JPH01175910A - Germicidal composition - Google Patents

Germicidal composition

Info

Publication number
JPH01175910A
JPH01175910A JP62330208A JP33020887A JPH01175910A JP H01175910 A JPH01175910 A JP H01175910A JP 62330208 A JP62330208 A JP 62330208A JP 33020887 A JP33020887 A JP 33020887A JP H01175910 A JPH01175910 A JP H01175910A
Authority
JP
Japan
Prior art keywords
active ingredients
parts
dideoxyarabinose
alanyl
diamino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62330208A
Other languages
Japanese (ja)
Inventor
Taizo Nakagawa
中川 泰三
Noriko Okuma
大熊 紀子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Nippon Kayaku Co Ltd
Original Assignee
Ajinomoto Co Inc
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc, Nippon Kayaku Co Ltd filed Critical Ajinomoto Co Inc
Priority to JP62330208A priority Critical patent/JPH01175910A/en
Publication of JPH01175910A publication Critical patent/JPH01175910A/en
Pending legal-status Critical Current

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE:To obtain a germicidal composition, containing a benzimidazle based germicide and 4-N-D-alanyl-2,4-diamino-2,4-dideoxyarabinose as active ingredients, effective against even chemical-resistant germs and capable of exhibiting high controlling effects especially by foliar spraying. CONSTITUTION:A germicidal composition obtained by containing methyl-1-(butylcarbamoyl)benzimidazol-2-yl-carbamate and 4-N-D-alanyl-2,4- diamino-2,4-dideoxyarabinose (hereinafter referred to as prumycin) as active ingredients. The blending ratio of the active ingredients is 20:1-1:2, preferably 16:1-1:1 weight ratio of the above-mentioned benzimidazole based germicide to the prumycin and the amount of the active ingredients is 0.1-99.9wt.%, preferably 0.2-80wt.% in the pharmaceutical. In application, the amount of the active ingredients is preferably 15-200g based on 10 areas. Furthermore, the composition is effective against, e.g. powdery mildew of apples and scab of pears.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明はベンズイミダゾール系殺菌剤とプルマイシンと
を有効成分として含有する殺菌組成物に関するものであ
り、水田、畑または果樹園などにおける農園芸用殺菌剤
として利用することができる。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a fungicidal composition containing a benzimidazole fungicide and purmycin as active ingredients, and is suitable for agricultural and horticultural use in paddy fields, fields, orchards, etc. It can be used as a disinfectant.

〔従来の技術〕[Conventional technology]

本発明組成物の有効成分の一つであるメチル園芸用作物
に寄生する種々の病原菌に対し優れた防除効果を示し、
現在農園芸用殺菌剤として広く一般に使用されている。
Methyl, which is one of the active ingredients of the composition of the present invention, exhibits excellent control effects against various pathogenic bacteria parasitic on horticultural crops,
Currently, it is widely used as a fungicide for agriculture and horticulture.

しかし、その連用によって特に灰色かび病をはじめ、種
々の病害で薬剤耐性菌の出現がみられ、防除効果が低下
し、一部の地域では、全(防除効果がみられな(なって
いる。一方、プルマイシンはJ、Antibiotic
s24:900〜901(1971)記載の既知の抗生
物質であり、特公昭57−8718により人造され、各
種農園芸用作物病害に有効であることが知られている(
特開昭5O−33128)。
However, due to its continued use, drug-resistant bacteria have appeared for various diseases, especially gray mold, and the control effect has decreased, and in some areas, no control effect has been observed at all. On the other hand, purmycin is classified by J. Antibiotic
s24:900-901 (1971), was created by Japanese Patent Publication No. 57-8718, and is known to be effective against various agricultural and horticultural crop diseases (
JP-A-5O-33128).

