JP2022136321A - Ant repellent product - Google Patents
Ant repellent product Download PDFInfo
- Publication number
- JP2022136321A JP2022136321A JP2022122632A JP2022122632A JP2022136321A JP 2022136321 A JP2022136321 A JP 2022136321A JP 2022122632 A JP2022122632 A JP 2022122632A JP 2022122632 A JP2022122632 A JP 2022122632A JP 2022136321 A JP2022136321 A JP 2022136321A
- Authority
- JP
- Japan
- Prior art keywords
- ant
- repellent
- ants
- acetate
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005871 repellent Substances 0.000 title claims abstract description 137
- 230000002940 repellent Effects 0.000 title claims abstract description 68
- -1 hydrocarbon aldehydes Chemical class 0.000 claims abstract description 73
- 241000257303 Hymenoptera Species 0.000 claims abstract description 64
- 239000000203 mixture Substances 0.000 claims abstract description 59
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 31
- 230000001846 repelling effect Effects 0.000 claims abstract description 14
- 229930003658 monoterpene Natural products 0.000 claims abstract description 8
- 235000002577 monoterpenes Nutrition 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
- 229910052799 carbon Inorganic materials 0.000 claims description 24
- 230000000694 effects Effects 0.000 claims description 18
- 239000004615 ingredient Substances 0.000 claims description 11
- 229920002379 silicone rubber Polymers 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 239000004945 silicone rubber Substances 0.000 claims description 9
- ULDHMXUKGWMISQ-SECBINFHSA-N (-)-carvone Chemical compound CC(=C)[C@@H]1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-SECBINFHSA-N 0.000 claims description 8
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 7
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 7
- 230000000749 insecticidal effect Effects 0.000 claims description 7
- XHXUANMFYXWVNG-ADEWGFFLSA-N (-)-Menthyl acetate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O XHXUANMFYXWVNG-ADEWGFFLSA-N 0.000 claims description 6
- IGODOXYLBBXFDW-UHFFFAOYSA-N alpha-Terpinyl acetate Chemical compound CC(=O)OC(C)(C)C1CCC(C)=CC1 IGODOXYLBBXFDW-UHFFFAOYSA-N 0.000 claims description 6
- WTWBUQJHJGUZCY-UHFFFAOYSA-N cuminaldehyde Chemical compound CC(C)C1=CC=C(C=O)C=C1 WTWBUQJHJGUZCY-UHFFFAOYSA-N 0.000 claims description 6
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 claims description 6
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims description 6
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 6
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- RUMOYJJNUMEFDD-UHFFFAOYSA-N perillyl aldehyde Chemical compound CC(=C)C1CCC(C=O)=CC1 RUMOYJJNUMEFDD-UHFFFAOYSA-N 0.000 claims description 6
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 claims description 6
- QCCDLTOVEPVEJK-UHFFFAOYSA-N phenylacetone Chemical compound CC(=O)CC1=CC=CC=C1 QCCDLTOVEPVEJK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000088 plastic resin Substances 0.000 claims description 6
- BGEHHAVMRVXCGR-UHFFFAOYSA-N tridecanal Chemical compound CCCCCCCCCCCCC=O BGEHHAVMRVXCGR-UHFFFAOYSA-N 0.000 claims description 6
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 claims description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 5
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 claims description 4
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 claims description 4
- 229960002903 benzyl benzoate Drugs 0.000 claims description 4
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Natural products CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 claims description 4
- KVWWIYGFBYDJQC-UHFFFAOYSA-N methyl dihydrojasmonate Chemical group CCCCCC1C(CC(=O)OC)CCC1=O KVWWIYGFBYDJQC-UHFFFAOYSA-N 0.000 claims description 4
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims description 3
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 claims description 3
- NZGWDASTMWDZIW-MRVPVSSYSA-N (+)-pulegone Chemical compound C[C@@H]1CCC(=C(C)C)C(=O)C1 NZGWDASTMWDZIW-MRVPVSSYSA-N 0.000 claims description 3
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 claims description 3
- GEWDNTWNSAZUDX-WQMVXFAESA-N (-)-methyl jasmonate Chemical compound CC\C=C/C[C@@H]1[C@@H](CC(=O)OC)CCC1=O GEWDNTWNSAZUDX-WQMVXFAESA-N 0.000 claims description 3
- SDOFMBGMRVAJNF-KVTDHHQDSA-N (2r,3r,4r,5r)-6-aminohexane-1,2,3,4,5-pentol Chemical compound NC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SDOFMBGMRVAJNF-KVTDHHQDSA-N 0.000 claims description 3
- 239000001605 (5-methyl-2-propan-2-ylcyclohexyl) acetate Substances 0.000 claims description 3
- 239000001371 (5E)-3,5-dimethylocta-1,5,7-trien-3-ol Substances 0.000 claims description 3
- 239000001674 (E)-1-(2,6,6-trimethyl-1-cyclohexenyl)but-2-en-1-one Substances 0.000 claims description 3
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 claims description 3
- XEJGJTYRUWUFFD-FNORWQNLSA-N (e)-1-(2,6,6-trimethyl-1-cyclohex-3-enyl)but-2-en-1-one Chemical compound C\C=C\C(=O)C1C(C)C=CCC1(C)C XEJGJTYRUWUFFD-FNORWQNLSA-N 0.000 claims description 3
- CRIGTVCBMUKRSL-FNORWQNLSA-N 1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enone Chemical compound C\C=C\C(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-FNORWQNLSA-N 0.000 claims description 3
- BGTBFNDXYDYBEY-UHFFFAOYSA-N 1-(2,6,6-trimethylcyclohexen-1-yl)but-2-en-1-one Chemical compound CC=CC(=O)C1=C(C)CCCC1(C)C BGTBFNDXYDYBEY-UHFFFAOYSA-N 0.000 claims description 3
- WAPNOHKVXSQRPX-UHFFFAOYSA-N 1-phenylethanol Chemical compound CC(O)C1=CC=CC=C1 WAPNOHKVXSQRPX-UHFFFAOYSA-N 0.000 claims description 3
- OFHHDSQXFXLTKC-UHFFFAOYSA-N 10-undecenal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 claims description 3
- SJWKGDGUQTWDRV-UHFFFAOYSA-N 2-Propenyl heptanoate Chemical compound CCCCCCC(=O)OCC=C SJWKGDGUQTWDRV-UHFFFAOYSA-N 0.000 claims description 3
- RCSBILYQLVXLJG-UHFFFAOYSA-N 2-Propenyl hexanoate Chemical compound CCCCCC(=O)OCC=C RCSBILYQLVXLJG-UHFFFAOYSA-N 0.000 claims description 3
- PJXHBTZLHITWFX-UHFFFAOYSA-N 2-heptylcyclopentan-1-one Chemical compound CCCCCCCC1CCCC1=O PJXHBTZLHITWFX-UHFFFAOYSA-N 0.000 claims description 3
- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 claims description 3
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 3
- XHXUANMFYXWVNG-UHFFFAOYSA-N D-menthyl acetate Natural products CC(C)C1CCC(C)CC1OC(C)=O XHXUANMFYXWVNG-UHFFFAOYSA-N 0.000 claims description 3
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 3
- KBEBGUQPQBELIU-CMDGGOBGSA-N Ethyl cinnamate Chemical compound CCOC(=O)\C=C\C1=CC=CC=C1 KBEBGUQPQBELIU-CMDGGOBGSA-N 0.000 claims description 3
