JP2019034906A - Ant repellent composition, and ant repellent product using the same - Google Patents
Ant repellent composition, and ant repellent product using the same Download PDFInfo
- Publication number
- JP2019034906A JP2019034906A JP2017157759A JP2017157759A JP2019034906A JP 2019034906 A JP2019034906 A JP 2019034906A JP 2017157759 A JP2017157759 A JP 2017157759A JP 2017157759 A JP2017157759 A JP 2017157759A JP 2019034906 A JP2019034906 A JP 2019034906A
- Authority
- JP
- Japan
- Prior art keywords
- ant
- ant repellent
- acetate
- repellent
- repellent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005871 repellent Substances 0.000 title claims abstract description 155
- 230000002940 repellent Effects 0.000 title claims abstract description 155
- 239000000203 mixture Substances 0.000 title claims abstract description 66
- -1 hydrocarbon aldehydes Chemical class 0.000 claims abstract description 75
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 31
- 230000000694 effects Effects 0.000 claims abstract description 31
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 8
- 229930003658 monoterpene Natural products 0.000 claims abstract description 8
- 235000002577 monoterpenes Nutrition 0.000 claims abstract description 8
- 241000517830 Solenopsis geminata Species 0.000 claims abstract description 5
- 241000257303 Hymenoptera Species 0.000 claims description 53
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 20
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims description 9
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- 239000004945 silicone rubber Substances 0.000 claims description 9
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- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims description 6
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- WTWBUQJHJGUZCY-UHFFFAOYSA-N cuminaldehyde Chemical compound CC(C)C1=CC=C(C=O)C=C1 WTWBUQJHJGUZCY-UHFFFAOYSA-N 0.000 claims description 6
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 claims description 6
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims description 6
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 6
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- 239000000088 plastic resin Substances 0.000 claims description 6
- CYIFVRUOHKNECG-UHFFFAOYSA-N tridecan-2-one Chemical compound CCCCCCCCCCCC(C)=O CYIFVRUOHKNECG-UHFFFAOYSA-N 0.000 claims description 6
- BGEHHAVMRVXCGR-UHFFFAOYSA-N tridecanal Chemical compound CCCCCCCCCCCCC=O BGEHHAVMRVXCGR-UHFFFAOYSA-N 0.000 claims description 6
- KMPQYAYAQWNLME-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 claims description 6
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
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- 229960002903 benzyl benzoate Drugs 0.000 claims description 4
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Natural products CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 claims description 4
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- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 4
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 claims description 4
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- 229960000790 thymol Drugs 0.000 claims description 4
- SFEOKXHPFMOVRM-UHFFFAOYSA-N (+)-(S)-gamma-ionone Natural products CC(=O)C=CC1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-UHFFFAOYSA-N 0.000 claims description 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims description 3
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 claims description 3
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 claims description 3
- 239000001871 (1R,2R,5S)-5-methyl-2-prop-1-en-2-ylcyclohexan-1-ol Substances 0.000 claims description 3
- SDOFMBGMRVAJNF-KVTDHHQDSA-N (2r,3r,4r,5r)-6-aminohexane-1,2,3,4,5-pentol Chemical compound NC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SDOFMBGMRVAJNF-KVTDHHQDSA-N 0.000 claims description 3
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- OFHHDSQXFXLTKC-UHFFFAOYSA-N 10-undecenal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 claims description 3
- SJWKGDGUQTWDRV-UHFFFAOYSA-N 2-Propenyl heptanoate Chemical compound CCCCCCC(=O)OCC=C SJWKGDGUQTWDRV-UHFFFAOYSA-N 0.000 claims description 3
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- NFAVNWJJYQAGNB-UHFFFAOYSA-N 2-methylundecanal Chemical compound CCCCCCCCCC(C)C=O NFAVNWJJYQAGNB-UHFFFAOYSA-N 0.000 claims description 3
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- XHXUANMFYXWVNG-UHFFFAOYSA-N D-menthyl acetate Natural products CC(C)C1CCC(C)CC1OC(C)=O XHXUANMFYXWVNG-UHFFFAOYSA-N 0.000 claims description 3
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A90/00—Technologies having an indirect contribution to adaptation to climate change
- Y02A90/40—Monitoring or fighting invasive species
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
Description
本発明は、アリ忌避組成物、及びこれを用いたアリ忌避製品に関するものである。 The present invention relates to an ant repellent composition and an ant repellent product using the same.
近年、屋外から家屋内に侵入するアリ類の被害や苦情が増加し、アリ類は重要な不快害虫の一つにあげられている。また、最近、特定外来生物に指定されている「ヒアリ」や「カミアリ」が日本数箇所で発見され社会問題になっているが、この種のアリは強い毒を持ち、繁殖力が高いことから速やかな侵入防止対策が求められている。従来、これらアリ類の防除方法としては、殺虫成分を含有する液剤やエアゾールを散布したり、ベイト剤を喫食させて巣に持ち帰らせ巣ごと退治する、いわゆる駆除が主体であった。
しかしながら、アリ類は、家屋内に侵入したり、危害を与えたりしなければ必ずしも駆除の必要がないとの声も聞かれる。更に、特定外来生物であるアリを駆除するために殺虫剤を多用すれば在来アリも殺してしまうことの問題点も指摘されている。このため、アリ類を駆除するのではなく、家屋の入り口や周辺等に予めアリ忌避剤を施用してアリ類を近づけない方法も模索されているのが現状である。
In recent years, the damage and complaints of ants entering the house from the outside have increased, and ants are listed as one of the important unpleasant insects. Recently, "hiari" and "kamimi", which have been designated as specific alien species, have been found in several places in Japan and have become a social problem, but this type of ant has a strong poison and high fertility. Prompt measures against intrusion are required. Conventionally, as a method for controlling these ants, so-called extermination was mainly performed by spraying a liquid agent or aerosol containing an insecticidal component, or eating a bait agent, bringing it back to the nest and extinguishing the nest.
However, it is heard that ants do not necessarily need to be removed unless they enter the house or cause harm. Furthermore, it has been pointed out that if a lot of insecticides are used to control ants that are specific exotic organisms, they also kill native ants. For this reason, the present condition is exploring the method of not applying an ant repellent to the entrance of a house, the circumference | surroundings, etc. in advance, but keeping an ant close, instead of exterminating an ant.
