JPH0329267B2 - - Google Patents

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Publication number
JPH0329267B2
JPH0329267B2 JP61256923A JP25692386A JPH0329267B2 JP H0329267 B2 JPH0329267 B2 JP H0329267B2 JP 61256923 A JP61256923 A JP 61256923A JP 25692386 A JP25692386 A JP 25692386A JP H0329267 B2 JPH0329267 B2 JP H0329267B2
Authority
JP
Japan
Prior art keywords
soil
fermentation
waste
medium
soil improvement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP61256923A
Other languages
Japanese (ja)
Other versions
JPS63112483A (en
Inventor
Hisanori Shirakawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YAMAGAMI HONSHA KK
Original Assignee
YAMAGAMI HONSHA KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YAMAGAMI HONSHA KK filed Critical YAMAGAMI HONSHA KK
Priority to JP61256923A priority Critical patent/JPS63112483A/en
Publication of JPS63112483A publication Critical patent/JPS63112483A/en
Publication of JPH0329267B2 publication Critical patent/JPH0329267B2/ja
Granted legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

Landscapes

  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Fertilizers (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

(産業上の利用分野) 本発明は魚廃、畜廃等有機廃棄物を利用して土
壌の活性化を高め、土の多面的働きを促す土壌改
良材の製法に関する。 (従来の技術) 最近の農業は、一作だけの高い収穫を上げるた
め、化学肥料や濃薬を多投することによつて支え
られている。しかし一方では土壌の悪化をもたら
した。このため近年、有機質肥料や堆肥材の見
直しや、土壌改良材の開発が行われてきてい
る。すなわち、 現在の有機質肥料や堆肥化材は、 (イ) 好気性または嫌気性発酵により完熟させる
方法 (ロ) 火力乾燥による方法 (ハ) 発酵の後、火力乾燥させる方法で作られ
る。 土壌改良材のうち、 (イ) 菌体肥料は堆肥化添加材としての効果が認
められている。 (ロ) 鉱物資材のゼオライト(同機能を有するも
のを含む)は、保肥能力が認められている。 (発明が解決しようとする問題点) 安定して高い収穫を与える土こそが本当に肥沃
な土である。肥沃な土の構造は有機物を仲立ちに
して微生物や小動物の働きでできあがる。土の中
の微生物の働きを大事にして土のもつ多面的な働
きをさせる必要があるにも拘らず、従来、 の(イ)は好気性、嫌気性を問わず発酵完熟され
たものは発酵中に肥料成分を放出し、更に微生物
増殖に必要な可分解有機物が少なく、土壌の活性
化は行われにくい。また施用しにくいものが多
い。 の(ロ)の火力乾燥したものは可分解有機物は多
く保有するが、微生物の大部分が死滅しているた
め土壌の活性化が遅く、土壌に施用した場合、有
害菌の増殖を促す危険が多い。 の(ハ)では、発酵の後、火力乾燥したものは、
肥料成分を放出し、可分解有機物が少なくかつ微
生物まで死滅しているため、土壌の活性化は更に
行われにくい。 の(イ)では、土壌改良材の中の菌体肥料中に含
まれる微生物は、施用された土壌に施されている
有機物との適合性や、その多少により土壌の活性
化は不安定である。 の(ロ)では、土壌改良材の中の鉱物質系のゼオ
ライトは保肥能力はもつものの、肥料成分は微量
要素を含むにすぎない。 上記のように各従来例はそれぞれの欠点をもつ
ため、単独での効果は少なく、化学肥料と併用し
ても、十分の効果をあげることができないものが
現状である。 本発明の目的は、土壌の活性化を図り、土のも
つ多面的な働きを促すことにある。 (問題点を解決するための手段) 本発明の土壌改良材の製法は、第1図に示すよ
うにゼオライト、ゼオライトと同性質を備えたベ
ントナイト、バーミキユライト、パーライト、活
性炭等鉱物(以下「鉱物質資材」という。)の粉
末に、適量の有機廃棄物を混合して含水率を調整
し、その後この混合物に有機廃棄物中より有機質
を分解する分解有用菌を抽出し、培養して作つた
麹を加えて攪拌し、これを中熟発酵で乾燥するこ
とを特徴とする。 有機廃棄物としては、魚廃棄物、畜廃棄物、家
禽廃棄物等を用いる。上記麹は、放置されている
有機廃棄物に米糖、澱粉を添加し、その後鉱物質
資材を加えて混合しながら含水率を調整し、混合
物を中熟発酵させて作つたものである。 上記中熟発酵とは、初期発酵から完熟発酵に至
る過程の中間で発酵を止めることである。止める
方法には急冷と乾燥の方法があり、この乾燥に
は、天日乾燥、低温通気乾燥、乾燥空気送風乾
燥、火力乾燥等があるが、有用菌を死滅させない
ことが前提である。そして自然乾燥による中熟発
酵法として、混合物を例えばペレツト状、粒状、
粉状等にして乾燥するものがあるが、特に混合物
をペレツト状に成形し、これを堆積すれば、通気
性が良くなつて、発酵が促される。 (発明の効果) (1) (イ) 鉱物質資材の粉末に有機廃棄物を混入攪
拌することににより有機廃棄物の悪臭は殆ど
なくなり、発酵に必要な含水率の調整が容易
である。 (ロ) 有機物に適合する有用菌が優先種として添
加発酵させるので、発酵期間が短くてすみ、
そのため製造日数が少なくてすみ生産性が良
く、そして発酵中の悪臭は少ない。 (ハ) 中熟発酵で乾燥状態に入るため、可分解有
機物が残存し、土壌の活性化が促がされる。 (ニ) 土壌中に可分解有機物が入つても、当該有
機物に適合する有用菌が優先種として添加増
殖されているので、土壌の活性化が早く有害
菌をふやすなどの攪乱は起りにくい。 (ホ) 土壌に施用された各種チツソは鉱物質資材
により吸着保持されたまま、作物に吸収され
やすい形に変化し、必要時まで保持するた
め、施肥が簡単になる。 (2) 生体系を乱すことなく、その地域の気候、当
該有機廃棄物処理に最も適合する強力な優先種
として、容易に得ることができる。 (3) 中熟発酵のため、可分解有機物が残存し、さ
らに当該有機物に最も適合する有用菌が増殖し
た段階で乾燥状態に入るため発酵を止めること
ができる。 (実施例) ゼオライトとして下記のもの、また有機廃棄物
として別表−1に示すものを使用した。 (ゼオライト) 塩基置換容量 ……145.58me/100g P.H. ……7.52 含 水 率 ……16.0%(実測) 以下本製法を各工程にしたがつて説明する。 (1) 最初に当該有機廃棄物に適合する有用菌の抽
出培養を行う。 放置されている有機廃棄物に米糖(有機物重量
の5%)を添加し、その後ゼオライトを加え良く
混合しながら含水率を約55%に調整した。 これをペレツト状(直径5m/m位)に成形
し、堆積(高さ15cm)し、空気の流通を良くして
発酵させた。2日後発酵温度は約40℃〜55℃位に
達し、4日後中熟発酵で乾燥状態に入り、そのま
ま自然乾燥(含水率15〜20%)して麹ができあが
つた。 (2) この「麹」を用いて土壌改良材を作つた。 (イ) ゼオライトと有機廃棄物を重量比2:1に
配合し、これに、当該有機廃棄物中より抽出
