JPH0139760B2 - - Google Patents
Info
- Publication number
- JPH0139760B2 JPH0139760B2 JP56039302A JP3930281A JPH0139760B2 JP H0139760 B2 JPH0139760 B2 JP H0139760B2 JP 56039302 A JP56039302 A JP 56039302A JP 3930281 A JP3930281 A JP 3930281A JP H0139760 B2 JPH0139760 B2 JP H0139760B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction zone
- continuously
- cellulose
- valve
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 claims description 105
- 229920002678 cellulose Polymers 0.000 claims description 53
- 239000001913 cellulose Substances 0.000 claims description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 36
- 239000002002 slurry Substances 0.000 claims description 28
- 239000002253 acid Substances 0.000 claims description 25
- 238000007789 sealing Methods 0.000 claims description 20
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 19
- 239000008103 glucose Substances 0.000 claims description 19
- 239000002994 raw material Substances 0.000 claims description 18
- 238000011144 upstream manufacturing Methods 0.000 claims description 18
- 230000007062 hydrolysis Effects 0.000 claims description 14
- 238000006460 hydrolysis reaction Methods 0.000 claims description 14
- 239000002699 waste material Substances 0.000 claims description 14
- 230000002378 acidificating effect Effects 0.000 claims description 12
- 239000003054 catalyst Substances 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 238000005903 acid hydrolysis reaction Methods 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 230000004044 response Effects 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 3
- 230000003301 hydrolyzing effect Effects 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 230000001276 controlling effect Effects 0.000 claims 2
- 230000001105 regulatory effect Effects 0.000 claims 2
- 230000001678 irradiating effect Effects 0.000 claims 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 18
- 229960001031 glucose Drugs 0.000 description 18
- 239000000376 reactant Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 230000009977 dual effect Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 229920001131 Pulp (paper) Polymers 0.000 description 5
- 239000002657 fibrous material Substances 0.000 description 5
- 229920005610 lignin Polymers 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 238000012544 monitoring process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003929 acidic solution Substances 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 235000019441 ethanol Nutrition 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 229920002488 Hemicellulose Polymers 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000005865 ionizing radiation Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical class COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000010793 Steam injection (oil industry) Methods 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000010006 flight Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K1/00—Glucose; Glucose-containing syrups
- C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/131,339 US4316748A (en) | 1980-03-18 | 1980-03-18 | Process for the acid hydrolysis of waste cellulose to glucose |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56169600A JPS56169600A (en) | 1981-12-26 |
| JPH0139760B2 true JPH0139760B2 (enExample) | 1989-08-23 |
Family
ID=22449010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3930281A Granted JPS56169600A (en) | 1980-03-18 | 1981-03-18 | Conversion of waste cellulose to glucose |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US4316748A (enExample) |
| JP (1) | JPS56169600A (enExample) |
