JPH0228522B2 - - Google Patents
Info
- Publication number
- JPH0228522B2 JPH0228522B2 JP57135532A JP13553282A JPH0228522B2 JP H0228522 B2 JPH0228522 B2 JP H0228522B2 JP 57135532 A JP57135532 A JP 57135532A JP 13553282 A JP13553282 A JP 13553282A JP H0228522 B2 JPH0228522 B2 JP H0228522B2
- Authority
- JP
- Japan
- Prior art keywords
- pores
- zeolite
- diameter
- volume occupied
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 51
- 239000011148 porous material Substances 0.000 claims description 45
- 238000009826 distribution Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 description 40
- 229910021536 Zeolite Inorganic materials 0.000 description 33
- 239000011734 sodium Substances 0.000 description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 229910052717 sulfur Inorganic materials 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 8
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 8
- 235000011130 ammonium sulphate Nutrition 0.000 description 8
- 239000000295 fuel oil Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 229920002521 macromolecule Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000004523 catalytic cracking Methods 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 150000002605 large molecules Chemical class 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- -1 nickel and panadium Chemical class 0.000 description 1
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/651—50-500 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57135532A JPS5926925A (ja) | 1982-08-02 | 1982-08-02 | 改質ゼオライト |
| US06/698,308 US4668649A (en) | 1982-08-02 | 1985-02-05 | Modified zeolite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57135532A JPS5926925A (ja) | 1982-08-02 | 1982-08-02 | 改質ゼオライト |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5926925A JPS5926925A (ja) | 1984-02-13 |
| JPH0228522B2 true JPH0228522B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-06-25 |
Family
ID=15153970
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57135532A Granted JPS5926925A (ja) | 1982-08-02 | 1982-08-02 | 改質ゼオライト |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4668649A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
| JP (1) | JPS5926925A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0547359U (ja) * | 1991-11-18 | 1993-06-22 | 日本サーモスタット株式会社 | サーモスタット |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8613131D0 (en) * | 1986-05-30 | 1986-07-02 | Shell Int Research | Hydrocarbon conversion |
| GB8613132D0 (en) * | 1986-05-30 | 1986-07-02 | Shell Int Research | Hydrocarbon conversion catalysts |
| US5069890A (en) * | 1989-06-19 | 1991-12-03 | Texaco Inc. | Zeolite treating process |
| EP0569626B1 (en) * | 1992-05-11 | 1996-09-18 | Abb Lummus Global Inc. | Novel zeolite and process for production thereof |
| US5601798A (en) * | 1993-09-07 | 1997-02-11 | Pq Corporation | Process for preparing zeolite Y with increased mesopore volume |
| KR19980702741A (ko) * | 1995-03-03 | 1998-08-05 | 반주트펜조한스아아르트 | 촉매 조성물, 및 탄화수소 전환 방법에서의 그것의 용도 |
| CN1297478C (zh) * | 2003-11-28 | 2007-01-31 | 上海家化联合股份有限公司 | 分子筛基纳米复合抗紫外材料、其制备方法和用途 |
| FR2969510B1 (fr) * | 2010-12-23 | 2014-06-13 | Total Raffinage Marketing | Procede de preparation d'un catalyseur industriel d'hydroconversion, catalyseur ainsi obtenu et son utilisation dans un procede d'hydroconversion |
| CN117776204B (zh) * | 2022-09-20 | 2025-02-25 | 中国石油天然气股份有限公司 | 改性分子筛及其制备方法和应用 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6503410A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1963-02-21 | 1965-09-20 | ||
| US3402996A (en) * | 1966-12-19 | 1968-09-24 | Grace W R & Co | Ion exchange of crystalline zeolites |
| US3945943A (en) * | 1971-10-20 | 1976-03-23 | Union Oil Company Of California | Zeolite containing compositions, catalysts and methods of making |
-
1982
- 1982-08-02 JP JP57135532A patent/JPS5926925A/ja active Granted
-
1985
- 1985-02-05 US US06/698,308 patent/US4668649A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0547359U (ja) * | 1991-11-18 | 1993-06-22 | 日本サーモスタット株式会社 | サーモスタット |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5926925A (ja) | 1984-02-13 |
| US4668649A (en) | 1987-05-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8148285B2 (en) | Method for manufacturing zeolite Y with aluminum and titanium inserted therein | |
| US6723297B2 (en) | Amorphous silica-alumina, a carrier combination and a hydrocracking catalyst containing the same, and processes for the preparation thereof | |
| US4480047A (en) | High performance catalysts for carbometallic oil conversion and their manufacturing and use | |
| JPH0239305B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| EP0947575B1 (en) | A process for hydrocracking a heavy distillate oil under middle pressure | |
| JPH0536099B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JPH0228522B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JP2021004288A (ja) | 重質油の水素化処理方法 | |
| JP2007313409A (ja) | 水素化分解触媒組成物およびその製造方法 | |
| CA1216835A (en) | Hydrocarbon conversion catalysts | |
| JP3772285B2 (ja) | 炭化水素油の水素化分解触媒および水素化分解方法 | |
| US4376039A (en) | Hydrocarbon conversion catalysts and processes utilizing the same | |
| US4631261A (en) | Method for preparing hydrocarbon catalytic cracking catalyst compositions | |
| JPH08173816A (ja) | 炭化水素の流動接触分解用触媒組成物および該組成物の製造方法 | |
| JPH07116451B2 (ja) | 炭化水素装入原料の品質改善方法 | |
| JPH0516907B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JP2000086233A (ja) | 鉄含有結晶性アルミノシリケート | |
| JPH0117414B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| US4572779A (en) | Process for the dewaxing of hydrocarbon fractions | |
| JP2750371B2 (ja) | 接触分解用触媒組成物およびそれを使用した重質炭化水素油の接触分解方法 | |
| JPH0462781B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| US20020011429A1 (en) | Iron-containing crystalline aluminosilicate | |
| JP3057651B2 (ja) | 炭化水素類の水素化分解方法 | |
| JPH0512023B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JP2750370B2 (ja) | 接触分解用触媒組成物およびその製造方法 |