JP7365467B2 - ant repellent products - Google Patents
ant repellent products Download PDFInfo
- Publication number
- JP7365467B2 JP7365467B2 JP2022122632A JP2022122632A JP7365467B2 JP 7365467 B2 JP7365467 B2 JP 7365467B2 JP 2022122632 A JP2022122632 A JP 2022122632A JP 2022122632 A JP2022122632 A JP 2022122632A JP 7365467 B2 JP7365467 B2 JP 7365467B2
- Authority
- JP
- Japan
- Prior art keywords
- ant repellent
- ant
- ants
- carbon number
- total carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005871 repellent Substances 0.000 title claims description 143
- 230000002940 repellent Effects 0.000 title claims description 143
- 241000257303 Hymenoptera Species 0.000 claims description 72
- -1 hydrocarbon aldehydes Chemical class 0.000 claims description 66
- 239000000203 mixture Substances 0.000 claims description 51
- 230000000694 effects Effects 0.000 claims description 29
- 229930195733 hydrocarbon Natural products 0.000 claims description 29
- 239000004215 Carbon black (E152) Substances 0.000 claims description 28
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 25
- 229910052799 carbon Inorganic materials 0.000 claims description 25
- 239000004615 ingredient Substances 0.000 claims description 21
- 229920002379 silicone rubber Polymers 0.000 claims description 10
- 239000004945 silicone rubber Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- ULDHMXUKGWMISQ-SECBINFHSA-N (-)-carvone Chemical compound CC(=C)[C@@H]1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-SECBINFHSA-N 0.000 claims description 8
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 7
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- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 claims description 6
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- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 6
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 claims description 6
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- CRIGTVCBMUKRSL-FNORWQNLSA-N 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enone Chemical compound C\C=C\C(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-FNORWQNLSA-N 0.000 claims description 3
- BGTBFNDXYDYBEY-UHFFFAOYSA-N 1-(2,6,6-trimethylcyclohexen-1-yl)but-2-en-1-one Chemical compound CC=CC(=O)C1=C(C)CCCC1(C)C BGTBFNDXYDYBEY-UHFFFAOYSA-N 0.000 claims description 3
- WAPNOHKVXSQRPX-UHFFFAOYSA-N 1-phenylethanol Chemical compound CC(O)C1=CC=CC=C1 WAPNOHKVXSQRPX-UHFFFAOYSA-N 0.000 claims description 3
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- PJXHBTZLHITWFX-UHFFFAOYSA-N 2-heptylcyclopentan-1-one Chemical compound CCCCCCCC1CCCC1=O PJXHBTZLHITWFX-UHFFFAOYSA-N 0.000 claims description 3
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 claims description 3
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- KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 claims description 3
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 claims description 3
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
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- Y02A90/40—Monitoring or fighting invasive species
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Description
本発明は、アリ忌避組成物、及びこれを用いたアリ忌避製品に関するものである。 The present invention relates to an ant repellent composition and an ant repellent product using the same.
近年、屋外から家屋内に侵入するアリ類の被害や苦情が増加し、アリ類は重要な不快害虫の一つにあげられている。また、最近、特定外来生物に指定されている「ヒアリ」や「カミアリ」が日本数箇所で発見され社会問題になっているが、この種のアリは強い毒を持ち、繁殖力が高いことから速やかな侵入防止対策が求められている。従来、これらアリ類の防除方法としては、殺虫成分を含有する液剤やエアゾールを散布したり、ベイト剤を喫食させて巣に持ち帰らせ巣ごと退治する、いわゆる駆除が主体であった。
しかしながら、アリ類は、家屋内に侵入したり、危害を与えたりしなければ必ずしも駆除の必要がないとの声も聞かれる。更に、特定外来生物であるアリを駆除するために殺虫剤を多用すれば在来アリも殺してしまうことの問題点も指摘されている。このため、アリ類を駆除するのではなく、家屋の入り口や周辺等に予めアリ忌避剤を施用してアリ類を近づけない方法も模索されているのが現状である。
In recent years, damage and complaints caused by ants that invade homes from outdoors have increased, and ants are considered to be one of the important unpleasant pests. In addition, "fire ants" and "fire ants," which are designated as specific alien species, have recently been discovered in several places in Japan and have become a social problem. Immediate measures to prevent intrusion are required. Conventionally, the main methods of controlling these ants have been so-called extermination, which involves spraying liquids or aerosols containing insecticidal ingredients, or making the ants eat bait and bring them back to their nests, thereby exterminating the entire nest.
However, some say that it is not necessary to exterminate ants unless they invade the house or cause harm. Furthermore, it has been pointed out that if pesticides are used extensively to exterminate ants, which are specified alien species, native ants will also be killed. For this reason, instead of exterminating ants, methods are currently being sought to keep ants away by applying an ant repellent to the entrances and surrounding areas of houses in advance.
例えば、特許第３８４８４１２号公報（特許文献１）には、天然精油であるオークモス、サンダルウッド油、スペアミント油、タイムホワイト油、バチョウリ油、ガーリック油、シナモンリーフ油、タイムレッド油、ペルーバルサムバルサムの１種又は２種以上を有効成分として含有するアリ類の忌避剤が記載されている。この忌避剤は、天然精油を使用するため安全性が高く屋内でも問題なく使用でき空間忌避効果も奏するとしているが、その忌避効果は十分とは言えない。
また、特許第５８４０４７７号公報（特許文献２）は、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、テトラヒドロゲラニオール、フェネチルイソアミルエーテル、ジヒドロインデニル－２，４－ジオキサン、マグノラン、及びルバフランから選ばれる１種又は２種以上をアリ忌避成分として含有するアリ防除剤を開示する。このアリ防除剤は、アリ忌避成分として比較的揮散性の低い香料成分を使用し、家屋の入り口や周辺等に施用するような場面では、１週間以上にわたりクロヤマアリ、アミメアリ等の在来アリ類を忌避させることができる反面、即効的な空間忌避効果を目的とするものではなかった。
このように、今般問題となっているヒアリやカミアリ等の特定外来生物に指定されているアリを含め、アリ類に対して十分実用的な空間忌避効果を奏するアリ忌避組成物、及びこれを用いたアリ忌避製品は未だ得られていないのが現状である。
For example, Japanese Patent No. 3848412 (Patent Document 1) describes natural essential oils such as oakmoss, sandalwood oil, spearmint oil, thyme white oil, bachouli oil, garlic oil, cinnamon leaf oil, thyme red oil, and Peruvian balsam. Ant repellents containing one or more types as active ingredients have been described. This repellent is said to be highly safe because it uses natural essential oils, can be used indoors without any problems, and has a space repellent effect, but its repellent effect is not sufficient.
