JPH03127455A - Flat type cell - Google Patents

Flat type cell

Info

Publication number
JPH03127455A
JPH03127455A JP1262387A JP26238789A JPH03127455A JP H03127455 A JPH03127455 A JP H03127455A JP 1262387 A JP1262387 A JP 1262387A JP 26238789 A JP26238789 A JP 26238789A JP H03127455 A JPH03127455 A JP H03127455A
Authority
JP
Japan
Prior art keywords
positive electrode
battery
thickness
metal net
discharge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1262387A
Other languages
Japanese (ja)
Inventor
Mitsugi Okahisa
岡久 貢
Koichi Makino
幸一 牧野
Isao Miyashita
勲 宮下
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP1262387A priority Critical patent/JPH03127455A/en
Publication of JPH03127455A publication Critical patent/JPH03127455A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Cell Electrode Carriers And Collectors (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

PURPOSE:To prevent a flat type cell from being expanded in thickness after discharge by making up a positive electrode core member out of a metal wire gauze 0.05 to 0.07mm in diameter. CONSTITUTION:In a positive electrode for a flat type cell in which a positive electrode active material 3 is carried by a positive electrode core member 2, the positive electrode core member 2 is made up out of a metal wire gauze 0.05 to 0.07mm in diameter. In general, the metal wire gauze 0.1mm in diameter which is usually available, is rolled so as to be formed into the metal wire gauze 0.05 to 0.07mm in thickness so that it is thereby used as the core member. Even if the positive electrode is expanded owing to the discharge of the cell, the positive electrode active material 3 is accelerated to be deformed in the radial direction, whereas the expansion in the thickness direction is restrained. Thus, the cell is prevented from being incapable of coming out of its mounting position because of expansion of its flat shape after use.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、薄形機器、例えばICカード、電卓等の電源
となる扁平形電池の改良に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to improvements in flat batteries that serve as power sources for thin devices such as IC cards and calculators.

従来の技術 この種の電池は、第1図に示すように9機溶媒電解液を
含浸させたポリプロピレン不織布からなるセパレータ1
を介在させて、金属ネットからなる正極芯材2に、金属
ハロゲン化物、金属酸化物の正極活物質3を充填した正
極体と、リチウムからなる負極活物質4の発電要素にポ
リエチレン。
BACKGROUND OF THE INVENTION As shown in FIG. 1, this type of battery has a separator 1 made of a polypropylene nonwoven fabric impregnated with a 9-solvent electrolyte.
A positive electrode core material 2 made of a metal net is filled with a positive electrode active material 3 made of a metal halide or a metal oxide, and a power generating element of a negative electrode active material 4 made of lithium is made of polyethylene.

ポリプロピレン等からなるシール材5を配備し、ステン
レス綱板、あるいはステンレス綱板にニッケルメッキを
施した正極端子板6と負極端子板7の周縁部を前記シー
ル材5を重ね合わせて熱溶着することにより発電要素を
密封口する構成である。また、上記金属ネット2は、一
般的に使われているステンレス綱、例えば5US304
,5US430の材質で線径0.1mn、  50me
shのものが使用されている。この種の電池は、ICカ
ードのメモリー保持電源のように超薄形機器に使用され
るため、電池に対してもできる限り薄いものが要望され
ている。ICカード用電源としては電池厚み0.5mi
以下が要望されている。
A sealing material 5 made of polypropylene or the like is provided, and the peripheral edges of a positive terminal plate 6 and a negative terminal plate 7 made of a stainless steel plate or a stainless steel plate plated with nickel are superimposed and thermally welded with the sealing material 5. This is a configuration in which the power generation element is sealed. The metal net 2 may be made of commonly used stainless steel, for example, 5US304.
, 5US430 material, wire diameter 0.1mm, 50me
sh is used. Since this type of battery is used in ultra-thin devices such as memory storage power supplies for IC cards, it is desired that the battery be as thin as possible. As a power source for IC cards, the battery thickness is 0.5mm.
The following is requested.

発明が解決しようとする課題 ところが、この扁平形電池は、例えば電池厚み0.5園
の電池を作り使用機器に挿入して使用すると電池部が膨
らみ、使用後には電池の厚みが約0.6m1gになる。
Problems to be Solved by the Invention However, with this flat type battery, for example, when a battery with a battery thickness of 0.5 mm is made and used by inserting it into a device, the battery part swells, and after use, the thickness of the battery becomes approximately 0.6 m/g. become.

