JP7485597B2 - 消臭剤及び不活性化剤 - Google Patents
消臭剤及び不活性化剤 Download PDFInfo
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- 239000002781 deodorant agent Substances 0.000 title claims description 105
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 60
- YWHLKYXPLRWGSE-UHFFFAOYSA-N Dimethyl trisulfide Chemical compound CSSSC YWHLKYXPLRWGSE-UHFFFAOYSA-N 0.000 claims description 50
- 230000001877 deodorizing effect Effects 0.000 claims description 45
- 239000011787 zinc oxide Substances 0.000 claims description 30
- 230000003340 mental effect Effects 0.000 claims description 29
- ULIKDJVNUXNQHS-UHFFFAOYSA-N 2-Propene-1-thiol Chemical compound SCC=C ULIKDJVNUXNQHS-UHFFFAOYSA-N 0.000 claims description 28
- 239000000126 substance Substances 0.000 claims description 26
- 229910021536 Zeolite Inorganic materials 0.000 claims description 21
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 21
- 239000010457 zeolite Substances 0.000 claims description 21
- 229910052709 silver Inorganic materials 0.000 claims description 16
- 239000004332 silver Substances 0.000 claims description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical group [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 15
- KLTVSWGXIAYTHO-UHFFFAOYSA-N 1-Octen-3-one Chemical compound CCCCCC(=O)C=C KLTVSWGXIAYTHO-UHFFFAOYSA-N 0.000 claims description 12
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 claims description 12
- 229940094522 laponite Drugs 0.000 claims description 10
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 claims description 10
- ODLHGICHYURWBS-LKONHMLTSA-N trappsol cyclo Chemical compound CC(O)COC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](COCC(C)O)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)COCC(O)C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1COCC(C)O ODLHGICHYURWBS-LKONHMLTSA-N 0.000 claims description 9
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 8
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 claims description 8
- 229940094952 green tea extract Drugs 0.000 claims description 8
- 235000020688 green tea extract Nutrition 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 230000004800 psychological effect Effects 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 235000019645 odor Nutrition 0.000 description 114
- 230000035882 stress Effects 0.000 description 54
- 230000000694 effects Effects 0.000 description 26
- 230000000937 inactivator Effects 0.000 description 22
- 230000000415 inactivating effect Effects 0.000 description 18
- 230000004913 activation Effects 0.000 description 14
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- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 10
- 235000010384 tocopherol Nutrition 0.000 description 10
- 229960001295 tocopherol Drugs 0.000 description 10
- 229930003799 tocopherol Natural products 0.000 description 10
- 239000011732 tocopherol Substances 0.000 description 10
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 150000003464 sulfur compounds Chemical class 0.000 description 9
- 208000035985 Body Odor Diseases 0.000 description 8
- 235000004347 Perilla Nutrition 0.000 description 8
- 241000229722 Perilla <angiosperm> Species 0.000 description 8
- 206010040904 Skin odour abnormal Diseases 0.000 description 8