Furthermore, Patent No. 5840477 (Patent Document 2) discloses tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, tetrahydrogeraniol, phenethyl isoamyl ether, dihydroindenyl- An ant repellent agent containing one or more selected from 2,4-dioxane, magnolan, and rubafuran as an ant repellent ingredient is disclosed. This ant control agent uses a relatively low-volatility fragrance ingredient as an ant repellent ingredient, and when applied to the entrance or surrounding area of a house, it will kill native ants such as black wood ants and red-eared ants for more than a week. On the other hand, it was not intended to have an immediate spatial repellent effect.
In this way, we have developed an ant repellent composition that has a sufficiently practical spatial repellent effect on ants, including ants designated as specific alien species such as fire ants and fire ants, which are currently a problem, and an ant repellent composition using the same. At present, an ant repellent product has not yet been obtained.
本発明は、アリ類、特にヒアリやカミアリ等の特定外来生物に指定されているアリに対する空間忌避効果が高いアリ忌避組成物、及びこれを用いたアリ忌避製品を提供することを目的とする。 An object of the present invention is to provide an ant repellent composition that has a high spatial repellency effect on ants, particularly ants designated as specific alien species such as fire ants and fire ants, and an ant repellent product using the same.
本発明は、以下の構成が上記目的を達成するために優れた効果を奏することを見出したものである。
（１）アリ忌避成分として、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを、（ａ）／（ｂ）＝０．１／１～１０／１の配合比率で含有するアリ忌避組成物。
（２）前記（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類は、デカナール、ウンデカナール、ドデカナール、２－メチルウンデカナール、トリデカナール、１０－ウンデセナール、シトラール、ネラール、フェニルアセトアルデヒド、シンナミックアルデヒド、α－アミルシンナミックアルデヒド、α－ヘキシルシンナミックアルデヒド、リリアール、ペリルアルデヒド、トリベルタール、クミンアルデヒド、ヘリオトロピン、トリデカノン、ｌ－カルボン、メントン、プレゴン、シス－ジャスモン、ジヒドロジャスモン、α－ダマスコン、β－ダマスコン、δ－ダマスコン、α－イオノン、β－イオノン、２－ペンチルシクロペンタノン、２－ヘキシルシクロペンタノン、２－ヘプチルシクロペンタノン、メチルベンジルケトン、メチルスチリルケトンであり、
前記（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類は、リナロール、デヒドロリナロール、ゲラニオール、ネロール、シトロネロール、メントール、テルピネオール、テルピネン－４－オール、イソプレゴール、ボルネオール、１－フェニルエチルアルコール、２－フェニルエチルアルコール、チモール、オイゲノールである（１）に記載のアリ忌避組成物。
（３）アリ忌避成分として、（ｃ）総炭素数が８～１６の炭化水素エステル類から選ばれる１種又は２種以上を更に含有する（１）又は（２）に記載のアリ忌避組成物。
（４）前記（ｃ）総炭素数が８～１６の炭化水素エステル類は、デシルアセテート、リナリルアセテート、ゲラニルアセテート、シトロネリルアセテート、メンチルアセテート、テルピニルアセテート、ネピルアセテート、ｐ－ｔ－ブチルシクロヘキシルアセテート、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、フェニルエチルアセテート、スチラリルアセテート、シンナミルアセテート、シンナミルプロピオネート、アリルヘキサノエート、アリルヘプタノエート、メチルベンゾエート、エチルベンゾエート、３－ヘキセニルベンゾエート、ベンジルベンゾエート、メチルシンナメート、エチルシンナメート、メチルサリシネート、エチルサリシネート、アミルサリシネート、メチルジャスモネート、メチルジヒドロジャスモネートである（３）に記載のアリ忌避組成物。
（５）更に、アリ忌避増強成分として、ディート、イカリジン、及びブチルアセチルアミノプロピオン酸エチル（以下、ＩＲ３５３５と略す）から選ばれる１種又は２種以上を含有する（１）ないし（４）のいずれか１に記載のアリ忌避組成物。
（６）実質的に殺虫成分を含有しない（１）ないし（５）のいずれか１に記載のアリ忌避組成物。
（７）前記アリは、ヒアリ又はカミアリである（１）ないし（６）のいずれか１に記載のアリ忌避組成物。
（８）（１）ないし（７）のいずれか１に記載のアリ忌避組成物を用い、液状製剤又は固形剤に調製してなるアリ忌避製品。
（９）前記固形剤は、前記アリ忌避組成物を含有させた担持体からアリ忌避成分を空間に揮散させてアリに対する忌避効果を奏し得るようになしたものである（８）に記載のアリ忌避製品。
（１０）前記担持体は、プラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体である（９）に記載のアリ忌避製品。
（１１）前記アリは、ヒアリ又はカミアリである（８）ないし（１０）のいずれか１に記載のアリ忌避製品。
The present invention is based on the discovery that the following configuration has excellent effects in achieving the above object.
(1) As an ant repellent component, (a) one or more types selected from hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16; and (b) a total carbon number of 8 to 16. Ant containing one or more selected from 12 monoterpene alcohols and/or aromatic alcohols at a blending ratio of (a)/(b) = 0.1/1 to 10/1. Repellent composition.
(2) Said (a) hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16 include decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, 10-undecenal, citral, Neral, phenylacetaldehyde, cinnamic aldehyde, α-amyl cinnamic aldehyde, α-hexyl cinnamic aldehyde, Lilial, peryl aldehyde, trivertal, cumin aldehyde, heliotropin, tridecanone, l-carvone, menthone, pulegone, cis-jasmone, Dihydrojasmone, α-damascone, β-damascone, δ-damascone, α-ionone, β-ionone, 2-pentylcyclopentanone, 2-hexylcyclopentanone, 2-heptylcyclopentanone, methylbenzylketone, methylstyryl is a ketone,
The monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12 (b) include linalool, dehydrolinalool, geraniol, nerol, citronellol, menthol, terpineol, terpinen-4-ol, isopulegol, and borneol. , 1-phenylethyl alcohol, 2-phenylethyl alcohol, thymol, and eugenol.
(3) The ant repellent composition according to (1) or (2), further containing as an ant repellent component, (c) one or more selected from hydrocarbon esters having a total carbon number of 8 to 16. .
(4) The above (c) hydrocarbon esters having a total carbon number of 8 to 16 include decyl acetate, linalyl acetate, geranyl acetate, citronellyl acetate, menthyl acetate, terpinyl acetate, nepylacetate, pt- Butyl cyclohexyl acetate, tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, phenylethyl acetate, styralyl acetate, cinnamyl acetate, cinnamyl propionate, allylhexano ate, allylheptanoate, methyl benzoate, ethyl benzoate, 3-hexenyl benzoate, benzyl benzoate, methyl cinnamate, ethyl cinnamate, methyl salicinate, ethyl salicinate, amyl salicinate, methyl jasmonate, methyl The ant repellent composition according to (3), which is dihydrojasmonate.
