JPH01198418A - Apparatus and method for vacuum degassing molten steel - Google Patents

Apparatus and method for vacuum degassing molten steel

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Publication number
JPH01198418A
JPH01198418A JP2175888A JP2175888A JPH01198418A JP H01198418 A JPH01198418 A JP H01198418A JP 2175888 A JP2175888 A JP 2175888A JP 2175888 A JP2175888 A JP 2175888A JP H01198418 A JPH01198418 A JP H01198418A
Authority
JP
Japan
Prior art keywords
molten steel
vacuum degassing
tube
ladle
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2175888A
Other languages
Japanese (ja)
Inventor
Yoshihiko Higuchi
善彦 樋口
Yoshiyasu Shirota
城田 良康
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP2175888A priority Critical patent/JPH01198418A/en
Publication of JPH01198418A publication Critical patent/JPH01198418A/en
Pending legal-status Critical Current

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  • Treatment Of Steel In Its Molten State (AREA)

Abstract

PURPOSE:To execute vacuum degassing treatment for short time by arranging plural submerged tubes in RH type vacuum degassing vessel and gas blowing hole for circulating molten steel in all submerged tubes and alternately changing plural submerged tubes to uptake tube and downtake tube. CONSTITUTION:Plural pieces of the submerged tubes 2A, 2B are arranged in the vacuum degassing vessel 1 and gas blowing hole 3A, 3D for circulating the molten steel is arranged in each tube and the submerged tubes 2A, 2B in the vacuum degassing vessel l are submerged into the molten steel 4 in a ladle 5. The air in the vacuum degassing vessel 1 is evacuated, and the molten steel 4 in the ladle 5 is risen into the vacuum degassing vessel 1. Successively, gas of Ar, etc., is blown from the gas blowing hole 3A in the submerged tube 2A, and the submerged tubes 2A is made to the uptake tube and the tube 2B is made to the downtake tube with rising force of the gas to circulate the molten steel 4 between the vacuum vessel 1 and the ladle, and the degassing treatment is executed in the vacuum degassing vessel 1. Successively, by changing the submerged tube 2B to the uptake tube and the tube 2A to the downtake tube, the whole quantity is risen into the degassing vessel 1 without remaining any part of molten steel in the ladle 5 and the vacuum degassing treatment is perfectly executed to the whole molten steel 4 for short time.

Description

【発明の詳細な説明】 (産業上の利用分野) この発明は、環流式真空脱ガス法により高効率で溶鋼を
真空脱ガス処理する設備および方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to equipment and a method for highly efficiently vacuum degassing molten steel by a recirculation vacuum degassing method.

(従来の技術およびその課!11) 近年、転炉で溶製された溶鋼に対して真空脱ガスを施し
、高級鋼を製造することが著しく多くなった。
(Prior art and its section! 11) In recent years, the production of high-grade steel by subjecting molten steel produced in a converter to vacuum degassing has significantly increased.

真空脱ガス法には、RH法、Dll法、vOD法などが
あるが、前記R1+真空脱ガス法は、 (1)−度に多量の溶鋼処理ができる、(2)溶鋼の脱
酸、脱水素等の脱ガスのみならず、低炭素鋼や清浄鋼の
製造に通している、 (3)合金鉄の使用により成分の微調整ができる、など
、他の真空脱ガス法が及ばない優れた点を有している。
Vacuum degassing methods include the RH method, Dll method, vOD method, etc., but the R1+ vacuum degassing method is capable of (1) processing a large amount of molten steel at a time, and (2) deoxidizing and dehydrating molten steel. It has advantages that other vacuum degassing methods cannot match, such as not only degassing raw materials but also producing low carbon steel and clean steel. (3) Fine adjustment of the composition by using ferroalloy. It has points.

さて、従来のRH真空脱ガス法の概要を第2図を用いて
説明する。
Now, an outline of the conventional RH vacuum degassing method will be explained using FIG. 2.

