JP7190752B2 - 硬化済み熱硬化性樹脂を成形する方法 - Google Patents
硬化済み熱硬化性樹脂を成形する方法 Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
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- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
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- B29K2105/243—Partially cured
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29K2309/00—Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Physics & Mathematics (AREA)
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- Mechanical Engineering (AREA)
- Engineering & Computer Science (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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- Application Of Or Painting With Fluid Materials (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Description
i. 硬化済み熱硬化性樹脂基材を用意するステップ;
ii. 閉鎖温度制御環境(confined temperature controlling environment)を用意するステップ;
iii. 硬化済み熱硬化性樹脂基材を閉鎖温度制御環境内に入れるステップ;
iv. 電磁放射線の供給源を用意するステップ;
v. 閉鎖温度制御環境内の硬化済み熱硬化性樹脂基材を照射するステップ;及び
vi. 照射された熱硬化性樹脂基材を成形するステップ
を含む、硬化済み熱硬化性樹脂基材を成形する方法が提供される。
(a)少なくとも1の反応度数(reactivity number)(以下に定義する)を有する液体フェノールレゾールと;
(b)レゾール用の強酸硬化剤と
の間の硬化反応を、
(c)液体レゾールの少なくとも5重量%の量で存在し、レゾール及び硬化剤を含有する混合物全体に実質的に均一に分散した、不活性且つ不溶性の微粉化粒子状固体
の存在下で実行することによって生成されてもよく、
熱を加えられることに起因する、レゾール及び硬化剤を含有する混合物の温度は85℃を超えず、前記温度及び酸硬化剤の濃度は、硬化反応の副生成物として生じる化合物が混合物の固化前に混合物中で揮発し、それによって発泡済みフェノール樹脂生成物が生成されるような温度及び濃度である。
好ましくは、電磁放射線は、マイクロ波放射線、電波(RF,radio wave)、超音波、及び赤外線、並びにそれらの組み合わせから選択される。
- シート状成形材料(sheet-form moulding material)を含む層を用意するステップ;
- 硬化済み連続気泡フェノール樹脂基材を用意するステップ;
- シート状材料の層を、硬化済み連続気泡フェノール樹脂基材の表面上に施すステップ;及びシート状材料を基材にプレスするステップ,
を含み、基材は、基材の一部分を通してプレスされる部位から気体及び/又は蒸気が排出されることが可能であるように実質的に連続気泡型の構造を有し、シート状材料の一部は、プレスステップ中に基材の表面に流入する。
i. (上記のような)硬化済み熱硬化性樹脂基材を用意するステップ;
ii. (上記のような)温度制御環境として流体を用意するステップ;
iii. (上記のように)硬化済み熱硬化性樹脂基材を流体中に少なくとも部分的に浸漬させるステップ;
iv. (上記のような)電磁放射線の供給源を用意するステップ;
v. (上記のように)少なくとも部分的に浸漬されている硬化済み熱硬化性樹脂基材を照射するステップ;及び
vi. (上記のように)照射された熱硬化性樹脂基材を成形するステップ
