JP7331693B2 - 導電性接着剤組成物及びこれを用いた接続構造体 - Google Patents
導電性接着剤組成物及びこれを用いた接続構造体 Download PDFInfo
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- JP7331693B2 JP7331693B2 JP2019529809A JP2019529809A JP7331693B2 JP 7331693 B2 JP7331693 B2 JP 7331693B2 JP 2019529809 A JP2019529809 A JP 2019529809A JP 2019529809 A JP2019529809 A JP 2019529809A JP 7331693 B2 JP7331693 B2 JP 7331693B2
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/04—Printing inks based on proteins
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
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- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R11/00—Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts
- H01R11/01—Individual connecting elements providing two or more spaced connecting locations for conductive members which are, or may be, thereby interconnected, e.g. end pieces for wires or cables supported by the wire or cable and having means for facilitating electrical connection to some other wire, terminal, or conductive member, blocks of binding posts characterised by the form or arrangement of the conductive interconnection between the connecting locations
Description
YL980(三菱ケミカル株式会社製、ビスフェノールF型エポキシ樹脂の商品名)17.7質量部と、2P4MHZ-PW(四国化成工業株式会社製、イミダゾール化合物の商品名)0.9質量部と、フラックス活性剤としてのBHPA(2,2-ビス(ヒドロキシメチル)プロピオン酸)6.4質量部とを混合し、混合物を3本ロールに3回通して、接着剤成分を調製した。
表1に示す組成に変更した以外は実施例1と同様にして、実施例2~9及び比較例1~6の導電性接着剤組成物を得た。比較例7~9では下記の市販の導電性接着剤を用いた。
<導電性粒子>
Sn42-Bi58はんだ粒子(三井金属鉱業株式会社製、融点138℃)
・Sn42-Bi58 10μm粒子:平均粒径10μm
・Sn42-Bi58 10~25μm粒子:平均粒径10μmを超えて25μm以下
・Sn42-Bi58 20~38μm粒子:平均粒径20~38μm
Sn42-Bi57-Ag1はんだ粒子(三井金属鉱業株式会社製、融点139℃)
・Sn42-Bi57-Ag1 5μm粒子:平均粒径5μm
<フラックス活性剤>
BHBA:2,2-ビスヒドロキシメチルブタン酸
酒石酸
グルタル酸
アジピン酸
<その他導電性接着剤>
Agペースト:藤倉化成株式会社製、ドータイト(商品名)
Sn42-Bi58クリームはんだ:千住金属工業株式会社製、エコソルダー(商品名)
Sn96.5-Ag3-Cu0.5クリームはんだ:千住金属工業株式会社製、エコソルダー(商品名)
実施例1~9、比較例1~9に係る導電性接着剤組成物の特性を下記の方法で測定した。その結果を表1、表2にまとめて示した。表中、「フラックス/金属比率(%)」は、導電性粒子に対するフラックス活性剤の比率(質量%)を意味する。
導電性接着剤組成物を銀めっき付き銅板上に約0.5mg塗布し、その上に2mm×2mm×0.25mmの矩形平板状の錫めっき付き銅板を圧着して試験片を得た。その後、実施例1~9及び比較例1~8に係る試験片に対しては、150℃、10分間の熱履歴を加えた。比較例9の試験片に対しては、260℃、10分間の熱履歴を加えた。熱履歴を加えた後の各試験片の25℃における接着強度(シェア強度)を、シェア速度500μm/sec、クリアランス100μmの条件でボンドテスター(DAGE社製、2400)を用いて測定した。
1mm×50mm×0.03mmの帯状の金めっき付き銅板2枚を、上記導電性接着剤組成物を介して、互いに直交するように貼り合わせて試験片を得た。銅板の直交部分における接着剤の層の寸法は1mm×1mm×0.03mmであった。続いて、上記(1)と同様の熱履歴を試験片に加えた。その後の試験片について、四端子法で体積抵抗率を測定した。