第2図において、lは図示しない真空ポンプに接続され
た真空脱ガス槽である。この脱ガス槽lは、その下部に
一本の上昇管2aと一本の下降管2bとを備え、前記上
昇管2aの中間部には、Arガス等を吹き込む環流ガス
吹き込み口3が°設けられている。
In FIG. 2, l is a vacuum degassing tank connected to a vacuum pump (not shown). This degassing tank l is equipped with one rising pipe 2a and one descending pipe 2b at its lower part, and a reflux gas blowing port 3 for blowing Ar gas etc. is provided in the middle part of the rising pipe 2a. It is being

このようなRH装置により溶鋼の脱ガスを行うには、溶
84を満たした取鍋5を脱ガス槽1の下方に配置し、そ
のあと脱ガス槽1を下降して上昇管2aと下降管2bを
取鍋5内の溶鋼4に浸漬する。
To degas molten steel using such an RH device, the ladle 5 filled with molten steel 84 is placed below the degassing tank 1, and then the degassing tank 1 is lowered to connect the ascending pipe 2a and the descending pipe. 2b is immersed in the molten steel 4 in the ladle 5.

そして、真空ポンプにより脱ガス槽1内を減圧して溶鋼
4を吸い上げると同時に、前記環流ガス吹き込み口3か
らArガスを吹き込み、Arガスの上昇流により上昇管
2a内に溶鋼流を生じさせ、取鍋5内溶l114を脱ガ
ス槽1に流入する。脱ガス槽l内に流入したtlj鋼4
は部分脱ガスされたあと、下降管2bを通じて取鍋5内
に環流される。通常、このような操業を20〜30分連
続して行うことによって、取鍋的全体の溶!1t14が
脱ガスされ、所望成分の溶鋼が製造されるのである。
Then, the pressure inside the degassing tank 1 is reduced by a vacuum pump to suck up the molten steel 4, and at the same time, Ar gas is blown in from the circulating gas blowing port 3 to cause a molten steel flow in the rising pipe 2a due to the upward flow of the Ar gas, The melt l114 in the ladle 5 flows into the degassing tank 1. tlj steel 4 flowing into the degassing tank l
After being partially degassed, it is refluxed into the ladle 5 through the downcomer pipe 2b. Normally, by performing this operation continuously for 20 to 30 minutes, the entire melt in the ladle is melted! 1t14 is degassed and molten steel with desired composition is produced.

さて、最近の極低炭素鋼等高級鋼の需要の増加に伴って
溶鋼の脱ガス処理量も増大しているが、処理能力が低い
ために対応できない状況にある。
Now, with the recent increase in demand for high-grade steels such as ultra-low carbon steel, the amount of molten steel degassed has also increased, but this cannot be handled due to low processing capacity.

そこで、処理能力向上のため、上昇管および下降管の管
径の拡大や環流ガスの増量等の方法で対処している。
Therefore, in order to improve processing capacity, measures such as increasing the diameters of the rising and descending pipes and increasing the amount of recirculated gas are being taken.

しかし、これらの対策を行っても、例えば、溶鋼中(C
)を2001)pHから15〜20ppmまで低減する
のに15〜25分を要し、15分以内にするという目標
には達していない、以下、その原因について、第2図を
用いて説明する。
However, even if these measures are taken, for example, molten steel (C
2001) It takes 15 to 25 minutes to reduce the pH to 15 to 20 ppm, and the goal of reducing the pH within 15 minutes has not been achieved.The reason for this will be explained below using FIG. 2.

第2図において、環流ガス吹き込み口3から吹き込まれ
たArガスにより、溶鋼4は脱ガス槽1内に流入し、脱
ガスされ、下降管2bを通って取鍋5内に環流するので
あるが、下降管2bから排出された脱ガス後の溶鋼は、
取締自溶鋼4に均一に分散混合せず、同図中矢印で示す
ように、直ちに上昇管2aに向かって流れる短絡流を形
成する。
In FIG. 2, molten steel 4 flows into the degassing tank 1 by Ar gas blown from the reflux gas inlet 3, is degassed, and then refluxes into the ladle 5 through the downcomer pipe 2b. , the degassed molten steel discharged from the downcomer pipe 2b is
It is not uniformly dispersed and mixed in the controlled self-melting steel 4, and forms a short-circuit flow that immediately flows toward the riser pipe 2a, as shown by the arrow in the figure.