例えば、特許第３８４８４１２号公報（特許文献１）には、天然精油であるオークモス、サンダルウッド油、スペアミント油、タイムホワイト油、バチョウリ油、ガーリック油、シナモンリーフ油、タイムレッド油、ペルーバルサムバルサムの１種又は２種以上を有効成分として含有するアリ類の忌避剤が記載されている。この忌避剤は、天然精油を使用するため安全性が高く屋内でも問題なく使用でき空間忌避効果も奏するとしているが、その忌避効果は十分とは言えない。
また、特許第５８４０４７７号公報（特許文献２）は、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、テトラヒドロゲラニオール、フェネチルイソアミルエーテル、ジヒドロインデニル−２，４−ジオキサン、マグノラン、及びルバフランから選ばれる１種又は２種以上をアリ忌避成分として含有するアリ防除剤を開示する。このアリ防除剤は、アリ忌避成分として比較的揮散性の低い香料成分を使用し、家屋の入り口や周辺等に施用するような場面では、１週間以上にわたりクロヤマアリ、アミメアリ等の在来アリ類を忌避させることができる反面、即効的な空間忌避効果を目的とするものではなかった。
このように、今般問題となっているヒアリやカミアリ等の特定外来生物に指定されているアリを含め、アリ類に対して十分実用的な空間忌避効果を奏するアリ忌避組成物、及びこれを用いたアリ忌避製品は未だ得られていないのが現状である。
For example, Japanese Patent No. 3848412 (Patent Document 1) includes natural oils such as oak moss, sandalwood oil, spearmint oil, thyme white oil, butterfly oil, garlic oil, cinnamon leaf oil, thyme red oil, Peruvian sam balsam. An ant repellent containing one or more active ingredients is described. Although this repellent uses natural essential oil, it is safe and can be used without problems even indoors, and has a space repellent effect, but the repellent effect is not sufficient.
Japanese Patent No. 5840477 (Patent Document 2) discloses tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, tetrahydrogeraniol, phenethyl isoamyl ether, dihydroindenyl- An ant control agent containing one or more selected from 2,4-dioxane, magnolan, and rubafuran as an ant repellent component is disclosed. This ant control agent uses a fragrance ingredient with relatively low volatility as an ant repellent ingredient, and in the scene where it is applied to the entrance of the house or the surrounding area, it is necessary to remove the conventional ants such as black ants and red ants for more than a week. Although it can be avoided, it was not intended for an immediate space-repelling effect.
Thus, the ant repellent composition that exhibits a sufficiently practical space repellent effect on ants, including ants designated as specific alien organisms such as fire ants and crabs, which are currently a problem, and the use thereof The present condition is that the ant repellent product which has been not yet obtained.
本発明は、アリ類、特にヒアリやカミアリ等の特定外来生物に指定されているアリに対する空間忌避効果が高いアリ忌避組成物、及びこれを用いたアリ忌避製品を提供することを目的とする。 An object of the present invention is to provide an ant repellent composition having a high space repellent effect on ants, particularly ants designated as specific alien organisms such as fire ants and ants, and an ant repellent product using the same.
本発明は、以下の構成が上記目的を達成するために優れた効果を奏することを見出したものである。
（１）アリ忌避成分として、（ａ）総炭素数が８〜１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８〜１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを、（ａ）／（ｂ）＝０．１／１〜１０／1の配合比率で含有するアリ忌避組成物。
（２）前記（ａ）総炭素数が８〜１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類は、デカナール、ウンデカナール、ドデカナール、２−メチルウンデカナール、トリデカナール、１０−ウンデセナール、シトラール、ネラール、フェニルアセトアルデヒド、シンナミックアルデヒド、α−アミルシンナミックアルデヒド、α−ヘキシルシンナミックアルデヒド、リリアール、ペリルアルデヒド、トリベルタール、クミンアルデヒド、ヘリオトロピン、トリデカノン、ｌ-カルボン、メントン、プレゴン、シス−ジャスモン、ジヒドロジャスモン、α−ダマスコン、β−ダマスコン、δ−ダマスコン、α−イオノン、β−イオノン、２−ペンチルシクロペンタノン、２−ヘキシルシクロペンタノン、２−ヘプチルシクロペンタノン、メチルベンジルケトン、メチルスチリルケトンであり、
前記（ｂ）総炭素数が８〜１２のモノテルペン系アルコール類及び／又は芳香族アルコール類は、リナロール、デヒドロリナロール、ゲラニオール、ネロール、シトロネロール、メントール、テルピネオール、テルピネン−４−オール、イソプレゴール、ボルネオール、１−フェニルエチルアルコール、２−フェニルエチルアルコール、チモール、オイゲノールである（１）に記載のアリ忌避組成物。
（３）アリ忌避成分として、（ｃ）総炭素数が８〜１６の炭化水素エステル類から選ばれる１種又は２種以上を更に含有する（１）又は（２）に記載のアリ忌避組成物。
（４）前記（ｃ）総炭素数が８〜１６の炭化水素エステル類は、デシルアセテート、リナリルアセテート、ゲラニルアセテート、シトロネリルアセテート、メンチルアセテート、テルピニルアセテート、ネピルアセテート、ｐ−ｔ-ブチルシクロヘキシルアセテート、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、フェニルエチルアセテート、スチラリルアセテート、シンナミルアセテート、シンナミルプロピオネート、アリルヘキサノエート、アリルヘプタノエート、メチルベンゾエート、エチルベンゾエート、３−ヘキセニルベンゾエート、ベンジルベンゾエート、メチルシンナメート、エチルシンナメート、メチルサリシネート、エチルサリシネート、アミルサリシネート、メチルジャスモネート、メチルジヒドロジャスモネートである（３）に記載のアリ忌避組成物。
（５）更に、アリ忌避増強成分として、ディート、イカリジン、及びブチルアセチルアミノプロピオン酸エチル（以下、ＩＲ３５３５と略す）から選ばれる１種又は２種以上を含有する（１）ないし（４）のいずれか１に記載のアリ忌避組成物。
（６）実質的に殺虫成分を含有しない（１）ないし（５）のいずれか１に記載のアリ忌避組成物。
（７）前記アリは、ヒアリ又はカミアリである（１）ないし（６）のいずれか１に記載のアリ忌避組成物。
（８）（１）ないし（７）のいずれか１に記載のアリ忌避組成物を用い、液状製剤又は固形剤に調製してなるアリ忌避製品。
（９）前記固形剤は、前記アリ忌避組成物を含有させた担持体からアリ忌避成分を空間に揮散させてアリに対する忌避効果を奏し得るようになしたものである（８）に記載のアリ忌避製品。
（１０）前記担持体は、プラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体である（９）に記載のアリ忌避製品。
（１１）前記アリは、ヒアリ又はカミアリである（８）ないし（１０）のいずれか１に記載のアリ忌避製品。
The present invention has been found that the following constitution has an excellent effect for achieving the above-mentioned object.
(1) As an ant repellent component, (a) one or more selected from hydrocarbon aldehydes and / or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) a total carbon number of 8 to Ali containing one or more selected from 12 monoterpene alcohols and / or aromatic alcohols at a blending ratio of (a) / (b) = 0.1 / 1 to 10/1 Repellent composition.