これはICカードのメモリー保持電源として扁平形電池
を組み込んで機器の母体にICカードを挿入した場合、
使用の初期段階は良いが、使用するにつれてICカード
が膨らんで機器の母体に挿入できなくなる。
This means that when an IC card is inserted into the motherboard of a device that incorporates a flat battery as a memory storage power source for the IC card,
The IC card is fine at the initial stage of use, but as it is used, the IC card swells up and cannot be inserted into the main body of the device.

以上のように従来の扁平形電池では、電池が消耗するに
つれて電池の厚みが増加して、扁平形電池を組み込んで
いるカード状機器がメモリー読み出し等をする機器本体
に差し込み不能になる問題がある。
As mentioned above, with conventional flat batteries, as the battery wears out, the thickness of the battery increases, making it impossible to insert the card-shaped device into which the flat battery is installed into the device used to read the memory. .

本発明は、このような問題点を解消するものである。The present invention solves these problems.

課題を解決するための手段 本発明は、上記問題点を解消するために正極内の金属ネ
ットからなる正極芯材2の線径を0.05閣〜0.07
閣にしたものである。また、一般的に入手し易い0.1
mm程度の線径の金属ネットを圧延して、合剤の厚み方
向に沿ったネットの厚みを0.05n+m=0.07m
mにして正極合剤を作り電池として構成するものである
Means for Solving the Problems In the present invention, in order to solve the above problems, the wire diameter of the positive electrode core material 2 made of a metal net in the positive electrode is set to 0.05 to 0.07 mm.
It was made into a temple. In addition, 0.1 which is generally easy to obtain
Roll a metal net with a wire diameter of about mm, and the thickness of the net along the thickness direction of the mixture is 0.05n+m=0.07m.
m to prepare a positive electrode mixture and configure it as a battery.

作用 このように本発明は、金属ネットからなる正極芯材2の
線径を0.05mm−0,07mmにすることにより、
電池を組み立てた直後から放電終了後までに電池の膨ら
みがなく、使用直前から使用後まで安定した電池を供給
できる。
Effect As described above, the present invention provides the following effects by setting the wire diameter of the positive electrode core material 2 made of metal net to 0.05 mm to 0.07 mm.
The battery does not swell from immediately after the battery is assembled to after the end of discharge, and a stable battery can be supplied from just before use to after use.

これは、正極合剤3に金属酸化物を用いて、負極活物質
4にリチウムを用いた場合、電池の放電と共に金属酸化
物が膨らんでいく。一方。負極活物質であるリチウム4
は、電池の放電と共にリチウムイオンとしてセパレータ
1を介して正極合剤3の方に移動して、放電終了時には
リチウム4がほとんどなくなる。この時、従来の構成で
は正極合剤3の膨らみが、負極活物質であるリチウム4
の減少より大きいために電池として放電終了時に電池が
膨らむ。
This is because when a metal oxide is used for the positive electrode mixture 3 and lithium is used for the negative electrode active material 4, the metal oxide expands as the battery discharges. on the other hand. Lithium 4, a negative electrode active material
As the battery is discharged, the lithium 4 moves as lithium ions through the separator 1 to the positive electrode mixture 3, and almost no lithium 4 is left at the end of the discharge. At this time, in the conventional configuration, the swelling of the positive electrode mixture 3 is caused by the lithium 4, which is the negative electrode active material.
The battery swells as the battery swells at the end of discharge as the decrease in battery is greater.

これらの現象に対して、従来構成の正極合剤3の膨らみ
状態を調べると、正極合剤3の厚み方向に対して膨らみ
が非常に大きい。一方、正極合剤3の径方向に対しては
ほとんど膨れていないここが解った。この現象について
解析してみると、金属ネットからなる正極芯材2が正極
合剤中に配備されていることにより金属ネット2の各線
が正極合剤3を囲んでいるために正極合剤の径方向に正
極活物質3が膨らむのを阻止する。また、正極合剤3が
径方向に膨らむことができないため、正極合剤3の厚み
方向に膨らんでいく。従って、電池の厚み方向に対して
、正極合剤の膨らみが大きくなる。
In response to these phenomena, when examining the state of swelling of the positive electrode mixture 3 of the conventional configuration, the swelling is extremely large in the thickness direction of the positive electrode mixture 3. On the other hand, it was found that the positive electrode mixture 3 hardly swelled in the radial direction. Analyzing this phenomenon, we found that since the positive electrode core material 2 made of metal net is placed in the positive electrode mixture, each wire of the metal net 2 surrounds the positive electrode mixture 3, so the diameter of the positive electrode mixture This prevents the positive electrode active material 3 from expanding in the direction. Further, since the positive electrode mixture 3 cannot expand in the radial direction, the positive electrode mixture 3 expands in the thickness direction. Therefore, the swelling of the positive electrode mixture increases in the thickness direction of the battery.

