JPH0461753A - Flat cell - Google Patents
Flat cellInfo
- Publication number
- JPH0461753A JPH0461753A JP17060190A JP17060190A JPH0461753A JP H0461753 A JPH0461753 A JP H0461753A JP 17060190 A JP17060190 A JP 17060190A JP 17060190 A JP17060190 A JP 17060190A JP H0461753 A JPH0461753 A JP H0461753A
- Authority
- JP
- Japan
- Prior art keywords
- pos
- positive electrode
- battery
- electrode
- metal net
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 claims abstract description 44
- 239000002184 metal Substances 0.000 claims abstract description 44
- 239000003566 sealing material Substances 0.000 claims description 5
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 239000003792 electrolyte Substances 0.000 claims description 2
- 238000000137 annealing Methods 0.000 claims 1
- 238000010248 power generation Methods 0.000 claims 1
- 206010042674 Swelling Diseases 0.000 abstract 3
- 230000008961 swelling Effects 0.000 abstract 3
- 239000013543 active substance Substances 0.000 abstract 2
- 238000007599 discharging Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 description 13
- 239000007774 positive electrode material Substances 0.000 description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- 239000007773 negative electrode material Substances 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 239000011162 core material Substances 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000005055 memory storage Effects 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- Y02E60/12—
Landscapes
- Cell Electrode Carriers And Collectors (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、薄形機器、例えばICカード、電卓等の電源
となる偏平形電池の改良に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to improvements in flat batteries that serve as power sources for thin devices such as IC cards and calculators.
従来の技術
この種の電池は、代表的には第1図に示すように有機溶
媒電解液を含浸させたポリプロピレン不織布からなるセ
パレータ1を中央に位置させ、その片側に、金属ネット
からなる正極芯材2に金属ハロゲン化物、金属酸化物の
正極活物質3を充填した正極体を、他方の側にリチウム
からなる負極活物質4をそれぞれ配した発電要素を備え
、これの外側にポリエチレン、ポリプロピレン等からな
るシール材5を配備し、ステンレス鋼板、あるいはステ
ンレス鋼板にニッケルメッキを施した正極端子板6と負
極端子板70周縁部を前記シール材5と重ね合わせて熱
溶着することにより密封口する構成である。また、上記
金属ネット2は、船釣に使われているステンレス鋼、例
えば5US304.5US316(7)材質で線径が0
.1閣。BACKGROUND ART This type of battery typically has a separator 1 made of a polypropylene nonwoven fabric impregnated with an organic solvent electrolyte located in the center, as shown in FIG. 1, and a positive electrode core made of a metal net on one side. A power generating element is provided, in which a positive electrode body 2 is filled with a positive electrode active material 3 made of a metal halide or a metal oxide, and a negative electrode active material 4 made of lithium is arranged on the other side, and polyethylene, polypropylene, etc. A sealing material 5 is provided, and the peripheral edges of a positive terminal plate 6 and a negative terminal plate 70 made of a stainless steel plate or a stainless steel plate plated with nickel are overlapped with the sealing material 5 and thermally welded to seal the opening. It is. The metal net 2 is made of stainless steel used for boat fishing, such as 5US304.5US316 (7), and has a wire diameter of 0.
.. 1 cabinet.
目数50メツシュのものが使用されている。この種の電
池は、ICカードのメモリー保持電源用として薄形機器
に使用されるため、電池に対してもできる限り薄いもの
が要望されている。このICカード用電源としては電池
厚み0.5+m以下が要望されている。The one with 50 meshes is used. Since this type of battery is used in thin devices as a memory holding power source for IC cards, it is desired that the battery be as thin as possible. As a power source for this IC card, a battery thickness of 0.5+m or less is required.
発明が解決しようとする課題
ところが、このような偏平形電池は、例えば電池厚み0
.5−の電池を作り、使用機器に挿入して使用すると、
電池部が膨らみ使用後には電池の厚みが約0.6wm+
になる。これは、ICカードのメモリー保持電源として
偏平形電池を組み込んで端末機等にICカードを挿入し
使用していると、使用の始めは良いが使用するにつれて
ICカードが膨らんで端末機から取り出しができなくな
る。Problems to be Solved by the Invention However, such a flat battery has a thickness of 0, for example.
.. 5- If you make a battery and insert it into the device you are using,
The battery part will swell and the thickness of the battery will be approximately 0.6wm+ after use.
become. This is because when an IC card is inserted into a terminal device, etc. with a flat battery installed as a memory storage power source for the IC card, the IC card swells up as it is used and becomes difficult to remove from the terminal device. become unable.
