JPH0119571B2 - - Google Patents
Info
- Publication number
- JPH0119571B2 JPH0119571B2 JP3747382A JP3747382A JPH0119571B2 JP H0119571 B2 JPH0119571 B2 JP H0119571B2 JP 3747382 A JP3747382 A JP 3747382A JP 3747382 A JP3747382 A JP 3747382A JP H0119571 B2 JPH0119571 B2 JP H0119571B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- general formula
- sensitizing dye
- silver halide
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000001235 sensitizing effect Effects 0.000 claims description 70
- -1 silver halide Chemical class 0.000 claims description 60
- 229910052709 silver Inorganic materials 0.000 claims description 38
- 239000004332 silver Substances 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 35
- 125000000217 alkyl group Chemical group 0.000 claims description 26
- 150000001450 anions Chemical class 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- 125000005843 halogen group Chemical group 0.000 claims description 11
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 10
- 125000003545 alkoxy group Chemical group 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 8
- 125000003277 amino group Chemical group 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 125000002252 acyl group Chemical group 0.000 claims description 2
- 125000004466 alkoxycarbonylamino group Chemical group 0.000 claims description 2
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 2
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000000975 dye Substances 0.000 description 81
- 239000000839 emulsion Substances 0.000 description 37
- 125000004432 carbon atom Chemical group C* 0.000 description 22
- 238000000034 method Methods 0.000 description 21
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 18
- 206010070834 Sensitisation Diseases 0.000 description 18
- 230000008313 sensitization Effects 0.000 description 18
- 239000000203 mixture Substances 0.000 description 12
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000011161 development Methods 0.000 description 9
- 238000004321 preservation Methods 0.000 description 9
- 239000000523 sample Substances 0.000 description 9
- 230000035945 sensitivity Effects 0.000 description 9
- 230000003595 spectral effect Effects 0.000 description 9
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 8
- 125000001309 chloro group Chemical group Cl* 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000013068 control sample Substances 0.000 description 7
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 7
- WMUIZUWOEIQJEH-UHFFFAOYSA-N benzo[e][1,3]benzoxazole Chemical group C1=CC=C2C(N=CO3)=C3C=CC2=C1 WMUIZUWOEIQJEH-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- 238000000586 desensitisation Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 4
- 229910021612 Silver iodide Inorganic materials 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 239000008273 gelatin Substances 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 235000011852 gelatine desserts Nutrition 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 4
- 229940045105 silver iodide Drugs 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229920002284 Cellulose triacetate Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 3
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 3
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 239000004848 polyfunctional curative Substances 0.000 description 3
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 206010034960 Photophobia Diseases 0.000 description 2
- 206010034972 Photosensitivity reaction Diseases 0.000 description 2
- 229910021607 Silver chloride Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- GYTPOXPRHJKGHD-UHFFFAOYSA-N benzo[f][1,3]benzoxazole Chemical group C1=CC=C2C=C(OC=N3)C3=CC2=C1 GYTPOXPRHJKGHD-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 208000013469 light sensitivity Diseases 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000036211 photosensitivity Effects 0.000 description 2
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000005070 ripening Effects 0.000 description 2
- 229930182490 saponin Natural products 0.000 description 2
- 150000007949 saponins Chemical class 0.000 description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 2
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- LUMLZKVIXLWTCI-NSCUHMNNSA-N (e)-2,3-dichloro-4-oxobut-2-enoic acid Chemical compound OC(=O)C(\Cl)=C(/Cl)C=O LUMLZKVIXLWTCI-NSCUHMNNSA-N 0.000 description 1
- ZKGIQGUWLGYKMA-UHFFFAOYSA-N 1,2-bis(ethenylsulfonyl)ethane Chemical compound C=CS(=O)(=O)CCS(=O)(=O)C=C ZKGIQGUWLGYKMA-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- PXDAXYDMZCYZNH-UHFFFAOYSA-N 3-methyl-2h-1,3-benzothiazole Chemical compound C1=CC=C2N(C)CSC2=C1 PXDAXYDMZCYZNH-UHFFFAOYSA-N 0.000 description 1
- INVVMIXYILXINW-UHFFFAOYSA-N 5-methyl-1h-[1,2,4]triazolo[1,5-a]pyrimidin-7-one Chemical compound CC1=CC(=O)N2NC=NC2=N1 INVVMIXYILXINW-UHFFFAOYSA-N 0.000 description 1
- DOHPJVZVZNYFRH-UHFFFAOYSA-N 5-methyl-[1,2,4]triazolo[1,5-a]pyrimidine Chemical compound N1=C(C)C=CN2N=CN=C21 DOHPJVZVZNYFRH-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RPWFJAMTCNSJKK-UHFFFAOYSA-N Dodecyl gallate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 RPWFJAMTCNSJKK-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Chemical class 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical class O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical class [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- 150000001541 aziridines Chemical class 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000000298 carbocyanine Substances 0.000 description 1
- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- ZUIVNYGZFPOXFW-UHFFFAOYSA-N chembl1717603 Chemical compound N1=C(C)C=C(O)N2N=CN=C21 ZUIVNYGZFPOXFW-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- KYQODXQIAJFKPH-UHFFFAOYSA-N diazanium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [NH4+].[NH4+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O KYQODXQIAJFKPH-UHFFFAOYSA-N 0.000 description 1
- 239000000555 dodecyl gallate Substances 0.000 description 1
- 229940080643 dodecyl gallate Drugs 0.000 description 1
- 235000010386 dodecyl gallate Nutrition 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000006627 ethoxycarbonylamino group Chemical group 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002545 isoxazoles Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N methanesulfonic acid Substances CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- QWYZFXLSWMXLDM-UHFFFAOYSA-M pinacyanol iodide Chemical compound [I-].C1=CC2=CC=CC=C2N(CC)C1=CC=CC1=CC=C(C=CC=C2)C2=[N+]1CC QWYZFXLSWMXLDM-UHFFFAOYSA-M 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- HERBOKBJKVUALN-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O HERBOKBJKVUALN-UHFFFAOYSA-K 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/28—Sensitivity-increasing substances together with supersensitising substances