〔発明が解決しようとしている問題点〕従来の殺菌剤に
対する薬剤耐性菌の出現は農園芸用作物病害の防除にお
いて非常に重大な問題となっており、これら薬剤耐性菌
が出現しに本発明者は化合物A(ベノミル)およびプル
為ことにより、従来の殺菌剤の欠点を補い、既存農薬に
対する耐性菌に卓効を示し、さらに植物体に薬害などの
悪影響を及ぼさない有用な農園芸用殺菌剤を提供しよう
とするものである。
[Problem to be solved by the invention] The emergence of drug-resistant bacteria to conventional fungicides has become a very serious problem in the control of agricultural and horticultural crop diseases. is a useful agricultural and horticultural fungicide that compensates for the drawbacks of conventional fungicides, is extremely effective against bacteria resistant to existing pesticides, and does not have any negative effects on plants such as phytotoxicity. This is what we are trying to provide.

本発明殺菌組成物を農園芸用殺菌剤として使用する場合
、使用目的に応じてそのままか又は効果を助長あるいは
安定にするために農薬補助剤を混用して、農薬製造分野
において一般に行なわれている方法により、粉剤、細粒
剤、粒剤、水和剤、フロアブル剤および乳剤等の製剤形
態にして使用することができる。
When the fungicidal composition of the present invention is used as a fungicide for agriculture and horticulture, depending on the purpose of use, it is generally used in the field of agrochemical manufacturing, either as is or with a mixture of pesticide adjuvants to enhance or stabilize the effect. Depending on the method, it can be used in the form of preparations such as powders, fine granules, granules, wettable powders, flowable preparations, and emulsions.

これらの種々の裂創は実際の使用に際しては直接そのま
ま使用するか、または水で所望の濃度に希釈して使用す
ることができる。
In actual use, these various lacerations can be used directly or diluted with water to a desired concentration.

好ましくは1鶏:1〜1:1の割合で、0.1〜99.
9係、好ましくは0.2〜80%含有するように、通常
の製剤方法に従って調整する。
Preferably at a ratio of 1:1 to 1:1, 0.1 to 99.
9, preferably 0.2 to 80%, according to a usual formulation method.

上記の農薬補助剤としては担体(希釈剤)およびその他
の補助剤たとえば展着剤、乳化剤、湿展剤、分散剤、固
着剤、崩壊剤等をあげることができる。
Examples of the above agricultural chemical auxiliary agents include carriers (diluents) and other auxiliary agents such as spreading agents, emulsifiers, wetting agents, dispersants, fixing agents, and disintegrants.

液体担体としてはトルエン、キシレン等の芳香族炭化水
素、メタノール、ブタノール、グリコール等のアルコー
ル類、アセトン等のケトン類、ジメチルホルムアミド等
のアミド類、ジメチルスルホキシド等のスルホキシド類
、メチルナフタレンシクロヘキサン、動植物油、脂肪酸
、脂肪酸エステル等があげられる。
Liquid carriers include aromatic hydrocarbons such as toluene and xylene, alcohols such as methanol, butanol, and glycol, ketones such as acetone, amides such as dimethylformamide, sulfoxides such as dimethyl sulfoxide, methylnaphthalenecyclohexane, and animal and vegetable oils. , fatty acids, fatty acid esters, etc.

固体担体としてはクレー、カオリン、タルク、珪藻土、
シリカ、炭酸カルシウム、モンモリロナイト、ベントナ
イト、長石、石英、アルミナ、鋸屑等があげられる。
Solid carriers include clay, kaolin, talc, diatomaceous earth,
Examples include silica, calcium carbonate, montmorillonite, bentonite, feldspar, quartz, alumina, and sawdust.

また乳化剤または分散剤としては通常界面活性剤が使用
され、たとえば高級アルコール硫酸ナトリウム、アテア
リルトリメチルアンモニウムクロライド、ポリオキシエ
チレンアルキルフェニルエーテル、ラウリルベタイン等
の陰イオン系界面活性剤、陽イオン系界面活性剤、非イ
オン系界面活性剤、両性イオン系界面活性剤があげられ
る。
In addition, surfactants are usually used as emulsifiers or dispersants, such as anionic surfactants such as higher alcohol sodium sulfate, atearyltrimethylammonium chloride, polyoxyethylene alkylphenyl ether, lauryl betaine, and cationic surfactants. surfactants, nonionic surfactants, and amphoteric surfactants.