培養した「麹」を全重量の2%を添加攪拌す
る。 この時の混合後における含水率は下記のとおり
であつた。
(Field of Industrial Application) The present invention relates to a method for producing a soil improvement material that utilizes organic waste such as fish waste and livestock waste to enhance the activation of soil and promote multifaceted functions of the soil. (Conventional technology) Modern agriculture is supported by the use of large amounts of chemical fertilizers and concentrated chemicals in order to increase the yield of just one crop. However, it also led to soil deterioration. For this reason, in recent years, organic fertilizers and compost materials have been reviewed, and soil improvement materials have been developed. In other words, current organic fertilizers and composting materials are produced by (a) ripening by aerobic or anaerobic fermentation, (b) drying by fire, and (c) drying by fire after fermentation. Among soil improvement materials, (a) bacterial fertilizer is recognized to be effective as a composting additive. (b) The mineral material zeolite (including those with the same function) is recognized for its ability to preserve fertilizers. (Problem that the invention seeks to solve) Only soil that gives a stable and high yield is truly fertile soil. A fertile soil structure is created by the action of microorganisms and small animals, with organic matter as a mediator. Although it is necessary to take care of the functions of microorganisms in the soil and allow the soil to perform its multifaceted functions, conventionally, (a) fermentation is carried out regardless of whether it is aerobic or anaerobic. Fertilizer components are released into the soil, and there is little decomposable organic matter necessary for microbial growth, making it difficult to activate the soil. Also, many of them are difficult to apply. The fire-dried material in (b) retains a large amount of decomposable organic matter, but since most of the microorganisms have been killed, soil activation is slow, and when applied to soil, there is a risk of promoting the growth of harmful bacteria. many. In (c), what is dried under fire after fermentation is
It is even more difficult to activate the soil because fertilizer components are released, there is little decomposable organic matter, and even microorganisms are dead. In (b), the activation of the soil is unstable depending on the compatibility of the microorganisms contained in the fungal fertilizer in the soil improvement material with the organic matter applied to the applied soil, and the degree of compatibility with the organic matter applied to the soil. . In (b), although the mineral zeolite in the soil conditioner has the ability to retain fertilizer, the fertilizer component only contains trace elements. As mentioned above, each conventional example has its own drawbacks, so it is not very effective when used alone, and even when used in combination with chemical fertilizers, it is currently not possible to achieve sufficient effects. The purpose of the present invention is to activate soil and promote the multifaceted functions of soil. (Means for Solving the Problems) As shown in FIG. The moisture content is adjusted by mixing an appropriate amount of organic waste with the powder of mineral materials (hereinafter referred to as "mineral materials"), and then into this mixture useful decomposing bacteria that decompose organic matter are extracted from the organic waste and cultivated. It is characterized by adding ivy koji, stirring, and drying it by medium fermentation. As the organic waste, fish waste, livestock waste, poultry waste, etc. are used. The