(2) The hydrocarbon aldehydes and / or hydrocarbon ketones having a total carbon number of 8 to 16 are decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, 10-undecenal, citral, Neral, phenylacetaldehyde, cinnamic aldehyde, α-amylcinnamic aldehyde, α-hexylcinnamic aldehyde, lyial, perylaldehyde, trivertal, cuminaldehyde, heliotropin, tridecanone, l-carvone, menthone, plegon, cis-jasmon, Dihydrojasmon, α-damascon, β-damascon, δ-damascon, α-ionone, β-ionone, 2-pentylcyclopentanone, 2-hexylcyclopentanone, 2-heptylcyclopentanone, methyl Njiruketon, methyl styryl ketone,
The (b) monoterpene alcohols and / or aromatic alcohols having a total carbon number of 8 to 12 are linalool, dehydrolinalol, geraniol, nerol, citronellol, menthol, terpineol, terpinen-4-ol, isopulegol, borneol. The ant repellent composition according to (1), which is 1-phenylethyl alcohol, 2-phenylethyl alcohol, thymol, eugenol.
(3) The ant repellent composition according to (1) or (2), further comprising (c) one or more selected from hydrocarbon esters having a total carbon number of 8 to 16 as an ant repellent component .
(4) The hydrocarbon ester (c) having 8 to 16 carbon atoms in total is decyl acetate, linalyl acetate, geranyl acetate, citronellyl acetate, menthyl acetate, terpinyl acetate, nepyrucetate, pt- Butylcyclohexyl acetate, tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, phenylethyl acetate, styryl acetate, cinnamyl acetate, cinnamyl propionate, allyl hexano Ate, allyl heptanoate, methyl benzoate, ethyl benzoate, 3-hexenyl benzoate, benzyl benzoate, methyl cinnamate, ethyl cinnamate, methyl salicinate, ethyl salicinate, amyl salicinate, The ant repellent composition according to (3), which is methyl jasmonate or methyl dihydrojasmonate.
(5) In addition, any one of (1) to (4) containing at least one selected from diet, icaridin, and ethyl butylacetylaminopropionate (hereinafter abbreviated as IR3535) as an ant repellent enhancement component The ant repellent composition according to claim 1.
(6) The ant repellent composition according to any one of (1) to (5), which contains substantially no insecticidal component.
(7) The ant repellent composition according to any one of (1) to (6), wherein the ant is a fire ant or a ant.
(8) An ant repellent product prepared by using the ant repellent composition according to any one of (1) to (7) to prepare a liquid preparation or a solid preparation.
(9) The ant according to (8), wherein the solid agent is configured so that an ant repellent component is volatilized from a carrier containing the ant repellent composition into a space to exert a repellent effect on the ant. Repellent product.
(10) The ant repellent product according to (9), wherein the carrier is a plastic resin film, a molded body, or a silicone rubber molded body.
(11) The ant repellent product according to any one of (8) to (10), wherein the ant is a fire ant or a ant.
本発明のアリ忌避組成物は、特定のアリ忌避成分を含有し、アリ類、特にヒアリやカミアリ等の特定外来生物であるアリに対する空間忌避効果に優れるので極めて実用性が高い。従って、このアリ忌避組成物を用いた本発明のアリ忌避製品も非常に有用なものである。 The ant repellent composition of the present invention contains a specific ant repellent component and is highly practical because it is excellent in the space repellent effect on ants, particularly ants that are specific alien organisms such as fire ants and ants. Therefore, the ant repellent product of the present invention using this ant repellent composition is also very useful.
本発明のアリ忌避組成物は、アリ忌避成分として、（ａ）総炭素数が８〜１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８〜１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを、（ａ）／（ｂ）＝０．１／１〜１０／1の配合比率で含有することを特徴とする。 The ant repellent composition of the present invention comprises, as an ant repellent component, (a) one or more selected from hydrocarbon aldehydes and / or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) One or more selected from monoterpene alcohols and / or aromatic alcohols having a total carbon number of 8 to 12, (a) / (b) = 0.1 / 1 to 10/1 It contains by the mixture ratio, It is characterized by the above-mentioned.
前記（ａ）総炭素数が８〜１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類の具体例としては、例えば、デカナール、ウンデカナール、ドデカナール、２−メチルウンデカナール、トリデカナール、１０−ウンデセナール、シトラール、ネラール、フェニルアセトアルデヒド、シンナミックアルデヒド、α−アミルシンナミックアルデヒド、α−ヘキシルシンナミックアルデヒド、リリアール、ペリルアルデヒド、トリベルタール、クミンアルデヒド、ヘリオトロピン、トリデカノン、ｌ-カルボン、メントン、プレゴン、シス−ジャスモン、ジヒドロジャスモン、α−ダマスコン、β−ダマスコン、δ−ダマスコン、α−イオノン、β−イオノン、２−ペンチルシクロペンタノン、２−ヘキシルシクロペンタノン、２−ヘプチルシクロペンタノン、メチルベンジルケトン、メチルスチリルケトンがあげられる。 Specific examples of the (a) hydrocarbon aldehydes having 8 to 16 carbon atoms and / or hydrocarbon ketones include, for example, decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, 10-undecenal. , Citral, neral, phenylacetaldehyde, cinnamic aldehyde, α-amylcinnamic aldehyde, α-hexylcinnamic aldehyde, lyial, perylaldehyde, trivertal, cuminaldehyde, heliotropin, tridecanone, l-carvone, menthone, pregon, cis -Jasmon, dihydrojasmon, α-damascon, β-damascon, δ-damascon, α-ionone, β-ionone, 2-pentylcyclopentanone, 2-hexylcyclopentanone, 2-heptylcyclope Thanong, methylbenzyl ketone, methyl styryl ketone.
一方、前記（ｂ）総炭素数が８〜１２のモノテルペン系アルコール類及び／又は芳香族アルコール類の具体例としては、例えば、リナロール、デヒドロリナロール、ゲラニオール、ネロール、シトロネロール、メントール、テルピネオール、テルピネン−４−オール、イソプレゴール、ボルネオール、１−フェニルエチルアルコール、２−フェニルエチルアルコール、チモール、オイゲノールがあげられる。 On the other hand, specific examples of the (b) monoterpene alcohols having 8 to 12 carbon atoms and / or aromatic alcohols include, for example, linalool, dehydrolinalol, geraniol, nerol, citronellol, menthol, terpineol, and terpinene. Examples include -4-ol, isopulegol, borneol, 1-phenylethyl alcohol, 2-phenylethyl alcohol, thymol, and eugenol.
