JPH0362727B2 - - Google Patents
Info
- Publication number
- JPH0362727B2 JPH0362727B2 JP58026897A JP2689783A JPH0362727B2 JP H0362727 B2 JPH0362727 B2 JP H0362727B2 JP 58026897 A JP58026897 A JP 58026897A JP 2689783 A JP2689783 A JP 2689783A JP H0362727 B2 JPH0362727 B2 JP H0362727B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- mol
- melt
- hydroquinone
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 125000003118 aryl group Chemical group 0.000 claims description 94
- 229920000728 polyester Polymers 0.000 claims description 78
- 239000000835 fiber Substances 0.000 claims description 24
- 239000002253 acid Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 8
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 3
- 150000002009 diols Chemical class 0.000 claims description 2
- -1 monosubstituted hydroquinones Chemical class 0.000 description 47
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 32
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 29
- 238000006243 chemical reaction Methods 0.000 description 26
- 238000000034 method Methods 0.000 description 26
- 150000001875 compounds Chemical class 0.000 description 21
- 238000006068 polycondensation reaction Methods 0.000 description 20
- 239000003054 catalyst Substances 0.000 description 15
- 238000010438 heat treatment Methods 0.000 description 13
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 12
- 238000002844 melting Methods 0.000 description 12
- 230000008018 melting Effects 0.000 description 12
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 10
- 239000000155 melt Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 9
- LMXZDVUCXQJEHS-UHFFFAOYSA-N 2-(1-phenylethyl)benzene-1,4-diol Chemical compound C=1C(O)=CC=C(O)C=1C(C)C1=CC=CC=C1 LMXZDVUCXQJEHS-UHFFFAOYSA-N 0.000 description 8
- XCZKKZXWDBOGPA-UHFFFAOYSA-N 2-phenylbenzene-1,4-diol Chemical class OC1=CC=C(O)C(C=2C=CC=CC=2)=C1 XCZKKZXWDBOGPA-UHFFFAOYSA-N 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 8
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 7
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 7
- HPGJOUYGWKFYQW-UHFFFAOYSA-N diphenyl benzene-1,4-dicarboxylate Chemical compound C=1C=C(C(=O)OC=2C=CC=CC=2)C=CC=1C(=O)OC1=CC=CC=C1 HPGJOUYGWKFYQW-UHFFFAOYSA-N 0.000 description 6
- 230000001747 exhibiting effect Effects 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 229910052787 antimony Inorganic materials 0.000 description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 4
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002074 melt spinning Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000005809 transesterification reaction Methods 0.000 description 4
- 238000004804 winding Methods 0.000 description 4
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229910052732 germanium Inorganic materials 0.000 description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 229910052718 tin Inorganic materials 0.000 description 3
- XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 description 2
- VJIDDJAKLVOBSE-UHFFFAOYSA-N 2-ethylbenzene-1,4-diol Chemical compound CCC1=CC(O)=CC=C1O VJIDDJAKLVOBSE-UHFFFAOYSA-N 0.000 description 2
- AULKDLUOQCUNOK-UHFFFAOYSA-N 3,5-dichloro-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC(Cl)=C(O)C(Cl)=C1 AULKDLUOQCUNOK-UHFFFAOYSA-N 0.000 description 2
- XMEQDAIDOBVHEK-UHFFFAOYSA-N 3-bromo-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(Br)=C1 XMEQDAIDOBVHEK-UHFFFAOYSA-N 0.000 description 2
- QGNLHMKIGMZKJX-UHFFFAOYSA-N 3-chloro-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(Cl)=C1 QGNLHMKIGMZKJX-UHFFFAOYSA-N 0.000 description 2
- LTFHNKUKQYVHDX-UHFFFAOYSA-N 4-hydroxy-3-methylbenzoic acid Chemical compound CC1=CC(C(O)=O)=CC=C1O LTFHNKUKQYVHDX-UHFFFAOYSA-N 0.000 description 2
- 150000005168 4-hydroxybenzoic acids Chemical group 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 125000001246 bromo group Chemical group Br* 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 229910000464 lead oxide Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 2
- 239000011654 magnesium acetate Substances 0.000 description 2
- 235000011285 magnesium acetate Nutrition 0.000 description 2
- 229940069446 magnesium acetate Drugs 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003504 terephthalic acids Chemical class 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- ZGSHFDSKHTZINF-UHFFFAOYSA-N (2-methyl-6-phenylphenyl) hydrogen carbonate Chemical compound CC1=CC=CC(C=2C=CC=CC=2)=C1OC(O)=O ZGSHFDSKHTZINF-UHFFFAOYSA-N 0.000 description 1
- NGHJLEBEDPZKHI-UHFFFAOYSA-N 1,3-diphenylnaphthalene-2,6-dicarboxylic acid Chemical compound OC(=O)C=1C(C=2C=CC=CC=2)=CC2=CC(C(=O)O)=CC=C2C=1C1=CC=CC=C1 NGHJLEBEDPZKHI-UHFFFAOYSA-N 0.000 description 1
- 125000004958 1,4-naphthylene group Chemical group 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- VUTICWRXMKBOSF-UHFFFAOYSA-N 2,5-dibromoterephthalic acid Chemical compound OC(=O)C1=CC(Br)=C(C(O)=O)C=C1Br VUTICWRXMKBOSF-UHFFFAOYSA-N 0.000 description 1
- 125000004959 2,6-naphthylene group Chemical group [H]C1=C([H])C2=C([H])C([*:1])=C([H])C([H])=C2C([H])=C1[*:2] 0.000 description 1
- XINMAGVSXCACDH-UHFFFAOYSA-N 2-(1-butylcyclohexyl)benzene-1,4-diol Chemical compound C=1C(O)=CC=C(O)C=1C1(CCCC)CCCCC1 XINMAGVSXCACDH-UHFFFAOYSA-N 0.000 description 1
- BKMYCIJAVZKRPQ-UHFFFAOYSA-N 2-(1-methylcyclohexyl)benzene-1,4-diol Chemical compound C=1C(O)=CC=C(O)C=1C1(C)CCCCC1 BKMYCIJAVZKRPQ-UHFFFAOYSA-N 0.000 description 1
- RDMIJQCFPQDYQN-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=CC=C1O RDMIJQCFPQDYQN-UHFFFAOYSA-N 0.000 description 1
- FKWOGPPGVRDIRZ-UHFFFAOYSA-N 2-(2-methylbutan-2-yl)benzene-1,4-diol Chemical compound CCC(C)(C)C1=CC(O)=CC=C1O FKWOGPPGVRDIRZ-UHFFFAOYSA-N 0.000 description 1
- PFTXJIDFNWHIFT-UHFFFAOYSA-N 2-(2-methylhexan-2-yl)benzene-1,4-diol Chemical compound CCCCC(C)(C)C1=CC(O)=CC=C1O PFTXJIDFNWHIFT-UHFFFAOYSA-N 0.000 description 1
- WWAUXRVRDGKTTA-UHFFFAOYSA-N 2-(2-methylpentan-2-yl)benzene-1,4-diol Chemical compound CCCC(C)(C)C1=CC(O)=CC=C1O WWAUXRVRDGKTTA-UHFFFAOYSA-N 0.000 description 1
- OFRAHNPFMRGJFL-UHFFFAOYSA-N 2-(2-phenylethyl)benzene-1,4-diol Chemical compound OC1=CC=C(O)C(CCC=2C=CC=CC=2)=C1 OFRAHNPFMRGJFL-UHFFFAOYSA-N 0.000 description 1
- LUELYTMQTXRXOI-UHFFFAOYSA-N 2-(2-phenylpropan-2-yl)benzene-1,4-diol Chemical compound C=1C(O)=CC=C(O)C=1C(C)(C)C1=CC=CC=C1 LUELYTMQTXRXOI-UHFFFAOYSA-N 0.000 description 1
- NTYIZBOVFIZNRO-UHFFFAOYSA-N 2-(4-butylcyclohexyl)benzene-1,4-diol Chemical compound C1CC(CCCC)CCC1C1=CC(O)=CC=C1O NTYIZBOVFIZNRO-UHFFFAOYSA-N 0.000 description 1
- TTZJAKPBLCJWBE-UHFFFAOYSA-N 2-(6,6-dimethylheptan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CCCC(C)C1=CC(O)=CC=C1O TTZJAKPBLCJWBE-UHFFFAOYSA-N 0.000 description 1
- JQACKWBUJFZIKS-UHFFFAOYSA-N 2-(naphthalen-1-ylmethyl)benzene-1,4-diol Chemical compound OC1=CC=C(O)C(CC=2C3=CC=CC=C3C=CC=2)=C1 JQACKWBUJFZIKS-UHFFFAOYSA-N 0.000 description 1
- NSBJQALAMJMQEZ-UHFFFAOYSA-N 2-(naphthalen-2-ylmethyl)benzene-1,4-diol Chemical compound OC1=CC=C(O)C(CC=2C=C3C=CC=CC3=CC=2)=C1 NSBJQALAMJMQEZ-UHFFFAOYSA-N 0.000 description 1
- CZKKYXUQBQAFCG-UHFFFAOYSA-N 2-[(2-butylphenyl)-phenylmethyl]benzene-1,4-diol Chemical compound CCCCC1=CC=CC=C1C(C=1C(=CC=C(O)C=1)O)C1=CC=CC=C1 CZKKYXUQBQAFCG-UHFFFAOYSA-N 0.000 description 1
- WNRZQBWYNZOMGQ-UHFFFAOYSA-N 2-[2-(4-methylphenyl)propan-2-yl]benzene-1,4-diol Chemical compound C1=CC(C)=CC=C1C(C)(C)C1=CC(O)=CC=C1O WNRZQBWYNZOMGQ-UHFFFAOYSA-N 0.000 description 1
- LISNKMZXPUZHMN-UHFFFAOYSA-N 2-benzhydrylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 LISNKMZXPUZHMN-UHFFFAOYSA-N 0.000 description 1
- REFDOIWRJDGBHY-UHFFFAOYSA-N 2-bromobenzene-1,4-diol Chemical compound OC1=CC=C(O)C(Br)=C1 REFDOIWRJDGBHY-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- 125000004182 2-chlorophenyl group Chemical group [H]C1=C([H])C(Cl)=C(*)C([H])=C1[H] 0.000 description 1
- ZPXGNBIFHQKREO-UHFFFAOYSA-N 2-chloroterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(Cl)=C1 ZPXGNBIFHQKREO-UHFFFAOYSA-N 0.000 description 1
- SNWSZCGYPHRJEY-UHFFFAOYSA-N 2-cyclohexylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C2CCCCC2)=C1 SNWSZCGYPHRJEY-UHFFFAOYSA-N 0.000 description 1
- NNTRLPYRNXLYPB-UHFFFAOYSA-N 2-cyclopentylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C2CCCC2)=C1 NNTRLPYRNXLYPB-UHFFFAOYSA-N 0.000 description 1