このような短絡流が生ずる結果、下降管2bと取鍋5と
の間には(C)濃度希薄部Aが、上昇管2aと取M45
との間には(C〕濃度濃縮部Bが貯留し、この貯留が存
在するために処理時間の短縮が図れないことが分かった
As a result of such a short-circuit flow, there is a (C) diluted concentration area A between the downcomer pipe 2b and the ladle 5, and there is a thin concentration area A between the downcomer pipe 2b and the ladle M45.
It was found that (C) the concentration concentrating section B was stored between the two, and that the presence of this storage made it impossible to shorten the processing time.

そこで、上記の貯留部を解消するため、取鍋内溶鋼を攪
拌する方法が提案されている0例えば、特開昭57−2
00514号公報に開示された方法もその一つである。
Therefore, in order to eliminate the above-mentioned storage area, a method of stirring the molten steel in the ladle has been proposed.
The method disclosed in Publication No. 00514 is one of them.

この方法は第3図に示すように、取鍋5の底部の上昇管
2aの直下の位置に、攪拌用ガス吹き込みノズル7を設
け、このノズル7からAr等の攪拌ガスを吹き込むので
ある。そうすると、攪拌ガスの上昇流によって、図中矢
印で示すような取鍋底部を大きく回流する溶鋼流が生ず
るので、短絡流が発生せず、溶鋼環流率が向上して処理
時間の短縮が図れる。
In this method, as shown in FIG. 3, a stirring gas blowing nozzle 7 is provided at the bottom of the ladle 5 at a position directly below the riser pipe 2a, and a stirring gas such as Ar is blown through the nozzle 7. In this case, the upward flow of the stirring gas generates a molten steel flow that circulates around the bottom of the ladle as shown by the arrow in the figure, so no short circuit flow occurs, the molten steel circulation rate improves, and the processing time can be shortened.

しかし、この方法では、取鍋底部から吹き込まれた攪拌
ガスの全部を上昇管2a内に収容することは難しく、上
昇管2a内に収納されなかった一部の攪拌ガスは、さら
に浮上して溶鋼表面を覆っているスラグ6を攪拌する。
However, with this method, it is difficult to store all of the stirring gas blown from the bottom of the ladle into the riser pipe 2a, and some of the stirring gas that is not stored in the riser pipe 2a further floats to the surface of the molten steel. The slag 6 covering the surface is stirred.

このスラグ6の攪拌によって、スラグ−メタル反応を引
き起こし、スラグ中のP、 S、 O,H等の不純元素
?鋼中に溶解することになり、溶鋼汚染を起こすなどの
新たな問題が出現した。
This stirring of the slag 6 causes a slag-metal reaction, and impurity elements such as P, S, O, and H in the slag. New problems have emerged, such as melting into the steel and causing molten steel contamination.

(!11題を解決するための手段) この発明は、上記問題点を解消するために成されたもの
であって、その要旨は「環流式真空脱ガス設備において
、真空脱ガス槽の下部に複数個の浸漬管が設けてあり、
これらの全ての管の長さ方向の中間部に環流ガス吹き込
み口を有することを特徴とする溶鋼の真空脱ガス設備、
および前記真空脱ガス設備の浸漬管を取鍋内溶鋼に浸漬
し、任意の位置と数の前記浸漬管から環流ガスを吹き込
んで溶鋼に上昇流をつくり、残りの浸漬管から溶鋼を下
降させ、所定の時間後に環流ガスを吹き込む浸漬管の位
置と数を変化させることにより溶鋼流の方向を変化させ
ることを特徴とする溶鋼の真空脱ガス方法」にある。
(Means for Solving!11 Problems) This invention was made to solve the above problems, and the gist is ``In a recirculation type vacuum degassing equipment, the lower part of the vacuum degassing tank is Multiple dip tubes are provided,
Vacuum degassing equipment for molten steel, characterized by having a reflux gas inlet in the longitudinally intermediate part of all these pipes,
and immersing the immersion tubes of the vacuum degassing equipment into the molten steel in the ladle, blowing reflux gas through arbitrary positions and numbers of the immersion tubes to create an upward flow in the molten steel, and descending the molten steel from the remaining immersion tubes; A method for vacuum degassing of molten steel, characterized in that the direction of the flow of molten steel is changed by changing the position and number of immersion tubes into which circulating gas is blown after a predetermined period of time.

