4 (en) * 2012-09-24 2016-06-01 Dexerials Corp Anisotropic conductive adhesive
US9676066B2 (en) 2012-09-24 2017-06-13 Dexerials Corporation Anisotropic conductive adhesive
WO2015056754A1 (en) * 2013-10-17 2015-04-23 デクセリアルズ株式会社 Anisotropic conductive adhesive and connection structure

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