JPH0242790B2 - - Google Patents
Info
- Publication number
- JPH0242790B2 JPH0242790B2 JP59264347A JP26434784A JPH0242790B2 JP H0242790 B2 JPH0242790 B2 JP H0242790B2 JP 59264347 A JP59264347 A JP 59264347A JP 26434784 A JP26434784 A JP 26434784A JP H0242790 B2 JPH0242790 B2 JP H0242790B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon
- boron
- resin
- composite
- laminate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 99
- 229910052799 carbon Inorganic materials 0.000 claims description 94
- 229920005989 resin Polymers 0.000 claims description 71
- 239000011347 resin Substances 0.000 claims description 71
- 239000002131 composite material Substances 0.000 claims description 59
- 229910052796 boron Inorganic materials 0.000 claims description 52
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 51
- 239000003575 carbonaceous material Substances 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 31
- 238000000576 coating method Methods 0.000 claims description 28
- 229920001187 thermosetting polymer Polymers 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 21
- 229910052751 metal Inorganic materials 0.000 claims description 19
- 239000002184 metal Substances 0.000 claims description 19
- 238000005229 chemical vapour deposition Methods 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 15
- 239000004634 thermosetting polymer Substances 0.000 claims description 15
- 239000003870 refractory metal Substances 0.000 claims description 14
- 239000011294 coal tar pitch Substances 0.000 claims description 9
- 150000001639 boron compounds Chemical class 0.000 claims description 6
- 238000005470 impregnation Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000004744 fabric Substances 0.000 description 17
- 239000011159 matrix material Substances 0.000 description 14
- 239000000835 fiber Substances 0.000 description 10
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Natural products OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 10
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 9
- 238000003763 carbonization Methods 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 150000001721 carbon Chemical class 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 229920000049 Carbon (fiber) Polymers 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- FQNHWXHRAUXLFU-UHFFFAOYSA-N carbon monoxide;tungsten Chemical group [W].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] FQNHWXHRAUXLFU-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011800 void material Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011304 carbon pitch Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011253 protective coating Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- PPWPWBNSKBDSPK-UHFFFAOYSA-N [B].[C] Chemical compound [B].[C] PPWPWBNSKBDSPK-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 229920005546 furfural resin Polymers 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920013657 polymer matrix composite Polymers 0.000 description 1
- 239000011160 polymer matrix composite Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
- D01F11/124—Boron, borides, boron nitrides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
- C04B35/83—Carbon fibres in a carbon matrix
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/14—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with organic compounds, e.g. macromolecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Products (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US56145983A | 1983-12-14 | 1983-12-14 | |
US561459 | 1990-08-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60200860A JPS60200860A (ja) | 1985-10-11 |
JPH0242790B2 true JPH0242790B2 (de) | 1990-09-26 |
Family
ID=24242063
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59264347A Granted JPS60200860A (ja) | 1983-12-14 | 1984-12-14 | 高強度、耐酸化性のカ−ボン/カ−ボン複合材の製造法 |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS60200860A (de) |
DE (1) | DE3445510A1 (de) |
FR (1) | FR2556713B1 (de) |
GB (1) | GB2151221B (de) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60242041A (ja) * | 1984-04-10 | 1985-12-02 | Kureha Chem Ind Co Ltd | 可撓性黒鉛シ−トの補強方法 |
GB2187178A (en) * | 1986-02-28 | 1987-09-03 | Plessey Co Plc | A method of improving the oxidation resistance of graphites |
JPH0829987B2 (ja) * | 1986-10-23 | 1996-03-27 | 三菱化学株式会社 | 炭素繊維強化炭素複合材の製造方法 |
JPH064513B2 (ja) * | 1990-03-20 | 1994-01-19 | 工業技術院長 | 高性能c/cコンポジットおよびその製造方法 |
FR2907778B1 (fr) * | 2006-10-26 | 2010-12-10 | Snecma Propulsion Solide | Procede de fabrication d'une piece en materiau composite thermostructural. |
US9605161B2 (en) * | 2012-06-15 | 2017-03-28 | Blue Cube Ip Llc | Conductive carbonized layered article |
CN104364297B (zh) * | 2012-06-15 | 2016-08-24 | 蓝立方知识产权有限责任公司 | 碳前体组合物 |
US10689305B2 (en) | 2015-06-26 | 2020-06-23 | Goodrich Corporation | Systems and methods for producing a carbon composite material |
US9725803B2 (en) * | 2015-07-02 | 2017-08-08 | Goodrich Corporation | Method of forming borides in carbon composites |
US9970497B2 (en) | 2015-12-18 | 2018-05-15 | Goodrich Corporation | Systems and methods for carbon-carbon materials incorporating yttrium and zirconium compounds |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5532710A (en) * | 1978-08-23 | 1980-03-07 | Toho Beslon Co | Carbon fiber reinforced carbon friction material |
JPS5551769A (en) * | 1972-03-28 | 1980-04-15 | Ducommun Inc | Manufacture of high strength fiberrreinforced compounded product |
JPS58130164A (ja) * | 1982-01-25 | 1983-08-03 | ハイトコ | 炭素−炭素複合材料ならびにその製造法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3672936A (en) * | 1968-04-18 | 1972-06-27 | Carborundum Co | Reinforced carbon and graphite articles |
GB1343773A (en) * | 1970-05-05 | 1974-01-16 | Atomic Energy Authority Uk | Graphite structures |
DE2430719A1 (de) * | 1974-06-26 | 1976-01-15 | Diethelm Dipl Chem Dr Bitzer | Verfahren zur herstellung einer kohlenstoffaserverstaerkten kohlenstoffmatrix |
US4321298A (en) * | 1980-02-26 | 1982-03-23 | Hitco | Carbon fabrics sequentially resin coated with (1) a metal-containing composition and (2) a boron-containing composition are laminated and carbonized |
DE3201429C2 (de) * | 1982-01-19 | 1986-04-03 | Hitco, Irving, Calif. | Verfahren zur Herstellung eines Kohlenstoff-Kohlenstoff-Verbundmaterials |
-
1984
- 1984-12-11 GB GB08431197A patent/GB2151221B/en not_active Expired
- 1984-12-12 FR FR8418967A patent/FR2556713B1/fr not_active Expired - Fee Related
- 1984-12-13 DE DE19843445510 patent/DE3445510A1/de not_active Ceased
- 1984-12-14 JP JP59264347A patent/JPS60200860A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5551769A (en) * | 1972-03-28 | 1980-04-15 | Ducommun Inc | Manufacture of high strength fiberrreinforced compounded product |
JPS5532710A (en) * | 1978-08-23 | 1980-03-07 | Toho Beslon Co | Carbon fiber reinforced carbon friction material |
JPS58130164A (ja) * | 1982-01-25 | 1983-08-03 | ハイトコ | 炭素−炭素複合材料ならびにその製造法 |
Also Published As
Publication number | Publication date |
---|---|
JPS60200860A (ja) | 1985-10-11 |
DE3445510A1 (de) | 1985-06-20 |
FR2556713A1 (fr) | 1985-06-21 |
GB2151221B (en) | 1987-09-23 |
FR2556713B1 (fr) | 1991-12-06 |
GB8431197D0 (en) | 1985-01-23 |
GB2151221A (en) | 1985-07-17 |
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