JPH0215858B2 - - Google Patents
Info
- Publication number
- JPH0215858B2 JPH0215858B2 JP5181880A JP5181880A JPH0215858B2 JP H0215858 B2 JPH0215858 B2 JP H0215858B2 JP 5181880 A JP5181880 A JP 5181880A JP 5181880 A JP5181880 A JP 5181880A JP H0215858 B2 JPH0215858 B2 JP H0215858B2
- Authority
- JP
- Japan
- Prior art keywords
- base paper
- photographic base
- paper according
- resin
- photographic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011347 resin Substances 0.000 claims description 79
- 229920005989 resin Polymers 0.000 claims description 79
- 239000003381 stabilizer Substances 0.000 claims description 33
- 239000011248 coating agent Substances 0.000 claims description 29
- 238000000576 coating method Methods 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- -1 p-hydroxyphenyl group Chemical group 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000004611 light stabiliser Substances 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 229910052791 calcium Chemical group 0.000 claims description 5
- 239000011575 calcium Chemical group 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical group C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 230000002265 prevention Effects 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 1
- BEWYQGKCWZSESF-UHFFFAOYSA-N OP(=O)OC(O)C1=CC=CC=C1 Chemical compound OP(=O)OC(O)C1=CC=CC=C1 BEWYQGKCWZSESF-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 11
- 229920001684 low density polyethylene Polymers 0.000 description 9
- 239000004702 low-density polyethylene Substances 0.000 description 9
- 238000003384 imaging method Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- WPRMJBJYCFNTKE-UHFFFAOYSA-L (3,5-ditert-butyl-4-hydroxyphenyl)methyl-ethoxyphosphinate;nickel(2+) Chemical compound [Ni+2].CCOP([O-])(=O)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1.CCOP([O-])(=O)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 WPRMJBJYCFNTKE-UHFFFAOYSA-L 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- SWZOQAGVRGQLDV-UHFFFAOYSA-N 4-[2-(4-hydroxy-2,2,6,6-tetramethylpiperidin-1-yl)ethoxy]-4-oxobutanoic acid Chemical compound CC1(C)CC(O)CC(C)(C)N1CCOC(=O)CCC(O)=O SWZOQAGVRGQLDV-UHFFFAOYSA-N 0.000 description 2
- AIXZBGVLNVRQSS-UHFFFAOYSA-N 5-tert-butyl-2-[5-(5-tert-butyl-1,3-benzoxazol-2-yl)thiophen-2-yl]-1,3-benzoxazole Chemical compound CC(C)(C)C1=CC=C2OC(C3=CC=C(S3)C=3OC4=CC=C(C=C4N=3)C(C)(C)C)=NC2=C1 AIXZBGVLNVRQSS-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007765 extrusion coating Methods 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000003504 photosensitizing agent Substances 0.000 description 2
- KEENCKJOBBYIEF-UHFFFAOYSA-N (3,5-ditert-butyl-2-ethyl-4-hydroxyphenyl)methylphosphonic acid Chemical compound CCC1=C(CP(O)(O)=O)C=C(C(C)(C)C)C(O)=C1C(C)(C)C KEENCKJOBBYIEF-UHFFFAOYSA-N 0.000 description 1
- WBSRIXCTCFFHEF-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methyl-ethoxyphosphinic acid Chemical compound CCOP(O)(=O)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 WBSRIXCTCFFHEF-UHFFFAOYSA-N 0.000 description 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 description 1
- 125000006701 (C1-C7) alkyl group Chemical group 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- USOCPWBICMUEKP-UHFFFAOYSA-N CC(C)(C)C(C(C=C1)=CC=C1O)OP(O)=O Chemical compound CC(C)(C)C(C(C=C1)=CC=C1O)OP(O)=O USOCPWBICMUEKP-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 206010051246 Photodermatosis Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000000181 anti-adherent effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- OOCILPYOPQKPJY-UHFFFAOYSA-N calcium;(3,5-ditert-butyl-4-hydroxyphenyl)methyl-ethoxyphosphinic acid Chemical compound [Ca].CCOP(O)(=O)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 OOCILPYOPQKPJY-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000004392 genitalia Anatomy 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 230000001617 migratory effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002367 phosphate rock Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical group OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 230000008845 photoaging Effects 0.000 description 1
- 208000017983 photosensitivity disease Diseases 0.000 description 1
- 231100000434 photosensitization Toxicity 0.000 description 1
- 230000010399 physical interaction Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000009528 severe injury Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/775—Photosensitive materials characterised by the base or auxiliary layers the base being of paper