(5) Any of (1) to (4) further contains one or more selected from DEET, icaridin, and ethyl butylacetylaminopropionate (hereinafter abbreviated as IR3535) as an ant repellent enhancing ingredient. The ant repellent composition according to item 1.
(6) The ant repellent composition according to any one of (1) to (5), which does not substantially contain an insecticidal component.
(7) The ant repellent composition according to any one of (1) to (6), wherein the ants are fire ants or fire ants.
(8) An ant repellent product prepared by preparing a liquid preparation or a solid preparation using the ant repellent composition according to any one of (1) to (7).
(9) The ant repellent according to (8), wherein the solid agent is capable of exhibiting an ant repellent effect by volatilizing an ant repellent component into the space from a carrier containing the ant repellent composition. Repellent products.
(10) The ant repellent product according to (9), wherein the carrier is a plastic resin film, a molded body, or a silicone rubber molded body.
(11) The ant repellent product according to any one of (8) to (10), wherein the ants are fire ants or fire ants.
本発明のアリ忌避組成物は、特定のアリ忌避成分を含有し、アリ類、特にヒアリやカミアリ等の特定外来生物であるアリに対する空間忌避効果に優れるので極めて実用性が高い。従って、このアリ忌避組成物を用いた本発明のアリ忌避製品も非常に有用なものである。 The ant repellent composition of the present invention contains a specific ant repellent component and has an excellent spatial repellent effect against ants, particularly ants that are specific alien species such as fire ants and fire ants, and is therefore extremely practical. Therefore, the ant repellent product of the present invention using this ant repellent composition is also very useful.
本発明のアリ忌避組成物は、アリ忌避成分として、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを、（ａ）／（ｂ）＝０．１／１～１０／１の配合比率で含有することを特徴とする。 The ant repellent composition of the present invention contains (a) one or more hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16 as ant repellent components, and (b) One or more types selected from monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12, and (a)/(b) = 0.1/1 to 10/1. It is characterized in that it is contained in a blending ratio.
前記（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類の具体例としては、例えば、デカナール、ウンデカナール、ドデカナール、２－メチルウンデカナール、トリデカナール、１０－ウンデセナール、シトラール、ネラール、フェニルアセトアルデヒド、シンナミックアルデヒド、α－アミルシンナミックアルデヒド、α－ヘキシルシンナミックアルデヒド、リリアール、ペリルアルデヒド、トリベルタール、クミンアルデヒド、ヘリオトロピン、トリデカノン、ｌ－カルボン、メントン、プレゴン、シス－ジャスモン、ジヒドロジャスモン、α－ダマスコン、β－ダマスコン、δ－ダマスコン、α－イオノン、β－イオノン、２－ペンチルシクロペンタノン、２－ヘキシルシクロペンタノン、２－ヘプチルシクロペンタノン、メチルベンジルケトン、メチルスチリルケトンがあげられる。 Specific examples of the hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16 (a) include decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, and 10-undecenal. , citral, neral, phenylacetaldehyde, cinnamic aldehyde, α-amyl cinnamic aldehyde, α-hexyl cinnamic aldehyde, lilyal, peryl aldehyde, tribertal, cumin aldehyde, heliotropin, tridecanone, l-carvone, menthone, pulegone, cis - Jasmone, dihydrojasmone, α-damascone, β-damascone, δ-damascone, α-ionone, β-ionone, 2-pentylcyclopentanone, 2-hexylcyclopentanone, 2-heptylcyclopentanone, methylbenzyl ketone , methylstyryl ketone.
一方、前記（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類の具体例としては、例えば、リナロール、デヒドロリナロール、ゲラニオール、ネロール、シトロネロール、メントール、テルピネオール、テルピネン－４－オール、イソプレゴール、ボルネオール、１－フェニルエチルアルコール、２－フェニルエチルアルコール、チモール、オイゲノールがあげられる。 On the other hand, specific examples of the monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12 (b) include linalool, dehydrolinalool, geraniol, nerol, citronellol, menthol, terpineol, and terpinene. -4-ol, isopulegol, borneol, 1-phenylethyl alcohol, 2-phenylethyl alcohol, thymol, and eugenol.
本発明では、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを併用する必要がある。そして、本発明者らの検討結果によれば、（ａ）／（ｂ）の配合比率が０．１／１～１０／１の範囲において、アリ類、特にヒアリやカミアリ等の特定外来生物であるアリに対し相乗的に高い空間忌避効果を奏することが認められた。（ａ）／（ｂ）の配合比率がこの範囲を外れると相乗効果が得られず併用するメリットはない。 In the present invention, (a) one or more hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16; and (b) a monoterpene having a total carbon number of 8 to 12. It is necessary to use one or more selected from alcohols and/or aromatic alcohols in combination. According to the study results of the present inventors, when the blending ratio of (a)/(b) is in the range of 0.1/1 to 10/1, specific alien species such as ants, especially fire ants and fire ants, It was found to have a synergistic high spatial repellency effect against certain ants. If the blending ratio of (a)/(b) is outside this range, no synergistic effect will be obtained and there will be no merit in using them together.
本発明のアリ忌避組成物は、アリ忌避成分として、（ｃ）総炭素数が８～１６の炭化水素エステル類から選ばれる１種又は２種以上を更に含有するのが好ましい。このような炭化水素エステル類は、アリ忌避効果の増強に寄与し得るものであり、具体例としては、例えば、デシルアセテート、リナリルアセテート、ゲラニルアセテート、シトロネリルアセテート、メンチルアセテート、テルピニルアセテート、ネピルアセテート、ｐ－ｔ－ブチルシクロヘキシルアセテート、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、フェニルエチルアセテート、スチラリルアセテート、シンナミルアセテート、シンナミルプロピオネート、アリルヘキサノエート、アリルヘプタノエート、メチルベンゾエート、エチルベンゾエート、３－ヘキセニルベンゾエート、ベンジルベンゾエート、メチルシンナメート、エチルシンナメート、メチルサリシネート、エチルサリシネート、アミルサリシネート、メチルジャスモネート、メチルジヒドロジャスモネートがあげられるが、これらに限定されない。 The ant repellent composition of the present invention preferably further contains, as an ant repellent component, one or more selected from (c) hydrocarbon esters having a total carbon number of 8 to 16. Such hydrocarbon esters can contribute to enhancing the ant repellent effect, and specific examples include decyl acetate, linalyl acetate, geranyl acetate, citronellyl acetate, menthyl acetate, terpinyl acetate, Nepylacetate, pt-butylcyclohexyl acetate, tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, phenylethyl acetate, styralyl acetate, cinnamyl acetate, cinnamon Milpropionate, allylhexanoate, allylheptanoate, methylbenzoate, ethylbenzoate, 3-hexenylbenzoate, benzylbenzoate, methylcinnamate, ethylcinnamate, methyl salicinate, ethyl salicinate, amyl salicinate Examples include, but are not limited to, ester, methyl jasmonate, and methyl dihydrojasmonate.