本発明では、（ａ）総炭素数が８〜１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種又は２種以上と、（ｂ）総炭素数が８〜１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種又は２種以上とを併用する必要がある。そして、本発明者らの検討結果によれば、（ａ）／（ｂ）の配合比率が０．１／１〜１０／1の範囲において、アリ類、特にヒアリやカミアリ等の特定外来生物であるアリに対し相乗的に高い空間忌避効果を奏することが認められた。（ａ）／（ｂ）の配合比率がこの範囲を外れると相乗効果が得られず併用するメリットはない。 In the present invention, (a) one or more selected from hydrocarbon aldehydes and / or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) a monoterpene having a total carbon number of 8 to 12 It is necessary to use together 1 type, or 2 or more types chosen from system alcohol and / or aromatic alcohol. And according to the examination results of the present inventors, in the range where the blending ratio of (a) / (b) is 0.1 / 1 to 10/1, ants, in particular exotic organisms such as fire ants and ants, Synergistically high spatial repellent effect was observed against an ant. If the blending ratio of (a) / (b) is outside this range, a synergistic effect cannot be obtained and there is no merit to use in combination.
本発明のアリ忌避組成物は、アリ忌避成分として、（ｃ）総炭素数が８〜１６の炭化水素エステル類から選ばれる１種又は２種以上を更に含有するのが好ましい。このような炭化水素エステル類は、アリ忌避効果の増強に寄与し得るものであり、具体例としては、例えば、デシルアセテート、リナリルアセテート、ゲラニルアセテート、シトロネリルアセテート、メンチルアセテート、テルピニルアセテート、ネピルアセテート、ｐ−ｔ-ブチルシクロヘキシルアセテート、トリシクロデセニルアセテート、トリシクロデセニルプロピオネート、トリシクロデセニルイソブチレート、フェニルエチルアセテート、スチラリルアセテート、シンナミルアセテート、シンナミルプロピオネート、アリルヘキサノエート、アリルヘプタノエート、メチルベンゾエート、エチルベンゾエート、３−ヘキセニルベンゾエート、ベンジルベンゾエート、メチルシンナメート、エチルシンナメート、メチルサリシネート、エチルサリシネート、アミルサリシネート、メチルジャスモネート、メチルジヒドロジャスモネートがあげられるが、これらに限定されない。 The ant repellent composition of the present invention preferably further contains, as an ant repellent component, (c) one or more selected from hydrocarbon esters having a total carbon number of 8 to 16. Such hydrocarbon esters can contribute to the enhancement of ant repellent effect, and specific examples include, for example, decyl acetate, linalyl acetate, geranyl acetate, citronellyl acetate, menthyl acetate, terpinyl acetate, Nepylacetate, pt-butylcyclohexyl acetate, tricyclodecenyl acetate, tricyclodecenyl propionate, tricyclodecenyl isobutyrate, phenylethyl acetate, styryl acetate, cinnamyl acetate, cinna Milpropionate, allyl hexanoate, allyl heptanoate, methyl benzoate, ethyl benzoate, 3-hexenyl benzoate, benzyl benzoate, methyl cinnamate, ethyl cinnamate, methyl salicinate, Examples include, but are not limited to, ethyl salicinate, amyl salicinate, methyl jasmonate, and methyl dihydrojasmonate.
本発明のアリ忌避組成物には、上記以外の香料成分、例えば、ｄ−リモネン、α−ピネン、β−ピネン等の炭化水素類、イソアミルフェニルエチルエーテル、リナロールオキサイド、１，８−シネオール、ローズオキサイド、ジフェニルエーテル、マグノラン、ルバフラン、ジヒドロインデニル−２，４−ジオキサン等の炭化水素エーテル類、２，６−ジメチル−３−エチルピラジン、シトロネリルニトリル、ステモン、ｏ−アミノアセトフェノン等の含窒素化合物類等を配合しても構わない。また、サンダルウッド油、スペアミント油、タイムホワイト油、バチョウリ油、ガーリック油、シナモンリーフ油、タイムレッド油、ジャスミン油、ネロリ油、ベルガモット油、オレンジ油、ゼラニウム油、プチグレン油、レモン油、レモングラス油、シナモン油、ユーカリ油等の精油類も適宜配合可能である。
なお、本発明においては、精油として配合されたとしても、前記アリ忌避成分が精油中に５質量％以上含まれる場合、個々のアリ忌避成分として配合されたものと定義する。
The ant repellent composition of the present invention includes perfume ingredients other than those described above, for example, hydrocarbons such as d-limonene, α-pinene and β-pinene, isoamylphenylethyl ether, linalool oxide, 1,8-cineole and rose. Hydrocarbon ethers such as oxide, diphenyl ether, magnolan, rubafuran, dihydroindenyl-2,4-dioxane, nitrogen-containing compounds such as 2,6-dimethyl-3-ethylpyrazine, citronellylnitrile, stemon, o-aminoacetophenone You may mix | blend. Also, sandalwood oil, spearmint oil, thyme white oil, butterfly oil, garlic oil, cinnamon leaf oil, thyme red oil, jasmine oil, neroli oil, bergamot oil, orange oil, geranium oil, petit glen oil, lemon oil, lemongrass Essential oils such as oil, cinnamon oil, and eucalyptus oil can be appropriately blended.
In addition, in this invention, even if it mix | blends as essential oil, when the said ant repellent component is contained in 5% by mass or more in essential oil, it defines as what was mix | blended as each ant repellent component.
本発明のアリ忌避組成物には、アリ忌避成分の揮散後の忌避効果持続成分として、２０℃における蒸気圧が０．２〜２０Ｐａのグリコール類及び／又はグリコールエーテル類の１種又は２種以上を配合してもよい。このようなグリコール類及び／又はグリコールエーテル類は、溶剤としてのみならず、アリ忌避成分に対して特異的に忌避効果の持続作用を奏し得ることを初めて知見したものである。
その具体的代表例（２０℃における蒸気圧を併記）としては、プロピレングリコール（１０．７Ｐａ）、ジプロピレングリコール（１．３Ｐａ）、トリプロピレングリコール（０．６７Ｐａ）、ジエチレングリコール（３Ｐａ）、トリエチレングリコール（１Ｐａ）、１，３−ブチレングリコール、ヘキシレングリコール（６．７Ｐａ）、ベンジルグリコール（２．７Ｐａ）、ジエチレングリコールモノブチルエーテル（３Ｐａ）、ジプロピレングリコールモノブチルエーテル、及びトリプロピレングリコールモノメチルエーテルがあげられ、なかんずく、ジプロピレングリコールが本発明の目的に合致する。
なお、忌避効果持続成分の配合量としては、前記アリ忌避成分の０．２〜１０倍程度が適当である。
In the ant repellent composition of the present invention, one or more of glycols and / or glycol ethers having a vapor pressure of 0.2 to 20 Pa at 20 ° C. as a repellent effect sustained component after volatilization of the ant repellent component May be blended. It has been found for the first time that such glycols and / or glycol ethers can not only serve as a solvent but also have a repellent effect-specific action on ant repellent components.
Specific examples thereof (including vapor pressure at 20 ° C.) include propylene glycol (10.7 Pa), dipropylene glycol (1.3 Pa), tripropylene glycol (0.67 Pa), diethylene glycol (3 Pa), and triethylene. Glycol (1 Pa), 1,3-butylene glycol, hexylene glycol (6.7 Pa), benzyl glycol (2.7 Pa), diethylene glycol monobutyl ether (3 Pa), dipropylene glycol monobutyl ether, and tripropylene glycol monomethyl ether In particular, dipropylene glycol meets the objectives of the present invention.