- G03C1/79—Macromolecular coatings or impregnations therefor, e.g. varnishes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/3188—Next to cellulosic
- Y10T428/31895—Paper or wood
- Y10T428/31899—Addition polymer of hydrocarbon[s] only
- Y10T428/31902—Monoethylenically unsaturated
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
æ¬çºæã¯æš¹èãã³ãŒãã€ã³ã°ããåççšããŒã¹
ããŒããŒåã³ãã®è£œé æ³ã«é¢ãããã®ã§ããã äžè¬ã«äœ¿çšãããŠããåççšããŒã¹ããŒããŒã®
å€ãã®ãã®ã¯æš¹èãã³ãŒãã€ã³ã°ããçš®é¡ã®ãã®
ã§ããããããã¯æå å€ã䜿çšããããšã«ãã€
ãŠãååŠç転åãªãã»ãããå³åžåçåã³åŸæ¥ã®
ãã¬ãŒããžã¿ã€ãã®ãã®ãªã©çš®ã ã®åççšå°ç»çŽ
ãäœããããå°ç»çŽã¯æš¹èãã³ãŒãã€ã³ã°ããã
ãŒã¹ããŒããŒåã³æš¹èã«æ¥çãããŠããç»å圢æ
å±€ããæ¬è³ªçã«æããç»å圢æå±€ããšãã«ãžãšã³
ã³ãŒãã€ã³ã°ã§ãããã¬ãŒããžã¿ã€ãã®ãã®ã®å Ž
åããšãã«ãžãšã³ã³ãŒãã€ã³ã°ãæš¹èã«è¯å¥œã«æ¥
çããããã«ãããããšãã«ãžãšã³ã³ãŒãã€ã³ã°
äžã«çµåå€ããã°ãã°äœ¿çšããããåŸæ¥ã¯çµåå€
ãšããŠãŒã©ãã³ã䜿çšãããŠããã代çšã®åæç©
質ã䜿çšã§ããã æš¹èã¯éåžžããªãªã¬ãã€ã³ãããšãã°ããªãšã
ã¬ã³ã§ãããæš¹èãã³ãŒãã€ã³ã°ããããŒã¹ããŒ
ããŒãåæ¥çã«æåããåå ã¯ãã®ç©è³ªã«ãããš
ããã倧ãããé žåããªãŠã ãã³ãŒãã€ã³ã°ãã
ããŒã¹ããŒããŒïŒãã©ã€ã¿çŽïŒãšã¯éã€ãŠããã
ãã¯æ°Žåã³åççšååŠåŠç液ã«å¯ŸããŠäžæµžéæ§ã§
ãããåŸã€ãŠãããã¯ä¹Ÿç¥æéãçããããã®çµ
æè¿ éã«åŠçã§ãããããã«ãããã¯åŠçè¬å€ã®
䜿çšãå°ãªããŠæžã¿ãåŸã€ãŠå€åœ¢ããããšãã»ãš
ãã©ãªãããããã®ç¹åŸŽã¯ããã¬ãŒããžã¿ã€ãã®
åçãç¹ã«çœé»åçã®å Žåããé·æéåŠç液ã«æµž
挬ããå¿ èŠãããã«ã©ãŒããªã³ãã«ãšã€ãŠéåžžã«
éèŠãªç¹æ§ã§ãããããããªãããæš¹èãã³ãŒã
ã€ã³ã°ããããŒã¹ããŒããŒãã補é ããåççšå°
ç»çŽã¯åšå²ã®æ¡ä»¶ã®å€åã«é·æéãããããå Ž
åãç»å圢æå±€åã³æš¹èå±€ã¯å€è³ªããŠå²ç®ãçã
ãŠçŸèŠ³ãæããããã²ã©ãå Žåã«ã¯å²ç®ãå°ç»çŽ
ã®å šé¢ã«åãã§ç»åãå®å šã«æå·ãããããšãã
ãããããã®å²ç®ãçããã®ã«ã¯äžè¬ã«æ°ã±æã
å Žåã«ãã€ãŠã¯æ°å¹Žãããããå°ç»çŽãåºããªã
ã€ã¹ã®ã·ãšãŠãŠã€ã³ããŠãªã©ã®èé ·ãªæ¡ä»¶äžã«ã
ãããå Žåã«ã¯å²ç®ãçããã®ãéãŸããå®éã«
ã·ãšãŠãŠã€ã³ããŠäžã§ã¯å²ç®ã¯æ°é±éã§çããã
ãšããããæš¹èã«æœããè¡šé¢ã®ä»äžãã¯äœã®åœ¹ã«
ãç«ããªãã å²ç®ãçããåºæ¬çåå ã¯ããããªãç¹ããã
ããç»å圢æå±€ãšæš¹èå±€ãšã®éã®ç©çççžäºäœçš
ã«ãããšããã倧ãããšèããããŠãããäžè¬ã«
èªãããŠãã説ã«ããã°ã枩床åã³æ¹¿åºŠãªã©ã®åš
å²ã®æ¡ä»¶ã®å€åã«å¿ããŠç»å圢æå±€ãšæš¹èå±€ãšã®
éã§èšè¹åã³åçž®ã®åºŠåã«å·®ãçããããã§ãã
ããšèããããŠãããæè¿ã®å°ç»çŽã§ã¯ãã®ãã
ãªåã®å·®ãçããŠãæš¹èã³ãŒãã€ã³ã°ã«ãã€ãŠè
ããããã«ãªã€ãŠããã®ã§å²ç®ã¯çããªãããã
ããªãããæãçµãã«åŸã€ãŠãæš¹èã¯å åã³ïŒå
ã¯ç±ãªã©ã®äœçšã«ãã€ãŠå£åããåŸåãããã
åŸã ã«ããããªãããããªããšæš¹èã¯åã®å·®ã«è
ããããªããªããç»å圢æå±€ãŸãã¯ç»å圢æå±€å
ã³æš¹èå±€ã®äž¡æ¹ã«å²ç®ãçãå§ããããã®ãã
ã«ãæš¹èå±€ã®å®å®æ§ã¯æ¯èŒçäœãããã«ãæš¹èã
æ¯æäœäžã«ã³ãŒãã€ã³ã°ããåã«å®å®å€ãæš¹èã«
çŽæ¥ã«æ··å ¥ããããšãè©Šã¿ããããããããåé¡
ããã€ãããããã®åé¡ã¯æš¹èãšããŒããŒãšã«é
ã®æ¥çåãäœäžããããšåã³æŒåºã³ãŒãã€ã³ã°æ
äœäžå®å®å€ãç±çã«å€è³ªããŠæš¹èã®å質ãå£äžã
ããããšãªã©ã§ããã ãããã®åé¡ãå æããããã«çŽæ¯æäœã«å®å®
å€ãæ··å ¥ããããå®å®å€ãæ¯æäœäžã«ã³ãŒãã€ã³
ã°ããæ¹æ³ãéçºããããäž¡æ¹ã®å Žåãšããå®å®
å€ã¯ãããåŸæœãããæš¹èå±€ã«ç§»åããããã«ã
ã€ãŠå²ç®ãçããªãããã«ãããã®ã§ãªããã°ãª
ããªãããã®æ¹æ³ã«ãã€ãŠäžå¿æš¹èã®çŽæ¯æäœãž
ã®æ¥çåãäœäžãããããšãªããæš¹èã³ãŒãã€ã³
ã°ã®å質ã«æ¯éãæ¥ããããšãªãå²ç®ãé²æ¢ã§ã
ãããå®å®å€ã¯é«äŸ¡ãªç©è³ªã§ããããã®æ¹æ³ïŒè±
åœç¹èš±ç¬¬1361219å·åç §ïŒã¯ããªãã®éãæ¶è²»ã
ãã®ã§ããã®æ¹æ³ãæºè¶³ãã¹ããã®ã§ã¯ãªãã æš¹èã³ãŒãã€ã³ã°äžã«ããçš®ã®å®å®å€ã䜿çšã
ãããšã«ãã€ãŠå²ç®ãå®è³ªçã«é²æ¢ã§ããããšã
æ¬çºæã«ãã€ãŠçºèŠããããããã«ãæ¬çºæã®ã
ããã®å®å®å€ã¯æš¹èãæ¯æäœäžã«æŒåºã³ãŒãã€ã³
ã°ããåã«æš¹èãšç°¡äŸ¿ã«æ··åã§ããæ¥çååã³æš¹
èç¹æ§ã«æªåœ±é¿ãåãŒããªããã®ã§ããã æ¬çºæã¯äžèšã®åŒïŒïŒã ïŒäžåŒäžR1ã¯ç«äœé害ã®ããããã·ããšãã«
ã§ãããR2ã¯C1ãC12ã®ã¢ã«ãã«ã§ãããïœã¯ïŒ
ãïŒã§ããïŒã®ååç©ãŸãã¯ãã®å¯Ÿå¿ããããªã¹
ããªããŒãã¢ããªã³ã®éå±å¡©ãå®å®å€ãšããŠå«æ
ããæš¹èã³ãŒãã€ã³ã°ãæããåççšããŒã¹ããŒ
ããŒãæäŸããã ããããã·ããšãã«ã®ç«äœé害ã¯å¥œãŸããã¯ïŒ
å以äžã®çŽéãŸãã¯æåããããéC1ãC12ã¢ã«
ãã«åºãããšãã°C1ãC7åã³C1ãC4ã¢ã«ãã«åºã
æã奜ãŸããã¯ïœâããã«åºã«ãã€ãŠéæãã
ããå¿ èŠã«å¿ããŠããããã·ããšãã«ã¯ãããã
ã·åºã«é£æ¥ããŠäž¡åŽã«ãããã®ïŒåã®åºã«ãã€ãŠ
眮æãããŠãããããããã·åºèªäœã¯ããšãã«ç°
ã®ãã©ã®äœçœ®ã«äœçœ®ããã®ãæãŸãããR2ã¯å¥œ
ãŸããã¯C1ãC8ãããã«å¥œãŸããã¯C1ãC4ã¢ã«
ãã«åºãããšãã°ãšãã«åºãè¡šãããïœã¯å¥œãŸã
ãã¯ïŒã§ããã以äžãèŠçŽãããšãåŒïŒïŒã«ç€º
ãããç«äœé害ã®ããããã·ããšããŒã«ã瀺ã
R1ã¯ãäŸãã°ïŒâããããã·åºã«çžé£ãïŒïŒïŒ
äœã®ãã¡å°ããšãïŒã€ã®çœ®æåºãçŽéåã¯æåã
ãããã¢ã«ãã«åºãæããïœâããããã·ããšã
ãŒã«åºã«ãã€ãŠä»£è¡šããããšããããšãã§ããã åè¿°ã®ããªã¹ããªããŒãã¢ããªã³ã®éå±å¡©ã¯äž
èšã®åŒïŒïŒ ïŒäžåŒäžãR1ïŒR2åã³ïœã¯åã«å®çŸ©ãããã®
ã§ãããïŒã¯éå±ã«ããªã³ã§ãããïœã¯ïŒãïŒã§
ãããïŒã®åå䟡ã«çããïŒãæãããéå±å¡©ã¯
奜ãŸããã¯å®è³ªçã«ç¡è²ã§ãããïŒã¯å¥œãŸããã¯
ããã±ã«ãŸãã¯ã«ã«ã·ãŠã ã§ãããïœã¯å¥œãŸãã
ã¯ïŒã§ããã åŒïŒïŒã«ãã€ãŠè¡šããããæãæå¹ãªå®å®å€
ã®äŸãšããŠã¯ïŒ¯âãšãã«âïŒïŒïŒâãžâïœâãã
ã«âïŒâããããã·ãã³ãžã«ããªã¹ããªã³é žåã³
ã«ã«ã·ãŠã åã³ããã±ã«ãã¹ïŒïœâãšãã«âïŒïŒ
ïŒâãžâïœâããã«âïŒâããããã·ãã³ãžã«ã
ãªã¹ããªããŒãïŒãããã äŸãã°äžèšã®ïŒ¯âãšãã«âïŒïŒïŒâãžâïœâã
ãã«âïŒâããããã·ãã³ãžã«ããªã¹ããªã³é žã
äžèšã®æ§é åŒã§ç€ºãã å®å®å€åŒïŒïŒè£œé æ³ã¯å ¬ç¥ã§ãããéé¢é žã¯
é©åœãªããã²ã³åããããã·ã¢ã©ã«ãã«ã第ïŒã