- 125000004198 2-fluorophenyl group Chemical group [H]C1=C([H])C(F)=C(*)C([H])=C1[H] 0.000 description 1
- VBGQEVXSPXTXAR-UHFFFAOYSA-N 2-heptan-2-ylbenzene-1,4-diol Chemical compound CCCCCC(C)C1=CC(O)=CC=C1O VBGQEVXSPXTXAR-UHFFFAOYSA-N 0.000 description 1
- LMNYOFWNRRDADM-UHFFFAOYSA-N 2-hexan-2-ylbenzene-1,4-diol Chemical compound CCCCC(C)C1=CC(O)=CC=C1O LMNYOFWNRRDADM-UHFFFAOYSA-N 0.000 description 1
- UFMBOFGKHIXOTA-UHFFFAOYSA-N 2-methylterephthalic acid Chemical compound CC1=CC(C(O)=O)=CC=C1C(O)=O UFMBOFGKHIXOTA-UHFFFAOYSA-N 0.000 description 1
- BANSWHXXYJGPAP-UHFFFAOYSA-N 2-octan-2-ylbenzene-1,4-diol Chemical compound CCCCCCC(C)C1=CC(O)=CC=C1O BANSWHXXYJGPAP-UHFFFAOYSA-N 0.000 description 1
- ACAFGTOPCUFNBP-UHFFFAOYSA-N 2-pentan-2-ylbenzene-1,4-diol Chemical compound CCCC(C)C1=CC(O)=CC=C1O ACAFGTOPCUFNBP-UHFFFAOYSA-N 0.000 description 1
- AMGSVJMOYVTZKK-UHFFFAOYSA-N 2-tritylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C(C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 AMGSVJMOYVTZKK-UHFFFAOYSA-N 0.000 description 1
- 125000004179 3-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(Cl)=C1[H] 0.000 description 1
- 125000004180 3-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C(F)=C1[H] 0.000 description 1
- PVFDJRIEGYDIEK-UHFFFAOYSA-N 3-tert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC=C1O PVFDJRIEGYDIEK-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- QLIQIXIBZLTPGQ-UHFFFAOYSA-N 4-(2-hydroxyethoxy)benzoic acid Chemical compound OCCOC1=CC=C(C(O)=O)C=C1 QLIQIXIBZLTPGQ-UHFFFAOYSA-N 0.000 description 1
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
- JTGCXYYDAVPSFD-UHFFFAOYSA-N 4-(4-hydroxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(O)C=C1 JTGCXYYDAVPSFD-UHFFFAOYSA-N 0.000 description 1
- PSAGPCOTGOTBQB-UHFFFAOYSA-N 4-hydroxynaphthalene-1-carboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(O)C2=C1 PSAGPCOTGOTBQB-UHFFFAOYSA-N 0.000 description 1
- YBKODUYVZRLSOK-UHFFFAOYSA-N 4-tert-butylbenzene-1,3-diol Chemical compound CC(C)(C)C1=CC=C(O)C=C1O YBKODUYVZRLSOK-UHFFFAOYSA-N 0.000 description 1
- KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 description 1
- OURWKHLDAVYMGO-UHFFFAOYSA-N 7-thiophen-2-ylpyrazolo[1,5-a]pyrimidine-3-carboxylic acid Chemical compound C=1C=NC2=C(C(=O)O)C=NN2C=1C1=CC=CS1 OURWKHLDAVYMGO-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- OGBVRMYSNSKIEF-UHFFFAOYSA-N Benzylphosphonic acid Chemical compound OP(O)(=O)CC1=CC=CC=C1 OGBVRMYSNSKIEF-UHFFFAOYSA-N 0.000 description 1
- 235000010893 Bischofia javanica Nutrition 0.000 description 1
- 240000005220 Bischofia javanica Species 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- WSFPUZLPKLZAIE-UHFFFAOYSA-N CC(C)COP(O)=O Chemical compound CC(C)COP(O)=O WSFPUZLPKLZAIE-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical class [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- INNSZZHSFSFSGS-UHFFFAOYSA-N acetic acid;titanium Chemical compound [Ti].CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O INNSZZHSFSFSGS-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- WXBLLCUINBKULX-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1 WXBLLCUINBKULX-UHFFFAOYSA-N 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- UOKRBSXOBUKDGE-UHFFFAOYSA-N butylphosphonic acid Chemical compound CCCCP(O)(O)=O UOKRBSXOBUKDGE-UHFFFAOYSA-N 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 239000004301 calcium benzoate Substances 0.000 description 1
- 235000010237 calcium benzoate Nutrition 0.000 description 1
- HZQXCUSDXIKLGS-UHFFFAOYSA-L calcium;dibenzoate;trihydrate Chemical compound O.O.O.[Ca+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 HZQXCUSDXIKLGS-UHFFFAOYSA-L 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- VGBWDOLBWVJTRZ-UHFFFAOYSA-K cerium(3+);triacetate Chemical compound [Ce+3].CC([O-])=O.CC([O-])=O.CC([O-])=O VGBWDOLBWVJTRZ-UHFFFAOYSA-K 0.000 description 1
- AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229940011182 cobalt acetate Drugs 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- VZEGPPPCKHRYGO-UHFFFAOYSA-N diethoxyphosphorylbenzene Chemical compound CCOP(=O)(OCC)C1=CC=CC=C1 VZEGPPPCKHRYGO-UHFFFAOYSA-N 0.000 description 1
- QLNYTKJCHFEIDA-UHFFFAOYSA-N dimethoxyphosphorylmethylbenzene Chemical compound COP(=O)(OC)CC1=CC=CC=C1 QLNYTKJCHFEIDA-UHFFFAOYSA-N 0.000 description 1
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 229910001867 inorganic solvent Inorganic materials 0.000 description 1
- 239000003049 inorganic solvent Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229960000869 magnesium oxide Drugs 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229940071125 manganese acetate Drugs 0.000 description 1
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- VYQNWZOUAUKGHI-UHFFFAOYSA-N monobenzone Chemical compound C1=CC(O)=CC=C1OCC1=CC=CC=C1 VYQNWZOUAUKGHI-UHFFFAOYSA-N 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- DFFZOPXDTCDZDP-UHFFFAOYSA-N naphthalene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1C(O)=O DFFZOPXDTCDZDP-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QKKWJYSVXDGOOJ-UHFFFAOYSA-N oxalic acid;oxotitanium Chemical compound [Ti]=O.OC(=O)C(O)=O QKKWJYSVXDGOOJ-UHFFFAOYSA-N 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000004300 potassium benzoate Substances 0.000 description 1
- 235000010235 potassium benzoate Nutrition 0.000 description 1
- 229940103091 potassium benzoate Drugs 0.000 description 1
- NSETWVJZUWGCKE-UHFFFAOYSA-N propylphosphonic acid Chemical compound CCCP(O)(O)=O NSETWVJZUWGCKE-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- RXSHXLOMRZJCLB-UHFFFAOYSA-L strontium;diacetate Chemical compound [Sr+2].CC([O-])=O.CC([O-])=O RXSHXLOMRZJCLB-UHFFFAOYSA-L 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 229940093635 tributyl phosphate Drugs 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229960000314 zinc acetate Drugs 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
- Artificial Filaments (AREA)
Description
ç£æ¥äžã®å©çšåé
æ¬çºæã¯æº¶èç°æ¹æ§å
šè³éŠæããªãšã¹ãã«ã«é¢
ãããããã«è©³ããã¯ãæ¬çºæã¯ç¹å®ã®çœ®æåºã§
æ žçœ®æãããã¢ã眮æãã€ããããã³ã«ç±æ¥ãã
åäœãå«æãã溶èç°æ¹æ§å šè³éŠæããªãšã¹ãã«
ã«é¢ããã該æ°èŠãªæº¶èç°æ¹æ§å šè³éŠæããªãšã¹
ãã«ã¯æº¶èç°æ¹æ§ã瀺ãã«ããããããããã®å
åŠçç°æ¹æ§æº¶èç©ãã容æã«æº¶èæ圢ããããšã
ã§ããæ©æ¢°çæ§è³ªã®åªããæ圢åãäŸãã°ç¹ç¶ãŸ
ãã¯ãã€ã«ã ãäžããã åŸæ¥æè¡ïŒœ åŸæ¥ãããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãã¯åªã
ãæ©æ¢°ç匷床ãæãããŸãèç±æ§ãèè¬åæ§çã«
åªããŠããããšãããç¹ç¶ããã€ã«ã ããã©ã¹ã
ãã¯çã®çŽ æãšããŠåºã䜿çšãããŠãããããã
ãªãããäŸãã°ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãç¹ç¶
ã¯å·¥æ¥çšéïŒäŸãã°ã¿ã€ã€ã³ãŒãçïŒã®ãããªé«
匷床ãé«ã€ã³ã°çãèŠæ±ãããçšéã«ãããŠã¯æª
ã ååãªãã®ã§ãããšã¯èšãé£ãã äžæ¹ã極ããŠé«ãã€ã³ã°çã匷床çãäžããç¹
ç¶çŽ æãšããŠãããªïœâããšãã¬ã³ãã¬ãã¿ã©ã
ããããªïœâãã³ã¶ããçã®è³éŠæããªã¢ããã
ç¥ãããŠããããããããããè³éŠæããªã¢ãã
ã¯ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãã溶è玡糞ã«ã
ã容æã«ç¹ç¶åã§ããã®ã«å¯Ÿãã溶è玡糞ãé£ã
ããå®éã«æº¶æ¶²çŽ¡ç³žïŒä¹ŸåŒãããã¯æ¹¿åŒçŽ¡ç³žïŒã«
ãã€ãŠç¹ç¶åããããåŸãªãç¶æ³ã«ããããã
æ ã溶å€ã®ååçãå¿ èŠã§ããä»ãåŸããã補å
ã®åœ¢ç¶ããã®æ圢æ¹æ³ã«ãã€ãŠå¶éãåããäŸã
ã°ç¹ç¶çã«éãããå·¥æ¥çã«ã¯æªã äžå©ãªç¹ã
å€ã æããŠããã ãããã®æ¬ ç¹ãæ¹è¯ããç®çã§ãè³éŠæãªãã·
ã«ã«ãã³é žãè³éŠæãžããããã·ååç©ããã³ã
ã¬ãã¿ã«é žãã€ãœãã¿ã«é žã®åŠãè³éŠæãžã«ã«ã
ã³é žæåãããªãå šè³éŠæã³ããªãšã¹ãã«ããã³
ãã®ç¹ç¶ãææ¡ãããŠããïŒç¹éæ50â43223å·
å ¬å ±ïŒããããããã®å Žåã«ãããžã«ã«ãã³é žæ
åãšããŠäŸãã°ïœâé åæ§ã§ãããã¬ãã¿ã«é žã
çšããå šè³éŠæããªãšã¹ãã«ã¯æ¥µããŠé«èç¹ãšãª
ããåŸã€ãŠé«éå床ã®ããªããŒã補é ãåŸããšã
ãŠã溶èæ圢ãäŸãã°æº¶è玡糞ã«ãã€ãŠæ圢ãã
ããšèªäœãå°é£ã§ããããŸãããã®ããé«åŒ·åºŠã
é«ã€ã³ã°çãæããæ圢åãäŸãã°ç¹ç¶ãå·¥æ¥ç
ã«ããã€å¹ççã«è£œé ããããšã¯å°é£ã§ããã äžæ¹ããžã«ã«ãã³é žæåãšããŠïœâé åæ§ã§ãª
ãäŸãã°ã€ãœãã¿ã«é žãçšããå šè³éŠæããªãšã¹
ãã«ã¯ã溶èç²åºŠããã¬ãã¿ã«é žãçšããäžèšã®
åŠãå šè³éŠæããªãšã¹ãã«ã«æ¯ããŠå€§å¹ ã«äœãã
ãã€æº¶èæ圢ã§ããå©ç¹ãæããããåé¢ã溶è
ç°æ¹æ§ãæããªãããšããã溶èæ圢ã®ã¿ã«ãã€
ãŠæ©æ¢°çæ§è³ªãäŸãã°ã€ã³ã°ççã®åªããæ圢
åãäŸãã°ç¹ç¶ããã€ã«ã ã補é ã§ããªããšãã
æ¬ ç¹ãæããŠããã äžèšæ现æžã«ã¯è³éŠæãžããããã·ååç©ãšã
ãŠãããã«ãã€ããããã³ãé瀺ãããŠãããã
ããã«ãã€ããããã³ãçšããå šè³éŠæããªãšã¹
ãã«ã®ã¿ãªããããã®è£œæ³ã¯èšèŒã瀺åããããŠ
ããªãã ãŸãããžã«ã«ãã³é žæåãšããŠãã¬ãã¿ã«é žãŸ
ãã¯ïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é žãçšããè³
éŠæãžããããã·ååç©ãšããŠæªçœ®æããšãã«ã
ã€ããããã³ãŸãã¯çœ®æããšãã«ãã€ããããã³
ãçšããå åŠç°æ¹æ§å šè³éŠæããªãšã¹ãã«ãç¥ã
ããŠããïŒç±³åœç¹èš±ç¬¬4159365å·ããã³4153779å·
æ现æžåç §ïŒãæªçœ®æããšãã«ãã€ããããã³ã
çšããŠåŸãããå šè³éŠæããªãšã¹ãã«ããã®ç¹ç¶
ã¯é«æž©ã«ããã匷床ä¿æçãé«ãç¹é·ãæããã
ãšãç±³åœç¹èš±ç¬¬4159365å·æ现æžã«é瀺ãããŠã
ãã ãŸããç¹éæ56â84718å·æ现æžã«ã¯äž»ããè³
éŠæãžããããã·ååç©ãšããŠæªçœ®æããšãã«ã