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 claims description 3
- NZGWDASTMWDZIW-UHFFFAOYSA-N Pulegone Natural products CC1CCC(=C(C)C)C(=O)C1 NZGWDASTMWDZIW-UHFFFAOYSA-N 0.000 claims description 3
- AXMVYSVVTMKQSL-UHFFFAOYSA-N UNPD142122 Natural products OC1=CC=C(C=CC=O)C=C1O AXMVYSVVTMKQSL-UHFFFAOYSA-N 0.000 claims description 3
- BCOXBEHFBZOJJZ-ONEGZZNKSA-N [(e)-hex-3-enyl] benzoate Chemical compound CC\C=C\CCOC(=O)C1=CC=CC=C1 BCOXBEHFBZOJJZ-ONEGZZNKSA-N 0.000 claims description 3
- HMKKIXGYKWDQSV-KAMYIIQDSA-N alpha-Amylcinnamaldehyde Chemical compound CCCCC\C(C=O)=C\C1=CC=CC=C1 HMKKIXGYKWDQSV-KAMYIIQDSA-N 0.000 claims description 3
- CRIGTVCBMUKRSL-UHFFFAOYSA-N alpha-Damascone Natural products CC=CC(=O)C1C(C)=CCCC1(C)C CRIGTVCBMUKRSL-UHFFFAOYSA-N 0.000 claims description 3
- QUMXDOLUJCHOAY-UHFFFAOYSA-N alpha-methylbenzyl acetate Natural products CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 claims description 3
- USMNOWBWPHYOEA-UHFFFAOYSA-N alpha-thujone Natural products CC1C(=O)CC2(C(C)C)C1C2 USMNOWBWPHYOEA-UHFFFAOYSA-N 0.000 claims description 3
- POIARNZEYGURDG-UHFFFAOYSA-N beta-damascenone Natural products CC=CC(=O)C1=C(C)C=CCC1(C)C POIARNZEYGURDG-UHFFFAOYSA-N 0.000 claims description 3
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 claims description 3
- 229940116229 borneol Drugs 0.000 claims description 3
- KBEBGUQPQBELIU-UHFFFAOYSA-N cinnamic acid ethyl ester Natural products CCOC(=O)C=CC1=CC=CC=C1 KBEBGUQPQBELIU-UHFFFAOYSA-N 0.000 claims description 3
- CCRCUPLGCSFEDV-UHFFFAOYSA-N cinnamic acid methyl ester Natural products COC(=O)C=CC1=CC=CC=C1 CCRCUPLGCSFEDV-UHFFFAOYSA-N 0.000 claims description 3
- 229940117916 cinnamic aldehyde Drugs 0.000 claims description 3
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 claims description 3
- WJSDHUCWMSHDCR-VMPITWQZSA-N cinnamyl acetate Natural products CC(=O)OC\C=C\C1=CC=CC=C1 WJSDHUCWMSHDCR-VMPITWQZSA-N 0.000 claims description 3
- 229940043350 citral Drugs 0.000 claims description 3
- ZJIQIJIQBTVTDY-SREVYHEPSA-N dehydrolinalool Chemical compound CC(=C)\C=C/CC(C)(O)C=C ZJIQIJIQBTVTDY-SREVYHEPSA-N 0.000 claims description 3
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 claims description 3
- 229940041616 menthol Drugs 0.000 claims description 3
- 229930007503 menthone Natural products 0.000 claims description 3
- GEWDNTWNSAZUDX-UHFFFAOYSA-N methyl 7-epi-jasmonate Natural products CCC=CCC1C(CC(=O)OC)CCC1=O GEWDNTWNSAZUDX-UHFFFAOYSA-N 0.000 claims description 3
- 229940095102 methyl benzoate Drugs 0.000 claims description 3
- CCRCUPLGCSFEDV-BQYQJAHWSA-N methyl trans-cinnamate Chemical compound COC(=O)\C=C\C1=CC=CC=C1 CCRCUPLGCSFEDV-BQYQJAHWSA-N 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
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- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
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- HTLBMZKXJYNJSK-UHFFFAOYSA-N 3-naphthalen-2-yl-1,2-oxazol-5-amine Chemical compound O1C(N)=CC(C=2C=C3C=CC=CC3=CC=2)=N1 HTLBMZKXJYNJSK-UHFFFAOYSA-N 0.000 claims description 2
- KGDJMNKPBUNHGY-RMKNXTFCSA-N [(e)-3-phenylprop-2-enyl] propanoate Chemical compound CCC(=O)OC\C=C\C1=CC=CC=C1 KGDJMNKPBUNHGY-RMKNXTFCSA-N 0.000 claims description 2
- 235000007586 terpenes Nutrition 0.000 claims description 2
- BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical compound CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 claims description 2
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
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- Y02A90/40—Monitoring or fighting invasive species
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Abstract
Description
本発明は、アリ忌避組成物、及びこれを用いたアリ忌避製品に関するものである。 The present invention relates to an ant-repellent composition and an ant-repellent product using the same.
近年、屋外から家屋内に侵入するアリ類の被害や苦情が増加し、アリ類は重要な不快害虫の一つにあげられている。また、最近、特定外来生物に指定されている「ヒアリ」や「カミアリ」が日本数箇所で発見され社会問題になっているが、この種のアリは強い毒を持ち、繁殖力が高いことから速やかな侵入防止対策が求められている。従来、これらアリ類の防除方法としては、殺虫成分を含有する液剤やエアゾールを散布したり、ベイト剤を喫食させて巣に持ち帰らせ巣ごと退治する、いわゆる駆除が主体であった。
しかしながら、アリ類は、家屋内に侵入したり、危害を与えたりしなければ必ずしも駆除の必要がないとの声も聞かれる。更に、特定外来生物であるアリを駆除するために殺虫剤を多用すれば在来アリも殺してしまうことの問題点も指摘されている。このため、アリ類を駆除するのではなく、家屋の入り口や周辺等に予めアリ忌避剤を施用してアリ類を近づけない方法も模索されているのが現状である。
In recent years, the number of complaints and damage caused by ants that invade homes from outdoors has increased, and ants have been identified as one of the important unpleasant pests. In addition, fire ants and fire ants, which are designated as invasive alien species, have recently been discovered in several places in Japan and have become a social problem. Prompt intrusion prevention measures are required. Conventionally, these ants are mainly exterminated by spraying a liquid agent or an aerosol containing an insecticidal component, or eating a bait agent and bringing it back to the nest to exterminate the entire nest.
However, some say that ants do not necessarily need to be exterminated unless they invade a house or cause harm. Furthermore, it has been pointed out that if insecticides are used extensively to exterminate ants, which are specific foreign organisms, the native ants will also be killed. For this reason, instead of exterminating ants, it is currently being sought to apply an ant repellent to the entrance and surroundings of a house in advance to prevent ants from approaching.
例えば、特許第３８４８４１２号公報（特許文献１）には、天然精油であるオークモス、サンダルウッド油、スペアミント油、タイムホワイト油、バチョウリ油、ガーリック油、シナモンリーフ油、タイムレッド油、ペルーバルサムバルサムの１種又は２種以上を有効成分として含有するアリ類の忌避剤が記載されている。この忌避剤は、天然精油を使用するため安全性が高く屋内でも問題なく使用でき空間忌避効果も奏するとしているが、その忌避効果は十分とは言えない。
また、特許第５８４０４７７号公報（特許文献２）は、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、テトラヒドロゲラニオール、フェネチルイソアミルエーテル、ジヒドロインデニル－２，４－ジオキサン、マグノラン、及びルバフランから選ばれる１種又は２種以上をアリ忌避成分として含有するアリ防除剤を開示する。このアリ防除剤は、アリ忌避成分として比較的揮散性の低い香料成分を使用し、家屋の入り口や周辺等に施用するような場面では、１週間以上にわたりクロヤマアリ、アミメアリ等の在来アリ類を忌避させることができる反面、即効的な空間忌避効果を目的とするものではなかった。
このように、今般問題となっているヒアリやカミアリ等の特定外来生物に指定されているアリを含め、アリ類に対して十分実用的な空間忌避効果を奏するアリ忌避組成物、及びこれを用いたアリ忌避製品は未だ得られていないのが現状である。
For example, Japanese Patent No. 3848412 (Patent Document 1) discloses natural essential oils such as oak moss, sandalwood oil, spearmint oil, thyme white oil, bacchouri oil, garlic oil, cinnamon leaf oil, thyme red oil, and Peruvian balsam balsam. An ant repellent containing one or more as active ingredients is described. Since this repellent uses natural essential oils, it is said that it is highly safe, can be used indoors without any problems, and has a spatial repellent effect, but the repellent effect is not sufficient.