- G03C1/29—Sensitivity-increasing substances together with supersensitising substances the supersensitising mixture being solely composed of dyes ; Combination of dyes, even if the supersensitising effect is not explicitly disclosed
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
Description
æ¬çºæã¯å¢æè²çŽ ã®æ°èŠãªçµåã䜿çšã«ãã匷
è²å¢æãããããã²ã³åéåçæå ææã«é¢ãã
ãã®ã§ãããæŽã«è©³ããã¯ã匷è²å¢æããããã€
ä¿åæ§ã®æ¹è¯ãããç¹ã«ãç·ææ§ããã²ã³åéå
çä¹³å€å±€ãæããŠãªãããã²ã³åéåçæå ææ
ïŒä»¥äžåã«ãæå ææãšèšãïŒã«é¢ãããã®ã§ã
ãã åŸæ¥ãæå ææã®ä¹³å€ã«å¢æè²çŽ ãå ããæå
ææã®ä¹³å€ã®æå æ³¢é·åãæ¡å€§ããåå çã«å¢æ
ããããšããããšã¯ç¥ãããŠãããããã®ç®çã®
çºã«äœ¿çšããå¢æè²çŽ ãéžæããå Žåãåºæ¬çã«
æºè¶³ãããã¹ãè«žæ¡ä»¶ãšããŠã¯ãäŸãã°ã次ã®æ§
ãªæ¡ä»¶ãèããããã ïŒ åå å¢ææ³¢é·åãé©åã§ããããš ïŒ åå å¢ææ床ãããé«ãããš ïŒ åççã«ãæªåœ±é¿ãäžããªãããšïŒå¢æè²çŽ
以å€ã®åççšæ·»å ç©ãšã®éã«æªãçžäºäœçšããª
ãããšïŒ ïŒ ããã²ã³åéåçä¹³å€ããã³æå ææãšããŠ
ã®ä¿åäžã§ã®æå 床ã®äœäžåã³å€åãå°ãªãã
ãš ïŒ ã«ããªã®çºçãå°ãªãããš ïŒ å¢æè²çŽ ãä»ã®æå å±€ãžæ¡æ£ããªãããš ïŒ çŸååŠçåŸã«è²çŽ æ±æãèµ·ããªãã㚠以äžã®æ¡ä»¶ããããããããããã«ãããã²ã³
åéåçä¹³å€ãå¡èšããŠåŸãããæå ææãé²å
ããåŸã«ãããã²ã³åéåçä¹³å€äžã«åœ¢æããã
æœåããé·æéã®ä¿åäžã«çµæãšããŠåçç¹æ§ç
ã«å€åããªãããšãéèŠã§ããããã®æœåã®ä¿å
æ§ã¯å€å±€ã«ã©ãŒæå ææã«ãããŠã¯ãåå±€ã®åç
æ§èœã®ç°ãªã€ãå€åã瀺ããå Žåãã«ã©ãŒãã©ã³
ã¹ããããè¯å¥œãªè²åçŸãåŸãããªããªããšãã
ããšã§ããããã®æœåã®ä¿åæ§ã¯å€§ããªåé¡ãšãª
ãããŸãæå ææã®é²å åã®ä¿åã«ããåçæ§èœ
ã®å€åã«ã€ããŠãåæ§ã§ãããä¿åããŠãåå±€ã®
å€åãã»ãšãã©ãªããããŸãã¯ãåå±€ããã©ã³ã¹
ããå€åããäºãæå ææã®åçç¹æ§äžéèŠãšã
ããã®ã§ããã ããã²ã³åéä¹³å€ã®åå å¢æã¯ïŒçš®é¡ã®å¢æè²
çŽ ã䜿çšããŠè¡ãªãããšãããã奜ãŸããåå å¢
æãè¡ãªãããã«ã¯ãéåžžïŒçš®ä»¥äžã®å¢æè²çŽ ã
çµåããŠäœ¿çšããå Žåãå€ãããã®å Žåã«ã¯åŒ·è²
å¢æäœçšãæããå¢æè²çŽ ãéžæã䜿çšããããš
ãäžè¬çã§ããããã®ãããªç®çã«åããããªå
å å¢ææè¡ãã€ãŸãé«æ床ã§è¯å¥œãªè²åçŸãäžã
åŸãé©åãªæ³¢é·åãåå å¢æããå¢æè²çŽ ã®çµå
ãã¯åŸæ¥ããå€ãã®äººã ã«ããç 究ãããŠããã
ããããªãããåŸæ¥ã®æè¡ã¯æå ææã®ä¿åäžã«
ãããŠãåçæ§èœã®å€åããããæ¬ é¥ããã€ãã®
ãå€ããšããããšãæã ã®ç 究ã§å€æãããäŸã
ã°ãç¹å ¬æ44â32753å·å ¬å ±çã«èšèŒãããŠãã
ãªããµã«ã«ãã·ã¢ãã³è²çŽ ãçšããå¢ææè¡ã§
ã¯ãæœåã®ä¿åæã®å€åã¯æœåéè¡ïŒé²å ã«ãã
ããã²ã³åéä¹³å€äžã«çããæœåããé žçŽ ã湿床
ã«ãã圱é¿ã§ãã®äžéšãç Žå£ããå®è³ªçã«æžæã
ãæ§ã«ãªãå Žåãæœåéè¡ãšãããïŒåŸåã瀺ã
ãã®ããããæŽã«ãé²å 以åã®æå ææã®ä¿åäž
ã«ãæžæãããããã®ãããããŸããç±³åœç¹èš±ç¬¬
2973264å·ãå第3173791å·ãå第3364031å·ãå
第3397060å·ãå第3506443å·ãç¹å ¬æ47â37443
å·å ¬å ±ãç¹å ¬æ48â28293å·å ¬å ±çã§ç¥ãããŠã
ãã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ ãçšããå¢ææ
è¡ã§ã¯ãæœåã®ä¿åæã®å€åã¯æœåé²è¡ïŒæœåé²
è¡ãšã¯éã«å®è³ªçã«å¢æããæ§ã«ãªãå Žåãèš
ããé²å åŸããçŸååŠçãè¡ãªã€ãå Žåã«ã¯ãçŸ
象ãããªãæ§ãªããã²ã³åéç²åã®äžéšãä¿åäž
ã«çŸåå¯èœãšãªãå Žåãæœåé²è¡ãšãããïŒåŸå
ã瀺ããã®ãå€ãããŸãæå ææã®ä¿åäžã«ãæž
æããã³åŒ·ãã«ããªãçºçãããã®ãå€ãããã
ã«å®¶å ·çããçºçãããã«ããªã³ã¬ã¹ã«ãããç¹
ç°çã«ã«ããªãçºçãããã®ãããã ãŸããç¹å ¬æ54â34535å·å ¬å ±ãç¹å ¬æ56â
38936å·å ¬å ±ãç¹éæ51â126140å·çã«èšèŒãã
ãŠããã¢ãã¡ãã³è²çŽ ãçšããå¢ææè¡ã§ã¯ãæœ
åã®ä¿åæã®å€åã¯æœåéè¡åŸåã瀺ããé²å å
ã®ä¿åã§ã¯æžæãããããã®ãããã ãã®ããã«åŸæ¥ããç¥ãããŠããå¢ææè¡ããš
ãã«ç·ææ§åå å¢ææè¡ã¯ãåªãã匷è²å¢æäœçš
ãè¯å¥œãªè²åçŸãåŸãããšãã§ããé©åãªåå æ³¢
é·åãåå å¢æããããæå ææã®ä¿åäžã§ã®æ§
èœã®å€åãèŠããä¿ååŸã«ã¯è¯å¥œãªè²åçŸãåŸã
ããªããã®ãå€ãèŠãããã åŸã€ãŠãæ¬çºæã®ç¬¬ïŒã®ç®çã¯ãæ®åœ±åŸæå æ
æãé·æéä¿åããå Žåã§ãæœåã®å€åãæ®ãã©
ãªãä¿åã«å¯ŸããŠåçç¹æ§ãå®å®ãªæå ææãæ
äŸããäºã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯æå ææã®è£œé åŸãé·æ
éã®ä¿åã«éããŠãæå 床ã®äœäžãã«ããªã®çºç
ã®å°ãªãå®å®ãªæå ææãæäŸããäºã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãç·è²æ³¢é·ååå å¢æã«
éããŠãé©åãªæ³¢é·åã«åå å¢æãããè²åçŸæ§
ã®è¯å¥œãªããã²ã³åéåçä¹³å€ãæäŸããããšã«
ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãç·è²æ³¢é·åãé«åºŠã«å
å å¢æããããªããã€çŸååŠçåŸã®æå ææã«è²
çŽ æ±æã®çããããšã®ãªãå¢æè²çŽ ã«ããåå å¢
æãããããã²ã³åéåçä¹³å€ãæäŸããããšã§
ããã æ¬çºæã®åèšã®ç®çã¯ãäžèšäžè¬åŒããã§è¡š
ããããå¢æè²çŽ ã®å°ãªããšãäžçš®ãšãäžèšäžè¬
åŒããã§è¡šããããå¢æè²çŽ ã®å°ãªããšãäžçš®
ãšããã«äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ
ã®å°ãªããšãäžçš®ãšãçµåãå«æããæå ææã«
ããéæãããããšãèŠãåºããã äžè¬åŒãã åŒäžãY1ãY2ãY3ããã³Y4ã¯ãã®ãã®ãæ°ŽçŽ
ååãããã²ã³ååãïŒããšãã°å¡©çŽ ååãèçŽ
ååïŒäœçŽã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒ
ãïŒã®ã¢ã«ãã«åºïŒããšãã°ã¡ãã«ããšãã«ïŒïŒã
ã¢ã«ã³ãã·åºïŒããšãã°ã¡ããã·ããšããã·ïŒã
ããããã·ãã«ã«ããã·ãã¢ãªãŒã«åºïŒããšãã°
ããšãã«ïŒãã·ã¢ããã¢ããåºïŒããšãã°ã¢ããã
ã¡ãã«ã¢ããïŒãããªãã«ãªãã¡ãã«ãã¢ã«ã³ã
ã·ã«ã«ããã«åºïŒããšãã°ã¡ããã·ã«ã«ããã«ã
ãšããã·ã«ã«ããã«ïŒãã«ã«ãã¢ã«ã³ãã·åºïŒã
ãšãã°ã«ã«ããšããã·ãã«ã«ãããããã·ïŒãã¢
ã·ã«ã¢ããåºïŒããšãã°ã¢ã»ãã¢ããïŒãã¢ã»ã
ãã·åºïŒããšãã°ã¢ã»ããã·ïŒãã¢ã·ã«åºïŒããš
ãã°ã¢ã»ãã«ïŒããŸãã¯ã¢ã«ã³ãã·ã«ã«ããã«ã¢
ããåºïŒããšãã°ãšããã·ã«ã«ããã«ã¢ããïŒã
è¡šãããY1ãšY2ãY3ãšY4ã¯ããããäºãã«é£çµ
ããŠç°ã圢æããŠãããïŒããããªããµãŸãŒã«ç°
ïŒããšãã°ããããïŒïŒïŒâïœããªããµãŸãŒã«
ç°ïŒïŒãR1ã¯æ°ŽçŽ ååãäœçŽã¢ã«ãã«åºïŒå¥œãŸã
ãã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«åºïŒããšãã°ã¡
ãã«ããšãã«ïŒïŒãè¡šãããR2ãšR3ã¯ãã®ãã®ã¢
ã«ãã«åºïŒå¥œãŸããã¯ã¹ã«ããŸãã¯ã«ã«ããã·ã§
眮æãããŠããããããã¯é眮æã®ãççŽ ååæ°
ïŒãïŒã®ã¢ã«ãã«ïŒããšãã°ãšãã«ãã¹ã«ããšã
ã«ïŒïŒãè¡šãããX1 ã¯ã¢ããªã³ãè¡šãããn1ã¯
ïŒãŸãã¯ïŒãè¡šãããïŒååå å¡©ã圢æããå Žå
ã¯ïŒã§ãããïŒ äžè¬åŒãã åŒäžãY5ãY6ãY7ããã³Y8ã¯ãã®ãã®ãæ°ŽçŽ
ååãããã²ã³ååïŒããšãã°å¡©çŽ ååãèçŽ å
åïŒã¢ã«ã³ãã·åºïŒããšãã°ã¡ããã·ããšãã
ã·ïŒãã¢ããåºãã¢ã·ã«ã¢ããåºïŒããšãã°ã¢ã»
ãã¢ããïŒãã¢ã»ããã·åºïŒããšãã°ã¢ã»ãã
ã·ïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒããšãã°ã¡ãã
ã·ã«ã«ããã«ïŒãã¢ã«ãã«ã¹ã«ããã«åºïŒããšã
ã°ã¡ãã«ã¹ã«ããã«ïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒããš
ãã°ã¡ãã«ã¹ã«ãã¢ã¢ã€ã«ïŒãã·ã¢ãåºããŸãã¯
ããªãã«ãªãã¡ãã«ãè¡šãããR4ãR5ãR6ãã
ã³R7ã¯ãã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒ
ãïŒã®çœ®æãé眮æã®ã¢ã«ãã«ïŒããšãã°ããšã
ã«ãã¹ã«ããšãã«ïŒã§ããããŸãé žçŽ ååçãä»
åšããŠããããïŒX2 ã¯ã¢ããªã³ãè¡šãããn2ã¯
ïŒãŸãã¯ïŒãè¡šãããïŒååå å¡©ã圢æããå Žå
ã¯ïŒã§ãããïŒ äžè¬åŒãã åŒäžãY9ãY10ãY11ããã³Y12ã¯ããã®ãã®ã
æ°ŽçŽ ååãããã²ã³ååïŒããšãã°å¡©çŽ ååïŒã
äœçŽã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒãïŒã®
ã¢ã«ãã«åºïŒããšãã°ã¡ãã«ïŒãã¢ã«ã³ãã·åº
ïŒããšãã°ã¡ããã·ïŒãã¢ã«ã³ãã·ã«ã«ããã«åº
ïŒããšãã°ã¡ããã·ã«ã«ããã«ïŒãããããã·ãã«
ã«ããã·ãã¢ãªãŒã«åºïŒããšãã°ããšãã«ïŒããŸ
ãã¯ããªãã«ãªãã¡ãã«ãè¡šãããY9ãšY10ã
Y11ãšY12ã¯ããããäºãã«é£çµããŠç°ã圢æã
ãŠãããïŒããããªããµãŸãŒã«ç°ïŒããšãã°ãã
ããïŒïŒïŒâïœããªããµãŸãŒã«ç°ïŒïŒãR8ãR9ã¯
ã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒãïŒã®çœ®
æãé眮æã®ã¢ã«ãã«ïŒããšãã°ãšãã«ãã¹ã«ã
ãšãã«ïŒïŒãè¡šãããX3 ã¯ã¢ããªã³ãè¡šããã
n3ã¯ïŒãŸãã¯ïŒãè¡šãããïŒååå å¡©ã圢æãã
å Žåã¯ïŒã§ãããïŒ æ¬çºæã«ãããŠãåèšäžè¬åŒããã§è¡šããã
ãå¢æè²çŽ ã®äžã§ç¹ã«æçšãªå¢æè²çŽ ã¯ãäžèšäž
è¬åŒããã§è¡šããããšãã§ããã äžè¬åŒãã åŒäžãY13ãY14ãY15ããã³Y16ã¯ããããã
æ°ŽçŽ ååãããã²ã³ååïŒããšãã°å¡©çŽ ååãè
çŽ ååïŒãççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«åºïŒããš
ãã°ã¡ãã«ããšãã«ïŒãççŽ ååæ°ïŒãïŒã®ã¢ã«
ã³ãã·åºïŒããšãã°ã¡ããã·ããšããã·ïŒããã
ããã·ãã«ã«ããã·ãã¢ãªãŒã«åºïŒããšãã°ããš
ãã«ïŒãã¢ã·ã«ã¢ããåºïŒããšãã°ã¢ã»ãã¢ã
ãïŒãã¢ã»ããã·åºïŒããšãã°ã¢ã»ããã·ïŒãããª
ãã«ãªãã¡ãã«ãççŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·
ã«ã«ããã«åºïŒããšãã°ã¡ããã·ã«ã«ããã«ïŒã
ççŽ ååæ°ïŒãïŒã®ã«ã«ãã¢ã«ã³ãã·åºïŒããšã
ã°ã«ã«ããšããã·ïŒãè¡šããããŸããY13ãšY14ã
Y15ãšY16ã¯ããããäºãã«é£çµããŠç°ã圢æã