ã€ããããã³ãšãšãã«ãã€ããããã³ãçšããå š
è³éŠæããªãšã¹ãã«ãé瀺ãããŠããããããã®
å šè³éŠæããªãšã¹ãã«ã¯ãã€ããããã³ãå šãã
ããã·æåã«å¯Ÿã50ã30ã¢ã«ïŒ ãšæ¯èŒçå€éã«çš
ããŠããã«ããããããæ¯èŒçé«ãèç¹ãæããŠ
ããç¹ã§ç¹åŸŽçã§ããããŸããææ©æº¶åªã«æº¶è§£ã
é£ãæ§è³ªãæããŠããã çºæã®ç®ç æ¬çºæã®ç®çã¯ãæ°èŠãªæº¶èç°æ¹æ§ã瀺ãå šè³
éŠæããªãšã¹ãã«ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ã溶èç°æ¹æ§ã瀺ãã«ãã
ããããæ¯èŒçèç¹ããã³æµåéå§æž©åºŠãäœãã
å åŠçç°æ¹æ§æº¶èç©ãã容æã«æº¶èæ圢ããããš
ãã§ãããæ°èŠãªæº¶èç°æ¹æ§å šè³éŠæããªãšã¹ã
ã«ãæäŸããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ã溶èæ圢ã®ã¿ãªã
ã溶液æ圢ãå¯èœãªææ©æº¶åªã«å¯Ÿããåªãã溶解
æ§ã瀺ãå šè³éŠæ§ããªãšã¹ãã«ã§ãããããæ ã
æ圢æ³ã®çžéã«åºã¥ãæ§èœã®å¶åŸ¡ãè¡ãããšã®å¯
èœãªæ圢æ§ã®åªããå šè³éŠæããªãšã¹ãã«ãæäŸ
ããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ãä»æ¹ã§ã¯ã溶èæ
圢ã容æã§ããããããææ©æº¶åªãŸãã¯ç¡æ©æº¶åª
ã«å¯ŸããŠåªããè溶å€æ§ã瀺ãå šè³éŠæããªãšã¹
ãã«ãæäŸããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ã溶èæ圢ã«ãã€ãŠ
åªããæ©æ¢°çæ§è³ªãäŸãã°åŒ·åºŠãã€ã³ã°ççã瀺
ãæ圢åãäžããããšã®ã§ãããæ°èŠãªå šè³éŠæ
ããªãšã¹ãã«ãæäŸããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ãé«æž©ã«ãããæ©æ¢°
çæ§è³ªã®ä¿æçã®é«ãæ圢åãäžãããç±å®å®æ§
ã®åªããå šè³éŠæããªãšã¹ãã«ãæäŸããããšã«
ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ãæ¯èŒçèç¹ããã³
æµãéå§æž©åºŠãäœããããæ 溶èæ圢枩床ãæ¯èŒ
çäœãããããšãã§ããæ圢æã®å ç±ã«ããç±å£
åãããã¯é žåå£åã極åæå¶ããŠåªããæ§èœã
åããæ圢åãäžãããå šè³éŠæããªãšã¹ãã«ã
æäŸããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ãæ¯èŒçèç¹ããã³
æµãéå§æž©åºŠãäœããããæ éåäœã補é ããé
ã®éå枩床ãæ¯èŒçäœãããããšãã§ããéåäœ
補é æã®ç±å£åãããã¯é žåå£åã極åæå¶ãã
é«éåäœã®å šè³éŠæããªãšã¹ãã«ãæäŸããããš
ã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ã以äžã®èª¬æããæ
ãããšãªããã çºæã®æ§æãå¹æ æ¬çºæã®ãããç®çããã³å©ç¹ã¯ãæ¬çºæã«ã
ãã°ãããªãšã¹ãã«ã®æ§æåäœãå®è³ªçã«äžèš
ãšïŒ»ïŒœããŸãã¯äžèšïŒ»ïŒœãšïŒ»ïŒœãš
ãšãããªãè³éŠæããªãšã¹ãã«ã§ãã€ãŠã âCOâArâ²âCOâ âŠâŠïŒ»ïŒœ ããã§Arâ²ã¯ïŒ°âé åæ§ã®ãã³ãŒã³ãŸãã¯ãã
ã¿ã¬ã³ã§ããã ããã§ãã¯
ãããããã«è©³ããã¯ãæ¬çºæã¯ç¹å®ã®çœ®æåºã§
æ žçœ®æãããã¢ã眮æãã€ããããã³ã«ç±æ¥ãã
åäœãå«æãã溶èç°æ¹æ§å šè³éŠæããªãšã¹ãã«
ã«é¢ããã該æ°èŠãªæº¶èç°æ¹æ§å šè³éŠæããªãšã¹
ãã«ã¯æº¶èç°æ¹æ§ã瀺ãã«ããããããããã®å
åŠçç°æ¹æ§æº¶èç©ãã容æã«æº¶èæ圢ããããšã
ã§ããæ©æ¢°çæ§è³ªã®åªããæ圢åãäŸãã°ç¹ç¶ãŸ
ãã¯ãã€ã«ã ãäžããã åŸæ¥æè¡ïŒœ åŸæ¥ãããããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãã¯åªã
ãæ©æ¢°ç匷床ãæãããŸãèç±æ§ãèè¬åæ§çã«
åªããŠããããšãããç¹ç¶ããã€ã«ã ããã©ã¹ã
ãã¯çã®çŽ æãšããŠåºã䜿çšãããŠãããããã
ãªãããäŸãã°ããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãç¹ç¶
ã¯å·¥æ¥çšéïŒäŸãã°ã¿ã€ã€ã³ãŒãçïŒã®ãããªé«
匷床ãé«ã€ã³ã°çãèŠæ±ãããçšéã«ãããŠã¯æª
ã ååãªãã®ã§ãããšã¯èšãé£ãã äžæ¹ã極ããŠé«ãã€ã³ã°çã匷床çãäžããç¹
ç¶çŽ æãšããŠãããªïœâããšãã¬ã³ãã¬ãã¿ã©ã
ããããªïœâãã³ã¶ããçã®è³éŠæããªã¢ããã
ç¥ãããŠããããããããããè³éŠæããªã¢ãã
ã¯ãããªãšãã¬ã³ãã¬ãã¿ã¬ãŒãã溶è玡糞ã«ã
ã容æã«ç¹ç¶åã§ããã®ã«å¯Ÿãã溶è玡糞ãé£ã
ããå®éã«æº¶æ¶²çŽ¡ç³žïŒä¹ŸåŒãããã¯æ¹¿åŒçŽ¡ç³žïŒã«
ãã€ãŠç¹ç¶åããããåŸãªãç¶æ³ã«ããããã
æ ã溶å€ã®ååçãå¿ èŠã§ããä»ãåŸããã補å
ã®åœ¢ç¶ããã®æ圢æ¹æ³ã«ãã€ãŠå¶éãåããäŸã
ã°ç¹ç¶çã«éãããå·¥æ¥çã«ã¯æªã äžå©ãªç¹ã
å€ã æããŠããã ãããã®æ¬ ç¹ãæ¹è¯ããç®çã§ãè³éŠæãªãã·
ã«ã«ãã³é žãè³éŠæãžããããã·ååç©ããã³ã
ã¬ãã¿ã«é žãã€ãœãã¿ã«é žã®åŠãè³éŠæãžã«ã«ã
ã³é žæåãããªãå šè³éŠæã³ããªãšã¹ãã«ããã³
ãã®ç¹ç¶ãææ¡ãããŠããïŒç¹éæ50â43223å·
å ¬å ±ïŒããããããã®å Žåã«ãããžã«ã«ãã³é žæ
åãšããŠäŸãã°ïœâé åæ§ã§ãããã¬ãã¿ã«é žã
çšããå šè³éŠæããªãšã¹ãã«ã¯æ¥µããŠé«èç¹ãšãª
ããåŸã€ãŠé«éå床ã®ããªããŒã補é ãåŸããšã
ãŠã溶èæ圢ãäŸãã°æº¶è玡糞ã«ãã€ãŠæ圢ãã
ããšèªäœãå°é£ã§ããããŸãããã®ããé«åŒ·åºŠã
é«ã€ã³ã°çãæããæ圢åãäŸãã°ç¹ç¶ãå·¥æ¥ç
ã«ããã€å¹ççã«è£œé ããããšã¯å°é£ã§ããã äžæ¹ããžã«ã«ãã³é žæåãšããŠïœâé åæ§ã§ãª
ãäŸãã°ã€ãœãã¿ã«é žãçšããå šè³éŠæããªãšã¹
ãã«ã¯ã溶èç²åºŠããã¬ãã¿ã«é žãçšããäžèšã®
åŠãå šè³éŠæããªãšã¹ãã«ã«æ¯ããŠå€§å¹ ã«äœãã
ãã€æº¶èæ圢ã§ããå©ç¹ãæããããåé¢ã溶è
ç°æ¹æ§ãæããªãããšããã溶èæ圢ã®ã¿ã«ãã€
ãŠæ©æ¢°çæ§è³ªãäŸãã°ã€ã³ã°ççã®åªããæ圢
åãäŸãã°ç¹ç¶ããã€ã«ã ã補é ã§ããªããšãã
æ¬ ç¹ãæããŠããã äžèšæ现æžã«ã¯è³éŠæãžããããã·ååç©ãšã
ãŠãããã«ãã€ããããã³ãé瀺ãããŠãããã
ããã«ãã€ããããã³ãçšããå šè³éŠæããªãšã¹
ãã«ã®ã¿ãªããããã®è£œæ³ã¯èšèŒã瀺åããããŠ
ããªãã ãŸãããžã«ã«ãã³é žæåãšããŠãã¬ãã¿ã«é žãŸ
ãã¯ïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é žãçšããè³
éŠæãžããããã·ååç©ãšããŠæªçœ®æããšãã«ã
ã€ããããã³ãŸãã¯çœ®æããšãã«ãã€ããããã³
ãçšããå åŠç°æ¹æ§å šè³éŠæããªãšã¹ãã«ãç¥ã
ããŠããïŒç±³åœç¹èš±ç¬¬4159365å·ããã³4153779å·
æ现æžåç §ïŒãæªçœ®æããšãã«ãã€ããããã³ã
çšããŠåŸãããå šè³éŠæããªãšã¹ãã«ããã®ç¹ç¶
ã¯é«æž©ã«ããã匷床ä¿æçãé«ãç¹é·ãæããã
ãšãç±³åœç¹èš±ç¬¬4159365å·æ现æžã«é瀺ãããŠã
ãã ãŸããç¹éæ56â84718å·æ现æžã«ã¯äž»ããè³
éŠæãžããããã·ååç©ãšããŠæªçœ®æããšãã«ã
ã€ããããã³ãšãšãã«ãã€ããããã³ãçšããå š
è³éŠæããªãšã¹ãã«ãé瀺ãããŠããããããã®
å šè³éŠæããªãšã¹ãã«ã¯ãã€ããããã³ãå šãã
ããã·æåã«å¯Ÿã50ã30ã¢ã«ïŒ ãšæ¯èŒçå€éã«çš
ããŠããã«ããããããæ¯èŒçé«ãèç¹ãæããŠ
ããç¹ã§ç¹åŸŽçã§ããããŸããææ©æº¶åªã«æº¶è§£ã
é£ãæ§è³ªãæããŠããã çºæã®ç®ç æ¬çºæã®ç®çã¯ãæ°èŠãªæº¶èç°æ¹æ§ã瀺ãå šè³
éŠæããªãšã¹ãã«ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ã溶èç°æ¹æ§ã瀺ãã«ãã
ããããæ¯èŒçèç¹ããã³æµåéå§æž©åºŠãäœãã
å åŠçç°æ¹æ§æº¶èç©ãã容æã«æº¶èæ圢ããããš
ãã§ãããæ°èŠãªæº¶èç°æ¹æ§å šè³éŠæããªãšã¹ã
ã«ãæäŸããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ã溶èæ圢ã®ã¿ãªã
ã溶液æ圢ãå¯èœãªææ©æº¶åªã«å¯Ÿããåªãã溶解
æ§ã瀺ãå šè³éŠæ§ããªãšã¹ãã«ã§ãããããæ ã
æ圢æ³ã®çžéã«åºã¥ãæ§èœã®å¶åŸ¡ãè¡ãããšã®å¯
èœãªæ圢æ§ã®åªããå šè³éŠæããªãšã¹ãã«ãæäŸ
ããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ãä»æ¹ã§ã¯ã溶èæ
圢ã容æã§ããããããææ©æº¶åªãŸãã¯ç¡æ©æº¶åª
ã«å¯ŸããŠåªããè溶å€æ§ã瀺ãå šè³éŠæããªãšã¹
ãã«ãæäŸããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ã溶èæ圢ã«ãã€ãŠ
åªããæ©æ¢°çæ§è³ªãäŸãã°åŒ·åºŠãã€ã³ã°ççã瀺
ãæ圢åãäžããããšã®ã§ãããæ°èŠãªå šè³éŠæ
ããªãšã¹ãã«ãæäŸããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ãé«æž©ã«ãããæ©æ¢°
çæ§è³ªã®ä¿æçã®é«ãæ圢åãäžãããç±å®å®æ§
ã®åªããå šè³éŠæããªãšã¹ãã«ãæäŸããããšã«
ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ãæ¯èŒçèç¹ããã³
æµãéå§æž©åºŠãäœããããæ 溶èæ圢枩床ãæ¯èŒ
çäœãããããšãã§ããæ圢æã®å ç±ã«ããç±å£
åãããã¯é žåå£åã極åæå¶ããŠåªããæ§èœã
åããæ圢åãäžãããå šè³éŠæããªãšã¹ãã«ã
æäŸããããšã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ãæ¯èŒçèç¹ããã³
æµãéå§æž©åºŠãäœããããæ éåäœã補é ããé
ã®éå枩床ãæ¯èŒçäœãããããšãã§ããéåäœ
補é æã®ç±å£åãããã¯é žåå£åã極åæå¶ãã
é«éåäœã®å šè³éŠæããªãšã¹ãã«ãæäŸããããš
ã«ããã æ¬çºæã®ããã«ä»ã®ç®çã¯ã以äžã®èª¬æããæ
ãããšãªããã çºæã®æ§æãå¹æ æ¬çºæã®ãããç®çããã³å©ç¹ã¯ãæ¬çºæã«ã
ãã°ãããªãšã¹ãã«ã®æ§æåäœãå®è³ªçã«äžèš
ãšïŒ»ïŒœããŸãã¯äžèšïŒ»ïŒœãšïŒ»ïŒœãš
ãšãããªãè³éŠæããªãšã¹ãã«ã§ãã€ãŠã âCOâArâ²âCOâ âŠâŠïŒ»ïŒœ ããã§Arâ²ã¯ïŒ°âé åæ§ã®ãã³ãŒã³ãŸãã¯ãã
ã¿ã¬ã³ã§ããã ããã§ãã¯
ãåŒãã§ç€ºããã
ççŽ æ°ïŒã10ã®ã¢ã©ã«ãã«åºã§ãããã¯æ°ŽçŽ ãŸ
ãã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºã§ããã ããã§ãã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯
ããã²ã³ååã§ãããïœã¯ïŒãŸãã¯ïŒã§ããã ãã€å šé žæåäžã«ãããäžèšïŒ»ïŒœã®å²åãçŽ90
ã¢ã«ïŒ 以äžã§ããã ãã€å šãžãªãŒã«æåäžã«ãããäžèšïŒ»ïŒœã®å²å
ã§çŽ80ã¢ã«ïŒ 以äžã§ããã ãããŠãå šæ§æåäœäžã®äžèšïŒ»ïŒœãå«ãŸããå Ž
åã¯å šãªãã·ã«ã«ãã³é žæåäžã®çŽ70ã¢ã«ïŒ 以äž
ãäžèšïŒ»ïŒœã§ããããã€äžèšïŒ»ïŒœãšïŒ»ïŒœã¯
ããããå šæ§æåäœã®å°ãªããšãçŽïŒã¢ã«ïŒ 以äž
ã§ããã該ããªããŒã®åºæç²åºŠã0.8以äžã§ãã
ããšãç¹åŸŽãšãã ç¹ç¶ãŸãã¯ãã€ã«ã 圢ææ§ã®æº¶èç°æ¹æ§å šè³éŠæ
ããªãšã¹ãã«ã«ãã€ãŠéæãããã ããã§äžèšïŒ»ïŒœïŒïŒ»ïŒœïŒïŒ»ïŒœã¯ããããè³éŠ
æãžã«ã«ãã³é žã«ç±æ¥ããåäœ(a)ãè³éŠæãžãã
ããã·ååç©ã«ç±æ¥ããåäœ(b)ãâé åæ§è³éŠ
æãªãã·ã«ã«ãã³é žã«ç±æ¥ããåäœ(c)ã§ãããå š
æ§æåäœäžã«äžèšïŒ»ïŒœãå«ãŸããå šè³éŠæããª
ãšã¹ãã«ã¯ãäžèšïŒ»ïŒœãäž»ããæ§æåäœãšããŠ
å«æããŠããç¹ã§äžèšïŒ»ïŒœã®å šè³éŠæããªãšã¹
ãã«ãšç°ãªã€ãŠãããããããã®å šè³éŠæããªãš
ã¹ãã«ãäžèšïŒ»ïŒœããã³ïŒ»ïŒœã®åäœç¹ã«æ¬çº
æã®ç¹åŸŽã®äžã€ã§ããã
ãã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºã§ããã ããã§ãã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯
ããã²ã³ååã§ãããïœã¯ïŒãŸãã¯ïŒã§ããã ãã€å šé žæåäžã«ãããäžèšïŒ»ïŒœã®å²åãçŽ90
ã¢ã«ïŒ 以äžã§ããã ãã€å šãžãªãŒã«æåäžã«ãããäžèšïŒ»ïŒœã®å²å
ã§çŽ80ã¢ã«ïŒ 以äžã§ããã ãããŠãå šæ§æåäœäžã®äžèšïŒ»ïŒœãå«ãŸããå Ž
åã¯å šãªãã·ã«ã«ãã³é žæåäžã®çŽ70ã¢ã«ïŒ 以äž
ãäžèšïŒ»ïŒœã§ããããã€äžèšïŒ»ïŒœãšïŒ»ïŒœã¯
ããããå šæ§æåäœã®å°ãªããšãçŽïŒã¢ã«ïŒ 以äž
ã§ããã該ããªããŒã®åºæç²åºŠã0.8以äžã§ãã
ããšãç¹åŸŽãšãã ç¹ç¶ãŸãã¯ãã€ã«ã 圢ææ§ã®æº¶èç°æ¹æ§å šè³éŠæ
ããªãšã¹ãã«ã«ãã€ãŠéæãããã ããã§äžèšïŒ»ïŒœïŒïŒ»ïŒœïŒïŒ»ïŒœã¯ããããè³éŠ
æãžã«ã«ãã³é žã«ç±æ¥ããåäœ(a)ãè³éŠæãžãã
ããã·ååç©ã«ç±æ¥ããåäœ(b)ãâé åæ§è³éŠ
æãªãã·ã«ã«ãã³é žã«ç±æ¥ããåäœ(c)ã§ãããå š
æ§æåäœäžã«äžèšïŒ»ïŒœãå«ãŸããå šè³éŠæããª
ãšã¹ãã«ã¯ãäžèšïŒ»ïŒœãäž»ããæ§æåäœãšããŠ
å«æããŠããç¹ã§äžèšïŒ»ïŒœã®å šè³éŠæããªãšã¹
ãã«ãšç°ãªã€ãŠãããããããã®å šè³éŠæããªãš
ã¹ãã«ãäžèšïŒ»ïŒœããã³ïŒ»ïŒœã®åäœç¹ã«æ¬çº
æã®ç¹åŸŽã®äžã€ã§ããã
ãåŒãïŒããã§ãã¯æ°ŽçŽ ãŸãã¯
ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºã§ããïŒã§ç€ºãããç
çŽ æ°ïŒã10ã®ã¢ã©ã«ãã«åºã§æ žçœ®æãããã¢ã眮
æãã€ããããã³ã«ç±æ¥ããåäœãå«æããç¹ã§
å ±éããŠããããŸãããããã®å šè³éŠæããªãšã¹
ãã«ã®ååéãçŽç·æ§ã«åªããå åŠç°æ¹æ§æº¶èç©
ãäžããç¹ã«ãããŠãå ±éããŠããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã圢æããè³éŠ
æãžã«ã«ãã³é žã«ç±æ¥ããåäœ(a)ã¯ãïœâé åæ§
è³éŠæãžã«ã«ãã³é žã«ç±æ¥ããåäœã«ãã€ãŠãã®
çŽ90ã¢ã«ïŒ 以äžãå ããããŠãããããã§ïœâé
åæ§è³éŠæãžã«ã«ãã³é žãšã¯ãè³éŠæ žã«çµåããŠ
ããïŒåã®ã«ã«ããã·ã«åºãïŒïŒïŒâããšãã¬
ã³ãïŒïŒïŒâãããã¬ã³ã®åŠãè³éŠæ žäžã«å軞ç