以上のように従来の偏平形電池では、電池が消耗するに
つれて電池の厚みが増加して、偏平形電池を組み込んで
いるカード状機器が使用末期になってくると機器本体に
差し込み不能になったり取り出し不可能になったりする
問題がある。As mentioned above, with conventional flat batteries, the thickness of the battery increases as the battery wears out, and when a card-shaped device incorporating a flat battery reaches the end of its use, it may become impossible to insert it into the device itself. There is a problem that it may become impossible to take it out.
本発明は、このような問題点を解消するものである。The present invention solves these problems.
課題を解決するための手段
本発明は、上記問題点を解消するために、正極内の金属
ネットからなる正極芯材2の線径を0.02〜0.05
+amとし、目数を30〜300メツシュにしたもので
ある。また、好ましくは上記金属ネットには、これを焼
鈍して線どうしを融着したものを用いたものである。Means for Solving the Problems In the present invention, in order to solve the above problems, the wire diameter of the positive electrode core material 2 made of a metal net in the positive electrode is set to 0.02 to 0.05.
+am, and the number of stitches is 30 to 300 meshes. Preferably, the metal net is annealed and the wires are fused together.
作用
このように本発明は、金属ネットからなる正極芯材2を
線径が0.02〜0.05鯨で、目数30〜300メツ
シュにすることにより、電池を組み立てた直後から放電
終了までに電池の膨らみがなく、使用直前から使用後ま
で安定した電池を供給できる。As described above, in the present invention, the positive electrode core material 2 made of a metal net has a wire diameter of 0.02 to 0.05 mm and a mesh number of 30 to 300, so that the battery can be used immediately after assembly until the end of discharge. There is no bulge in the battery, and a stable battery can be supplied from just before use to after use.
これは、正極合剤3に金属酸化物を用いて、負極活物質
4にリチウムを用いた電池においては、電池の放電とと
もに金属酸化物が膨らんでいく。This is because in a battery using a metal oxide for the positive electrode mixture 3 and lithium for the negative electrode active material 4, the metal oxide expands as the battery discharges.
一方、負極活物質であるリチウム4は、電池の放電と共
にリチウムイオンとしてセパレータ1を介して正極合剤
3の方に移動して、放電終了後にはリチウムがほとんど
なくなる。この時、従来の構成では正極合剤3の膨らみ
が負極活物質であるリチウム4の減少より大きいため電
池として放電終了時に電池が膨らむ。On the other hand, lithium 4, which is the negative electrode active material, moves as lithium ions through the separator 1 toward the positive electrode mixture 3 as the battery is discharged, and almost no lithium is left after the discharge ends. At this time, in the conventional configuration, the expansion of the positive electrode mixture 3 is greater than the decrease in lithium 4, which is the negative electrode active material, so that the battery swells at the end of discharge.
これらの現象に対して、従来構成の電池を調べると、正
極合剤3の径方向に対してはほとんど膨れいないが、正
極合剤3の厚み方向の膨れが非常に大きいことが解った
。この現象について解析してみると、金属ネットからな
る正極芯材2が正極合剤中に配備されていることにより
金属ネット2の各金属線が正極合剤3を囲んでいるため
に正極合剤の径方向に膨らむのを阻止する。また、正極
合剤3が径方向に膨らむことができないため、厚み方向
に膨らんでいく。従って、厚み方向への膨らみが非常に
大きくなる。Regarding these phenomena, when a conventionally configured battery was investigated, it was found that although the positive electrode mixture 3 hardly swelled in the radial direction, the bulge in the thickness direction of the positive electrode mixture 3 was extremely large. Analyzing this phenomenon, we found that since the positive electrode core material 2 made of a metal net is placed in the positive electrode mixture, each metal wire of the metal net 2 surrounds the positive electrode mixture 3, so that the positive electrode mixture prevents the radial expansion of the Furthermore, since the positive electrode mixture 3 cannot swell in the radial direction, it swells in the thickness direction. Therefore, the bulge in the thickness direction becomes very large.
そこで本発明は、上記解析から正極合剤の径方向の正極
活物質3が膨らむことができるように金属ネット2の線
径を細くして、正極物質を囲む体積を小さ(して正極合
剤3の厚み方向への彫版を抑制したものである。Therefore, based on the above analysis, the present invention reduces the wire diameter of the metal net 2 so that the positive electrode active material 3 in the radial direction of the positive electrode mixture can expand, thereby reducing the volume surrounding the positive electrode material. 3, the engraving in the thickness direction is suppressed.