- 241001092070 Eriobotrya Species 0.000 description 7
- 235000009008 Eriobotrya japonica Nutrition 0.000 description 7
- 230000008451 emotion Effects 0.000 description 7
- 229940057070 sugarcane extract Drugs 0.000 description 7
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 6
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 102400001107 Secretory component Human genes 0.000 description 5
- 230000032683 aging Effects 0.000 description 5
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- 244000237986 Melia azadirachta Species 0.000 description 4
- 235000013500 Melia azadirachta Nutrition 0.000 description 4
- 230000036506 anxiety Effects 0.000 description 4
- 238000004332 deodorization Methods 0.000 description 4
- 206010016256 fatigue Diseases 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 206010024264 Lethargy Diseases 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 210000003128 head Anatomy 0.000 description 3
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- 239000002245 particle Substances 0.000 description 3
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- 230000000284 resting effect Effects 0.000 description 3
- OTKQNSSMCDLVQV-UHFFFAOYSA-N Butyl 2-methylbutanoate Chemical compound CCCCOC(=O)C(C)CC OTKQNSSMCDLVQV-UHFFFAOYSA-N 0.000 description 2
- 206010020400 Hostility Diseases 0.000 description 2
- ZOYASYRPGHCQHW-UHFFFAOYSA-N Methyl propyl trisulfide Chemical compound CCCSSSC ZOYASYRPGHCQHW-UHFFFAOYSA-N 0.000 description 2
- 102000012547 Olfactory receptors Human genes 0.000 description 2
- 108050002069 Olfactory receptors Proteins 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000031018 biological processes and functions Effects 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 208000035475 disorder Diseases 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 208000020016 psychiatric disease Diseases 0.000 description 2
- 230000003248 secreting effect Effects 0.000 description 2
- 230000008786 sensory perception of smell Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- YHQGMYUVUMAZJR-UHFFFAOYSA-N α-terpinene Chemical compound CC(C)C1=CC=C(C)CC1 YHQGMYUVUMAZJR-UHFFFAOYSA-N 0.000 description 2
- VVGOCOMZRGWHPI-ARJAWSKDSA-N (z)-4-heptenal Chemical compound CC\C=C/CCC=O VVGOCOMZRGWHPI-ARJAWSKDSA-N 0.000 description 1
- RFFOTVCVTJUTAD-AOOOYVTPSA-N 1,4-cineole Chemical compound CC(C)[C@]12CC[C@](C)(CC1)O2 RFFOTVCVTJUTAD-AOOOYVTPSA-N 0.000 description 1
- 206010006326 Breath odour Diseases 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- CCEFMUBVSUDRLG-XNWIYYODSA-N Limonene-1,2-epoxide Chemical compound C1[C@H](C(=C)C)CCC2(C)OC21 CCEFMUBVSUDRLG-XNWIYYODSA-N 0.000 description 1
- WSTYNZDAOAEEKG-UHFFFAOYSA-N Mayol Natural products CC1=C(O)C(=O)C=C2C(CCC3(C4CC(C(CC4(CCC33C)C)=O)C)C)(C)C3=CC=C21 WSTYNZDAOAEEKG-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000001343 butyl (2R)-2-methylbutanoate Substances 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- RFFOTVCVTJUTAD-UHFFFAOYSA-N cineole Natural products C1CC2(C)CCC1(C(C)C)O2 RFFOTVCVTJUTAD-UHFFFAOYSA-N 0.000 description 1
- 230000009982 effect on human Effects 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- -1 silver ions Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/27—Zinc; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biotechnology (AREA)