ãªã¹ãã¢ã€ããšåå¿ãããããšã«ãã€ãŠè£œé ã§ã
ãããã®éé¢é žã¯ãããåŸå¿ èŠã«å¿ããŠéå±å¡©å
ç©ãªã©ã®é©åœãªéå±èªå°äœãšåå¿ãããããšã«ã
ã€ãŠéå±å¡©ã«è»¢åããŠãè¯ãããããã¯éå±å¡©ã®
ãããã®ã¯åžè²©ãããŠããããã®ãŸãŸäœ¿çšããŠã
è¯ãããå¡©é žãªã©ã䜿çšããŠéé¢é žã«æ»ããŠãè¯
ãããã®ããã«ããŠåŸãããéé¢é žã¯ãããåŸæ¬
çºæã§ãã®ãŸãŸäœ¿çšããŠãè¯ãããä»ã®éå±å¡©ã«
転åããããã®åºçºåæãšããŠäœ¿çšããŠãè¯ãã æ¬çºæã§äœ¿çšãããå®å®å€ã¯åççšå°ç»çŽãé·
æéå²ç®ã®çããªãç¶æ ã«ä¿ã¡ããã®å¹æã¯åç
åŠçå·¥çšäžã«éåžžééããåºç¯å²ã®æªæ¡ä»¶ã«ãã
ããŠãè¡°ããªãã åççšããŒã¹ããŒããŒã¯éåžžã¯ã€ã€åŽïŒè£ïŒå
ã³è¡šé¢åŽïŒè¡šïŒã®äž¡æ¹ã«æš¹èã³ãŒãã€ã³ã°ãæã
ããæ¬çºæã®åŒïŒïŒã®å®å®å€ã®å©ç¹ã¯è¡šé¢åŽã³
ãŒãã€ã³ã°å ããå®è³ªçã«ç§»åããªãããšã§ã
ããæš¹èãã³ãŒãã€ã³ã°ããåççšããŒã¹ããŒã
ãŒã¯éåžžãªãŒã«ã«å·»ããããã®ãŸãŸé·æé貯èµã
ããã®ã§ãã®ããšã¯æ¬çºæã®éèŠãªç¹åŸŽã§ããã
ãã®ãããªç¶æ ã§ã¯è¡šé¢åŽïŒè¡šïŒãšã¯ã€ã€åŽ
ïŒè£ïŒãšã¯æ¥è§ŠããŠããã®ã§ç§»åæ§å®å®å€ã ãšå²
ç®ã®çºçãé²æ¢ããå¿ èŠã®ãªãã¯ã€ã€åŽæš¹èã³ãŒ
ãã€ã³ã°ã«ç§»åããŠããŸããããããªãããåŒ
ïŒïŒã®å®å®å€ã¯å®è³ªçã«é移åæ§ã§ããã®ã§ã
ã®ãããªåé¡ã¯çããªãã æ¬çºæã®å®å®å€ã®äœ¿çšéã¯åºç¯å²ã«ããããã
äžè¬ã«æäœã®æå¹äœ¿çšéã¯æš¹èã®ééã®çŽ0.01ïŒ
ã§ããããã以äžå ããŠãå²ç®é²æ¢å¹æã«å€åã
äžããªãæ倧䜿çšéã®æš¹èã®ééã®çŽïŒïŒ ã§ã
ããäžè¬ã«0.2ã0.5ééïŒ ãå²ç®ã«å¯ŸããŠéåžžã«
æçšãªé²æ¢å¹æãæäŸããã æ¬çºæã®åççšããŒã¹ããŒããŒã®æš¹èã³ãŒãã€
ã³ã°ã«ã¯åèšåŒã®å®å®å€ã®ä»ã«ãå¥ã®ã¿ã€ãã®å®
å®å€ãå ããŠãè¯ããããšãã°ãåŒïŒïŒã®å®å®
å€ã®äºè£é²æ¢å¹æã«çžä¹äœçšãä»äžããå®å®å€ã®
䜿çšã奜ãŸããããã®ãããªçžä¹äœçšãä»äžãã
å®å®å€ã®äŸãšããŠã¯å å®å®å€ãããšãã°ç«äœé害
ã¢ãã³ãããããã®çš®ã®å å®å®å€ã¯åéäœããŸã
ã¯å¥œãŸããã¯éåäœã§ãããåéäœã®ç«äœé害ã¢
ãã³å å®å®å€ã®äŸãšããŠã¯ãã¹ïŒïŒïŒïŒïŒïŒïŒïŒ
âããã©ã¡ãã«âïŒâãããªãžãã«ïŒã»ãã±ãŒã
ããããããã¯âTinuvin770âã®åååã§Ciba
âGeigy瀟ã«ãã€ãŠåžè²©ãããŠããã奜ãŸããæ¹
ã®éåäœã®ç«äœé害ã¢ãã³å å®å®å€ã®äŸãšããŠã¯
åååâTinuvin622âåã³âChimassorb994â
ãšããŠCibaâGeigy瀟åã³Chimosa瀟ããããã
ãåžè²©ãããŠãããã®ããããç«äœé害ã¢ãã³å
å®å®å€ãæ¬çºæã§äœ¿çšããããšã¯å©ç¹ãããã æ¬çºæã®æš¹èã³ãŒãã€ã³ã°ã¯åŸæ¥ã®æ·»å å€ãã
ãšãã°äºé žåãã¿ã³ãé žåäºéãç¡«é žããªãŠã ã
äžé žåã¢ã³ãã¢ã³åã³ã«ãŒãã³ãã©ãã¯ãªã©ã®é¡
æïŒææïŒâUvitexOBâïŒCibaâGeigy瀟ïŒãªã©
ã®å åŠçå¢çœå€ïŒåã³éé»é²æ¢å€ãªã©ãå«æããŠ
ãè¯ããåœç¶ã®ããšãªãããå å®å®å€åã³å åŠç
å¢çœå€ã®äž¡æ¹ã䜿çšããå Žåã«ã¯ãåãæ³¢é·ã®å
ã®ç«¶åãé¿ããŠå¹æãæé«ã«ããããã«éã€ãæ³¢
é·åã§åžåãè¡ãããã«ããå¿ èŠãããã æš¹èèªäœã¯éåžžããªãªã¬ãã€ã³ã奜ãŸããã¯ã
ãªãšãã¬ã³ã§ãããçš®ã ã®è¡šé¢ä»äžããããšãã°
å æ²¢ä»äžããè·æ¶ä»äžããã·ã«ã¯ä»äžããç¹ææš¡
æ§ä»äžãããã©ãããã»ã°ã¬ãŒã³ä»äžãåã³è·åº
ä»äžããå¯èœã§ããã æ¬çºæã¯ããã«åèšåŒïŒïŒã®ååç©ãŸãã¯ã
ã®éå±å¡©ã®å®å®å€ãæš¹èæ··åç©ã«æ··å ¥ããåèšæš¹
èæ··åç©ãããŒã¹ããŒããŒäžã«æŒåºãã³ãŒãã€ã³
ã°ããå·¥çšãå«ãåççšããŒã¹ããŒããŒã®è£œé æ¹
æ³ãæäŸãããã®ã§ããã æå æ§ãä»äžããåã«ãæš¹èã³ãŒãã€ã³ã°ãã
ãåççšããŒã¹ããŒããŒã¯ç»å圢æå±€ãšæš¹èå±€ãš
ã®éã®æ¥çã匷åºãšãªãããã«éåžžã³ããåŠçã
ããããã®ãããªã³ããåŠçã¯åççšããŒã¹ããŒ
ããŒè£œé æ¥è ã«ãã€ãŠäžè¬ã«è¡ãããæå å€ãç»
å圢æå±€ã«æœããããŸã§ãã®åŠçãä¿è·ãããã
ã«ãåŠçãããæš¹èã¯è±åœç¹èš±ç¬¬1134211å·ã«èš
èŒãããŠããããã«æ¥çåäœäžé²æ¢æº¶æ¶²ã§çŽã¡ã«
ã³ãŒãã€ã³ã°ããã®ãæãŸããã æ¬çºæã¯äžèšã®å®æœäŸã«ãã€ãŠããã«è©³ãã説
æããããã®è£œåãããã€ãã®äžèšã®ãã¹ãã«ã
ããã  äºè£ãå²ç®ãã¹ã æš¹èãã³ãŒãã€ã³ã°ããçŽãããŒã©ãã³ã¹ãŒã
ãŒã³ãŒããæããã¯ããïŒãããã€ããšãã«ãžãš
ã³ã䜿çšããŠãšãã«ãžãšã³ã³ãŒãã€ã³ã°ãããé²
å åŸããã®åççšããŒããŒãäžèšã®æ§ã«åŠçã
ãã çŸ å ïŒå å® ç 1/2å æŽ æµ ïŒå é²å ããŠçŸåãããµã³ãã«ãIlfospeed4250ã
ã©ã€ã€ãŒã䜿çšããŠä¹Ÿç¥ãããã®çµæåŸãããå
çããã€ããã«å ¥ããäžèšã®æ¡ä»¶äžã§æ宀åã³æ
宀ã®ãµã€ã¯ã«ã亀äºã«ç¹°è¿ããã æ宀ãµã€ã¯ãïŒïŒæéïŒ 70ã80âïŒæé«ïŒ çžå¯Ÿæ¹¿åºŠïŒ15ïŒ æ宀ãµã€ã¯ã«ïŒïŒæéïŒ 30âïŒæäœïŒ çžå¯Ÿæ¹¿åºŠïŒ80ïŒ å ã¯ãã€ããããã®éæãªé éšãã50cmé¢ãã
äœçœ®ã«çœ®ãããïŒåã®150Wã®Osramåççšã©ã³
ãããçºçããããã€ãããããžã®ç©ºæ°æµã¯æ宀
ãµã€ã¯ã«ã®å ŽåïŒãªããã«ïŒåã§ãããæ宀ãµã€
ã¯ã«ã®å Žå10ãªããã«ïŒåã§ãã€ãã ãããåŸãåçç»åãå®å šã«æå·ãããŸã§ãã
ãªãã¡ãšãã«ãžãšã³åã³æš¹èå±€ã®äž¡æ¹ãäºè£ãç
ããŠåçç»åäžã®æ å ±ã倱ãããããã«ãªããŸã§
ã®æéã枬å®ããã  å èåãã¹ã ããªãšãã¬ã³ãå£åããã«åŸã€ãŠãé žåãèµ·
ããã«ã«ããã«åºãçæãããåŸã€ãŠã«ã«ããã«
åžåã枬å®ããããšã«ãã€ãŠå£åã®çšåºŠããã
ããé²å åãé²å äžåã³é²å åŸãäœåããã®ãã
ãªæž¬å®ãè¡ãããšã«ãã€ãŠäºè£é²æ¢èœåãããã
ã©ããããããã ããã§ãæš¹èã®ã³ãŒãã€ã³ã°ãããçŽããã»ã
ã³ç¯èåè©Šéšè£ 眮ïŒ150WeatherometerïŒäžã§å
èš400æéé²å ãããè£ çœ®äžã§ã®æ¡ä»¶ã¯25âã§çž
察湿床ã50ïŒ ã§ãã€ãããã®æž¬å®ã¯è©Šéšæéäžé²
å ã®ååŸã§èµ€å€ç·åå èšã®1710cm-1ã®æ³¢é·ã«ãã
ããµã³ãã«ã®åžåã枬å®ããããšããæã€ããã
ããåŸãé²å æéã«å¯Ÿããã«ã«ããã«åžåã®å¢å
ãã°ã©ãã«ãããããããã®ã°ã©ãããã«ã«ãã
ã«åžåãæªé²å æš¹èã³ãŒãã€ã³ã°çŽãã0.1å¢å
ããæã®æéãèªåã€ãã  é°éšã®å£åãã¹ã æš¹èã³ãŒãã€ã³ã°ããçŽã105âã§72æé埪ç°
空æ°åã®çã®äžã§ç±ã§èåããããé°éšã®å£åå€
ã¯å£åãã¹ãã®ååŸã§430nïœã®æ³¢é·ã«ããããµ
ã³ãã«ïŒäžå®ã®é»çŽäœ¿çšïŒã®åå°çã枬å®ããã
ã®å·®ããå²åºãããåå°çã®æž¬å®ã¯Pretema
FS3Aã¹ãã¯ãããããã䜿çšããŠè¡ã€ãã  æ¥çåãã¹ã æš¹èå±€ãšããŒã¹ããŒããŒãšã®æ¥çåã枬å®ãã
ãã®çµæãïŒãïŒã®ïŒæ®µéã«è©äŸ¡ããè¯å¥œãªæ¥ç
ã¯äœãæ°åã§ç€ºããæªãæ¥çã¯é«ãæ°åã§ç€ºã
ãã äŸ ïŒ æ¯èŒäŸãšããŠè¡šé¢åŽïŒè¡šïŒæš¹èæ··åç©ãäžèšã®