展着剤としてはポリオキシエチレンノニルフェニルエー
テル、ポリオキシエチレンラウリルエーテル等が、湿展
剤としてはポリオキシエチレンノニルフェニル、ジアル
キルスルホサクシネート等が、固着剤としてはカルボキ
シメチルセルローズ、ポリビニルアルコールが、崩壊剤
としてはりゲニンスルホン酸ナトリウム、ラウリル硫酸
ナトリウム等があげられる。
Spreading agents include polyoxyethylene nonylphenyl ether, polyoxyethylene lauryl ether, etc. Wetting agents include polyoxyethylene nonylphenyl, dialkyl sulfosuccinate, etc., and fixing agents include carboxymethyl cellulose and polyvinyl alcohol. Examples of disintegrants include sodium pyrogenin sulfonate and sodium lauryl sulfate.

いずれの裂1剤もそのまま単独でしようできるのみなら
ず、他の農園芸用殺菌剤、殺虫剤、植物成長調節剤、殺
ダニ剤と混合して使用することもできる。
Not only can any of the fission agents be used alone, but they can also be used in combination with other agricultural and horticultural fungicides, insecticides, plant growth regulators, and acaricides.

本発明殺菌組成物を農園芸用殺菌剤として施用する場合
、その施用量は通常10アールあたり有効成分量で10
〜300g、好ましくハ15〜2oogが使用される。
When the fungicidal composition of the present invention is applied as a fungicide for agriculture and horticulture, the amount of application is usually 100% of the active ingredient per 10ares.
~300 g, preferably 15-20 g is used.

その施用濃度は水和剤、液剤等水で希釈して施用する場
合、o、ooi〜0.4係の範囲が好ましい。
The application concentration is preferably in the range of o, ooi to 0.4 when diluted with water, such as a wettable powder or liquid preparation.

また、粉剤、粒剤、微粒剤等の場合は、剤型、使用する
方法、時期、その他の条件によって異なり、さらに上記
の範囲にこだわることな(増減し、濃度を変更してもよ
い。
In addition, in the case of powders, granules, fine granules, etc., it varies depending on the dosage form, method of use, timing, and other conditions, and the range is not limited to the above (it may be increased or decreased, and the concentration may be changed).

本発明は下記の作物病害の防除に有効であるがこれらに
限定されるものでない。
The present invention is effective for controlling the following crop diseases, but is not limited thereto.

リンゴうどんこ病(Podosphaera 1euc
otricha)リンゴ黒星病(Venturia 1
naequalis)リンゴ斑点落葉病(Altern
aria mali)リンゴモニリア病(Monili
nia mali)ブドウ灰色かび病(Botryti
s cinerea)ブドウうどんこ病(Uncinu
la necator)ムギ類赤さび病(Puccin
ia recondita)ムギ類裸黒穂病(Usti
lage nuda)ムギ類赤かび病(Gibbell
era zeae)キーウリ灰色かび病(Botryt
is cinerea)キュウリ菌核病(Sclero
tinia sclerotiorum )キュウリ黒
星病(Cladosporium cucumerin
um)トマト灰色かび病(坐泣虫金上) トマト菌核病(Sclerotinia sclero
tiorum)トマト葉かび病(Cladospori
um fulvum)ナス灰色かび病(Botryti
s cinerea)ナス菌核病(Sclerotin
ia sclerotiorum )ピーマン灰色かび
病(主遼裏珈二) イチゴ灰色かび病(Botrytisヰニ)タマネギ灰
色腐敗病(敗町囲煎) 〔発明の効果〕 本発明の殺菌組成物は特に茎葉散布によって高い防除効
果を示し、薬剤耐性の菌にも有効であり、また予期し−
えない高い相乗効果を有することを見出し、本発明を完
成した。
Apple powdery mildew (Podosphaera 1euc)
otricha) apple scab (Venturia 1)
naequalis) apple spot leaf disease (Altern)
aria mali) apple moniliosis (monili)
nia mali) grape gray mold (Botryti)
s cinerea) grape powdery mildew (Uncinu
la necator) Wheat Rust (Puccin)
ia recondita) wheat naked smut (Usti
gibbell)
era zeae) Botrytis botrytis
is cinerea) cucumber sclerotia
tinia sclerotiorum) cucumber scab (Cladosporium cucumerin)
um) Tomato gray mold (Sclerotinia sclero)
tiorum) tomato leaf mold (Cladospori)
um fulvum) Botryti
S cinerea) Solanum sclerotia
ia sclerotiorum) Botrytis gray mold of green pepper (Botrytis wini) Gray mold of onion (Setsumachi Isen) [Effects of the invention] The fungicidal composition of the present invention has a high effect, especially when sprayed on foliage. It shows a control effect, is effective against drug-resistant bacteria, and has an unexpected -
The present invention was completed based on the discovery that the present invention has an extremely high synergistic effect.