ã«å察äœçœ®ã«é 眮ããŠãããããŸãã¯ïŒïŒïŒâã
ããã¬ã³ãïŒïŒïŒâãããã¬ã³ã®åŠãè€æ°ã®ãã³
ãŒã³ç°ãçŽæ¥çž®åãŸãã¯çµåããŠãã該è€æ°ã®ã
ã³ãŒã³ç°ãããªãè³éŠæ žäžã«å¹³è¡è»žçã«å察äœçœ®
ãŸãã¯å¯Ÿç§°äœçœ®ã«é 眮ããŠããè³éŠæãžã«ã«ãã³
é žãããã ïœâé åæ§è³éŠæãžã«ã«ãã³é žãšããŠã¯ãäŸã
ã°ãã¬ãã¿ã«é žãã¯ãã«ãã¬ãã¿ã«é žãããã ã
ã¬ãã¿ã«é žãïŒïŒïŒâãžããã ãã¬ãã¿ã«é žãã¡
ãã«ãã¬ãã¿ã«é žã®åŠããã¬ãã¿ã«é žé¡ïŒïŒïŒïŒ
âããã¿ã¬ã³ãžã«ã«ãã³é žãïŒïŒïŒâããã¿ã¬ã³
ãžã«ã«ãã³é žãïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é ž
ã®åŠãããã¿ã¬ã³ãžã«ã«ãã³é žé¡ãæããããšã
ã§ããããããã¯ïŒçš®ãŸãã¯ïŒçš®ä»¥äžäžç·ã«çšã
ãããããããã®ãã¡ããã¬ãã¿ã«é žé¡ãç¹ã«ã
ã¬ãã¿ã«é žã奜ãŸããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã圢æããè³éŠ
æãžããããã·ååç©ã«ç±æ¥ããåäœ(b)ã¯ã
çŽ æ°ïŒã10ã®ã¢ã©ã«ãã«åºã§æ žçœ®æãããã¢ã眮
æãã€ããããã³ã«ç±æ¥ããåäœãå«æããç¹ã§
å ±éããŠããããŸãããããã®å šè³éŠæããªãšã¹
ãã«ã®ååéãçŽç·æ§ã«åªããå åŠç°æ¹æ§æº¶èç©
ãäžããç¹ã«ãããŠãå ±éããŠããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã圢æããè³éŠ
æãžã«ã«ãã³é žã«ç±æ¥ããåäœ(a)ã¯ãïœâé åæ§
è³éŠæãžã«ã«ãã³é žã«ç±æ¥ããåäœã«ãã€ãŠãã®
çŽ90ã¢ã«ïŒ 以äžãå ããããŠãããããã§ïœâé
åæ§è³éŠæãžã«ã«ãã³é žãšã¯ãè³éŠæ žã«çµåããŠ
ããïŒåã®ã«ã«ããã·ã«åºãïŒïŒïŒâããšãã¬
ã³ãïŒïŒïŒâãããã¬ã³ã®åŠãè³éŠæ žäžã«å軞ç
ã«å察äœçœ®ã«é 眮ããŠãããããŸãã¯ïŒïŒïŒâã
ããã¬ã³ãïŒïŒïŒâãããã¬ã³ã®åŠãè€æ°ã®ãã³
ãŒã³ç°ãçŽæ¥çž®åãŸãã¯çµåããŠãã該è€æ°ã®ã
ã³ãŒã³ç°ãããªãè³éŠæ žäžã«å¹³è¡è»žçã«å察äœçœ®
ãŸãã¯å¯Ÿç§°äœçœ®ã«é 眮ããŠããè³éŠæãžã«ã«ãã³
é žãããã ïœâé åæ§è³éŠæãžã«ã«ãã³é žãšããŠã¯ãäŸã
ã°ãã¬ãã¿ã«é žãã¯ãã«ãã¬ãã¿ã«é žãããã ã
ã¬ãã¿ã«é žãïŒïŒïŒâãžããã ãã¬ãã¿ã«é žãã¡
ãã«ãã¬ãã¿ã«é žã®åŠããã¬ãã¿ã«é žé¡ïŒïŒïŒïŒ
âããã¿ã¬ã³ãžã«ã«ãã³é žãïŒïŒïŒâããã¿ã¬ã³
ãžã«ã«ãã³é žãïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é ž
ã®åŠãããã¿ã¬ã³ãžã«ã«ãã³é žé¡ãæããããšã
ã§ããããããã¯ïŒçš®ãŸãã¯ïŒçš®ä»¥äžäžç·ã«çšã
ãããããããã®ãã¡ããã¬ãã¿ã«é žé¡ãç¹ã«ã
ã¬ãã¿ã«é žã奜ãŸããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã圢æããè³éŠ
æãžããããã·ååç©ã«ç±æ¥ããåäœ(b)ã¯ã
ãåŒãïŒããã§ãã¯æ°ŽçŽ ãŸãã¯
ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºã§ããïŒã§ç€ºãããç
çŽ æ°ïŒã10ã®ã¢ã©ã«ãã«åºã§æ žçœ®æãããã¢ã眮
æãã€ããããã³ã«ç±æ¥ããåäœãçŽ80ã¢ã«ïŒ 以
äžã§å«æããã ã®ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãšããŠã¯ãäŸã
ã°ã¡ãã«ããšãã«ããããã«çãæããããšãã§
ããã ãããã¢ã眮æãã€ããããã³ã¯ããã€ããã
ãã³ãšçžåœããã¢ã«ã³ãŒã«ãŸãã¯ããã«æ§äºéçµ
åãæããäžé£œåååç©ãšãããªã³é žãŸãã¯ç¡«é ž
çã®é žæ§è§Šåªã®ååšäžãè³éŠæçåæ°ŽçŽ ãäŸãã°
ãã³ãŒã³äžã§å ç±åå¿ãããããããèªäœå ¬ç¥ã®
æ¹æ³ã«ãã€ãŠè£œé ããããšãã§ããã äžèšè³éŠæãžããããã·ååç©ã«ç±æ¥ããåäœ
(b)ã¯ãã¢ã眮æãã€ããããã³ã«ç±æ¥ããåäœä»¥
å€ã®çœ®æãã€ããããã³ãçŽ20ã¢ã«ïŒ 以äžã§å«æ
ããŠããŠããããããããã®ä»ã®çœ®æãã€ããã
ãã³ã¯ã奜ãŸããã¯ççŽ æ°ïŒã10ã®ã¢ã«ãã«åºã
äŸãã°ã¡ãã«ããšãã«ããããã«ãããã«ããã³
ãã«ãããã·ã«ããããã«ããªã¯ãã«ãããã«ã
ãã·ã«çããããã¯ççŽ æ°ïŒã10ã®ç¬¬ïŒçŽã¢ã©ã«
ãã«åºãäŸãã°ïŒâããšãã«ãããâïŒâã€ã«ã
ïŒâïŒïœïŒïœâãŸãã¯ïœâã¯ããããšãã«ïŒãã
ãâïŒâã€ã«ãïŒâïŒïœâïŒïœâãŸãã¯ïœâãã«
ãªãããšãã«ïŒãããâïŒâã€ã«ãïŒâïŒïœâã
ãã¢ããšãã«ïŒãããâïŒâã€ã«ãïŒâïŒïœâãš
ãŒãããšãã«ïŒãããâïŒâã€ã«çããããã¯ç
çŽ æ°11以äžã®ã¢ã©ã«ãã«åºãäŸãã°ïŒâïŒããã
âïŒâãŸãã¯âïŒâã€ã«ïŒãããâïŒâã€ã«ãïŒ
âïŒâïŒïŒâãŸãã¯ïŒâïŒïŒâC1ã3ã¢ã«ãã«âã
ããâïŒâã€ã«ïŒããšãã«ïŒœâãããâïŒâã€ã«
çããããã¯ããã²ã³ååãäŸãã°ã¯ãããŸãã¯
ããã¢ã«ãã€ãŠçœ®æããããã€ããããã³ã§ã
ãã ããã眮æãã€ããããã³ãšããŠã¯ãäŸãã°ã¡
ãã«ãã€ããããã³ããšãã«ãã€ããããã³ãïœ
âããã«ãã€ããããã³ãã¯ãããã€ãããã
ã³ãããã¢ãã€ããããã³ãïŒâïœâã¢ãã«ãã€
ããããã³ãïŒâïœâããã·ã«ãã€ããããã³ã
ïŒâïœâãããã«ãã€ããããã³ãïŒâïœâãªã¯
ãã«ãã€ããããã³ãïŒâïœâããã«ãã€ããã
ãã³ãïŒâïœâãã·ã«ãã€ããããã³ãïŒâïŒïŒïŒ
ïŒïŒïŒâããªã¡ãã«ããã·ã«âïŒâã€ã«ïŒãã€ã
ãããã³ãïŒâïŒïŒïŒïŒïŒïŒâããªã¡ãã«ããã
ã«âïŒâã€ã«ïŒãã€ããããã³ãïŒâsecâã¢ã
ã«ãã€ããããã³ãïŒâsecâããã·ã«ãã€ãã
ããã³ãïŒâsecâãããã«ãã€ããããã³ãïŒ
âsecâãªã¯ãã«ãã€ããããã³ãïŒâïŒïŒïŒïŒâ
ãžã¡ãã«ãããâïŒâã€ã«ïŒãã€ããããã³ïŒïŒ
âïŒïŒâããšãã«ãããâïŒâã€ã«ïŒãã€ããã
ãã³ãïŒâïŒâïŒïŒâã¡ãã«ããšãã«ïŒãããâ
ïŒâã€ã«ïŒœãã€ããããã³ãïŒãžããšãã«ã¡ãã«ïŒ
ãã€ããããã³ãïŒããšãã«ïŒâããªã¡ãã«ïŒã
ã€ããããã³ãïŒããšãã«ïŒâããã«ããšãã«ã¡
ãã«ïŒãã€ããããã³ãïŒïŒâãããã«ã¡ãã«ïŒ
ãã€ããããã³ãïŒïŒâãããã«ã¡ãã«ïŒãã€ã
ãããã³ãïŒããªããšãã«ã¡ãã«ïŒãã€ãããã
ã³ãïŒÎ±ïŒÎ±âãžããšãã«ãšãã«ïŒãã€ãããã
ã³ãïŒÎ±ïŒÎ±âãžããšãã«âïœâãããã«ïŒãã€
ããããã³ãïŒÎ±âïŒâãããã«ãšãã«ïŒãã€ã
ãããã³ãïŒÎ±âïŒâãããã«ãšãã«ïŒãã€ãã
ããã³ãã·ã¯ããã³ãã«ãã€ããããã³ãïŒïŒâ
ãšãã«ã·ã¯ããã³ãã«ïŒãã€ããããã³ãã·ã¯ã
ããã·ã«ãã€ããããã³ãïŒïŒâã¡ãã«ã·ã¯ãã
ãã·ã«ïŒãã€ããããã³ãïŒïŒâããã«ã·ã¯ãã
ãã·ã«ïŒãã€ããããã³ãïŒïŒâããã«ã·ã¯ãã
ãã·ã«ïŒãã€ããããã³çãæããããšãã§ã
ãã äžèšçœ®æãã€ããããã³ã¯çœ®æã¢ã«ãã«åºãŸã
ã¯ã¢ã©ã«ãã«åºããã€ããããã³éªšæ Œã«ïŒçŽççŽ
ååã«ãã€ãŠçµåããŠãããã®ããã奜ãŸããã ïŒçŽççŽ ååã«ãã€ãŠãã€ããããã³éªšæ Œã«çµ
åããŠãããããã眮æåºãæã€ã¢ã眮æãã€ã
ãããã³ã«ç±æ¥ããåäœãæããæ¬çºæã®å šè³éŠ
æããªãšã¹ãã«ã¯ãé«æž©åºŠã«ãããé žåå®å®æ§ã
ãã³è溶å€æ§ã«åªããŠããã äžèš(b)ã®åäœã¯åè¿°ã®åŠãã¢ã眮æãã€ããã
ãã³ã«ç±æ¥ããåäœãçŽ80ã¢ã«ïŒ 以äžãå ãã
ãããŸãã¯ã¢ã眮æãã€ããããã³ããã³ã¢ã眮
æãã€ããããã³ä»¥å€ã®çœ®æãã€ããããã³ã«ç±
æ¥ããåäœã®åèšéãçŽ80ã¢ã«ïŒ 以äžãå ããã
ãšãå¿ èŠã§ãããäžèš(b)åäœã®çŽ20ã¢ã«ïŒ 以äž
ã¯ãããæ æªçœ®æãã€ããããã³ä»¥å€ã®ãã®ä»ã®
è³éŠæãžããããã·ååç©ã«ç±æ¥ããåäœãå ã
ãããšãã§ããã ããããã®ä»ã®è³éŠæãžããããã·ååç©ãšã
ãŠã¯ãäŸãã°ãã¬ãŸã«ã·ã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ããšãã«ïŒãããã³ããã¹ïŒïŒâãã
ããã·ããšãã«ïŒã¹ã«ãã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ããšãã«ïŒã·ã¯ããããµã³ãïŒïŒ4â²â
ãžããããã·ãžããšãã«ãïŒïŒ4â²âãžããããã·
ãžããšãã«ãšãŒãã«ãïŒâïœâããã«ã¬ãŸã«ã·ã³
çãæããããšãã§ããã äžèšè³éŠæãžããããã·ååç©ã«ç±æ¥ããåäœ
(b)ã¯ãæ¬çºæã«ããã°ãäžèšã¢ã眮æãã€ããã
ãã³ã«ç±æ¥ããåäœããå®è³ªçã«æããããŸãã¯
äžèšã¢ã眮æãã€ããããã³ã«ç±æ¥ããåäœãšäž
èšã¢ã眮æãã€ããããã³ä»¥å€ã®çœ®æãã€ããã
ãã³ã«ç±æ¥ããåäœãšããå®è³ªçã«æãã®ã奜ãŸ
ããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã圢æããïœâ
é åæ§è³éŠæãªãã·ã«ã«ãã³é žã«ç±æ¥ããåäœ(c)
ã¯ãïœâããããã·å®æ¯éŠé žããã³ïŒãŸãã¯ã¢ã
眮æïœâããããã·å®æ¯éŠé žã«ç±æ¥ããåäœãçŽ
70ã¢ã«ïŒ 以äžã§å«æããã 眮æïœâããããã·å®æ¯éŠé žãšããŠã¯ãäŸãã°
ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãäŸãã°ã¡ãã«ããšã
ã«ããããã«ãããã«ãããã¯ããã²ã³ååãäŸ
ãã°ã¯ãããããã¢çã«ãã€ãŠçœ®æãããïœâã
ãããã·å®æ¯éŠé žã奜ãŸããçšãããããäŸã
ã°ãïŒâã¯ããâïŒâããããã·å®æ¯éŠé žãïŒâ
ããã¢âïŒâããããã·å®æ¯éŠé žãïŒïŒïŒâãžã¯
ããâïŒâããããã·å®æ¯éŠé žãïŒâã¡ãã«âïŒ
âããããã·å®æ¯éŠé žãïŒâïœâããã«âïŒâã
ãããã·å®æ¯éŠé žçãæããããšãã§ããã äžèš70ã¢ã«ïŒ 以äžã§å«æãããåäœãšããŠã¯ã
ïœâããããã·å®æ¯éŠé žã«ç±æ¥ããåäœãããæ
ãŸããã ïœâããããã·å®æ¯éŠé žããã³ïŒãŸãã¯ã¢ã眮
æïœâããããã·å®æ¯éŠé žã«ç±æ¥ããåäœã¯ã奜
ãŸããã¯ãåäœ(c)ã®çŽ80ã¢ã«ïŒ 以äžããã奜ãŸã
ãã¯çŽ90ã¢ã«ïŒ 以äžãå ããã ãŸããäžèšåäœ(c)ã¯ãïœâããããã·å®æ¯éŠé ž
ããã³ïŒãŸãã¯ã¢ã眮æïœâããããã·å®æ¯éŠé ž
ã«ç±æ¥ããåäœããå®è³ªçã«æãã®ãç¹ã«å¥œãŸã
ãã äžèšåäœ(c)ã¯ãçŽ30ã¢ã«ïŒ 以äžã§ïœâãããã
ã·å®æ¯éŠé žããã³ïŒãŸãã¯ã¢ã眮æïœâãããã
ã·å®æ¯éŠé žã«ç±æ¥ããåäœä»¥å€ã®ïœâé åæ§è³éŠ
æãªãã·ã«ã«ãã³é žã«ç±æ¥ããåäœãå«æããã
ãšãã§ããã ããã§ãïœâé åæ§è³éŠæãªãã·ã«ã«ãã³é žãš
ã¯ãè³éŠæã«çµåããŠããããããã·ã«åºãŸãã¯
ãã®ããããã·ã«åºããèªå°ãããåºãšã«ã«ãã
ã·ã«åºãšã®é¢ä¿ããå ã«ïœâé åæ§è³éŠæãžã«ã«
ãã³é žã«ã€ããŠèšè¿°ããïŒåã®ã«ã«ããã·ã«åºã®
é¢ä¿ãšåæ§ã§ãããã®ãããããã®ä»ã®ïœâé å
æ§è³éŠæãªãã·ã«ã«ãã³é žãšããŠã¯ãäŸãã°ïœâ
ïŒÎ²âããããã·ãšããã·ïŒå®æ¯éŠé žãïœâïŒïŒâ
ããããã·ããšããã·ïŒå®æ¯éŠé žãïŒâãããã
ã·âïŒâããããšé žãïŒâããããã·âïŒâãã
ããšé žãïœâïŒïŒâããããã·ããšãã«ïŒå®æ¯éŠ
é žçãæããããšãã§ããã æ¬çºæã®æº¶èç°æ¹æ§å šè³éŠæããªãšã¹ãã«ã¯ã
äžèš(a)ããã³(b)ã®åäœããå®è³ªçã«æããããŸã
ã¯äžèš(a)ïŒ(b)ããã³(c)ã®åäœããå®è³ªçã«æãã
(c)ã®åäœãå«ãåŸè ã®å šè³éŠæããªãšã¹ãã«ã¯ã
åèšããïœâé åæ§è³éŠæãžã«ã«ãã³é žã«ç±æ¥ã
ãåäœããã³
çŽ æ°ïŒã10ã®ã¢ã©ã«ãã«åºã§æ žçœ®æãããã¢ã眮
æãã€ããããã³ã«ç±æ¥ããåäœãçŽ80ã¢ã«ïŒ 以
äžã§å«æããã ã®ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãšããŠã¯ãäŸã
ã°ã¡ãã«ããšãã«ããããã«çãæããããšãã§
ããã ãããã¢ã眮æãã€ããããã³ã¯ããã€ããã
ãã³ãšçžåœããã¢ã«ã³ãŒã«ãŸãã¯ããã«æ§äºéçµ
åãæããäžé£œåååç©ãšãããªã³é žãŸãã¯ç¡«é ž
çã®é žæ§è§Šåªã®ååšäžãè³éŠæçåæ°ŽçŽ ãäŸãã°
ãã³ãŒã³äžã§å ç±åå¿ãããããããèªäœå ¬ç¥ã®
æ¹æ³ã«ãã€ãŠè£œé ããããšãã§ããã äžèšè³éŠæãžããããã·ååç©ã«ç±æ¥ããåäœ
(b)ã¯ãã¢ã眮æãã€ããããã³ã«ç±æ¥ããåäœä»¥
å€ã®çœ®æãã€ããããã³ãçŽ20ã¢ã«ïŒ 以äžã§å«æ
ããŠããŠããããããããã®ä»ã®çœ®æãã€ããã
ãã³ã¯ã奜ãŸããã¯ççŽ æ°ïŒã10ã®ã¢ã«ãã«åºã
äŸãã°ã¡ãã«ããšãã«ããããã«ãããã«ããã³
ãã«ãããã·ã«ããããã«ããªã¯ãã«ãããã«ã
ãã·ã«çããããã¯ççŽ æ°ïŒã10ã®ç¬¬ïŒçŽã¢ã©ã«
ãã«åºãäŸãã°ïŒâããšãã«ãããâïŒâã€ã«ã
ïŒâïŒïœïŒïœâãŸãã¯ïœâã¯ããããšãã«ïŒãã
ãâïŒâã€ã«ãïŒâïŒïœâïŒïœâãŸãã¯ïœâãã«
ãªãããšãã«ïŒãããâïŒâã€ã«ãïŒâïŒïœâã
ãã¢ããšãã«ïŒãããâïŒâã€ã«ãïŒâïŒïœâãš
ãŒãããšãã«ïŒãããâïŒâã€ã«çããããã¯ç
çŽ æ°11以äžã®ã¢ã©ã«ãã«åºãäŸãã°ïŒâïŒããã
âïŒâãŸãã¯âïŒâã€ã«ïŒãããâïŒâã€ã«ãïŒ
âïŒâïŒïŒâãŸãã¯ïŒâïŒïŒâC1ã3ã¢ã«ãã«âã
ããâïŒâã€ã«ïŒããšãã«ïŒœâãããâïŒâã€ã«
çããããã¯ããã²ã³ååãäŸãã°ã¯ãããŸãã¯
ããã¢ã«ãã€ãŠçœ®æããããã€ããããã³ã§ã
ãã ããã眮æãã€ããããã³ãšããŠã¯ãäŸãã°ã¡
ãã«ãã€ããããã³ããšãã«ãã€ããããã³ãïœ
âããã«ãã€ããããã³ãã¯ãããã€ãããã
ã³ãããã¢ãã€ããããã³ãïŒâïœâã¢ãã«ãã€
ããããã³ãïŒâïœâããã·ã«ãã€ããããã³ã
ïŒâïœâãããã«ãã€ããããã³ãïŒâïœâãªã¯
ãã«ãã€ããããã³ãïŒâïœâããã«ãã€ããã
ãã³ãïŒâïœâãã·ã«ãã€ããããã³ãïŒâïŒïŒïŒ
ïŒïŒïŒâããªã¡ãã«ããã·ã«âïŒâã€ã«ïŒãã€ã
ãããã³ãïŒâïŒïŒïŒïŒïŒïŒâããªã¡ãã«ããã
ã«âïŒâã€ã«ïŒãã€ããããã³ãïŒâsecâã¢ã
ã«ãã€ããããã³ãïŒâsecâããã·ã«ãã€ãã
ããã³ãïŒâsecâãããã«ãã€ããããã³ãïŒ
âsecâãªã¯ãã«ãã€ããããã³ãïŒâïŒïŒïŒïŒâ
ãžã¡ãã«ãããâïŒâã€ã«ïŒãã€ããããã³ïŒïŒ
âïŒïŒâããšãã«ãããâïŒâã€ã«ïŒãã€ããã