ãŠãããïŒããããªããµãŸãŒã«ç°ïŒããšãã°ãã
ããïŒïŒïŒâïœããªããµãŸãŒã«ç°ïŒïŒãA1ã¯ççŽ
ååæ°ïŒãïŒãŸã§ã®ã¢ã«ãã¬ã³åºïŒããšãã°ãšã
ã¬ã³ïŒãè¡šãããR10ã¯R1ã§ç€ºãããã®ãšåãã
ã®ãè¡šãããR11ã¯ã¹ã«ããŸãã¯ã«ã«ããã·ã§çœ®
æãããã¢ã«ãã«ãŸãã¯é眮æã®ççŽ ååæ°ïŒã
ïŒã®ã¢ã«ãã«ïŒããšãã°ãšãã«ãã¹ã«ããšãã«ïŒ
ãè¡šãããX4 ã¯ã¢ããªã³ãè¡šãããn4ã¯ïŒå
ã¯ïŒãè¡šãããïŒååå å¡©ã圢æããå Žåã¯ïŒã§
ãããïŒ äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ ã®ã
ã¡ãäžã§ãç¹ã«æçšãªå¢æè²çŽ ã¯ãäžèšäžè¬åŒ
ããããã³ããã§è¡šããããšãã§ããã äžè¬åŒãã äžè¬åŒãã åŒäžãY17ãY18ã¯ãããã²ã³ååïŒããšãã°
å¡©çŽ ååïŒãã¢ãªãŒã«åºïŒããšãã°ããšãã«ïŒã
è¡šããã A2ãA3ã¯A1ã§ç€ºãããã®ãšåããã®ãè¡šã
ããR12ãR14ã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«åº
ïŒããšãã°ã¡ãã«ïŒãè¡šãããR13ãR15ã¯R11ã§
瀺ãããã®ãšåããã®ãè¡šãããX5 ãšX6 ã¯ã
ã¢ããªã³ãè¡šãããn5ãšn6ã¯ãããããïŒåã¯ïŒ
ãè¡šãããïŒn4ã®å Žåãšåãäºã瀺ããïŒ æ¬çºæã«ãããŠåèšäžè¬åŒããã§è¡šãããã
å¢æè²çŽ ã®äžã§ç¹ã«æçšãªå¢æè²çŽ ã¯äžèšäžè¬åŒ
ããã§è¡šããããšãã§ããã äžè¬åŒãã åŒäžãY19ãY20ãY21ããã³Y22ã¯ããããã
æ°ŽçŽ ååãããã²ã³ååïŒããšãã°å¡©çŽ ååãè
çŽ ååïŒãã¢ããåºãã¢ã·ã«ã¢ããåºïŒããšãã°
ã¢ã»ãã¢ããïŒãççŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·
ã«ã«ããã«åºïŒããšãã°ã¡ããã·ã«ã«ããã«ïŒã
ãŸãã¯ã·ã¢ããè¡šãããR16ãR17ã¯ççŽ ååæ°
ïŒãïŒã®ã¢ã«ãã«åºïŒããšãã°ãšãã«ïŒã§ããã
é žçŽ ååçãä»åšããŠããŠããããR18ãR19ã¯ã
ã¹ã«ããŸãã¯ã«ã«ããã·ã§çœ®æãããŠããããã
ãã¯é眮æã®ãççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«ïŒã
ãšãã°ãšãã«ãã¹ã«ããšãã«ïŒã§ãããé žçŽ åå
çãä»åšããŠããŠããããåãå°ããšãäžæ¹ãã¹
ã«ãã¢ã«ãã«åºãã«ã«ããã·ã¢ã«ãã«åºã§ããã
X7 ã¯ã¢ããªã³ã§ããn7ã¯ïŒåã¯ïŒã§ãããn2
ã§ç€ºãããã®ãšåãã§ããã äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ ã®ã
ã¡ãäžã§ãç¹ã«æçšãªå¢æè²çŽ ã¯äžèšäžè¬åŒ
ããã§è¡šããããšãã§ããã äžè¬åŒãã åŒäžãY23ãšY24ã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ã
ã«åºïŒããšãã°ãšãã«ïŒãè¡šãããR20ãšR21ã¯
ããããR16ãR17ãšåããã®ãè¡šãããR22ãš
R23ã¯ããããR18ãR19ãšåããã®ãè¡šãããX8
ã¯ã¢ããªã³ãè¡šãããn8ã¯n7ãšåããã®ãè¡šã
ãã æ¬çºæã«ãããŠåèšäžè¬åŒããã§è¡šãããã
å¢æè²çŽ ã®äžã§ç¹ã«æçšãªå¢æè²çŽ ã¯ãäžèšäžè¬
åŒããã§è¡šããããšãã§ããã äžè¬åŒãã åŒäžãY25ãY26ããã³Y27ã¯ãããããæ°ŽçŽ å
åãããã²ã³ååïŒããšãã°å¡©çŽ ååïŒãççŽ å
åæ°ïŒãïŒã®ã¢ã«ãã«åºïŒããšãã°ã¡ãã«ïŒãç
çŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·åºïŒããšãã°ã¡ãã
ã·ïŒãççŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·ã«ã«ããã«
åºïŒããšãã°ã¡ããã·ã«ã«ããã«ïŒãããããã·ã
ã«ã«ããã·ãã¢ãªãŒã«åºïŒããšãã°ããšãã«ïŒã
ãŸãã¯ãããªãã«ãªãã¡ãã«ãè¡šããã Y25ãšY26ã¯äºãã«é£çµããŠç°ã圢æããŠãã
ããªããµãŸãŒã«ç°ïŒããšãã°ããããïŒïŒïŒâ
ïœããªããµãŸãŒã«ç°ïŒã圢æããŠããããR24ãš
R25ã¯ãã¹ã«ããŸãã¯ã«ã«ããã·ã§çœ®æãããŠã
ãããããã¯é眮æã®ãççŽ ååæ°ïŒãïŒã®ã¢ã«
ãã«ãè¡šãããX9 ã¯ã¢ããªã³ãè¡šãããn9ã¯ã
n3ãšåãã§ããã äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ ã®ãã¡
ç¹ã«æçšãªå¢æè²çŽ ã¯äžèšäžè¬åŒããã§è¡šãã
ããšãã§ããã äžè¬åŒãã åŒäžãY28ãšY29ã¯ãããããæ°ŽçŽ ååããã
ã²ã³ååïŒããšãã°å¡©çŽ ååïŒãççŽ ååæ°ïŒã
ïŒã®ã¢ã«ãã«åºïŒããšãã°ã¡ãã«ïŒãççŽ ååæ°
ïŒãïŒã®ã¢ã«ã³ãã·åºïŒããšãã°ã¡ããã·ïŒãç
çŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·ã«ã«ããã«åºïŒããš
ãã°ã¡ããã·ã«ã«ããã«ïŒãã¢ãªãŒã«åºïŒããšã
ã°ããšãã«ïŒããŸãã¯ããªãã«ãªãã¡ãã«ãè¡šã
ããA4ã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ãã¬ã³åºïŒã
ãšãã°ãšãã¬ã³ïŒãè¡šãããR26ã¯R24ããã³R26
ãšåããã®ãè¡šãããX10ã¯ã¢ããªã³ãè¡šããã
n10ã¯n9ãšåãæå³ãè¡šããã æ¬çºæã®äžè¬åŒããããã³ããã§è¡šããã
ãå¢æè²çŽ ã¯ç±³åœç¹èš±ç¬¬3397060å·ãå第3506443
å·çã«èšèŒãããŠããããŸããäžè¬åŒããã§è¡š
ããããå¢æè²çŽ ã¯ç±³åœç¹èš±ç¬¬3149105å·çã«èš
èŒãããŠããããŸãäžèšã®ç¹èš±ã«èšèŒã®ãªãå¢æ
è²çŽ ãäžèšç¹èš±ã®æ¹æ³ã«æºããŠåœè©²æ¥è ã容æã«
åæããããšãã§ããã 以äžã«æ¬çºæã«ãããŠçšããããäžè¬åŒããã
ããåã³ããã«ãã€ãŠè¡šããããå¢æè²çŽ ã®
代衚çãªãã®ã瀺ãããæ¬çºæããããã«éå®ã
ãããã®ã§ã¯ãªãã ïŒäžè¬åŒããã®äŸç€ºååç©ïŒ æ¬çºæã®åèšäžè¬åŒãããããããã³ãã
ã§è¡šããããå¢æè²çŽ ãããã²ã³åéåçä¹³å€ã«
æ·»å ããããå Žåã®å¥œãŸããæ·»å éã¯ããã²ã³å
éïŒã¢ã«ãããå¢æè²çŽ ãããïŒÃ10-4ã¢ã«ãª
ãã2.5Ã10-3ã¢ã«ãç¹ã«å¥œãŸããã¯ã1.5Ã10-4
ã¢ã«ãªãã1.2Ã10-3ã¢ã«ã§ãããå¢æè²çŽ ãã
ã¯ãåãã1.5Ã10-6ã¢ã«ãªããïŒÃ10-3ã¢ã«ã
奜ãŸãããç¹ã«å¥œãŸããã¯3.5Ã10-6ã¢ã«ãªãã
1.5Ã10-4ã¢ã«ã§ãããå¢æè²çŽ ããã¯åãã
1.2Ã10-5ã¢ã«ãªãã1.5Ã10-3ã¢ã«ã奜ãŸããã
ç¹ã«å¥œãŸããã¯ïŒÃ10-5ã¢ã«ãªããïŒÃ10-4ã¢ã«
ã®ç¯å²ã§ããããŸãæ¬çºæã®åå¢æè²çŽ ã®å¥œãŸã
ã䜿çšæ¯çã¯ãå¢æè²çŽ ããïŒå¢æè²çŽ ãã
ã¯ã¢ã«æ¯ã§340ïŒïŒãªããïŒïŒïŒãééæ¯ã§ã¯
200ïŒïŒãªããïŒïŒïŒã®ç¯å²ã§ããããŸãå¢æè²
çŽ ããïŒå¢æè²çŽ ããã¯ãã¢ã«æ¯ã§ïŒïŒ170
ãªããïŒïŒ0.2ãééæ¯ã§ïŒïŒ80ãªããïŒïŒ0.2ã®
ç¯å²ã§ããããŸãäžèšç¯å²ã®ãªãã§å¢æè²çŽ
ãããããããã³ããã®æ¯çã¯ãã¢ã«æ¯ãªã
ã³ã«ééæ¯ãšãã«å¢æè²çŽ ããããã€ãšãå€
ããå¢æè²çŽ ããããã€ãšãå°ãªãæ¡ä»¶ã«ãã
ãŠãæ¬çºæã®å¹æããã€ãšãé¡èã«çºæ®ãããã
ãŸãäžèšç¯å²å ã§å¢æè²çŽ ããã«å¯ŸããŠå¢æè²
çŽ ãããããã®æ·»å éãå€åãããããšã§ä»ã®
è«žç¹æ§ãå€åãããªãã§åœè©²å±€ã®æœåã®ä¿åã«ã
ããå€åå·Ÿãªãã³ã«å€åæ¹åãå€åãããããšã
å¯èœã§ããããã®ããšã¯ç¹ã«å€å±€ã«ã©ãŒæå ææ
ã®å Žåã«ãããŠç·æå±€ãèµ€æå±€ããã³éæå±€ã®å€
åå·Ÿãªãã³ã«å€åæ¹åã«åèŽããã³ã³ãããŒã«ã
ãããšããè¯å¥œãªè²åçŸãç¶æããçºã«ã¯å¿ èŠãª
å Žåãããããããé¢ã§ããã®ããšã¯ãæ¬çºæã®
å¹æã®å€§ããªç¹åŸŽã®äžã€ã§ãããæ¬çºæã®å¢æè²
çŽ ãããã²ã³åéåçä¹³å€äžã«æ·»å ããææãšã
ãŠã¯ãä¹³å€ã®ç¬¬çæäžãããã¯å¡åžã«å ç«ã€ãŠ
æ·»å ããã®ãåšç¥ã®æ¹æ³ã§ãããæ¬çºæãåæ§ã§
ãããããã奜ãŸããå¹æãçºæ®ãããçºã«ã¯ã
å¢æè²çŽ ããããã³ãããå ã«æ·»å ãããã
ãåŸã«æ·»å ããã®ããããããã«ã¯å¢æè²çŽ
ããããã³ããã第çæäžã«æ·»å ããã
ã¯å¡åžã«å ç«ã€ãŠæ·»å ããæ¹ããã€ãšãèããå¹
æãçºæ®ããã ãŸãæ¬çºæã®åèšåäžè¬åŒã§ç€ºãããå¢æè²çŽ
ãäžèšåçä¹³å€ã«æ·»å ããæ¹æ³ãšããŠã¯åŸæ¥ãã
ææ¡ãããŠããçš®ã ã®æ¹æ³ãé©çšã§ãããäŸãã°
ç±³åœç¹èš±ç¬¬3469987å·ã«èšèŒãããåŠããå¢æè²
çŽ ãæ®çºæ§ææ©æº¶åªã«æº¶è§£ãã該溶液ã芪氎æ§ã³
ãã€ãäžã«åæ£ãããã®åæ£ç©ãä¹³å€ã«æ·»å ãã
æ¹æ³ã«ããè¡ãªã€ãŠãããããŸãããã«ãæ¬çºæ
ã®å¢æè²çŽ ã¯ãåã ã«ãåäžãŸãã¯ç°ãªã溶åªã«
溶解ããä¹³å€ã«æ·»å ããåã«ããããã®æº¶æ¶²ãæ··
åããããå¥ã ã«æ·»å ããããšãã§ããã æ¬çºæã®åèšåäžè¬åŒã§ç€ºãããå¢æè²çŽ ãã
ãã²ã³åéåçä¹³å€ã«æ·»å ãããšãã®è²çŽ ã®æº¶åª
ãšããŠã¯ãäŸãã°ã¡ãã«ã¢ã«ã³ãŒã«ããšãã«ã¢ã«
ã³ãŒã«ãã¢ã»ãã³çã®æ°Žæ··åæ§ææ©æº¶åªã奜ãŸã
ãçšããããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã«çšããããã
ãã²ã³åéã®çµæãšããŠã¯ãäŸãã°å¡©åéãèå
éãæ²åéãå¡©èåéãæ²èåéãå¡©æ²èåéç
åçš®ã®ãã®ã䜿çšããããšãã§ããããç¹ã«æ²è
åéã®äœ¿çšãé©ããŠããããŸããã®ç²åŸã¯0.2ã
2.0ÎŒçšåºŠã奜ãŸãããããã®ç¯å²ã«éå®ãããã
ã®ã§ã¯ãªãããããŠãããã®ããã²ã³åéç²å
ã¯ãå ¬ç¥ã®äŸãã°ã·ã³ã°ã«ãžãšããæ³ãããã«ãž
ãšããæ³ãããã¯ã³ã³ãããŒã«ããã«ãžãšããæ³
ã®ãããªå皮混åæ³ã«ãã圢æãããããã®ãã
ã«åœ¢æãããããã²ã³åéç²åã®æ¶çã¯ãç«æ¹
äœãå «é¢äœããŸãã¯ååé¢äœäœãã®æ¶çãæããŠ
ãããã®ã§ãããããŸããããã®åçš®ã®æ¶çãæ··
åããŠããŠãããããåæ¶ãå«ããã®ã§ãããã ããã«äžèšããã²ã³åéç²åã®çµæ¶æ§é ã¯ãå
éšãŸã§äžæ§ã®æ§é ã§ãã€ãŠãããŸãå±€ç¶æ§é ããª
ãããããããã¯ç±³åœç¹èš±ç¬¬3622318å·ã«èšèŒã
ããŠãããããªã³ã³ããŒãžãšã³åã®ãã®ã§ãã€ãŠ
ãããããŸãããã«ã¯ç±³åœç¹èš±ç¬¬4094684å·ã«èš
èŒã®ããæ²åéçµæ¶è¡šé¢ã«å¡©åéçµæ¶ããšãã¿ã
ã·ãŒçµåããŠãããããªæ§é ã®ãã®ã§ããããã
è¡šé¢æœååãå éšæœååãããã«å±ãããã®ã§ã
ããã äžèšã®åŠãããã²ã³åéç²åãããªãåçä¹³å€
ã¯ãäŸãã°ã·ãŒã»ã€ãŒã»ã±ãŒã»ããŒã¹ããã³ã
ãŒã»ãšã€ãã»ãžãšãŒã ãºèã®âã¶ã»ã»ãªãªãŒã»ãª
ãã»ã¶ã»ããªãã°ã©ãã€ãã¯ã»ããã»ã¹çã«èšèŒ
ãããè¯ãç¥ãããã¢ã³ã¢ãã¢æ³ãäžæ§æ³ãé žæ§
æ³çã®ä¹³å€èª¿è£œæ³ã«ãã調補ããããšãã§ããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã®ãã€ã³ããŒãš
ããŠã¯ããŒã©ãã³ãã³ãã€ãç¶ã¢ã«ããã³ãå¯
倩ãå æ°Žå解ãããã»ã«ããŒãºã¢ã»ããŒããã¡ã
ã«ã»ã«ããŒãºçã®ã»ã«ããŒãºèªå°äœãåæãã€ã³
ããŒãäŸãã°ããªããã«ã¢ã«ã³ãŒã«ãããªïŒ®ïŒïŒ®
âãžã¡ãã«ã¢ã¯ãªã«ã¢ãããããªïŒ®âããã«ãã
ãªãã³ã氎溶æ§ããªããŒããã¿ã«åãŒã©ãã³çã®
ãŒã©ãã³èªå°äœãã¢ã¯ãªããããªã«çéåå¯èœãª
ãšãã¬ã³åºãæã€åéäœããŒã©ãã³ã«ã°ã©ããå ±
éåãããã®çããããããããããã®ãã€ã³ã
ãŒã¯å¿ èŠã«å¿ããŠïŒã€ä»¥äžã®çžæº¶æ§æ··åç©ãšããŠ