次に本発明の農園芸用殺菌剤としての製剤例を具体的に
さらに詳細に説明するが、農薬補助剤の種類および混合
比率はこれらのみに限定されることなく、広い範囲で使
用可能である。なお、「部」とあるのは「重量部」を意
味する。
Next, examples of the formulation as an agricultural and horticultural fungicide of the present invention will be specifically explained in more detail, but the types and mixing ratios of the pesticide adjuvant are not limited to these, and can be used in a wide range. . Note that "parts" means "parts by weight."

製剤例1.粉 剤 化合物A4部とプルマイシン1部とタルク46部および
クレー49部を混合粉砕し、粉剤とする。
Formulation example 1. Powder 4 parts of compound A, 1 part of purmycin, 46 parts of talc, and 49 parts of clay are mixed and ground to form a powder.

リン45部と高級アルコール硫酸ナトリウム3部および
リグニンスルホン酸ナトリウム2部とを混合粉砕し水和
剤とする。
45 parts of phosphorus, 3 parts of higher alcohol sodium sulfate, and 2 parts of sodium lignin sulfonate are mixed and ground to prepare a wettable powder.

35部、ベントナイト23部、メルク30部および崩壊
剤2部を混合した後、水18部を加え、均等に湿潤させ
、次に射出成形機を通して押し出し、造粒し、整粒機で
整粒した後、乾燥し粒径0.6mm−1mmの粒剤とす
る。
After mixing 35 parts of bentonite, 23 parts of bentonite, 30 parts of Merck and 2 parts of disintegrant, 18 parts of water was added to evenly moisten, then extruded through an injection molding machine, granulated, and sized with a sizing machine. After that, it is dried to form granules with a particle size of 0.6 mm to 1 mm.

製剤例4.微粒剤 化合物A6部とプルマイシン2部をポリビニルアルコー
ル6部およびクレー9部を均一に混合粉砕し、濃厚粉状
物となす。別に74〜105μの油井吸収性の鉱物質粗
粉80部を適当な混合機に入れ回転しながら水20部を
加え湿らせ、上記濃厚粉状物を添加し被覆せしめ乾燥し
微粒剤とする。
Formulation example 4. 6 parts of fine granule compound A and 2 parts of purmycin are uniformly mixed and pulverized with 6 parts of polyvinyl alcohol and 9 parts of clay to form a thick powder. Separately, 80 parts of oil well-absorbing mineral coarse powder of 74 to 105 microns is placed in a suitable mixer, and 20 parts of water is added while rotating to moisten it, and the above-mentioned thick powder is added, coated, and dried to form fine granules.

レン63部に溶解し、これにアルキルフェノールエチレ
ンオキシド縮合物とアルキルベンゼンスルホン酸カルシ
ウムの混合物(8: 2)17部を混合溶解して乳剤と
する。
A mixture of an alkylphenol ethylene oxide condensate and calcium alkylbenzene sulfonate (8:2) (17 parts) was mixed and dissolved therein to prepare an emulsion.