In addition, Japanese Patent No. 5840477 (Patent Document 2) discloses tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, tetrahydrogeraniol, phenethyl isoamyl ether, dihydroindenyl- Disclosed is an ant control agent containing one or more selected from 2,4-dioxane, magnolan, and lubafuran as an ant-repelling component. This ant control agent uses a fragrance component with relatively low volatility as an ant repellent component, and when applied to the entrance or surroundings of a house, it can kill native ants such as black mountain ants and reticulum ants for more than a week. Although it can be repelled, it was not intended for an immediate spatial repelling effect.
Thus, an ant-repellent composition that exerts a sufficiently practical space-repellent effect against ants, including ants designated as specific alien species such as fire ants and fire ants, which have recently become a problem, and use thereof The current situation is that no ant repellent product has been obtained yet.
本発明は、アリ類、特にヒアリやカミアリ等の特定外来生物に指定されているアリに対する空間忌避効果が高いアリ忌避組成物、及びこれを用いたアリ忌避製品を提供することを目的とする。 An object of the present invention is to provide an ant-repellent composition having a high space-repellent effect against ants, particularly ants designated as specific alien species such as fire ants and fire ants, and an ant-repellent product using the same.
本発明は、以下の構成が上記目的を達成するために優れた効果を奏することを見出したものである。
（１）アリ忌避成分として、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを、（ａ）／（ｂ）＝０．１／１～１０／１の配合比率で含有するアリ忌避組成物。
（２）前記（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類は、デカナール、ウンデカナール、ドデカナール、２－メチルウンデカナール、トリデカナール、１０－ウンデセナール、シトラール、ネラール、フェニルアセトアルデヒド、シンナミックアルデヒド、α－アミルシンナミックアルデヒド、α－ヘキシルシンナミックアルデヒド、リリアール、ペリルアルデヒド、トリベルタール、クミンアルデヒド、ヘリオトロピン、トリデカノン、ｌ－カルボン、メントン、プレゴン、シス－ジャスモン、ジヒドロジャスモン、α－ダマスコン、β－ダマスコン、δ－ダマスコン、α－イオノン、β－イオノン、２－ペンチルシクロペンタノン、２－ヘキシルシクロペンタノン、２－ヘプチルシクロペンタノン、メチルベンジルケトン、メチルスチリルケトンであり、
前記（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類は、リナロール、デヒドロリナロール、ゲラニオール、ネロール、シトロネロール、メントール、テルピネオール、テルピネン－４－オール、イソプレゴール、ボルネオール、１－フェニルエチルアルコール、２－フェニルエチルアルコール、チモール、オイゲノールである（１）に記載のアリ忌避組成物。
（３）アリ忌避成分として、（ｃ）総炭素数が８～１６の炭化水素エステル類から選ばれる１種又は２種以上を更に含有する（１）又は（２）に記載のアリ忌避組成物。
（４）前記（ｃ）総炭素数が８～１６の炭化水素エステル類は、デシルアセテート、リナリルアセテート、ゲラニルアセテート、シトロネリルアセテート、メンチルアセテート、テルピニルアセテート、ネピルアセテート、ｐ－ｔ－ブチルシクロヘキシルアセテート、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、フェニルエチルアセテート、スチラリルアセテート、シンナミルアセテート、シンナミルプロピオネート、アリルヘキサノエート、アリルヘプタノエート、メチルベンゾエート、エチルベンゾエート、３－ヘキセニルベンゾエート、ベンジルベンゾエート、メチルシンナメート、エチルシンナメート、メチルサリシネート、エチルサリシネート、アミルサリシネート、メチルジャスモネート、メチルジヒドロジャスモネートである（３）に記載のアリ忌避組成物。
（５）更に、アリ忌避増強成分として、ディート、イカリジン、及びブチルアセチルアミノプロピオン酸エチル（以下、ＩＲ３５３５と略す）から選ばれる１種又は２種以上を含有する（１）ないし（４）のいずれか１に記載のアリ忌避組成物。
（６）実質的に殺虫成分を含有しない（１）ないし（５）のいずれか１に記載のアリ忌避組成物。
（７）前記アリは、ヒアリ又はカミアリである（１）ないし（６）のいずれか１に記載のアリ忌避組成物。
（８）（１）ないし（７）のいずれか１に記載のアリ忌避組成物を用い、液状製剤又は固形剤に調製してなるアリ忌避製品。
（９）前記固形剤は、前記アリ忌避組成物を含有させた担持体からアリ忌避成分を空間に揮散させてアリに対する忌避効果を奏し得るようになしたものである（８）に記載のアリ忌避製品。
（１０）前記担持体は、プラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体である（９）に記載のアリ忌避製品。
（１１）前記アリは、ヒアリ又はカミアリである（８）ないし（１０）のいずれか１に記載のアリ忌避製品。
The present invention has found that the following configuration has excellent effects for achieving the above object.
(1) As ant repellent components, (a) one or more selected from hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) a total carbon number of 8 to An ant containing one or more selected from 12 monoterpene alcohols and/or aromatic alcohols at a blending ratio of (a)/(b) = 0.1/1 to 10/1 repellent composition.
(2) The (a) hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16 are decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, 10-undecenal, citral, neral, phenylacetaldehyde, cinnamic aldehyde, α-amyl cinnamic aldehyde, α-hexyl cinnamic aldehyde, lyrial, perillaldehyde, tribertal, cumin aldehyde, heliotropine, tridecanone, l-carvone, menthone, pulegone, cis-jasmon, Dihydrojasmone, α-damascone, β-damascone, δ-damascone, α-ionone, β-ionone, 2-pentylcyclopentanone, 2-hexylcyclopentanone, 2-heptylcyclopentanone, methylbenzylketone, methylstyryl is a ketone,
The (b) monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12 are linalool, dehydrolinalool, geraniol, nerol, citronellol, menthol, terpineol, terpinen-4-ol, isopulegol, and borneol. , 1-phenylethyl alcohol, 2-phenylethyl alcohol, thymol, and eugenol.
(3) The ant-repellent composition according to (1) or (2), further containing (c) one or more selected from hydrocarbon esters having a total carbon number of 8 to 16 as the ant-repellent component. .
(4) The (c) hydrocarbon esters having a total carbon number of 8 to 16 include decyl acetate, linalyl acetate, geranyl acetate, citronellyl acetate, menthyl acetate, terpinyl acetate, nepyryl acetate, pt- Butyl cyclohexyl acetate, tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, phenylethyl acetate, styraryl acetate, cinnamyl acetate, cinnamyl propionate, allyl hexano ate, allyl heptanoate, methyl benzoate, ethyl benzoate, 3-hexenyl benzoate, benzyl benzoate, methyl cinnamate, ethyl cinnamate, methyl salicinate, ethyl salicinate, amyl salicinate, methyl jasmonate, methyl The ant-repellent composition according to (3), which is dihydrojasmonate.
(5) Any of (1) to (4), further containing one or more selected from DEET, Icaridin, and ethyl butylacetylaminopropionate (hereinafter abbreviated as IR3535) as an ant-repellent enhancing component. 2. The ant repelling composition according to 1.
(6) The ant-repellent composition according to any one of (1) to (5), which does not substantially contain an insecticidal component.
(7) The ant-repellent composition according to any one of (1) to (6), wherein the ants are fire ants or fire ants.
(8) An ant-repellent product prepared by preparing a liquid or solid formulation using the ant-repellent composition according to any one of (1) to (7).
(9) The ant according to (8), wherein the solid agent is capable of volatilizing the ant-repellent component into space from the carrier containing the ant-repellent composition, thereby exerting an ant-repellent effect. Repellent product.
(10) The ant-repellent product according to (9), wherein the carrier is a plastic resin film, molded article, or silicone rubber molded article.
(11) The ant repellent product according to any one of (8) to (10), wherein the ants are fire ants or fire ants.