above-mentioned koji is made by adding rice sugar and starch to left-over organic waste, then adding mineral materials to adjust the moisture content while mixing, and then subjecting the mixture to medium fermentation. The above-mentioned medium-ripe fermentation refers to stopping fermentation in the middle of the process from initial fermentation to full-ripe fermentation. There are quenching and drying methods to stop the process, and these drying methods include sun drying, low-temperature ventilation drying, dry air blast drying, and fire drying, but the premise is that useful bacteria will not be killed. Then, as a medium fermentation method using natural drying, the mixture can be made into pellets, granules, etc.
Some products can be dried in the form of powder, but if the mixture is formed into pellets and piled up, this improves air permeability and promotes fermentation. (Effects of the invention) (1) (a) By mixing organic waste into mineral material powder and stirring, the bad odor of the organic waste is almost eliminated, and the moisture content required for fermentation can be easily adjusted. (b) Since useful bacteria that are compatible with organic matter are added and fermented as priority species, the fermentation period is short;
Therefore, the production time is short, productivity is high, and there is little odor during fermentation. (c) Because the medium-ripening fermentation enters a dry state, decomposable organic matter remains and soil activation is promoted. (d) Even if decomposable organic matter enters the soil, useful bacteria that are compatible with the organic matter are added and propagated as priority species, so the soil becomes activated quickly and disturbances such as the proliferation of harmful bacteria are unlikely to occur. (e) Fertilizers of various types applied to the soil are adsorbed and retained by mineral materials and change into a form that is easily absorbed by crops, where they are retained until needed, making fertilization easier. (2) It can be easily obtained as a strong priority species that is most compatible with the local climate and the organic waste treatment in question, without disturbing the biological system. (3) Due to medium-ripening fermentation, decomposable organic matter remains, and when useful bacteria that are most compatible with the organic matter have proliferated, the fermentation can be stopped because it enters a dry state. (Example) The following zeolite and the organic waste shown in Attached Table 1 were used. (Zeolite) Base substitution capacity...145.58me/100g PH...7.52 Water content...16.0% (actually measured) This production method will be explained below according to each step. (1) First, extract and culture useful bacteria that are compatible with the organic waste. Rice sugar (5% of the weight of organic matter) was added to the organic waste that had been left unattended, and then zeolite was added and mixed well to adjust the moisture content to approximately 55%. This was formed into pellets (about 5 m/m in diameter), piled up (15 cm in height), and fermented with good air circulation. After 2 days, the fermentation temperature reached about 40°C to 55°C, and after 4 days, it entered a dry state with medium-mature fermentation, and was left to dry naturally (moisture content 15-20%) to complete koji. (2) This ``koji'' was used to make a soil improvement material. (a) Zeolite and organic waste are mixed at a weight ratio of 2:1, and 2% of the total weight of "koji" extracted and cultured from the organic waste is added and stirred. The moisture content after mixing at this time was as follows.

