JPH0146976B2 - - Google Patents
Info
- Publication number
- JPH0146976B2 JPH0146976B2 JP8204981A JP8204981A JPH0146976B2 JP H0146976 B2 JPH0146976 B2 JP H0146976B2 JP 8204981 A JP8204981 A JP 8204981A JP 8204981 A JP8204981 A JP 8204981A JP H0146976 B2 JPH0146976 B2 JP H0146976B2
- Authority
- JP
- Japan
- Prior art keywords
- cathode
- melting point
- hexaboride
- support piece
- point metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 238000002844 melting Methods 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- 230000004888 barrier function Effects 0.000 claims description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 230000008018 melting Effects 0.000 claims description 18
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 13
- 238000005245 sintering Methods 0.000 claims description 13
- 229910052580 B4C Inorganic materials 0.000 claims description 7
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 6
- 150000002910 rare earth metals Chemical class 0.000 claims description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 29
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 20
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 10
- 229910052721 tungsten Inorganic materials 0.000 description 10
- 239000010937 tungsten Substances 0.000 description 10
- 229910052715 tantalum Inorganic materials 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229910052746 lanthanum Inorganic materials 0.000 description 6
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 150000001247 metal acetylides Chemical class 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- -1 hafnium nitride Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000003870 refractory metal Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- LRTTZMZPZHBOPO-UHFFFAOYSA-N [B].[B].[Hf] Chemical compound [B].[B].[Hf] LRTTZMZPZHBOPO-UHFFFAOYSA-N 0.000 description 2
- CFJRGWXELQQLSA-UHFFFAOYSA-N azanylidyneniobium Chemical compound [Nb]#N CFJRGWXELQQLSA-UHFFFAOYSA-N 0.000 description 2
- SKKMWRVAJNPLFY-UHFFFAOYSA-N azanylidynevanadium Chemical compound [V]#N SKKMWRVAJNPLFY-UHFFFAOYSA-N 0.000 description 2
- VDZMENNHPJNJPP-UHFFFAOYSA-N boranylidyneniobium Chemical compound [Nb]#B VDZMENNHPJNJPP-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZVWKZXLXHLZXLS-UHFFFAOYSA-N zirconium nitride Chemical compound [Zr]#N ZVWKZXLXHLZXLS-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910007948 ZrB2 Inorganic materials 0.000 description 1
- DBNPLCUZNLSUCT-UHFFFAOYSA-N [B].[B].[B].[B].[B].[B].[Ba] Chemical compound [B].[B].[B].[B].[B].[B].[Ba] DBNPLCUZNLSUCT-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- VWZIXVXBCBBRGP-UHFFFAOYSA-N boron;zirconium Chemical compound B#[Zr]#B VWZIXVXBCBBRGP-UHFFFAOYSA-N 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/02—Manufacture of electrodes or electrode systems
- H01J9/04—Manufacture of electrodes or electrode systems of thermionic cathodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/02—Main electrodes
- H01J1/13—Solid thermionic cathodes
- H01J1/14—Solid thermionic cathodes characterised by the material
- H01J1/148—Solid thermionic cathodes characterised by the material with compounds having metallic conductive properties, e.g. lanthanum boride, as an emissive material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
- H01J1/02—Main electrodes
- H01J1/13—Solid thermionic cathodes
- H01J1/15—Cathodes heated directly by an electric current
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Solid Thermionic Cathode (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8204981A JPS57196443A (en) | 1981-05-29 | 1981-05-29 | Manufacture of hot cathode |
| US06/341,078 US4482839A (en) | 1981-05-29 | 1982-01-20 | Thermionic emission cathode and preparation thereof |
| GB8201785A GB2099625B (en) | 1981-05-29 | 1982-01-22 | Thermionic emission cathode |
| DE19823203917 DE3203917A1 (de) | 1981-05-29 | 1982-02-05 | Thermionische emissionskathode und verfahren zur herstellung derselben |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8204981A JPS57196443A (en) | 1981-05-29 | 1981-05-29 | Manufacture of hot cathode |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63267301A Division JPH01154424A (ja) | 1988-10-25 | 1988-10-25 | 熱電子放射陰極 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57196443A JPS57196443A (en) | 1982-12-02 |
| JPH0146976B2 true JPH0146976B2 (US06252093-20010626-C00008.png) | 1989-10-12 |
Family
ID=13763648