そこで本発明は、上記解析結果から正極合剤の径方向に
正極活物質3が膨脹できるように金属ネット2の線径を
細くして、正極活物質を囲む体積を小さくして正極合剤
3の径方向に対する膨脹を促進させ、逆に正極合剤3の
厚み方向への膨脹を抑制したものである。
Therefore, based on the above analysis results, the present invention reduces the wire diameter of the metal net 2 so that the positive electrode active material 3 can expand in the radial direction of the positive electrode mixture, and reduces the volume surrounding the positive electrode active material. The expansion of the positive electrode mixture 3 in the radial direction is promoted, and the expansion of the positive electrode mixture 3 in the thickness direction is suppressed.

また、金属ネット2の線径は、0.1nn以上のものが
ネットとして編み易く、一般的によく使われている。し
かし、線径が0.1m以下のものは製造がしにくく一般
的にあまり使われていない。また、線径を細くした場合
、金属ネット2の強度が弱くなり正極合剤3を充填した
状態で正極体から正極合剤3と共にはずれてしまう問題
がある。そこで、従来使用していた線径0.1+nmの
金属ネット2をローラーにより圧延して正極合剤3の厚
み方向のネットの厚みを0.05mn〜0.07m11
にして上記金属ネット2の線径を細くするものと同様に
放電後の電池膨脂を抑制することができた。この方法を
採れば、金属ネット2の強度は非常に強く正極合剤3と
共にはずれることはなくなった。
Further, the wire diameter of the metal net 2 is 0.1 nn or more, which is easy to knit as a net, and is commonly used. However, wires with a diameter of 0.1 m or less are difficult to manufacture and are not generally used. Further, when the wire diameter is made thinner, the strength of the metal net 2 becomes weaker, and there is a problem that the metal net 2, filled with the positive electrode mixture 3, is separated from the positive electrode body together with the positive electrode mixture 3. Therefore, the metal net 2 with a wire diameter of 0.1+nm, which had been used conventionally, was rolled with a roller to reduce the thickness of the net in the thickness direction of the positive electrode mixture 3 to 0.05 mm to 0.07 m11.
Similarly to the case where the wire diameter of the metal net 2 is made thinner, swelling of the battery after discharge can be suppressed. By adopting this method, the strength of the metal net 2 was so strong that it did not come off together with the positive electrode mixture 3.

以下本発明について実施例により詳述する。The present invention will be explained in detail below with reference to Examples.

実施例 第工図に本発明の実施例の断面図を示す。有機溶媒とし
てプロピレンカーボネートに1モル、/7!の過塩素酸
リチウムを含有した電解液を含浸させたプロピレン不織
布からなるセパレータ1の上面に二酸化マンガンとカー
ボンと結着剤を混練して0.05閣の線径の5US30
4の金慎ネット2に充填して圧延、乾燥した正極体を配
備し下面にはリチウムらなる負極活物質4を配備し、中
央部を外側へ膨出させたステンレス鋼板の正極端子板6
と平板のステンレス鋼板の負極端子板7で包含し、正極
端子板6と負極端子板7の周縁部をポリプロピレンから
なるシール材5と重ね合わせて周縁部を熱溶着により封
止して電池を組み立てた。
Embodiment The first drawing shows a sectional view of an embodiment of the present invention. 1 mole in propylene carbonate as an organic solvent, /7! Manganese dioxide, carbon, and a binder are kneaded on the upper surface of a separator 1 made of a propylene nonwoven fabric impregnated with an electrolytic solution containing lithium perchlorate to form a 5US30 wire with a wire diameter of 0.05 mm.
A negative electrode active material 4 made of lithium is provided on the lower surface, and a positive electrode terminal plate 6 made of a stainless steel plate has a central portion bulged outward.
and a negative terminal plate 7 made of a flat stainless steel plate, the peripheral edges of the positive terminal plate 6 and negative terminal plate 7 are overlapped with a sealing material 5 made of polypropylene, and the peripheral edges are sealed by heat welding to assemble the battery. Ta.

