JPH02229201A

JPH02229201A - フィット性にすぐれたストッキング

フィット性にすぐれたストッキング

Info

Publication number: JPH02229201A
Authority: JP; Japan
Prior art keywords: stockings; polyester; units; block copolymer; yarn
Prior art date: 1990-01-12
Legal status : Granted

Application number

JP591490A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0375641B2 (enrdf_load_stackoverflow

Inventor

Ryoji Komatsu

良二小松

Masakatsu Oguchi

大口　正勝

Nobuhisa Okazaki

岡崎　修久

Current Assignee

Toyobo Co Ltd

Original Assignee

Toyobo Co Ltd

Priority date

1990-01-12

Filing date

1990-01-12

Publication date

1990-09-12

1990-01-12 Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd

1990-01-12 Priority to JP591490A priority Critical patent/JPH02229201A/ja

1990-09-12 Publication of JPH02229201A publication Critical patent/JPH02229201A/ja

1991-12-02 Publication of JPH0375641B2 publication Critical patent/JPH0375641B2/ja

Status Granted legal-status Critical Current

Links

229920000728 polyester Polymers 0.000 claims abstract description 27
-1 polytetramethylene terephthalate units Polymers 0.000 claims abstract description 24
229920001400 block copolymer Polymers 0.000 claims abstract description 22
239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 21
229920000570 polyether Polymers 0.000 claims abstract description 21
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 15
238000002844 melting Methods 0.000 claims abstract description 9
230000008018 melting Effects 0.000 claims abstract description 9
229920000642 polymer Polymers 0.000 claims abstract description 9
229910052751 metal Inorganic materials 0.000 claims abstract description 8
239000002184 metal Substances 0.000 claims abstract description 8
239000002253 acid Substances 0.000 claims abstract description 6
229920001281 polyalkylene Polymers 0.000 claims abstract description 5
125000003827 glycol group Chemical group 0.000 claims abstract description 4
229920000909 polytetrahydrofuran Polymers 0.000 claims abstract description 4
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 6
238000005406 washing Methods 0.000 abstract description 14
238000009940 knitting Methods 0.000 abstract description 8
230000000704 physical effect Effects 0.000 abstract description 4
239000000463 material Substances 0.000 abstract 1
230000000052 comparative effect Effects 0.000 description 24
238000004043 dyeing Methods 0.000 description 19
238000011084 recovery Methods 0.000 description 13
239000000975 dye Substances 0.000 description 10
239000000047 product Substances 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
238000002074 melt spinning Methods 0.000 description 5
238000000034 method Methods 0.000 description 5
229920002292 Nylon 6 Polymers 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
WOZVHXUHUFLZGK-UHFFFAOYSA-N terephthalic acid dimethyl ester Natural products COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
238000005562 fading Methods 0.000 description 3
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
238000009987 spinning Methods 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
230000003078 antioxidant effect Effects 0.000 description 2
230000003796 beauty Effects 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
230000008602 contraction Effects 0.000 description 2
239000000986 disperse dye Substances 0.000 description 2
239000000835 fiber Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
210000002414 leg Anatomy 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000011160 research Methods 0.000 description 2
238000007665 sagging Methods 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
238000010186 staining Methods 0.000 description 2
230000037303 wrinkles Effects 0.000 description 2
YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 1
VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
229920002302 Nylon 6,6 Polymers 0.000 description 1
241001483078 Phyto Species 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
210000003423 ankle Anatomy 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000012752 auxiliary agent Substances 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
238000004737 colorimetric analysis Methods 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
239000004744 fabric Substances 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
238000011835 investigation Methods 0.000 description 1
210000003127 knee Anatomy 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
239000006224 matting agent Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000010446 mirabilite Substances 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
MTZWHHIREPJPTG-UHFFFAOYSA-N phorone Chemical compound CC(C)=CC(=O)C=C(C)C MTZWHHIREPJPTG-UHFFFAOYSA-N 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920000874 polytetramethylene terephthalate Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
238000009958 sewing Methods 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
LLHSEQCZSNZLRI-UHFFFAOYSA-M sodium;3,5-bis(methoxycarbonyl)benzenesulfonate Chemical compound [Na+].COC(=O)C1=CC(C(=O)OC)=CC(S([O-])(=O)=O)=C1 LLHSEQCZSNZLRI-UHFFFAOYSA-M 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1