また、この金属ネット2の線径0.02〜0.05−の
ものは、スクリーン印刷用の版に使用されており、容易
に入手できるが、目数は300メツシュ以上のものがほ
とんどである。しかし、この300メツシュ以上のもの
は、開口率が小さく金属ネットから正極合剤3がはずれ
てしまう問題がある。そこで上記金属ネットの口数の小
さいものを検討すると、300メツシュ以下であれば正
極活物質の保持が可能である。また、30メツシュ以下
は、ネットを編んでもほどけてしまい使用できない。In addition, this metal net 2 with a wire diameter of 0.02 to 0.05 is used in screen printing plates and is easily available, but most have mesh numbers of 300 or more. . However, the mesh of 300 or more has a problem that the aperture ratio is small and the positive electrode mixture 3 comes off from the metal net. Therefore, when considering the metal net having a small number of meshes, it is possible to retain the positive electrode active material if the number of meshes is 300 or less. Also, if the net is less than 30 meshes, it cannot be used because it will come undone even if the net is woven.
また、上記金属ネット、すなわち線径0.02〜0.0
5mmで目数30〜300メツシュのものは、正極合剤
3を金属ネット上にスクリーン印刷方式(バッチ式)で
つける場合は、金属ネットにほとんど力をかけずにでき
るが、連続方式で金属ネットの長尺を用いた場合、金属
ネットに力がかかり変形してしまう。そこで、上記金属
ネットを焼鈍して線どうしを融着して変形しないものと
した。In addition, the above metal net, that is, wire diameter 0.02 to 0.0
For 5mm mesh with 30 to 300 meshes, if you apply the positive electrode mixture 3 onto the metal net by screen printing method (batch method), you can apply almost no force to the metal net, but if you apply the positive electrode mixture 3 onto the metal net using a continuous method, If a long length is used, force will be applied to the metal net and it will deform. Therefore, the metal net was annealed to fuse the wires together to prevent deformation.
以下本発明について実施例により詳述する。The present invention will be explained in detail below using examples.
実施例
第1図に本発明の実施例の断面図を示す。有機溶媒とし
てプロピレンカーボネートに1モル/1の過塩素酸リチ
ウムを含有した電解液を含浸させたプロピレン不織布か
らなるセパレータ1の上面に二酸化マンガンとカーボン
と結着剤を混練して線径0.O:2+mで、目数50メ
ツシュの5US304の金属ネット2に充填して圧延、
乾燥した正極体を配備し、下面にはリチウムからなる負
極活物質4を配備し、中央部を膨出させたステンレス鋼
板の正極端子板6と平板のステンレス鋼板の負極端子板
7で包含し、正極端子板6と負極端子板7の周縁部をポ
リプロピレンからなるシール材5と重ね合わせて周縁部
を熱溶着により封止して電池を組み立てた。以下同様に
して金属ネットの線径をそれぞれ0.03mm、 0.
04mm、 0.05on、0.06wnとして電池を
組み立てた。次に従来例として金属ネット2の線径0.
1++++eのものを同様にして組み立てた。いずれも
口数は50メツシュとした。また、これらの電池は、電
池サイズ22 wn X 29 ran 、厚み0.5
onmとし、正極体の寸法は、17 m X 24 m
、厚み0.23+w+とじた6″この時の各電池の正
極体の体積を同一とし、また、正極体の充填密度を2.
80g/■とじた。Embodiment FIG. 1 shows a sectional view of an embodiment of the present invention. Manganese dioxide, carbon, and a binder are kneaded on the upper surface of a separator 1 made of a propylene nonwoven fabric impregnated with an electrolytic solution containing 1 mol/1 lithium perchlorate in propylene carbonate as an organic solvent. O: 2+m, filled with 5US304 metal net 2 with 50 meshes and rolled.
A dry positive electrode body is provided, a negative electrode active material 4 made of lithium is provided on the lower surface, and the central portion is surrounded by a positive electrode terminal plate 6 made of a bulged stainless steel plate and a negative electrode terminal plate 7 made of a flat stainless steel plate, The peripheral edges of the positive terminal plate 6 and the negative terminal plate 7 were overlapped with a sealing material 5 made of polypropylene, and the peripheral edges were sealed by thermal welding to assemble the battery. Similarly, the wire diameters of the metal nets were adjusted to 0.03 mm and 0.03 mm, respectively.