【表】 (ロ) 上記混合物を中熟発酵法により発酵させ
る。すなわち空気の流通を良くするため、ペ
レツト状(直径5m/m位)に成形し、これ
を平板上に高さ15cmで堆積(網の上で行う場
合は30cm)発酵させた。2日後発酵温度は約
40〜55℃位に達し、4日後中熟発酵で乾燥状
態に入り、そのまま自然乾燥させて土壌改良
材を得た。 (ハ) 乾燥後、土壌改良材の使用方法に合せて、
ペレツト状、粒状、粉末状と篩い分ける。な
お、粉末状の土壌改良材には上記麹が含まれ
ているので、新たに麹を培養製造することな
く、この粉末状の土壌改良材を麹の代用とし
て使用できる(第1図鎖線図示)。 でき上つた土壌改良材の成分分析結果は、別表
−2のとおりであつた。 この分析結果から肥料成分は非常に少ない値で
ある。 次に、でき上つた土壌改良材の施用試験を行
なつた。 (1) 試験圃場として、川砂土(砂利混り)の土地
を選定し、1区画2平方メートルとして、10区
画別表−3のとおり設定した。 なお、土壌改良材については全面散布後、鋤
き込みを行ない、化成肥料は市販品のビート用
S182を標準反当り施用量160Kg/10aの約80%に
当る130Kg/10aで作条施肥により行なつた。 (2) 成育状況について 第2はビート移植後38日目の葉長測定を実施
した時のそれぞれの区画の平均葉長をグラフに
表わしたものであり、同様に第3図は65日目の
各区画の平均葉長を表す。 なお、試験作物として、前記ビートの他にホ
ーレン草、大豆、大根で行なつた結果、前記ビ
ートとほぼ同様の成長が記録された。 本願で得た各土壌改良材は有効と思われる肥
料成分を有しないにも拘らず、上述のような好
成績を発揮したのは、 (イ) 中熟発酵でかつ有益菌が優先種となつてい
る堆肥化材と、吸水性とイオン交換特性、特
にアンモニアイオンに対する選択交換特性を
持つゼオライトを一体化し施用することによ
り、 (a) 土壌に可分解有機物と当該有機物に適合
する有用菌を優先種として供給する。 (b) 土壌中で有用菌が増殖することにより、
土壌が活性化し、土の構造が変わり、土の
多面的働きを促す。 (c) 施用された各種チツソはゼオライトによ
り吸着保持されたまま、作物に吸収される
形に変化し、必要時まで流亡させない。 (d) 化成肥料との併用により、相乗効果が出
た。 などの作用によるものと判断できる。 (ロ) 放置された有機廃棄物を種に好気性発酵せ
ることにより、当該有機廃棄物中の有用菌
で、自然淘汰された最も強力な菌が増殖し、
優先種となるからである。 (ハ) 有機混合物をペレツト状にして堆積するこ
とにより、空気の流通が良くなり、発酵が促
進され、かつ乾燥も同時に進行するために中
熟発酵が容易にできるからである。
[Table] (b) Ferment the above mixture using the medium fermentation method. That is, in order to improve air circulation, the pellets were formed into pellets (about 5 m/m in diameter), which were piled up on a flat plate at a height of 15 cm (30 cm if carried out on a screen) for fermentation. After 2 days, the fermentation temperature is approx.
The temperature reached about 40 to 55°C, and after 4 days it entered a dry state due to medium fermentation, and was left to dry naturally to obtain a soil improvement material. (c) After drying, according to the method of using the soil improvement material,
Sieve into pellets, granules, and powders. In addition, since the powdered soil improvement material contains the above-mentioned koji, this powdered soil improvement material can be used as a substitute for koji without culturing and manufacturing new koji (as shown by the chain line in Figure 1). . The results of component analysis of the finished soil improvement material were as shown in Attached Table-2. The results of this analysis indicate that the fertilizer components have very low values. Next, we conducted an application test of the finished soil improvement material. (1) A plot of river sand soil (mixed with gravel) was selected as a test field, and 10 plots were set up as shown in Attached Table 3, with each plot measuring 2 square meters. For soil improvement materials, plow them in after spreading them over the entire surface, and use commercially available beet fertilizers for chemical fertilizers.