- Botany (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
消臭剤0.05質量%とジプロピレングリコール99.95質量%とを混合して、それぞれの消臭剤について消臭剤溶液を作製した。消臭剤溶液1mLと、消臭剤1質量部に対して5×10-4質量部のジメチルトリスルフィドと、を30ミリリットル容量のサンプル管に注入した。専門パネル3人が、サンプル管内の匂いを嗅いで、以下の基準で各消臭剤のジメチルトリスルフィドに対する消臭効果を評価した。
2点:専門パネルが、消臭剤の消臭効果が高いと評価した;
1点:専門パネルが、消臭剤の消臭効果がやや高いと評価した;
0点:専門パネルが、消臭剤の消臭効果が無いと評価した。
B:1.5点以上2点未満;
C:1点以上1.5点未満;
D:1点未満。
消臭剤0.10質量%とジプロピレングリコール99.90質量%とを混合して、それぞれの消臭剤について消臭剤溶液を作製した。消臭剤溶液1mLと、消臭剤1質量部に対して5×10-6質量部のアリルメルカプタンと、を30ミリリットル容量のサンプル管に注入した。専門パネル3人が、サンプル管内の匂いを嗅いで、以下の基準で各消臭剤のアリルメルカプタンに対する消臭効果を評価した。表2に、試験した消臭剤と、各消臭剤についての専門パネルによる消臭効果の評価を示す。評価基準は実施例1と同様である。
消臭剤0.10質量%とジプロピレングリコール99.90質量%とを混合して、それぞれの消臭剤について消臭剤溶液を作製した。消臭剤は、成分Aとして酸化亜鉛50質量%と、表3に示す成分B50質量%と、を含有する。消臭剤溶液1mLと、消臭剤1質量部に対して2.5×10-6質量部のアリルメルカプタンと、を30ミリリットル容量のサンプル管に注入した。専門パネル3人が、サンプル管内の匂いを嗅いで、以下の基準で各消臭剤のアリルメルカプタンに対する消臭効果を評価した。表3に、試験した消臭剤と、各消臭剤についての専門パネルによる消臭効果の評価を示す。評価基準は実施例1と同様である。
成分Aとして酸化亜鉛、成分Bとしてヒドロキシプロピル-β-デキストリンを含有する、表4に示す消臭剤を作製した。次に、表5に示す緊張臭成分を含有する緊張臭モデル組成物を作製した。次に、100mLの密閉ガラス容器中で緊張臭モデル組成物100μL及び消臭剤10μLを混合した。そして、密閉ガラス容器を10分間静置した後、密閉ガラス容器の上部空間に存在する気体成分を直接質量分析法により分析した。
被験者に緊張臭のモデル組成物を嗅がせて、POMS(登録商標)及びGACLを用いて緊張臭による被験者の心理的・精神的変化を確認した。その結果、被験者は、緊張臭を嗅ぐと覚醒、疲労及び混乱が生じることが確認された。
1点:提示された気分が少しあった;
2点:提示された気分がまあまああった;
3点:提示された気分がかなりあった;
4点:提示された気分が非常に多くあった。
Claims (4)
- 緊張臭消臭剤であって、
緊張臭成分中のアリルメルカプタン及びジメチルトリスルフィドによるネガティブな心理的又は精神的作用を不活性化する第1の消臭成分及び第2の消臭成分を含み、
前記第1の消臭成分は、銀担持ゼオライトであり、
前記第2の消臭成分は、銀担持ゼオライト、酸化亜鉛、及びこれらの組合せからなる群から選択される少なくとも1つであり、
前記緊張臭の原因物質は、アリルメルカプタン及びジメチルトリスルフィドを含む、
緊張臭消臭剤。 - 緊張臭消臭剤であって、
緊張臭成分中のアリルメルカプタン及びジメチルトリスルフィドによるネガティブな心理的又は精神的作用を不活性化する第1の消臭成分及び第2の消臭成分を含み、
前記第1の消臭成分は、酸化亜鉛であり、
前記第2の消臭成分は、酸化亜鉛、ラポナイト、銀担持ゼオライト、ヒドロキシプロピル-β-シクロデキストリン、緑茶エキス、及びこれらの組合せからなる群から選択される少なくとも1つであり、
前記緊張臭の原因物質は、アリルメルカプタン及びジメチルトリスルフィドを含む、
緊張臭消臭剤。 - 前記原因物質が、メチルメルカプタン、ジメチルスルフィド、ジメチルジスルフィド、及びこれらの組合せからなる群から選択される少なくとも1つの化合物をさらに含有する、請求項1~2のいずれか一項に記載の緊張臭消臭剤。
- 前記原因物質が、1-オクテン-3-オンをさらに含む、請求項1~3のいずれか一項に記載の緊張臭消臭剤。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2018100599 | 2018-05-25 | ||
JP2018100599 | 2018-05-25 | ||
PCT/JP2019/020760 WO2019225755A1 (ja) | 2018-05-25 | 2019-05-24 | 消臭剤及び不活性化剤 |
Publications (2)
Publication Number | Publication Date |
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JPWO2019225755A1 JPWO2019225755A1 (ja) | 2021-07-26 |
JP7485597B2 true JP7485597B2 (ja) | 2024-05-16 |
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JP2020520404A Active JP7485597B2 (ja) | 2018-05-25 | 2019-05-24 | 消臭剤及び不活性化剤 |
Country Status (4)
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JP (1) | JP7485597B2 (ja) |
CN (1) | CN112203631B (ja) |
TW (1) | TW202002936A (ja) |
WO (1) | WO2019225755A1 (ja) |
Citations (3)
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JP2017061423A (ja) | 2015-09-24 | 2017-03-30 | 株式会社ベネフィット−イオン | 消臭製品の製造方法及び評価装置 |
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JP4500705B2 (ja) * | 2005-02-22 | 2010-07-14 | ニベア花王株式会社 | デオドラント化粧料 |
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CN107375047A (zh) * | 2017-07-03 | 2017-11-24 | 李剑峰 | 白藜芦醇‑环糊精包合物凝胶及其制备方法和应用 |
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WO2019225755A1 (ja) | 2019-11-28 |
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