JPH0245147B2 - - Google Patents
Info
- Publication number
- JPH0245147B2 JPH0245147B2 JP56133087A JP13308781A JPH0245147B2 JP H0245147 B2 JPH0245147 B2 JP H0245147B2 JP 56133087 A JP56133087 A JP 56133087A JP 13308781 A JP13308781 A JP 13308781A JP H0245147 B2 JPH0245147 B2 JP H0245147B2
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- potential
- reference electrode
- present
- electrodes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 12
- 238000006116 polymerization reaction Methods 0.000 claims description 12
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 12
- 229910052946 acanthite Inorganic materials 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 claims description 6
- 229940056910 silver sulfide Drugs 0.000 claims description 6
- 239000002861 polymer material Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003456 ion exchange resin Substances 0.000 claims description 2
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000005342 ion exchange Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 description 24
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 15
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 15
- 229910052753 mercury Inorganic materials 0.000 description 15
- 239000012488 sample solution Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 13
- 239000010408 film Substances 0.000 description 12
- 150000002500 ions Chemical class 0.000 description 12
- 238000005868 electrolysis reaction Methods 0.000 description 11
- 239000012528 membrane Substances 0.000 description 11
- 239000004793 Polystyrene Substances 0.000 description 10
- 239000008151 electrolyte solution Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 229920002223 polystyrene Polymers 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000010409 thin film Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 229940021013 electrolyte solution Drugs 0.000 description 7
- 238000004458 analytical method Methods 0.000 description 6
- 239000001103 potassium chloride Substances 0.000 description 6
- 235000011164 potassium chloride Nutrition 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000004313 potentiometry Methods 0.000 description 5
- 238000004832 voltammetry Methods 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000005669 field effect Effects 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920006254 polymer film Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- GTKRFUAGOKINCA-UHFFFAOYSA-M chlorosilver;silver Chemical compound [Ag].[Ag]Cl GTKRFUAGOKINCA-UHFFFAOYSA-M 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000000840 electrochemical analysis Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910001453 nickel ion Inorganic materials 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229920005597 polymer membrane Polymers 0.000 description 2
- 238000004451 qualitative analysis Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- WYEPLZROMPCSKP-UHFFFAOYSA-N [He].[F] Chemical compound [He].[F] WYEPLZROMPCSKP-UHFFFAOYSA-N 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 238000012742 biochemical analysis Methods 0.000 description 1
- 238000011325 biochemical measurement Methods 0.000 description 1
- 239000013060 biological fluid Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000009614 chemical analysis method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000003969 polarography Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000004445 quantitative analysis Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/301—Reference electrodes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56133087A JPS5834352A (ja) | 1981-08-24 | 1981-08-24 | ソリッドステートレファレンス電極 |
| PCT/JP1981/000334 WO1982001772A1 (en) | 1980-11-17 | 1981-11-16 | Reference electrode |
| EP81903068A EP0068025B1 (en) | 1980-11-17 | 1981-11-16 | Reference electrode |
| DE8181903068T DE3176510D1 (en) | 1980-11-17 | 1981-11-16 | Reference electrode |
| DK317782A DK159861C (da) | 1980-11-17 | 1982-07-15 | Referenceelektrode med inaktiv polymermembran og fremgangsmaade til fremstilling heraf |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56133087A JPS5834352A (ja) | 1981-08-24 | 1981-08-24 | ソリッドステートレファレンス電極 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5834352A JPS5834352A (ja) | 1983-02-28 |
| JPH0245147B2 true JPH0245147B2 (zh) | 1990-10-08 |
Family
ID=15096542
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56133087A Granted JPS5834352A (ja) | 1980-11-17 | 1981-08-24 | ソリッドステートレファレンス電極 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5834352A (zh) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6074068U (ja) * | 1983-10-28 | 1985-05-24 | 新神戸電機株式会社 | 容量センサ |
| JPS6193093A (ja) * | 1984-10-01 | 1986-05-12 | 日本クラウンコルク株式会社 | 樹脂ボトルの密封方法 |
| JPH0623732B2 (ja) * | 1986-07-18 | 1994-03-30 | 日本電気株式会社 | ボルタンメトリツクな測定方法 |
| JPH02127286A (ja) * | 1989-09-14 | 1990-05-15 | Shibasaki Seisakusho:Kk | キャップ装着装置 |
| JP2585159B2 (ja) * | 1992-02-27 | 1997-02-26 | 株式会社日本製鋼所 | 電気化学的特性評価装置 |
| EP0580525A1 (en) * | 1992-07-13 | 1994-01-26 | Eastman Kodak Company | Particle size probe for silver halide emulsion |
| DE19512905A1 (de) * | 1995-04-06 | 1996-10-10 | Boehringer Mannheim Gmbh | Vorrichtung zum Herausziehen oder Abdrehen von Verschlüssen von Gefäßen |
| JP4903684B2 (ja) * | 2007-12-28 | 2012-03-28 | 株式会社堀場製作所 | 比較電極 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5481897A (en) * | 1977-12-12 | 1979-06-29 | Kuraray Co | Fet comparison electrode |
| JPS55101853A (en) * | 1979-01-30 | 1980-08-04 | Agency Of Ind Science & Technol | Method of fabricating comparison electrode with fet |
| JPS55101852A (en) * | 1979-01-30 | 1980-08-04 | Agency Of Ind Science & Technol | Method of fabricating comparison electrode with fet |
-
1981
- 1981-08-24 JP JP56133087A patent/JPS5834352A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5481897A (en) * | 1977-12-12 | 1979-06-29 | Kuraray Co | Fet comparison electrode |
| JPS55101853A (en) * | 1979-01-30 | 1980-08-04 | Agency Of Ind Science & Technol | Method of fabricating comparison electrode with fet |
| JPS55101852A (en) * | 1979-01-30 | 1980-08-04 | Agency Of Ind Science & Technol | Method of fabricating comparison electrode with fet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5834352A (ja) | 1983-02-28 |
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