本発明のアリ忌避組成物は、特定のアリ忌避成分を含有し、アリ類、特にヒアリやカミアリ等の特定外来生物であるアリに対する空間忌避効果に優れるので極めて実用性が高い。従って、このアリ忌避組成物を用いた本発明のアリ忌避製品も非常に有用なものである。 INDUSTRIAL APPLICABILITY The ant-repellent composition of the present invention contains a specific ant-repellent component and has excellent spatial repellency against ants, particularly ants that are specific foreign organisms such as fire ants and fire ants, and is extremely practical. Therefore, the ant-repellent product of the present invention using this ant-repellent composition is also very useful.
本発明のアリ忌避組成物は、アリ忌避成分として、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを、（ａ）／（ｂ）＝０．１／１～１０／１の配合比率で含有することを特徴とする。 The ant-repellent composition of the present invention comprises, as ant-repellent components, (a) one or more selected from hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) One or two or more selected from monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12, (a) / (b) = 0.1/1 to 10/1 It is characterized by being contained in a compounding ratio.
前記（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類の具体例としては、例えば、デカナール、ウンデカナール、ドデカナール、２－メチルウンデカナール、トリデカナール、１０－ウンデセナール、シトラール、ネラール、フェニルアセトアルデヒド、シンナミックアルデヒド、α－アミルシンナミックアルデヒド、α－ヘキシルシンナミックアルデヒド、リリアール、ペリルアルデヒド、トリベルタール、クミンアルデヒド、ヘリオトロピン、トリデカノン、ｌ－カルボン、メントン、プレゴン、シス－ジャスモン、ジヒドロジャスモン、α－ダマスコン、β－ダマスコン、δ－ダマスコン、α－イオノン、β－イオノン、２－ペンチルシクロペンタノン、２－ヘキシルシクロペンタノン、２－ヘプチルシクロペンタノン、メチルベンジルケトン、メチルスチリルケトンがあげられる。 Specific examples of (a) hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16 include decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, and 10-undecenal. , citral, neral, phenylacetaldehyde, cinnamic aldehyde, α-amyl cinnamic aldehyde, α-hexyl cinnamic aldehyde, lyrial, perillaldehyde, tribertal, cumin aldehyde, heliotropine, tridecanone, l-carvone, menthone, pulegone, cis - jasmone, dihydrojasmone, α-damascone, β-damascone, δ-damascone, α-ionone, β-ionone, 2-pentylcyclopentanone, 2-hexylcyclopentanone, 2-heptylcyclopentanone, methylbenzyl ketone , and methyl styryl ketone.
一方、前記（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類の具体例としては、例えば、リナロール、デヒドロリナロール、ゲラニオール、ネロール、シトロネロール、メントール、テルピネオール、テルピネン－４－オール、イソプレゴール、ボルネオール、１－フェニルエチルアルコール、２－フェニルエチルアルコール、チモール、オイゲノールがあげられる。 On the other hand, specific examples of (b) monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12 include linalool, dehydrolinalool, geraniol, nerol, citronellol, menthol, terpineol, and terpinene. -4-ol, isopulegol, borneol, 1-phenylethyl alcohol, 2-phenylethyl alcohol, thymol, eugenol.
本発明では、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを併用する必要がある。そして、本発明者らの検討結果によれば、（ａ）／（ｂ）の配合比率が０．１／１～１０／１の範囲において、アリ類、特にヒアリやカミアリ等の特定外来生物であるアリに対し相乗的に高い空間忌避効果を奏することが認められた。（ａ）／（ｂ）の配合比率がこの範囲を外れると相乗効果が得られず併用するメリットはない。 In the present invention, (a) one or more selected from hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) a monoterpene having a total carbon number of 8 to 12 It is necessary to use one or more selected from alcohols and/or aromatic alcohols in combination. According to the study results of the present inventors, when the blending ratio of (a) / (b) is in the range of 0.1/1 to 10/1, ants, especially fire ants and fire ants, are specific alien organisms. It was confirmed that a synergistic high spatial repelling effect was exhibited against a certain ant. If the mixing ratio of (a)/(b) is out of this range, a synergistic effect cannot be obtained and there is no advantage in using them together.
本発明のアリ忌避組成物は、アリ忌避成分として、（ｃ）総炭素数が８～１６の炭化水素エステル類から選ばれる１種又は２種以上を更に含有するのが好ましい。このような炭化水素エステル類は、アリ忌避効果の増強に寄与し得るものであり、具体例としては、例えば、デシルアセテート、リナリルアセテート、ゲラニルアセテート、シトロネリルアセテート、メンチルアセテート、テルピニルアセテート、ネピルアセテート、ｐ－ｔ－ブチルシクロヘキシルアセテート、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、フェニルエチルアセテート、スチラリルアセテート、シンナミルアセテート、シンナミルプロピオネート、アリルヘキサノエート、アリルヘプタノエート、メチルベンゾエート、エチルベンゾエート、３－ヘキセニルベンゾエート、ベンジルベンゾエート、メチルシンナメート、エチルシンナメート、メチルサリシネート、エチルサリシネート、アミルサリシネート、メチルジャスモネート、メチルジヒドロジャスモネートがあげられるが、これらに限定されない。 The ant-repellent composition of the present invention preferably further contains (c) one or more selected from hydrocarbon esters having a total carbon number of 8 to 16 as an ant-repellent component. Such hydrocarbon esters can contribute to enhancing the ant-repellent effect, and specific examples include decyl acetate, linalyl acetate, geranyl acetate, citronellyl acetate, menthyl acetate, terpinyl acetate, nepyr acetate, pt-butylcyclohexyl acetate, tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, phenylethyl acetate, styraryl acetate, cinnamyl acetate, thinner Myl Propionate, Allyl Hexanoate, Allyl Heptanoate, Methyl Benzoate, Ethyl Benzoate, 3-Hexenyl Benzoate, Benzyl Benzoate, Methyl Cinnamate, Ethyl Cinnamate, Methyl Salicinate, Ethyl Salicinate, Amyl Salicinate jasmonate, methyl jasmonate, methyl dihydrojasmonate.
本発明のアリ忌避組成物には、上記以外の香料成分、例えば、ｄ－リモネン、α－ピネン、β－ピネン等の炭化水素類、イソアミルフェニルエチルエーテル、リナロールオキサイド、１，８－シネオール、ローズオキサイド、ジフェニルエーテル、マグノラン、ルバフラン、ジヒドロインデニル－２，４－ジオキサン等の炭化水素エーテル類、２，６－ジメチル－３－エチルピラジン、シトロネリルニトリル、ステモン、ｏ－アミノアセトフェノン等の含窒素化合物類等を配合しても構わない。また、サンダルウッド油、スペアミント油、タイムホワイト油、バチョウリ油、ガーリック油、シナモンリーフ油、タイムレッド油、ジャスミン油、ネロリ油、ベルガモット油、オレンジ油、ゼラニウム油、プチグレン油、レモン油、レモングラス油、シナモン油、ユーカリ油等の精油類も適宜配合可能である。
なお、本発明においては、精油として配合されたとしても、前記アリ忌避成分が精油中に５質量％以上含まれる場合、個々のアリ忌避成分として配合されたものと定義する。
The ant-repellent composition of the present invention may contain perfume ingredients other than those mentioned above, such as hydrocarbons such as d-limonene, α-pinene, and β-pinene, isoamylphenylethyl ether, linalool oxide, 1,8-cineol, and rose. Oxide, diphenyl ether, magnolan, rubafran, dihydroindenyl-2,4-dioxane and other hydrocarbon ethers, 2,6-dimethyl-3-ethylpyrazine, citronellylnitrile, stemone, o-aminoacetophenone and other nitrogen-containing compounds It does not matter if the same kind or the like is blended. In addition, sandalwood oil, spearmint oil, thyme white oil, bachouri oil, garlic oil, cinnamon leaf oil, thyme red oil, jasmine oil, neroli oil, bergamot oil, orange oil, geranium oil, petitgrain oil, lemon oil, lemongrass. Oil, cinnamon oil, eucalyptus oil and other essential oils can also be blended as appropriate.