本発明のアリ忌避組成物には、上記以外の香料成分、例えば、ｄ－リモネン、α－ピネン、β－ピネン等の炭化水素類、イソアミルフェニルエチルエーテル、リナロールオキサイド、１，８－シネオール、ローズオキサイド、ジフェニルエーテル、マグノラン、ルバフラン、ジヒドロインデニル－２，４－ジオキサン等の炭化水素エーテル類、２，６－ジメチル－３－エチルピラジン、シトロネリルニトリル、ステモン、ｏ－アミノアセトフェノン等の含窒素化合物類等を配合しても構わない。また、サンダルウッド油、スペアミント油、タイムホワイト油、バチョウリ油、ガーリック油、シナモンリーフ油、タイムレッド油、ジャスミン油、ネロリ油、ベルガモット油、オレンジ油、ゼラニウム油、プチグレン油、レモン油、レモングラス油、シナモン油、ユーカリ油等の精油類も適宜配合可能である。
なお、本発明においては、精油として配合されたとしても、前記アリ忌避成分が精油中に５質量％以上含まれる場合、個々のアリ忌避成分として配合されたものと定義する。
The ant repellent composition of the present invention may contain fragrance components other than those mentioned above, such as hydrocarbons such as d-limonene, α-pinene, and β-pinene, isoamyl phenylethyl ether, linalool oxide, 1,8-cineole, rose Hydrocarbon ethers such as oxide, diphenyl ether, magnolan, rubafuran, dihydroindenyl-2,4-dioxane, nitrogen-containing compounds such as 2,6-dimethyl-3-ethylpyrazine, citronellylnitrile, stemone, o-aminoacetophenone, etc. You may also combine the following. Also available are sandalwood oil, spearmint oil, white thyme oil, bachouli oil, garlic oil, cinnamon leaf oil, thyme red oil, jasmine oil, neroli oil, bergamot oil, orange oil, geranium oil, petitgrain oil, lemon oil, lemon grass. Essential oils such as oil, cinnamon oil, and eucalyptus oil can also be blended as appropriate.
In the present invention, even if the ant repellent component is blended as an essential oil, if the ant repellent component is contained in the essential oil in an amount of 5% by mass or more, it is defined as being blended as an individual ant repellent component.
本発明のアリ忌避組成物には、アリ忌避成分の揮散後の忌避効果持続成分として、２０℃における蒸気圧が０．２～２０Ｐａのグリコール類及び／又はグリコールエーテル類の１種又は２種以上を配合してもよい。このようなグリコール類及び／又はグリコールエーテル類は、溶剤としてのみならず、アリ忌避成分に対して特異的に忌避効果の持続作用を奏し得ることを初めて知見したものである。
その具体的代表例（２０℃における蒸気圧を併記）としては、プロピレングリコール（１０．７Ｐａ）、ジプロピレングリコール（１．３Ｐａ）、トリプロピレングリコール（０．６７Ｐａ）、ジエチレングリコール（３Ｐａ）、トリエチレングリコール（１Ｐａ）、１，３－ブチレングリコール、ヘキシレングリコール（６．７Ｐａ）、ベンジルグリコール（２．７Ｐａ）、ジエチレングリコールモノブチルエーテル（３Ｐａ）、ジプロピレングリコールモノブチルエーテル、及びトリプロピレングリコールモノメチルエーテルがあげられ、なかんずく、ジプロピレングリコールが本発明の目的に合致する。
なお、忌避効果持続成分の配合量としては、前記アリ忌避成分の０．２～１０倍程度が適当である。
The ant repellent composition of the present invention contains one or more glycols and/or glycol ethers having a vapor pressure of 0.2 to 20 Pa at 20°C as a component that maintains the repellent effect after volatilization of the ant repellent component. may be blended. This is the first time that it has been discovered that such glycols and/or glycol ethers can not only act as a solvent, but also have a specific and sustained repellent effect on ant repellent components.
Specific representative examples (vapor pressure at 20°C are also listed) include propylene glycol (10.7 Pa), dipropylene glycol (1.3 Pa), tripropylene glycol (0.67 Pa), diethylene glycol (3 Pa), triethylene Glycol (1 Pa), 1,3-butylene glycol, hexylene glycol (6.7 Pa), benzyl glycol (2.7 Pa), diethylene glycol monobutyl ether (3 Pa), dipropylene glycol monobutyl ether, and tripropylene glycol monomethyl ether are listed. Among them, dipropylene glycol meets the purpose of the present invention.
The appropriate amount of the component that maintains the repellent effect is about 0.2 to 10 times the amount of the ant repellent component.
本発明では、前記各種成分に、本発明の効果に支障を来たさない限りにおいて、例えば、蚊に対する忌避成分、殺虫成分、消臭成分、除菌・抗菌成分等の他の機能性成分を配合してアリ忌避組成物を構成してもよい。
かかる機能性成分のうち、蚊に対する忌避成分であるディート、イカリジン、ＩＲ３５３５は、アリ忌避成分と混用することによってそのアリ忌避効果を増強させ得ることが認められた。一方、殺虫成分としては、常温揮散性ピレスロイド系のエムペントリン、トランスフルトリン、メトフルトリン、プロフルトリン等が好適な代表例としてあげられるが、本発明の趣旨に照らし、配合するとしても極力微量に留めるのが好ましい。また、消臭成分としては、イネ科、ツバキ科、イチョウ科、モクセイ科、クワ科、ミカン科、キントラノオ科、カキノキ科の中から選ばれる植物抽出物が代表的である。更に、「緑の香り」と呼ばれる青葉アルコールや青葉アルデヒド等を添加してリラックス効果を付与することもできる。
なお、アリ忌避組成物を、例えば、マイクロカプセル化したり、サイクロデキストリン化して当該組成物の安定化を図ったり、アリ忌避成分の揮散性を調節することも可能である。
In the present invention, other functional ingredients such as mosquito repellent ingredients, insecticidal ingredients, deodorizing ingredients, and sterilizing/antibacterial ingredients are added to the above-mentioned various ingredients as long as they do not interfere with the effects of the present invention. They may be combined to form an ant repellent composition.
Among such functional ingredients, DEET, icaridin, and IR3535, which are mosquito repellent ingredients, have been found to be able to enhance their ant repellent effects when mixed with ant repellent ingredients. On the other hand, typical examples of insecticidal ingredients include pyrethroid empenthrin, transfluthrin, metofluthrin, profluthrin, etc., which are volatile at room temperature, but in light of the purpose of the present invention, it is best to keep them in as small a quantity as possible. preferable. In addition, typical deodorizing ingredients include plant extracts selected from Poaceae, Camellia, Ginkgo, Oleaceae, Moraceae, Rutaceae, Trifoliaceae, and Arcanaceae. Furthermore, a relaxing effect can be imparted by adding green leaf alcohol, green leaf aldehyde, etc., which are called "green scents".