æåãã調補ããã äœå¯åºŠããªãšãã¬ã³äžTiO250ïŒ ïŒKg äœå¯åºŠããªãšãã¬ã³äžUvitexOB2ïŒ ïŒKg äœå¯åºŠããªãšãã¬ã³ 29.5Kg ãã®çµæåŸãããæ··åç©ããããåŸ30.5ïœïŒå
ïŒ100ãã€ãŒãïŒåïŒã®æ©æ¢°é床ã§178ïœïŒm2ã®é
éã®ããŒã¹ããŒããŒäžã«ã³ãŒãã€ã³ã°ãããæŒåº
溶è枩床ã¯300ã320âã§ãã®çµæåŸãããã³ãŒã
ã€ã³ã°ã®ééã¯40ïœïŒm2ã§ãã€ãããã®åŸæ¥ã®æš¹
èãã³ãŒãã€ã³ã°ããåççšããŒã¹ããŒããŒã«ã€
ããŠã®ãã¹ãçµæãäžèšã®è¡šïŒã«ç€ºãã äŸ ïŒ æš¹èã®ééã®0.25ã0.5ïŒ ã®ããã±ã«ãã¹â
ïŒïœâãšãã«ïŒïŒïŒâãžâïœâããã«âïŒâãã
ããã·ãã³ãžã«ããªã¹ããªããŒãïŒã§ãã
Irgastab2002HTïŒCibaâGeigyïŒãæš¹èæ··åç©ã«
å ãã以å€ã¯äŸïŒãšåãæé ãç¹°è¿ãããåæ§ã«
äžèšã®è¡šïŒã«ç€ºãããããªä»ã®ã¿ã€ãã®å®å®å€ã
å¥ã®æš¹èæ··åç©ã«å ããïŒæš¹èã®ééã«å¯Ÿãã
ïŒ ïŒããã®çµæãäžèšã®è¡šïŒã«ç€ºãã äŸ ïŒ ã«ã«ã·ãŠã ãã¹âïŒïœâãšãã«âïŒïŒïŒâãžâ
ïœâããã«âïŒâããããã·ãã³ãžã«ããªã¹ããª
ããŒãïŒã§ããIrgastab1425ïŒCibaâGeigyïŒã
æš¹èã®ééã®0.05ã0.25ïŒ å ãã以å€ã¯äŸïŒãšå
ãæé ãç¹°è¿ãããåæ§ã«äžèšã®è¡šïŒã«ç€ºããã
ããªä»ã®ã¿ã€ãã®å®å®å€ãå¥ã®æš¹èæ··åç©ã«å ã
ãïŒæš¹èã®ééã«å¯ŸããïŒ ïŒããã®çµæãäžèšã®
è¡šïŒã«ç€ºãã
ããŒããŒåã³ãã®è£œé æ³ã«é¢ãããã®ã§ããã äžè¬ã«äœ¿çšãããŠããåççšããŒã¹ããŒããŒã®
å€ãã®ãã®ã¯æš¹èãã³ãŒãã€ã³ã°ããçš®é¡ã®ãã®
ã§ããããããã¯æå å€ã䜿çšããããšã«ãã€
ãŠãååŠç転åãªãã»ãããå³åžåçåã³åŸæ¥ã®
ãã¬ãŒããžã¿ã€ãã®ãã®ãªã©çš®ã ã®åççšå°ç»çŽ
ãäœããããå°ç»çŽã¯æš¹èãã³ãŒãã€ã³ã°ããã
ãŒã¹ããŒããŒåã³æš¹èã«æ¥çãããŠããç»å圢æ
å±€ããæ¬è³ªçã«æããç»å圢æå±€ããšãã«ãžãšã³
ã³ãŒãã€ã³ã°ã§ãããã¬ãŒããžã¿ã€ãã®ãã®ã®å Ž
åããšãã«ãžãšã³ã³ãŒãã€ã³ã°ãæš¹èã«è¯å¥œã«æ¥
çããããã«ãããããšãã«ãžãšã³ã³ãŒãã€ã³ã°
äžã«çµåå€ããã°ãã°äœ¿çšããããåŸæ¥ã¯çµåå€
ãšããŠãŒã©ãã³ã䜿çšãããŠããã代çšã®åæç©
質ã䜿çšã§ããã æš¹èã¯éåžžããªãªã¬ãã€ã³ãããšãã°ããªãšã
ã¬ã³ã§ãããæš¹èãã³ãŒãã€ã³ã°ããããŒã¹ããŒ
ããŒãåæ¥çã«æåããåå ã¯ãã®ç©è³ªã«ãããš
ããã倧ãããé žåããªãŠã ãã³ãŒãã€ã³ã°ãã
ããŒã¹ããŒããŒïŒãã©ã€ã¿çŽïŒãšã¯éã€ãŠããã
ãã¯æ°Žåã³åççšååŠåŠç液ã«å¯ŸããŠäžæµžéæ§ã§
ãããåŸã€ãŠãããã¯ä¹Ÿç¥æéãçããããã®çµ
æè¿ éã«åŠçã§ãããããã«ãããã¯åŠçè¬å€ã®
䜿çšãå°ãªããŠæžã¿ãåŸã€ãŠå€åœ¢ããããšãã»ãš
ãã©ãªãããããã®ç¹åŸŽã¯ããã¬ãŒããžã¿ã€ãã®
åçãç¹ã«çœé»åçã®å Žåããé·æéåŠç液ã«æµž
挬ããå¿ èŠãããã«ã©ãŒããªã³ãã«ãšã€ãŠéåžžã«
éèŠãªç¹æ§ã§ãããããããªãããæš¹èãã³ãŒã
ã€ã³ã°ããããŒã¹ããŒããŒãã補é ããåççšå°
ç»çŽã¯åšå²ã®æ¡ä»¶ã®å€åã«é·æéãããããå Ž
åãç»å圢æå±€åã³æš¹èå±€ã¯å€è³ªããŠå²ç®ãçã
ãŠçŸèŠ³ãæããããã²ã©ãå Žåã«ã¯å²ç®ãå°ç»çŽ
ã®å šé¢ã«åãã§ç»åãå®å šã«æå·ãããããšãã
ãããããã®å²ç®ãçããã®ã«ã¯äžè¬ã«æ°ã±æã
å Žåã«ãã€ãŠã¯æ°å¹Žãããããå°ç»çŽãåºããªã
ã€ã¹ã®ã·ãšãŠãŠã€ã³ããŠãªã©ã®èé ·ãªæ¡ä»¶äžã«ã
ãããå Žåã«ã¯å²ç®ãçããã®ãéãŸããå®éã«
ã·ãšãŠãŠã€ã³ããŠäžã§ã¯å²ç®ã¯æ°é±éã§çããã
ãšããããæš¹èã«æœããè¡šé¢ã®ä»äžãã¯äœã®åœ¹ã«
ãç«ããªãã å²ç®ãçããåºæ¬çåå ã¯ããããªãç¹ããã
ããç»å圢æå±€ãšæš¹èå±€ãšã®éã®ç©çççžäºäœçš
ã«ãããšããã倧ãããšèããããŠãããäžè¬ã«
èªãããŠãã説ã«ããã°ã枩床åã³æ¹¿åºŠãªã©ã®åš
å²ã®æ¡ä»¶ã®å€åã«å¿ããŠç»å圢æå±€ãšæš¹èå±€ãšã®
éã§èšè¹åã³åçž®ã®åºŠåã«å·®ãçããããã§ãã
ããšèããããŠãããæè¿ã®å°ç»çŽã§ã¯ãã®ãã
ãªåã®å·®ãçããŠãæš¹èã³ãŒãã€ã³ã°ã«ãã€ãŠè
ããããã«ãªã€ãŠããã®ã§å²ç®ã¯çããªãããã
ããªãããæãçµãã«åŸã€ãŠãæš¹èã¯å åã³ïŒå
ã¯ç±ãªã©ã®äœçšã«ãã€ãŠå£åããåŸåãããã
åŸã ã«ããããªãããããªããšæš¹èã¯åã®å·®ã«è
ããããªããªããç»å圢æå±€ãŸãã¯ç»å圢æå±€å
ã³æš¹èå±€ã®äž¡æ¹ã«å²ç®ãçãå§ããããã®ãã
ã«ãæš¹èå±€ã®å®å®æ§ã¯æ¯èŒçäœãããã«ãæš¹èã
æ¯æäœäžã«ã³ãŒãã€ã³ã°ããåã«å®å®å€ãæš¹èã«
çŽæ¥ã«æ··å ¥ããããšãè©Šã¿ããããããããåé¡
ããã€ãããããã®åé¡ã¯æš¹èãšããŒããŒãšã«é
ã®æ¥çåãäœäžããããšåã³æŒåºã³ãŒãã€ã³ã°æ
äœäžå®å®å€ãç±çã«å€è³ªããŠæš¹èã®å質ãå£äžã
ããããšãªã©ã§ããã ãããã®åé¡ãå æããããã«çŽæ¯æäœã«å®å®
å€ãæ··å ¥ããããå®å®å€ãæ¯æäœäžã«ã³ãŒãã€ã³
ã°ããæ¹æ³ãéçºããããäž¡æ¹ã®å Žåãšããå®å®
å€ã¯ãããåŸæœãããæš¹èå±€ã«ç§»åããããã«ã
ã€ãŠå²ç®ãçããªãããã«ãããã®ã§ãªããã°ãª
ããªãããã®æ¹æ³ã«ãã€ãŠäžå¿æš¹èã®çŽæ¯æäœãž
ã®æ¥çåãäœäžãããããšãªããæš¹èã³ãŒãã€ã³
ã°ã®å質ã«æ¯éãæ¥ããããšãªãå²ç®ãé²æ¢ã§ã
ãããå®å®å€ã¯é«äŸ¡ãªç©è³ªã§ããããã®æ¹æ³ïŒè±
åœç¹èš±ç¬¬1361219å·åç §ïŒã¯ããªãã®éãæ¶è²»ã
ãã®ã§ããã®æ¹æ³ãæºè¶³ãã¹ããã®ã§ã¯ãªãã æš¹èã³ãŒãã€ã³ã°äžã«ããçš®ã®å®å®å€ã䜿çšã
ãããšã«ãã€ãŠå²ç®ãå®è³ªçã«é²æ¢ã§ããããšã
æ¬çºæã«ãã€ãŠçºèŠããããããã«ãæ¬çºæã®ã
ããã®å®å®å€ã¯æš¹èãæ¯æäœäžã«æŒåºã³ãŒãã€ã³
ã°ããåã«æš¹èãšç°¡äŸ¿ã«æ··åã§ããæ¥çååã³æš¹
èç¹æ§ã«æªåœ±é¿ãåãŒããªããã®ã§ããã æ¬çºæã¯äžèšã®åŒïŒïŒã ïŒäžåŒäžR1ã¯ç«äœé害ã®ããããã·ããšãã«
ã§ãããR2ã¯C1ãC12ã®ã¢ã«ãã«ã§ãããïœã¯ïŒ
ãïŒã§ããïŒã®ååç©ãŸãã¯ãã®å¯Ÿå¿ããããªã¹
ããªããŒãã¢ããªã³ã®éå±å¡©ãå®å®å€ãšããŠå«æ
ããæš¹èã³ãŒãã€ã³ã°ãæããåççšããŒã¹ããŒ
ããŒãæäŸããã ããããã·ããšãã«ã®ç«äœé害ã¯å¥œãŸããã¯ïŒ
å以äžã®çŽéãŸãã¯æåããããéC1ãC12ã¢ã«
ãã«åºãããšãã°C1ãC7åã³C1ãC4ã¢ã«ãã«åºã
æã奜ãŸããã¯ïœâããã«åºã«ãã€ãŠéæãã
ããå¿ èŠã«å¿ããŠããããã·ããšãã«ã¯ãããã
ã·åºã«é£æ¥ããŠäž¡åŽã«ãããã®ïŒåã®åºã«ãã€ãŠ
眮æãããŠãããããããã·åºèªäœã¯ããšãã«ç°
ã®ãã©ã®äœçœ®ã«äœçœ®ããã®ãæãŸãããR2ã¯å¥œ
ãŸããã¯C1ãC8ãããã«å¥œãŸããã¯C1ãC4ã¢ã«
ãã«åºãããšãã°ãšãã«åºãè¡šãããïœã¯å¥œãŸã
ãã¯ïŒã§ããã以äžãèŠçŽãããšãåŒïŒïŒã«ç€º
ãããç«äœé害ã®ããããã·ããšããŒã«ã瀺ã
R1ã¯ãäŸãã°ïŒâããããã·åºã«çžé£ãïŒïŒïŒ
äœã®ãã¡å°ããšãïŒã€ã®çœ®æåºãçŽéåã¯æåã
ãããã¢ã«ãã«åºãæããïœâããããã·ããšã
ãŒã«åºã«ãã€ãŠä»£è¡šããããšããããšãã§ããã åè¿°ã®ããªã¹ããªããŒãã¢ããªã³ã®éå±å¡©ã¯äž
èšã®åŒïŒïŒ ïŒäžåŒäžãR1ïŒR2åã³ïœã¯åã«å®çŸ©ãããã®
ã§ãããïŒã¯éå±ã«ããªã³ã§ãããïœã¯ïŒãïŒã§
ãããïŒã®åå䟡ã«çããïŒãæãããéå±å¡©ã¯