In the present invention, even if the ant-repellent component is blended as an essential oil, when the ant-repellent component is contained in the essential oil in an amount of 5% by mass or more, it is defined as being blended as an individual ant-repellent component.
本発明のアリ忌避組成物には、アリ忌避成分の揮散後の忌避効果持続成分として、２０℃における蒸気圧が０．２～２０Ｐａのグリコール類及び／又はグリコールエーテル類の１種又は２種以上を配合してもよい。このようなグリコール類及び／又はグリコールエーテル類は、溶剤としてのみならず、アリ忌避成分に対して特異的に忌避効果の持続作用を奏し得ることを初めて知見したものである。
その具体的代表例（２０℃における蒸気圧を併記）としては、プロピレングリコール（１０．７Ｐａ）、ジプロピレングリコール（１．３Ｐａ）、トリプロピレングリコール（０．６７Ｐａ）、ジエチレングリコール（３Ｐａ）、トリエチレングリコール（１Ｐａ）、１，３－ブチレングリコール、ヘキシレングリコール（６．７Ｐａ）、ベンジルグリコール（２．７Ｐａ）、ジエチレングリコールモノブチルエーテル（３Ｐａ）、ジプロピレングリコールモノブチルエーテル、及びトリプロピレングリコールモノメチルエーテルがあげられ、なかんずく、ジプロピレングリコールが本発明の目的に合致する。
なお、忌避効果持続成分の配合量としては、前記アリ忌避成分の０．２～１０倍程度が適当である。
In the ant-repellent composition of the present invention, one or two or more glycols and/or glycol ethers having a vapor pressure of 0.2 to 20 Pa at 20° C. are used as the component for sustaining the repellent effect after volatilization of the ant-repellent component. may be blended. This is the first discovery that such glycols and/or glycol ethers can not only act as a solvent, but also exert a specific and sustained repellent effect on ant-repellent components.
Specific representative examples thereof (vapor pressure at 20°C is also indicated) include propylene glycol (10.7 Pa), dipropylene glycol (1.3 Pa), tripropylene glycol (0.67 Pa), diethylene glycol (3 Pa), and triethylene. Glycol (1 Pa), 1,3-butylene glycol, hexylene glycol (6.7 Pa), benzyl glycol (2.7 Pa), diethylene glycol monobutyl ether (3 Pa), dipropylene glycol monobutyl ether, and tripropylene glycol monomethyl ether. and dipropylene glycol, among others, is suitable for the purposes of the present invention.
It should be noted that the appropriate amount of the repellent effect-sustaining component is about 0.2 to 10 times that of the ant-repellent component.
本発明では、前記各種成分に、本発明の効果に支障を来たさない限りにおいて、例えば、蚊に対する忌避成分、殺虫成分、消臭成分、除菌・抗菌成分等の他の機能性成分を配合してアリ忌避組成物を構成してもよい。
かかる機能性成分のうち、蚊に対する忌避成分であるディート、イカリジン、ＩＲ３５３５は、アリ忌避成分と混用することによってそのアリ忌避効果を増強させ得ることが認められた。一方、殺虫成分としては、常温揮散性ピレスロイド系のエムペントリン、トランスフルトリン、メトフルトリン、プロフルトリン等が好適な代表例としてあげられるが、本発明の趣旨に照らし、配合するとしても極力微量に留めるのが好ましい。また、消臭成分としては、イネ科、ツバキ科、イチョウ科、モクセイ科、クワ科、ミカン科、キントラノオ科、カキノキ科の中から選ばれる植物抽出物が代表的である。更に、「緑の香り」と呼ばれる青葉アルコールや青葉アルデヒド等を添加してリラックス効果を付与することもできる。
なお、アリ忌避組成物を、例えば、マイクロカプセル化したり、サイクロデキストリン化して当該組成物の安定化を図ったり、アリ忌避成分の揮散性を調節することも可能である。
In the present invention, other functional ingredients such as repellent ingredients against mosquitoes, insecticidal ingredients, deodorizing ingredients, disinfecting/antibacterial ingredients, etc. They may be blended to form an ant repellent composition.
Among such functional ingredients, DEET, Icaridin, and IR3535, which are repellent ingredients against mosquitoes, were found to be able to enhance their ant-repellent effect by being mixed with ant-repellent ingredients. On the other hand, typical examples of insecticidal components include pyrethroid volatiles such as empenthrin, transfluthrin, metofluthrin, and profluthrin, which are volatile at room temperature. preferable. Representative examples of the deodorizing component are plant extracts selected from the family Gramineae, Theaceae, Ginkgoaceae, Oleaceae, Moraceae, Rutaceae, Chrysanthemum family, and Persimmon family. Furthermore, green leaf alcohol, green leaf aldehyde, or the like, which is called "green fragrance", can be added to impart a relaxing effect.
The ant-repellent composition can be, for example, microencapsulated or cyclodextrinized to stabilize the composition, or to adjust the volatility of the ant-repellent component.
こうして得られた本発明のアリ忌避組成物は、そのまま若しくは希釈して使用することもできるが、通常、これを用いて種々剤型のアリ忌避製品を調製する。
その剤型としては、スプレーの形態で用いられる液剤、乳剤、水溶剤、マイクロエマルジョンやエアゾール等の液状製剤と、粉剤、粒剤、ベイト剤等の固形剤があげられる。そして、かかるアリ忌避製品を製するにあたっては、必要に応じ、溶剤、界面活性剤、可溶化剤、ゲル化剤、分散剤、安定化剤、ｐＨ調整剤、着色剤等を適宜配合してもよい。
The ant-repellent composition of the present invention thus obtained can be used as it is or after being diluted, but it is usually used to prepare ant-repellent products of various dosage forms.
The dosage forms include liquid preparations such as liquids, emulsions, aqueous solutions, microemulsions and aerosols used in the form of sprays, and solid preparations such as powders, granules and baits. In the production of such ant-repellent products, solvents, surfactants, solubilizers, gelling agents, dispersants, stabilizers, pH adjusters, coloring agents, etc. may be added as appropriate. good.
アリ忌避製品の調製に用いる溶剤としては、例えば、水、エタノール、イソプロパノール等の低級アルコール、ケトン系溶剤、エステル系溶剤、ノルマルパラフィンやイソパラフィン等の炭化水素系溶剤等があげられる。
界面活性剤としては、例えば、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレン高級アルキルエーテル類（ポリオキシエチレンラウリルエーテル、ポリオキシエチレンオレイルエーテル等）、ポリオキシエチレンアルキルフェニルエーテル類、ポリオキシエチレン高級脂肪酸エステル類、ポリオキシエチレンソルビタン脂肪酸エステル類、ポリオキシエチレングリセリン脂肪酸エステル類、ポリオキシエチレンポリオキシプロピレンアルキルエーテル等の非イオン系界面活性剤や、ラウリルアミンオキサイド、ステアリルアミンオキサイド、ラウリル酸アミドプロピルジメチルアミンオキサイド等の高級アルキルアミンオキサイド系界面活性剤を例示することができる。
また、ゲル化剤としては、ポリビニルアルコール、アルギン酸、カラギーナン等が適宜用いられる。
Solvents used in the preparation of ant repellent products include, for example, water, lower alcohols such as ethanol and isopropanol, ketone solvents, ester solvents, and hydrocarbon solvents such as normal paraffin and isoparaffin.
Surfactants include, for example, polyoxyethylene hydrogenated castor oil, polyoxyethylene higher alkyl ethers (polyoxyethylene lauryl ether, polyoxyethylene oleyl ether, etc.), polyoxyethylene alkylphenyl ethers, polyoxyethylene higher fatty acid Nonionic surfactants such as esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene glycerin fatty acid esters, polyoxyethylene polyoxypropylene alkyl ethers, laurylamine oxide, stearylamine oxide, laurylamide propyl dimethyl Higher alkylamine oxide surfactants such as amine oxide can be exemplified.
As a gelling agent, polyvinyl alcohol, alginic acid, carrageenan and the like are appropriately used.