本則は水で薄めて、乳濁液として使用する。The basic rule is to dilute it with water and use it as an emulsion.

次に本発明の殺菌組成物が各種の農園芸用作物病害に対
し、すぐれた防除効果を有していることを実験例により
説明する。
Next, it will be explained using experimental examples that the fungicidal composition of the present invention has excellent control effects against various agricultural and horticultural crop diseases.

実験例1.インゲン灰色かび病防除試験(薬剤窓性菌) 製剤例2.に準じて炸裂した水和剤を水で希釈し、イン
ゲンマメの初生葉(品種:新江戸用)に散布し風乾径径
5uのコルクポーラで打ち抜いた灰色かび病菌(Bot
rytis cinerea)の、菌糸片を静置し、温
室状態に保ち発病させ、72時間後に病斑直径を調査し
、防除価を算出した。
Experimental example 1. Green bean gray mold control test (drug window fungus) Formulation example 2. The hydrating agent exploded in accordance with
rytis cinerea) were allowed to develop in a greenhouse, and the lesion diameter was examined after 72 hours to calculate the control value.

結果は第1表のとおりである。防除価は次のように算出
した。
The results are shown in Table 1. The control value was calculated as follows.

第1表 実験例2. インゲン灰色かび病防除試験(薬剤耐性角
) 灰色かび病菌はベンズイミダゾール系耐性菌を用いた。
Table 1 Experimental Example 2. Green bean gray mold control test (drug resistance) A benzimidazole-resistant bacteria was used as the gray mold fungus.

他の試験方法は実験例1.に準じた。結果は第2表のと
おりである。
Other test methods are Experimental Example 1. According to. The results are shown in Table 2.

第2表 特許出願人  日本化薬株式会社Table 2 Patent applicant: Nippon Kayaku Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] メチル−1−(ブチルカルバモイル)ベンズイミダゾー
ル−2−イルカーバメイトと4−N−D−アラニル−2
,4−ジアミノ−2,4−ジデオキシアラビノース(以
下プルマイシンと称す)とを有効成分として含有するこ
とを特徴とする農園芸用殺菌組成物
Methyl-1-(butylcarbamoyl)benzimidazol-2-ylcarbamate and 4-N-D-alanyl-2
, 4-diamino-2,4-dideoxyarabinose (hereinafter referred to as purmycin) as an active ingredient.
JP62330208A 1987-12-28 1987-12-28 Germicidal composition Pending JPH01175910A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62330208A JPH01175910A (en) 1987-12-28 1987-12-28 Germicidal composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62330208A JPH01175910A (en) 1987-12-28 1987-12-28 Germicidal composition

Publications (1)

Publication Number Publication Date
JPH01175910A true JPH01175910A (en) 1989-07-12

Family

ID=18230054

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62330208A Pending JPH01175910A (en) 1987-12-28 1987-12-28 Germicidal composition

Country Status (1)

Country Link
JP (1) JPH01175910A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006526537A (en) * 2003-06-04 2006-11-24 ベール ゲーエムベーハー ウント コー カーゲー Air conditioning equipment for automobile air conditioning equipment
KR20180119689A (en) 2016-08-09 2018-11-02 가부시키가이샤 에스디에스 바이오텍크 Disinfecting composition for agricultural and horticultural use and method for controlling plant disease

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006526537A (en) * 2003-06-04 2006-11-24 ベール ゲーエムベーハー ウント コー カーゲー Air conditioning equipment for automobile air conditioning equipment
KR20180119689A (en) 2016-08-09 2018-11-02 가부시키가이샤 에스디에스 바이오텍크 Disinfecting composition for agricultural and horticultural use and method for controlling plant disease
US10412963B2 (en) 2016-08-09 2019-09-17 Sds Biotech K.K. Agricultural and horticultural fungicide composition and plant disease controlling method

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