(作用) 全ての浸漬管に環流ガス吹き込み口を設けることにより
、溶鋼流の上昇管と下降管を任意に選定・変化させるこ
とができるから、溶鋼の貯留部が生じないようにするこ
とができ、脱ガス速度を促進させることができる。以下
、この発明の真空脱ガス設備および脱ガス方法について
、第1図を用いて説明する。
(Function) By providing circulating gas inlets in all the immersion pipes, the ascending pipes and descending pipes for the molten steel flow can be selected and changed at will, making it possible to prevent the formation of molten steel reservoirs. , which can accelerate the degassing rate. Hereinafter, the vacuum degassing equipment and degassing method of the present invention will be explained using FIG. 1.

第1図は浸漬管が2本の場合の例示であって、lは真空
脱ガス槽、2^および2Bは浸漬管、3Aおよび3Bは
環流ガス吹き込み口、4は溶鋼、5は取鍋である。なお
、本発明では、浸漬管は複数本であって、例えば4本と
する場合、任意の2本を上昇管、他の2本を下降管とし
て使用する。
Figure 1 shows an example of two immersion tubes, where l is a vacuum degassing tank, 2^ and 2B are immersion tubes, 3A and 3B are reflux gas inlets, 4 is molten steel, and 5 is a ladle. be. In the present invention, if there are a plurality of immersion pipes, for example four, any two of them are used as ascending pipes and the other two are used as descending pipes.

このような構成からなる装置により、本発明法を実施す
るには、溶鋼4を受鋼した取鍋5を真空脱ガス槽lの直
下に配置した後、前記脱ガス槽lを下方に移動して浸漬
管2Aおよび2Bを溶鋼4中に挿入する。同時に脱ガス
槽1内を真空ポンプにより減圧し、溶m4を再浸漬管を
通じて脱ガス槽1内に吸い上げる。
In order to carry out the method of the present invention using an apparatus having such a configuration, the ladle 5 receiving the molten steel 4 is placed directly below the vacuum degassing tank l, and then the degassing tank l is moved downward. and insert the dip tubes 2A and 2B into the molten steel 4. At the same time, the pressure inside the degassing tank 1 is reduced by a vacuum pump, and the melt m4 is sucked up into the degassing tank 1 through the re-immersion pipe.

このような状態において、まづ浸漬管2Aの中間部に設
けられた環流ガス吹き込み口3AからArガス等の環流
ガスを吹き込む。
In such a state, first, a reflux gas such as Ar gas is blown in from the reflux gas blowing port 3A provided in the middle of the immersion tube 2A.

そうすると、環流ガスの上昇によって浸漬管2A内に、
図中実線矢印で示すような溶鋼流が生じ、取鍋5内溶鋼
4が脱ガス槽1内に流入する。流入した溶鋼4は槽内で
脱ガスされたあと、図中実線矢印で示すように浸漬管2
Bを介して取鍋5に戻される。この操業を所定時間継続
したあと、環流ガス吹き込み口3Aからのガスの吹き込
みを止める。
Then, due to the rise of the reflux gas, inside the immersion tube 2A,
A molten steel flow as shown by the solid arrow in the figure is generated, and the molten steel 4 in the ladle 5 flows into the degassing tank 1. After the inflowing molten steel 4 is degassed in the tank, it flows into the immersion pipe 2 as shown by the solid arrow in the figure.
It is returned to the ladle 5 via B. After continuing this operation for a predetermined period of time, the blowing of gas from the recirculation gas blowing port 3A is stopped.