S182 was applied by row fertilization at 130 kg/10 a , which is about 80% of the standard application rate of 160 kg/10 a . (2) Regarding the growth status The second graph shows the average leaf length of each plot when leaf length was measured on the 38th day after beet transplanting, and similarly, the third graph shows the average leaf length on the 65th day after beet transplantation. It represents the average leaf length of each plot. In addition to the beet, spinach, soybean, and radish were tested as test crops, and almost the same growth as the beet was recorded. Even though each of the soil improvement materials obtained in this application does not contain fertilizer ingredients that are considered to be effective, the reason why they achieved the above-mentioned good results is because (a) medium-ripening fermentation was performed and beneficial bacteria were the priority species; By integrating and applying zeolite, which has water absorption and ion exchange properties, especially selective exchange properties for ammonia ions, with a composting material containing organic matter, (a) priority species of decomposable organic matter and useful bacteria compatible with the organic matter are added to the soil; Supply as. (b) By the proliferation of useful bacteria in the soil,
The soil is activated, its structure changes, and the multifaceted functions of the soil are promoted. (c) The various types of applied zeolite remain adsorbed and retained by zeolite and change into a form that can be absorbed by crops, preventing them from being washed away until needed. (d) A synergistic effect was obtained when used in combination with chemical fertilizers. It can be concluded that this is due to the effects of (b) By aerobically fermenting abandoned organic waste into seeds, the most powerful naturally selected useful bacteria in the organic waste will proliferate.
This is because it is a priority species. (c) By depositing the organic mixture in the form of pellets, air circulation is improved, fermentation is promoted, and drying proceeds at the same time, making it easier to carry out medium-aged fermentation.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本製法のブロツクダイヤグラム、第2
図は38日目のビート葉長の成長状況を示すグラ
フ、第3図は6日目のビート葉長の成長状況を示
すグラフである。
Figure 1 is a block diagram of this manufacturing method, Figure 2
The figure is a graph showing the growth status of beet leaf length on the 38th day, and FIG. 3 is a graph showing the growth status of beet leaf length on the 6th day.

