JPH0148937B2 - - Google Patents
Info
- Publication number
- JPH0148937B2 JPH0148937B2 JP4740082A JP4740082A JPH0148937B2 JP H0148937 B2 JPH0148937 B2 JP H0148937B2 JP 4740082 A JP4740082 A JP 4740082A JP 4740082 A JP4740082 A JP 4740082A JP H0148937 B2 JPH0148937 B2 JP H0148937B2
- Authority
- JP
- Japan
- Prior art keywords
- styrene
- butadiene
- molecular weight
- weight
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 30
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 28
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 23
- 229920001971 elastomer Polymers 0.000 claims description 21
- 239000005060 rubber Substances 0.000 claims description 21
- 229920001577 copolymer Polymers 0.000 claims description 12
- 230000009477 glass transition Effects 0.000 claims description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 229920000642 polymer Polymers 0.000 description 18
- 238000006116 polymerization reaction Methods 0.000 description 17
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- -1 tin halide compound Chemical class 0.000 description 5
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002900 organolithium compounds Chemical class 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000001979 organolithium group Chemical group 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- UIEKYBOPAVTZKW-UHFFFAOYSA-L naphthalene-2-carboxylate;nickel(2+) Chemical compound [Ni+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 UIEKYBOPAVTZKW-UHFFFAOYSA-L 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- HSJXWMZKBLUOLQ-UHFFFAOYSA-M potassium;2-dodecylbenzenesulfonate Chemical compound [K+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HSJXWMZKBLUOLQ-UHFFFAOYSA-M 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4740082A JPS58167633A (ja) | 1982-03-26 | 1982-03-26 | 分岐状スチレン・ブタジエン共重合体ゴム組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4740082A JPS58167633A (ja) | 1982-03-26 | 1982-03-26 | 分岐状スチレン・ブタジエン共重合体ゴム組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58167633A JPS58167633A (ja) | 1983-10-03 |
| JPH0148937B2 true JPH0148937B2 (en, 2012) | 1989-10-23 |
Family
ID=12774056
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4740082A Granted JPS58167633A (ja) | 1982-03-26 | 1982-03-26 | 分岐状スチレン・ブタジエン共重合体ゴム組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58167633A (en, 2012) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0635519B2 (ja) * | 1984-04-13 | 1994-05-11 | 日本合成ゴム株式会社 | ゴム組成物 |
| JPS61203145A (ja) * | 1985-03-05 | 1986-09-09 | Bridgestone Corp | 競技用タイヤ |
| US5232987A (en) * | 1988-02-01 | 1993-08-03 | Japan Synthetic Rubber Co., Ltd. | Rubber compositions |
| JPH0637578B2 (ja) * | 1988-02-01 | 1994-05-18 | 日本合成ゴム株式会社 | ゴム組成物 |
| US8030406B2 (en) | 2005-03-04 | 2011-10-04 | Bridgestone Corporation | Rubber composition and pneumatic tire using the same |
| JP4902974B2 (ja) * | 2005-08-05 | 2012-03-21 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
| JP4846250B2 (ja) * | 2005-03-04 | 2011-12-28 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
| US7868081B2 (en) | 2005-03-04 | 2011-01-11 | Bridgestone Corporation | Rubber composition and tire using same |
| JP4911904B2 (ja) * | 2005-03-04 | 2012-04-04 | 株式会社ブリヂストン | ゴム組成物及びそれを用いたタイヤ |
-
1982
- 1982-03-26 JP JP4740082A patent/JPS58167633A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58167633A (ja) | 1983-10-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4540744A (en) | Butadiene-base polymer and a process for producing the same | |
| JPH10237120A (ja) | コンパンドにした時に低いヒステリシス特性を示す大環状ポリマー類の合成 | |
| JPH0348220B2 (en, 2012) | ||
| JPS634579B2 (en, 2012) | ||
| JPS60228511A (ja) | 溶液重合によるゴム状共重合体 | |
| JPH0148937B2 (en, 2012) | ||
| JPH0345099B2 (en, 2012) | ||
| JP2992102B2 (ja) | 空気入りタイヤ | |
| JPS6326136B2 (en, 2012) | ||
| JPH0345097B2 (en, 2012) | ||
| JPS5938209A (ja) | 分岐状共役ジエン系重合体 | |
| JPH0345098B2 (en, 2012) | ||
| JPS58162605A (ja) | 分子量分布の広いスチレン−ブタジエン共重合体 | |
| JPH066639B2 (ja) | ゴム組成物 | |
| JPH051298B2 (en, 2012) | ||
| JPH0686500B2 (ja) | 共役ジオレフィン系重合体の製造方法 | |
| JPH01135844A (ja) | タイヤ用ゴム組成物 | |
| JPH0456043B2 (en, 2012) | ||
| JPH0138809B2 (en, 2012) | ||
| JPH0322413B2 (en, 2012) | ||
| JPS62215639A (ja) | タイヤ用ゴム組成物 | |
| JP2589142B2 (ja) | タイヤ用ゴム組成物 | |
| JPH0353340B2 (en, 2012) | ||
| JPH0310644B2 (en, 2012) | ||
| JPH0138810B2 (en, 2012) |