䜿çšããããšãã§ããã äžè¿°ã®ããã²ã³åéç²åããã€ã³ããŒæ¶²äžã«å
æ£ããããããã²ã³åéåçä¹³å€ã¯ãååŠå¢æå€
ã«ããå¢æããããšãã§ãããæ¬çºæã®åçä¹³å€
ã«ã¯è²Žéå±å¢æå€ãç¡«é»å¢æå€ãã»ã¬ã³å¢æå€å
ã³éå å¢æå€ã«ããååŠå¢æãæå©ã«äœµçšã§ã
ããäŸãã°ç±³åœç¹èš±ç¬¬2448060å·èšèŒã®è²Žéå±å¢
ææ³ãç±³åœç¹èš±ç¬¬2399083å·èšèŒã®éå¢ææ³çã«
ããå¢æãããã ãŸãæ¬çºæã®åèšäžè¬åŒã§ç€ºãããå¢æè²çŽ 以
å€ã®å¢æè²çŽ ãŸãã¯åŒ·è²å¢æå€ã«ãã€ãŠå¢æãã
ãŠããŠãããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã«ã¯å®å®å€ãã
ã³ã«ããªæå¶å€ãå«æããããããšãã§ããã代
è¡šçãªå®å®å€ããã³ã«ããªæå¶å€ãšããŠã¯äžèšã®
ãã®ãæããããšãã§ããã äŸãã°ãïŒâããšãã«âïŒâã¡ã«ã«ããããã©
ãŸãŒã«ãïŒâã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâãã
ããã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©
ã¢ã¶ã€ã³ãã³çã®è€çŽ ç°ååç©ãã¡ã«ã«ããåå
ç©ãéå±å¡©é¡çã®çš®ã ã®ååç©ãæ·»å ããããšã
ã§ããããŸããåèšãã€ã³ããŒäŸãšããŠèšèŒãã
ããªïŒ®âããã«ãããªãã³ã¯ãç©ççŸåæå¶å€ãš
ããŠã®å¹æããããååé10äžä»¥äžã®ãã®ããã
ã²ã³åéïŒã¢ã«ããããå°ãªããšã0.2ïœå«æã
ããããšã«ãããé¡èãªå¹æããããããã®ã§ã
ãæ¬çºæã«ãé©çšã§ããã ä¹³å€ã®ç¡¬èåŠçã¯åžžæ³ã«åŸã€ãŠå®æœãããã䜿
çšããã硬èå€ã¯éåžžã®åççšç¡¬èå€ãããšãã°
ãã«ã ã¢ã«ããããã®åŠãã¢ã«ãããç³»ååç©å
ã³ãããã®ã¢ã»ã¿ãŒã«æãã¯éäºç¡«é žãœãŒãä»å
ç©ã®ãããªãèªå°äœååç©ïŒã¡ã¿ã³ã¹ã«ãã³é žãš
ã¹ãã«ç³»ååç©ïŒã ã³ã¯ãã«é žæãã¯ã ã³ããã²
ã³é žç³»ååç©ïŒãšããã·ç³»ååç©ïŒã¢ãžãªãžã³ç³»
ååç©ïŒæŽ»æ§ããã²ã³ç³»ååç©ïŒãã¬ã€ã³é žã€ã
ãç³»ååç©ïŒæŽ»æ§ããã«ç³»ååç©ïŒã«ã«ããžã€ã
ãç³»ååç©ïŒã€ãœãªããµãŸãŒã«ç³»ååç©ïŒïŒ®âã¡
ãããŒã«ç³»ååç©ïŒã€ãœã·ã¢ããŒãç³»ååç©ïŒã¯
ãã æãã³ãç¡«é žãžã«ã³ããŠã çã®ç¡æ©ç¡¬èå€ç
ããããããšãåºæ¥ãã æ¬çºæã«ãããããã²ã³åéåçä¹³å€ã¯çé¢æŽ»
æ§å€ãåç¬ãããã¯æ··åããŠæ·»å ããŠãããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã«ã¯ã玫å€ç·åž
åå€ãå¢ç²å€ãå¯å¡å€ãè¢å å¢çœå€ãçŸåä¿é²
å€ãè²èª¿å€çãé©å®å ããããšãã§ããã ç¹ã«æ¬çºæã®ããã²ã³åéåçä¹³å€ãã«ã©ãŒçš
æå ææãšããŠçšããããå Žåã«ã¯ãåèšäžè¬åŒ
ã§ç€ºãããå¢æè²çŽ ã®ã»ããããããã®ããã²ã³
åéåçä¹³å€å±€ãå¢æããããã«ãèµ€ææ§ããã
ã¯éææ§ã®å¢æè²çŽ ã䜵çšããå¿ èŠããããéåžž
䜿çšãããå¢æè²çŽ ãšããŠã¯ã·ã¢ãã³ãã¡ãã·ã¢
ãã³ãã«ã«ãã·ã¢ãã³çã®ã·ã¢ãã³è²çŽ é¡ã®åç¬
ãããã¯çµåã䜿çšããŸãã¯ããããšåŒ·è²å¢æå¹
æã®ããååç©ãšã®çµåã䜿çšããããšãã§ã
ããã«ã©ãŒæå ææã®å Žåçšããã«ãã©ãŒãšããŠ
ã¯äŸãã°ãééã¡ãã¬ã³ç³»ã€ãšããŒã«ãã©ãŒãïŒ
âãã©ãŸãã³ç³»ããŒã³ã¿ã«ãã©ãŒãããšããŒã«ç³»
ãŸãã¯ããããŒã«ç³»ã·ã¢ã³ã«ãã©ãŒçãæããã
ãšãã§ããããããã®ã«ãã©ãŒã¯æè¬ïŒåœéåã
ããã¯ïŒåœéåã«ãã©ãŒã§ãã€ãŠãããããŸãã
ããã®ã«ãã©ãŒã«çµåããŠããªãŒããã¹ã¯ããã
ããã®ã¢ãŸåã«ã©ãŒãã«ãã©ãŒããªãµãŸã³ååå
ç©ãæ¡æ£æ§è²çŽ æŸåºåã«ãã©ãŒãªã©ãçšããããš
ãå¯èœã§ãããããã«åçç¹æ§ãåäžããããã
ã«ãåèšã«ãã©ãŒãšäœµçšããŠãæè¬ã³ã³ããŒãã³
ã°ã«ãã©ãŒãDIRã«ãã©ãŒïŒDevelopment
Inhibitor Releasing CouplerïŒãBARã«ãã©ãŒ
ïŒBleach Accelerator Releasing CouplerïŒãªã©
ãšåŒã°ããã«ãã©ãŒãå«ãããšãã§ããã å€ãã®å Žåãã«ãã©ãŒã¯è£œé å·¥çšäžãæå ææ
ã®ä¿åäžåã³åŠçå·¥çšäžã«ãç¹å®å±€ã«ãšã©ãŸãä»
ã®å±€ãžæ¡æ£ããªãæ§é ããã€ããšãæãŸããã ãããã®ã«ãã©ãŒã¯ãäžè¬ã«ãé©åœãªæ¥µæ§ãæ
ãã溶åªãšãšãã«ãããã²ã³åéåçä¹³å€å±€äžã«
åæ£ãããããããŠäžèšä¹³å€ãæ¯æäœäžã«æå å±€
ãšããŠå¡åžããããšã«ããæå ææãåŸããã
ãããã®ããã²ã³åéåçæå ææã®æ¯æäœãšã
ãŠã¯ããã©ã€ã¿çŽãããªãªã¬ãã€ã³è¢«èŠçŽãã¯ã
ãã»ã«ããŒãºããªã¢ã»ããŒããããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããããªã«ãŒãããŒãçã®ãã©ã¹ããã¯
ãã€ã«ã çãããããã®ã䜿çšã§ããã ãã®ãããªæ¬çºæã«ããåçæå ææã¯ãäžè¬
çšçœé»æå ææïŒãã¬ããªããŒãµã«ãå°ç»çŽçïŒã
å°å·çšæå ææããã€ã¯ãçšæå ææãç·çšæ
å ææãã«ã©ãŒçšæå ææïŒãã¬ããªããŒãµã«ã
å°ç»çŽçïŒçããããããã²ã³åéåçæå ææ
ã«é©çšããããšãã§ããã 次ã«æ¬çºæãå®æœäŸã«ããå ·äœçã«èª¬æãã
ããããã«ããæ¬çºæã®å®æœã®æ æ§ãéå®ããã
ãã®ã§ã¯ãªãã å®æœäŸ ïŒ ã¿ãã«ãžãšããæ³ã«ãã€ãŠèª¿æŽããæ²åéãïŒ
ã¢ã«ïŒ å«æããé«æ床æ²èåéä¹³å€ã«éå¢æãç¡«
é»å¢æãæœããåŸåå²ãããã®ä¹³å€ïŒKgïŒããã²
ã³åéïŒã¢ã«å«æïŒã«å¯ŸããŠæ¬çºæã«çšãããã
äžè¬åŒãããããããã³ããã§è¡šããããå¢
æè²çŽ ãšãæ¯èŒçšå¢æè²çŽ ã第ïŒè¡šã®ããã«ãã
ããã¡ã¿ããŒã«æº¶æ¶²ãšããŠæ·»å ããããã ããäž
è¬åŒããããã³æ¯èŒçšå¢æè²çŽ ã¯ãäžèšå®å®å€
ãšåæã«æ·»å ããã 次ã«åä¹³å€ã«å®å®å€ãšããŠãïŒâããããã·â
ïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ã
ã³ãå¡åžå©å€ãšããŠãµããã³ãããã³ç¡¬èå€ãšã
ãŠãã«ããªã³ãããããé©éãæ·»å ããåŸã»ã«ã
ãŒã¹ããªã¢ã»ããŒãããŒã¹æ¯æäœäžã«å¡åžã也ç¥
ããŠè©Šæãäœæããã ãããã®ãããããã®è©Šæã«ã€ããããããïŒ
éšã®ã¹ããªããã¹ãäœæããäžéšã¯æ±äº¬è浊é»æ©
æ ªåŒäŒç€Ÿè£œé»è²ãã€ã«ã¿ãŒãçšããŠãŠãšããžé²å
ãæœãŠããä¿ååŠçãè¡ãªã€ããäžéšã¯æªé²å ã®
ãŸãŸãä¿ååŠçãæœãããä¿ååŠçæ¥æ°ã¯17æ¥é
ã§æåã®ïŒæ¥éã¯55âã27ïŒ RHã®é°å²æ°ã§æ®ã
ã®14æ¥éã¯40âã80ïŒ RHã®é°å²æ°ã«ç©ºèª¿ããã
容åšäžã«ä¿æãããæ®ãã®äžéšã¯ã³ã³ãããŒã«è©Š
æãšããŠå·èµä¿åããã次ãã§æªé²å ã®ãŸãŸä¿å
åŠçãæœããè©Šæãšãå·èµä¿åãããã³ã³ãããŒ
ã«è©Šæã«ãä¿ååŠçãæœããé²å æžè©Šæã«äžãã
ãšåæ§ã®é²å ãããåŸãäžèšçµæã®çŸå液ã§30
âãïŒåéçŸåããåŸãå®çãšæ°ŽæŽã®åŠçãè¡ãª
ã€ãã çŸå液çµæ ç¡«é žââã¡ãã«ã¢ããããšããŒã« ïŒïœ ç¡æ°Žäºç¡«é žãããªãŠã 50ïœ ãã€ããããã³ ïŒïœ çé žãããªãŠã 29.5ïœ èåã«ãªãŠã ïŒïœ æ°Žãå ã㊠ïŒã«ãã åŸãããéç»åã«ã€ããŠæ¿åºŠæž¬å®ããŠãé»è²å
æ床ïŒSyïŒããã³ã«ããªãæ±ãããæ床ã¯ãã«
ããªïŒ0.1ãã®å åŠæ¿åºŠãäžããã®ã«å¿ èŠãªé²å
éããæ±ããè©ŠæNo.ïŒã®ã³ã³ãããŒã«è©Šæã®æ床
ã100ãšããçžå¯Ÿå€ã§è¡šç€ºããã çµæã¯ç¬¬ïŒè¡šã«ç€ºãã
è²å¢æãããããã²ã³åéåçæå ææã«é¢ãã
ãã®ã§ãããæŽã«è©³ããã¯ã匷è²å¢æããããã€
ä¿åæ§ã®æ¹è¯ãããç¹ã«ãç·ææ§ããã²ã³åéå
çä¹³å€å±€ãæããŠãªãããã²ã³åéåçæå ææ
ïŒä»¥äžåã«ãæå ææãšèšãïŒã«é¢ãããã®ã§ã
ãã åŸæ¥ãæå ææã®ä¹³å€ã«å¢æè²çŽ ãå ããæå
ææã®ä¹³å€ã®æå æ³¢é·åãæ¡å€§ããåå çã«å¢æ
ããããšããããšã¯ç¥ãããŠãããããã®ç®çã®
çºã«äœ¿çšããå¢æè²çŽ ãéžæããå Žåãåºæ¬çã«
æºè¶³ãããã¹ãè«žæ¡ä»¶ãšããŠã¯ãäŸãã°ã次ã®æ§
ãªæ¡ä»¶ãèããããã ïŒ åå å¢ææ³¢é·åãé©åã§ããããš ïŒ åå å¢ææ床ãããé«ãããš ïŒ åççã«ãæªåœ±é¿ãäžããªãããšïŒå¢æè²çŽ
以å€ã®åççšæ·»å ç©ãšã®éã«æªãçžäºäœçšããª
ãããšïŒ ïŒ ããã²ã³åéåçä¹³å€ããã³æå ææãšããŠ
ã®ä¿åäžã§ã®æå 床ã®äœäžåã³å€åãå°ãªãã
ãš ïŒ ã«ããªã®çºçãå°ãªãããš ïŒ å¢æè²çŽ ãä»ã®æå å±€ãžæ¡æ£ããªãããš ïŒ çŸååŠçåŸã«è²çŽ æ±æãèµ·ããªãã㚠以äžã®æ¡ä»¶ããããããããããã«ãããã²ã³
åéåçä¹³å€ãå¡èšããŠåŸãããæå ææãé²å
ããåŸã«ãããã²ã³åéåçä¹³å€äžã«åœ¢æããã
æœåããé·æéã®ä¿åäžã«çµæãšããŠåçç¹æ§ç
ã«å€åããªãããšãéèŠã§ããããã®æœåã®ä¿å
æ§ã¯å€å±€ã«ã©ãŒæå ææã«ãããŠã¯ãåå±€ã®åç
æ§èœã®ç°ãªã€ãå€åã瀺ããå Žåãã«ã©ãŒãã©ã³
ã¹ããããè¯å¥œãªè²åçŸãåŸãããªããªããšãã
ããšã§ããããã®æœåã®ä¿åæ§ã¯å€§ããªåé¡ãšãª
ãããŸãæå ææã®é²å åã®ä¿åã«ããåçæ§èœ
ã®å€åã«ã€ããŠãåæ§ã§ãããä¿åããŠãåå±€ã®
å€åãã»ãšãã©ãªããããŸãã¯ãåå±€ããã©ã³ã¹
ããå€åããäºãæå ææã®åçç¹æ§äžéèŠãšã
ããã®ã§ããã ããã²ã³åéä¹³å€ã®åå å¢æã¯ïŒçš®é¡ã®å¢æè²
çŽ ã䜿çšããŠè¡ãªãããšãããã奜ãŸããåå å¢
æãè¡ãªãããã«ã¯ãéåžžïŒçš®ä»¥äžã®å¢æè²çŽ ã
çµåããŠäœ¿çšããå Žåãå€ãããã®å Žåã«ã¯åŒ·è²
å¢æäœçšãæããå¢æè²çŽ ãéžæã䜿çšããããš
ãäžè¬çã§ããããã®ãããªç®çã«åããããªå
å å¢ææè¡ãã€ãŸãé«æ床ã§è¯å¥œãªè²åçŸãäžã
åŸãé©åãªæ³¢é·åãåå å¢æããå¢æè²çŽ ã®çµå
ãã¯åŸæ¥ããå€ãã®äººã ã«ããç 究ãããŠããã
ããããªãããåŸæ¥ã®æè¡ã¯æå ææã®ä¿åäžã«
ãããŠãåçæ§èœã®å€åããããæ¬ é¥ããã€ãã®
ãå€ããšããããšãæã ã®ç 究ã§å€æãããäŸã
ã°ãç¹å ¬æ44â32753å·å ¬å ±çã«èšèŒãããŠãã
ãªããµã«ã«ãã·ã¢ãã³è²çŽ ãçšããå¢ææè¡ã§
ã¯ãæœåã®ä¿åæã®å€åã¯æœåéè¡ïŒé²å ã«ãã
ããã²ã³åéä¹³å€äžã«çããæœåããé žçŽ ã湿床
ã«ãã圱é¿ã§ãã®äžéšãç Žå£ããå®è³ªçã«æžæã
ãæ§ã«ãªãå Žåãæœåéè¡ãšãããïŒåŸåã瀺ã
ãã®ããããæŽã«ãé²å 以åã®æå ææã®ä¿åäž
ã«ãæžæãããããã®ãããããŸããç±³åœç¹èš±ç¬¬
2973264å·ãå第3173791å·ãå第3364031å·ãå
第3397060å·ãå第3506443å·ãç¹å ¬æ47â37443
å·å ¬å ±ãç¹å ¬æ48â28293å·å ¬å ±çã§ç¥ãããŠã
ãã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ ãçšããå¢ææ
è¡ã§ã¯ãæœåã®ä¿åæã®å€åã¯æœåé²è¡ïŒæœåé²
è¡ãšã¯éã«å®è³ªçã«å¢æããæ§ã«ãªãå Žåãèš
ããé²å åŸããçŸååŠçãè¡ãªã€ãå Žåã«ã¯ãçŸ
象ãããªãæ§ãªããã²ã³åéç²åã®äžéšãä¿åäž
ã«çŸåå¯èœãšãªãå Žåãæœåé²è¡ãšãããïŒåŸå
ã瀺ããã®ãå€ãããŸãæå ææã®ä¿åäžã«ãæž
æããã³åŒ·ãã«ããªãçºçãããã®ãå€ãããã
ã«å®¶å ·çããçºçãããã«ããªã³ã¬ã¹ã«ãããç¹
ç°çã«ã«ããªãçºçãããã®ãããã ãŸããç¹å ¬æ54â34535å·å ¬å ±ãç¹å ¬æ56â