In addition, as a compounding quantity of a repellent effect sustained component, about 0.2 to 10 times the said ant repellent component is suitable.
本発明では、前記各種成分に、本発明の効果に支障を来たさない限りにおいて、例えば、蚊に対する忌避成分、殺虫成分、消臭成分、除菌・抗菌成分等の他の機能性成分を配合してアリ忌避組成物を構成してもよい。
かかる機能性成分のうち、蚊に対する忌避成分であるディート、イカリジン、ＩＲ３５３５は、アリ忌避成分と混用することによってそのアリ忌避効果を増強させ得ることが認められた。一方、殺虫成分としては、常温揮散性ピレスロイド系のエムペントリン、トランスフルトリン、メトフルトリン、プロフルトリン等が好適な代表例としてあげられるが、本発明の趣旨に照らし、配合するとしても極力微量に留めるのが好ましい。また、消臭成分としては、イネ科、ツバキ科、イチョウ科、モクセイ科、クワ科、ミカン科、キントラノオ科、カキノキ科の中から選ばれる植物抽出物が代表的である。更に、「緑の香り」と呼ばれる青葉アルコールや青葉アルデヒド等を添加してリラックス効果を付与することもできる。
なお、アリ忌避組成物を、例えば、マイクロカプセル化したり、サイクロデキストリン化して当該組成物の安定化を図ったり、アリ忌避成分の揮散性を調節することも可能である。
In the present invention, other functional components such as mosquito repellent components, insecticidal components, deodorizing components, antibacterial / antibacterial components, and the like are included in the various components as long as they do not hinder the effects of the present invention. You may mix | blend and may comprise an ant repellent composition.
Among such functional components, it has been recognized that diet, ikalizine, and IR3535, which are repellent components against mosquitoes, can enhance the ant repellent effect when mixed with ant repellent components. On the other hand, room temperature volatile pyrethroids such as empentrin, transfluthrin, methfluthrin, profluthrin and the like are preferable representative examples. However, in light of the gist of the present invention, the amount of the insecticidal component should be kept as small as possible. preferable. Moreover, as a deodorant component, the plant extract chosen from the gramineae, camelliaceae, ginkgoceae, oleaceae, mulberry, citrus, quintranoaceae, and oysteraceae is typical. Furthermore, green leaf alcohol or green leaf aldehyde called “green fragrance” can be added to give a relaxing effect.
The ant repellent composition can be, for example, microencapsulated or cyclodextrin to stabilize the composition, and the volatility of the ant repellent component can be adjusted.
こうして得られた本発明のアリ忌避組成物は、そのまま若しくは希釈して使用することもできるが、通常、これを用いて種々剤型のアリ忌避製品を調製する。
その剤型としては、スプレーの形態で用いられる液剤、乳剤、水溶剤、マイクロエマルジョンやエアゾール等の液状製剤と、粉剤、粒剤、ベイト剤等の固形剤があげられる。そして、かかるアリ忌避製品を製するにあたっては、必要に応じ、溶剤、界面活性剤、可溶化剤、ゲル化剤、分散剤、安定化剤、ｐＨ調整剤、着色剤等を適宜配合してもよい。
The ant repellent composition of the present invention thus obtained can be used as it is or after being diluted, but usually, ant repellent products of various dosage forms are prepared using this composition.
Examples of the dosage form include liquid preparations such as liquids, emulsions, aqueous solvents, microemulsions and aerosols used in the form of sprays, and solid preparations such as powders, granules and baits. And in manufacturing such an ant repellent product, a solvent, a surfactant, a solubilizer, a gelling agent, a dispersant, a stabilizer, a pH adjuster, a colorant, etc. may be appropriately blended as necessary. Good.
アリ忌避製品の調製に用いる溶剤としては、例えば、水、エタノール、イソプロパノール等の低級アルコール、ケトン系溶剤、エステル系溶剤、ノルマルパラフィンやイソパラフィン等の炭化水素系溶剤等があげられる。
界面活性剤としては、例えば、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレン高級アルキルエーテル類（ポリオキシエチレンラウリルエーテル、ポリオキシエチレンオレイルエーテル等）、ポリオキシエチレンアルキルフェニルエーテル類、ポリオキシエチレン高級脂肪酸エステル類、ポリオキシエチレンソルビタン脂肪酸エステル類、ポリオキシエチレングリセリン脂肪酸エステル類、ポリオキシエチレンポリオキシプロピレンアルキルエーテル等の非イオン系界面活性剤や、ラウリルアミンオキサイド、ステアリルアミンオキサイド、ラウリル酸アミドプロピルジメチルアミンオキサイド等の高級アルキルアミンオキサイド系界面活性剤を例示することができる。
また、ゲル化剤としては、ポリビニルアルコール、アルギン酸、カラギーナン等が適宜用いられる。
Examples of the solvent used for preparing the ant repellent product include water, lower alcohols such as ethanol and isopropanol, ketone solvents, ester solvents, hydrocarbon solvents such as normal paraffin and isoparaffin.
Examples of the surfactant include polyoxyethylene hydrogenated castor oil, polyoxyethylene higher alkyl ethers (polyoxyethylene lauryl ether, polyoxyethylene oleyl ether, etc.), polyoxyethylene alkylphenyl ethers, polyoxyethylene higher fatty acid. Nonionic surfactants such as esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene glycerin fatty acid esters, polyoxyethylene polyoxypropylene alkyl ether, laurylamine oxide, stearylamine oxide, amidopropyldimethyl laurate Examples thereof include higher alkyl amine oxide surfactants such as amine oxide.
As the gelling agent, polyvinyl alcohol, alginic acid, carrageenan and the like are appropriately used.
本発明のアリ忌避製品は、液状製剤よりも固形剤が好ましい。これは、使い易いこと、液漏れの心配がないことや薬液が手指に触れる危険性の少ないこと等のメリットが勘案されるためである。なかでも、アリ忌避組成物を担持体に含有させ、この担持体からアリ忌避成分を空間に揮散させる形態が好適に採用される。
ここで担持体としては、木粉、小麦粉等の各種植物質粉末、紙、織布、不織布等の基布、ビスコパール等の多孔質有機成形体、カオリン、タルク、炭酸カルシウム、珪石、珪砂、セラミックス等の無機担持体、ポリエチレン、ポリプロピレン、エチレン／酢酸ビニル共重合体（ＥＶＡ）、エチレン／メタクリル酸メチル共重合体（ＥＭＭＡ）、スチレン系ジブロックポリマー、スチレン系トリブロックポリマー、熱可塑性プラスチックエラストマー（ＴＰＥ、ＴＰＯ）等から構成されるプラスチック樹脂フィルム又は成形体、シリコーンゴム等があげられるが、これらに限定されない。
これらのうち、担持体としてプラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体を用いて調製した固形剤は、アリ類に対して効率的に優れた空間忌避効果を奏し、有用性が高いアリ忌避製品の一つである。
The ant repellent product of the present invention is preferably a solid agent rather than a liquid preparation. This is because merits such as ease of use, no risk of liquid leakage, and low risk of contact with the chemical liquid are taken into consideration. Especially, the form which makes an ant repellent composition contain in a support body and volatilizes an ant repellent component from this support body to a space is employ | adopted suitably.