奜ãŸããã¯å®è³ªçã«ç¡è²ã§ãããïŒã¯å¥œãŸããã¯
ããã±ã«ãŸãã¯ã«ã«ã·ãŠã ã§ãããïœã¯å¥œãŸãã
ã¯ïŒã§ããã åŒïŒïŒã«ãã€ãŠè¡šããããæãæå¹ãªå®å®å€
ã®äŸãšããŠã¯ïŒ¯âãšãã«âïŒïŒïŒâãžâïœâãã
ã«âïŒâããããã·ãã³ãžã«ããªã¹ããªã³é žåã³
ã«ã«ã·ãŠã åã³ããã±ã«ãã¹ïŒïœâãšãã«âïŒïŒ
ïŒâãžâïœâããã«âïŒâããããã·ãã³ãžã«ã
ãªã¹ããªããŒãïŒãããã äŸãã°äžèšã®ïŒ¯âãšãã«âïŒïŒïŒâãžâïœâã
ãã«âïŒâããããã·ãã³ãžã«ããªã¹ããªã³é žã
äžèšã®æ§é åŒã§ç€ºãã å®å®å€åŒïŒïŒè£œé æ³ã¯å ¬ç¥ã§ãããéé¢é žã¯
é©åœãªããã²ã³åããããã·ã¢ã©ã«ãã«ã第ïŒã
ãªã¹ãã¢ã€ããšåå¿ãããããšã«ãã€ãŠè£œé ã§ã
ãããã®éé¢é žã¯ãããåŸå¿ èŠã«å¿ããŠéå±å¡©å
ç©ãªã©ã®é©åœãªéå±èªå°äœãšåå¿ãããããšã«ã
ã€ãŠéå±å¡©ã«è»¢åããŠãè¯ãããããã¯éå±å¡©ã®
ãããã®ã¯åžè²©ãããŠããããã®ãŸãŸäœ¿çšããŠã
è¯ãããå¡©é žãªã©ã䜿çšããŠéé¢é žã«æ»ããŠãè¯
ãããã®ããã«ããŠåŸãããéé¢é žã¯ãããåŸæ¬
çºæã§ãã®ãŸãŸäœ¿çšããŠãè¯ãããä»ã®éå±å¡©ã«
転åããããã®åºçºåæãšããŠäœ¿çšããŠãè¯ãã æ¬çºæã§äœ¿çšãããå®å®å€ã¯åççšå°ç»çŽãé·
æéå²ç®ã®çããªãç¶æ ã«ä¿ã¡ããã®å¹æã¯åç
åŠçå·¥çšäžã«éåžžééããåºç¯å²ã®æªæ¡ä»¶ã«ãã
ããŠãè¡°ããªãã åççšããŒã¹ããŒããŒã¯éåžžã¯ã€ã€åŽïŒè£ïŒå
ã³è¡šé¢åŽïŒè¡šïŒã®äž¡æ¹ã«æš¹èã³ãŒãã€ã³ã°ãæã
ããæ¬çºæã®åŒïŒïŒã®å®å®å€ã®å©ç¹ã¯è¡šé¢åŽã³
ãŒãã€ã³ã°å ããå®è³ªçã«ç§»åããªãããšã§ã
ããæš¹èãã³ãŒãã€ã³ã°ããåççšããŒã¹ããŒã
ãŒã¯éåžžãªãŒã«ã«å·»ããããã®ãŸãŸé·æé貯èµã
ããã®ã§ãã®ããšã¯æ¬çºæã®éèŠãªç¹åŸŽã§ããã
ãã®ãããªç¶æ ã§ã¯è¡šé¢åŽïŒè¡šïŒãšã¯ã€ã€åŽ
ïŒè£ïŒãšã¯æ¥è§ŠããŠããã®ã§ç§»åæ§å®å®å€ã ãšå²
ç®ã®çºçãé²æ¢ããå¿ èŠã®ãªãã¯ã€ã€åŽæš¹èã³ãŒ
ãã€ã³ã°ã«ç§»åããŠããŸããããããªãããåŒ
ïŒïŒã®å®å®å€ã¯å®è³ªçã«é移åæ§ã§ããã®ã§ã
ã®ãããªåé¡ã¯çããªãã æ¬çºæã®å®å®å€ã®äœ¿çšéã¯åºç¯å²ã«ããããã
äžè¬ã«æäœã®æå¹äœ¿çšéã¯æš¹èã®ééã®çŽ0.01ïŒ
ã§ããããã以äžå ããŠãå²ç®é²æ¢å¹æã«å€åã
äžããªãæ倧䜿çšéã®æš¹èã®ééã®çŽïŒïŒ ã§ã
ããäžè¬ã«0.2ã0.5ééïŒ ãå²ç®ã«å¯ŸããŠéåžžã«
æçšãªé²æ¢å¹æãæäŸããã æ¬çºæã®åççšããŒã¹ããŒããŒã®æš¹èã³ãŒãã€
ã³ã°ã«ã¯åèšåŒã®å®å®å€ã®ä»ã«ãå¥ã®ã¿ã€ãã®å®
å®å€ãå ããŠãè¯ããããšãã°ãåŒïŒïŒã®å®å®
å€ã®äºè£é²æ¢å¹æã«çžä¹äœçšãä»äžããå®å®å€ã®
䜿çšã奜ãŸããããã®ãããªçžä¹äœçšãä»äžãã
å®å®å€ã®äŸãšããŠã¯å å®å®å€ãããšãã°ç«äœé害
ã¢ãã³ãããããã®çš®ã®å å®å®å€ã¯åéäœããŸã
ã¯å¥œãŸããã¯éåäœã§ãããåéäœã®ç«äœé害ã¢
ãã³å å®å®å€ã®äŸãšããŠã¯ãã¹ïŒïŒïŒïŒïŒïŒïŒïŒ
âããã©ã¡ãã«âïŒâãããªãžãã«ïŒã»ãã±ãŒã
ããããããã¯âTinuvin770âã®åååã§Ciba
âGeigy瀟ã«ãã€ãŠåžè²©ãããŠããã奜ãŸããæ¹
ã®éåäœã®ç«äœé害ã¢ãã³å å®å®å€ã®äŸãšããŠã¯
åååâTinuvin622âåã³âChimassorb994â
ãšããŠCibaâGeigy瀟åã³Chimosa瀟ããããã
ãåžè²©ãããŠãããã®ããããç«äœé害ã¢ãã³å
å®å®å€ãæ¬çºæã§äœ¿çšããããšã¯å©ç¹ãããã æ¬çºæã®æš¹èã³ãŒãã€ã³ã°ã¯åŸæ¥ã®æ·»å å€ãã
ãšãã°äºé žåãã¿ã³ãé žåäºéãç¡«é žããªãŠã ã
äžé žåã¢ã³ãã¢ã³åã³ã«ãŒãã³ãã©ãã¯ãªã©ã®é¡
æïŒææïŒâUvitexOBâïŒCibaâGeigy瀟ïŒãªã©
ã®å åŠçå¢çœå€ïŒåã³éé»é²æ¢å€ãªã©ãå«æããŠ
ãè¯ããåœç¶ã®ããšãªãããå å®å®å€åã³å åŠç
å¢çœå€ã®äž¡æ¹ã䜿çšããå Žåã«ã¯ãåãæ³¢é·ã®å
ã®ç«¶åãé¿ããŠå¹æãæé«ã«ããããã«éã€ãæ³¢
é·åã§åžåãè¡ãããã«ããå¿ èŠãããã æš¹èèªäœã¯éåžžããªãªã¬ãã€ã³ã奜ãŸããã¯ã
ãªãšãã¬ã³ã§ãããçš®ã ã®è¡šé¢ä»äžããããšãã°
å æ²¢ä»äžããè·æ¶ä»äžããã·ã«ã¯ä»äžããç¹ææš¡
æ§ä»äžãããã©ãããã»ã°ã¬ãŒã³ä»äžãåã³è·åº
ä»äžããå¯èœã§ããã æ¬çºæã¯ããã«åèšåŒïŒïŒã®ååç©ãŸãã¯ã
ã®éå±å¡©ã®å®å®å€ãæš¹èæ··åç©ã«æ··å ¥ããåèšæš¹
èæ··åç©ãããŒã¹ããŒããŒäžã«æŒåºãã³ãŒãã€ã³
ã°ããå·¥çšãå«ãåççšããŒã¹ããŒããŒã®è£œé æ¹
æ³ãæäŸãããã®ã§ããã æå æ§ãä»äžããåã«ãæš¹èã³ãŒãã€ã³ã°ãã
ãåççšããŒã¹ããŒããŒã¯ç»å圢æå±€ãšæš¹èå±€ãš
ã®éã®æ¥çã匷åºãšãªãããã«éåžžã³ããåŠçã
ããããã®ãããªã³ããåŠçã¯åççšããŒã¹ããŒ
ããŒè£œé æ¥è ã«ãã€ãŠäžè¬ã«è¡ãããæå å€ãç»
å圢æå±€ã«æœããããŸã§ãã®åŠçãä¿è·ãããã
ã«ãåŠçãããæš¹èã¯è±åœç¹èš±ç¬¬1134211å·ã«èš
èŒãããŠããããã«æ¥çåäœäžé²æ¢æº¶æ¶²ã§çŽã¡ã«
ã³ãŒãã€ã³ã°ããã®ãæãŸããã æ¬çºæã¯äžèšã®å®æœäŸã«ãã€ãŠããã«è©³ãã説
æããããã®è£œåãããã€ãã®äžèšã®ãã¹ãã«ã
ããã  äºè£ãå²ç®ãã¹ã æš¹èãã³ãŒãã€ã³ã°ããçŽãããŒã©ãã³ã¹ãŒã
ãŒã³ãŒããæããã¯ããïŒãããã€ããšãã«ãžãš
ã³ã䜿çšããŠãšãã«ãžãšã³ã³ãŒãã€ã³ã°ãããé²
å åŸããã®åççšããŒããŒãäžèšã®æ§ã«åŠçã
ãã çŸ å ïŒå å® ç 1/2å æŽ æµ ïŒå é²å ããŠçŸåãããµã³ãã«ãIlfospeed4250ã
ã©ã€ã€ãŒã䜿çšããŠä¹Ÿç¥ãããã®çµæåŸãããå
çããã€ããã«å ¥ããäžèšã®æ¡ä»¶äžã§æ宀åã³æ
宀ã®ãµã€ã¯ã«ã亀äºã«ç¹°è¿ããã æ宀ãµã€ã¯ãïŒïŒæéïŒ 70ã80âïŒæé«ïŒ çžå¯Ÿæ¹¿åºŠïŒ15ïŒ æ宀ãµã€ã¯ã«ïŒïŒæéïŒ 30âïŒæäœïŒ çžå¯Ÿæ¹¿åºŠïŒ80ïŒ å ã¯ãã€ããããã®éæãªé éšãã50cmé¢ãã
äœçœ®ã«çœ®ãããïŒåã®150Wã®Osramåççšã©ã³
ãããçºçããããã€ãããããžã®ç©ºæ°æµã¯æ宀
ãµã€ã¯ã«ã®å ŽåïŒãªããã«ïŒåã§ãããæ宀ãµã€
ã¯ã«ã®å Žå10ãªããã«ïŒåã§ãã€ãã ãããåŸãåçç»åãå®å šã«æå·ãããŸã§ãã
ãªãã¡ãšãã«ãžãšã³åã³æš¹èå±€ã®äž¡æ¹ãäºè£ãç
ããŠåçç»åäžã®æ å ±ã倱ãããããã«ãªããŸã§
ã®æéã枬å®ããã  å èåãã¹ã ããªãšãã¬ã³ãå£åããã«åŸã€ãŠãé žåãèµ·
ããã«ã«ããã«åºãçæãããåŸã€ãŠã«ã«ããã«
åžåã枬å®ããããšã«ãã€ãŠå£åã®çšåºŠããã
ããé²å åãé²å äžåã³é²å åŸãäœåããã®ãã
ãªæž¬å®ãè¡ãããšã«ãã€ãŠäºè£é²æ¢èœåãããã
ã©ããããããã ããã§ãæš¹èã®ã³ãŒãã€ã³ã°ãããçŽããã»ã
ã³ç¯èåè©Šéšè£ 眮ïŒ150WeatherometerïŒäžã§å
èš400æéé²å ãããè£ çœ®äžã§ã®æ¡ä»¶ã¯25âã§çž
察湿床ã50ïŒ ã§ãã€ãããã®æž¬å®ã¯è©Šéšæéäžé²
å ã®ååŸã§èµ€å€ç·åå èšã®1710cm-1ã®æ³¢é·ã«ãã
ããµã³ãã«ã®åžåã枬å®ããããšããæã€ããã
ããåŸãé²å æéã«å¯Ÿããã«ã«ããã«åžåã®å¢å
ãã°ã©ãã«ãããããããã®ã°ã©ãããã«ã«ãã
ã«åžåãæªé²å æš¹èã³ãŒãã€ã³ã°çŽãã0.1å¢å
ããæã®æéãèªåã€ãã  é°éšã®å£åãã¹ã æš¹èã³ãŒãã€ã³ã°ããçŽã105âã§72æé埪ç°