ãã³ãïŒâïŒâïŒïŒâã¡ãã«ããšãã«ïŒãããâ
ïŒâã€ã«ïŒœãã€ããããã³ãïŒãžããšãã«ã¡ãã«ïŒ
ãã€ããããã³ãïŒããšãã«ïŒâããªã¡ãã«ïŒã
ã€ããããã³ãïŒããšãã«ïŒâããã«ããšãã«ã¡
ãã«ïŒãã€ããããã³ãïŒïŒâãããã«ã¡ãã«ïŒ
ãã€ããããã³ãïŒïŒâãããã«ã¡ãã«ïŒãã€ã
ãããã³ãïŒããªããšãã«ã¡ãã«ïŒãã€ãããã
ã³ãïŒÎ±ïŒÎ±âãžããšãã«ãšãã«ïŒãã€ãããã
ã³ãïŒÎ±ïŒÎ±âãžããšãã«âïœâãããã«ïŒãã€
ããããã³ãïŒÎ±âïŒâãããã«ãšãã«ïŒãã€ã
ãããã³ãïŒÎ±âïŒâãããã«ãšãã«ïŒãã€ãã
ããã³ãã·ã¯ããã³ãã«ãã€ããããã³ãïŒïŒâ
ãšãã«ã·ã¯ããã³ãã«ïŒãã€ããããã³ãã·ã¯ã
ããã·ã«ãã€ããããã³ãïŒïŒâã¡ãã«ã·ã¯ãã
ãã·ã«ïŒãã€ããããã³ãïŒïŒâããã«ã·ã¯ãã
ãã·ã«ïŒãã€ããããã³ãïŒïŒâããã«ã·ã¯ãã
ãã·ã«ïŒãã€ããããã³çãæããããšãã§ã
ãã äžèšçœ®æãã€ããããã³ã¯çœ®æã¢ã«ãã«åºãŸã
ã¯ã¢ã©ã«ãã«åºããã€ããããã³éªšæ Œã«ïŒçŽççŽ
ååã«ãã€ãŠçµåããŠãããã®ããã奜ãŸããã ïŒçŽççŽ ååã«ãã€ãŠãã€ããããã³éªšæ Œã«çµ
åããŠãããããã眮æåºãæã€ã¢ã眮æãã€ã
ãããã³ã«ç±æ¥ããåäœãæããæ¬çºæã®å šè³éŠ
æããªãšã¹ãã«ã¯ãé«æž©åºŠã«ãããé žåå®å®æ§ã
ãã³è溶å€æ§ã«åªããŠããã äžèš(b)ã®åäœã¯åè¿°ã®åŠãã¢ã眮æãã€ããã
ãã³ã«ç±æ¥ããåäœãçŽ80ã¢ã«ïŒ 以äžãå ãã
ãããŸãã¯ã¢ã眮æãã€ããããã³ããã³ã¢ã眮
æãã€ããããã³ä»¥å€ã®çœ®æãã€ããããã³ã«ç±
æ¥ããåäœã®åèšéãçŽ80ã¢ã«ïŒ 以äžãå ããã
ãšãå¿ èŠã§ãããäžèš(b)åäœã®çŽ20ã¢ã«ïŒ 以äž
ã¯ãããæ æªçœ®æãã€ããããã³ä»¥å€ã®ãã®ä»ã®
è³éŠæãžããããã·ååç©ã«ç±æ¥ããåäœãå ã
ãããšãã§ããã ããããã®ä»ã®è³éŠæãžããããã·ååç©ãšã
ãŠã¯ãäŸãã°ãã¬ãŸã«ã·ã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ããšãã«ïŒãããã³ããã¹ïŒïŒâãã
ããã·ããšãã«ïŒã¹ã«ãã³ãïŒïŒïŒâãã¹ïŒïŒâ
ããããã·ããšãã«ïŒã·ã¯ããããµã³ãïŒïŒ4â²â
ãžããããã·ãžããšãã«ãïŒïŒ4â²âãžããããã·
ãžããšãã«ãšãŒãã«ãïŒâïœâããã«ã¬ãŸã«ã·ã³
çãæããããšãã§ããã äžèšè³éŠæãžããããã·ååç©ã«ç±æ¥ããåäœ
(b)ã¯ãæ¬çºæã«ããã°ãäžèšã¢ã眮æãã€ããã
ãã³ã«ç±æ¥ããåäœããå®è³ªçã«æããããŸãã¯
äžèšã¢ã眮æãã€ããããã³ã«ç±æ¥ããåäœãšäž
èšã¢ã眮æãã€ããããã³ä»¥å€ã®çœ®æãã€ããã
ãã³ã«ç±æ¥ããåäœãšããå®è³ªçã«æãã®ã奜ãŸ
ããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã圢æããïœâ
é åæ§è³éŠæãªãã·ã«ã«ãã³é žã«ç±æ¥ããåäœ(c)
ã¯ãïœâããããã·å®æ¯éŠé žããã³ïŒãŸãã¯ã¢ã
眮æïœâããããã·å®æ¯éŠé žã«ç±æ¥ããåäœãçŽ
70ã¢ã«ïŒ 以äžã§å«æããã 眮æïœâããããã·å®æ¯éŠé žãšããŠã¯ãäŸãã°
ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãäŸãã°ã¡ãã«ããšã
ã«ããããã«ãããã«ãããã¯ããã²ã³ååãäŸ
ãã°ã¯ãããããã¢çã«ãã€ãŠçœ®æãããïœâã
ãããã·å®æ¯éŠé žã奜ãŸããçšãããããäŸã
ã°ãïŒâã¯ããâïŒâããããã·å®æ¯éŠé žãïŒâ
ããã¢âïŒâããããã·å®æ¯éŠé žãïŒïŒïŒâãžã¯
ããâïŒâããããã·å®æ¯éŠé žãïŒâã¡ãã«âïŒ
âããããã·å®æ¯éŠé žãïŒâïœâããã«âïŒâã
ãããã·å®æ¯éŠé žçãæããããšãã§ããã äžèš70ã¢ã«ïŒ 以äžã§å«æãããåäœãšããŠã¯ã
ïœâããããã·å®æ¯éŠé žã«ç±æ¥ããåäœãããæ
ãŸããã ïœâããããã·å®æ¯éŠé žããã³ïŒãŸãã¯ã¢ã眮
æïœâããããã·å®æ¯éŠé žã«ç±æ¥ããåäœã¯ã奜
ãŸããã¯ãåäœ(c)ã®çŽ80ã¢ã«ïŒ 以äžããã奜ãŸã
ãã¯çŽ90ã¢ã«ïŒ 以äžãå ããã ãŸããäžèšåäœ(c)ã¯ãïœâããããã·å®æ¯éŠé ž
ããã³ïŒãŸãã¯ã¢ã眮æïœâããããã·å®æ¯éŠé ž
ã«ç±æ¥ããåäœããå®è³ªçã«æãã®ãç¹ã«å¥œãŸã
ãã äžèšåäœ(c)ã¯ãçŽ30ã¢ã«ïŒ 以äžã§ïœâãããã
ã·å®æ¯éŠé žããã³ïŒãŸãã¯ã¢ã眮æïœâãããã
ã·å®æ¯éŠé žã«ç±æ¥ããåäœä»¥å€ã®ïœâé åæ§è³éŠ
æãªãã·ã«ã«ãã³é žã«ç±æ¥ããåäœãå«æããã
ãšãã§ããã ããã§ãïœâé åæ§è³éŠæãªãã·ã«ã«ãã³é žãš
ã¯ãè³éŠæã«çµåããŠããããããã·ã«åºãŸãã¯
ãã®ããããã·ã«åºããèªå°ãããåºãšã«ã«ãã
ã·ã«åºãšã®é¢ä¿ããå ã«ïœâé åæ§è³éŠæãžã«ã«
ãã³é žã«ã€ããŠèšè¿°ããïŒåã®ã«ã«ããã·ã«åºã®
é¢ä¿ãšåæ§ã§ãããã®ãããããã®ä»ã®ïœâé å
æ§è³éŠæãªãã·ã«ã«ãã³é žãšããŠã¯ãäŸãã°ïœâ
ïŒÎ²âããããã·ãšããã·ïŒå®æ¯éŠé žãïœâïŒïŒâ
ããããã·ããšããã·ïŒå®æ¯éŠé žãïŒâãããã
ã·âïŒâããããšé žãïŒâããããã·âïŒâãã
ããšé žãïœâïŒïŒâããããã·ããšãã«ïŒå®æ¯éŠ
é žçãæããããšãã§ããã æ¬çºæã®æº¶èç°æ¹æ§å šè³éŠæããªãšã¹ãã«ã¯ã
äžèš(a)ããã³(b)ã®åäœããå®è³ªçã«æããããŸã
ã¯äžèš(a)ïŒ(b)ããã³(c)ã®åäœããå®è³ªçã«æãã
(c)ã®åäœãå«ãåŸè ã®å šè³éŠæããªãšã¹ãã«ã¯ã
åèšããïœâé åæ§è³éŠæãžã«ã«ãã³é žã«ç±æ¥ã
ãåäœããã³
ãåŒãïŒããã§ãã¯åèšå®çŸ©ãš
åãïŒã§ç€ºãããççŽ æ°ïŒã10ã®ã¢ã©ã«ãã«åºã§
眮æãããã¢ã眮æãã€ããããã³ã«ç±æ¥ããå
äœãããããå šæ§æåäœã®å°ãªããšãçŽïŒã¢ã«
ïŒ ã奜ãŸããã¯çŽ20ã¢ã«ïŒ ããã奜ãŸããã¯çŽ30
ã¢ã«ïŒ ãå«æããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ãåœè©²æè¡å
éã§ããç¥ãããŠããããã«ãçåœéã®ãããã
ã·ã«åºãšã«ã«ããã·ã«åºãšãåå¿ããŠäž»éã圢æ
ãããšã¹ãã«çµåãçæãããã®ã§ãããããå®
質çã«äžèš(a)åäœãšäžèš(b)åäœãšãçåœéã§å«æ
ããŠããã åŸã€ãŠãäŸãã°ãã¬ãã¿ã«é ž10ã¢ã«ãïŒâαâ
ããšããã«ãã€ããããã³10ã¢ã«ããã³ïœâãªã
ã·å®æ¯éŠé ž90ã¢ã«ãšãã圢æããããäžèš(c)åäœ
ãå«ãå šè³éŠæããªãšã¹ãã«ã¯ããã¬ãã¿ã«é žã«
ç±æ¥ããåäœ(a)ããã³ïŒâαâããšããã«ãã€ã
ãããã³ã«ç±æ¥ããåäœ(b)ãããããå šæ§æåäœ
ïŒ110ã¢ã«ïŒã«å¯ŸãçŽïŒã¢ã«ïŒ ã§å«æããããšã«ãª
ãã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ãäžèšã®åŠã
æ§ææåããç解ããããšãããååéã¯çŽç·æ§
ã«åªãããã®æº¶èç©ã¯å åŠçç°æ¹æ§ãæãããæ¬
çºæã®å šè³éŠæããªãšã¹ãã«ã¯ãããã«ãããã
ããæ¯èŒçäœãèç¹ãšåŸã«å®çŸ©ããæµãéå§æž©
床ãäŸãã°çŽ250ãçŽ360âãšãæããŠããããã
æ 溶èæ圢æ§ã«åªãããã€æº¶èæ圢æã«é žåå解
ãç±å解ã«ããå£åãã倧ããä¿è·ãããåªãã
çš®ã ã®æ圢åãäžããããšãã§ããã ç¹ã«æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ææ©æº¶
åªãäŸãã°ã¯ããããšããŒã«ãããšããŒã«ãšãã
ã©ã¯ãããšã¿ã³ã®æ··å液ãïœâã¯ããããšããŒã«
ãšããã©ã¯ãããšã¿ã³ã®æ··å液ãããªãã«ãªãé ¢
é žãšã¯ãããã«ã ã®æ··å液ããã³ããªãã«ãªãé ¢
é žãšããã©ã¯ãããšã¿ã³ã®æ··å液çã«å¯ŸããŠæº¶è§£
æ§ã瀺ãããŸãããã®ãããªå šè³éŠæããªãšã¹ã
ã«ã¯ãææ©æº¶åªã«å¯ŸããŠæº¶è§£æ§ã瀺ãããã«ãäŸ
ãã°çš®ã ã®ããã«æ§ååç©ã«å¯ŸããŠèŠªåæ§ã瀺
ããããæ ãã®æ圢åãããã«æ§ååç©ã§åŠçã
ãããšã«ããæ圢åäžã«ããã«ååç©ãå°å ¥ãã
ããšãã§ããããã®ããšã¯ãæ¬çºæã®å šè³éŠæã
ãªãšã¹ãã«ã«å¯ŸããåŸå å·¥ã«ãã€ãŠãããã«çš®ã
ã®ææã®æ§è³ªãäŸãã°å¯žæ³å®å®æ§ãèé žåæ§ãå
åŠæµæçãä»äžã§ããããšãæå³ããŠããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ãåŸã«å®çŸ©ã
ãæ¹æ³ã«åŸã€ãŠïœâã¯ããããšããŒã«ãšããã©ã¯
ãããšã¿ã³ã®æ··å溶åªäžã®æº¶æ¶²ãšããŠæž¬å®ããåº
æç²åºŠãã奜ãŸããã¯0.8以äžã§ããããã奜ãŸ
ããã¯2.0以äžãç¹ã«å¥œãŸããã¯3.0以äžã§ããã æ¬çºæã«ãããâ溶èç°æ¹æ§âãšã¯ãããªããŒ
ã溶èç¶æ ã«ãã€ãŠãå åŠçã«ç°æ¹æ§ã瀺ãããš
ãæå³ãããäŸãã°ãç¹éæ53â109598å·å ¬å ±ã«
ã¯æº¶èç°æ¹æ§ã瀺ãå šè³éŠæããªãšã¹ãã«ã®ç¹æ§
ã詳述ããŠããã æ¬çºæã®æº¶èç°æ¹æ§å šè³éŠæããªãšã¹ãã«ã¯ã
å®éçš®ã ã®æ¹æ³ã§è£œé ããããšãã§ãããäŸã
ã°ãã¢ãªãŒã«ã«ãŒãããŒãã®ååšäžã§æå®ã®æå
ãå ç±éçž®åããããæ¹æ³ãè³éŠæãžã«ã«ãã³
é žãè³éŠæãžããããã·ååç©ããã³ïœâé åæ§
è³éŠæãªãã·ã«ã«ãã³é žã®å°ãªããšãããããäž
ã€ããšã¹ãã«ãšããŠçšããæå®ã®æåãå ç±éçž®
åããããæ¹æ³çãæããããã ãããã®æ¹æ³ã«å å«ããã奜ãŸããå®æœæ æ§
ãã説æã®äŸ¿ã®ããããã¬ãã¿ã«é žãïŒâαâã
ãšããã«ãã€ããããã³ããã³ïœâãªãã·å®æ¯éŠ
é žã«ç±æ¥ããåäœãããªãæ¬çºæã®å šè³éŠæããª
ãšã¹ãã«ã補é ããå Žåã«ã€ããŠä»¥äžã«èª¬æã
ãã (1) ãã¬ãã¿ã«é žãšïœâãªãã·å®æ¯éŠé žã«ãžããš
ãã«ã«ãŒãããŒãã®åŠãã¢ãªãŒã«ã«ãŒãããŒã
ãå ããå ç±ããšã¹ãã«ååå¿ãè¡ãªãããã®
ã¡ãïŒâαâããšããã«ãã€ããããã³ãå ã
ãŠå ç±éçž®åãããæ¹æ³ïŒä»¥äžã第ïŒã®æ¹æ³ãš
ããïŒ (2) ïœâãªãã·å®æ¯éŠé žããšãã«ããã¬ãã¿ã«é ž
ãžããšãã«ããã³ïŒâαâããšããã«ãã€ãã
ããã³ã®æ··åç©ãå ç±ãéçž®åãããæ¹æ³ïŒä»¥
äžç¬¬ïŒã®æ¹æ³ãšããïŒ ç¬¬ïŒã®æ¹æ³ã«ã€ããŠå ã説æããã ã¢ãªãŒã«ã«ãŒãããŒããšããŠã¯ãäŸãã°ãžããš
ãã«ã«ãŒãããŒãããžããªã«ã«ãŒãããŒãããžïœ
âã¯ãã«ããšãã«ã«ãŒãããŒããããšãã«ããªã«
ã«ãŒãããŒãããã³ããªïŒâαâããšããã«ããš
ãã¬ã³ã«ãŒãããŒãã®åŠãããªã«ãŒãããŒããæ
ããããšãã§ããããããã®ãã¡ãžããšãã«ã«ãŒ
ãããŒããå質ã®å®å®æ§ãçŽåºŠãåå¿æ§çã®ç¹ã
ã奜ãŸããçšããããããã®ã¢ãªãŒã«ã«ãŒãããŒ
ãã®äœ¿çšéã¯ããã¬ãã¿ã«é žããã³ïœâãªãã·å®
æ¯éŠé žã®éé¢ã«ã«ããã·ã«åºïŒåœéåœãã«ãŒãã
ãŒãçµåæç®å€ã§0.9ã1.1ååœéãç¹ã«ã»ãŒïŒå
åœéã§ããããšã奜ãŸããã åå¿ã¯éåžž200ã300âã奜ãŸããã¯200ã280â
ã®æž©åºŠã«ãŠãåå¿ã«ãã€ãŠçæããçé žã¬ã¹ã®çº
çãå®è³ªçã«åæ¢ãããŸã§è¡ãªãããã®åå¿ã¯ïŒ
ãïŒæéãé©åœã§ããã奜ãŸããã¯è§Šåªã®ååšäž
ã§è¡ãªãããã®è§ŠåªãšããŠã¯ããã¿ã³ååç©ãäŸ
ãã°ãã¿ã³ããã©ãããã·ããã·ãŠãŠé žãã¿ã
ã«ãé ¢é žãã¿ã³çïŒã¹ãºååç©ãäŸãã°é ¢é žç¬¬ïŒ
ã¹ãºïŒãã®ä»çé žäºéãé žåéãäžé žåã¢ã³ãã¢
ã³ãäºé žåã¢ã³ãã¢ã³ãäžé žåãã¹ãã¹ãé ¢é žã»
ãªãŠã ãé žåã©ã³ã¿ã³ãé žåãªããŠã ãå®æ¯éŠé ž
ã«ãªãé ¢é žã«ã«ã·ãŠã ãé žåãã°ãã·ãŠã ãé ¢é ž
ãã°ãã·ãŠã ãªã©ã®åŠãéãã¢ã³ãã¢ã³ããã¹ã
ã¹ãã»ãªãŠã ãã©ã³ã¿ã³ããªããŠã ããããªãŠ
ã ãã«ãªãŠã ãäºéããã°ãã·ãŠã ãã«ã«ã·ãŠã
çã®éå±ãå«ãååç©ãäŸç€ºããããšãã§ããã
ãããã®ãã¡ãã¿ã³ãã¹ãºããã³ã¢ã³ãã¢ã³ãå«
ãååç©ãã次ã®éçž®ååå¿ãšå ±éããŠçšããã
ãšãã§ããã®ã§å¥œãŸããã觊åªã®äœ¿çšéã¯ãã¬ã
ã¿ã«é žã«å¯Ÿã0.005ã0.5ã¢ã«ïŒ ãããã«ã¯0.01ã
0.1ã¢ã«ïŒ ã§ããããšã奜ãŸããã ãã®ããã«ããŠãã¬ãã¿ã«é žãšã¢ãªãŒã«ã«ãŒã
ããŒãã®åå¿ãçµçµãããšãåå¿ç³»å ã®æž©åºŠã
200ã280âã«ä¿ã¡ã€ã€ããã¬ãã¿ã«é žæåïŒã¢ã«
åœã1.0ã1.3ã¢ã«ããã奜ãŸããã¯1.01ã1.2ã¢ã«
ã®ïŒâαâããšããã«ãã€ããããã³ãæ·»å ãã
次ã®éçž®ååå¿ãè¡ãªãã éçž®ååå¿ã¯ãå®è³ªçã«ç¡è§Šåªã§ãé²è¡ãã
ããåŸæ¥å ¬ç¥ã®ãšã¹ãã«äº€æ觊åªãçšããŠè¡ãªã
ã®ã奜ãŸããããã®ãšã¹ãã«äº€æ觊åªã®ãã¡å¥œé©
ãªãã®ãšããŠã«ã«ã·ãŠã ããã°ãã·ãŠã ãã¹ãã
ã³ããŠã ãããªãŠã ãã©ã³ã¿ã³ãã»ãªãŠã ããã³
ã¬ã³ãã³ãã«ããäºéãã²ã«ãããŠã ãã¹ãºã
éãã¢ã³ãã¢ã³ããã¹ãã¹ãªã©ã®éå±ãå«ãåå
ç©ãäŸç€ºã§ããããã«ãã®å ·äœäŸãšããŠé ¢é žãã°
ãã·ãŠã ãå®æ¯éŠé žã«ã«ã·ãŠã ãé ¢é žã¹ããã³ã
ãŠã ãããããªã³é žããªãŠã ãçé žã©ã³ã¿ã ãé ž
åã»ãªãŠã ãé ¢é žãã³ã¬ã³ãé ¢é žã³ãã«ããé ¢é ž
äºéãé žåã²ã«ãããŠã ãé ¢é žç¬¬ïŒã¹ãºãé žå
éãäžé žåã¢ã³ãã¢ã³ãäžé žåãã¹ãã¹ãªã©ãäŸ
瀺ã§ããã ãããã®ãšã¹ãã«äº€æïŒéçž®åïŒè§Šåªãšãšãã«
å®å®å€ã䜿çšããããšã奜ãŸããã奜ãŸããå®å®
å€ã®äŸã¯ãåŸæ¥å ¬ç¥ã®ïŒäŸ¡ãããã¯ïŒäŸ¡ã®ãªã³å
åç©ãŸãã¯ãã®ãšã¹ãã«é¡ã§ãããäŸãã°äºãªã³
é žããªã³é žãããšãã«ãã¹ãã³é žãã¡ãã«ãã¹ã
ã³é žããšãã«ãã¹ãã³é žããããã«ãã¹ãã³é žã
ããã«ãã¹ãã³é žããã³ãžã«ãã¹ãã³é žãããªã¡
ãã«ãã¹ãã¢ã€ããããªã¡ãã«ãã¹ããšãŒããã
ãªãšãã«ãã¹ããšãŒããããªããã«ãã¹ããšãŒ
ããããªããšãã«ãã¹ãã¢ã€ããããªããšãã«ã
ã¹ããšãŒãããžãšãã«ããšãã«ãã¹ãããŒãããž
ã¡ãã«âïŒã¡ãã«ïŒãã¹ãããŒãããžã¡ãã«âïŒãš
ãã«ïŒãã¹ãããŒãããžã¡ãã«ïŒãã³ãžã«ïŒãã¹
ãããŒããªã©ãæããããšãã§ããããããå®å®
å€ã¯ãããªããŒã®æº¶èå®å®æ§ãè²èª¿ãæ¹è¯ãã
ãã觊åªã®çš®é¡ã«ãã€ãŠã¯è©²éçž®å觊åªãäžæŽ»æ§
åãããããããŠè§ŠåªãäžæŽ»æ§åããå Žåã«ã¯ã
å®å®å€ã¯éçž®ååå¿çµäºåŸã«å ããããšã奜ãŸã