本発明のアリ忌避製品は、液状製剤よりも固形剤が好ましい。これは、使い易いこと、液漏れの心配がないことや薬液が手指に触れる危険性の少ないこと等のメリットが勘案されるためである。なかでも、アリ忌避組成物を担持体に含有させ、この担持体からアリ忌避成分を空間に揮散させる形態が好適に採用される。
ここで担持体としては、木粉、小麦粉等の各種植物質粉末、紙、織布、不織布等の基布、ビスコパール等の多孔質有機成形体、カオリン、タルク、炭酸カルシウム、珪石、珪砂、セラミックス等の無機担持体、ポリエチレン、ポリプロピレン、エチレン／酢酸ビニル共重合体（ＥＶＡ）、エチレン／メタクリル酸メチル共重合体（ＥＭＭＡ）、スチレン系ジブロックポリマー、スチレン系トリブロックポリマー、熱可塑性プラスチックエラストマー（ＴＰＥ、ＴＰＯ）等から構成されるプラスチック樹脂フィルム又は成形体、シリコーンゴム等があげられるが、これらに限定されない。
これらのうち、担持体としてプラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体を用いて調製した固形剤は、アリ類に対して効率的に優れた空間忌避効果を奏し、有用性が高いアリ忌避製品の一つである。
The ant repellent product of the present invention is preferably a solid formulation rather than a liquid formulation. This is because advantages such as ease of use, no risk of liquid leakage, and low risk of the liquid coming into contact with fingers are taken into account. Among them, a form in which the ant-repellent composition is contained in a carrier and the ant-repellent component is volatilized into space from the carrier is preferably adopted.
Examples of the carrier include various vegetable powders such as wood flour and wheat flour, base fabrics such as paper, woven fabrics and non-woven fabrics, porous organic moldings such as Viscopearl, kaolin, talc, calcium carbonate, silica stone, silica sand, Inorganic carriers such as ceramics, polyethylene, polypropylene, ethylene/vinyl acetate copolymer (EVA), ethylene/methyl methacrylate copolymer (EMMA), styrene diblock polymers, styrene triblock polymers, thermoplastic elastomers Plastic resin films or moldings composed of (TPE, TPO) and the like, silicone rubbers, and the like, but not limited to these.
Among these, the solid agent prepared by using a plastic resin film or molded article, or a silicone rubber molded article as a carrier has an efficient and excellent spatial repelling effect against ants, and is highly useful in repelling ants. It is one of the products.
本発明のアリ忌避製品に含有されるアリ忌避組成物の配合量は、当該忌避製品の使用用途、使用期間、及びその仕様等によって適宜決定すればよいが、液状製剤の場合、０．０１～２０ｗ／ｖ％、一方、固形剤の場合、０．０１～１０ｗ／ｗ％程度が適当である。
なお、担持体にアリ忌避組成物を含有させる固形剤においては、１回あたり８～１２時間使用の忌避製品の場合、アリ忌避組成物を担持体あたり１０～５０ｍｇ、一方、１５～３０日使用の忌避製品にあっては１００～２０００ｍｇ程度含有させればよい。
The amount of the ant-repellent composition contained in the ant-repellent product of the present invention may be appropriately determined according to the intended use, period of use, specifications, etc. of the ant-repellent product. 20 w/v %, while in the case of solid formulations, about 0.01 to 10 w/w % is appropriate.
In addition, in the solid formulation containing the ant repellent composition in the carrier, in the case of a repellent product that is used for 8 to 12 hours per time, the ant repellent composition is 10 to 50 mg per carrier, while the ant repellent composition is used for 15 to 30 days. 100 to 2000 mg may be contained in repellent products.
本発明のアリ忌避製品を製造するに際しては何ら特別の技術を必要としない。
アリ忌避組成物を担持体に含有させるに際しても、必要に応じて溶剤や界面活性剤等を添加し、従来公知の方法を適宜採用することができる。例えば、担持体が不織布の場合、アリ忌避組成物を薬液分注方式や塗布方式によって担持させてもよいし、あるいはパラフィンワックスと共に包埋させるようにしても構わない。
また、プラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体等にこれを担持させるにあたっては、本発明のアリ忌避組成物が揮散性のため高温下での混合工程は避け、薬液分注方式や塗布方式を採用したり、アリ忌避組成物を必要に応じ溶剤と共に噴霧又は滴下して成形体に浸透させる方式が適当である。あるいは、高濃度にアリ忌避組成物を含有させたシリコーンゴム成形体と無処理のシリコーンゴム成形体を密閉容器中に混在させ、適当時間放置してシリコーンゴム成形体全体に亘ってアリ忌避組成物濃度を平均化させる方法によっても本発明のアリ忌避製品を製造可能である。
No special technique is required to produce the ant repellent product of the present invention.
When the ant-repellent composition is contained in the carrier, a conventionally known method can be appropriately employed by adding a solvent, a surfactant, etc., as necessary. For example, when the carrier is a non-woven fabric, the ant repellent composition may be carried by a chemical dispensing method or coating method, or may be embedded together with paraffin wax.
In addition, when the ant-repellent composition of the present invention is carried on a plastic resin film, a molded article, or a silicone rubber molded article, etc., a mixing process at a high temperature is avoided because of the volatility of the ant-repellent composition. method, or a method in which the ant-repellent composition is sprayed or dropped together with a solvent as necessary to permeate the molded article. Alternatively, a silicone rubber molded article containing an ant repellent composition at a high concentration and an untreated silicone rubber molded article are mixed in a sealed container and left for an appropriate time to allow the ant repellent composition to spread over the entire silicone rubber molded article. The ant repellent product of the present invention can also be produced by a concentration averaging method.
こうして得られた本発明のアリ忌避製品は、その剤型に応じて様々な使用場面に適用される。アリ忌避製品が液剤、エアゾール剤、粉剤、粒剤のような製剤の場合、玄関、台所、トイレ、リビングルーム、寝室などの室内、倉庫、車中等や、ベランダ、ポーチ、庭先、家屋の周囲などに、所定量を散布したり載置したりして、アリ類が近づかない空間を形成することが可能である。その施用量としては、例えば、玄関まわりで液状製剤を使用する場合、１０～５０ｍＬ／ｍ２、固形剤にあっては、１０～５０ｇ／ｍ２程度が適当である。
一方、上記担持体がプラスチック樹脂成形体やシリコーンゴム成形体の場合、足バンドとして足首や靴等に巻装したり、当該成形体をクリップのような固定具で靴等に装着して使用すれば効果的であるし、また、担持体がシールのような場合、フィルム状担持体の下面に粘着層を設けズボンの下部や靴等に貼付して用いるのが便利である。
The thus obtained ant-repellent product of the present invention is applied to various usage scenes depending on its dosage form. If the ant repellent product is a formulation such as liquid, aerosol, powder, or granules, it can be used indoors such as entrances, kitchens, toilets, living rooms, bedrooms, warehouses, cars, balconies, porches, gardens, around houses, etc. In addition, it is possible to form a space where ants do not approach by spraying or placing a predetermined amount. Appropriate application amounts are, for example, 10 to 50 mL/m 2 when liquid formulations are used around entrances, and approximately 10 to 50 g/m 2 for solid formulations.
On the other hand, when the carrier is a plastic resin molded body or a silicone rubber molded body, it can be used by wrapping it around an ankle or a shoe as a foot band, or by attaching the molded body to a shoe or the like with a fixture such as a clip. In addition, when the carrier is a sticker, it is convenient to provide an adhesive layer on the underside of the film-like carrier and attach it to the bottom of trousers, shoes, or the like.