38936å·å ¬å ±ãç¹éæ51â126140å·çã«èšèŒãã
ãŠããã¢ãã¡ãã³è²çŽ ãçšããå¢ææè¡ã§ã¯ãæœ
åã®ä¿åæã®å€åã¯æœåéè¡åŸåã瀺ããé²å å
ã®ä¿åã§ã¯æžæãããããã®ãããã ãã®ããã«åŸæ¥ããç¥ãããŠããå¢ææè¡ããš
ãã«ç·ææ§åå å¢ææè¡ã¯ãåªãã匷è²å¢æäœçš
ãè¯å¥œãªè²åçŸãåŸãããšãã§ããé©åãªåå æ³¢
é·åãåå å¢æããããæå ææã®ä¿åäžã§ã®æ§
èœã®å€åãèŠããä¿ååŸã«ã¯è¯å¥œãªè²åçŸãåŸã
ããªããã®ãå€ãèŠãããã åŸã€ãŠãæ¬çºæã®ç¬¬ïŒã®ç®çã¯ãæ®åœ±åŸæå æ
æãé·æéä¿åããå Žåã§ãæœåã®å€åãæ®ãã©
ãªãä¿åã«å¯ŸããŠåçç¹æ§ãå®å®ãªæå ææãæ
äŸããäºã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯æå ææã®è£œé åŸãé·æ
éã®ä¿åã«éããŠãæå 床ã®äœäžãã«ããªã®çºç
ã®å°ãªãå®å®ãªæå ææãæäŸããäºã«ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãç·è²æ³¢é·ååå å¢æã«
éããŠãé©åãªæ³¢é·åã«åå å¢æãããè²åçŸæ§
ã®è¯å¥œãªããã²ã³åéåçä¹³å€ãæäŸããããšã«
ããã æ¬çºæã®ç¬¬ïŒã®ç®çã¯ãç·è²æ³¢é·åãé«åºŠã«å
å å¢æããããªããã€çŸååŠçåŸã®æå ææã«è²
çŽ æ±æã®çããããšã®ãªãå¢æè²çŽ ã«ããåå å¢
æãããããã²ã³åéåçä¹³å€ãæäŸããããšã§
ããã æ¬çºæã®åèšã®ç®çã¯ãäžèšäžè¬åŒããã§è¡š
ããããå¢æè²çŽ ã®å°ãªããšãäžçš®ãšãäžèšäžè¬
åŒããã§è¡šããããå¢æè²çŽ ã®å°ãªããšãäžçš®
ãšããã«äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ
ã®å°ãªããšãäžçš®ãšãçµåãå«æããæå ææã«
ããéæãããããšãèŠãåºããã äžè¬åŒãã åŒäžãY1ãY2ãY3ããã³Y4ã¯ãã®ãã®ãæ°ŽçŽ
ååãããã²ã³ååãïŒããšãã°å¡©çŽ ååãèçŽ
ååïŒäœçŽã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒ
ãïŒã®ã¢ã«ãã«åºïŒããšãã°ã¡ãã«ããšãã«ïŒïŒã
ã¢ã«ã³ãã·åºïŒããšãã°ã¡ããã·ããšããã·ïŒã
ããããã·ãã«ã«ããã·ãã¢ãªãŒã«åºïŒããšãã°
ããšãã«ïŒãã·ã¢ããã¢ããåºïŒããšãã°ã¢ããã
ã¡ãã«ã¢ããïŒãããªãã«ãªãã¡ãã«ãã¢ã«ã³ã
ã·ã«ã«ããã«åºïŒããšãã°ã¡ããã·ã«ã«ããã«ã
ãšããã·ã«ã«ããã«ïŒãã«ã«ãã¢ã«ã³ãã·åºïŒã
ãšãã°ã«ã«ããšããã·ãã«ã«ãããããã·ïŒãã¢
ã·ã«ã¢ããåºïŒããšãã°ã¢ã»ãã¢ããïŒãã¢ã»ã
ãã·åºïŒããšãã°ã¢ã»ããã·ïŒãã¢ã·ã«åºïŒããš
ãã°ã¢ã»ãã«ïŒããŸãã¯ã¢ã«ã³ãã·ã«ã«ããã«ã¢
ããåºïŒããšãã°ãšããã·ã«ã«ããã«ã¢ããïŒã
è¡šãããY1ãšY2ãY3ãšY4ã¯ããããäºãã«é£çµ
ããŠç°ã圢æããŠãããïŒããããªããµãŸãŒã«ç°
ïŒããšãã°ããããïŒïŒïŒâïœããªããµãŸãŒã«
ç°ïŒïŒãR1ã¯æ°ŽçŽ ååãäœçŽã¢ã«ãã«åºïŒå¥œãŸã
ãã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«åºïŒããšãã°ã¡
ãã«ããšãã«ïŒïŒãè¡šãããR2ãšR3ã¯ãã®ãã®ã¢
ã«ãã«åºïŒå¥œãŸããã¯ã¹ã«ããŸãã¯ã«ã«ããã·ã§
眮æãããŠããããããã¯é眮æã®ãççŽ ååæ°
ïŒãïŒã®ã¢ã«ãã«ïŒããšãã°ãšãã«ãã¹ã«ããšã
ã«ïŒïŒãè¡šãããX1 ã¯ã¢ããªã³ãè¡šãããn1ã¯
ïŒãŸãã¯ïŒãè¡šãããïŒååå å¡©ã圢æããå Žå
ã¯ïŒã§ãããïŒ äžè¬åŒãã åŒäžãY5ãY6ãY7ããã³Y8ã¯ãã®ãã®ãæ°ŽçŽ
ååãããã²ã³ååïŒããšãã°å¡©çŽ ååãèçŽ å
åïŒã¢ã«ã³ãã·åºïŒããšãã°ã¡ããã·ããšãã
ã·ïŒãã¢ããåºãã¢ã·ã«ã¢ããåºïŒããšãã°ã¢ã»
ãã¢ããïŒãã¢ã»ããã·åºïŒããšãã°ã¢ã»ãã
ã·ïŒãã¢ã«ã³ãã·ã«ã«ããã«åºïŒããšãã°ã¡ãã
ã·ã«ã«ããã«ïŒãã¢ã«ãã«ã¹ã«ããã«åºïŒããšã
ã°ã¡ãã«ã¹ã«ããã«ïŒãã¹ã«ãã¢ã¢ã€ã«åºïŒããš
ãã°ã¡ãã«ã¹ã«ãã¢ã¢ã€ã«ïŒãã·ã¢ãåºããŸãã¯
ããªãã«ãªãã¡ãã«ãè¡šãããR4ãR5ãR6ãã
ã³R7ã¯ãã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒ
ãïŒã®çœ®æãé眮æã®ã¢ã«ãã«ïŒããšãã°ããšã
ã«ãã¹ã«ããšãã«ïŒã§ããããŸãé žçŽ ååçãä»
åšããŠããããïŒX2 ã¯ã¢ããªã³ãè¡šãããn2ã¯
ïŒãŸãã¯ïŒãè¡šãããïŒååå å¡©ã圢æããå Žå
ã¯ïŒã§ãããïŒ äžè¬åŒãã åŒäžãY9ãY10ãY11ããã³Y12ã¯ããã®ãã®ã
æ°ŽçŽ ååãããã²ã³ååïŒããšãã°å¡©çŽ ååïŒã
äœçŽã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒãïŒã®
ã¢ã«ãã«åºïŒããšãã°ã¡ãã«ïŒãã¢ã«ã³ãã·åº
ïŒããšãã°ã¡ããã·ïŒãã¢ã«ã³ãã·ã«ã«ããã«åº
ïŒããšãã°ã¡ããã·ã«ã«ããã«ïŒãããããã·ãã«
ã«ããã·ãã¢ãªãŒã«åºïŒããšãã°ããšãã«ïŒããŸ
ãã¯ããªãã«ãªãã¡ãã«ãè¡šãããY9ãšY10ã
Y11ãšY12ã¯ããããäºãã«é£çµããŠç°ã圢æã
ãŠãããïŒããããªããµãŸãŒã«ç°ïŒããšãã°ãã
ããïŒïŒïŒâïœããªããµãŸãŒã«ç°ïŒïŒãR8ãR9ã¯
ã¢ã«ãã«åºïŒå¥œãŸããã¯ççŽ ååæ°ïŒãïŒã®çœ®
æãé眮æã®ã¢ã«ãã«ïŒããšãã°ãšãã«ãã¹ã«ã
ãšãã«ïŒïŒãè¡šãããX3 ã¯ã¢ããªã³ãè¡šããã
n3ã¯ïŒãŸãã¯ïŒãè¡šãããïŒååå å¡©ã圢æãã
å Žåã¯ïŒã§ãããïŒ æ¬çºæã«ãããŠãåèšäžè¬åŒããã§è¡šããã
ãå¢æè²çŽ ã®äžã§ç¹ã«æçšãªå¢æè²çŽ ã¯ãäžèšäž
è¬åŒããã§è¡šããããšãã§ããã äžè¬åŒãã åŒäžãY13ãY14ãY15ããã³Y16ã¯ããããã
æ°ŽçŽ ååãããã²ã³ååïŒããšãã°å¡©çŽ ååãè
çŽ ååïŒãççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«åºïŒããš
ãã°ã¡ãã«ããšãã«ïŒãççŽ ååæ°ïŒãïŒã®ã¢ã«
ã³ãã·åºïŒããšãã°ã¡ããã·ããšããã·ïŒããã
ããã·ãã«ã«ããã·ãã¢ãªãŒã«åºïŒããšãã°ããš
ãã«ïŒãã¢ã·ã«ã¢ããåºïŒããšãã°ã¢ã»ãã¢ã
ãïŒãã¢ã»ããã·åºïŒããšãã°ã¢ã»ããã·ïŒãããª
ãã«ãªãã¡ãã«ãççŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·
ã«ã«ããã«åºïŒããšãã°ã¡ããã·ã«ã«ããã«ïŒã
ççŽ ååæ°ïŒãïŒã®ã«ã«ãã¢ã«ã³ãã·åºïŒããšã
ã°ã«ã«ããšããã·ïŒãè¡šããããŸããY13ãšY14ã
Y15ãšY16ã¯ããããäºãã«é£çµããŠç°ã圢æã
ãŠãããïŒããããªããµãŸãŒã«ç°ïŒããšãã°ãã
ããïŒïŒïŒâïœããªããµãŸãŒã«ç°ïŒïŒãA1ã¯ççŽ
ååæ°ïŒãïŒãŸã§ã®ã¢ã«ãã¬ã³åºïŒããšãã°ãšã
ã¬ã³ïŒãè¡šãããR10ã¯R1ã§ç€ºãããã®ãšåãã
ã®ãè¡šãããR11ã¯ã¹ã«ããŸãã¯ã«ã«ããã·ã§çœ®
æãããã¢ã«ãã«ãŸãã¯é眮æã®ççŽ ååæ°ïŒã
ïŒã®ã¢ã«ãã«ïŒããšãã°ãšãã«ãã¹ã«ããšãã«ïŒ
ãè¡šãããX4 ã¯ã¢ããªã³ãè¡šãããn4ã¯ïŒå
ã¯ïŒãè¡šãããïŒååå å¡©ã圢æããå Žåã¯ïŒã§
ãããïŒ äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ ã®ã
ã¡ãäžã§ãç¹ã«æçšãªå¢æè²çŽ ã¯ãäžèšäžè¬åŒ
ããããã³ããã§è¡šããããšãã§ããã äžè¬åŒãã äžè¬åŒãã åŒäžãY17ãY18ã¯ãããã²ã³ååïŒããšãã°
å¡©çŽ ååïŒãã¢ãªãŒã«åºïŒããšãã°ããšãã«ïŒã
è¡šããã A2ãA3ã¯A1ã§ç€ºãããã®ãšåããã®ãè¡šã
ããR12ãR14ã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«åº
ïŒããšãã°ã¡ãã«ïŒãè¡šãããR13ãR15ã¯R11ã§
瀺ãããã®ãšåããã®ãè¡šãããX5 ãšX6 ã¯ã
ã¢ããªã³ãè¡šãããn5ãšn6ã¯ãããããïŒåã¯ïŒ
ãè¡šãããïŒn4ã®å Žåãšåãäºã瀺ããïŒ æ¬çºæã«ãããŠåèšäžè¬åŒããã§è¡šãããã
å¢æè²çŽ ã®äžã§ç¹ã«æçšãªå¢æè²çŽ ã¯äžèšäžè¬åŒ
ããã§è¡šããããšãã§ããã äžè¬åŒãã åŒäžãY19ãY20ãY21ããã³Y22ã¯ããããã
æ°ŽçŽ ååãããã²ã³ååïŒããšãã°å¡©çŽ ååãè
çŽ ååïŒãã¢ããåºãã¢ã·ã«ã¢ããåºïŒããšãã°
ã¢ã»ãã¢ããïŒãççŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·
ã«ã«ããã«åºïŒããšãã°ã¡ããã·ã«ã«ããã«ïŒã
ãŸãã¯ã·ã¢ããè¡šãããR16ãR17ã¯ççŽ ååæ°
ïŒãïŒã®ã¢ã«ãã«åºïŒããšãã°ãšãã«ïŒã§ããã
é žçŽ ååçãä»åšããŠããŠããããR18ãR19ã¯ã
ã¹ã«ããŸãã¯ã«ã«ããã·ã§çœ®æãããŠããããã
ãã¯é眮æã®ãççŽ ååæ°ïŒãïŒã®ã¢ã«ãã«ïŒã
ãšãã°ãšãã«ãã¹ã«ããšãã«ïŒã§ãããé žçŽ åå
çãä»åšããŠããŠããããåãå°ããšãäžæ¹ãã¹
ã«ãã¢ã«ãã«åºãã«ã«ããã·ã¢ã«ãã«åºã§ããã
X7 ã¯ã¢ããªã³ã§ããn7ã¯ïŒåã¯ïŒã§ãããn2
ã§ç€ºãããã®ãšåãã§ããã äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ ã®ã
ã¡ãäžã§ãç¹ã«æçšãªå¢æè²çŽ ã¯äžèšäžè¬åŒ
ããã§è¡šããããšãã§ããã äžè¬åŒãã åŒäžãY23ãšY24ã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ã
ã«åºïŒããšãã°ãšãã«ïŒãè¡šãããR20ãšR21ã¯
ããããR16ãR17ãšåããã®ãè¡šãããR22ãš
R23ã¯ããããR18ãR19ãšåããã®ãè¡šãããX8
ã¯ã¢ããªã³ãè¡šãããn8ã¯n7ãšåããã®ãè¡šã
ãã æ¬çºæã«ãããŠåèšäžè¬åŒããã§è¡šãããã
å¢æè²çŽ ã®äžã§ç¹ã«æçšãªå¢æè²çŽ ã¯ãäžèšäžè¬
åŒããã§è¡šããããšãã§ããã äžè¬åŒãã åŒäžãY25ãY26ããã³Y27ã¯ãããããæ°ŽçŽ å
åãããã²ã³ååïŒããšãã°å¡©çŽ ååïŒãççŽ å
åæ°ïŒãïŒã®ã¢ã«ãã«åºïŒããšãã°ã¡ãã«ïŒãç
çŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·åºïŒããšãã°ã¡ãã
ã·ïŒãççŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·ã«ã«ããã«
åºïŒããšãã°ã¡ããã·ã«ã«ããã«ïŒãããããã·ã
ã«ã«ããã·ãã¢ãªãŒã«åºïŒããšãã°ããšãã«ïŒã
ãŸãã¯ãããªãã«ãªãã¡ãã«ãè¡šããã Y25ãšY26ã¯äºãã«é£çµããŠç°ã圢æããŠãã
ããªããµãŸãŒã«ç°ïŒããšãã°ããããïŒïŒïŒâ
ïœããªããµãŸãŒã«ç°ïŒã圢æããŠããããR24ãš
R25ã¯ãã¹ã«ããŸãã¯ã«ã«ããã·ã§çœ®æãããŠã
ãããããã¯é眮æã®ãççŽ ååæ°ïŒãïŒã®ã¢ã«
ãã«ãè¡šãããX9 ã¯ã¢ããªã³ãè¡šãããn9ã¯ã
n3ãšåãã§ããã äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ ã®ãã¡
ç¹ã«æçšãªå¢æè²çŽ ã¯äžèšäžè¬åŒããã§è¡šãã
ããšãã§ããã äžè¬åŒãã åŒäžãY28ãšY29ã¯ãããããæ°ŽçŽ ååããã
ã²ã³ååïŒããšãã°å¡©çŽ ååïŒãççŽ ååæ°ïŒã
ïŒã®ã¢ã«ãã«åºïŒããšãã°ã¡ãã«ïŒãççŽ ååæ°
ïŒãïŒã®ã¢ã«ã³ãã·åºïŒããšãã°ã¡ããã·ïŒãç
çŽ ååæ°ïŒãïŒã®ã¢ã«ã³ãã·ã«ã«ããã«åºïŒããš
ãã°ã¡ããã·ã«ã«ããã«ïŒãã¢ãªãŒã«åºïŒããšã
ã°ããšãã«ïŒããŸãã¯ããªãã«ãªãã¡ãã«ãè¡šã
ããA4ã¯ççŽ ååæ°ïŒãïŒã®ã¢ã«ãã¬ã³åºïŒã
ãšãã°ãšãã¬ã³ïŒãè¡šãããR26ã¯R24ããã³R26