The battery was assembled as 04 mm, 0.05 on, and 0.06 wn. Next, as a conventional example, the wire diameter of the metal net 2 is 0.
1++++e was assembled in the same manner. In both cases, the number of participants was 50 meshes. In addition, these batteries have a battery size of 22 wn x 29 ran and a thickness of 0.5
onm, and the dimensions of the positive electrode body are 17 m x 24 m.
, thickness 0.23 + w + 6", the volume of the positive electrode body of each battery at this time is the same, and the packing density of the positive electrode body is 2.
80g/■.
上記各電池について、室温中で30にΩ定抵抗で放電し
、電池電圧が2.5vになった時点で放電を終了し、各
電池の厚みを測定した。その結果を表−1に示す。Each of the above batteries was discharged at a constant resistance of 30Ω at room temperature, and when the battery voltage reached 2.5V, the discharge was terminated and the thickness of each battery was measured. The results are shown in Table-1.
(以 下 余 白)
また、上記金属ネットの線径と同様の0.02am、
0.03+IIIw、 0.04mm、 0.05mm
、 0.06■の線径で目数300メツシュのものを上
記と同様にして電池を組み立てて、放電をし各電池の厚
みを測定した。この時の電池厚みは、上記表−1と同様
の結果が得られた。(Margin below) In addition, the wire diameter of 0.02 am, which is the same as the wire diameter of the metal net above,
0.03+IIIw, 0.04mm, 0.05mm
Batteries with a wire diameter of 0.06 square meters and a mesh count of 300 were assembled in the same manner as above, discharged, and the thickness of each battery was measured. Regarding the battery thickness at this time, results similar to those shown in Table 1 above were obtained.
以上の結果から金属ネット線径0.1mmの従来電池は
、放電終了後の電池厚みが放電前の電池厚み0.05m
mから0.59mmまで膨れている。しかし、本発明に
よる金属ネット線径0.02〜0.05晒で目数50〜
300メツシュのものは、放電終了後、放電前の電池厚
み0.50mmを越えることなく、逆に金属ネット線径
0.02〜0.05mmのものは放電終了後電池厚みが
低くなっている。From the above results, for a conventional battery with a metal net wire diameter of 0.1 mm, the battery thickness after discharge is 0.05 m before discharge.
It swells from m to 0.59mm. However, the metal net wire diameter according to the present invention is 0.02 to 0.05, and the number of meshes is 50 to 50 when bleached.
In the case of 300 mesh, the battery thickness before discharge does not exceed 0.50 mm after the end of discharge, and on the contrary, in the case of the metal net wire diameter of 0.02 to 0.05 mm, the battery thickness after end of discharge is low.
また、上記金属ネット線径で目数を300メツシュ以上
にして正極活物質を充填し圧延を行ったが、この圧延の
際に正極物質が金属ネットよりはずれた。これは、金属
ネットの開口率が少ないため、正極活物質が開口部へ入
り込まないからである。逆に30メツシュ以下について
は、非常に金属ネットの強度が弱くネットを引っ張ると
変形し、原形が保てなくなり、ネットがほどけてしまう
。Moreover, the number of meshes was set to 300 meshes or more using the metal net wire diameter, and the positive electrode active material was filled and rolled, but the positive electrode material came off from the metal net during rolling. This is because the positive electrode active material does not enter the openings because the metal net has a small opening ratio. On the other hand, if the mesh is less than 30, the strength of the metal net is very weak, and when the net is pulled, it deforms and cannot maintain its original shape, causing the net to unravel.
また、上記各金属ネットにおいて50メツシュと300
メツシュの放電後電池厚みが同様であったが、この実施
例では正極体の厚みを同じにして正極体の体積を同一に
していることから反応に関与しない金属ネットの占める
体積の少ない50メツシュのものが電池容量の面で有利
である。In addition, in each of the above metal nets, 50 mesh and 300 mesh
Although the cell thicknesses of the meshes after discharge were the same, in this example, the thickness of the positive electrode body was the same and the volume of the positive electrode body was the same, so the 50 mesh battery had a smaller volume occupied by the metal net that did not participate in the reaction. This is advantageous in terms of battery capacity.
