JPH0215246B2 - - Google Patents
Info
- Publication number
- JPH0215246B2 JPH0215246B2 JP17059083A JP17059083A JPH0215246B2 JP H0215246 B2 JPH0215246 B2 JP H0215246B2 JP 17059083 A JP17059083 A JP 17059083A JP 17059083 A JP17059083 A JP 17059083A JP H0215246 B2 JPH0215246 B2 JP H0215246B2
- Authority
- JP
- Japan
- Prior art keywords
- polysiloxane
- formula
- membrane
- gas
- oxygen gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 polysiloxane Polymers 0.000 claims description 57
- 239000012528 membrane Substances 0.000 claims description 49
- 229920001296 polysiloxane Polymers 0.000 claims description 43
- 229920000642 polymer Polymers 0.000 claims description 21
- 239000003446 ligand Substances 0.000 claims description 15
- 239000007789 gas Substances 0.000 claims description 14
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 8
- 150000004753 Schiff bases Chemical class 0.000 claims description 7
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 6
- 125000003277 amino group Chemical group 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 229910001431 copper ion Inorganic materials 0.000 claims description 6
- 125000002883 imidazolyl group Chemical group 0.000 claims description 6
- 239000002262 Schiff base Substances 0.000 claims description 3
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 27
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 26
- 239000002131 composite material Substances 0.000 description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 17
- 238000000926 separation method Methods 0.000 description 17
- 229910001873 dinitrogen Inorganic materials 0.000 description 13
- 230000035699 permeability Effects 0.000 description 12
- 239000010408 film Substances 0.000 description 11
- 239000004743 Polypropylene Substances 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229920001155 polypropylene Polymers 0.000 description 8
- 150000004696 coordination complex Chemical group 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 229910021645 metal ion Inorganic materials 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 229910001429 cobalt ion Inorganic materials 0.000 description 4
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920002873 Polyethylenimine Polymers 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 150000003222 pyridines Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 2
- LLIFKTIQXYJAHL-UHFFFAOYSA-N 3-imidazol-1-ylpropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCN1C=CN=C1 LLIFKTIQXYJAHL-UHFFFAOYSA-N 0.000 description 1
- 102000001554 Hemoglobins Human genes 0.000 description 1
- 108010054147 Hemoglobins Proteins 0.000 description 1
- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- VZHHNBNSMNNUAD-UHFFFAOYSA-N cobalt 2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol Chemical compound [Co].OC1=CC=CC=C1C=NCCN=CC1=CC=CC=C1O VZHHNBNSMNNUAD-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 108060003552 hemocyanin Proteins 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- MMZPUXVBQAQQDQ-UHFFFAOYSA-N triethoxy(2-pyridin-4-ylethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=NC=C1 MMZPUXVBQAQQDQ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17059083A JPS6064601A (ja) | 1983-09-17 | 1983-09-17 | 気体選択透過膜 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17059083A JPS6064601A (ja) | 1983-09-17 | 1983-09-17 | 気体選択透過膜 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6064601A JPS6064601A (ja) | 1985-04-13 |
| JPH0215246B2 true JPH0215246B2 (enrdf_load_stackoverflow) | 1990-04-11 |
Family
ID=15907652
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17059083A Granted JPS6064601A (ja) | 1983-09-17 | 1983-09-17 | 気体選択透過膜 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6064601A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2023056647A (ja) * | 2021-10-08 | 2023-04-20 | 国立大学法人広島大学 | 分離膜及び分離膜の製造方法 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02308857A (ja) * | 1989-05-02 | 1990-12-21 | Union Carbide Chem & Plast Co Inc | 室温硬化ポリオルガノシロキサン |
| JPH0377890A (ja) * | 1989-08-18 | 1991-04-03 | Sagami Chem Res Center | ピリジン環を末端に有するポリオルガノシロキサンおよびその製造方法 |
| KR100315894B1 (ko) * | 1999-12-30 | 2001-12-24 | 박호군 | 고분자 전해질을 이용한 알켄 분리용 고체상 촉진 수송분리막 |
| US6547859B1 (en) * | 2000-11-21 | 2003-04-15 | Praxair Technology, Inc. | Process for making microporous membranes having selected gas-selective sites and the membranes so made |
| EP2415515A4 (en) * | 2009-03-31 | 2013-08-28 | Toray Industries | COMPOSITE SEMI-PERMEABLE MEMBRANE AND METHOD FOR MANUFACTURING THE SAME |
| US8672143B2 (en) * | 2010-03-30 | 2014-03-18 | Toray Industries, Inc. | Composite semipermeable membrane |
| JP6121106B2 (ja) * | 2011-07-06 | 2017-04-26 | 日本碍子株式会社 | 選択的酸素透過基体、空気電池用正極、空気電池、及び選択的酸素透過膜 |
-
1983
- 1983-09-17 JP JP17059083A patent/JPS6064601A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2023056647A (ja) * | 2021-10-08 | 2023-04-20 | 国立大学法人広島大学 | 分離膜及び分離膜の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6064601A (ja) | 1985-04-13 |
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