JP7465811B2 - 非極性有機ポリマーおよび超低湿潤性カーボンブラックの複合物 - Google Patents
非極性有機ポリマーおよび超低湿潤性カーボンブラックの複合物 Download PDFInfo
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- JP7465811B2 JP7465811B2 JP2020550130A JP2020550130A JP7465811B2 JP 7465811 B2 JP7465811 B2 JP 7465811B2 JP 2020550130 A JP2020550130 A JP 2020550130A JP 2020550130 A JP2020550130 A JP 2020550130A JP 7465811 B2 JP7465811 B2 JP 7465811B2
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- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- LRGQZEKJTHEMOJ-UHFFFAOYSA-N propane-1,2,3-triol;zinc Chemical compound [Zn].OCC(O)CO LRGQZEKJTHEMOJ-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000000974 shear rheometry Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical class [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004441 surface measurement Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052713 technetium Inorganic materials 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/201—Pre-melted polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/20—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils
- H01B3/22—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances liquids, e.g. oils hydrocarbons
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/02—Disposition of insulation
- H01B7/0275—Disposition of insulation comprising one or more extruded layers of insulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Conductive Materials (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Description
Claims (12)
- 半導電性複合材料であって、
(A)非極性ポリオレフィンポリマー、
(B)導電有効量である20重量%未満の超低湿潤性カーボンブラック(ULW-CB)であって、Brunauer-Emmett-Teller(BET)窒素表面積試験方法によって測定された、35~190平方メートル/グラム(m2/g)のBET窒素表面積と、吸油量試験方法によって測定された、115~180ミリリットル油/100グラム(mL/100g)の吸油量(OAN)と、吸湿性試験方法によって測定された、400~2400百万分率(ppm、重量)の吸水性と、を有する、超低湿潤性カーボンブラック、及び、
5.0重量%未満の極性有機ポリマーを含む、半導電性複合材料。 - 前記(B)ULW-CBが、限定(i)~(iii):(i)前記(B)ULW-CBが、前記BET窒素表面積試験方法によって測定された、40~63m2/gのBET窒素表面積と、前記吸油量試験方法によって測定された、120~150mL/100gのOANと、を有する、(ii)前記(B)ULW-CBが、前記BET窒素表面積試験方法によって測定された、120~180m2/gのBET窒素表面積と、前記吸油量試験方法によって測定された、150~175mL/100gのOANと、を有する、ならびに(iii)前記(B)ULW-CBが、(i)および(ii)の前記ULW-CBのブレンドである、のうちのいずれか1つによって特徴付けられる、請求項1に記載の半導電性複合材料。
- 前記(B)ULW-CBが、限定(i):(i)前記BET窒素表面積試験方法によって測定された、40~180m2/gのBET窒素表面積によって特徴付けられる、請求項1に記載の半導電性複合材料。
- 前記超低湿潤性カーボンブラック以外のカーボンブラックを含まない、請求項1~3のいずれか1項に記載の半導電性複合材料。
- 限定(i)~(v):(i)前記半導電性複合材料の総重量に基づいて、61.0~99.0重量%の前記(A)非極性ポリオレフィンポリマー、および19.0~1.5重量%の前記(B)ULW-CBを含む、(ii)前記(A)非極性ポリオレフィンポリマーが、非極性エチレン系ポリマーである、(iii)(i)および(ii)の両方、(iv)前記(A)非極性ポリオレフィンポリマーが、非極性プロピレン系ポリマーである、ならびに(v)(i)および(iv)の両方、のうちのいずれか1つによって特徴付けられる、請求項1~4のいずれか1項に記載の半導電性複合材料。
- (C)プラストマー、(D)酸化防止剤、(E)有機過酸化物、(F)スコーチ遅延剤、(G)アルケニル官能性補助剤、(H)核形成剤、(I)加工助剤、(J)エキステンダー油、(K)安定剤(例えば、紫外線(UV)光に関連する劣化を抑制する化合物)から選択される少なくとも1種の添加剤をさらに含む、請求項1~5のいずれか1項に記載の半導電性複合材料。