ããã¢ã³ãã¢ã³ãŸãã¯ã²ã«ãããŠã ãå«ãéçž®å
觊åªã¯å®å®å€ã«ãã€ãŠäžæŽ»æ§åãããªãã®ã§ã該
觊åªãçšããå Žåã«ã¯å®å®å€ã¯éçž®ååå¿ã®æå
ããå ããããšãã§ããã ããããšã¹ãã«äº€æïŒéçž®åïŒè§Šåªã®äœ¿çšé
ã¯ããã¬ãã¿ã«é žãšïœâãªãã·å®æ¯éŠé žã®åèšã¢
ã«æ°ã®0.005ã0.5ã¢ã«ïŒ ãããã«ã¯0.01ã0.1ã¢ã«
ïŒ ã§ããããšã奜ãŸããããŸãå®å®å€ã®é(p)ã¯äž
èšéçž®å觊åªã®äœ¿çšéïŒïŒ®ã¢ã«ïŒã«å¯Ÿãã0.8ïŒ
ïŒïŒ®ïŒ1.5ïŒäœããïŒå®å®å€ã®ã¢ã«ïŒäœ¿çšãã
ã®ã奜ãŸããã ãããéã®è§Šåªãå Žåã«ãã€ãŠã¯å®å®å€ããã³
ïŒâαâããšããã«ãã€ããããã³ãåå¿ç³»ã«æ·»
å ããã®ã¡ãåå¿ç³»ãäŸãã°250ã300âãšããŠåžž
å§äžåå¿ãè¡ãªããçæããã¢ãããããã·è³éŠ
æååç©ãäŸãã°ããšããŒã«ãç³»å€ã«æºåºããã
ãŠéçž®åãé²è¡ãããããéçž®ååå¿ã¯çæãã
ã¢ãããããã·è³éŠæååç©ãç³»å€ã«æºåºããã
ã€ã€ãæåã¯åžžå§äžã次ãã§æžå§äžã§è¡ãªãã åžžå§äžã®åå¿ã¯åå¿æž©åºŠãé次äžæããããŠå®
æœããã®ã奜ãŸããããããåžžå§äžã®åå¿ã¯è³éŠ
æã¢ãããããã·ååç©ãæºåºããããéããã§
ããã ãäœãåå¿æž©åºŠã§é²è¡ããããã®ã奜ãŸã
ããäŸãã°ã250â以äžã®æž©åºŠã§ãéçž®ååå¿ã¯
ãã€ãããšé²è¡ãããããã®ãããªæž©åºŠã§ã¯çæ
ããè³éŠæã¢ãããããã·ååç©ãã»ãšãã©åå¿
ç³»å€ã«æºåºããªãã®ã§ãéçž®ååå¿ã¯ãŸããªãå¹³
è¡¡ã«éããŠããŸãã åŸã€ãŠãå®éçã«ã¯260âçšåºŠã®åå¿æž©åºŠãã
éçž®ååå¿ãå§ããŠæ¬¡ç¬¬ã«ææž©ããè³éŠæã¢ãã
ãããã·ååç©ã®çè«æºåºéã®çŽ35ã60ïŒ ã«éã
ãæç¹ã§290âçšåºŠã®åå¿æž©åºŠãšããã®ã奜ãŸã
ããåå¿æž©åºŠãæåãã290âãããã¯ãã以äž
ã®é«æž©ã«èšå®ããŠåå¿ãé²è¡ãããããšãã²ã«å
çã®å¥œãŸãããªãå¯åå¿ãåŒãèµ·ããããšãã
ãããããéã®è³éŠæã¢ãããããã·ååç©ãç³»
å€ã«æºåºããåŸã次ãã§åå¿ç³»ãæžå§ã«ãããã
ã«çæããè³éŠæã¢ãããããã·ååç©ãç³»å€ã«
æºåºãããã€ã€ã次第ã«æžå§åºŠããã³åå¿æž©åºŠã
é«ãæçµçã«ïŒmmHgçšåºŠãããã¯ãã以äžã®å§
åäžã320ã370âã®åå¿æž©åºŠã§åå¿ããããŠæå®
ã®éå床ã®ããªããŒãçæããããããšã奜ãŸã
ãã 次ã«ç¬¬ïŒã®æ¹æ³ã«ã€ããŠèª¬æããã ïœâãªãã·å®æ¯éŠé žããšãã«ããã³ãã¬ãã¿ã«
é žãžããšãã«ã¯ãäŸãã°ïœâãªãã·å®æ¯éŠé žãŸã
ã¯ãã¬ãã¿ã«é žããžããšãã«ã«ãŒãããŒããŸãã¯
ããšããŒã«ãšããèªäœå ¬ç¥ã®æ¹æ³ã«åŸã€ãŠåå¿ã
ãããããšã«ãã補é ããããšãã§ããã ïœâãªãã·å®æ¯éŠé žããšãã«ããã³ãã¬ãã¿ã«
é žãžããšãã«ãšïŒâαâããšããã«ãã€ãããã
ã³ãšã®æ··åç©ããå ç±éçž®åããããæ¹æ³ã¯ãäž
èšç¬¬ïŒã®æ¹æ³ã«ãããŠèšèŒããéçž®ååå¿æ¡ä»¶ãš
å šãåæ§ã®æ¡ä»¶äžã§å®æœããããšãã§ããã ãã®ç¬¬ïŒã®æ¹æ³ã«ããã°ãïœâãªãã·å®æ¯éŠé ž
ããšãã«ããã³ãã¬ãã¿ã«é žãžããšãã«ãé«çŽåºŠ
ã®ç¶æ ã§ïŒâαâããšããã«ãã€ããããã³ãšå
å¿ããããããšãã§ããã®ã§ãåŸãããå šè³éŠæ
ããªãšã¹ãã«ã®å質ã¯ããåäžããã第ïŒã®æ¹æ³
ã¯ãããæå³ã«ãããŠäžèšç¬¬ïŒã®æ¹æ³ããã奜ãŸ
ããã ããããŠåŸãããæ¬çºæã®å šè³éŠæããªãšã¹ã
ã«ã¯ãäžèšãããšããã溶èç°æ¹æ§ã瀺ãã«ãã
ãããããæ¯èŒçèç¹ããã³æµåéå§æž©åºŠãäœ
ããåŸã€ãŠå åŠçç°æ¹æ§æº¶èç©ãã容æã«æº¶è圢
æãåŸãç¹åŸŽãæããŠããã ããæ ãæ¬çºæã«ããã°ãæ¬çºæã®æº¶èç°æ¹æ§
å šè³éŠæããªãšã¹ãã«ãç±æº¶èããããŠå åŠçç°
æ¹æ§æº¶èç©ã圢æãã該溶èç©ãããèªäœå ¬ç¥ã®
溶èæ圢æ³ã«åŸã€ãŠãã€ã«ã ãŸãã¯ç¹ç¶ã«å€æã
ãããšãç¹åŸŽãšããã溶èç°æ¹æ§å šè³éŠæããªãš
ã¹ãã«ã®ãã€ã«ã ãŸãã¯ç¹ç¶ã補é ããæ¹æ³ãå
æ§ã«æäŸãããã åŸæ¥å ¬ç¥ã®æº¶èç°æ¹æ§å šè³éŠæããªãšã¹ãã«ã¯
äžè¬ã«æ¯èŒçèç¹ããã³æµåéå§æž©åºŠãé«ããã
ãæ ã該ããªãšã¹ãã«ã®ç±å解枩床ãé¿ããŠå®å®
ãªæº¶èç©ã圢æã§ãã枩床ç¯å²ãéåžžã«çãããŸ
ãæ¯èŒçé«ã溶èç²åºŠã瀺ã溶èç©ãäžããã
ãã溶èæ圢æ³ã«åŸã€ãŠåªããæ©æ¢°çæ§è³ªã瀺ã
æ圢åãäžããããšã¯å°é£ã§ãããäžå¯èœã§ãã€
ãã æ¬çºæã«ããã°ãå šè³éŠæããªãšã¹ãã«ã¯èç¹
ãšå解枩床ã®éã®æž©åºŠã«å ç±ãããŠå åŠçç°æ¹æ§
溶èç©ã圢æãããäžè¬ã«ãå ç±æž©åºŠã¯å šè³éŠæ
ããªãšã¹ãã«ã®æµãéå§æž©åºŠãšèç¹ããçŽ50âé«
ã枩床ãšã®éãšããã®ã奜ãŸããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ã奜ãŸããã¯
æµãéå§æž©åºŠãçŽ250ãçŽ360âã®éã«ããããã
äŸãã°ãããå šè³éŠæããªãšã¹ãã«ã¯ãäŸãã°çŽ
400âããäœã枩床ã§å®æœã§ãããäžè¬ã«ã¯ãçŽ
300âãçŽ400âã®æž©åºŠã奜ãŸããæ¡çšãããã æ¬çºææ¹æ³ã«ããã°ãæ¬çºæã®å šè³éŠæããªãš
ã¹ãã«ããçš®ã ã®åœ¢æ ã®æ圢åã補é ããããšã
ã§ãããããå ·äœçã«èª¬æããã°ãäŸãã°ç¹ç¶ã¯
å šè³éŠæããªãšã¹ãã«ãäŸãã°300ã400âã§æº¶è
ãã玡糞å£éããæŒåºããŠãã©ããçïŒã500ã
å·»åé床10ã500ïœïŒminã§å·»åãããšã«ããåŸ
ãããšãã§ãããåŸãããããªãšã¹ãã«ç¹ç¶ã¯ã
å¿ ããã延䌞ãç±åŠçã«ä»ãå¿ èŠã¯ãªãã溶è玡
糞ãå·»åãã ãã§ãäŸãã°åŒ·åºŠïŒïœïŒde以äžã
ã€ã³ã°ïœç2500KgïŒmm2以äžã®é«åŒ·åºŠãé«ã€ã³ã°ç
ã®ç¹ç¶ãåŸãããšãã§ããããã®ç¹ç¶ãç¹ç¶ã®åœ¢
æ ãä¿æããŠãäŸãã°200ã300âã§çŽ10æéç±åŠ
çããã°ã匷床ãããã«æ°åã®å€ã«ãŸã§é«ããã
ãšãã§ããããã®ç¹ç¶ã¯ã¿ã€ã€ã³ãŒãããŽã è£åŒ·
æããã€ã©ãŒããã®ä»èç±æ§å·¥æ¥è³æçã«æå©ã«
çšããããšãã§ããã ãŸãããã€ã«ã ã¯äŸãã°300ã400âã§ãã€ãã
溶èæŒåºãããã©ã ã«å·»åãããšã«ãã€ãŠåŸãã
ãšãã§ããããã€ã«ã æ圢æ©ã¯ãåŸæ¥å ¬ç¥ã®è£ 眮
ã䜿çšããããšãã§ãããæŒåºæã®ãã©ããã¯ïŒ
ã50ã奜ãŸããã¯ïŒã10ã§ããããã©ã äžã«æŒã
åºããããã€ã«ã ã¯åžžæž©ã§æŸå·ããŠãããããŸã
æ°Žäžã§æ¥å·ããŠããããããããŠåŸãããããªãš
ã¹ãã«ãã€ã«ã ã¯ã次ãã§å¿ èŠã«ããäºè»žå»¶äŒžã
ãããšãã§ãããäºè»žå»¶äŒžã¯ããèªäœå ¬ç¥ã®æ¹æ³
ããã³è£ 眮ãçšããŠè¡ãªãããšãã§ãããéåžžã
äºè»žå»¶äŒžã¯æ©æ¢°è»žæ¹åããã³ãããšçŽè§æ¹åã«ã
ãããçŽ1.1ãçŽïŒåã«å»¶äŒžããããšã«ããå®æœ
ã§ããã延䌞ã¯çŽ150ãçŽ250ã®æž©åºŠã§å®æœããã
ãšãã§ããã æ¬çºææ¹æ³ã«ããåŸããããã€ã«ã ã¯ãæªå»¶äŒž
ãã€ã«ã ã§ãããäŸãã°çŽ30KgïŒmm2以äžã®åŒ·åºŠã
çŽ700KgïŒmm2以äžã®ã€ã³ã°çã瀺ãã é«ã匷床ãã€ã³ã°çã瀺ããããæ¬çºæã®ãã€
ã«ã ã¯ããããã®åªããæ©æ¢°çæ§è³ªãå©çšããŠã
äŸãã°ç£æ°ããŒãçšãã€ã«ã ãéå±èžççšãã€ã«
ã ããã¬ãã·ãã«ããªã³ãé ç·çšãã€ã«ã ãé»æ°
絶çžçšãã€ã«ã çãšããŠçšããããšãã§ããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ãå°±äžãã€ãã
ããã³éªšæ Œã«ïŒçŽãŸãã¯ïŒçŽã®ççŽ ååã§çµåã
ãŠãã眮æåºãæããŠããã¢ã眮æãã€ãããã
ã³ã«ç±æ¥ããåäœãå«æããå šè³éŠæããªãšã¹ã
ã«ã¯ãåèšã®ãšãããææ©æº¶åªã«æº¶è§£æ§ã瀺ãã®
ã§ãææ©æº¶åªäžã®ããŒãã調補ããããèªäœå ¬ç¥
ã®äŸãã°æµå»¶æ³ã«åŸã€ãŠãã€ã«ã ã«å€æããããš
ãã§ããã ãã®ããã«ããŠè£œé ãããã€ã«ã ããŸãäžèšæº¶
èæ圢æ³ã«ãã€ãŠåŸããããã€ã«ã ãšåæ§ã«ãé«
ã匷床ãšã€ã³ã°çãšãæããŠããã å®æœäŸïŒœ 以äžãå®æœäŸã«ãã€ãŠæ¬çºæã説æããããªã
å®æœäŸäžãéšããšããã®ã¯ãã¹ãŠãéééšãã§ã
ãããŸããæ¬çºæã«ãããåºæç²åºŠã¯å šè³éŠæã
ãªãšã¹ãã«10mgã10mlã®æ··å溶åªïŒïœâã¯ããã
ãšããŒã«ïŒããã©ã¯ãããšã¿ã³ïŒïŒïŒ1volïŒvol
æ··åç©ïŒã«æº¶è§£ãã50âã§çžå¯Ÿç²åºŠïŒÎ·rïŒããªã¹
ãã¯ã«ãç²åºŠèšã«ããæ±ããäžèšåŒã§æ±ããã åºæç²åºŠïŒln ηrïŒ0.1 ãŸããæµãéå§æž©åºŠã¯å šè³éŠæããªãšã¹ãã«ã
å£åŸ0.5mmãé·ãïŒmmã®å£éãåããé«ååŒãã
ãŒãã¹ã¿ãŒã«å ¥ãã60KgïŒcm2ã®å å§äžã«æ¯åçŽïŒ
âã§ææž©ãã該ããªãšã¹ãã«ãå£éããæµåºãé
å§ãã枩床ãšããŠæ±ããã ããã«ãŸããæ¯éã¯ãããªããŒã200âã§ïŒæ
éå ç±åŠçããŠçµæ¶åãããåå¡©åççŽ âïœâã
ããµã³æ··å溶åªãçšããŠæ¯éç¶ã§æž¬å®ããã ããã«ãèå æ°Žå解æ§ã¯ãããªããŒ1.0ïœã240
âã®æž©åºŠã§15æéç±åŠçããŠçµæ¶åãããã®ã¡ã
10mlã®èžçæ°Žãšãšãã«å°ç®¡ãã次ãã§120âã®æž©
床ã§48æéç±åŠçãã該å ç±åŠçåã®åºæç²åºŠ
ïŒÎ·inhïŒããšåŠçåŸã®åºæç²åºŠïŒÎ·inhïŒãæ±ãäžèš
åŒããæ±ããã èå æ°Žå解æ§ïŒïŒ ïŒïŒïœïŒÎ·inhïŒïŒïŒÎ·inhïŒ0ïœ
Ã100 å®æœäŸ ïŒ ãã¬ãã¿ã«é žãžããšãã« 318éš ã¢ãã¡ãã«ãã³ãžã«ãã€ããããã³ 225éš äžé žåã¢ã³ãã¢ã³ 0.1éš ãåžžå§äž260âã§30åã270âã§30åãããã«290
âã§30åããšããŒã«ãçå»ãã€ã€åå¿ããããã
次ãã§æ¬¡ç¬¬ã«ææž©ãã€ã€ããã€20åéã«100mmHg
ãã€æžå§åºŠãé«ãã€ã€ããšããŒã«ãçå»ããŠéçž®
ååå¿ãè¡ãªããæåŸã«çŽïŒmmHgã®é«ç空äž360
âã§20åéçž®åãè¡ãªãããã åŸãããããªãšã¹ãã«ã®æµãéå§æž©åºŠã¯345âã
åºæç²åºŠã¯3.55ã§ãã€ãã ãã®ããªãšã¹ãã«ã380âã§æº¶èããå£åŸ0.3mm
ã®å£éãæã€çŽ¡ç³žæ©ãçšããŠæŒåºããæ¯å50ïœã®
é床ã§ãã©ãã20ã§å·»åã€ããåŸãããç¹ç¶ã®ç¹
床ã¯40ãããŒã«ã匷床6.2ïœïŒdeãã€ã³ã°ç5000
KgïŒmmã䌞床2.4ïŒ ã§ãã€ãããŸããããªãšã¹ã
ã«ã®æ¯éã¯1.200ãèå æ°Žå解æ§ã¯95ïŒ ã§ãã€ãã ãŸãããã®ããªãšã¹ãã«ã370âã§æº¶èæ圢ã
ãæ圢åã®ç±å€åœ¢æž©åºŠïŒç±å€åœ¢æž©åºŠã®æž¬å®ã¯
ASTMNO â648ïŒã¯300â以äžã§ããã極ã
ãŠé«ãç±å€åœ¢æž©åºŠãæããã å®æœäŸ ïŒãïŒ ç¬¬ïŒè¡šã«ç€ºãçµæã®åæã䜿çšããå®æœäŸïŒãš
åæ§ã«ããŠããªãšã¹ãã«ã補é ããããã«æº¶è玡
糞ãæ圢ããã
眮æãããã¢ã眮æãã€ããããã³ã«ç±æ¥ããå
äœãããããå šæ§æåäœã®å°ãªããšãçŽïŒã¢ã«
ïŒ ã奜ãŸããã¯çŽ20ã¢ã«ïŒ ããã奜ãŸããã¯çŽ30
ã¢ã«ïŒ ãå«æããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ãåœè©²æè¡å
éã§ããç¥ãããŠããããã«ãçåœéã®ãããã
ã·ã«åºãšã«ã«ããã·ã«åºãšãåå¿ããŠäž»éã圢æ
ãããšã¹ãã«çµåãçæãããã®ã§ãããããå®
質çã«äžèš(a)åäœãšäžèš(b)åäœãšãçåœéã§å«æ
ããŠããã åŸã€ãŠãäŸãã°ãã¬ãã¿ã«é ž10ã¢ã«ãïŒâαâ
ããšããã«ãã€ããããã³10ã¢ã«ããã³ïœâãªã
ã·å®æ¯éŠé ž90ã¢ã«ãšãã圢æããããäžèš(c)åäœ
ãå«ãå šè³éŠæããªãšã¹ãã«ã¯ããã¬ãã¿ã«é žã«
ç±æ¥ããåäœ(a)ããã³ïŒâαâããšããã«ãã€ã
ãããã³ã«ç±æ¥ããåäœ(b)ãããããå šæ§æåäœ
ïŒ110ã¢ã«ïŒã«å¯ŸãçŽïŒã¢ã«ïŒ ã§å«æããããšã«ãª
ãã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ãäžèšã®åŠã
æ§ææåããç解ããããšãããååéã¯çŽç·æ§
ã«åªãããã®æº¶èç©ã¯å åŠçç°æ¹æ§ãæãããæ¬
çºæã®å šè³éŠæããªãšã¹ãã«ã¯ãããã«ãããã
ããæ¯èŒçäœãèç¹ãšåŸã«å®çŸ©ããæµãéå§æž©
床ãäŸãã°çŽ250ãçŽ360âãšãæããŠããããã
æ 溶èæ圢æ§ã«åªãããã€æº¶èæ圢æã«é žåå解
ãç±å解ã«ããå£åãã倧ããä¿è·ãããåªãã
çš®ã ã®æ圢åãäžããããšãã§ããã ç¹ã«æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ææ©æº¶
åªãäŸãã°ã¯ããããšããŒã«ãããšããŒã«ãšãã
ã©ã¯ãããšã¿ã³ã®æ··å液ãïœâã¯ããããšããŒã«
ãšããã©ã¯ãããšã¿ã³ã®æ··å液ãããªãã«ãªãé ¢
é žãšã¯ãããã«ã ã®æ··å液ããã³ããªãã«ãªãé ¢
é žãšããã©ã¯ãããšã¿ã³ã®æ··å液çã«å¯ŸããŠæº¶è§£
æ§ã瀺ãããŸãããã®ãããªå šè³éŠæããªãšã¹ã
ã«ã¯ãææ©æº¶åªã«å¯ŸããŠæº¶è§£æ§ã瀺ãããã«ãäŸ
ãã°çš®ã ã®ããã«æ§ååç©ã«å¯ŸããŠèŠªåæ§ã瀺
ããããæ ãã®æ圢åãããã«æ§ååç©ã§åŠçã
ãããšã«ããæ圢åäžã«ããã«ååç©ãå°å ¥ãã
ããšãã§ããããã®ããšã¯ãæ¬çºæã®å šè³éŠæã
ãªãšã¹ãã«ã«å¯ŸããåŸå å·¥ã«ãã€ãŠãããã«çš®ã
ã®ææã®æ§è³ªãäŸãã°å¯žæ³å®å®æ§ãèé žåæ§ãå
åŠæµæçãä»äžã§ããããšãæå³ããŠããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ãåŸã«å®çŸ©ã
ãæ¹æ³ã«åŸã€ãŠïœâã¯ããããšããŒã«ãšããã©ã¯
ãããšã¿ã³ã®æ··å溶åªäžã®æº¶æ¶²ãšããŠæž¬å®ããåº
æç²åºŠãã奜ãŸããã¯0.8以äžã§ããããã奜ãŸ
ããã¯2.0以äžãç¹ã«å¥œãŸããã¯3.0以äžã§ããã æ¬çºæã«ãããâ溶èç°æ¹æ§âãšã¯ãããªããŒ
ã溶èç¶æ ã«ãã€ãŠãå åŠçã«ç°æ¹æ§ã瀺ãããš
ãæå³ãããäŸãã°ãç¹éæ53â109598å·å ¬å ±ã«
ã¯æº¶èç°æ¹æ§ã瀺ãå šè³éŠæããªãšã¹ãã«ã®ç¹æ§
ã詳述ããŠããã æ¬çºæã®æº¶èç°æ¹æ§å šè³éŠæããªãšã¹ãã«ã¯ã
å®éçš®ã ã®æ¹æ³ã§è£œé ããããšãã§ãããäŸã
ã°ãã¢ãªãŒã«ã«ãŒãããŒãã®ååšäžã§æå®ã®æå
ãå ç±éçž®åããããæ¹æ³ãè³éŠæãžã«ã«ãã³
é žãè³éŠæãžããããã·ååç©ããã³ïœâé åæ§
è³éŠæãªãã·ã«ã«ãã³é žã®å°ãªããšãããããäž