空æ°åã®çã®äžã§ç±ã§èåããããé°éšã®å£åå€
ã¯å£åãã¹ãã®ååŸã§430nïœã®æ³¢é·ã«ããããµ
ã³ãã«ïŒäžå®ã®é»çŽäœ¿çšïŒã®åå°çã枬å®ããã
ã®å·®ããå²åºãããåå°çã®æž¬å®ã¯Pretema
FS3Aã¹ãã¯ãããããã䜿çšããŠè¡ã€ãã  æ¥çåãã¹ã æš¹èå±€ãšããŒã¹ããŒããŒãšã®æ¥çåã枬å®ãã
ãã®çµæãïŒãïŒã®ïŒæ®µéã«è©äŸ¡ããè¯å¥œãªæ¥ç
ã¯äœãæ°åã§ç€ºããæªãæ¥çã¯é«ãæ°åã§ç€ºã
ãã äŸ ïŒ æ¯èŒäŸãšããŠè¡šé¢åŽïŒè¡šïŒæš¹èæ··åç©ãäžèšã®
æåãã調補ããã äœå¯åºŠããªãšãã¬ã³äžTiO250ïŒ ïŒKg äœå¯åºŠããªãšãã¬ã³äžUvitexOB2ïŒ ïŒKg äœå¯åºŠããªãšãã¬ã³ 29.5Kg ãã®çµæåŸãããæ··åç©ããããåŸ30.5ïœïŒå
ïŒ100ãã€ãŒãïŒåïŒã®æ©æ¢°é床ã§178ïœïŒm2ã®é
éã®ããŒã¹ããŒããŒäžã«ã³ãŒãã€ã³ã°ãããæŒåº
溶è枩床ã¯300ã320âã§ãã®çµæåŸãããã³ãŒã
ã€ã³ã°ã®ééã¯40ïœïŒm2ã§ãã€ãããã®åŸæ¥ã®æš¹
èãã³ãŒãã€ã³ã°ããåççšããŒã¹ããŒããŒã«ã€
ããŠã®ãã¹ãçµæãäžèšã®è¡šïŒã«ç€ºãã äŸ ïŒ æš¹èã®ééã®0.25ã0.5ïŒ ã®ããã±ã«ãã¹â
ïŒïœâãšãã«ïŒïŒïŒâãžâïœâããã«âïŒâãã
ããã·ãã³ãžã«ããªã¹ããªããŒãïŒã§ãã
Irgastab2002HTïŒCibaâGeigyïŒãæš¹èæ··åç©ã«
å ãã以å€ã¯äŸïŒãšåãæé ãç¹°è¿ãããåæ§ã«
äžèšã®è¡šïŒã«ç€ºãããããªä»ã®ã¿ã€ãã®å®å®å€ã
å¥ã®æš¹èæ··åç©ã«å ããïŒæš¹èã®ééã«å¯Ÿãã
ïŒ ïŒããã®çµæãäžèšã®è¡šïŒã«ç€ºãã äŸ ïŒ ã«ã«ã·ãŠã ãã¹âïŒïœâãšãã«âïŒïŒïŒâãžâ
ïœâããã«âïŒâããããã·ãã³ãžã«ããªã¹ããª
ããŒãïŒã§ããIrgastab1425ïŒCibaâGeigyïŒã
æš¹èã®ééã®0.05ã0.25ïŒ å ãã以å€ã¯äŸïŒãšå
ãæé ãç¹°è¿ãããåæ§ã«äžèšã®è¡šïŒã«ç€ºããã
ããªä»ã®ã¿ã€ãã®å®å®å€ãå¥ã®æš¹èæ··åç©ã«å ã
ãïŒæš¹èã®ééã«å¯ŸããïŒ ïŒããã®çµæãäžèšã®
è¡šïŒã«ç€ºãã
ãè¡šã
äŸ ïŒ
æ¯èŒäŸãšããŠè¡šé¢åŽæš¹èæ··åç©ãäžèšã®æåã
ã調補ããã äœå¯åºŠããªãšãã¬ã³äžTiO250ïŒ 14Kg äœå¯åºŠããªãšãã¬ã³äžUvitexOB2ïŒ 2.5Kg äœå¯åºŠããªãšãã¬ã³ 58.5Kg ãã®çµæåŸãããæ··åç©ãæ©æ¢°é床ã79.3ïœïŒ
åïŒ260ãã€ãŒãïŒïœïŒã«ãã以å€ã¯äŸïŒãšåã
æé ã§ã³ãŒãã€ã³ã°ããããã®æš¹èãã³ãŒãã€ã³
ã°ããããŒããŒããããåŸãšãã«ãžãšã³ã³ãŒãã€
ã³ã°ããŠåŠçããè©ŠéšãããåŸãããçµæãè¡šïŒ
ã«ç€ºãã äŸ ïŒ ä»ã®ç©è³ªãé©å®äœ¿çšãã0.2ïŒ ã®
Irgastab2002HTãæ·»å ãã以å€ã¯äŸïŒãšåãæ
é ãïŒåç¹°è¿ãããåŸãããçµæãè¡šïŒã«ç€ºãã
ã調補ããã äœå¯åºŠããªãšãã¬ã³äžTiO250ïŒ 14Kg äœå¯åºŠããªãšãã¬ã³äžUvitexOB2ïŒ 2.5Kg äœå¯åºŠããªãšãã¬ã³ 58.5Kg ãã®çµæåŸãããæ··åç©ãæ©æ¢°é床ã79.3ïœïŒ
åïŒ260ãã€ãŒãïŒïœïŒã«ãã以å€ã¯äŸïŒãšåã
æé ã§ã³ãŒãã€ã³ã°ããããã®æš¹èãã³ãŒãã€ã³
ã°ããããŒããŒããããåŸãšãã«ãžãšã³ã³ãŒãã€
ã³ã°ããŠåŠçããè©ŠéšãããåŸãããçµæãè¡šïŒ
ã«ç€ºãã äŸ ïŒ ä»ã®ç©è³ªãé©å®äœ¿çšãã0.2ïŒ ã®
Irgastab2002HTãæ·»å ãã以å€ã¯äŸïŒãšåãæ
é ãïŒåç¹°è¿ãããåŸãããçµæãè¡šïŒã«ç€ºãã
ãè¡šã
äŸ ïŒ
æ¯èŒäŸãšããŠè¡šé¢åŽæš¹èæ··åç©ãäžèšã®æåã
ã調補ããã äœå¯åºŠããªãšãã¬ã³äžTiO250ïŒ ïŒKg äœå¯åºŠããªãšãã¬ã³äžUvitexOB2ïŒ 0.67Kg äœå¯åºŠããªãšãã¬ã³ 19.33Kg ãã®çµæåŸãããæ··åç©ãäŸïŒãšåæ§ã«ã³ãŒã
ã€ã³ã°ãããåŸããããã¹ãçµæãäžèšã®è¡šïŒã«
瀺ãã äŸ ïŒ æš¹èæ··åç©ã«Irganox1425åã³Tinuvin622ãå
ãã以å€ã¯äŸïŒãšåãæé ãç¹°è¿ããã ãã¹ãçµæãè¡šïŒã«ç€ºãã äŸ ïŒ æš¹èæ··åç©ã«Irgastab2002HTåã³Tinuvin770
ãå ãã以å€ã¯äŸïŒãšåãæé ãç¹°è¿ããã ãã¹ãçµæãè¡šïŒã«ç€ºãã
ã調補ããã äœå¯åºŠããªãšãã¬ã³äžTiO250ïŒ ïŒKg äœå¯åºŠããªãšãã¬ã³äžUvitexOB2ïŒ 0.67Kg äœå¯åºŠããªãšãã¬ã³ 19.33Kg ãã®çµæåŸãããæ··åç©ãäŸïŒãšåæ§ã«ã³ãŒã
ã€ã³ã°ãããåŸããããã¹ãçµæãäžèšã®è¡šïŒã«
瀺ãã äŸ ïŒ æš¹èæ··åç©ã«Irganox1425åã³Tinuvin622ãå
ãã以å€ã¯äŸïŒãšåãæé ãç¹°è¿ããã ãã¹ãçµæãè¡šïŒã«ç€ºãã äŸ ïŒ æš¹èæ··åç©ã«Irgastab2002HTåã³Tinuvin770
ãå ãã以å€ã¯äŸïŒãšåãæé ãç¹°è¿ããã ãã¹ãçµæãè¡šïŒã«ç€ºãã
ãè¡šã
äŸ ïŒ
äŸïŒã®æé ãïŒåç¹°è¿ãããã®ãã¡ïŒåç®ã¯äŸ
ïŒãšå šãåãã§ãããïŒåç®ã¯æš¹èæ··åç©ã«ïœâ
ãšãã«âïŒïŒïŒâãžâïœâããã«âïŒâãããã
ã·ãã³ãžã«ããªã¹ããªã³é žãå ãããåŸãããçµ
æãè¡šïŒã«ç€ºãã
ïŒãšå šãåãã§ãããïŒåç®ã¯æš¹èæ··åç©ã«ïœâ
ãšãã«âïŒïŒïŒâãžâïœâããã«âïŒâãããã
ã·ãã³ãžã«ããªã¹ããªã³é žãå ãããåŸãããçµ
æãè¡šïŒã«ç€ºãã
ãè¡šã
åèšçµæããæãããªããã«ãäºè£ã¯æš¹èã³ãŒ
ãã€ã³ã°äžã«åŒïŒïŒã®å®å®å€ãååšããããšã«
ãã€ãŠé²æ¢ããããäºæ³ã«åããŠå®å®å€ã¯æš¹èâ
ããŒã¹ããŒããŒéã®æ¥çååã³æš¹èã³ãŒãã€ã³ã°
ã®å質ã«æªåœ±é¿ãåãŒãããšãªããæš¹èæ··åç©ã«
çŽæ¥ã«æ··å ¥ã§ããããšãããã€ãã
ãã€ã³ã°äžã«åŒïŒïŒã®å®å®å€ãååšããããšã«
ãã€ãŠé²æ¢ããããäºæ³ã«åããŠå®å®å€ã¯æš¹èâ
ããŒã¹ããŒããŒéã®æ¥çååã³æš¹èã³ãŒãã€ã³ã°
ã®å質ã«æªåœ±é¿ãåãŒãããšãªããæš¹èæ··åç©ã«
çŽæ¥ã«æ··å ¥ã§ããããšãããã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ R1ã¯ïŒâããããã·åºã«çžé£ãïŒïŒïŒäœã®
ãã¡ã®å°ããšãïŒã€ã®çœ®æåºãçŽéåã¯æåãã
ããã¢ã«ãã«åºã§ããïœâããããã·ããšããŒã«
åºã§ãããR2ã¯C1ãC12ã®ã¢ã«ãã«åºã§ãããïœ
ã¯ïŒãïŒã§ãããšããäžèšã®åŒïŒïŒã®ååç©ã åã¯åèšåŒïŒïŒã®ååç©ã«å¯Ÿå¿ããããªã¹ã
ãªããŒãã¢ããªã³ã®éå±å¡© ãå®å®å€ãšããŠå«æããæš¹èã³ãŒãã€ã³ã°ãæã
ãåççšããŒã¹ããŒããŒã ïŒ ïŒã¯éå±ã«ããªã³ã§ãããïœã¯ïŒãïŒã§åèš
ïŒã®åå䟡ã«çããå€ã§ãããšããäžèšã®åŒ
ïŒïŒ ã®åèšéå±å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
åççšããŒã¹ããŒããŒã ïŒ çŽéåã¯æåããããã¢ã«ãã«åºã¯C1ãC12
ã¢ã«ãã«åºã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒ
é èšèŒã®åççšããŒã¹ããŒããŒã ïŒ åèšã¢ã«ãã«åºãC1ãC4ã¢ã«ãã«åºã§ãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åççšããŒã¹ããŒã
ãŒã ïŒ åèšã¢ã«ãã«åºãïœâããã«åºã§ããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åççšããŒã¹ããŒããŒã ïŒ åèšR1ã¯ããããã·åºäž¡åŽã«é£æ¥ããïŒå
ã®ã¢ã«ãã«åºã§çœ®æãããŠããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã第ïŒé ã®ããããã«èšèŒã®åççšããŒã¹ã
