JPH0120983Y2 - - Google Patents

Info

Publication number

JPH0120983Y2

JPH0120983Y2 JP150485U JP150485U JPH0120983Y2 JP H0120983 Y2 JPH0120983 Y2 JP H0120983Y2 JP 150485 U JP150485 U JP 150485U JP 150485 U JP150485 U JP 150485U JP H0120983 Y2 JPH0120983 Y2 JP H0120983Y2

Authority

JP

Japan

Prior art keywords

catalyst

exhaust gas

platinum

cerium

catalyst layer

Prior art date

1985-01-11

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

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• 239000003054 catalyst Substances 0.000 claims description 80
• BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 33
• 229910052684 Cerium Inorganic materials 0.000 claims description 17
• GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 12
• 239000010949 copper Substances 0.000 claims description 11
• 229910052802 copper Inorganic materials 0.000 claims description 9
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
• 238000007084 catalytic combustion reaction Methods 0.000 claims description 5
• 239000002131 composite material Substances 0.000 claims description 4
• 239000007789 gas Substances 0.000 description 40
• KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 24
• 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 21
• 229910052763 palladium Inorganic materials 0.000 description 18
• 235000019645 odor Nutrition 0.000 description 16
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
• 150000001298 alcohols Chemical class 0.000 description 9
• 238000006356 dehydrogenation reaction Methods 0.000 description 9
• 238000001035 drying Methods 0.000 description 9
• 150000002989 phenols Chemical class 0.000 description 9
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
• 239000011248 coating agent Substances 0.000 description 8
• 238000000576 coating method Methods 0.000 description 8
• 229910052739 hydrogen Inorganic materials 0.000 description 8
• 239000001257 hydrogen Substances 0.000 description 8
• 229910052697 platinum Inorganic materials 0.000 description 8
• 239000001569 carbon dioxide Substances 0.000 description 7
• 229910002092 carbon dioxide Inorganic materials 0.000 description 7
• 230000001877 deodorizing effect Effects 0.000 description 7
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
• IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 6
• 238000002485 combustion reaction Methods 0.000 description 6
• 230000000694 effects Effects 0.000 description 6
• 239000012210 heat-resistant fiber Substances 0.000 description 6
• 230000009965 odorless effect Effects 0.000 description 6
• VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 5
• 239000003973 paint Substances 0.000 description 5
• UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
• 229910002091 carbon monoxide Inorganic materials 0.000 description 4
• 238000002474 experimental method Methods 0.000 description 4
• 238000010438 heat treatment Methods 0.000 description 4
• PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
• 150000001875 compounds Chemical class 0.000 description 3
• 238000000354 decomposition reaction Methods 0.000 description 3
• 238000004070 electrodeposition Methods 0.000 description 3
• 229930195733 hydrocarbon Natural products 0.000 description 3
• 150000002430 hydrocarbons Chemical class 0.000 description 3
• 238000004519 manufacturing process Methods 0.000 description 3
• 238000005259 measurement Methods 0.000 description 3
• 238000007254 oxidation reaction Methods 0.000 description 3
• 239000000126 substance Substances 0.000 description 3
• 238000003915 air pollution Methods 0.000 description 2
• 239000007864 aqueous solution Substances 0.000 description 2
• 150000001735 carboxylic acids Chemical class 0.000 description 2
• 230000003197 catalytic effect Effects 0.000 description 2
• 230000000052 comparative effect Effects 0.000 description 2
• 238000010586 diagram Methods 0.000 description 2
• AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
• 239000013067 intermediate product Substances 0.000 description 2
• 229910052751 metal Inorganic materials 0.000 description 2
• 239000002184 metal Substances 0.000 description 2
• 150000002739 metals Chemical class 0.000 description 2
• 239000008188 pellet Substances 0.000 description 2
• 238000012545 processing Methods 0.000 description 2
• 239000000047 product Substances 0.000 description 2
• 229920005989 resin Polymers 0.000 description 2
• 239000011347 resin Substances 0.000 description 2
• 230000001953 sensory effect Effects 0.000 description 2
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
• 230000010718 Oxidation Activity Effects 0.000 description 1
• 239000000853 adhesive Substances 0.000 description 1
• 230000001070 adhesive effect Effects 0.000 description 1
• 229910052799 carbon Inorganic materials 0.000 description 1
• 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
• 239000000919 ceramic Substances 0.000 description 1
• SKEYZPJKRDZMJG-UHFFFAOYSA-N cerium copper Chemical compound [Cu].[Ce] SKEYZPJKRDZMJG-UHFFFAOYSA-N 0.000 description 1
• HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 1
• 238000006243 chemical reaction Methods 0.000 description 1
• 229910000428 cobalt oxide Inorganic materials 0.000 description 1
• IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
• 238000007796 conventional method Methods 0.000 description 1
• XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
• 229910052878 cordierite Inorganic materials 0.000 description 1
• 238000001514 detection method Methods 0.000 description 1
• 238000007865 diluting Methods 0.000 description 1
• 238000010790 dilution Methods 0.000 description 1
• 239000012895 dilution Substances 0.000 description 1
• JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
• 150000002148 esters Chemical class 0.000 description 1
• 239000004744 fabric Substances 0.000 description 1
• 239000000835 fiber Substances 0.000 description 1
• 239000006260 foam Substances 0.000 description 1
• 235000019256 formaldehyde Nutrition 0.000 description 1
• 239000003205 fragrance Substances 0.000 description 1
• 239000011521 glass Substances 0.000 description 1
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
• 239000002440 industrial waste Substances 0.000 description 1
• 239000000976 ink Substances 0.000 description 1
• 238000000034 method Methods 0.000 description 1
• 238000002156 mixing Methods 0.000 description 1
• 239000000203 mixture Substances 0.000 description 1
• 150000002894 organic compounds Chemical class 0.000 description 1
• 230000003647 oxidation Effects 0.000 description 1
• 238000010422 painting Methods 0.000 description 1
• 239000011120 plywood Substances 0.000 description 1
• 231100000614 poison Toxicity 0.000 description 1
• 231100000572 poisoning Toxicity 0.000 description 1
• 230000000607 poisoning effect Effects 0.000 description 1
• 230000007096 poisonous effect Effects 0.000 description 1
• 230000002265 prevention Effects 0.000 description 1
• 238000000746 purification Methods 0.000 description 1
• 230000008786 sensory perception of smell Effects 0.000 description 1
• LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Substances [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 239000000725 suspension Substances 0.000 description 1
• 239000000057 synthetic resin Substances 0.000 description 1
• 229920003002 synthetic resin Polymers 0.000 description 1
• 231100000331 toxic Toxicity 0.000 description 1
• 230000002588 toxic effect Effects 0.000 description 1
• 239000002918 waste heat Substances 0.000 description 1