In addition, it is also possible to stabilize the ant repellent composition by, for example, microcapsulating it or converting it into a cyclodextrin, or to adjust the volatility of the ant repellent component.
こうして得られた本発明のアリ忌避組成物は、そのまま若しくは希釈して使用することもできるが、通常、これを用いて種々剤型のアリ忌避製品を調製する。
その剤型としては、スプレーの形態で用いられる液剤、乳剤、水溶剤、マイクロエマルジョンやエアゾール等の液状製剤と、粉剤、粒剤、ベイト剤等の固形剤があげられる。そして、かかるアリ忌避製品を製するにあたっては、必要に応じ、溶剤、界面活性剤、可溶化剤、ゲル化剤、分散剤、安定化剤、ｐＨ調整剤、着色剤等を適宜配合してもよい。
The ant repellent composition of the present invention thus obtained can be used as it is or after being diluted, but it is usually used to prepare ant repellent products in various dosage forms.
The dosage forms include liquid preparations such as liquid preparations, emulsions, aqueous solutions, microemulsions, and aerosols used in the form of sprays, and solid preparations such as powders, granules, and baits. When producing such ant repellent products, solvents, surfactants, solubilizers, gelling agents, dispersants, stabilizers, pH adjusters, colorants, etc. may be added as appropriate. good.
アリ忌避製品の調製に用いる溶剤としては、例えば、水、エタノール、イソプロパノール等の低級アルコール、ケトン系溶剤、エステル系溶剤、ノルマルパラフィンやイソパラフィン等の炭化水素系溶剤等があげられる。
界面活性剤としては、例えば、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレン高級アルキルエーテル類（ポリオキシエチレンラウリルエーテル、ポリオキシエチレンオレイルエーテル等）、ポリオキシエチレンアルキルフェニルエーテル類、ポリオキシエチレン高級脂肪酸エステル類、ポリオキシエチレンソルビタン脂肪酸エステル類、ポリオキシエチレングリセリン脂肪酸エステル類、ポリオキシエチレンポリオキシプロピレンアルキルエーテル等の非イオン系界面活性剤や、ラウリルアミンオキサイド、ステアリルアミンオキサイド、ラウリル酸アミドプロピルジメチルアミンオキサイド等の高級アルキルアミンオキサイド系界面活性剤を例示することができる。
また、ゲル化剤としては、ポリビニルアルコール、アルギン酸、カラギーナン等が適宜用いられる。
Examples of the solvent used in preparing the ant repellent product include water, lower alcohols such as ethanol and isopropanol, ketone solvents, ester solvents, and hydrocarbon solvents such as normal paraffin and isoparaffin.
Examples of surfactants include polyoxyethylene hydrogenated castor oil, polyoxyethylene higher alkyl ethers (polyoxyethylene lauryl ether, polyoxyethylene oleyl ether, etc.), polyoxyethylene alkylphenyl ethers, and polyoxyethylene higher fatty acids. Nonionic surfactants such as esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene glycerin fatty acid esters, polyoxyethylene polyoxypropylene alkyl ether, lauryl amine oxide, stearyl amine oxide, amidopropyl dimethyl laurate Examples include higher alkylamine oxide surfactants such as amine oxide.
Further, as the gelling agent, polyvinyl alcohol, alginic acid, carrageenan, etc. are used as appropriate.
本発明のアリ忌避製品は、液状製剤よりも固形剤が好ましい。これは、使い易いこと、液漏れの心配がないことや薬液が手指に触れる危険性の少ないこと等のメリットが勘案されるためである。なかでも、アリ忌避組成物を担持体に含有させ、この担持体からアリ忌避成分を空間に揮散させる形態が好適に採用される。
ここで担持体としては、木粉、小麦粉等の各種植物質粉末、紙、織布、不織布等の基布、ビスコパール等の多孔質有機成形体、カオリン、タルク、炭酸カルシウム、珪石、珪砂、セラミックス等の無機担持体、ポリエチレン、ポリプロピレン、エチレン／酢酸ビニル共重合体（ＥＶＡ）、エチレン／メタクリル酸メチル共重合体（ＥＭＭＡ）、スチレン系ジブロックポリマー、スチレン系トリブロックポリマー、熱可塑性プラスチックエラストマー（ＴＰＥ、ＴＰＯ）等から構成されるプラスチック樹脂フィルム又は成形体、シリコーンゴム等があげられるが、これらに限定されない。
これらのうち、担持体としてプラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体を用いて調製した固形剤は、アリ類に対して効率的に優れた空間忌避効果を奏し、有用性が高いアリ忌避製品の一つである。
The ant repellent product of the present invention is preferably a solid formulation rather than a liquid formulation. This is because advantages such as ease of use, no fear of liquid leakage, and low risk of the chemical liquid coming into contact with fingers and fingers are taken into consideration. Among these, a mode in which the ant repellent composition is contained in a carrier and the ant repellent component is volatilized into the space from the carrier is preferably adopted.
Here, the carriers include various vegetable powders such as wood flour and wheat flour, paper, base fabrics such as woven fabrics and non-woven fabrics, porous organic molded bodies such as viscopal, kaolin, talc, calcium carbonate, silica stone, silica sand, Inorganic supports such as ceramics, polyethylene, polypropylene, ethylene/vinyl acetate copolymer (EVA), ethylene/methyl methacrylate copolymer (EMMA), styrenic diblock polymer, styrenic triblock polymer, thermoplastic elastomer Examples include, but are not limited to, plastic resin films or molded bodies made of (TPE, TPO), silicone rubber, and the like.
Among these, solid agents prepared using plastic resin films or molded bodies, or silicone rubber molded bodies as carriers have an efficient and excellent space repelling effect against ants, and are highly useful as ant repellents. It is one of the products.
本発明のアリ忌避製品に含有されるアリ忌避組成物の配合量は、当該忌避製品の使用用途、使用期間、及びその仕様等によって適宜決定すればよいが、液状製剤の場合、０．０１～２０ｗ／ｖ％、一方、固形剤の場合、０．０１～１０ｗ／ｗ％程度が適当である。
なお、担持体にアリ忌避組成物を含有させる固形剤においては、１回あたり８～１２時間使用の忌避製品の場合、アリ忌避組成物を担持体あたり１０～５０ｍｇ、一方、１５～３０日使用の忌避製品にあっては１００～２０００ｍｇ程度含有させればよい。
The amount of the ant repellent composition contained in the ant repellent product of the present invention may be appropriately determined depending on the purpose of use, period of use, and specifications of the repellent product, but in the case of a liquid preparation, 0.01~ 20 w/v%, while in the case of solid preparations, about 0.01 to 10 w/w% is appropriate.