| ZA (1) | ZA811415B (enExample) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES8201627A1 (es) | 1980-02-23 | 1981-12-16 | Reitter Franz Johann | Procedimiento e instalacion para la hidrolisis continua de hemicelulosas que contienen pentosanas de celulosa. |
| US4390375A (en) * | 1980-03-18 | 1983-06-28 | New York University | Process and continuous apparatus for chemical conversion of materials |
| DE3048802A1 (de) * | 1980-12-23 | 1982-07-08 | Werner & Pfleiderer, 7000 Stuttgart | Verfahren zur hydrolyse von zellulose pflanzlicher rohstoffe zu glukose und vorrichtung zur durchfuehrung des verfahrens |
| US4591386A (en) * | 1981-04-17 | 1986-05-27 | New York University | Continuous apparatus for chemical conversion of materials |
| USRE32217E (en) * | 1982-11-12 | 1986-07-29 | The Dow Chemical Company | Graft copolymerization process |
| JPS59192094A (ja) * | 1983-04-14 | 1984-10-31 | Res Assoc Petroleum Alternat Dev<Rapad> | バイオマスの酵素処理用前処理法 |
| US4728367A (en) * | 1985-01-31 | 1988-03-01 | Wenger Manufacturing, Inc. | Extrusion method and apparatus for acid treatment of cellulosic materials |
| US4965086A (en) * | 1988-01-04 | 1990-10-23 | Degussa Aktiengesellschaft | Chemical-mechanical treatment of lignocellulosics to improve nutritive value |
| US4842877A (en) * | 1988-04-05 | 1989-06-27 | Xylan, Inc. | Delignification of non-woody biomass |
| US5023097A (en) * | 1988-04-05 | 1991-06-11 | Xylan, Inc. | Delignification of non-woody biomass |
| US5366755A (en) * | 1989-02-10 | 1994-11-22 | Maritta Timonen | Foodstuffs containing novel degraded cellulose derivatives |
| US5972118A (en) * | 1995-10-27 | 1999-10-26 | Tennessee Valley Authority | Concentrated sulfuric acid hydrolysis of lignocellulosics |
| US5876505A (en) * | 1998-01-13 | 1999-03-02 | Thermo Fibergen, Inc. | Method of producing glucose from papermaking sludge using concentrated or dilute acid hydrolysis |
| US6632286B2 (en) * | 2001-03-19 | 2003-10-14 | Trustees Of Dartmouth College | Cross-flow process for the production of decomposable soluble products from a slurry of solids |
| BRPI0516755A (pt) * | 2004-09-30 | 2008-09-16 | Iogen Energy Corp | processo contìnuo para o pré-tratamento de uma carga de alimentação lignocelulósica |
| US7600707B2 (en) * | 2005-06-21 | 2009-10-13 | Purevision Technology, Inc. | Apparatus for the separation and treatment of solid biomass |
| US7758719B2 (en) * | 2005-12-16 | 2010-07-20 | Fiberight Management Llc | Wet pulping system and method for producing cellulosic insulation with low ash content |
| US7815876B2 (en) | 2006-11-03 | 2010-10-19 | Olson David A | Reactor pump for catalyzed hydrolytic splitting of cellulose |
| US7815741B2 (en) * | 2006-11-03 | 2010-10-19 | Olson David A | Reactor pump for catalyzed hydrolytic splitting of cellulose |
| US8057639B2 (en) | 2008-02-28 | 2011-11-15 | Andritz Inc. | System and method for preextraction of hemicellulose through using a continuous prehydrolysis and steam explosion pretreatment process |
| US8546560B2 (en) * | 2008-07-16 | 2013-10-01 | Renmatix, Inc. | Solvo-thermal hydrolysis of cellulose |
| CN102239184B (zh) * | 2008-07-16 | 2014-07-23 | 瑞恩麦特克斯股份有限公司 | 使用一种或多种超临界流体从生物质萃取糠醛和葡萄糖的方法 |
| US8915644B2 (en) | 2008-07-24 | 2014-12-23 | Abengoa Bioenergy New Technologies, Llc. | Method and apparatus for conveying a cellulosic feedstock |
| CA2638160C (en) * | 2008-07-24 | 2015-02-17 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| US9127325B2 (en) | 2008-07-24 | 2015-09-08 | Abengoa Bioenergy New Technologies, Llc. | Method and apparatus for treating a cellulosic feedstock |