以下同様にして金属ネット線径をそれぞれ0.06mm
、0.07m1,0.08mm、0.09mmとして電
池を組み立てた。次に従来例として金属ネット2の線径
0.1mmのものを同様にして組み立てた。
Similarly, the diameter of each metal net wire is 0.06 mm.
, 0.07 m1, 0.08 mm, and 0.09 mm, and the batteries were assembled. Next, as a conventional example, a metal net 2 having a wire diameter of 0.1 mm was assembled in the same manner.

この各金属ネット2は5Qmeshのものを使用した。Each of the metal nets 2 was made of 5Qmesh.

また、これらの電池は、いずれも電池サイズ22mnX
29mra、厚み0.5mmとし、正極体の寸法は、1
7.5mnX 24.5m3 厚み0.23n+raと
した。
In addition, all of these batteries have a battery size of 22 mm
29 mra, thickness 0.5 mm, and the dimensions of the positive electrode body are 1
7.5mn×24.5m3 Thickness: 0.23n+ra.

電池容量は45mAhである。The battery capacity is 45mAh.

上記各電池について、室温中で68にΩ定抵抗で放電し
、電池電圧が2.5Vになった時点で放電を終了し、各
電池の厚みを測定した。その結果を第2図に示す。
Each of the above batteries was discharged at a constant resistance of 68Ω at room temperature, and when the battery voltage reached 2.5V, the discharge was terminated and the thickness of each battery was measured. The results are shown in FIG.

次に上記放電後の各電池を分解して正極体3の厚みを測
定した。その結果を第3図に示す。
Next, each battery after the discharge was disassembled and the thickness of the positive electrode body 3 was measured. The results are shown in FIG.

以上の結果から金属ネット線径0.1m1Mの従来電池
は、放電終了後の電池厚みが放電前の電池厚み0.5m
mから0.57mmまで膨れている。しかし、本発明に
よる金属ネッ)・線径0.05mm、  0.06mm
、0.07mraの電池は放電終了後、放電前の電池厚
み0 、5 m11からほとんど変化なく、逆に金属ネ
ット線径0.05mn+、  0.06n+n+の電池
は低くなっている。また、この電池厚みと正極体の厚み
に相関があり、金属ネット線径が細くなるにつれて、放
電後の正極体厚みが低くなっていることがわかった。
From the above results, for a conventional battery with a metal net wire diameter of 0.1 m and 1M, the battery thickness after discharge is 0.5 m before discharge.
It swells from m to 0.57 mm. However, the metal wire according to the present invention has a wire diameter of 0.05 mm and 0.06 mm.
, 0.07 mra, after the end of discharge, there is almost no change in the battery thickness from 0.5 m11 before discharge, and conversely, the thickness of the battery with metal net wire diameters of 0.05 m+, 0.06 n+n+ is lower. It was also found that there is a correlation between the battery thickness and the thickness of the positive electrode body, and as the metal net wire diameter becomes thinner, the thickness of the positive electrode body after discharge becomes lower.

これらのことは、金属ネット線径を細くすることにより
正極活物質3が径方向に膨らむのを抑制する度合いが少
なくなるからである。
This is because by reducing the diameter of the metal net wire, the extent to which the positive electrode active material 3 is prevented from expanding in the radial direction becomes smaller.

次に、上記従来電池で使用している金属ネット2の線径
0.1mmのものを、ローラーにより圧延をして、金属
ネット2の厚みを0.05m+n〜0.09閣にして上
記と同様にmMを組み立てて放電後電池厚みを測定した
ところ、0 、05 mm 〜0 、07 mrnの金
属ネット2を用いたものは電池厚み0 、5 m11以
下となった。また、この金属ネット2を0.05m1B
〜0.07+niに圧延して得られた正極体3は、前述
した金属ネット線径0.0511T1〜0.0711I
n+より強度が強く、合剤と共に正極体の周辺が欠ける
現象は見られなかった。
Next, the metal net 2 with a wire diameter of 0.1 mm used in the above conventional battery is rolled with a roller to make the thickness of the metal net 2 0.05 m + n ~ 0.09 mm in the same manner as above. When the battery thickness was measured after discharging by assembling the mM, it was found that the thickness of the battery using the metal net 2 of 0.05 mm to 0.07 mrn was 0.5 m11 or less. In addition, this metal net 2 is 0.05m1B
The positive electrode body 3 obtained by rolling to ~0.07+ni has the aforementioned metal net wire diameter of 0.0511T1 to 0.0711I.
The strength was stronger than that of n+, and no phenomenon of chipping around the positive electrode body together with the mixture was observed.