本発明のアリ忌避製品は、アリ類、具体的には、クロヤマアリ、アミメアリ、トビイロケアリ、トビイロシワアリ、ルリアリ、クロオオアリ、イエヒメアリ、アルゼンチンアリ等に対して実用的な空間忌避効果を示し、特にヒアリやカミアリ等の特定外来生物であるアリに対して効果的である。本発明者らの検討結果によれば、当該アリ忌避製品は、これらのアリによる刺咬被害を防止できるだけでなく、ハチ類、ヤマビル等にも忌避効果を示すことが認められた。しかも、実質的に殺虫成分を含有していない本製品は、殺虫剤の使用を嫌がる人にも手軽に使用できるのでその実用性は極めて高い。 The ant repellent product of the present invention exhibits a practical spatial repelling effect against ants, specifically, black wood ant, reticulum ant, black ant, black ant, blue ant, carpenter ant, carpenter ant, carpenter ant, Argentine ant, etc. In particular, fire ant, fire ant, etc. It is effective against ants, which are specific alien organisms. According to the study results of the present inventors, it was confirmed that the ant repellent product can not only prevent the bite damage caused by these ants, but also show a repelling effect against bees, mountain birch, and the like. In addition, the product, which does not substantially contain insecticidal ingredients, can be easily used by people who dislike the use of insecticides, so its practicality is extremely high.
次に具体的な実施例に基づき、本発明のアリ忌避組成物、及びこれを用いたアリ忌避製品について更に詳細に説明するが、本発明はこれらに限定されるものではない。 Next, the ant-repellent composition of the present invention and the ant-repellent product using the same will be described in more detail based on specific examples, but the present invention is not limited to these.
表１に示す供試アリ忌避組成物をアセトン１０ｍＬに溶解して供試薬液を調製し、下記の忌避効力試験を実施した。
［忌避効力試験－１］
供試薬液０．５ｍＬを直径９ｃｍの濾紙に滴下し、風乾後この濾紙を半分に切断した。この半面と無処理濾紙の半面を重ならないように直径９ｃｍのガラスシャーレに置いた。ガラスシャーレの内壁にタルクを塗り、トビイロシワアリ５０匹又はヒアリ５０匹を放し、５分後、ならびに２時間後に処理面及び無処理面にいる虫数を数え、下式に従って忌避率を求めた。結果を表２に示す。
忌避率＝［（無処理面の侵入虫数－処理面の侵入虫数）／供試虫数×１００］
A test reagent solution was prepared by dissolving the test ant repellent composition shown in Table 1 in 10 mL of acetone, and the following repellent efficacy test was conducted.
[Repellent efficacy test-1]
0.5 mL of the test reagent solution was dropped onto a filter paper with a diameter of 9 cm, and after air-drying, the filter paper was cut in half. This half surface and the untreated filter paper half surface were placed on a glass petri dish having a diameter of 9 cm so as not to overlap each other. Talc was applied to the inner wall of a glass petri dish, 50 brown ants or 50 fire ants were released, and after 5 minutes and 2 hours, the number of insects on the treated and untreated surfaces was counted, and the repellency rate was calculated according to the following formula. Table 2 shows the results.
Repellent rate = [(number of invading insects on untreated surface - number of invading insects on treated surface)/number of test insects x 100]
試験の結果、アリ忌避成分として、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種とを、（ａ）／（ｂ）＝０．１／１～１０／１の配合比率で含有する本発明のアリ忌避組成物は、トビイロシワアリのような在来アリはもちろん、特定外来生物であるヒアリに対しても同等以上のアリ忌避効果を示すことが確認された。なお、本発明５、本発明６、本発明１２及び本発明１３のように、（ａ）及び（ｂ）のアリ忌避成分に、更に（ｃ）総炭素数が８～１６の炭化水素エステル類や人体用の蚊忌避剤であるＩＲ３５３５やイカリジンを配合することによってアリ忌避効果が増強した。また、本発明７及び本発明１４が示す如く、ジプロピレングリコールやヘキシレングリコールの配合は、アリ忌避成分の忌避効果を持続させるうえで効果的であることが認められた。
これに対し、本発明が規定するアリ忌避組成物以外を用いた比較例では、アリ忌避効果が十分と言えないばかりか、ヒアリに対するアリ忌避効果はトビイロシワアリを対象とする場合よりも劣る傾向が認められた。
As a result of the test, as the ant repellent component, (a) one selected from hydrocarbon aldehydes and / or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) a substance having a total carbon number of 8 to 12 The ant repellent composition of the present invention containing one selected from terpene alcohols and/or aromatic alcohols at a blending ratio of (a)/(b) = 0.1/1 to 10/1 , It was confirmed that the ant-repellent effect was equal to or greater than that of fire ants, which is a specific alien species, as well as native ants such as the brown wrinkled ant. In addition, as in Invention 5, Invention 6, Invention 12 and Invention 13, in addition to the ant repellent components (a) and (b), (c) hydrocarbon esters having a total carbon number of 8 to 16 The ant repelling effect was enhanced by adding IR3535, which is a mosquito repellent for humans, and Icaridin. Moreover, as shown by Inventions 7 and 14, it was confirmed that the addition of dipropylene glycol or hexylene glycol is effective in sustaining the repelling effect of the ant-repellent component.
On the other hand, in the comparative examples using compositions other than the ant-repellent composition defined by the present invention, not only is the ant-repellent effect not sufficient, but the ant-repellent effect against fire ants tends to be inferior to that in the case of targeting brown ants. was taken.
表３に示す供試アリ忌避組成物にｎ－パラフィン（ネオチオゾール）を加えエアゾール原液を調製した（アリ忌避組成物含量：エアゾール原液に対し２．０ｗ／ｖ％）。このエアゾール原液５０ｍＬをエアゾール容器に充填後、液化石油ガス（ＬＰＧ）５０ｍＬを加圧充填してエアゾール形態の本発明のアリ忌避製品を得た。このアリ忌避製品につき、下記の忌避効力試験を実施した。
［忌避効力試験－２］
２０ｃｍ角のタイルに供試アリ忌避製品を１ｍ２あたり２０ｍＬになるように滴下した。このタイルの中央に誘引剤として３％ショ糖水溶液を含浸させた脱脂綿を置き、在来アリ又は特定外来生物であるアリが生息する草むらに設置した。設置直後、及び設置３日後に、誘引剤に集まったアリを数え、アリ忌避効果を調べた。結果を表４に示す。
評価基準（集まったアリ数）；
０匹；◎、 １～５匹；○～◎、 ６～１０匹；〇、 １１～２０匹；△、
２１～３０匹；×～△、 ３１匹以上；×
An aerosol stock solution was prepared by adding n-paraffin (neothiosol) to the test ant repellent composition shown in Table 3 (ant repellent composition content: 2.0 w/v% relative to the aerosol stock solution). After filling 50 mL of this aerosol stock solution into an aerosol container, 50 mL of liquefied petroleum gas (LPG) was filled under pressure to obtain the ant repellent product of the present invention in the form of an aerosol. For this ant repellent product, the following repellent efficacy test was performed.
[Repellent efficacy test-2]
The test ant repellent product was dropped onto a tile of 20 cm square so that 20 mL per 1 m 2 was obtained. Absorbent cotton impregnated with a 3% sucrose aqueous solution was placed in the center of this tile as an attractant, and placed in a grassy area inhabited by native ants or ants that are specific alien species. Immediately after installation and three days after installation, the ants gathered in the attractant were counted to examine the ant repelling effect. Table 4 shows the results.
evaluation criteria (number of ants gathered);
0 animals; ◎, 1 to 5 animals; ○ to ◎, 6 to 10 animals; ◯, 11 to 20 animals;
21 to 30 animals; × to △, 31 or more animals; ×
試験の結果、本発明のアリ忌避組成物を用いて調製したエアゾール形態のアリ忌避製品は、実施例１と同様、在来アリ及び特定外来生物であるアリのいずれに対しても優れたアリ忌避効果を示した。なお、ＩＲ３５３５の配合は忌避効果増強の点で有用であり、また、ジプロピレングリコールの配合は忌避効果の持続性向上に寄与することが認められた。
別途、本発明２１につき、勝手口や玄関のスペースに１ｍ２あたり約２０ｍＬ噴霧処理したところ、７日間にわたりアリ類の家屋内への侵入は見られなかった。また、処理した所から少し離れた場所に死亡したクロヤマアリやアミメアリが何個体か観察され、アリ忌避成分の忌避効果に加え、殺虫成分であるエムペントリンの作用が覗えた。
As a result of the test, the aerosol-type ant repellent product prepared using the ant repellent composition of the present invention was excellent in repelling both native ants and ants that are specific foreign organisms, as in Example 1. showed an effect. In addition, it was confirmed that the compounding of IR3535 is useful in terms of enhancing the repellent effect, and the compounding of dipropylene glycol contributes to improving the durability of the repellent effect.