| CA2638150C (en) * | 2008-07-24 | 2012-03-27 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| CA2650919C (en) * | 2009-01-23 | 2014-04-22 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| CA2650913C (en) * | 2009-01-23 | 2013-10-15 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| CA2638159C (en) * | 2008-07-24 | 2012-09-11 | Sunopta Bioprocess Inc. | Method and apparatus for treating a cellulosic feedstock |
| CA2638152C (en) * | 2008-07-24 | 2013-07-16 | Sunopta Bioprocess Inc. | Method and apparatus for treating a cellulosic feedstock |
| CA2638157C (en) * | 2008-07-24 | 2013-05-28 | Sunopta Bioprocess Inc. | Method and apparatus for conveying a cellulosic feedstock |
| KR102033270B1 (ko) * | 2008-11-17 | 2019-10-16 | 질레코 인코포레이티드 | 바이오매스의 가공처리방법 |
| CA2673134A1 (en) * | 2009-07-17 | 2011-01-17 | Murray J. Burke | Method and apparatus for the heat treatment of a cellulosic feedstock upstream of hydrolysis |
| ES2458554T3 (es) | 2009-08-24 | 2014-05-06 | Abengoa Bioenergy New Technologies, Inc. | Procedimientos de producción de etanol y coproductos a partir de biomasa celulósica |
| US8597431B2 (en) * | 2009-10-05 | 2013-12-03 | Andritz (Usa) Inc. | Biomass pretreatment |
| BR112012017850B8 (pt) | 2010-01-19 | 2020-12-01 | Renmatix Inc | método para o tratamento contínuo de biomassa |
| JP5378306B2 (ja) * | 2010-06-15 | 2013-12-25 | 月島機械株式会社 | バイオマスの処理装置及び処理方法 |
| RU2602068C2 (ru) | 2011-05-04 | 2016-11-10 | Ренмэтикс, Инк. | Получение лигнина из лигноцеллюлозной биомассы |
| US8801859B2 (en) | 2011-05-04 | 2014-08-12 | Renmatix, Inc. | Self-cleaning apparatus and method for thick slurry pressure control |
| US8759498B2 (en) | 2011-12-30 | 2014-06-24 | Renmatix, Inc. | Compositions comprising lignin |
| KR101926193B1 (ko) * | 2012-04-10 | 2018-12-07 | 에스케이이노베이션 주식회사 | 바이오매스로부터 유기산의 제조 방법 |
| KR101966210B1 (ko) * | 2012-09-20 | 2019-08-13 | 노람 엔지니어링 앤드 콘스트럭터스 엘티디. | 압축된 셀룰로오스성 물질을 사용하여 부분적으로-가수분해된 셀룰로오스를 제조하는 방법 |
| US9102885B2 (en) | 2013-07-26 | 2015-08-11 | Renmatix, Inc. | Method of transporting viscous slurries |
| SG11201701740VA (en) | 2014-09-26 | 2017-04-27 | Renmatix Inc | Cellulose-containing compositions and methods of making same |
| WO2019067526A1 (en) | 2017-09-26 | 2019-04-04 | Poet Research, Inc. | SYSTEMS AND METHODS FOR TREATING LIGNOCELLULOSIC BIOMASS |
| FR3075202B1 (fr) * | 2017-12-20 | 2020-08-28 | Ifp Energies Now | Procede de traitement de biomasse ligno-cellulosique |
| JP2019122262A (ja) * | 2018-01-11 | 2019-07-25 | 株式会社ダイセル | グルコースの製造方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1502335B2 (de) * | 1965-02-13 | 1971-10-21 | Werner & Pfleiderer, 7000 Stuttgart | Schneckenstrangprese fuer die verarbeitung von kunststoff |
| US3917507A (en) * | 1971-02-22 | 1975-11-04 | Welding Engineers | Countercurrent combined liquid and vapor stripping in screw devolatilizer |
| SU633586A1 (ru) * | 1975-01-13 | 1978-11-25 | Предприятие П/Я Р-6729 | Устройство дл гидролиза торфа |
| SU682491A1 (ru) * | 1975-04-03 | 1979-08-30 | Предприятие П/Я Р-6729 | Устройство дл гидролиза торфа |
| FR2319737A1 (fr) * | 1975-07-31 | 1977-02-25 | Creusot Loire | Procede et machine de fabrication de pate a papier |
| FR2418295A1 (fr) * | 1978-02-27 | 1979-09-21 | Creusot Loire | Procede et installation de traitement en continu d'une matiere cellulosique |
| US4201596A (en) * | 1979-01-12 | 1980-05-06 | American Can Company | Continuous process for cellulose saccharification |
-
1980
- 1980-03-18 US US06/131,339 patent/US4316748A/en not_active Expired - Lifetime
-
1981
- 1981-03-03 ZA ZA00811415A patent/ZA811415B/xx unknown
- 1981-03-18 JP JP3930281A patent/JPS56169600A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56169600A (en) | 1981-12-26 |
| US4316748A (en) | 1982-02-23 |
| ZA811415B (en) | 1982-06-30 |
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