ãšåããã®ãè¡šãããX10ã¯ã¢ããªã³ãè¡šããã
n10ã¯n9ãšåãæå³ãè¡šããã æ¬çºæã®äžè¬åŒããããã³ããã§è¡šããã
ãå¢æè²çŽ ã¯ç±³åœç¹èš±ç¬¬3397060å·ãå第3506443
å·çã«èšèŒãããŠããããŸããäžè¬åŒããã§è¡š
ããããå¢æè²çŽ ã¯ç±³åœç¹èš±ç¬¬3149105å·çã«èš
èŒãããŠããããŸãäžèšã®ç¹èš±ã«èšèŒã®ãªãå¢æ
è²çŽ ãäžèšç¹èš±ã®æ¹æ³ã«æºããŠåœè©²æ¥è ã容æã«
åæããããšãã§ããã 以äžã«æ¬çºæã«ãããŠçšããããäžè¬åŒããã
ããåã³ããã«ãã€ãŠè¡šããããå¢æè²çŽ ã®
代衚çãªãã®ã瀺ãããæ¬çºæããããã«éå®ã
ãããã®ã§ã¯ãªãã ïŒäžè¬åŒããã®äŸç€ºååç©ïŒ æ¬çºæã®åèšäžè¬åŒãããããããã³ãã
ã§è¡šããããå¢æè²çŽ ãããã²ã³åéåçä¹³å€ã«
æ·»å ããããå Žåã®å¥œãŸããæ·»å éã¯ããã²ã³å
éïŒã¢ã«ãããå¢æè²çŽ ãããïŒÃ10-4ã¢ã«ãª
ãã2.5Ã10-3ã¢ã«ãç¹ã«å¥œãŸããã¯ã1.5Ã10-4
ã¢ã«ãªãã1.2Ã10-3ã¢ã«ã§ãããå¢æè²çŽ ãã
ã¯ãåãã1.5Ã10-6ã¢ã«ãªããïŒÃ10-3ã¢ã«ã
奜ãŸãããç¹ã«å¥œãŸããã¯3.5Ã10-6ã¢ã«ãªãã
1.5Ã10-4ã¢ã«ã§ãããå¢æè²çŽ ããã¯åãã
1.2Ã10-5ã¢ã«ãªãã1.5Ã10-3ã¢ã«ã奜ãŸããã
ç¹ã«å¥œãŸããã¯ïŒÃ10-5ã¢ã«ãªããïŒÃ10-4ã¢ã«
ã®ç¯å²ã§ããããŸãæ¬çºæã®åå¢æè²çŽ ã®å¥œãŸã
ã䜿çšæ¯çã¯ãå¢æè²çŽ ããïŒå¢æè²çŽ ãã
ã¯ã¢ã«æ¯ã§340ïŒïŒãªããïŒïŒïŒãééæ¯ã§ã¯
200ïŒïŒãªããïŒïŒïŒã®ç¯å²ã§ããããŸãå¢æè²
çŽ ããïŒå¢æè²çŽ ããã¯ãã¢ã«æ¯ã§ïŒïŒ170
ãªããïŒïŒ0.2ãééæ¯ã§ïŒïŒ80ãªããïŒïŒ0.2ã®
ç¯å²ã§ããããŸãäžèšç¯å²ã®ãªãã§å¢æè²çŽ
ãããããããã³ããã®æ¯çã¯ãã¢ã«æ¯ãªã
ã³ã«ééæ¯ãšãã«å¢æè²çŽ ããããã€ãšãå€
ããå¢æè²çŽ ããããã€ãšãå°ãªãæ¡ä»¶ã«ãã
ãŠãæ¬çºæã®å¹æããã€ãšãé¡èã«çºæ®ãããã
ãŸãäžèšç¯å²å ã§å¢æè²çŽ ããã«å¯ŸããŠå¢æè²
çŽ ãããããã®æ·»å éãå€åãããããšã§ä»ã®
è«žç¹æ§ãå€åãããªãã§åœè©²å±€ã®æœåã®ä¿åã«ã
ããå€åå·Ÿãªãã³ã«å€åæ¹åãå€åãããããšã
å¯èœã§ããããã®ããšã¯ç¹ã«å€å±€ã«ã©ãŒæå ææ
ã®å Žåã«ãããŠç·æå±€ãèµ€æå±€ããã³éæå±€ã®å€
åå·Ÿãªãã³ã«å€åæ¹åã«åèŽããã³ã³ãããŒã«ã
ãããšããè¯å¥œãªè²åçŸãç¶æããçºã«ã¯å¿ èŠãª
å Žåãããããããé¢ã§ããã®ããšã¯ãæ¬çºæã®
å¹æã®å€§ããªç¹åŸŽã®äžã€ã§ãããæ¬çºæã®å¢æè²
çŽ ãããã²ã³åéåçä¹³å€äžã«æ·»å ããææãšã
ãŠã¯ãä¹³å€ã®ç¬¬çæäžãããã¯å¡åžã«å ç«ã€ãŠ
æ·»å ããã®ãåšç¥ã®æ¹æ³ã§ãããæ¬çºæãåæ§ã§
ãããããã奜ãŸããå¹æãçºæ®ãããçºã«ã¯ã
å¢æè²çŽ ããããã³ãããå ã«æ·»å ãããã
ãåŸã«æ·»å ããã®ããããããã«ã¯å¢æè²çŽ
ããããã³ããã第çæäžã«æ·»å ããã
ã¯å¡åžã«å ç«ã€ãŠæ·»å ããæ¹ããã€ãšãèããå¹
æãçºæ®ããã ãŸãæ¬çºæã®åèšåäžè¬åŒã§ç€ºãããå¢æè²çŽ
ãäžèšåçä¹³å€ã«æ·»å ããæ¹æ³ãšããŠã¯åŸæ¥ãã
ææ¡ãããŠããçš®ã ã®æ¹æ³ãé©çšã§ãããäŸãã°
ç±³åœç¹èš±ç¬¬3469987å·ã«èšèŒãããåŠããå¢æè²
çŽ ãæ®çºæ§ææ©æº¶åªã«æº¶è§£ãã該溶液ã芪氎æ§ã³
ãã€ãäžã«åæ£ãããã®åæ£ç©ãä¹³å€ã«æ·»å ãã
æ¹æ³ã«ããè¡ãªã€ãŠãããããŸãããã«ãæ¬çºæ
ã®å¢æè²çŽ ã¯ãåã ã«ãåäžãŸãã¯ç°ãªã溶åªã«
溶解ããä¹³å€ã«æ·»å ããåã«ããããã®æº¶æ¶²ãæ··
åããããå¥ã ã«æ·»å ããããšãã§ããã æ¬çºæã®åèšåäžè¬åŒã§ç€ºãããå¢æè²çŽ ãã
ãã²ã³åéåçä¹³å€ã«æ·»å ãããšãã®è²çŽ ã®æº¶åª
ãšããŠã¯ãäŸãã°ã¡ãã«ã¢ã«ã³ãŒã«ããšãã«ã¢ã«
ã³ãŒã«ãã¢ã»ãã³çã®æ°Žæ··åæ§ææ©æº¶åªã奜ãŸã
ãçšããããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã«çšããããã
ãã²ã³åéã®çµæãšããŠã¯ãäŸãã°å¡©åéãèå
éãæ²åéãå¡©èåéãæ²èåéãå¡©æ²èåéç
åçš®ã®ãã®ã䜿çšããããšãã§ããããç¹ã«æ²è
åéã®äœ¿çšãé©ããŠããããŸããã®ç²åŸã¯0.2ã
2.0ÎŒçšåºŠã奜ãŸãããããã®ç¯å²ã«éå®ãããã
ã®ã§ã¯ãªãããããŠãããã®ããã²ã³åéç²å
ã¯ãå ¬ç¥ã®äŸãã°ã·ã³ã°ã«ãžãšããæ³ãããã«ãž
ãšããæ³ãããã¯ã³ã³ãããŒã«ããã«ãžãšããæ³
ã®ãããªå皮混åæ³ã«ãã圢æãããããã®ãã
ã«åœ¢æãããããã²ã³åéç²åã®æ¶çã¯ãç«æ¹
äœãå «é¢äœããŸãã¯ååé¢äœäœãã®æ¶çãæããŠ
ãããã®ã§ãããããŸããããã®åçš®ã®æ¶çãæ··
åããŠããŠãããããåæ¶ãå«ããã®ã§ãããã ããã«äžèšããã²ã³åéç²åã®çµæ¶æ§é ã¯ãå
éšãŸã§äžæ§ã®æ§é ã§ãã€ãŠãããŸãå±€ç¶æ§é ããª
ãããããããã¯ç±³åœç¹èš±ç¬¬3622318å·ã«èšèŒã
ããŠãããããªã³ã³ããŒãžãšã³åã®ãã®ã§ãã€ãŠ
ãããããŸãããã«ã¯ç±³åœç¹èš±ç¬¬4094684å·ã«èš
èŒã®ããæ²åéçµæ¶è¡šé¢ã«å¡©åéçµæ¶ããšãã¿ã
ã·ãŒçµåããŠãããããªæ§é ã®ãã®ã§ããããã
è¡šé¢æœååãå éšæœååãããã«å±ãããã®ã§ã
ããã äžèšã®åŠãããã²ã³åéç²åãããªãåçä¹³å€
ã¯ãäŸãã°ã·ãŒã»ã€ãŒã»ã±ãŒã»ããŒã¹ããã³ã
ãŒã»ãšã€ãã»ãžãšãŒã ãºèã®âã¶ã»ã»ãªãªãŒã»ãª
ãã»ã¶ã»ããªãã°ã©ãã€ãã¯ã»ããã»ã¹çã«èšèŒ
ãããè¯ãç¥ãããã¢ã³ã¢ãã¢æ³ãäžæ§æ³ãé žæ§
æ³çã®ä¹³å€èª¿è£œæ³ã«ãã調補ããããšãã§ããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã®ãã€ã³ããŒãš
ããŠã¯ããŒã©ãã³ãã³ãã€ãç¶ã¢ã«ããã³ãå¯
倩ãå æ°Žå解ãããã»ã«ããŒãºã¢ã»ããŒããã¡ã
ã«ã»ã«ããŒãºçã®ã»ã«ããŒãºèªå°äœãåæãã€ã³
ããŒãäŸãã°ããªããã«ã¢ã«ã³ãŒã«ãããªïŒ®ïŒïŒ®
âãžã¡ãã«ã¢ã¯ãªã«ã¢ãããããªïŒ®âããã«ãã
ãªãã³ã氎溶æ§ããªããŒããã¿ã«åãŒã©ãã³çã®
ãŒã©ãã³èªå°äœãã¢ã¯ãªããããªã«çéåå¯èœãª
ãšãã¬ã³åºãæã€åéäœããŒã©ãã³ã«ã°ã©ããå ±
éåãããã®çããããããããããã®ãã€ã³ã
ãŒã¯å¿ èŠã«å¿ããŠïŒã€ä»¥äžã®çžæº¶æ§æ··åç©ãšããŠ
䜿çšããããšãã§ããã äžè¿°ã®ããã²ã³åéç²åããã€ã³ããŒæ¶²äžã«å
æ£ããããããã²ã³åéåçä¹³å€ã¯ãååŠå¢æå€
ã«ããå¢æããããšãã§ãããæ¬çºæã®åçä¹³å€
ã«ã¯è²Žéå±å¢æå€ãç¡«é»å¢æå€ãã»ã¬ã³å¢æå€å
ã³éå å¢æå€ã«ããååŠå¢æãæå©ã«äœµçšã§ã
ããäŸãã°ç±³åœç¹èš±ç¬¬2448060å·èšèŒã®è²Žéå±å¢
ææ³ãç±³åœç¹èš±ç¬¬2399083å·èšèŒã®éå¢ææ³çã«
ããå¢æãããã ãŸãæ¬çºæã®åèšäžè¬åŒã§ç€ºãããå¢æè²çŽ 以
å€ã®å¢æè²çŽ ãŸãã¯åŒ·è²å¢æå€ã«ãã€ãŠå¢æãã
ãŠããŠãããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã«ã¯å®å®å€ãã
ã³ã«ããªæå¶å€ãå«æããããããšãã§ããã代
è¡šçãªå®å®å€ããã³ã«ããªæå¶å€ãšããŠã¯äžèšã®
ãã®ãæããããšãã§ããã äŸãã°ãïŒâããšãã«âïŒâã¡ã«ã«ããããã©
ãŸãŒã«ãïŒâã¡ãã«ãã³ãŸãã¢ãŸãŒã«ãïŒâãã
ããã·âïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©
ã¢ã¶ã€ã³ãã³çã®è€çŽ ç°ååç©ãã¡ã«ã«ããåå
ç©ãéå±å¡©é¡çã®çš®ã ã®ååç©ãæ·»å ããããšã
ã§ããããŸããåèšãã€ã³ããŒäŸãšããŠèšèŒãã
ããªïŒ®âããã«ãããªãã³ã¯ãç©ççŸåæå¶å€ãš
ããŠã®å¹æããããååé10äžä»¥äžã®ãã®ããã
ã²ã³åéïŒã¢ã«ããããå°ãªããšã0.2ïœå«æã
ããããšã«ãããé¡èãªå¹æããããããã®ã§ã
ãæ¬çºæã«ãé©çšã§ããã ä¹³å€ã®ç¡¬èåŠçã¯åžžæ³ã«åŸã€ãŠå®æœãããã䜿
çšããã硬èå€ã¯éåžžã®åççšç¡¬èå€ãããšãã°
ãã«ã ã¢ã«ããããã®åŠãã¢ã«ãããç³»ååç©å
ã³ãããã®ã¢ã»ã¿ãŒã«æãã¯éäºç¡«é žãœãŒãä»å
ç©ã®ãããªãèªå°äœååç©ïŒã¡ã¿ã³ã¹ã«ãã³é žãš
ã¹ãã«ç³»ååç©ïŒã ã³ã¯ãã«é žæãã¯ã ã³ããã²
ã³é žç³»ååç©ïŒãšããã·ç³»ååç©ïŒã¢ãžãªãžã³ç³»
ååç©ïŒæŽ»æ§ããã²ã³ç³»ååç©ïŒãã¬ã€ã³é žã€ã
ãç³»ååç©ïŒæŽ»æ§ããã«ç³»ååç©ïŒã«ã«ããžã€ã
ãç³»ååç©ïŒã€ãœãªããµãŸãŒã«ç³»ååç©ïŒïŒ®âã¡
ãããŒã«ç³»ååç©ïŒã€ãœã·ã¢ããŒãç³»ååç©ïŒã¯
ãã æãã³ãç¡«é žãžã«ã³ããŠã çã®ç¡æ©ç¡¬èå€ç
ããããããšãåºæ¥ãã æ¬çºæã«ãããããã²ã³åéåçä¹³å€ã¯çé¢æŽ»
æ§å€ãåç¬ãããã¯æ··åããŠæ·»å ããŠãããã æ¬çºæã®ããã²ã³åéåçä¹³å€ã«ã¯ã玫å€ç·åž
åå€ãå¢ç²å€ãå¯å¡å€ãè¢å å¢çœå€ãçŸåä¿é²
å€ãè²èª¿å€çãé©å®å ããããšãã§ããã ç¹ã«æ¬çºæã®ããã²ã³åéåçä¹³å€ãã«ã©ãŒçš
æå ææãšããŠçšããããå Žåã«ã¯ãåèšäžè¬åŒ
ã§ç€ºãããå¢æè²çŽ ã®ã»ããããããã®ããã²ã³
åéåçä¹³å€å±€ãå¢æããããã«ãèµ€ææ§ããã
ã¯éææ§ã®å¢æè²çŽ ã䜵çšããå¿ èŠããããéåžž
䜿çšãããå¢æè²çŽ ãšããŠã¯ã·ã¢ãã³ãã¡ãã·ã¢
ãã³ãã«ã«ãã·ã¢ãã³çã®ã·ã¢ãã³è²çŽ é¡ã®åç¬
ãããã¯çµåã䜿çšããŸãã¯ããããšåŒ·è²å¢æå¹
æã®ããååç©ãšã®çµåã䜿çšããããšãã§ã
ããã«ã©ãŒæå ææã®å Žåçšããã«ãã©ãŒãšããŠ
ã¯äŸãã°ãééã¡ãã¬ã³ç³»ã€ãšããŒã«ãã©ãŒãïŒ
âãã©ãŸãã³ç³»ããŒã³ã¿ã«ãã©ãŒãããšããŒã«ç³»
ãŸãã¯ããããŒã«ç³»ã·ã¢ã³ã«ãã©ãŒçãæããã
ãšãã§ããããããã®ã«ãã©ãŒã¯æè¬ïŒåœéåã
ããã¯ïŒåœéåã«ãã©ãŒã§ãã€ãŠãããããŸãã
ããã®ã«ãã©ãŒã«çµåããŠããªãŒããã¹ã¯ããã
ããã®ã¢ãŸåã«ã©ãŒãã«ãã©ãŒããªãµãŸã³ååå
ç©ãæ¡æ£æ§è²çŽ æŸåºåã«ãã©ãŒãªã©ãçšããããš
ãå¯èœã§ãããããã«åçç¹æ§ãåäžããããã
ã«ãåèšã«ãã©ãŒãšäœµçšããŠãæè¬ã³ã³ããŒãã³
ã°ã«ãã©ãŒãDIRã«ãã©ãŒïŒDevelopment
Inhibitor Releasing CouplerïŒãBARã«ãã©ãŒ
ïŒBleach Accelerator Releasing CouplerïŒãªã©
ãšåŒã°ããã«ãã©ãŒãå«ãããšãã§ããã å€ãã®å Žåãã«ãã©ãŒã¯è£œé å·¥çšäžãæå ææ
ã®ä¿åäžåã³åŠçå·¥çšäžã«ãç¹å®å±€ã«ãšã©ãŸãä»
ã®å±€ãžæ¡æ£ããªãæ§é ããã€ããšãæãŸããã ãããã®ã«ãã©ãŒã¯ãäžè¬ã«ãé©åœãªæ¥µæ§ãæ
ãã溶åªãšãšãã«ãããã²ã³åéåçä¹³å€å±€äžã«
åæ£ãããããããŠäžèšä¹³å€ãæ¯æäœäžã«æå å±€
ãšããŠå¡åžããããšã«ããæå ææãåŸããã
ãããã®ããã²ã³åéåçæå ææã®æ¯æäœãšã
ãŠã¯ããã©ã€ã¿çŽãããªãªã¬ãã€ã³è¢«èŠçŽãã¯ã
ãã»ã«ããŒãºããªã¢ã»ããŒããããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããããªã«ãŒãããŒãçã®ãã©ã¹ããã¯
ãã€ã«ã çãããããã®ã䜿çšã§ããã ãã®ãããªæ¬çºæã«ããåçæå ææã¯ãäžè¬
çšçœé»æå ææïŒãã¬ããªããŒãµã«ãå°ç»çŽçïŒã
å°å·çšæå ææããã€ã¯ãçšæå ææãç·çšæ
å ææãã«ã©ãŒçšæå ææïŒãã¬ããªããŒãµã«ã