次に上記正極活物質3を充填する方法として、501v
11×300Mの金属ネット上に塗りつけて行ったが量
産性を高めるため数Loomの長尺でする場合、強度が
弱(また編んだ金属ネットがはずれる問題点があった。Next, as a method of filling the positive electrode active material 3, 501v
It was applied on a metal net of 11 x 300M, but when it was made into a long piece of several looms to increase mass production, the strength was weak (and there was a problem that the woven metal net could come off).
そこで、この金属ネット3を900℃で焼鈍して金属線
どうしを融着して、強度を高めた。この焼鈍した金属ネ
ットを使用すると編んだ金属ネットがはずれることなく
、長尺においても可能となった。Therefore, this metal net 3 was annealed at 900° C. to fuse the metal wires together to increase its strength. By using this annealed metal net, the knitted metal net will not come off and can be made in long lengths.
発明の効果
これらのことから、本発明の電池は、放電した後も膨れ
ることなく、薄形機器に挿入した場合でも安定した電源
として電力供給ができるものである。Effects of the Invention From the above, the battery of the present invention does not swell even after being discharged, and can supply power as a stable power source even when inserted into a thin device.
第1図は本発明の実施例における電池の断面図である。
1・・・・・・セパレータ、2・・・・・・金属ネット
、3・・・・・・正極活物質、4・・・・・・負極活物
質、5・・・・・・シール材、6・・・・・・正極端子
板、7・・・・・・負極端子板。
代理人の氏名 弁理士 粟野重孝 ほか1名第
図
イー・−′e)\°L−夕
2−−一呟ソ島ネット
3−−一正賜拮W隻
千−柄壬措功頁
5−−−ラール打FIG. 1 is a sectional view of a battery in an embodiment of the present invention. 1...Separator, 2...Metal net, 3...Positive electrode active material, 4...Negative electrode active material, 5...Sealing material , 6... Positive terminal plate, 7... Negative terminal plate. Name of agent: Patent attorney Shigetaka Awano and one other person Figure E-'e)\°L-Yu2--Itsutsu Sojima Net 3--Kazumasa Takahashi Wsensen-Karami Keiko Page 5- --Ral strike
Claims (2)
る発電要素を、シート状の正、負極端子板及びこの両者
の周縁部間に介在した窓枠状の絶縁シール材により密封
した偏平形電池であって、前記正極には線径が0.02
〜0.05mmで目数30〜300メッシュの金属ネッ
トを配備した偏平形電池。(1) A flat battery in which a power generation element consisting of a positive electrode, a negative electrode, and a separator holding an electrolyte is sealed with a sheet-shaped positive and negative terminal plate and a window frame-shaped insulating sealing material interposed between the peripheral edges of both. The positive electrode has a wire diameter of 0.02
A flat battery equipped with a metal net of ~0.05 mm and 30 to 300 meshes.
どうしを融着させたものである偏平形電池。(2) The flat battery according to claim 1, wherein the metal net is formed by annealing and fusing metal wires together.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17060190A JPH0461753A (en) | 1990-06-28 | 1990-06-28 | Flat cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17060190A JPH0461753A (en) | 1990-06-28 | 1990-06-28 | Flat cell |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0461753A true JPH0461753A (en) | 1992-02-27 |
Family
ID=15907875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP17060190A Pending JPH0461753A (en) | 1990-06-28 | 1990-06-28 | Flat cell |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0461753A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20030071090A (en) * | 2002-02-27 | 2003-09-03 | 주식회사 비츠로셀 | A lithium battery collector made with metal wire |
US20190003063A1 (en) * | 2013-02-26 | 2019-01-03 | Vlaamse Instelling Voor Technologisch Onderzoek (Vito) Nv | Current density distributor for use in an electrode |
JP2019140126A (en) * | 2019-05-30 | 2019-08-22 | 株式会社Nbcメッシュテック | Manufacturing method of current collector for lithium ion secondary battery |
-
1990
- 1990-06-28 JP JP17060190A patent/JPH0461753A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20030071090A (en) * | 2002-02-27 | 2003-09-03 | 주식회사 비츠로셀 | A lithium battery collector made with metal wire |
US20190003063A1 (en) * | 2013-02-26 | 2019-01-03 | Vlaamse Instelling Voor Technologisch Onderzoek (Vito) Nv | Current density distributor for use in an electrode |
JP2019140126A (en) * | 2019-05-30 | 2019-08-22 | 株式会社Nbcメッシュテック | Manufacturing method of current collector for lithium ion secondary battery |
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