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8204981A Granted JPS57196443A (en) | 1981-05-29 | 1981-05-29 | Manufacture of hot cathode |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4482839A (US06252093-20010626-C00008.png) |
| JP (1) | JPS57196443A (US06252093-20010626-C00008.png) |
| DE (1) | DE3203917A1 (US06252093-20010626-C00008.png) |
| GB (1) | GB2099625B (US06252093-20010626-C00008.png) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008166265A (ja) * | 2006-12-04 | 2008-07-17 | Denki Kagaku Kogyo Kk | 電子放出源 |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3516955A1 (de) * | 1985-05-10 | 1986-11-13 | Elektroschmelzwerk Kempten GmbH, 8000 München | Polykristalline sinterkoerper auf basis von lanthanhexaborid und verfahren zu ihrer herstellung |
| EP0204297B1 (en) * | 1985-06-04 | 1991-01-23 | Denki Kagaku Kogyo Kabushiki Kaisha | Charged particle emission source structure |
| US4740705A (en) * | 1986-08-11 | 1988-04-26 | Electron Beam Memories | Axially compact field emission cathode assembly |
| CH672860A5 (US06252093-20010626-C00008.png) * | 1986-09-29 | 1989-12-29 | Balzers Hochvakuum | |
| US4924136A (en) * | 1987-09-28 | 1990-05-08 | Siemens Aktiengesellschaft | Beam generating system for electron beam measuring instruments having cathode support structure |
| US6815876B1 (en) * | 1999-06-23 | 2004-11-09 | Agere Systems Inc. | Cathode with improved work function and method for making the same |
| JP2001325910A (ja) * | 2000-05-16 | 2001-11-22 | Denki Kagaku Kogyo Kk | 電子銃とその使用方法 |
| WO2006008785A1 (ja) * | 2004-07-15 | 2006-01-26 | Sumitomo Metal Mining Co., Ltd. | ホウ化物微粒子含有繊維およびこれを用いた繊維製品 |
| US7544523B2 (en) * | 2005-12-23 | 2009-06-09 | Fei Company | Method of fabricating nanodevices |
| US8247070B2 (en) * | 2006-10-30 | 2012-08-21 | Barry Chin Li Cheung | Crystalline nanostructures |
| UA113827C2 (xx) * | 2016-09-07 | 2017-03-10 | Аксіальна електронна гармата | |
| US9790620B1 (en) * | 2017-01-06 | 2017-10-17 | Nuflare Technology, Inc. | Method of reducing work function in carbon coated LaB6 cathodes |
| JP6636472B2 (ja) | 2017-02-28 | 2020-01-29 | 株式会社日立ハイテクノロジーズ | 電子源およびそれを用いた電子線装置 |
| US11915921B2 (en) * | 2020-04-21 | 2024-02-27 | Denka Company Limited | Electron source, method for manufacturing same, emitter, and device including same |
| GB2619965A (en) * | 2022-06-24 | 2023-12-27 | Aquasium Tech Limited | Electron beam emitting assembly |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2900281A (en) * | 1953-07-20 | 1959-08-18 | Gen Electric | Method of bonding metal borides to graphite |
| US3312856A (en) * | 1963-03-26 | 1967-04-04 | Gen Electric | Rhenium supported metallic boride cathode emitters |
| US3440475A (en) * | 1967-04-11 | 1969-04-22 | Lokomotivbau Elektrotech | Lanthanum hexaboride cathode system for an electron beam generator |
| NL7207276A (US06252093-20010626-C00008.png) * | 1972-05-30 | 1973-12-04 | ||
| NL167796C (nl) * | 1972-05-30 | 1982-01-18 | Philips Nv | Werkwijze voor het vervaardigen van een met lanthaanhexaboride geactiveerde kathode voor een elektrische ontladingsbuis. |
| US4055780A (en) * | 1975-04-10 | 1977-10-25 | National Institute For Researches In Inorganic Materials | Thermionic emission cathode having a tip of a single crystal of lanthanum hexaboride |
| JPS53128971A (en) * | 1977-04-18 | 1978-11-10 | Hitachi Ltd | Manufacture of electron radiation cathode |
| US4168565A (en) * | 1977-05-18 | 1979-09-25 | Denki Kagaku Kogyo Kabushiki Kaisha | Method for manufacturing thermionic cathode |
| US4137476A (en) * | 1977-05-18 | 1979-01-30 | Denki Kagaku Kogyo Kabushiki Kaisha | Thermionic cathode |
| CH617793A5 (US06252093-20010626-C00008.png) * | 1977-09-02 | 1980-06-13 | Balzers Hochvakuum | |
| JPH05264268A (ja) * | 1992-03-17 | 1993-10-12 | Mitsubishi Electric Corp | 三角測量法 |
| JP3078640B2 (ja) * | 1992-03-19 | 2000-08-21 | 株式会社トプコン | レーザ測量機 |
-
1981
- 1981-05-29 JP JP8204981A patent/JPS57196443A/ja active Granted
-
1982
- 1982-01-20 US US06/341,078 patent/US4482839A/en not_active Expired - Lifetime
- 1982-01-22 GB GB8201785A patent/GB2099625B/en not_active Expired
- 1982-02-05 DE DE19823203917 patent/DE3203917A1/de active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008166265A (ja) * | 2006-12-04 | 2008-07-17 | Denki Kagaku Kogyo Kk | 電子放出源 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2099625B (en) | 1985-02-27 |
| DE3203917C2 (US06252093-20010626-C00008.png) | 1990-07-19 |
| JPS57196443A (en) | 1982-12-02 |
| DE3203917A1 (de) | 1982-12-16 |
| US4482839A (en) | 1984-11-13 |
| GB2099625A (en) | 1982-12-08 |
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