そして、今度は浸漬管2Bの環流ガス吹き込み口3Bか
ら環流ガスを吹き込むのである。そうすると、浸漬管2
B内に図中点線矢印で示すような上昇溶鋼流が生じ、溶
114は脱ガス槽l内に流入する。流入溶鋼は脱ガス槽
l内で脱ガスされたあと、浸漬管2Aを通って取w45
に環流される。
Then, the reflux gas is blown in from the reflux gas blowing port 3B of the immersion tube 2B. Then, dip tube 2
An upward flow of molten steel as shown by the dotted arrow in the figure is generated in B, and the molten steel 114 flows into the degassing tank l. After the inflowing molten steel is degassed in the degassing tank l, it is taken out through the immersion pipe 2A w45.
It is circulated to.

このように、環流ガスを交互に切り換えて吹き込むこと
により、取鍋5内の全体の溶鋼4が環流作用を起こすの
で、局所的な溶鋼の滞留が生じない、その結果、溶鋼環
流率が向上し、処理時間の短縮が図れるのである。
In this way, by alternately switching and blowing the reflux gas, the entire molten steel 4 in the ladle 5 causes a reflux effect, so that local molten steel does not stagnate, and as a result, the molten steel reflux rate improves. , the processing time can be shortened.

ところで、上記のような吹き込みガスの切り換えは、浸
漬管が4本の場合、隣合わせの2本をグループとして上
昇管に、他を下降管としてもよく、相対する2本を上昇
管、他を下降管としてもよい。
By the way, when switching the blowing gas as described above, when there are four immersion pipes, two adjacent pipes may be grouped as ascending pipes and the others may be used as descending pipes, or two opposing pipes may be used as ascending pipes and the others as descending pipes. It can also be used as a pipe.

これらの切り換えは、予め設定したプログラムにしかっ
て自動的に操作することもできる。その切り換え間隔は
60秒以上とするのが好ましい、 60秒未満では、脱
ガス槽l内で溶鋼流の流れの方向が変わる際に、淀みを
生ずる頻度が多くなり、環流率が低下するからである。
These switching operations can also be performed automatically according to a preset program. It is preferable that the switching interval is 60 seconds or more; if it is less than 60 seconds, stagnation will occur more frequently when the flow direction of the molten steel changes in the degassing tank l, and the reflux rate will decrease. be.

(実施例) 本発明法により極低炭素鋼を製造し、脱ガス処理時間と
溶鋼中(C)の変化を調査した。
(Example) Ultra-low carbon steel was manufactured by the method of the present invention, and changes in degassing treatment time and (C) in molten steel were investigated.

なお、本発明の効果を明確にするため、同等の条件で従
来法も実施した。その時の提言条件を第1表に示す。
In order to clarify the effects of the present invention, a conventional method was also carried out under the same conditions. Table 1 shows the proposed conditions at that time.

(以下余白) 第1表 *片側の浸漬管のみ この結果を第4図に示す。(Margin below) Table 1 *One side dip tube only The results are shown in FIG.

第4図から分かるように、従来法では、当初溶鋼中[C
)濃度が295ppmあったものを10 ppmまで低
減するのに15分を要している。
As can be seen from Figure 4, in the conventional method, initially in the molten steel [C
) It took 15 minutes to reduce the concentration from 295 ppm to 10 ppm.

これに対し、本発明法においては、当初(C)濃度29
5pp−からBpp−にするのに11分で行うことがで
き、従来法より約30%短縮できた。
In contrast, in the method of the present invention, the initial (C) concentration is 29
It took 11 minutes to change from 5pp- to Bpp-, which was about 30% shorter than the conventional method.

なお、上記操業では、溶鋼中(C1のみ調査したが、他
の調査では、酸素、水素、窒素等の脱ガスにも同様の効
果があることが確認されている。
In addition, in the above operation, only C1 was investigated in molten steel, but other investigations have confirmed that degassing of oxygen, hydrogen, nitrogen, etc. has a similar effect.