Here, as the support, various vegetable powders such as wood flour, wheat flour, base fabrics such as paper, woven fabric and non-woven fabric, porous organic molded bodies such as viscopearl, kaolin, talc, calcium carbonate, silica stone, quartz sand, Inorganic supports such as ceramics, polyethylene, polypropylene, ethylene / vinyl acetate copolymer (EVA), ethylene / methyl methacrylate copolymer (EMMA), styrene diblock polymer, styrene triblock polymer, thermoplastic elastomer Examples thereof include, but are not limited to, a plastic resin film or molded body composed of (TPE, TPO) and the like, and silicone rubber.
Among these, the solid agent prepared using a plastic resin film or molded body, or a silicone rubber molded body as a carrier, has an excellent space repellent effect on ants and is highly useful. One of the products.
本発明のアリ忌避製品に含有されるアリ忌避組成物の配合量は、当該忌避製品の使用用途、使用期間、及びその仕様等によって適宜決定すればよいが、液状製剤の場合、０．０１〜２０ｗ／ｖ％、一方、固形剤の場合、０．０１〜１０ｗ／ｗ％程度が適当である。
なお、担持体にアリ忌避組成物を含有させる固形剤においては、１回あたり８〜１２時間使用の忌避製品の場合、アリ忌避組成物を担持体あたり１０〜５０ｍｇ、一方、１５〜３０日使用の忌避製品にあっては１００〜２０００ｍｇ程度含有させればよい。
The compounding amount of the ant repellent composition contained in the ant repellent product of the present invention may be determined as appropriate depending on the intended use, use period, and specifications of the repellent product. On the other hand, in the case of a solid preparation, about 0.01 to 10 w / w% is appropriate.
In the case of a solid preparation containing an ant repellent composition in a carrier, in the case of a repellent product used for 8 to 12 hours per time, the ant repellent composition is used in an amount of 10 to 50 mg per carrier, while it is used for 15 to 30 days. The repellent product may contain about 100 to 2000 mg.
本発明のアリ忌避製品を製造するに際しては何ら特別の技術を必要としない。
アリ忌避組成物を担持体に含有させるに際しても、必要に応じて溶剤や界面活性剤等を添加し、従来公知の方法を適宜採用することができる。例えば、担持体が不織布の場合、アリ忌避組成物を薬液分注方式や塗布方式によって担持させてもよいし、あるいはパラフィンワックスと共に包埋させるようにしても構わない。
また、プラスチック樹脂フィルム又は成形体、もしくはシリコーンゴム成形体等にこれを担持させるにあたっては、本発明のアリ忌避組成物が揮散性のため高温下での混合工程は避け、薬液分注方式や塗布方式を採用したり、アリ忌避組成物を必要に応じ溶剤と共に噴霧又は滴下して成形体に浸透させる方式が適当である。あるいは、高濃度にアリ忌避組成物を含有させたシリコーンゴム成形体と無処理のシリコーンゴム成形体を密閉容器中に混在させ、適当時間放置してシリコーンゴム成形体全体に亘ってアリ忌避組成物濃度を平均化させる方法によっても本発明のアリ忌避製品を製造可能である。
No special technique is required to produce the ant repellent product of the present invention.
When the ant repellent composition is contained in the carrier, a conventionally known method can be appropriately employed by adding a solvent, a surfactant or the like as necessary. For example, when the carrier is a nonwoven fabric, the ant repellent composition may be carried by a chemical liquid dispensing method or a coating method, or may be embedded with paraffin wax.
In addition, when carrying this on a plastic resin film or molded body, or a silicone rubber molded body, etc., the ant repellent composition of the present invention is volatilizable, so avoid the mixing step at high temperature, and use a chemical dispensing method or coating. A method that employs a method or a method in which an ant repellent composition is sprayed or dropped together with a solvent as required to penetrate into a molded article is appropriate. Alternatively, an ant repellent composition containing the ant repellent composition at a high concentration and an untreated silicone rubber molded body are mixed in a sealed container and left for an appropriate time to cover the entire silicone rubber molded body. The ant repellent product of the present invention can also be produced by a method of averaging the concentration.
こうして得られた本発明のアリ忌避製品は、その剤型に応じて様々な使用場面に適用される。アリ忌避製品が液剤、エアゾール剤、粉剤、粒剤のような製剤の場合、玄関、台所、トイレ、リビングルーム、寝室などの室内、倉庫、車中等や、ベランダ、ポーチ、庭先、家屋の周囲などに、所定量を散布したり載置したりして、アリ類が近づかない空間を形成することが可能である。その施用量としては、例えば、玄関まわりで液状製剤を使用する場合、１０〜５０ｍＬ／ｍ2、固形剤にあっては、１０〜５０ｇ／ｍ2程度が適当である。
一方、上記担持体がプラスチック樹脂成形体やシリコーンゴム成形体の場合、足バンドとして足首や靴等に巻装したり、当該成形体をクリップのような固定具で靴等に装着して使用すれば効果的であるし、また、担持体がシールのような場合、フィルム状担持体の下面に粘着層を設けズボンの下部や靴等に貼付して用いるのが便利である。
The ant repellent product of the present invention thus obtained is applied to various usage scenes depending on the dosage form. When the ant repellent product is a liquid, aerosol, powder, granule, etc., the entrance, kitchen, toilet, living room, bedroom, etc., warehouse, in the car, etc., around the veranda, porch, garden, house, etc. Moreover, it is possible to form a space where ants do not approach by spraying or placing a predetermined amount. As the application amount, for example, when using a liquid formulation around the entrance, 10-50 ml / m 2, In the solid agent, about 10 to 50 g / m 2 are suitable.
On the other hand, when the carrier is a plastic resin molded body or a silicone rubber molded body, it can be used by being wound around an ankle or shoes as a foot band, or by mounting the molded body on a shoe or the like with a fastener such as a clip. If the carrier is a seal, it is convenient to provide an adhesive layer on the lower surface of the film carrier and stick it to the lower part of trousers or shoes.