In addition, in the case of a solid preparation containing the ant repellent composition in a carrier, in the case of a repellent product that is used for 8 to 12 hours per use, the ant repellent composition is 10 to 50 mg per carrier, whereas the ant repellent composition is used for 15 to 30 days. For repellent products, it is sufficient to contain about 100 to 2000 mg.
本発明のアリ忌避製品を製造するに際しては何ら特別の技術を必要としない。
アリ忌避組成物を担持体に含有させるに際しても、必要に応じて溶剤や界面活性剤等を添加し、従来公知の方法を適宜採用することができる。例えば、担持体が不織布の場合、アリ忌避組成物を薬液分注方式や塗布方式によって担持させてもよいし、あるいはパラフィンワックスと共に包埋させるようにしても構わない。
また、プラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体等にこれを担持させるにあたっては、本発明のアリ忌避組成物が揮散性のため高温下での混合工程は避け、薬液分注方式や塗布方式を採用したり、アリ忌避組成物を必要に応じ溶剤と共に噴霧又は滴下して成形体に浸透させる方式が適当である。あるいは、高濃度にアリ忌避組成物を含有させたシリコーンゴム成形体と無処理のシリコーンゴム成形体を密閉容器中に混在させ、適当時間放置してシリコーンゴム成形体全体に亘ってアリ忌避組成物濃度を平均化させる方法によっても本発明のアリ忌避製品を製造可能である。
No special technology is required to manufacture the ant repellent product of the present invention.
When the ant repellent composition is incorporated into the carrier, a solvent, a surfactant, etc. can be added as necessary, and conventionally known methods can be adopted as appropriate. For example, when the carrier is a nonwoven fabric, the ant repellent composition may be supported by a chemical liquid dispensing method or a coating method, or it may be embedded together with paraffin wax.
In addition, when supporting the ant repellent composition on a plastic resin film, a molded body, or a silicone rubber molded body, etc., since the ant repellent composition of the present invention is volatile, a mixing process at high temperatures should be avoided, and a chemical liquid dispensing method or coating method should be used. It is appropriate to adopt a method in which the ant repellent composition is sprayed or dripped together with a solvent as necessary and permeated into the molded body. Alternatively, a silicone rubber molded product containing a high concentration of the ant repellent composition and an untreated silicone rubber molded product are mixed in a sealed container, and left for an appropriate period of time to spread the ant repellent composition over the entire silicone rubber molded product. The ant repellent product of the present invention can also be produced by a method of averaging the concentration.
こうして得られた本発明のアリ忌避製品は、その剤型に応じて様々な使用場面に適用される。アリ忌避製品が液剤、エアゾール剤、粉剤、粒剤のような製剤の場合、玄関、台所、トイレ、リビングルーム、寝室などの室内、倉庫、車中等や、ベランダ、ポーチ、庭先、家屋の周囲などに、所定量を散布したり載置したりして、アリ類が近づかない空間を形成することが可能である。その施用量としては、例えば、玄関まわりで液状製剤を使用する場合、１０～５０ｍＬ／ｍ２、固形剤にあっては、１０～５０ｇ／ｍ２程度が適当である。
一方、上記担持体がプラスチック樹脂成形体やシリコーンゴム成形体の場合、足バンドとして足首や靴等に巻装したり、当該成形体をクリップのような固定具で靴等に装着して使用すれば効果的であるし、また、担持体がシールのような場合、フィルム状担持体の下面に粘着層を設けズボンの下部や靴等に貼付して用いるのが便利である。
The thus obtained ant repellent product of the present invention can be used in various situations depending on its dosage form. If the ant repellent product is a liquid, aerosol, powder, or granule formulation, it can be used indoors such as entrances, kitchens, toilets, living rooms, bedrooms, warehouses, cars, balconies, porches, gardens, and around houses. By spraying or placing a predetermined amount on a container, it is possible to create a space where ants cannot approach. The appropriate application amount is, for example, 10 to 50 mL/m 2 when a liquid preparation is used around the entrance, and about 10 to 50 g/m 2 for a solid preparation.
On the other hand, if the carrier is a plastic resin molded product or a silicone rubber molded product, it can be used by wrapping it around an ankle or shoes as a foot band, or by attaching the molded product to shoes with a fixing device such as a clip. In addition, when the carrier is a sticker, it is convenient to provide an adhesive layer on the lower surface of the film-like carrier and attach it to the bottom of pants, shoes, etc.
本発明のアリ忌避製品は、アリ類、具体的には、クロヤマアリ、アミメアリ、トビイロケアリ、トビイロシワアリ、ルリアリ、クロオオアリ、イエヒメアリ、アルゼンチンアリ等に対して実用的な空間忌避効果を示し、特にヒアリやカミアリ等の特定外来生物であるアリに対して効果的である。本発明者らの検討結果によれば、当該アリ忌避製品は、これらのアリによる刺咬被害を防止できるだけでなく、ハチ類、ヤマビル等にも忌避効果を示すことが認められた。しかも、実質的に殺虫成分を含有していない本製品は、殺虫剤の使用を嫌がる人にも手軽に使用できるのでその実用性は極めて高い。 The ant repellent product of the present invention exhibits a practical spatial repellent effect against ants, specifically, black wood ants, red-eared ants, brown ants, brown ants, blue ants, black carpenter ants, house ants, Argentine ants, etc., and particularly against fire ants, fire ants, etc. It is effective against ants, which are a specific invasive species. According to the study results of the present inventors, it was found that the ant repellent product not only prevents bite damage caused by these ants, but also exhibits a repellent effect on bees, cylindrical bees, and the like. Moreover, this product, which does not substantially contain any insecticidal ingredients, can be easily used even by people who dislike the use of insecticides, making it highly practical.
次に具体的な実施例に基づき、本発明のアリ忌避組成物、及びこれを用いたアリ忌避製品について更に詳細に説明するが、本発明はこれらに限定されるものではない。 Next, the ant repellent composition of the present invention and an ant repellent product using the same will be described in more detail based on specific examples, but the present invention is not limited thereto.
表１に示す供試アリ忌避組成物をアセトン１０ｍＬに溶解して供試薬液を調製し、下記の忌避効力試験を実施した。
［忌避効力試験－１］
供試薬液０．５ｍＬを直径９ｃｍの濾紙に滴下し、風乾後この濾紙を半分に切断した。この半面と無処理濾紙の半面を重ならないように直径９ｃｍのガラスシャーレに置いた。ガラスシャーレの内壁にタルクを塗り、トビイロシワアリ５０匹又はヒアリ５０匹を放し、５分後、ならびに２時間後に処理面及び無処理面にいる虫数を数え、下式に従って忌避率を求めた。結果を表２に示す。
忌避率＝［（無処理面の侵入虫数－処理面の侵入虫数）／供試虫数×１００］
A test chemical solution was prepared by dissolving the test ant repellent composition shown in Table 1 in 10 mL of acetone, and the following repellent efficacy test was conducted.