【表】【table】

【表】【table】

【表】【table】

Claims (1)

【特許請求の範囲】 1 鉱物質資材の粉末に適量の魚廃、畜廃、家禽
廃等の有機廃棄物を混入し、含水率を調整し、調
整後麹を加えて攪拌混合し、混合物を中熟発酵で
乾燥し、上記麹は有機廃棄物中より有用菌を抽出
して、培養して製造したものであり、上記乾燥は
有用菌を死滅させない温度で行うものであること
を特徴とする土壌改良材の製法。 2 特許請求の範囲第1項において、鉱物質資材
の粉末は、ゼオライトの粉末であることを特徴と
する土壌改良材の製法。 3 特許請求の範囲第1項において、麹は、有機
廃棄物に米糠を添加し、添加後鉱物質資材を加え
て混合しながら含水率を調整し、混合物を中熟発
酵することにより、有機廃棄物に適合する有用菌
を抽出して、培養して製造したものであることを
特徴とする土壌改良材の製法。 4 特許請求の範囲第1項又は第3項において、
中熟発酵は、混合物をペレツト状に成形し、これ
を所定の高さに堆積して発酵させ、中熟発酵状態
で自然乾燥させたものであることを特徴とする土
壌改良材の製法。
[Claims] 1. Mix an appropriate amount of organic waste such as fish waste, livestock waste, poultry waste, etc. with the powder of mineral materials, adjust the moisture content, and after adjusting, add koji and stir and mix. The koji is dried by medium fermentation and is produced by extracting and culturing useful bacteria from organic waste, and the drying is carried out at a temperature that does not kill the useful bacteria. Method for manufacturing soil improvement materials. 2. The method for producing a soil improvement material according to claim 1, wherein the mineral material powder is zeolite powder. 3 In claim 1, koji is produced by adding rice bran to organic waste, adding mineral materials after the addition to adjust the moisture content while mixing, and subjecting the mixture to medium fermentation. A method for producing a soil improvement material, characterized in that it is produced by extracting and culturing useful bacteria that are compatible with the soil. 4 In claim 1 or 3,
Medium-fermentation is a method for producing a soil improvement material that is characterized by forming a mixture into pellets, piling them up at a predetermined height, fermenting them, and naturally drying them in a medium-fermented state.
JP61256923A 1986-10-30 1986-10-30 Manufacture of soil improver Granted JPS63112483A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61256923A JPS63112483A (en) 1986-10-30 1986-10-30 Manufacture of soil improver

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61256923A JPS63112483A (en) 1986-10-30 1986-10-30 Manufacture of soil improver

Publications (2)

Publication Number Publication Date
JPS63112483A JPS63112483A (en) 1988-05-17
JPH0329267B2 true JPH0329267B2 (en) 1991-04-23

Family

ID=17299254

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61256923A Granted JPS63112483A (en) 1986-10-30 1986-10-30 Manufacture of soil improver

Country Status (1)

Country Link
JP (1) JPS63112483A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0761882A (en) * 1993-06-16 1995-03-07 Nippon Gijutsu Kaihatsu Center:Kk Method for composing organic substance

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5191171A (en) * 1975-02-01 1976-08-10 Sangyohaikibutsuto kogaiodeibutsuto nosanhaikibutsuya hatsukobutsuo shugenryotoshita hatsukodatsushuseitaihidojokairyobutsu
JPS60118291A (en) * 1983-11-29 1985-06-25 Jiemu Kogyo Kk Preparation of granular solidified substance of excessive sludge

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5191171A (en) * 1975-02-01 1976-08-10 Sangyohaikibutsuto kogaiodeibutsuto nosanhaikibutsuya hatsukobutsuo shugenryotoshita hatsukodatsushuseitaihidojokairyobutsu
JPS60118291A (en) * 1983-11-29 1985-06-25 Jiemu Kogyo Kk Preparation of granular solidified substance of excessive sludge

Also Published As

Publication number Publication date
JPS63112483A (en) 1988-05-17

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