- 請求項1~6のいずれか1項に記載の半導電性複合材料の作製方法であって、導電有効量である20重量%未満の前記(B)超低湿潤性カーボンブラック(ULW-CB)を、前記(A)非極性ポリオレフィンポリマーの溶融物に混合して、成分(A)および(B)を含む溶融ブレンドとして、前記半導電性複合材料を得ることを含む、方法。
- 請求項1~6のいずれか1項に記載の半導電性複合材料を硬化させた生成物である架橋ポリエチレン生成物。
- 請求項1~6のいずれか1項に記載の、もしくは請求項7に記載の方法によって作製された半導電性複合材料、または請求項8に記載の架橋ポリエチレン生成物の成形形態を含む、製造物品。
- 導電性コアと、前記導電性コアを少なくとも部分的に被覆する半導電性層と、を含む導電体デバイスであって、前記半導電性層の少なくとも一部が、請求項1~6のいずれか1項に記載の半導電性複合材料、請求項7に記載の方法によって作製された半導電性複合材料、または請求項8に記載の架橋ポリエチレン生成物を含む、デバイス。
- 電気の伝導方法であって、請求項10に記載の導電体デバイスの導電性コアにわたって電圧を印加して、前記導電性コアを通る電気の流動を発生させることを含む、方法。
- 請求項1~6のいずれか1項に記載の半導電性複合材料を、前記半導電性複合材料を170℃~190℃に1~5分間加熱することを含む熱サイクルに付し、次いで30℃に冷却して、冷却された熱サイクル半導電性複合材料を得ることを含む、熱サイクル半導電性複合材料の作製方法。
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US201862649114P | 2018-03-28 | 2018-03-28 | |
US62/649,114 | 2018-03-28 | ||
PCT/US2019/023505 WO2019190899A1 (en) | 2018-03-28 | 2019-03-22 | Composite of non-polar organic polymer and ultra-low-wettability carbon black |
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JP7465811B2 true JP7465811B2 (ja) | 2024-04-11 |
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US (1) | US11993693B2 (ja) |
EP (1) | EP3775010A1 (ja) |
JP (1) | JP7465811B2 (ja) |
KR (1) | KR20200135981A (ja) |
CN (1) | CN111971334B (ja) |
CA (1) | CA3094807A1 (ja) |
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TW202239854A (zh) | 2021-03-31 | 2022-10-16 | 美商陶氏全球科技有限責任公司 | 可濕固化半導電調配物 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001040148A (ja) | 1999-06-30 | 2001-02-13 | Union Carbide Chem & Plast Technol Corp | ケーブル半導電性シールド |
JP2001310980A (ja) | 2000-04-28 | 2001-11-06 | Nippon Unicar Co Ltd | 架橋性エチレン系樹脂組成物及びこれを被覆してなる電線・ケーブル |
JP2004510836A (ja) | 1999-12-02 | 2004-04-08 | キャボット コーポレイション | 電線およびケーブル用コンパウンドに有用なカーボンブラック |
JP2007505975A (ja) | 2003-09-18 | 2007-03-15 | コロンビアン ケミカルズ カンパニー | 各種用途に用いられる熱改質カーボンブラック及びその製造方法 |
JP2020524362A (ja) | 2017-06-15 | 2020-08-13 | キャボット コーポレイションCabot Corporation | 異なるカーボンブラック粒子を含有する電極及び電池 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4018852A (en) | 1974-11-27 | 1977-04-19 | Union Carbide Corporation | Composition with triallyl compounds and process for avoiding scorching of ethylene polymer composition |
US5266627A (en) | 1991-02-25 | 1993-11-30 | Quantum Chemical Corporation | Hydrolyzable silane copolymer compositions resistant to premature crosslinking and process |
US5246783A (en) | 1991-08-15 | 1993-09-21 | Exxon Chemical Patents Inc. | Electrical devices comprising polymeric insulating or semiconducting members |
US5346961A (en) | 1993-04-07 | 1994-09-13 | Union Carbide Chemicals & Plastics Technology Corporation | Process for crosslinking |