Separately, according to Invention 21, when about 20 mL per 1 m 2 of the back door and entrance space was sprayed, no ants entered the house for 7 days. In addition, some dead black wood ants and reticulum ants were observed in a place a little away from the treated place, and in addition to the repelling effect of the ant-repellent component, the action of the insecticidal component empentrin could be seen.
アリ忌避成分の（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類として、α－ヘキシルシンナミックアルデヒドを８．５質量％とｌ－カルボンを４．９質量％、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類として、リナロールを９．０質量％、テルピネオールを３．５質量％とチモールを６．３質量％、更に（ｃ）総炭素数が８～１６の炭化水素エステル類として、ベンジルベンゾエートを１１．７質量％、ベンジルアセテートを８．４質量％とスチラリルアセテートを５．１質量％、ならびにその他の成分を配合して本発明のアリ忌避組成物を調製した。なお、このアリ忌避組成物における（ａ）／（ｂ）比率は０．７１／１であった。
このアリ忌避組成物の３０ｍｇを、担持体としてのリング状シリコーンゴム（１．６ｇ）に含有させ、リストバンド形態の本発明のアリ忌避製品を得た。
このリストバンドを２本ずつ両足首に巻装して外出したところ、８～１２時間にわたり、アリ類だけでなく、ワラジムシ、ダンゴムシ等の各種匍匐害虫や、蚊、ブユ、ハチ類、ユスリカ等の各種飛翔害虫、更にはヤマヒル等に煩わされることがなく、実用的な忌避効果が確認された。
As the ant-repellent component (a) hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16, 8.5% by mass of α-hexyl cinnamic aldehyde and 4.9% by mass of l-carvone , (b) as monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12, 9.0% by mass of linalool, 3.5% by mass of terpineol and 6.3% by mass of thymol, Furthermore, (c) as hydrocarbon esters having a total carbon number of 8 to 16, 11.7% by mass of benzyl benzoate, 8.4% by mass of benzyl acetate, 5.1% by mass of styralyl acetate, and other components was blended to prepare the ant repellent composition of the present invention. The (a)/(b) ratio in this ant repellent composition was 0.71/1.
30 mg of this ant-repellent composition was contained in a ring-shaped silicone rubber (1.6 g) as a carrier to obtain an ant-repellent product of the present invention in the form of a wristband.
When I put two of these wristbands around my ankles and went out for 8 to 12 hours, not only ants, but also various creeping pests such as woodlice and pill bugs, as well as mosquitoes, blackflies, wasps, midges, etc. Practical repellent effect was confirmed without being bothered by various flying pests, and even by mountain leeches.
本発明のアリ忌避組成物、及びこれを用いたアリ忌避製品は、アリ用だけでなく広範な害虫駆除を目的として利用することが可能である。 The ant-repellent composition of the present invention and ant-repellent products using the same can be used not only for ants but also for a wide range of pest control purposes.
Claims (3)
前記固形剤は、前記アリ忌避組成物を含有させた担持体からアリ忌避成分を空間に揮散させてアリに対する忌避効果を奏し得るようになしたものであり、
前記担持体は、プラスチック樹脂フィルム又は成形体、あるいはシリコーンゴム成形体であり、
前記アリ忌避組成物は、
アリ忌避成分として、（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを、（ａ）／（ｂ）＝０．１／１～１０／１の配合比率で含有し、
前記（ａ）総炭素数が８～１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類は、デカナール、ウンデカナール、ドデカナール、２－メチルウンデカナール、トリデカナール、１０－ウンデセナール、シトラール、シンナミックアルデヒド、α－アミルシンナミックアルデヒド、α－ヘキシルシンナミックアルデヒド、リリアール、ペリルアルデヒド、トリベルタール、クミンアルデヒド、ヘリオトロピン、ｌ－カルボン、メントン、プレゴン、α－ダマスコン、β－ダマスコン、δ－ダマスコン、２－ヘプチルシクロペンタノン、メチルベンジルケトン、又はメチルスチリルケトンであり、
前記（ｂ）総炭素数が８～１２のモノテルペン系アルコール類及び／又は芳香族アルコール類は、デヒドロリナロール、メントール、ボルネオール、１－フェニルエチルアルコール、又は２－フェニルエチルアルコールであり、
更に、アリ忌避成分として、（ｃ）総炭素数が８～１６の炭化水素エステル類から選ばれる１種又は２種以上を含有し、
前記（ｃ）総炭素数が８～１６の炭化水素エステル類は、メンチルアセテート、テルピニルアセテート、ネピルアセテート、フェニルエチルアセテート、スチラリルアセテート、シンナミルアセテート、シンナミルプロピオネート、アリルヘキサノエート、アリルヘプタノエート、メチルベンゾエート、エチルベンゾエート、３－ヘキセニルベンゾエート、ベンジルベンゾエート、メチルシンナメート、エチルシンナメート、メチルサリシネート、エチルサリシネート、アミルサリシネート、メチルジャスモネート、又はメチルジヒドロジャスモネートであるアリ忌避製品。 An ant repellent product prepared as a solid formulation using an ant repellent composition,
The solid agent is capable of volatilizing the ant-repellent component into space from the carrier containing the ant-repellent composition, thereby exerting an effect of repelling ants,
The carrier is a plastic resin film or molding, or a silicone rubber molding,
The ant repellent composition is
As the ant-repellent component, (a) one or more selected from hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) a substance having a total carbon number of 8 to 12 containing one or more selected from terpene alcohols and/or aromatic alcohols at a blending ratio of (a)/(b) = 0.1/1 to 10/1,
The (a) hydrocarbon aldehydes and/or hydrocarbon ketones having a total carbon number of 8 to 16 are decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, 10-undecenal, citral, and cinnamic aldehyde. , α-amyl cinnamic aldehyde, α-hexyl cinnamic aldehyde, lyrial, perillaldehyde, tribertal, cuminaldehyde, heliotropine, l-carvone, menthone, pulegone, α-damascone, β-damascone, δ-damascone, 2- heptylcyclopentanone, methylbenzyl ketone, or methylstyryl ketone,
The (b) monoterpene alcohols and/or aromatic alcohols having a total carbon number of 8 to 12 are dehydrolinalool, menthol, borneol, 1-phenylethyl alcohol, or 2-phenylethyl alcohol,
Furthermore, as an ant repellent component, (c) one or more selected from hydrocarbon esters having a total carbon number of 8 to 16,
The (c) hydrocarbon esters having a total of 8 to 16 carbon atoms include menthyl acetate, terpinyl acetate, nepyr acetate, phenylethyl acetate, styralyl acetate, cinnamyl acetate, cinnamyl propionate, allyl hexa noate, allylheptanoate, methylbenzoate, ethylbenzoate, 3-hexenylbenzoate, benzylbenzoate, methylcinnamate, ethylcinnamate, methylsalicinate, ethylsalicinate, amylsalicinate, methyljasmonate, Or an ant repellent product that is methyl dihydrojasmonate.
実質的に殺虫成分を含有しない請求項１に記載のアリ忌避製品。 The ant repellent composition is
2. The ant repellent product of claim 1, which is substantially free of insecticidal ingredients.
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| CN116569921B (en) * | 2023-07-05 | 2023-09-15 | 广东省林业科学研究院 | Application of menthyl acetate in repelling solenopsis invicta |
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| JP2019034906A (en) | 2019-03-07 |
| JP7365467B2 (en) | 2023-10-19 |
| JP6887342B2 (en) | 2021-06-16 |
| JP7117418B2 (en) | 2022-08-12 |
| JP2021121607A (en) | 2021-08-26 |
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