ãŒããŒã ïŒ R2ãC1ãC8ã¢ã«ãã«åºã§ããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé ã第ïŒé ã®ããããã«èšèŒã®åççšããŒ
ã¹ããŒããŒã ïŒ R2ããšãã«åºã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé
èšèŒã®åççšããŒã¹ããŒããŒã ïŒ ïœãïŒã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé
ã®ããããã«èšèŒã®åççšããŒã¹ããŒããŒã ïŒïŒ åèšå®å®å€ãâãšãã«âïŒïŒïŒâãžâïœ
âããã«âïŒâããããã·ãã³ãžã«ããªã¹ããªã³
é žã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åççšããŒ
ã¹ããŒããŒã ïŒïŒ ïŒãããã±ã«ãŸãã¯ã«ã«ã·ãŠã ã§ããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åççšããŒã¹ããŒããŒã ïŒïŒ åèšå®å®å€ãã«ã«ã·ãŠã ãŸãã¯ããã±ã«ã
ã¹ïŒïŒ¯âãšãã«âïŒïŒïŒâãžâïœâããã«âïŒâ
ããããã·ãã³ãžã«ããªã¹ããªããŒãïŒã§ããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®åççšããŒã¹ããŒã
ãŒã ïŒïŒ åèšå®å®å€ãæš¹èã®0.01ãïŒééïŒ ã®éã§
ååšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ãã
ããã«èšèŒã®åççšããŒã¹ããŒããŒã ïŒïŒ åèšå®å®å€ãæš¹èã®0.2ã0.5ééïŒ ã®éã§
ååšããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®åççšã
ãŒã¹ããŒããŒã ïŒïŒ åèšæš¹èã³ãŒãã€ã³ã°ãåéäœã®ããŸãã¯
éåäœã®ç«äœé害ã®ã¢ãã³å å®å®å€ãå«æããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ããããã«èšèŒ
ã®åççšããŒã¹ããŒããŒã ïŒïŒ åèšå å®å®å€ããã¹ïŒïŒïŒïŒïŒïŒïŒïŒâã
ãã©ã¡ãã«âïŒâãããªãžãã«ïŒã»ãã±ãŒãã§ã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®åççšããŒã¹ã
ãŒããŒã ïŒïŒ åèšæš¹èã³ãŒãã€ã³ã°ãäºé žåãã¿ããŠã
ãå«æããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ã
ãããã«èšèŒã®åççšããŒã¹ããŒããŒã ïŒïŒ åèšæš¹èã³ãŒãã€ã³ã°ãå åŠçå¢çœå€ãå«
æããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ããã
ãã«èšèŒã®åççšããŒã¹ããŒããŒã ïŒïŒ åèšæš¹èãããªãªã¬ãã€ã³ã奜ãŸããã¯ã
ãªãšãã¬ã³ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒ
é ã®ããããã«èšèŒã®åççšããŒã¹ããŒããŒã ïŒïŒ åèšæš¹èã³ãŒãã€ã³ã°ãã³ããåŠçãããŠ
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ãããã
ã«èšèŒã®åççšããŒã¹ããŒããŒã ïŒïŒ åèšåŠçãããŠããæš¹èã³ãŒãã€ã³ã°ã«æ¥
çåäœäžé²æ¢æº¶æ¶²ãæœãããŠããç¹èš±è«æ±ã®ç¯å²
第ïŒïŒé èšèŒã®åççšããŒã¹ããŒããŒã ïŒïŒ R1ã¯ïŒâããããã·åºã«çžé£ãïŒïŒïŒäœ
ã®çœ®æåºãçŽéåã¯æåããããã¢ã«ãã«åºã§ã
ãïœâããããã·ããšãã«åºã§ãããR2ã¯C1ã
C12ã®ã¢ã«ãã«åºã§ãããïœã¯ïŒãïŒã§ãããšãã
äžèšã®åŒïŒïŒã®ååç©ã åã¯åèšåŒïŒïŒã®ååç©ã«å¯Ÿå¿ããããªã¹ã
ãªããŒãã¢ããªã³ã®éå±å¡©ãå®å®å€ãšããŠå«æã
ãæš¹èã³ãŒãã€ã³ã°ãæããåççšããŒã¹ããŒã
ãŒåã³åèšæš¹èã³ãŒãã€ã³ã°ã«æ¥çãããŠããç»
å圢æå±€ãæããåççšå°ç»çŽã ïŒïŒ åèšç»å圢æå±€ããšãã«ãžãšã³ã³ãŒãã€ã³
ã°ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®åççšå°
ç»çŽã ïŒïŒ R1ã¯ïœâããããã·åºã«çžé£ãïŒïŒïŒäœ
ã®çœ®æåºãçŽéåã¯æåããããã¢ã«ãã«åºã§ã
ãïœâããããã·ããšãã«åºã§ãããR2ã¯C1ã
C12ã®ã¢ã«ãã«åºã§ãããïœã¯ïŒãïŒã§ãããšãã
äžèšã®åŒïŒïŒã®ååç©ã åã¯åèšåŒïŒïŒã®ååç©ã«å¯Ÿå¿ããããªã¹ã
ãªããŒãã¢ããªã³ã®éå±å¡©ã®å®å®å€ãæš¹èæ··åç©
ã«æ··å ¥ããåèšæš¹èæ··åç©ãããŒã¹ããŒããŒäžã«
æŒåºãã³ãŒãã€ã³ã°ããå·¥çšãå«ãåççšããŒã¹
ããŒããŒã®è£œé æ¹æ³ã
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB7913740 | 1979-04-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55142335A JPS55142335A (en) | 1980-11-06 |
JPH0215858B2 true JPH0215858B2 (ja) | 1990-04-13 |
Family
ID=10504666
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5181880A Granted JPS55142335A (en) | 1979-04-20 | 1980-04-21 | Photography base paper |
Country Status (12)
Country | Link |
---|---|
US (1) | US4562145A (ja) |
JP (1) | JPS55142335A (ja) |
BE (1) | BE882751A (ja) |
CH (1) | CH645195A5 (ja) |
DE (1) | DE3015023A1 (ja) |
DK (1) | DK165380A (ja) |
ES (1) | ES490691A0 (ja) |
FR (1) | FR2454643B1 (ja) |
IT (1) | IT1145336B (ja) |
NL (1) | NL8002242A (ja) |
NO (1) | NO801113L (ja) |
SE (1) | SE8002855L (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1984001628A1 (en) * | 1982-10-12 | 1984-04-26 | Eastman Kodak Co | Imaging elements containing pigmented layers |
JPS63314539A (ja) * | 1987-06-17 | 1988-12-22 | Fuji Photo Film Co Ltd | æå ææ |
US5998119A (en) * | 1998-08-27 | 1999-12-07 | Eastman Kodak Company | Imaging element with a substrate containing low molecular weight hindered amine stabilizer |
US6171751B1 (en) | 1998-08-27 | 2001-01-09 | Eastman Kodak Company | Imaging element with hindered amine stabilizer in the base |
US6080534A (en) * | 1998-08-27 | 2000-06-27 | Eastman Kodak Company | Imaging element with a substrate containing hindered amine stabilizer |
US6824936B1 (en) | 2003-08-05 | 2004-11-30 | Eastman Kodak Company | Hindered amine light stabilizer for improved yellow dark stability |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3607345A (en) * | 1958-04-26 | 1971-09-21 | Eastman Kodak Co | Process for coating photographic emulsion layers |
NL277231A (ja) * | 1961-04-14 | |||
GB1033258A (en) * | 1963-10-22 | 1966-06-22 | Toyo Rayon Co Ltd | Stabilized polymers of propylene |