ã€ããšã¹ãã«ãšããŠçšããæå®ã®æåãå ç±éçž®
åããããæ¹æ³çãæããããã ãããã®æ¹æ³ã«å å«ããã奜ãŸããå®æœæ æ§
ãã説æã®äŸ¿ã®ããããã¬ãã¿ã«é žãïŒâαâã
ãšããã«ãã€ããããã³ããã³ïœâãªãã·å®æ¯éŠ
é žã«ç±æ¥ããåäœãããªãæ¬çºæã®å šè³éŠæããª
ãšã¹ãã«ã補é ããå Žåã«ã€ããŠä»¥äžã«èª¬æã
ãã (1) ãã¬ãã¿ã«é žãšïœâãªãã·å®æ¯éŠé žã«ãžããš
ãã«ã«ãŒãããŒãã®åŠãã¢ãªãŒã«ã«ãŒãããŒã
ãå ããå ç±ããšã¹ãã«ååå¿ãè¡ãªãããã®
ã¡ãïŒâαâããšããã«ãã€ããããã³ãå ã
ãŠå ç±éçž®åãããæ¹æ³ïŒä»¥äžã第ïŒã®æ¹æ³ãš
ããïŒ (2) ïœâãªãã·å®æ¯éŠé žããšãã«ããã¬ãã¿ã«é ž
ãžããšãã«ããã³ïŒâαâããšããã«ãã€ãã
ããã³ã®æ··åç©ãå ç±ãéçž®åãããæ¹æ³ïŒä»¥
äžç¬¬ïŒã®æ¹æ³ãšããïŒ ç¬¬ïŒã®æ¹æ³ã«ã€ããŠå ã説æããã ã¢ãªãŒã«ã«ãŒãããŒããšããŠã¯ãäŸãã°ãžããš
ãã«ã«ãŒãããŒãããžããªã«ã«ãŒãããŒãããžïœ
âã¯ãã«ããšãã«ã«ãŒãããŒããããšãã«ããªã«
ã«ãŒãããŒãããã³ããªïŒâαâããšããã«ããš
ãã¬ã³ã«ãŒãããŒãã®åŠãããªã«ãŒãããŒããæ
ããããšãã§ããããããã®ãã¡ãžããšãã«ã«ãŒ
ãããŒããå質ã®å®å®æ§ãçŽåºŠãåå¿æ§çã®ç¹ã
ã奜ãŸããçšããããããã®ã¢ãªãŒã«ã«ãŒãããŒ
ãã®äœ¿çšéã¯ããã¬ãã¿ã«é žããã³ïœâãªãã·å®
æ¯éŠé žã®éé¢ã«ã«ããã·ã«åºïŒåœéåœãã«ãŒãã
ãŒãçµåæç®å€ã§0.9ã1.1ååœéãç¹ã«ã»ãŒïŒå
åœéã§ããããšã奜ãŸããã åå¿ã¯éåžž200ã300âã奜ãŸããã¯200ã280â
ã®æž©åºŠã«ãŠãåå¿ã«ãã€ãŠçæããçé žã¬ã¹ã®çº
çãå®è³ªçã«åæ¢ãããŸã§è¡ãªãããã®åå¿ã¯ïŒ
ãïŒæéãé©åœã§ããã奜ãŸããã¯è§Šåªã®ååšäž
ã§è¡ãªãããã®è§ŠåªãšããŠã¯ããã¿ã³ååç©ãäŸ
ãã°ãã¿ã³ããã©ãããã·ããã·ãŠãŠé žãã¿ã
ã«ãé ¢é žãã¿ã³çïŒã¹ãºååç©ãäŸãã°é ¢é žç¬¬ïŒ
ã¹ãºïŒãã®ä»çé žäºéãé žåéãäžé žåã¢ã³ãã¢
ã³ãäºé žåã¢ã³ãã¢ã³ãäžé žåãã¹ãã¹ãé ¢é žã»
ãªãŠã ãé žåã©ã³ã¿ã³ãé žåãªããŠã ãå®æ¯éŠé ž
ã«ãªãé ¢é žã«ã«ã·ãŠã ãé žåãã°ãã·ãŠã ãé ¢é ž
ãã°ãã·ãŠã ãªã©ã®åŠãéãã¢ã³ãã¢ã³ããã¹ã
ã¹ãã»ãªãŠã ãã©ã³ã¿ã³ããªããŠã ããããªãŠ
ã ãã«ãªãŠã ãäºéããã°ãã·ãŠã ãã«ã«ã·ãŠã
çã®éå±ãå«ãååç©ãäŸç€ºããããšãã§ããã
ãããã®ãã¡ãã¿ã³ãã¹ãºããã³ã¢ã³ãã¢ã³ãå«
ãååç©ãã次ã®éçž®ååå¿ãšå ±éããŠçšããã
ãšãã§ããã®ã§å¥œãŸããã觊åªã®äœ¿çšéã¯ãã¬ã
ã¿ã«é žã«å¯Ÿã0.005ã0.5ã¢ã«ïŒ ãããã«ã¯0.01ã
0.1ã¢ã«ïŒ ã§ããããšã奜ãŸããã ãã®ããã«ããŠãã¬ãã¿ã«é žãšã¢ãªãŒã«ã«ãŒã
ããŒãã®åå¿ãçµçµãããšãåå¿ç³»å ã®æž©åºŠã
200ã280âã«ä¿ã¡ã€ã€ããã¬ãã¿ã«é žæåïŒã¢ã«
åœã1.0ã1.3ã¢ã«ããã奜ãŸããã¯1.01ã1.2ã¢ã«
ã®ïŒâαâããšããã«ãã€ããããã³ãæ·»å ãã
次ã®éçž®ååå¿ãè¡ãªãã éçž®ååå¿ã¯ãå®è³ªçã«ç¡è§Šåªã§ãé²è¡ãã
ããåŸæ¥å ¬ç¥ã®ãšã¹ãã«äº€æ觊åªãçšããŠè¡ãªã
ã®ã奜ãŸããããã®ãšã¹ãã«äº€æ觊åªã®ãã¡å¥œé©
ãªãã®ãšããŠã«ã«ã·ãŠã ããã°ãã·ãŠã ãã¹ãã
ã³ããŠã ãããªãŠã ãã©ã³ã¿ã³ãã»ãªãŠã ããã³
ã¬ã³ãã³ãã«ããäºéãã²ã«ãããŠã ãã¹ãºã
éãã¢ã³ãã¢ã³ããã¹ãã¹ãªã©ã®éå±ãå«ãåå
ç©ãäŸç€ºã§ããããã«ãã®å ·äœäŸãšããŠé ¢é žãã°
ãã·ãŠã ãå®æ¯éŠé žã«ã«ã·ãŠã ãé ¢é žã¹ããã³ã
ãŠã ãããããªã³é žããªãŠã ãçé žã©ã³ã¿ã ãé ž
åã»ãªãŠã ãé ¢é žãã³ã¬ã³ãé ¢é žã³ãã«ããé ¢é ž
äºéãé žåã²ã«ãããŠã ãé ¢é žç¬¬ïŒã¹ãºãé žå
éãäžé žåã¢ã³ãã¢ã³ãäžé žåãã¹ãã¹ãªã©ãäŸ
瀺ã§ããã ãããã®ãšã¹ãã«äº€æïŒéçž®åïŒè§Šåªãšãšãã«
å®å®å€ã䜿çšããããšã奜ãŸããã奜ãŸããå®å®
å€ã®äŸã¯ãåŸæ¥å ¬ç¥ã®ïŒäŸ¡ãããã¯ïŒäŸ¡ã®ãªã³å
åç©ãŸãã¯ãã®ãšã¹ãã«é¡ã§ãããäŸãã°äºãªã³
é žããªã³é žãããšãã«ãã¹ãã³é žãã¡ãã«ãã¹ã
ã³é žããšãã«ãã¹ãã³é žããããã«ãã¹ãã³é žã
ããã«ãã¹ãã³é žããã³ãžã«ãã¹ãã³é žãããªã¡
ãã«ãã¹ãã¢ã€ããããªã¡ãã«ãã¹ããšãŒããã
ãªãšãã«ãã¹ããšãŒããããªããã«ãã¹ããšãŒ
ããããªããšãã«ãã¹ãã¢ã€ããããªããšãã«ã
ã¹ããšãŒãããžãšãã«ããšãã«ãã¹ãããŒãããž
ã¡ãã«âïŒã¡ãã«ïŒãã¹ãããŒãããžã¡ãã«âïŒãš
ãã«ïŒãã¹ãããŒãããžã¡ãã«ïŒãã³ãžã«ïŒãã¹
ãããŒããªã©ãæããããšãã§ããããããå®å®
å€ã¯ãããªããŒã®æº¶èå®å®æ§ãè²èª¿ãæ¹è¯ãã
ãã觊åªã®çš®é¡ã«ãã€ãŠã¯è©²éçž®å觊åªãäžæŽ»æ§
åãããããããŠè§ŠåªãäžæŽ»æ§åããå Žåã«ã¯ã
å®å®å€ã¯éçž®ååå¿çµäºåŸã«å ããããšã奜ãŸã
ããã¢ã³ãã¢ã³ãŸãã¯ã²ã«ãããŠã ãå«ãéçž®å
觊åªã¯å®å®å€ã«ãã€ãŠäžæŽ»æ§åãããªãã®ã§ã該
觊åªãçšããå Žåã«ã¯å®å®å€ã¯éçž®ååå¿ã®æå
ããå ããããšãã§ããã ããããšã¹ãã«äº€æïŒéçž®åïŒè§Šåªã®äœ¿çšé
ã¯ããã¬ãã¿ã«é žãšïœâãªãã·å®æ¯éŠé žã®åèšã¢
ã«æ°ã®0.005ã0.5ã¢ã«ïŒ ãããã«ã¯0.01ã0.1ã¢ã«
ïŒ ã§ããããšã奜ãŸããããŸãå®å®å€ã®é(p)ã¯äž
èšéçž®å觊åªã®äœ¿çšéïŒïŒ®ã¢ã«ïŒã«å¯Ÿãã0.8ïŒ
ïŒïŒ®ïŒ1.5ïŒäœããïŒå®å®å€ã®ã¢ã«ïŒäœ¿çšãã
ã®ã奜ãŸããã ãããéã®è§Šåªãå Žåã«ãã€ãŠã¯å®å®å€ããã³
ïŒâαâããšããã«ãã€ããããã³ãåå¿ç³»ã«æ·»
å ããã®ã¡ãåå¿ç³»ãäŸãã°250ã300âãšããŠåžž
å§äžåå¿ãè¡ãªããçæããã¢ãããããã·è³éŠ
æååç©ãäŸãã°ããšããŒã«ãç³»å€ã«æºåºããã
ãŠéçž®åãé²è¡ãããããéçž®ååå¿ã¯çæãã
ã¢ãããããã·è³éŠæååç©ãç³»å€ã«æºåºããã
ã€ã€ãæåã¯åžžå§äžã次ãã§æžå§äžã§è¡ãªãã åžžå§äžã®åå¿ã¯åå¿æž©åºŠãé次äžæããããŠå®
æœããã®ã奜ãŸããããããåžžå§äžã®åå¿ã¯è³éŠ
æã¢ãããããã·ååç©ãæºåºããããéããã§
ããã ãäœãåå¿æž©åºŠã§é²è¡ããããã®ã奜ãŸã
ããäŸãã°ã250â以äžã®æž©åºŠã§ãéçž®ååå¿ã¯
ãã€ãããšé²è¡ãããããã®ãããªæž©åºŠã§ã¯çæ
ããè³éŠæã¢ãããããã·ååç©ãã»ãšãã©åå¿
ç³»å€ã«æºåºããªãã®ã§ãéçž®ååå¿ã¯ãŸããªãå¹³
è¡¡ã«éããŠããŸãã åŸã€ãŠãå®éçã«ã¯260âçšåºŠã®åå¿æž©åºŠãã
éçž®ååå¿ãå§ããŠæ¬¡ç¬¬ã«ææž©ããè³éŠæã¢ãã
ãããã·ååç©ã®çè«æºåºéã®çŽ35ã60ïŒ ã«éã
ãæç¹ã§290âçšåºŠã®åå¿æž©åºŠãšããã®ã奜ãŸã
ããåå¿æž©åºŠãæåãã290âãããã¯ãã以äž
ã®é«æž©ã«èšå®ããŠåå¿ãé²è¡ãããããšãã²ã«å
çã®å¥œãŸãããªãå¯åå¿ãåŒãèµ·ããããšãã
ãããããéã®è³éŠæã¢ãããããã·ååç©ãç³»
å€ã«æºåºããåŸã次ãã§åå¿ç³»ãæžå§ã«ãããã
ã«çæããè³éŠæã¢ãããããã·ååç©ãç³»å€ã«
æºåºãããã€ã€ã次第ã«æžå§åºŠããã³åå¿æž©åºŠã
é«ãæçµçã«ïŒmmHgçšåºŠãããã¯ãã以äžã®å§
åäžã320ã370âã®åå¿æž©åºŠã§åå¿ããããŠæå®
ã®éå床ã®ããªããŒãçæããããããšã奜ãŸã
ãã 次ã«ç¬¬ïŒã®æ¹æ³ã«ã€ããŠèª¬æããã ïœâãªãã·å®æ¯éŠé žããšãã«ããã³ãã¬ãã¿ã«
é žãžããšãã«ã¯ãäŸãã°ïœâãªãã·å®æ¯éŠé žãŸã
ã¯ãã¬ãã¿ã«é žããžããšãã«ã«ãŒãããŒããŸãã¯
ããšããŒã«ãšããèªäœå ¬ç¥ã®æ¹æ³ã«åŸã€ãŠåå¿ã
ãããããšã«ãã補é ããããšãã§ããã ïœâãªãã·å®æ¯éŠé žããšãã«ããã³ãã¬ãã¿ã«
é žãžããšãã«ãšïŒâαâããšããã«ãã€ãããã
ã³ãšã®æ··åç©ããå ç±éçž®åããããæ¹æ³ã¯ãäž
èšç¬¬ïŒã®æ¹æ³ã«ãããŠèšèŒããéçž®ååå¿æ¡ä»¶ãš
å šãåæ§ã®æ¡ä»¶äžã§å®æœããããšãã§ããã ãã®ç¬¬ïŒã®æ¹æ³ã«ããã°ãïœâãªãã·å®æ¯éŠé ž
ããšãã«ããã³ãã¬ãã¿ã«é žãžããšãã«ãé«çŽåºŠ
ã®ç¶æ ã§ïŒâαâããšããã«ãã€ããããã³ãšå
å¿ããããããšãã§ããã®ã§ãåŸãããå šè³éŠæ
ããªãšã¹ãã«ã®å質ã¯ããåäžããã第ïŒã®æ¹æ³
ã¯ãããæå³ã«ãããŠäžèšç¬¬ïŒã®æ¹æ³ããã奜ãŸ
ããã ããããŠåŸãããæ¬çºæã®å šè³éŠæããªãšã¹ã
ã«ã¯ãäžèšãããšããã溶èç°æ¹æ§ã瀺ãã«ãã
ãããããæ¯èŒçèç¹ããã³æµåéå§æž©åºŠãäœ
ããåŸã€ãŠå åŠçç°æ¹æ§æº¶èç©ãã容æã«æº¶è圢
æãåŸãç¹åŸŽãæããŠããã ããæ ãæ¬çºæã«ããã°ãæ¬çºæã®æº¶èç°æ¹æ§
å šè³éŠæããªãšã¹ãã«ãç±æº¶èããããŠå åŠçç°
æ¹æ§æº¶èç©ã圢æãã該溶èç©ãããèªäœå ¬ç¥ã®
溶èæ圢æ³ã«åŸã€ãŠãã€ã«ã ãŸãã¯ç¹ç¶ã«å€æã
ãããšãç¹åŸŽãšããã溶èç°æ¹æ§å šè³éŠæããªãš
ã¹ãã«ã®ãã€ã«ã ãŸãã¯ç¹ç¶ã補é ããæ¹æ³ãå
æ§ã«æäŸãããã åŸæ¥å ¬ç¥ã®æº¶èç°æ¹æ§å šè³éŠæããªãšã¹ãã«ã¯
äžè¬ã«æ¯èŒçèç¹ããã³æµåéå§æž©åºŠãé«ããã
ãæ ã該ããªãšã¹ãã«ã®ç±å解枩床ãé¿ããŠå®å®
ãªæº¶èç©ã圢æã§ãã枩床ç¯å²ãéåžžã«çãããŸ
ãæ¯èŒçé«ã溶èç²åºŠã瀺ã溶èç©ãäžããã
ãã溶èæ圢æ³ã«åŸã€ãŠåªããæ©æ¢°çæ§è³ªã瀺ã
æ圢åãäžããããšã¯å°é£ã§ãããäžå¯èœã§ãã€
ãã æ¬çºæã«ããã°ãå šè³éŠæããªãšã¹ãã«ã¯èç¹
ãšå解枩床ã®éã®æž©åºŠã«å ç±ãããŠå åŠçç°æ¹æ§
溶èç©ã圢æãããäžè¬ã«ãå ç±æž©åºŠã¯å šè³éŠæ
ããªãšã¹ãã«ã®æµãéå§æž©åºŠãšèç¹ããçŽ50âé«
ã枩床ãšã®éãšããã®ã奜ãŸããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ã¯ã奜ãŸããã¯
æµãéå§æž©åºŠãçŽ250ãçŽ360âã®éã«ããããã
äŸãã°ãããå šè³éŠæããªãšã¹ãã«ã¯ãäŸãã°çŽ
400âããäœã枩床ã§å®æœã§ãããäžè¬ã«ã¯ãçŽ
300âãçŽ400âã®æž©åºŠã奜ãŸããæ¡çšãããã æ¬çºææ¹æ³ã«ããã°ãæ¬çºæã®å šè³éŠæããªãš
ã¹ãã«ããçš®ã ã®åœ¢æ ã®æ圢åã補é ããããšã
ã§ãããããå ·äœçã«èª¬æããã°ãäŸãã°ç¹ç¶ã¯
å šè³éŠæããªãšã¹ãã«ãäŸãã°300ã400âã§æº¶è
ãã玡糞å£éããæŒåºããŠãã©ããçïŒã500ã
å·»åé床10ã500ïœïŒminã§å·»åãããšã«ããåŸ
ãããšãã§ãããåŸãããããªãšã¹ãã«ç¹ç¶ã¯ã
å¿ ããã延䌞ãç±åŠçã«ä»ãå¿ èŠã¯ãªãã溶è玡
糞ãå·»åãã ãã§ãäŸãã°åŒ·åºŠïŒïœïŒde以äžã
ã€ã³ã°ïœç2500KgïŒmm2以äžã®é«åŒ·åºŠãé«ã€ã³ã°ç
ã®ç¹ç¶ãåŸãããšãã§ããããã®ç¹ç¶ãç¹ç¶ã®åœ¢
æ ãä¿æããŠãäŸãã°200ã300âã§çŽ10æéç±åŠ
çããã°ã匷床ãããã«æ°åã®å€ã«ãŸã§é«ããã
ãšãã§ããããã®ç¹ç¶ã¯ã¿ã€ã€ã³ãŒãããŽã è£åŒ·
æããã€ã©ãŒããã®ä»èç±æ§å·¥æ¥è³æçã«æå©ã«
çšããããšãã§ããã ãŸãããã€ã«ã ã¯äŸãã°300ã400âã§ãã€ãã
溶èæŒåºãããã©ã ã«å·»åãããšã«ãã€ãŠåŸãã
ãšãã§ããããã€ã«ã æ圢æ©ã¯ãåŸæ¥å ¬ç¥ã®è£ 眮
ã䜿çšããããšãã§ãããæŒåºæã®ãã©ããã¯ïŒ
ã50ã奜ãŸããã¯ïŒã10ã§ããããã©ã äžã«æŒã
åºããããã€ã«ã ã¯åžžæž©ã§æŸå·ããŠãããããŸã
æ°Žäžã§æ¥å·ããŠããããããããŠåŸãããããªãš
ã¹ãã«ãã€ã«ã ã¯ã次ãã§å¿ èŠã«ããäºè»žå»¶äŒžã
ãããšãã§ãããäºè»žå»¶äŒžã¯ããèªäœå ¬ç¥ã®æ¹æ³
ããã³è£ 眮ãçšããŠè¡ãªãããšãã§ãããéåžžã
äºè»žå»¶äŒžã¯æ©æ¢°è»žæ¹åããã³ãããšçŽè§æ¹åã«ã
ãããçŽ1.1ãçŽïŒåã«å»¶äŒžããããšã«ããå®æœ
ã§ããã延䌞ã¯çŽ150ãçŽ250ã®æž©åºŠã§å®æœããã
ãšãã§ããã æ¬çºææ¹æ³ã«ããåŸããããã€ã«ã ã¯ãæªå»¶äŒž
ãã€ã«ã ã§ãããäŸãã°çŽ30KgïŒmm2以äžã®åŒ·åºŠã
çŽ700KgïŒmm2以äžã®ã€ã³ã°çã瀺ãã é«ã匷床ãã€ã³ã°çã瀺ããããæ¬çºæã®ãã€
ã«ã ã¯ããããã®åªããæ©æ¢°çæ§è³ªãå©çšããŠã
äŸãã°ç£æ°ããŒãçšãã€ã«ã ãéå±èžççšãã€ã«
ã ããã¬ãã·ãã«ããªã³ãé ç·çšãã€ã«ã ãé»æ°
絶çžçšãã€ã«ã çãšããŠçšããããšãã§ããã æ¬çºæã®å šè³éŠæããªãšã¹ãã«ãå°±äžãã€ãã
ããã³éªšæ Œã«ïŒçŽãŸãã¯ïŒçŽã®ççŽ ååã§çµåã
ãŠãã眮æåºãæããŠããã¢ã眮æãã€ãããã
ã³ã«ç±æ¥ããåäœãå«æããå šè³éŠæããªãšã¹ã
ã«ã¯ãåèšã®ãšãããææ©æº¶åªã«æº¶è§£æ§ã瀺ãã®
ã§ãææ©æº¶åªäžã®ããŒãã調補ããããèªäœå ¬ç¥
ã®äŸãã°æµå»¶æ³ã«åŸã€ãŠãã€ã«ã ã«å€æããããš
ãã§ããã ãã®ããã«ããŠè£œé ãããã€ã«ã ããŸãäžèšæº¶
èæ圢æ³ã«ãã€ãŠåŸããããã€ã«ã ãšåæ§ã«ãé«
ã匷床ãšã€ã³ã°çãšãæããŠããã å®æœäŸïŒœ 以äžãå®æœäŸã«ãã€ãŠæ¬çºæã説æããããªã
å®æœäŸäžãéšããšããã®ã¯ãã¹ãŠãéééšãã§ã
ãããŸããæ¬çºæã«ãããåºæç²åºŠã¯å šè³éŠæã
ãªãšã¹ãã«10mgã10mlã®æ··å溶åªïŒïœâã¯ããã
ãšããŒã«ïŒããã©ã¯ãããšã¿ã³ïŒïŒïŒ1volïŒvol
æ··åç©ïŒã«æº¶è§£ãã50âã§çžå¯Ÿç²åºŠïŒÎ·rïŒããªã¹
ãã¯ã«ãç²åºŠèšã«ããæ±ããäžèšåŒã§æ±ããã åºæç²åºŠïŒln ηrïŒ0.1 ãŸããæµãéå§æž©åºŠã¯å šè³éŠæããªãšã¹ãã«ã
å£åŸ0.5mmãé·ãïŒmmã®å£éãåããé«ååŒãã
ãŒãã¹ã¿ãŒã«å ¥ãã60KgïŒcm2ã®å å§äžã«æ¯åçŽïŒ
âã§ææž©ãã該ããªãšã¹ãã«ãå£éããæµåºãé
å§ãã枩床ãšããŠæ±ããã ããã«ãŸããæ¯éã¯ãããªããŒã200âã§ïŒæ
éå ç±åŠçããŠçµæ¶åãããåå¡©åççŽ âïœâã
ããµã³æ··å溶åªãçšããŠæ¯éç¶ã§æž¬å®ããã ããã«ãèå æ°Žå解æ§ã¯ãããªããŒ1.0ïœã240