本発明のアリ忌避製品は、アリ類、具体的には、クロヤマアリ、アミメアリ、トビイロケアリ、トビイロシワアリ、ルリアリ、クロオオアリ、イエヒメアリ、アルゼンチンアリ等に対して実用的な空間忌避効果を示し、特にヒアリやカミアリ等の特定外来生物であるアリに対して効果的である。本発明者らの検討結果によれば、当該アリ忌避製品は、これらのアリによる刺咬被害を防止できるだけでなく、ハチ類、ヤマビル等にも忌避効果を示すことが認められた。しかも、実質的に殺虫成分を含有していない本製品は、殺虫剤の使用を嫌がる人にも手軽に使用できるのでその実用性は極めて高い。 The ant repellent product of the present invention exhibits a practical space repellent effect on ants, specifically, black ants, red ants, flying squirrels, white whale ants, rugliari, black ants, green ants, Argentine ants, etc., especially fire ants, ants, etc. It is effective against ants that are specific exotic organisms. According to the study results of the present inventors, it was confirmed that the ant repellent product not only prevents bite damage caused by these ants, but also exhibits a repellent effect on bees, yamavir, and the like. In addition, this product, which does not substantially contain an insecticidal component, can be easily used by those who dislike the use of insecticides, so its practicality is extremely high.
次に具体的な実施例に基づき、本発明のアリ忌避組成物、及びこれを用いたアリ忌避製品について更に詳細に説明するが、本発明はこれらに限定されるものではない。 Next, the ant repellent composition of the present invention and the ant repellent product using the same will be described in more detail based on specific examples, but the present invention is not limited thereto.
表１に示す供試アリ忌避組成物をアセトン１０ｍLに溶解して供試薬液を調製し、下記の忌避効力試験を実施した。
［忌避効力試験−１］
供試薬液０．５ｍＬを直径９ｃｍの濾紙に滴下し、風乾後この濾紙を半分に切断した。この半面と無処理濾紙の半面を重ならないように直径９ｃｍのガラスシャーレに置いた。ガラスシャーレの内壁にタルクを塗り、トビイロシワアリ５０匹又はヒアリ５０匹を放し、５分後、ならびに２時間後に処理面及び無処理面にいる虫数を数え、下式に従って忌避率を求めた。結果を表２に示す。
忌避率＝［(無処理面の侵入虫数−処理面の侵入虫数)／供試虫数×１００］
The test ant repellent composition shown in Table 1 was dissolved in 10 mL of acetone to prepare a reagent solution, and the following repellent efficacy test was performed.
[Repellent efficacy test-1]
The reagent solution 0.5 mL was dropped onto a filter paper having a diameter of 9 cm, and after air drying, the filter paper was cut in half. This half and the untreated filter paper were placed on a glass petri dish having a diameter of 9 cm so as not to overlap. Talc was applied to the inner wall of the glass petri dish, 50 flying ants or 50 fire ants were released, the number of insects on the treated surface and untreated surface was counted after 5 minutes and 2 hours, and the repelling rate was determined according to the following formula. The results are shown in Table 2.
Repellent rate = [(number of invading insects on untreated surface−number of invading insects on treated surface) / number of insects to be tested × 100]
試験の結果、アリ忌避成分として、（ａ）総炭素数が８〜１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類から選ばれる１種と、（ｂ）総炭素数が８〜１２のモノテルペン系アルコール類及び／又は芳香族アルコール類から選ばれる１種とを、（ａ）／（ｂ）＝０．１／１〜１０／1の配合比率で含有する本発明のアリ忌避組成物は、トビイロシワアリのような在来アリはもちろん、特定外来生物であるヒアリに対しても同等以上のアリ忌避効果を示すことが確認された。なお、本発明５、本発明６、本発明１２及び本発明１３のように、（ａ）及び（ｂ）のアリ忌避成分に、更に（ｃ）総炭素数が８〜１６の炭化水素エステル類や人体用の蚊忌避剤であるＩＲ３５３５やイカリジンを配合することによってアリ忌避効果が増強した。また、本発明７及び本発明１４が示す如く、ジプロピレングリコールやヘキシレングリコールの配合は、アリ忌避成分の忌避効果を持続させるうえで効果的であることが認められた。
これに対し、本発明が規定するアリ忌避組成物以外を用いた比較例では、アリ忌避効果が十分と言えないばかりか、ヒアリに対するアリ忌避効果はトビイロシワアリを対象とする場合よりも劣る傾向が認められた。
As a result of the test, as an ant repellent component, (a) one kind selected from hydrocarbon aldehydes and / or hydrocarbon ketones having a total carbon number of 8 to 16, and (b) monocyclic compounds having a total carbon number of 8 to 12 The ant repellent composition of the present invention containing one selected from terpene alcohols and / or aromatic alcohols at a blending ratio of (a) / (b) = 0.1 / 1 to 10/1 It has been confirmed that ant repellent effects are equivalent to or better than the native ants such as the white-winged ants, as well as the specific alien fire ants. In addition, as in the present invention 5, the present invention 6, the present invention 12 and the present invention 13, in addition to the ant repellent components of (a) and (b), (c) hydrocarbon esters having a total carbon number of 8 to 16 The ant repellent effect was enhanced by adding IR3535 and icaridin, which are mosquito repellents for humans and human bodies. Moreover, as this invention 7 and this invention 14 showed, it was recognized that the mixing | blending of dipropylene glycol and hexylene glycol is effective in maintaining the repellent effect of an ant repellent component.
On the other hand, in comparative examples using other than the ant repellent composition prescribed by the present invention, not only the ant repellent effect is sufficient, but the ant repellent effect against fire ants tends to be inferior to that of the case of the white whale ant. It was.
表３に示す供試アリ忌避組成物にｎ−パラフィン（ネオチオゾール）を加えエアゾール原液を調製した（アリ忌避組成物含量：エアゾール原液に対し２．０ｗ／ｖ％）。このエアゾール原液５０ｍＬをエアゾール容器に充填後、液化石油ガス（ＬＰＧ）５０ｍＬを加圧充填してエアゾール形態の本発明のアリ忌避製品を得た。このアリ忌避製品につき、下記の忌避効力試験を実施した。
［忌避効力試験−２］
２０ｃｍ角のタイルに供試アリ忌避製品を１ｍ２あたり２０ｍＬになるように滴下した。このタイルの中央に誘引剤として３％ショ糖水溶液を含浸させた脱脂綿を置き、在来アリ又は特定外来生物であるアリが生息する草むらに設置した。設置直後、及び設置３日後に、誘引剤に集まったアリを数え、アリ忌避効果を調べた。結果を表４に示す。
評価基準（集まったアリ数）；
０匹；◎、 １〜５匹；○〜◎、 ６〜１０匹；〇、 １１〜２０匹；△、
２１〜３０匹；×〜△、 ３１匹以上；×
An aerosol stock solution was prepared by adding n-paraffin (neothiozole) to the test ant repellent composition shown in Table 3 (content of ant repellent composition: 2.0 w / v% with respect to the aerosol stock solution). After 50 mL of this aerosol stock solution was filled into an aerosol container, 50 mL of liquefied petroleum gas (LPG) was pressurized and filled to obtain an ant repellent product of the present invention in the form of an aerosol. The following repellent efficacy test was performed on this ant repellent product.