US5733480A (en) | 1996-09-24 | 1998-03-31 | Quantum Chemical Corporation | Semiconductive extrudable polyolefin compositions and articles |
AU739038B2 (en) | 1998-02-12 | 2001-10-04 | Cabot Corporation | Conductive polymer blends with finely divided conductive material selectively localized in continuous polymer phase or continuous interface |
US6277303B1 (en) | 1998-07-10 | 2001-08-21 | Pirelli Cable Corporation | Conductive polymer composite materials and methods of making same |
US6284832B1 (en) | 1998-10-23 | 2001-09-04 | Pirelli Cables And Systems, Llc | Crosslinked conducting polymer composite materials and method of making same |
US6277925B1 (en) | 1999-03-18 | 2001-08-21 | Hercules Incorporated | Allyl compounds, compositions containing allyl compounds and processes for forming and curing polymer compositions |
US6496629B2 (en) | 1999-05-28 | 2002-12-17 | Tycom (Us) Inc. | Undersea telecommunications cable |
JP4780491B2 (ja) * | 2001-07-27 | 2011-09-28 | 東海カーボン株式会社 | ブラックマトリックス用カーボンブラックとその製造方法 |
US6714707B2 (en) | 2002-01-24 | 2004-03-30 | Alcatel | Optical cable housing an optical unit surrounded by a plurality of gel layers |
US7767910B2 (en) | 2006-02-06 | 2010-08-03 | Dow Global Technologies Inc | Semiconductive compositions |
FR2950728B1 (fr) * | 2009-09-30 | 2012-08-17 | Nexans | Cable electrique a moyenne ou haute tension |
CN103897368B (zh) * | 2012-12-28 | 2016-04-20 | 金发科技股份有限公司 | 一种导电聚碳酸酯复合材料及其制品和制备方法 |
EP2886585A1 (en) * | 2013-12-20 | 2015-06-24 | Borealis AG | Semiconductive polymer composition for electric power cables |
WO2016200600A1 (en) | 2015-06-11 | 2016-12-15 | Dow Global Technologies Llc | Cable insulation comprising a blend of ldpe and polypropylene |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001040148A (ja) | 1999-06-30 | 2001-02-13 | Union Carbide Chem & Plast Technol Corp | ケーブル半導電性シールド |
JP2004510836A (ja) | 1999-12-02 | 2004-04-08 | キャボット コーポレイション | 電線およびケーブル用コンパウンドに有用なカーボンブラック |
JP2001310980A (ja) | 2000-04-28 | 2001-11-06 | Nippon Unicar Co Ltd | 架橋性エチレン系樹脂組成物及びこれを被覆してなる電線・ケーブル |
JP2007505975A (ja) | 2003-09-18 | 2007-03-15 | コロンビアン ケミカルズ カンパニー | 各種用途に用いられる熱改質カーボンブラック及びその製造方法 |
JP2020524362A (ja) | 2017-06-15 | 2020-08-13 | キャボット コーポレイションCabot Corporation | 異なるカーボンブラック粒子を含有する電極及び電池 |
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BR112020019372A2 (pt) | 2020-12-29 |
US11993693B2 (en) | 2024-05-28 |
CN111971334B (zh) | 2023-08-18 |
JP2021518461A (ja) | 2021-08-02 |
CN111971334A (zh) | 2020-11-20 |
KR20200135981A (ko) | 2020-12-04 |
MX2020009792A (es) | 2020-10-12 |
WO2019190899A1 (en) | 2019-10-03 |
US20210002452A1 (en) | 2021-01-07 |
EP3775010A1 (en) | 2021-02-17 |
CA3094807A1 (en) | 2019-10-03 |
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