隣り合う2つの銅箔ランド(0.2mm×0.4mm)を備え、銅箔ランド間の距離が100μmである、100mm×50mm×0.5mmの矩形平板状の薄型FR4基板を準備した。次いで、銅箔ランド上に導電性接着剤組成物をメタルマスク(厚み100μm、開口寸法0.2mm×0.3mm)を用いて印刷した。その上に、電極間距離が100μmの小型チップ抵抗(0.2mm×0.4mm)を、導電性接着剤組成物を介して電極と銅箔ランドが対向するように載せた。得られた部品搭載基板に上記(1)と同様の熱履歴を加え、耐TCT性評価用の試験基板を得た。この試験基板の初期抵抗を簡易テスターを用いて確認した。その後、試験基板を、熱衝撃試験機を用いて、-55℃で30分間保持、125℃まで5分間で昇温、125℃で30分間保持、及び-55℃まで5分間で降温の順の温度変化を1サイクルとする熱衝撃試験に供した。熱衝撃試験後の試験基板の接続抵抗を測定した。サイクル数を増やしながら試験基板の接続抵抗を測定し、初期抵抗に対して±10%以内の抵抗変化率を示した時点までのサイクル数を、耐TCT性の指標とした。表中、「初期オープン」は初期導通性が著しく低かったことを意味する。「初期ショート」は熱衝撃試験前にショートが発生していたことを意味する。
Claims (9)
- 前記導電性粒子の比表面積が0.060~90m2/gである、請求項1に記載の導電性接着剤組成物。
- 前記熱硬化性樹脂がエポキシ樹脂を含む、請求項1又は2に記載の導電性接着剤組成物。
- 当該導電性接着剤組成物が、25℃でペースト状である、請求項1~3のいずれか一項に記載の導電性接着剤組成物。
- 前記回路基板が基材及び該基材の主面上に配置された2以上の接続端子を有し、該2以上の接続端子と前記電子部品の接続端子とを電気的に接続するために用いられる、請求項1~4のいずれか一項に記載の導電性接着剤組成物。
- 前記回路基板の前記2以上の接続端子が、互いに200μm以下の間隔を空けて前記基材の主面上に配置されている、請求項5に記載の導電性接着剤組成物。
- 基材及び該基材の主面上に設けられた2以上の接続端子を有する回路基板と、
前記回路基板の2以上の前記接続端子と対向する2以上の接続端子を有する電子部品と、
前記回路基板と前記電子部品との間に配置され、これらを接合している接続部と、
を備え、
前記接続部が、前記回路基板の前記接続端子と前記電子部品の前記接続端子との間に配置され、それらを電気的に接続している導電部を含み、
前記導電部が、請求項1~4のいずれか一項に記載の導電性接着剤組成物に含まれていた導電性粒子を含み、
前記接続部が、前記導電部の周囲に形成された樹脂部を更に含み、前記樹脂部が、請求項1~4のいずれか一項に記載の導電性接着剤組成物における導電性粒子以外の成分である接着剤成分の硬化物を含む、
接続構造体。 - 前記電子部品が、ドライバーIC、センサ素子を内蔵したモジュール部品、ショットキーバリアダイオード、及び熱電変換素子からなる群より選ばれる少なくとも1種を含む、請求項7に記載の接続構造体。
- 前記基材がフレキシブル基材である、請求項7又は8に記載の接続構造体。
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---|---|---|---|---|
JP2007182562A (ja) | 2005-12-08 | 2007-07-19 | Hitachi Chem Co Ltd | 電子部品用液状樹脂組成物及び電子部品装置 |
JP2008150597A (ja) | 2006-11-22 | 2008-07-03 | Hitachi Chem Co Ltd | 導電性接着剤組成物、電子部品搭載基板及び半導体装置 |
JP2015053342A (ja) | 2013-09-05 | 2015-03-19 | デクセリアルズ株式会社 | 導電性接着剤、太陽電池モジュール、及び太陽電池モジュールの製造方法 |
JP2016014115A (ja) | 2014-07-03 | 2016-01-28 | 積水化学工業株式会社 | 導電材料及び接続構造体 |
JP2017112312A (ja) | 2015-12-18 | 2017-06-22 | 日立化成株式会社 | 導電性接着剤組成物、接続構造体及び半導体発光素子搭載フレキシブル配線基板 |
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KR20070049169A (ko) * | 2004-08-25 | 2007-05-10 | 마츠시타 덴끼 산교 가부시키가이샤 | 땜납 조성물, 납땜 접합 방법, 및 납땜 접합 구조 |
JP2006199937A (ja) | 2004-12-15 | 2006-08-03 | Tamura Kaken Co Ltd | 導電性接着剤、これを用いた導電部及び電子部品モジュール |
JP2014017248A (ja) | 2012-06-14 | 2014-01-30 | Sekisui Chem Co Ltd | 導電材料、導電材料の製造方法及び接続構造体 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007182562A (ja) | 2005-12-08 | 2007-07-19 | Hitachi Chem Co Ltd | 電子部品用液状樹脂組成物及び電子部品装置 |
JP2008150597A (ja) | 2006-11-22 | 2008-07-03 | Hitachi Chem Co Ltd | 導電性接着剤組成物、電子部品搭載基板及び半導体装置 |
JP2015053342A (ja) | 2013-09-05 | 2015-03-19 | デクセリアルズ株式会社 | 導電性接着剤、太陽電池モジュール、及び太陽電池モジュールの製造方法 |
JP2016014115A (ja) | 2014-07-03 | 2016-01-28 | 積水化学工業株式会社 | 導電材料及び接続構造体 |
JP2017112312A (ja) | 2015-12-18 | 2017-06-22 | 日立化成株式会社 | 導電性接着剤組成物、接続構造体及び半導体発光素子搭載フレキシブル配線基板 |
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