[Repellent efficacy test-2]
The test ant repellent product was dropped on a 20 cm square tile so as to be 20 mL per 1 m 2 . Absorbent cotton impregnated with a 3% sucrose aqueous solution as an attractant was placed in the center of the tile, and placed on the grass that inhabited ants that are native or specific alien organisms. Immediately after the installation and 3 days after the installation, ants gathered in the attractant were counted, and the ant repellent effect was examined. The results are shown in Table 4.
Evaluation criteria (number of ants gathered);
0; ◎, 1 to 5; ○ to ◎, 6 to 10; 〇, 11 to 20;
21-30 animals; x- △, 31 or more animals; x
試験の結果、本発明のアリ忌避組成物を用いて調製したエアゾール形態のアリ忌避製品は、実施例１と同様、在来アリ及び特定外来生物であるアリのいずれに対しても優れたアリ忌避効果を示した。なお、ＩＲ３５３５の配合は忌避効果増強の点で有用であり、また、ジプロピレングリコールの配合は忌避効果の持続性向上に寄与することが認められた。
別途、本発明２１につき、勝手口や玄関のスペースに１ｍ２あたり約２０ｍＬ噴霧処理したところ、７日間にわたりアリ類の家屋内への侵入は見られなかった。また、処理した所から少し離れた場所に死亡したクロヤマアリやアミメアリが何個体か観察され、アリ忌避成分の忌避効果に加え、殺虫成分であるエムペントリンの作用が覗えた。
As a result of the test, the ant repellent product in the aerosol form prepared using the ant repellent composition of the present invention was superior to both the native ant and the ant that is a specific alien organism as in Example 1. Showed the effect. In addition, it was recognized that the blending of IR3535 is useful in terms of enhancing the repellent effect, and that the blending of dipropylene glycol contributes to the improvement of the sustainability of the repellent effect.
Separately, according to the present invention 21, about 20 mL per 1 m 2 was sprayed on the doorway or entrance space, and no ants entered the house for 7 days. In addition, several black ants and red ants that died at a distance from the treated site were observed, and in addition to the repellent effect of the ant repellent component, the action of empentrin, an insecticidal component, was observed.
アリ忌避成分の（ａ）総炭素数が８〜１６の炭化水素アルデヒド類及び／又は炭化水素ケトン類として、α−ヘキシルシンナミックアルデヒドを８．５質量％とｌ−カルボンを４．９質量％、（ｂ）総炭素数が８〜１２のモノテルペン系アルコール類及び／又は芳香族アルコール類として、リナロールを９．０質量％、テルピネオールを３．５質量％とチモールを６．３質量％、更に（ｃ）総炭素数が８〜１６の炭化水素エステル類として、ベンジルベンゾエートを１１．７質量％、ベンジルアセテートを８．４質量％とスチラリルアセテートを５．１質量％、ならびにその他の成分を配合して本発明のアリ忌避組成物を調製した。なお、このアリ忌避組成物における（ａ）／（ｂ）比率は０．７１／１であった。
このアリ忌避組成物の３０ｍｇを、担持体としてのリング状シリコーンゴム（１．６ｇ）に含有させ、リストバンド形態の本発明のアリ忌避製品を得た。
このリストバンドを２本ずつ両足首に巻装して外出したところ、８〜１２時間にわたり、アリ類だけでなく、ワラジムシ、ダンゴムシ等の各種匍匐害虫や、蚊、ブユ、ハチ類、ユスリカ等の各種飛翔害虫、更にはヤマヒル等に煩わされることがなく、実用的な忌避効果が確認された。
As the ant repellent component (a) hydrocarbon aldehydes and / or hydrocarbon ketones having a total carbon number of 8 to 16, α-hexylcinnamic aldehyde is 8.5% by mass and l-carvone is 4.9% by mass. (B) As monoterpene alcohols and / or aromatic alcohols having a total carbon number of 8 to 12, linalool is 9.0% by mass, terpineol is 3.5% by mass, thymol is 6.3% by mass, Furthermore, (c) 11.7% by mass of benzyl benzoate, 8.4% by mass of benzyl acetate, 5.1% by mass of styryl acetate, and other components as hydrocarbon esters having 8 to 16 carbon atoms in total Was added to prepare an ant repellent composition of the present invention. In addition, (a) / (b) ratio in this ant repellent composition was 0.71 / 1.
30 mg of this ant repellent composition was contained in a ring-shaped silicone rubber (1.6 g) as a carrier to obtain an ant repellent product of the present invention in the form of a wristband.
When two wristbands were wrapped around both ankles and went out for 8 to 12 hours, not only ants, but also various insect pests such as warabimushi and dandelion, mosquitoes, flyfish, bees, chironomids, etc. A practical repellent effect was confirmed without being bothered by various flying pests and further Yamahill.
本発明のアリ忌避組成物、及びこれを用いたアリ忌避製品は、アリ用だけでなく広範な害虫駆除を目的として利用することが可能である。
The ant repellent composition and the ant repellent product using the ant repellent composition of the present invention can be used not only for ants but also for the purpose of controlling a wide range of pests.
Claims (11)
前記（ｂ）総炭素数が８〜１２のモノテルペン系アルコール類及び／又は芳香族アルコール類は、リナロール、デヒドロリナロール、ゲラニオール、ネロール、シトロネロール、メントール、テルピネオール、テルピネン−４−オール、イソプレゴール、ボルネオール、１−フェニルエチルアルコール、２−フェニルエチルアルコール、チモール、オイゲノールである請求項１に記載のアリ忌避組成物。 The hydrocarbon aldehydes and / or hydrocarbon ketones having a total carbon number of 8 to 16 are decanal, undecanal, dodecanal, 2-methylundecanal, tridecanal, 10-undecenal, citral, neral, phenyl. Acetaldehyde, cinnamic aldehyde, α-amylcinnamic aldehyde, α-hexylcinnamic aldehyde, lyial, perylaldehyde, trivertal, cuminaldehyde, heliotropin, tridecanone, l-carvone, menthone, pregon, cis-jasmon, dihydrojasmon, α-damascon, β-damascon, δ-damascon, α-ionone, β-ionone, 2-pentylcyclopentanone, 2-hexylcyclopentanone, 2-heptylcyclopentanone, methylbenzy Ketone, methyl styryl ketone,
The (b) monoterpene alcohols and / or aromatic alcohols having a total carbon number of 8 to 12 are linalool, dehydrolinalol, geraniol, nerol, citronellol, menthol, terpineol, terpinen-4-ol, isopulegol, borneol. The ant repellent composition according to claim 1, which is 1-phenylethyl alcohol, 2-phenylethyl alcohol, thymol, eugenol.
The ant repellent product according to any one of claims 8 to 10, wherein the ant is a fire ant or a ant.
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