発明の効果 これらのことから、本発明電池は、電池を放電した後も
膨れることなく、ICカード用電源とし使用した場合、
カード自体も膨れることなく、薄形機器の電源として最
適なものである。
Effects of the Invention Based on the above, the battery of the present invention does not swell even after being discharged, and when used as a power source for an IC card,
The card itself does not swell, making it ideal as a power source for thin devices.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例における電池の断面図、第2図
は本発明の実施例における放電後の電池厚みを示す図、
第3図は本発明の実施例における放電後の電池正極体の
厚みを示す図である。 1・・・・・・セパレータ、2・・・・・・金属ネット
、3・・・・・・正極活物質、4・・・・・・負極活物
質、5・・・・・・シール材、6・・・正極端子板、7
・・・・・・負極端子板。
FIG. 1 is a cross-sectional view of a battery in an embodiment of the present invention, FIG. 2 is a diagram showing the battery thickness after discharge in an embodiment of the present invention,
FIG. 3 is a diagram showing the thickness of the battery positive electrode body after discharge in an example of the present invention. 1...Separator, 2...Metal net, 3...Positive electrode active material, 4...Negative electrode active material, 5...Sealing material , 6... Positive terminal plate, 7
...Negative terminal plate.

Claims (2)

【特許請求の範囲】[Claims] (1)正極と負極と、電解液を保持したセパレータより
なる発電要素を、シート状の正、負極端子板及びこの両
者の周縁部間に介在した窓枠状の絶縁シール材により密
封した扁平形電池であって、前記正極に線径が0.05
〜0.07mmの金属ネットを配備した扁平形電池。
(1) A flat type in which a power generating element consisting of a positive electrode, a negative electrode, and a separator holding an electrolyte is sealed with a sheet-shaped positive and negative electrode terminal plate and a window frame-shaped insulating sealing material interposed between the peripheral edges of both. In the battery, the positive electrode has a wire diameter of 0.05.
A flat battery equipped with a ~0.07mm metal net.
(2)圧延によりその厚みを0.05〜0.07mmと
した金属ネットを正確に配備した特許請求の範囲第1項
記載の扁平形電池。
(2) A flat battery according to claim 1, in which a metal net having a thickness of 0.05 to 0.07 mm is precisely arranged by rolling.
JP1262387A 1989-10-06 1989-10-06 Flat type cell Pending JPH03127455A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1262387A JPH03127455A (en) 1989-10-06 1989-10-06 Flat type cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1262387A JPH03127455A (en) 1989-10-06 1989-10-06 Flat type cell

Publications (1)

Publication Number Publication Date
JPH03127455A true JPH03127455A (en) 1991-05-30

Family

ID=17375054

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1262387A Pending JPH03127455A (en) 1989-10-06 1989-10-06 Flat type cell

Country Status (1)

Country Link
JP (1) JPH03127455A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002008729A (en) * 2000-06-19 2002-01-11 Toshiba Battery Co Ltd Flat nonaqueous electrolyte secondary battery
KR20030071090A (en) * 2002-02-27 2003-09-03 주식회사 비츠로셀 A lithium battery collector made with metal wire
JP2019140126A (en) * 2019-05-30 2019-08-22 株式会社Nbcメッシュテック Manufacturing method of current collector for lithium ion secondary battery

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002008729A (en) * 2000-06-19 2002-01-11 Toshiba Battery Co Ltd Flat nonaqueous electrolyte secondary battery
KR20030071090A (en) * 2002-02-27 2003-09-03 주식회사 비츠로셀 A lithium battery collector made with metal wire
JP2019140126A (en) * 2019-05-30 2019-08-22 株式会社Nbcメッシュテック Manufacturing method of current collector for lithium ion secondary battery

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