[Repellent efficacy test-1]
0.5 mL of the test drug solution was dropped onto a 9 cm diameter filter paper, and after air drying, the filter paper was cut in half. This half surface and the half surface of the untreated filter paper were placed in a glass Petri dish with a diameter of 9 cm so that they did not overlap. Talc was applied to the inner wall of a glass petri dish, 50 brown ants or 50 fire ants were released, and the number of insects on the treated and untreated surfaces was counted after 5 minutes and 2 hours, and the repellency rate was determined according to the formula below. The results are shown in Table 2.
Repellent rate = [(Number of invading insects on untreated surface - Number of invading insects on treated surface)/Number of tested insects x 100]
試験の結果、アリ忌避成分として、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種とを、（ａ）／（ｂ）＝０．１／１～１０／１の配合比率で含有する本発明のアリ忌避組成物は、トビイロシワアリのような在来アリはもちろん、特定外来生物であるヒアリに対しても同等以上のアリ忌避効果を示すことが確認された。なお、本発明５、本発明６、本発明１２及び本発明１３のように、（ａ）及び（ｂ）のアリ忌避成分に、更に（ｃ）総炭素数が８～１６の炭化水素エステル類や人体用の蚊忌避剤であるＩＲ３５３５やイカリジンを配合することによってアリ忌避効果が増強した。また、本発明７及び本発明１４が示す如く、ジプロピレングリコールやヘキシレングリコールの配合は、アリ忌避成分の忌避効果を持続させるうえで効果的であることが認められた。
これに対し、本発明が規定するアリ忌避組成物以外を用いた比較例では、アリ忌避効果が十分と言えないばかりか、ヒアリに対するアリ忌避効果はトビイロシワアリを対象とする場合よりも劣る傾向が認められた。
As a result of the test, the ant repellent ingredients were (a) one selected from hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) monomers having a total carbon number of 8 to 12. The ant repellent composition of the present invention contains one selected from terpene alcohols and/or aromatic alcohols in a blending ratio of (a)/(b) = 0.1/1 to 10/1. It has been confirmed that it has an equal or higher ant repellent effect not only on native ants such as the brown ants, but also on the fire ant, which is a specific invasive species. In addition, as in Invention 5, Invention 6, Invention 12, and Invention 13, in addition to the ant repellent components (a) and (b), (c) hydrocarbon esters having a total carbon number of 8 to 16. The ant repellent effect was enhanced by adding IR3535, a mosquito repellent for human use, and icaridin. Furthermore, as shown in Present Inventions 7 and 14, it was found that the combination of dipropylene glycol and hexylene glycol is effective in sustaining the repellent effect of the ant repellent component.
On the other hand, in comparative examples using compositions other than the ant repellent composition specified by the present invention, not only the ant repellent effect was not sufficient, but also the ant repellent effect against fire ants tended to be inferior to that when targeting brown ants. It was done.
表３に示す供試アリ忌避組成物にｎ－パラフィン（ネオチオゾール）を加えエアゾール原液を調製した（アリ忌避組成物含量：エアゾール原液に対し２．０ｗ／ｖ％）。このエアゾール原液５０ｍＬをエアゾール容器に充填後、液化石油ガス（ＬＰＧ）５０ｍＬを加圧充填してエアゾール形態の本発明のアリ忌避製品を得た。このアリ忌避製品につき、下記の忌避効力試験を実施した。
［忌避効力試験－２］
２０ｃｍ角のタイルに供試アリ忌避製品を１ｍ２あたり２０ｍＬになるように滴下した。このタイルの中央に誘引剤として３％ショ糖水溶液を含浸させた脱脂綿を置き、在来アリ又は特定外来生物であるアリが生息する草むらに設置した。設置直後、及び設置３日後に、誘引剤に集まったアリを数え、アリ忌避効果を調べた。結果を表４に示す。
評価基準（集まったアリ数）；
０匹；◎、 １～５匹；○～◎、 ６～１０匹；〇、 １１～２０匹；△、
２１～３０匹；×～△、 ３１匹以上；×
N-paraffin (neothiosol) was added to the test ant repellent composition shown in Table 3 to prepare an aerosol stock solution (ant repellent composition content: 2.0 w/v% with respect to the aerosol stock solution). After filling 50 mL of this aerosol stock solution into an aerosol container, 50 mL of liquefied petroleum gas (LPG) was filled under pressure to obtain an ant repellent product of the present invention in aerosol form. The following repellent efficacy test was conducted on this ant repellent product.
[Repellent efficacy test-2]
The test ant repellent product was dropped onto a 20 cm square tile at a concentration of 20 mL per square meter . Absorbent cotton impregnated with a 3% sucrose aqueous solution as an attractant was placed in the center of this tile, and placed in a grassy area inhabited by native ants or ants that are specific alien species. Immediately after installation and 3 days after installation, the ants that had gathered on the attractant were counted and the ant repellent effect was examined. The results are shown in Table 4.
Evaluation criteria (number of ants gathered);
0 animals; ◎, 1 to 5 animals; ○ to ◎, 6 to 10 animals; ○, 11 to 20 animals; △,
21 to 30 animals; × to △, 31 or more animals; ×
試験の結果、本発明のアリ忌避組成物を用いて調製したエアゾール形態のアリ忌避製品は、実施例１と同様、在来アリ及び特定外来生物であるアリのいずれに対しても優れたアリ忌避効果を示した。なお、ＩＲ３５３５の配合は忌避効果増強の点で有用であり、また、ジプロピレングリコールの配合は忌避効果の持続性向上に寄与することが認められた。
別途、本発明２１につき、勝手口や玄関のスペースに１ｍ２あたり約２０ｍＬ噴霧処理したところ、７日間にわたりアリ類の家屋内への侵入は見られなかった。また、処理した所から少し離れた場所に死亡したクロヤマアリやアミメアリが何個体か観察され、アリ忌避成分の忌避効果に加え、殺虫成分であるエムペントリンの作用が覗えた。
As a result of the test, the aerosol form of the ant repellent product prepared using the ant repellent composition of the present invention was found to be excellent in repelling both native ants and ants, which are specific alien species, as in Example 1. It was shown to be effective. It has been found that the combination of IR3535 is useful in enhancing the repellent effect, and the combination of dipropylene glycol contributes to improving the sustainability of the repellent effect.
Separately, when Invention 21 was sprayed at about 20 mL per 1 m 2 in the back door and entrance space, no ants were observed to invade the house for 7 days. In addition, several dead black wood ants and red-eared ants were observed at a distance from the treated area, indicating the effect of the insecticidal ingredient empenthrin in addition to the repellent effect of the ant repellent ingredient.