å°ç»çŽçïŒçããããããã²ã³åéåçæå ææ
ã«é©çšããããšãã§ããã 次ã«æ¬çºæãå®æœäŸã«ããå ·äœçã«èª¬æãã
ããããã«ããæ¬çºæã®å®æœã®æ æ§ãéå®ããã
ãã®ã§ã¯ãªãã å®æœäŸ ïŒ ã¿ãã«ãžãšããæ³ã«ãã€ãŠèª¿æŽããæ²åéãïŒ
ã¢ã«ïŒ å«æããé«æ床æ²èåéä¹³å€ã«éå¢æãç¡«
é»å¢æãæœããåŸåå²ãããã®ä¹³å€ïŒKgïŒããã²
ã³åéïŒã¢ã«å«æïŒã«å¯ŸããŠæ¬çºæã«çšãããã
äžè¬åŒãããããããã³ããã§è¡šããããå¢
æè²çŽ ãšãæ¯èŒçšå¢æè²çŽ ã第ïŒè¡šã®ããã«ãã
ããã¡ã¿ããŒã«æº¶æ¶²ãšããŠæ·»å ããããã ããäž
è¬åŒããããã³æ¯èŒçšå¢æè²çŽ ã¯ãäžèšå®å®å€
ãšåæã«æ·»å ããã 次ã«åä¹³å€ã«å®å®å€ãšããŠãïŒâããããã·â
ïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ã
ã³ãå¡åžå©å€ãšããŠãµããã³ãããã³ç¡¬èå€ãšã
ãŠãã«ããªã³ãããããé©éãæ·»å ããåŸã»ã«ã
ãŒã¹ããªã¢ã»ããŒãããŒã¹æ¯æäœäžã«å¡åžã也ç¥
ããŠè©Šæãäœæããã ãããã®ãããããã®è©Šæã«ã€ããããããïŒ
éšã®ã¹ããªããã¹ãäœæããäžéšã¯æ±äº¬è浊é»æ©
æ ªåŒäŒç€Ÿè£œé»è²ãã€ã«ã¿ãŒãçšããŠãŠãšããžé²å
ãæœãŠããä¿ååŠçãè¡ãªã€ããäžéšã¯æªé²å ã®
ãŸãŸãä¿ååŠçãæœãããä¿ååŠçæ¥æ°ã¯17æ¥é
ã§æåã®ïŒæ¥éã¯55âã27ïŒ RHã®é°å²æ°ã§æ®ã
ã®14æ¥éã¯40âã80ïŒ RHã®é°å²æ°ã«ç©ºèª¿ããã
容åšäžã«ä¿æãããæ®ãã®äžéšã¯ã³ã³ãããŒã«è©Š
æãšããŠå·èµä¿åããã次ãã§æªé²å ã®ãŸãŸä¿å
åŠçãæœããè©Šæãšãå·èµä¿åãããã³ã³ãããŒ
ã«è©Šæã«ãä¿ååŠçãæœããé²å æžè©Šæã«äžãã
ãšåæ§ã®é²å ãããåŸãäžèšçµæã®çŸå液ã§30
âãïŒåéçŸåããåŸãå®çãšæ°ŽæŽã®åŠçãè¡ãª
ã€ãã çŸå液çµæ ç¡«é žââã¡ãã«ã¢ããããšããŒã« ïŒïœ ç¡æ°Žäºç¡«é žãããªãŠã 50ïœ ãã€ããããã³ ïŒïœ çé žãããªãŠã 29.5ïœ èåã«ãªãŠã ïŒïœ æ°Žãå ã㊠ïŒã«ãã åŸãããéç»åã«ã€ããŠæ¿åºŠæž¬å®ããŠãé»è²å
æ床ïŒSyïŒããã³ã«ããªãæ±ãããæ床ã¯ãã«
ããªïŒ0.1ãã®å åŠæ¿åºŠãäžããã®ã«å¿ èŠãªé²å
éããæ±ããè©ŠæNo.ïŒã®ã³ã³ãããŒã«è©Šæã®æ床
ã100ãšããçžå¯Ÿå€ã§è¡šç€ºããã çµæã¯ç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
ãè¡šã
第ïŒè¡šããæãããªããã«ãæ¬çºæã«ä¿ãè©Šæ
ïŒNo.ïŒãïŒïŒã¯ãæ¯èŒè©Šæã«æ¯ã¹ã«ããªãäœãã
ãã€é«æ床ãç¶æããä¿ååŠçã«ãããŠããæœå
ã®å®å®æ§ãåäžããæªé²å ã®æå ææã®æžæãã
ã³ã«ããªã®çºçãæããããŠããã®ãããããå®
æœäŸïŒã§çšããæ¯èŒçšå¢æè²çŽ ã®æ§é ã¯äžèšã®é
ãã§ããã å®æœäŸ ïŒ ããã«ãžãšããæ³ã«ãã€ãŠèª¿æŽãããæ²åéã
ïŒã¢ã«ïŒ å«æããé«æ床æ²èåéä¹³å€ã«éå¢æã
ç¡«é»å¢æãæœããåŸåå²ãããã®ä¹³å€ïŒKgïŒãã
ã²ã³åéïŒã¢ã«å«æïŒã«å¯ŸããŠæ¬çºæã«çšããã
ãäžè¬åŒãããããããã³ããã§è¡šãããã
å¢æè²çŽ ãšãæ¯èŒçšå¢æè²çŽ ããããã第ïŒè¡šã®
ããã«ã¡ã¿ããŒã«æº¶æ¶²ãšããŠæ·»å ããããã ãäž
è¬åŒããããã³æ¯èŒçšã®ã¢ãã¡ãã³å¢æè²çŽ
(D)ã(E)ã¯äžèšå®å®å€ã®æ·»å åŸã«æ·»å ããã 次ã«åä¹³å€ã«ãå®å®å€ãšããŠïŒâããããã·â
ïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ã
ã³ãå¡åžå©å€ãšããŠãµããã³ãããã³ç¡¬èå€ãšã
ãŠïŒïŒïŒâãã¹ïŒããã«ã¹ã«ããã«ïŒãšã¿ã³ãã
ãããé©éããã³ãŒãã©ã«ã¢ããªã³ã¢ã³ããã€ã«
ã ã³ãŒãã¬ãŒã·ãšã³è£œPVKâ90ïŒãã«ïŒ®âããã«
ãããªãã³ïŒãïŒïœæ·»å ããããã«ãããã¯ãå
æ£ããããŒã³ã¿ã«ãã©ãŒãšããŠãïŒâïŒïŒïŒïŒïŒ
ïŒâããªã¯ããããšãã«ïŒâïŒâãïŒâïŒïŒïŒïŒâ
ãžâïœâã¢ãã«ããšããã·ã¢ã»ãã¢ããïŒãã³ãº
ã¢ãããâïŒâãã©ãŸãã³54ïœãïŒâïŒïŒïŒïŒïŒïŒ
âããªã¯ããããšãã«ïŒâïŒâïŒïŒâããã·ã«ãµã¯
ã·ã³ã€ãããã³ãºã¢ããïŒâïŒâãã©ãŸãã³22ïœã
ã«ã©ãŒãããŒã³ã¿ã«ãã©ãŒãšããŠïŒâïŒïŒïŒïŒïŒ
ïŒâããªã¯ããããšãã«ïŒâïŒâïŒïŒâãããã«ã¢
ãŸïŒâïŒâïŒïŒâã¯ããâïŒâãªã¯ã¿ãã»ãã«ã¹ã¯
ã·ã³ã€ããã¢ããªãïŒâïŒâãã©ãŸãã³2.5ïœãã
ãã·ã«ã¬ã¬ãŒã0.5ïœã®åæ£æ¶²ãæ·»å ããã ããããŠèª¿æŽããä¹³å€ãã»ã«ããŒã¹ããªã¢ã»ã
ãŒãããŒã¹æ¯æäœäžã«å¡åžã也ç¥ããŠè©Šæãäœæ
ããã ãããã®ããããã®è©Šæã«ã€ãããããïŒéšã®
ã¹ããªããã¹ãäœæããäžéšã¯ãæ±äº¬è浊é»æ©æ ª
åŒäŒç€Ÿè£œã®ç·è²ãã€ã«ã¿ãŒãä»ããŠãŠãšããžé²å
ããä¿ååŠçãè¡ãªã€ããåãããäžéšã¯æªé²å
ã®ãŸãŸä¿ååŠçãæœãããä¿ååŠçã®æ¥æ°ã¯10æ¥
éã§ãæåã®ïŒæ¥éã¯ã55â27ïŒ RHã®é°å²æ°ã§
æ®ãã®ïŒæ¥éã¯ã40â80ïŒ RHã®é°å²æ°ã«ç©ºèª¿ã
ãã容åšäžã«ä¿æããã æ®ãã®ïŒéšã¯ã³ã³ãããŒã«è©ŠæãšããŠå·èµä¿å
ããã 次ãã§æªé²å ã®ãŸãŸä¿ååŠçãæœããè©Šæãšå·
èµä¿åããã³ã³ãããŒã«è©Šæã«ãä¿ååŠçãæœã
ãé²å æžè©Šæãšåæ§ã®é²å ãæœããåŸãäžèšã®ã«
ã©ãŒãã¬çŸååŠçãè¡ã€ãã ïŒçŸåæ¡ä»¶ïŒ åŠçå·¥çšïŒ38âïŒ åŠçæé çºè²çŸåâŠâŠâŠâŠâŠâŠïŒå15ç§ æŒçœâŠâŠâŠâŠâŠâŠïŒå30ç§ æ°ŽæŽâŠâŠâŠâŠâŠâŠïŒå15ç§ å®çâŠâŠâŠâŠâŠâŠïŒå30ç§ æ°ŽæŽâŠâŠâŠâŠâŠâŠïŒå15ç§ å®å®åâŠâŠâŠâŠâŠâŠïŒå30ç§ åŠçå·¥çšã«ãããŠäœ¿çšããåŠç液çµæã¯äžèšã®
åŠãã§ããã çºè²çŸå液çµæïŒ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââïŒÎ²
âããããã·ãšãã«ïŒâã¢ããªã³ç¡«é žå¡© 4.8ïœ ç¡æ°Žäºç¡«é žãããªãŠã 0.14ïœ ããããã·ã¢ãã³ã»1/2ç¡«é žå¡© 1.98ïœ ç¡« é ž 0.74mg ç¡æ°Žçé žã«ãªãŠã 28.85ïœ ç¡æ°Žçé žæ°ŽçŽ ã«ãªãŠã 3.46ïœ ç¡æ°Žäºç¡«é žã«ãªãŠã 5.10ïœ èåã«ãªãŠã 1.16ïœ å¡©åãããªãŠã 0.14ïœ ãããªãããªé ¢é žã»ïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
1.20ïœ æ°Žé žåã«ãªãŠã 1.48ïœ æ°Žãå ããŠïŒãšããã æŒçœæ¶²çµæïŒ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
100.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
10.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°·é ¢é ž 10.0ml æ°Žãå ããŠïŒãšãã¢ã³ã¢ãã¢æ°ŽãçšããŠPH6.0
ã«èª¿æŽããã å®ç液çµæïŒ ããªç¡«é žã¢ã³ã¢ããŠã 175.0ïœ ç¡æ°Žäºç¡«é žãããªãŠã 8.6ïœ ã¡ã¿äºç¡«é žãããªãŠã 2.3ïœ æ°Žãå ããŠïŒãšãé ¢é žãçšããŠPH6.0ã«èª¿æŽã
ãã å®å®å液çµæïŒ ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ 1.5ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žãå ããŠïŒãšããã åŸãããè²çŽ ç»åã«ã€ããŠãããããç·è²ãã€
ã«ã¿ãŒãéããŠæ¿åºŠæž¬å®ãè¡ãªããç·è²å æ床
ïŒsgïŒåã³ã«ããªãæ±ãããæ床ã¯ãã«ããªïŒ
0.1ãã®å åŠæ¿åºŠãäžããã®ã«å¿ èŠãªé²å éãã
æ±ããã æ床ã¯ãè©ŠæNo.ïŒã®ã³ã³ãããŒã«è©Šæã®æ床ã
100ãšããŠãçžå¯Ÿå€ã§è¡šç€ºããã çµæã¯ç¬¬ïŒè¡šã«ç€ºãã
ïŒNo.ïŒãïŒïŒã¯ãæ¯èŒè©Šæã«æ¯ã¹ã«ããªãäœãã
ãã€é«æ床ãç¶æããä¿ååŠçã«ãããŠããæœå
ã®å®å®æ§ãåäžããæªé²å ã®æå ææã®æžæãã
ã³ã«ããªã®çºçãæããããŠããã®ãããããå®
æœäŸïŒã§çšããæ¯èŒçšå¢æè²çŽ ã®æ§é ã¯äžèšã®é
ãã§ããã å®æœäŸ ïŒ ããã«ãžãšããæ³ã«ãã€ãŠèª¿æŽãããæ²åéã
ïŒã¢ã«ïŒ å«æããé«æ床æ²èåéä¹³å€ã«éå¢æã
ç¡«é»å¢æãæœããåŸåå²ãããã®ä¹³å€ïŒKgïŒãã
ã²ã³åéïŒã¢ã«å«æïŒã«å¯ŸããŠæ¬çºæã«çšããã
ãäžè¬åŒãããããããã³ããã§è¡šãããã
å¢æè²çŽ ãšãæ¯èŒçšå¢æè²çŽ ããããã第ïŒè¡šã®
ããã«ã¡ã¿ããŒã«æº¶æ¶²ãšããŠæ·»å ããããã ãäž
è¬åŒããããã³æ¯èŒçšã®ã¢ãã¡ãã³å¢æè²çŽ
(D)ã(E)ã¯äžèšå®å®å€ã®æ·»å åŸã«æ·»å ããã 次ã«åä¹³å€ã«ãå®å®å€ãšããŠïŒâããããã·â
ïŒâã¡ãã«âïŒïŒïŒïŒ3aïŒïŒâããã©ã¶ã€ã³ã
ã³ãå¡åžå©å€ãšããŠãµããã³ãããã³ç¡¬èå€ãšã
ãŠïŒïŒïŒâãã¹ïŒããã«ã¹ã«ããã«ïŒãšã¿ã³ãã
ãããé©éããã³ãŒãã©ã«ã¢ããªã³ã¢ã³ããã€ã«
ã ã³ãŒãã¬ãŒã·ãšã³è£œPVKâ90ïŒãã«ïŒ®âããã«
ãããªãã³ïŒãïŒïœæ·»å ããããã«ãããã¯ãå
æ£ããããŒã³ã¿ã«ãã©ãŒãšããŠãïŒâïŒïŒïŒïŒïŒ
ïŒâããªã¯ããããšãã«ïŒâïŒâãïŒâïŒïŒïŒïŒâ
ãžâïœâã¢ãã«ããšããã·ã¢ã»ãã¢ããïŒãã³ãº
ã¢ãããâïŒâãã©ãŸãã³54ïœãïŒâïŒïŒïŒïŒïŒïŒ
âããªã¯ããããšãã«ïŒâïŒâïŒïŒâããã·ã«ãµã¯
ã·ã³ã€ãããã³ãºã¢ããïŒâïŒâãã©ãŸãã³22ïœã
ã«ã©ãŒãããŒã³ã¿ã«ãã©ãŒãšããŠïŒâïŒïŒïŒïŒïŒ
ïŒâããªã¯ããããšãã«ïŒâïŒâïŒïŒâãããã«ã¢
ãŸïŒâïŒâïŒïŒâã¯ããâïŒâãªã¯ã¿ãã»ãã«ã¹ã¯
ã·ã³ã€ããã¢ããªãïŒâïŒâãã©ãŸãã³2.5ïœãã
ãã·ã«ã¬ã¬ãŒã0.5ïœã®åæ£æ¶²ãæ·»å ããã ããããŠèª¿æŽããä¹³å€ãã»ã«ããŒã¹ããªã¢ã»ã
ãŒãããŒã¹æ¯æäœäžã«å¡åžã也ç¥ããŠè©Šæãäœæ
ããã ãããã®ããããã®è©Šæã«ã€ãããããïŒéšã®
ã¹ããªããã¹ãäœæããäžéšã¯ãæ±äº¬è浊é»æ©æ ª
åŒäŒç€Ÿè£œã®ç·è²ãã€ã«ã¿ãŒãä»ããŠãŠãšããžé²å
ããä¿ååŠçãè¡ãªã€ããåãããäžéšã¯æªé²å
ã®ãŸãŸä¿ååŠçãæœãããä¿ååŠçã®æ¥æ°ã¯10æ¥
éã§ãæåã®ïŒæ¥éã¯ã55â27ïŒ RHã®é°å²æ°ã§
æ®ãã®ïŒæ¥éã¯ã40â80ïŒ RHã®é°å²æ°ã«ç©ºèª¿ã
ãã容åšäžã«ä¿æããã æ®ãã®ïŒéšã¯ã³ã³ãããŒã«è©ŠæãšããŠå·èµä¿å
ããã 次ãã§æªé²å ã®ãŸãŸä¿ååŠçãæœããè©Šæãšå·
èµä¿åããã³ã³ãããŒã«è©Šæã«ãä¿ååŠçãæœã
ãé²å æžè©Šæãšåæ§ã®é²å ãæœããåŸãäžèšã®ã«
ã©ãŒãã¬çŸååŠçãè¡ã€ãã ïŒçŸåæ¡ä»¶ïŒ åŠçå·¥çšïŒ38âïŒ åŠçæé çºè²çŸåâŠâŠâŠâŠâŠâŠïŒå15ç§ æŒçœâŠâŠâŠâŠâŠâŠïŒå30ç§ æ°ŽæŽâŠâŠâŠâŠâŠâŠïŒå15ç§ å®çâŠâŠâŠâŠâŠâŠïŒå30ç§ æ°ŽæŽâŠâŠâŠâŠâŠâŠïŒå15ç§ å®å®åâŠâŠâŠâŠâŠâŠïŒå30ç§ åŠçå·¥çšã«ãããŠäœ¿çšããåŠç液çµæã¯äžèšã®
åŠãã§ããã çºè²çŸå液çµæïŒ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«ââïŒÎ²
âããããã·ãšãã«ïŒâã¢ããªã³ç¡«é žå¡© 4.8ïœ ç¡æ°Žäºç¡«é žãããªãŠã 0.14ïœ ããããã·ã¢ãã³ã»1/2ç¡«é žå¡© 1.98ïœ ç¡« é ž 0.74mg ç¡æ°Žçé žã«ãªãŠã 28.85ïœ ç¡æ°Žçé žæ°ŽçŽ ã«ãªãŠã 3.46ïœ ç¡æ°Žäºç¡«é žã«ãªãŠã 5.10ïœ èåã«ãªãŠã 1.16ïœ å¡©åãããªãŠã 0.14ïœ ãããªãããªé ¢é žã»ïŒãããªãŠã å¡©ïŒïŒæ°Žå¡©ïŒ