(発明の効果) 上記説明したように、本発明法によれば、両方の浸漬管
に環流ガス吹き込み口を設け、交互に環流ガスを吹き込
むだけで、真空脱ガス処理時間を大幅に短縮でき、生産
性の向上が図られるとともに高級鋼の増産の要請にも十
分に応えられるようになった。
(Effects of the Invention) As explained above, according to the method of the present invention, the vacuum degassing process time can be significantly shortened by simply providing reflux gas blowing ports in both immersion tubes and blowing reflux gas alternately. Not only has productivity been improved, but the company has also been able to fully meet the demand for increased production of high-grade steel.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明を実施する真空脱ガス装置の概略図、 第2図は従来の真空脱ガス装置の図、 第3図は従来の取鍋底部に攪拌ガスを有する真空脱ガス
装置の図、 第4図は本発明法と従来法の真空脱ガス処理時間と溶鋼
中(C)の変化を示す図、である。 1は真空脱ガス槽、2A、2Bは浸漬管、2aは上昇管
、2bは下降管、3.3A、3Bは環流ガス吹き込み口
、4は溶鋼、5は取鍋、6はスラグ、
Fig. 1 is a schematic diagram of a vacuum degassing device implementing the present invention, Fig. 2 is a diagram of a conventional vacuum degassing device, and Fig. 3 is a diagram of a conventional vacuum degassing device having a stirring gas at the bottom of a ladle. , FIG. 4 is a diagram showing the vacuum degassing treatment time and the change in molten steel (C) in the method of the present invention and the conventional method. 1 is a vacuum degassing tank, 2A and 2B are immersion pipes, 2a is a rising pipe, 2b is a descending pipe, 3.3A and 3B are reflux gas inlets, 4 is molten steel, 5 is a ladle, 6 is slag,

Claims (2)

【特許請求の範囲】[Claims] (1)環流式真空脱ガス設備において、真空脱ガス槽の
下部に複数個の浸漬管が設けてあり、これらの全ての管
の長さ方向の中間部に環流ガス吹き込む口を有すること
を特徴とする溶鋼の真空脱ガス設備。
(1) A recirculation type vacuum degassing equipment is characterized in that a plurality of immersion pipes are provided at the bottom of the vacuum degassing tank, and all of these pipes have an opening for blowing the recirculation gas into the middle part in the length direction. Vacuum degassing equipment for molten steel.
(2)特許請求の範囲第1項記載設備の浸漬管を取鍋内
溶鋼に浸漬し、任意の位置と数の前記浸漬管から環流ガ
スを吹き込んで溶鋼に上昇流をつくり、残りの浸漬管か
ら溶鋼を下降させ、所定の時間後に環流ガスを吹き込む
浸漬管の位置と数を変化させることにより溶鋼流の方向
を変化させることを特徴とする溶鋼の真空脱ガス方法。
(2) The immersion tube of the equipment described in claim 1 is immersed in molten steel in a ladle, and reflux gas is blown into the molten steel from arbitrary positions and numbers of immersion tubes to create an upward flow into the molten steel, and the remaining immersion tubes are A vacuum degassing method for molten steel, characterized in that the direction of the molten steel flow is changed by changing the position and number of immersion tubes that blow reflux gas into the molten steel after a predetermined period of time.
JP2175888A 1988-02-01 1988-02-01 Apparatus and method for vacuum degassing molten steel Pending JPH01198418A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2175888A JPH01198418A (en) 1988-02-01 1988-02-01 Apparatus and method for vacuum degassing molten steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2175888A JPH01198418A (en) 1988-02-01 1988-02-01 Apparatus and method for vacuum degassing molten steel

Publications (1)

Publication Number Publication Date
JPH01198418A true JPH01198418A (en) 1989-08-10

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Country Status (1)

Country Link
JP (1) JPH01198418A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011023337A1 (en) 2009-08-28 2011-03-03 Sms Siemag Aktiengesellschaft Device for degassing molten steel with an improved discharge nozzle
CN106435094A (en) * 2016-12-08 2017-02-22 中冶京诚工程技术有限公司 RH method vacuum tank with lifting gas pipeline and arrangement method of lifting gas pipeline thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011023337A1 (en) 2009-08-28 2011-03-03 Sms Siemag Aktiengesellschaft Device for degassing molten steel with an improved discharge nozzle
DE102009039260A1 (en) 2009-08-28 2011-03-03 Sms Siemag Ag Apparatus for degassing a molten steel with an improved spout
CN106435094A (en) * 2016-12-08 2017-02-22 中冶京诚工程技术有限公司 RH method vacuum tank with lifting gas pipeline and arrangement method of lifting gas pipeline thereof

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