アリ忌避成分の（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類として、α－ヘキシルシンナミックアルデヒドを８．５質量％とｌ－カルボンを４．９質量％、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類として、リナロールを９．０質量％、テルピネオールを３．５質量％とチモールを６．３質量％、更に（ｃ）総炭素数が８～１６の炭化水素エステル類として、ベンジルベンゾエートを１１．７質量％、ベンジルアセテートを８．４質量％とスチラリルアセテートを５．１質量％、ならびにその他の成分を配合して本発明のアリ忌避組成物を調製した。なお、このアリ忌避組成物における（ａ）／（ｂ）比率は０．７１／１であった。
このアリ忌避組成物の３０ｍｇを、担持体としてのリング状シリコーンゴム（１．６ｇ）に含有させ、リストバンド形態の本発明のアリ忌避製品を得た。
このリストバンドを２本ずつ両足首に巻装して外出したところ、８～１２時間にわたり、アリ類だけでなく、ワラジムシ、ダンゴムシ等の各種匍匐害虫や、蚊、ブユ、ハチ類、ユスリカ等の各種飛翔害虫、更にはヤマヒル等に煩わされることがなく、実用的な忌避効果が確認された。
As (a) hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16 in the ant repellent component, 8.5% by mass of α-hexyl cinnamic aldehyde and 4.9% by mass of l-carvone. (b) As monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12, 9.0% by mass of linalool, 3.5% by mass of terpineol, and 6.3% by mass of thymol, Furthermore, (c) as hydrocarbon esters having a total carbon number of 8 to 16, 11.7% by mass of benzyl benzoate, 8.4% by mass of benzyl acetate, 5.1% by mass of styralyl acetate, and other components. The ant repellent composition of the present invention was prepared by blending the following. Note that the (a)/(b) ratio in this ant repellent composition was 0.71/1.
30 mg of this ant repellent composition was contained in a ring-shaped silicone rubber (1.6 g) as a carrier to obtain an ant repellent product of the present invention in the form of a wristband.
When I went out with two of these wristbands tied around each ankle, I found that over a period of 8 to 12 hours, I was attacked by not only ants but also various creeping pests such as woodlice and pill bugs, mosquitoes, black flies, wasps, midges, etc. It was confirmed to have a practical repellent effect without being bothered by various flying pests or even mountain leeches.
本発明のアリ忌避組成物、及びこれを用いたアリ忌避製品は、アリ用だけでなく広範な害虫駆除を目的として利用することが可能である。 The ant repellent composition of the present invention and ant repellent products using the same can be used not only for ants but also for a wide range of pest control purposes.
Claims (3)
前記固形剤は、前記アリ忌避組成物を含有させた担持体からアリ忌避成分を空間に揮散させてアリに対する忌避効果を奏し得るようになしたものであり、
前記担持体は、プラスチック樹脂フィルム又は成形体、あるいはシリコーンゴム成形体であり、
前記アリ忌避組成物は、
アリ忌避成分として、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを、（ａ）／（ｂ）＝０．１／１～１０／１の配合比率で含有し、
前記（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類は、デカナール、ウンデカナール、ドデカナール、２－メチルウンデカナール、トリデカナール、１０－ウンデセナール、シトラール、シンナミックアルデヒド、α－アミルシンナミックアルデヒド、α－ヘキシルシンナミックアルデヒド、リリアール、ペリルアルデヒド、トリベルタール、クミンアルデヒド、ヘリオトロピン、ｌ－カルボン、メントン、プレゴン、α－ダマスコン、β－ダマスコン、δ－ダマスコン、２－ヘプチルシクロペンタノン、メチルベンジルケトン、又はメチルスチリルケトンであり、
前記（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類は、デヒドロリナロール、メントール、ボルネオール、１－フェニルエチルアルコール、又は２－フェニルエチルアルコールであり、
更に、アリ忌避成分として、（ｃ）総炭素数が８～１６の炭化水素エステル類から選ばれる１種又は２種以上を含有し、
前記（ｃ）総炭素数が８～１６の炭化水素エステル類は、メンチルアセテート、テルピニルアセテート、ネピルアセテート、フェニルエチルアセテート、スチラリルアセテート、シンナミルアセテート、シンナミルプロピオネート、アリルヘキサノエート、アリルヘプタノエート、メチルベンゾエート、エチルベンゾエート、３－ヘキセニルベンゾエート、ベンジルベンゾエート、メチルシンナメート、エチルシンナメート、メチルサリシネート、エチルサリシネート、アミルサリシネート、メチルジャスモネート、又はメチルジヒドロジャスモネートであるアリ忌避製品。 An ant repellent product prepared in a solid form using an ant repellent composition,
The solid agent is capable of exhibiting an ant repellent effect by volatilizing the ant repellent component into the space from the carrier containing the ant repellent composition,
The carrier is a plastic resin film, a molded body, or a silicone rubber molded body,
The ant repellent composition includes:
As the ant repellent component, (a) one or more selected from hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) monomers having a total carbon number of 8 to 12. Contains one or more selected from terpene alcohols and/or aromatic alcohols at a blending ratio of (a)/(b) = 0.1/1 to 10/1,
Said (a) hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16 include decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, 10-undecenal, citral, and cinnamic aldehyde. , α-amyl cinnamic aldehyde, α-hexyl cinnamic aldehyde, Lilial, peryl aldehyde, tribertal, cumin aldehyde, heliotropin, l-carvone, menthone, pulegone, α-damascone, β-damascone, δ-damascone, 2- heptylcyclopentanone, methylbenzyl ketone, or methylstyryl ketone,
Said (b) monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12 are dehydrolinalool, menthol, borneol, 1-phenylethyl alcohol, or 2-phenylethyl alcohol,
Furthermore, as an ant repellent component, it contains one or more selected from (c) hydrocarbon esters having a total carbon number of 8 to 16;
The hydrocarbon esters having a total carbon number of 8 to 16 (c) include menthyl acetate, terpinyl acetate, nepylacetate, phenylethyl acetate, styralyl acetate, cinnamyl acetate, cinnamyl propionate, and allylhexane. Noate, allylheptanoate, methyl benzoate, ethyl benzoate, 3-hexenyl benzoate, benzyl benzoate, methyl cinnamate, ethyl cinnamate, methyl salicinate, ethyl salicinate, amyl salicinate, methyl jasmonate, or an ant repellent product that is methyl dihydrojasmonate.
実質的に殺虫成分を含有しない請求項１に記載のアリ忌避製品。 The ant repellent composition includes:
An ant repellent product according to claim 1, which is substantially free of insecticidal ingredients.
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| JP2019034906A (en) | 2019-03-07 |
| JP2022136321A (en) | 2022-09-15 |
| JP6887342B2 (en) | 2021-06-16 |
| JP7117418B2 (en) | 2022-08-12 |
| JP2021121607A (en) | 2021-08-26 |
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