âã®æž©åºŠã§15æéç±åŠçããŠçµæ¶åãããã®ã¡ã
10mlã®èžçæ°Žãšãšãã«å°ç®¡ãã次ãã§120âã®æž©
床ã§48æéç±åŠçãã該å ç±åŠçåã®åºæç²åºŠ
ïŒÎ·inhïŒããšåŠçåŸã®åºæç²åºŠïŒÎ·inhïŒãæ±ãäžèš
åŒããæ±ããã èå æ°Žå解æ§ïŒïŒ ïŒïŒïœïŒÎ·inhïŒïŒïŒÎ·inhïŒ0ïœ
Ã100 å®æœäŸ ïŒ ãã¬ãã¿ã«é žãžããšãã« 318éš ã¢ãã¡ãã«ãã³ãžã«ãã€ããããã³ 225éš äžé žåã¢ã³ãã¢ã³ 0.1éš ãåžžå§äž260âã§30åã270âã§30åãããã«290
âã§30åããšããŒã«ãçå»ãã€ã€åå¿ããããã
次ãã§æ¬¡ç¬¬ã«ææž©ãã€ã€ããã€20åéã«100mmHg
ãã€æžå§åºŠãé«ãã€ã€ããšããŒã«ãçå»ããŠéçž®
ååå¿ãè¡ãªããæåŸã«çŽïŒmmHgã®é«ç空äž360
âã§20åéçž®åãè¡ãªãããã åŸãããããªãšã¹ãã«ã®æµãéå§æž©åºŠã¯345âã
åºæç²åºŠã¯3.55ã§ãã€ãã ãã®ããªãšã¹ãã«ã380âã§æº¶èããå£åŸ0.3mm
ã®å£éãæã€çŽ¡ç³žæ©ãçšããŠæŒåºããæ¯å50ïœã®
é床ã§ãã©ãã20ã§å·»åã€ããåŸãããç¹ç¶ã®ç¹
床ã¯40ãããŒã«ã匷床6.2ïœïŒdeãã€ã³ã°ç5000
KgïŒmmã䌞床2.4ïŒ ã§ãã€ãããŸããããªãšã¹ã
ã«ã®æ¯éã¯1.200ãèå æ°Žå解æ§ã¯95ïŒ ã§ãã€ãã ãŸãããã®ããªãšã¹ãã«ã370âã§æº¶èæ圢ã
ãæ圢åã®ç±å€åœ¢æž©åºŠïŒç±å€åœ¢æž©åºŠã®æž¬å®ã¯
ASTMNO â648ïŒã¯300â以äžã§ããã極ã
ãŠé«ãç±å€åœ¢æž©åºŠãæããã å®æœäŸ ïŒãïŒ ç¬¬ïŒè¡šã«ç€ºãçµæã®åæã䜿çšããå®æœäŸïŒãš
åæ§ã«ããŠããªãšã¹ãã«ã補é ããããã«æº¶è玡
糞ãæ圢ããã
ãè¡šã
åŸãããããªãšã¹ãã«æ圢åã®ç±å€åœ¢æž©åºŠãç²
床ããã³ç³žç©æ§ã¯ç¬¬ïŒè¡šã®åŠãã§ãã€ãã
床ããã³ç³žç©æ§ã¯ç¬¬ïŒè¡šã®åŠãã§ãã€ãã
ãè¡šã
å®æœäŸ ïŒãïŒ
第ïŒè¡šã«ç€ºãçµæã®åæã䜿çšããå®æœäŸïŒãš
åæ§ã«ããŠããªãšã¹ãã«ã補é ããã
åæ§ã«ããŠããªãšã¹ãã«ã補é ããã
ãè¡šã
åŸãããããªãšã¹ãã«ã®ç²åºŠãæ圢åã®ç±å€åœ¢
枩床ããã³ç³žç©æ§ã¯ç¬¬ïŒè¡šã®åŠãã§ãã€ãã
枩床ããã³ç³žç©æ§ã¯ç¬¬ïŒè¡šã®åŠãã§ãã€ãã
ãè¡šã
å®æœäŸ ïŒã10
çŽïŒmmHgã®é«ç空äžã§æž©åºŠã330âãšãã以å€
ã¯å®æœäŸïŒãšåæ§ã«è¡ãªã€ãŠã第ïŒè¡šã«ç€ºãããª
ãšã¹ãã«ãåŸãã
ã¯å®æœäŸïŒãšåæ§ã«è¡ãªã€ãŠã第ïŒè¡šã«ç€ºãããª
ãšã¹ãã«ãåŸãã
ãè¡šã
ãè¡šã
èš»ïŒè¡šäžã®å®æœäŸã®ããªãšã¹ãã«ã¯ãããããè¡šäž
ã«èšèŒãããåæ§æåäœãçã¢ã«éã§
å«æããŠããã
å®æœäŸ 11 å®æœäŸïŒã§åŸãããåºæç²åºŠ1.9ã®ããªãšã¹ã
ã«ãçŽ10ã16ã¡ãã·ãŠã«ç²ç ãã200âãã290â
ãŸã§ïŒæéãèŠããŠåŸã ã«ææž©ãããã€290âã§
ïŒæéå ç±ããŠçªçŽ æ°æµäžã§åºçžéåããããåº
æç²åºŠ6.4ã®ããªããŒãåŸãã ãã®ããªããŒãïœâã¯ããããšããŒã«å¯ŸïŒïŒ
ïŒïŒïŒïŒïŒâããã©ã¯ãããšã¿ã³ãïŒå¯ŸïŒïŒéé
æ¯ïŒã®æ··å溶åªäžã«140âã§æº¶è§£ããããªããŒã«
ã€ããŠïŒééïŒ ã®ããŒãã調補ããã ãã®ããŒããã¬ã©ã¹æ¿äžã«æµå»¶ãããã®ãŸãŸå€
éã®ã¢ã»ãã³äžã«æµžæŒ¬ããŠæº¶åªã®å€§éšåãé€å»
ããèªç«æ§ã®ãããã€ã«ã ç¶ç©ãšããã次ãã§ã
ãã®ãã®ãéæ ã§åºå®ããç空äžã60âã§ïŒæ
éã100âã§ïŒæéãããã«150âã§ïŒæé也ç¥ã
ç±åŠçããåãçŽ30ÎŒã®ãã€ã«ã ãåŸãã åŸãããããªãšã¹ãã«ãã€ã«ã ã®ç©æ§ã第ïŒè¡š
ã«ç€ºãã
ã«èšèŒãããåæ§æåäœãçã¢ã«éã§
å«æããŠããã
å®æœäŸ 11 å®æœäŸïŒã§åŸãããåºæç²åºŠ1.9ã®ããªãšã¹ã
ã«ãçŽ10ã16ã¡ãã·ãŠã«ç²ç ãã200âãã290â
ãŸã§ïŒæéãèŠããŠåŸã ã«ææž©ãããã€290âã§
ïŒæéå ç±ããŠçªçŽ æ°æµäžã§åºçžéåããããåº
æç²åºŠ6.4ã®ããªããŒãåŸãã ãã®ããªããŒãïœâã¯ããããšããŒã«å¯ŸïŒïŒ
ïŒïŒïŒïŒïŒâããã©ã¯ãããšã¿ã³ãïŒå¯ŸïŒïŒéé
æ¯ïŒã®æ··å溶åªäžã«140âã§æº¶è§£ããããªããŒã«
ã€ããŠïŒééïŒ ã®ããŒãã調補ããã ãã®ããŒããã¬ã©ã¹æ¿äžã«æµå»¶ãããã®ãŸãŸå€
éã®ã¢ã»ãã³äžã«æµžæŒ¬ããŠæº¶åªã®å€§éšåãé€å»
ããèªç«æ§ã®ãããã€ã«ã ç¶ç©ãšããã次ãã§ã
ãã®ãã®ãéæ ã§åºå®ããç空äžã60âã§ïŒæ
éã100âã§ïŒæéãããã«150âã§ïŒæé也ç¥ã
ç±åŠçããåãçŽ30ÎŒã®ãã€ã«ã ãåŸãã åŸãããããªãšã¹ãã«ãã€ã«ã ã®ç©æ§ã第ïŒè¡š
ã«ç€ºãã
ãè¡šã
å®æœäŸ 12
ãã¬ãã¿ã«é
žãžããšãã« 318éš
ãã³ãžã«ãã€ããããã³ 220éš
äžé
žåã¢ã³ãã¢ã³ 0.1éš
ãåžžå§äžã260âã§30åã270âã§30åãããã«
290âã§30åããšããŒã«ãçå»ãã€ã€åå¿ããã
ãã次ãã§æ¬¡ç¬¬ã«ææž©ãã€ã€ããã€20åéã«100
mmHgãã€æžå§åºŠãé«ãã€ã€ãããšããŒã«ãçå»
ããŠéçž®ååå¿ãè¡ãªããæåŸã«çŽïŒmmHgã®é«
ç空äž330âã§20åéçž®åãè¡ãªãããã åŸãããããªãšã¹ãã«ãçŽ10ã16ã¡ãã·ãŠã«ç²
ç ãã200âãã290âãŸã§ïŒæéãèŠããŠåŸã ã«
ææž©ãããã€290âã§ïŒæéå ç±ããŠçªçŽ æ°æµäž
ã§åºçžéåããããåºæç²åºŠ7.1ã®ããªããŒãåŸ
ãã ãã®ããªããŒãçšããŠå®æœäŸ11ãšåæ§ã«ããŠã
ãŒãã調æŽããããã«ãã€ã«ã ãåŸãã åŸãããããªãšã¹ãã«ãã€ã«ã ã®ç©æ§ã第ïŒè¡š
ã«ç€ºãã
290âã§30åããšããŒã«ãçå»ãã€ã€åå¿ããã
ãã次ãã§æ¬¡ç¬¬ã«ææž©ãã€ã€ããã€20åéã«100
mmHgãã€æžå§åºŠãé«ãã€ã€ãããšããŒã«ãçå»
ããŠéçž®ååå¿ãè¡ãªããæåŸã«çŽïŒmmHgã®é«
ç空äž330âã§20åéçž®åãè¡ãªãããã åŸãããããªãšã¹ãã«ãçŽ10ã16ã¡ãã·ãŠã«ç²
ç ãã200âãã290âãŸã§ïŒæéãèŠããŠåŸã ã«
ææž©ãããã€290âã§ïŒæéå ç±ããŠçªçŽ æ°æµäž
ã§åºçžéåããããåºæç²åºŠ7.1ã®ããªããŒãåŸ
ãã ãã®ããªããŒãçšããŠå®æœäŸ11ãšåæ§ã«ããŠã
ãŒãã調æŽããããã«ãã€ã«ã ãåŸãã åŸãããããªãšã¹ãã«ãã€ã«ã ã®ç©æ§ã第ïŒè¡š
ã«ç€ºãã
ãè¡šã
å®æœäŸ 13
ïŒâαâããšããã«ãã€ããããã³ 218éš
ãžããšãã«ïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é
ž
368éš äžé žåã¢ã³ãã¢ã³ 0.1éš ãåžžå§äž260âïŒ30åã次ãã§270âïŒ30åããã
ã«290âïŒ30åéããšããŒã«ãç³»å€ã«çå»ããã€
ã€åå¿ãããã次ãã§æž©åºŠã340âãŸã§åŸã ã«äž
ãã€ã€ãç³»å ãæžå§ãšãã30ååŸã«ã¯ïŒmmHgã®
æžå§ãšããããã«20ååå¿ãããã åŸãããããªãšã¹ãã«ã®æµãéå§æž©åºŠã¯335âã
åºæç²åºŠã¯1.6ã§ãã€ãã
368éš äžé žåã¢ã³ãã¢ã³ 0.1éš ãåžžå§äž260âïŒ30åã次ãã§270âïŒ30åããã
ã«290âïŒ30åéããšããŒã«ãç³»å€ã«çå»ããã€
ã€åå¿ãããã次ãã§æž©åºŠã340âãŸã§åŸã ã«äž
ãã€ã€ãç³»å ãæžå§ãšãã30ååŸã«ã¯ïŒmmHgã®
æžå§ãšããããã«20ååå¿ãããã åŸãããããªãšã¹ãã«ã®æµãéå§æž©åºŠã¯335âã
åºæç²åºŠã¯1.6ã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ããªãšã¹ãã«ã®æ§æåäœãå®è³ªçã«äžèš
ãšïŒ»ïŒœããŸãã¯äžèšïŒ»ïŒœãšïŒ»ïŒœãš
ãšãããªãè³éŠæããªãšã¹ãã«ã§ãã€ãŠã âCOâArâ²âCOâ âŠâŠïŒ»ïŒœ ããã§Arâ²ã¯ïŒ°âé åæ§ã®ãã³ãŒã³ãŸãã¯ãã
ã¿ã¬ã³ã§ããã ããã§ãã¯ãåŒãã§ç€ºããã ççŽ æ°ïŒã10ã®ã¢ã©ã«ãã«åºã§ãããã¯æ°ŽçŽ ãŸ
ãã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºã§ããã ããã§ãã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯
ããã²ã³ååã§ãããïœã¯ïŒãŸãã¯ïŒã§ããã ãã€å šé žæåäžã«ãããäžèšïŒ»ïŒœã®å²åãçŽ90
ã¢ã«ïŒ 以äžã§ããã ãã€å šãžãªãŒã«æåäžã«ãããäžèšïŒ»ïŒœã®å²å
ã§çŽ80ã¢ã«ïŒ 以äžã§ããã ãããŠãå šæ§æåäœäžã®äžèšïŒ»ïŒœãå«ãŸããå Ž
åã¯å šãªãã·ã«ã«ãã³é žæåäžã®çŽ70ã¢ã«ïŒ 以äž
ãäžèšïŒ»ïŒœã§ããããã€äžèšïŒ»ïŒœãšïŒ»ïŒœã¯
ããããå šæ§æåäœã®å°ãªããšãçŽïŒã¢ã«ïŒ 以äž
ã§ããã該ããªããŒã®åºæç²åºŠã0.8以äžã§ãã
ããšãç¹åŸŽãšãã ç¹ç¶ãŸãã¯ãã€ã«ã 圢ææ§ã®æº¶èç°æ¹æ§å šè³éŠæ
ããªãšã¹ãã«ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2689783A JPS5978232A (ja) | 1983-02-22 | 1983-02-22 | 溶èç°æ¹æ§å šè³éŠæããªãšã¹ãã« |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2689783A JPS5978232A (ja) | 1983-02-22 | 1983-02-22 | 溶èç°æ¹æ§å šè³éŠæããªãšã¹ãã« |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5978232A JPS5978232A (ja) | 1984-05-07 |
| JPH0362727B2 true JPH0362727B2 (ja) | 1991-09-26 |
Family
ID=12206028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2689783A Granted JPS5978232A (ja) | 1983-02-22 | 1983-02-22 | 溶èç°æ¹æ§å šè³éŠæããªãšã¹ãã« |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5978232A (ja) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07696B2 (ja) * | 1986-04-30 | 1995-01-11 | äžäºç³æ²¹ååŠå·¥æ¥æ ªåŒäŒç€Ÿ | è³éŠæããªãšã¹ãã« |
| US4746566A (en) * | 1987-05-06 | 1988-05-24 | E. I. Dupont De Nemours And Company | Optically anisotropic melt forming aromatic copolyesters based on t-butyl-4-hydroxybenzoic acid |
| JPH0759628B2 (ja) * | 1988-05-26 | 1995-06-28 | å·¥æ¥æè¡é¢é· | é«åŒŸæ§çå ±éåããªãšã¹ãã« |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4913294A (ja) * | 1972-05-17 | 1974-02-05 | ||
| JPS5865629A (ja) * | 1981-10-15 | 1983-04-19 | Asahi Chem Ind Co Ltd | æ°èŠãªããªãšã¹ãã«ç¹ç¶ãŸãã¯ãã€ã«ã ããã³ãããã®è£œæ³ |
-
1983
- 1983-02-22 JP JP2689783A patent/JPS5978232A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4913294A (ja) * | 1972-05-17 | 1974-02-05 | ||
| JPS5865629A (ja) * | 1981-10-15 | 1983-04-19 | Asahi Chem Ind Co Ltd | æ°èŠãªããªãšã¹ãã«ç¹ç¶ãŸãã¯ãã€ã«ã ããã³ãããã®è£œæ³ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5978232A (ja) | 1984-05-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4447593A (en) | Melt-anisotropic wholly aromatic polyester and fibers or films thereof | |
| US4107143A (en) | Aromatic polyester carbonate and method for producing the same | |
| US3778410A (en) | Process for preparing a final copolyester by reacting a starting polyester with an acyloxy aromatic carboxylic acid | |
| EP0045499B1 (en) | Novel wholly aromatic copolyester, process for production thereof, and film melt-shaped therefrom | |
| JP3001732B2 (ja) | å ±éåããªãšã¹ãã«ããã³ããããåŸãããç¹ç¶ | |
| JPS60135428A (ja) | è³éŠæããªãšã¹ãã«åã³ãã®è£œé æ³ | |
| JPH02214720A (ja) | æ°èŠãªç±äºå€æ§ããªãšã¹ãã«ããã®è£œé æ¹æ³åã³æ圢åããã€ã©ã¡ã³ããçç¹ç¶åã³ãã€ã«ã ã®è£œé ã®ããã®ãããã®äœ¿çš | |
| JPS5845224A (ja) | 溶èç°æ¹æ§è³éŠæããªãšã¹ãã«åã³ãã®è£œé æ¹æ³ | |
| JPH0362727B2 (ja) | ||
| JPS61246229A (ja) | è³éŠæããªãšã¹ãã«åã³ãã®è£œé æ³ | |
| EP0119731B1 (en) | Copolyester of polyethylene terephthalate, process for making it and its use in producing molded articles | |
| JPH0231095B2 (ja) | Yojuihoseihokozokuhoriesuteruoyobisonoseizohoho | |
| JPH07119100B2 (ja) | ããªãšã¹ãã«æåœ¢äœ | |
| JPS5931529B2 (ja) | ããªãšã¹ãã«æ圢å | |
| JP2818098B2 (ja) | ããªãšã¹ãã«ã®è£œé æ¹æ³ | |
| JPS6050821B2 (ja) | å ±éåããªãšã¹ãã« | |
| JPS6258378B2 (ja) | ||
| JPH0253451B2 (ja) | ||
| JP2702334B2 (ja) | è³éŠæããªãšã¹ãã«åã³ãã®è£œé æ³ | |
| JPH0231096B2 (ja) | Zenhokozokuhoriesuteruoyobisonoseizoho | |
| JP2865979B2 (ja) | è³éŠæããªãšã¹ãã«ã®è£œé æ¹æ³ | |
| JP3056601B2 (ja) | å ±éåããªãšã¹ãã«ããã³ãã®ç¹ç¶ | |
| JPH0291119A (ja) | è³éŠæããªãšã¹ãã«ããã³ãã®è£œé æ³ | |
| JPS6361334B2 (ja) | ||
| JPH0257091B2 (ja) |