GB1134211A (en) * | 1964-11-17 | 1968-11-20 | Wiggins Teape Res Dev | Improvements in or relating to photographic materials |
DE1696264B2 (de) * | 1966-03-31 | 1974-06-20 | Fa. Felix Schoeller Jun., 4500 Osnabrueck | Verfahren zur Herstellung lichtundurchlÀssiger Papiere fÌr fotografische Zwecke |
US3501298A (en) * | 1966-04-08 | 1970-03-17 | Eastman Kodak Co | Photographic papers |
US3525621A (en) * | 1968-02-12 | 1970-08-25 | Eastman Kodak Co | Antistatic photographic elements |
US3582339A (en) * | 1968-10-30 | 1971-06-01 | Eastman Kodak Co | Photographic element |
CA945426A (en) * | 1969-04-08 | 1974-04-16 | Eastman Kodak Company | Antistatic layers for photographic films |
GB1341688A (en) * | 1970-12-01 | 1973-12-25 | Ici Ltd | Insulated conductor |
US3755069A (en) * | 1970-12-14 | 1973-08-28 | Eastman Kodak Co | Highly stable resin coated paper products and method of making same |
US3853592A (en) * | 1970-12-14 | 1974-12-10 | Eastman Kodak Co | Highly stable resin coated paper products and method for making same |
JPS5321168B2 (ja) * | 1973-02-19 | 1978-06-30 | ||
US4115125A (en) * | 1977-05-09 | 1978-09-19 | Eastman Kodak Company | Polymeric films peelably adhered to a pressure-sensitive adhesive photographic element |
-
1980
- 1980-04-11 BE BE0/200195A patent/BE882751A/fr not_active IP Right Cessation
- 1980-04-15 IT IT4842180A patent/IT1145336B/it active
- 1980-04-16 SE SE8002855A patent/SE8002855L/ unknown
- 1980-04-17 CH CH299280A patent/CH645195A5/de not_active IP Right Cessation
- 1980-04-17 NO NO801113A patent/NO801113L/no unknown
- 1980-04-17 NL NL8002242A patent/NL8002242A/nl not_active Application Discontinuation
- 1980-04-18 FR FR8008755A patent/FR2454643B1/fr not_active Expired
- 1980-04-18 DK DK165380A patent/DK165380A/da not_active IP Right Cessation
- 1980-04-18 ES ES490691A patent/ES490691A0/es active Granted
- 1980-04-18 DE DE19803015023 patent/DE3015023A1/de active Granted
- 1980-04-21 JP JP5181880A patent/JPS55142335A/ja active Granted
-
1983
- 1983-06-20 US US06/505,842 patent/US4562145A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US4562145A (en) | 1985-12-31 |
FR2454643B1 (fr) | 1987-07-24 |
CH645195A5 (de) | 1984-09-14 |
SE8002855L (sv) | 1980-10-21 |
NO801113L (no) | 1980-10-21 |
NL8002242A (nl) | 1980-10-22 |
BE882751A (fr) | 1980-07-31 |
IT1145336B (it) | 1986-11-05 |
DK165380A (da) | 1980-10-21 |
JPS55142335A (en) | 1980-11-06 |
IT8048421A0 (it) | 1980-04-15 |
ES8103851A1 (es) | 1981-03-16 |
ES490691A0 (es) | 1981-03-16 |
DE3015023A1 (de) | 1980-11-06 |
DE3015023C2 (ja) | 1987-07-09 |
FR2454643A1 (fr) | 1980-11-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4063952A (en) | Process for hardening silver halide containing photographic layers with sulpho- or sulphoalkyl-substituted carbamoyl pyridinium compounds | |
DE2816226A1 (de) | Photographisches silberhalogenidmaterial mit dem gehalt eines ultraviolettlicht absorbierenden mittels sowie verfahren zur verringerung des effektes von ultraviolettlicht auf das photographische silberhalogenidmaterial | |
US2342546A (en) | Production and use of dyestuffs | |
US3269840A (en) | Method and material for surface brightening layers containing gelatin as the binding agent using anionic water-soluble diaminostilbene fluorescent compounds | |
JPH0128938B2 (ja) | ||
JPH0215858B2 (ja) | ||
JPS6021371B2 (ja) | ããã²ã³åéåçæå ææã®è£œé æ¹æ³ | |
JPS58154838A (ja) | åççšåçŽåã³ãã®è£œé æ¹æ³ | |
US2808330A (en) | Photographic elements containing thiazolidine derivatives | |
JPS643251B2 (ja) | ||
GB2048278A (en) | Photographic Bass Papers | |
JPS6313984B2 (ja) | ||
EP0330401A2 (en) | Method of processing silver halide photographic material | |
DE69322296T2 (de) | Photographisches lichtempfindliches Silberhalogenidmaterial | |
JPS6142654A (ja) | ããã²ã³åéåçæå ææ | |
US3549369A (en) | Antistatic acylhydrazinium salt | |
US4255515A (en) | Photographic films | |
DE821759C (de) | Verfahren zur Herstellung von Diazotypie-Zwischenkopien | |
JPS59149350A (ja) | ããã²ã³åéåçæå ææ | |
US3725074A (en) | Fogged,direct positive silver halide emulsions containing hydroxyphthalein dyes and sulfonated compounds | |
DE1547851C3 (de) | Photographisches Aufzeichnungsmaterial mit einer auf einen SchichttrÀger aufgebrachten spektral sensibilisierten Silberhalogenidemulsionsschicht | |
US2542848A (en) | Diazotypes containing thiobarbituric acid | |
JPS6177045A (ja) | ããã²ã³åéåçæå ææ | |
JPH01196040A (ja) | åççšåžå ææ | |
DE2433072A1 (de) | Lichtempfindliches photographisches material |