1.20ïœ æ°Žé žåã«ãªãŠã 1.48ïœ æ°Žãå ããŠïŒãšããã æŒçœæ¶²çµæïŒ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žéã¢ã³ã¢ããŠã å¡©
100.0ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã å¡©
10.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°·é ¢é ž 10.0ml æ°Žãå ããŠïŒãšãã¢ã³ã¢ãã¢æ°ŽãçšããŠPH6.0
ã«èª¿æŽããã å®ç液çµæïŒ ããªç¡«é žã¢ã³ã¢ããŠã 175.0ïœ ç¡æ°Žäºç¡«é žãããªãŠã 8.6ïœ ã¡ã¿äºç¡«é žãããªãŠã 2.3ïœ æ°Žãå ããŠïŒãšãé ¢é žãçšããŠPH6.0ã«èª¿æŽã
ãã å®å®å液çµæïŒ ãã«ããªã³ïŒ37ïŒ æ°Žæº¶æ¶²ïŒ 1.5ml ã³ãããã¯ã¹ïŒå°è¥¿å åçå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒ
7.5ml æ°Žãå ããŠïŒãšããã åŸãããè²çŽ ç»åã«ã€ããŠãããããç·è²ãã€
ã«ã¿ãŒãéããŠæ¿åºŠæž¬å®ãè¡ãªããç·è²å æ床
ïŒsgïŒåã³ã«ããªãæ±ãããæ床ã¯ãã«ããªïŒ
0.1ãã®å åŠæ¿åºŠãäžããã®ã«å¿ èŠãªé²å éãã
æ±ããã æ床ã¯ãè©ŠæNo.ïŒã®ã³ã³ãããŒã«è©Šæã®æ床ã
100ãšããŠãçžå¯Ÿå€ã§è¡šç€ºããã çµæã¯ç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
第ïŒè¡šãããæãããªããã«ãæ¬çºæã«ä¿ãè©Š
æïŒïŒãïŒãïŒã10ã14ã15ïŒã¯æ¯èŒè©Šæã«æ¯ã¹
ãŠãã³ã³ãããŒã«è©ŠæïŒéä¿ååŠçïŒã«ãããŠ
ã¯ãã«ããªã¯äœãããã€é«æ床ãç¶æããŠããã
ãŸãä¿ååŠçã«ãããŠã¯ãæœåã®å€åå·Ÿãå°ã
ããã«ããªã®çºçãæªé²å ä¿ååŠçã§ã®æžæã«ã
æ¹è¯å¹æãã¿ãããã å®æœäŸïŒã§çšããæ¯èŒçšå¢æè²çŽ ã®æ§é ã¯äžèš
ã®éãã§ããã å®æœäŸ ïŒ å®æœäŸïŒã§äœæããè©Šæã«ã€ããããããïŒéš
ã®ã¹ããªããã¹ãäœæããããããŠã35ïŒ ã°ãªã»
ãªã³æ°Žæº¶æ¶²ã300mlããã40ïŒ ãã«ã ã¢ã«ããã
氎溶液ïŒmlãå«ãã 液ãåºéšã«ããããã€ããã®
液ãšå¹³è¡æ°Žæ ã«éããé°å²æ°ãå å ããå¯é容åš
ã«åèšã¹ããªããã¹ã®ïŒéšãå ¥ã30âã§ïŒæ¥éè©Š
æãåèšé°å²æ°äžã«ä¿åãããæ®ãã®ïŒéšã¯ã³ã³
ãããŒã«è©Šæãšããããã«ããªã³é°å²æ°ä¿ååŠç
ããè©Šæããã³ã³ã³ãããŒã«è©Šæãå®æœäŸïŒãšå
æ§ã®çŸååŠçãæœããåŸãããè©Šæã®ã«ããªæž¬å®
ãè¡ã€ãããã®çµæã¯ç¬¬ïŒè¡šã«ç€ºãã
æïŒïŒãïŒãïŒã10ã14ã15ïŒã¯æ¯èŒè©Šæã«æ¯ã¹
ãŠãã³ã³ãããŒã«è©ŠæïŒéä¿ååŠçïŒã«ãããŠ
ã¯ãã«ããªã¯äœãããã€é«æ床ãç¶æããŠããã
ãŸãä¿ååŠçã«ãããŠã¯ãæœåã®å€åå·Ÿãå°ã
ããã«ããªã®çºçãæªé²å ä¿ååŠçã§ã®æžæã«ã
æ¹è¯å¹æãã¿ãããã å®æœäŸïŒã§çšããæ¯èŒçšå¢æè²çŽ ã®æ§é ã¯äžèš
ã®éãã§ããã å®æœäŸ ïŒ å®æœäŸïŒã§äœæããè©Šæã«ã€ããããããïŒéš
ã®ã¹ããªããã¹ãäœæããããããŠã35ïŒ ã°ãªã»
ãªã³æ°Žæº¶æ¶²ã300mlããã40ïŒ ãã«ã ã¢ã«ããã
氎溶液ïŒmlãå«ãã 液ãåºéšã«ããããã€ããã®
液ãšå¹³è¡æ°Žæ ã«éããé°å²æ°ãå å ããå¯é容åš
ã«åèšã¹ããªããã¹ã®ïŒéšãå ¥ã30âã§ïŒæ¥éè©Š
æãåèšé°å²æ°äžã«ä¿åãããæ®ãã®ïŒéšã¯ã³ã³
ãããŒã«è©Šæãšããããã«ããªã³é°å²æ°ä¿ååŠç
ããè©Šæããã³ã³ã³ãããŒã«è©Šæãå®æœäŸïŒãšå
æ§ã®çŸååŠçãæœããåŸãããè©Šæã®ã«ããªæž¬å®
ãè¡ã€ãããã®çµæã¯ç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
ãè¡šã
åè¿°ããæ§ã«ãã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ
ãçšããå Žåããã«ããªã³ã¬ã¹ã«ããç¹ç°çã«ã«
ããªãçºçããäºãç¥ãããŠãããã第ïŒè¡šãã
æãããªæ§ã«ãã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ ã
çšããæ¬çºæã«ä¿ãå¢æè²çŽ ã®çµåããçšããäº
ã«ããããã«ããªã³ã¬ã¹ã«å¯ŸããŠãé¡èãªã«ããª
é²æ¢å¹æãæããŠããäºãå€ãã
ãçšããå Žåããã«ããªã³ã¬ã¹ã«ããç¹ç°çã«ã«
ããªãçºçããäºãç¥ãããŠãããã第ïŒè¡šãã
æãããªæ§ã«ãã€ãããŸãã«ã«ãã·ã¢ãã³è²çŽ ã
çšããæ¬çºæã«ä¿ãå¢æè²çŽ ã®çµåããçšããäº
ã«ããããã«ããªã³ã¬ã¹ã«å¯ŸããŠãé¡èãªã«ããª
é²æ¢å¹æãæããŠããäºãå€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžèšäžè¬åŒããã§è¡šããããå¢æè²çŽ ã®å°
ãªããšãäžçš®ãäžèšã®äžè¬åŒããã§è¡šãããã
å¢æè²çŽ ã®å°ãªããšãäžçš®ãåã³äžèšäžè¬åŒ
ããã§è¡šããããå¢æè²çŽ ã®å°ãªããšãäžçš®ãš
ãçµåãå«æããããã²ã³åéåçæå ææã äžè¬åŒãã ïŒåŒäžãY1ãY2ãY3ããã³Y4ã¯ãããããæ°ŽçŽ
ååãããã²ã³ååãäœçŽã¢ã«ãã«åºãã¢ã«ã³ã
ã·åºãããããã·ãã«ã«ããã·ãã¢ãªãŒã«åºãã·
ã¢ããã¢ããåºãããªãã«ãªãã¡ãã«ãã¢ã«ã³ã
ã·ã«ã«ããã«åºãã«ã«ãã¢ã«ã³ãã·åºãã¢ã·ã«ã¢
ããåºãã¢ã»ããã·åºãã¢ã·ã«åºããŸãã¯ã¢ã«ã³
ãã·ã«ã«ããã«ã¢ããåºãè¡šããããŸãY1ãšY2ã
Y3ãšY4ã¯ããããäºãã«é£çµããŠç°ã圢æããŠ
ããããR1ã¯æ°ŽçŽ ååãäœçŽã¢ã«ãã«åºãè¡šã
ããR2ãšR3ã¯ãããããã¢ã«ãã«åºãè¡šããã
X1 ã¯ã¢ããªã³ãè¡šãããn1ã¯ïŒãŸãã¯ïŒãè¡š
ãããïŒ äžè¬åŒãã ïŒåŒäžãY5ãY6ãY7ããã³Y8ã¯ãããããæ°ŽçŽ
ååãããã²ã³ååãã¢ã«ã³ãã·åºãã¢ããåºã
ã¢ã·ã«ã¢ããåºãã¢ã»ããã·åºãã¢ã«ã³ãã·ã«ã«
ããã«åºãã¢ã«ãã«ã¹ã«ããã«åºãã¹ã«ãã¢ã¢ã€
ã«åºãã·ã¢ãåºãŸãã¯ãããªãã«ãªãã¡ãã«ãè¡š
ãããR4ãR5ãR6ããã³R7ã¯ãã¢ã«ãã«åºã§ã
ããX2 ã¯ã¢ããªã³åºãè¡šãããn2ã¯ïŒãŸãã¯
ïŒãè¡šãããïŒ äžè¬åŒãã ïŒåŒäžãY9ãY10ãY11ããã³Y12ã¯ãããããã
æ°ŽçŽ ååãããã²ã³ååãäœçŽã¢ã«ãã«åºãã¢ã«
ã³ãã·åºãã¢ã«ã³ãã·ã«ã«ããã«åºããããã
ã·ãã«ã«ããã·ãã¢ãªãŒã«åºããŸãã¯ããªãã«ãª
ãã¡ãã«ãè¡šãããY9ãY10ãY11ãšY12ã¯ããã
ãäºãã«é£çµããŠç°ã圢æããŠããããR8ãR9
ã¯ãã¢ã«ãã«åºãè¡šãããX3 ã¯ã¢ããªã³ãè¡š
ãããn3ã¯ïŒãŸãã¯ïŒãè¡šãããïŒ
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3747382A JPS58153926A (ja) | 1982-03-09 | 1982-03-09 | ããã²ã³åéåçæå ææ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3747382A JPS58153926A (ja) | 1982-03-09 | 1982-03-09 | ããã²ã³åéåçæå ææ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58153926A JPS58153926A (ja) | 1983-09-13 |
| JPH0119571B2 true JPH0119571B2 (ja) | 1989-04-12 |
Family
ID=12498487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3747382A Granted JPS58153926A (ja) | 1982-03-09 | 1982-03-09 | ããã²ã³åéåçæå ææ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58153926A (ja) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4725529A (en) | 1985-04-30 | 1988-02-16 | Konishiroku Photo Industry Co., Ltd. | Developing inhibitor arrangment in light-sensitive silver halide color photographic materials |
| AU590563B2 (en) | 1985-05-16 | 1989-11-09 | Konishiroku Photo Industry Co., Ltd. | Method for color-developing a silver halide color photographic light-sensitive material |
| JP2517250B2 (ja) * | 1986-12-03 | 1996-07-24 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ã«ã©âééåçš¿ããé»çœç»åãããªã³ãããæ¹æ³ |
| JPH0348235A (ja) * | 1989-07-17 | 1991-03-01 | Fuji Photo Film Co Ltd | ããã²ã³åéåçä¹³å€ |
-
1982
- 1982-03-09 JP JP3747382A patent/JPS58153926A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58153926A (ja) | 1983-09-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4311781A (en) | Highly-sensitive high-contrast photographic materials | |
| GB2036351A (en) | Silver halide photographic emulsions | |
| US3976492A (en) | Silver halide photographic emulsions | |
| JPH07119976B2 (ja) | è¿ éåŠçå¯èœã§ã«ããªé²æ¢å¹æçã«ããããããã²ã³åéã«ã©âåçæå ææ | |
| JPS5911094B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPH06100795B2 (ja) | ããã²ã³åéåçæå ææ | |
| US5413905A (en) | Photographic sensitivity increasing alkynylamine compounds and photographic elements | |
| US4268617A (en) | Color photographic light-sensitive material | |
| JPH0119571B2 (ja) | ||
| US5389510A (en) | Photographic elements containing alkynylamine dopants | |
| EP0241107A2 (en) | Silver halide photograhic material that is resistant to fogging during storage | |
| JPH0558533B2 (ja) | ||
| US4544628A (en) | Silver halide photographic emulsion | |
| JPH02216147A (ja) | ããã²ã³åéã«ã©ãŒåçæå ææ | |
| EP0278666A2 (en) | Method of making a direct positive silver halide light- sensitive photographic material | |
| JPS6255644A (ja) | ããã²ã³åéåçæå ææ | |
| JP2651614B2 (ja) | ããã²ã³åéåçæå ææ | |
| JP2603066B2 (ja) | ããã²ã³åéåçæå ææ | |
| JPS62187339A (ja) | ããã²ã³åéåçæå ææ | |
| JPH11143000A (ja) | ããã²ã³åéåçæå ææåã³ç»å圢ææ¹æ³ | |
| JPH0558534B2 (ja) | ||
| JPH11133530A (ja) | ããã²ã³åéåçæå ææåã³ç»å圢ææ¹æ³ | |
| JPS62187842A (ja) | ããã²ã³åéåçæå ææ | |
| JPH032286B2 (ja) | ||
| JPS63316039A (ja) | ããã²ã³åéåçæå ææ |