を含む、硬化済み熱硬化性樹脂基材を成形する方法が提供される。
i. 硬化済み熱硬化性連続気泡発泡樹脂基材を用意するステップ;
ii. 温度制御環境として液体を用意するステップ;
iii. 硬化済み熱硬化性発泡樹脂基材の連続気泡を、液体で少なくとも部分的に飽和させるステップ;
iv. 電磁放射線の供給源を用意するステップ;
v. 少なくとも部分的に飽和した硬化済み連続気泡熱硬化性発泡樹脂基材を照射するステップ;及び
vi. 照射された連続気泡熱硬化性発泡樹脂基材を成形するステップ
を含む、硬化済み連続気泡熱硬化性発泡樹脂基材を成形する方法が提供される。
i. 予備成形された硬化済み熱硬化性樹脂基材を用意するステップ;
ii. 閉鎖温度制御環境を用意するステップ;
iii. 予備成形された硬化済み熱硬化性樹脂基材を閉鎖温度制御環境内に入れるステップ;
iv. 電磁放射線の供給源を用意するステップ;
v. 閉鎖温度制御環境内の予備成形された硬化済み熱硬化性樹脂基材を照射するステップ;及び
vi. 照射された熱硬化性樹脂基材を再成形するステップ
を含む、予備成形された硬化済み熱硬化性樹脂基材をリサイクルする方法が提供される。
(i) 硬化済み熱硬化性樹脂を受容するための容器;
(ii) 温度制御環境の供給源;及び
(iii) 制御可能な電磁放射線供給源
を含む、硬化済み熱硬化性樹脂の成形に使用するための装置が提供される。
[実施例]
Claims (16)
- i. 硬化済み熱硬化性樹脂基材を用意するステップ;
ii. 閉鎖温度制御環境を用意するステップであって、選択された前記閉鎖温度制御環境は、前記硬化済み熱硬化性樹脂基材と化学的に反応しないステップ;
iii. 前記硬化済み熱硬化性樹脂基材を前記閉鎖温度制御環境内に入れるステップ;
iv. 電磁放射線の供給源を用意するステップ;
v. 前記閉鎖温度制御環境内の前記硬化済み熱硬化性樹脂基材を前記電磁放射線の供給源により照射するステップ;及び
vi. 前記照射された熱硬化性樹脂基材を成形するステップ
を含む、硬化済み熱硬化性樹脂基材を成形する方法。 - 温度制御環境が、気体、蒸気、液体、若しくはゲル、又はそれらの組み合わせの形態である、請求項1に記載の方法。
- 液体が、エチレングリコール、ブタノール、トルエン、デカン、及び水、並びにそれらの組み合わせから選択される、請求項2に記載の方法。
- 液体が、照射中に20~95℃の温度に加熱される、請求項2又は3に記載の方法。
- 硬化済み熱硬化性樹脂が、閉鎖温度制御環境内に少なくとも実質的に浸漬されている、請求項1~4のいずれかに記載の方法。
- 硬化済み熱硬化性樹脂が、フェノール樹脂、ポリエステル、アクリル樹脂、ビニルエステル、ポリウレタン、エポキシ樹脂、及びシート状成形材料から選択される、請求項1~5のいずれかに記載の方法。
- 硬化済み熱硬化性樹脂が、1又は2以上の充填剤をさらに含む、請求項1~6のいずれかに記載の方法。
- 硬化済み熱硬化性樹脂が発泡済みである、請求項1~7のいずれかに記載の方法。
- 硬化済み熱硬化性樹脂の利用可能な細孔容積の少なくとも50%が温度制御環境で満たされる、請求項8に記載の方法。
- 電磁放射線が、マイクロ波、RF、超音波、及び赤外線から選択される、請求項1~9のいずれかに記載の方法。
- マイクロ波放射線が1mm~1mの波長、及び/又は
マイクロ波放射線が300GHz~300MHzの周波数、及び/又は
マイクロ波放射線が500W~120kWの電力を伝送する、請求項10に記載の方法。 - 硬化済み熱硬化性樹脂が、30分間未満照射される、請求項1~11のいずれかに記載の方法。
- 硬化済み熱硬化性樹脂基材が、照射される前に事前処理される、請求項1~12のいずれかに記載の方法。
- 硬化済み熱硬化性樹脂基材が予備成形され、前記予備成形された形状を成形中に変化させることを含む、請求項1~13のいずれかに記載の方法。
- 以下のステップを含む、硬化済み熱硬化性樹脂基材を、成形する方法。
i. 硬化済み熱硬化性樹脂基材を用意するステップ;
ii. 温度制御環境として流体を用意するステップであって、選択された前記温度制御環境は、前記硬化済み熱硬化性樹脂基材と化学的に反応しないステップ;
iii. 前記硬化済み熱硬化性樹脂基材を前記流体中に少なくとも部分的に浸漬させるステップ;
iv. 電磁放射線の供給源を用意するステップ;
v. 前記少なくとも部分的に浸漬されている硬化済み熱硬化性樹脂基材を照射するステップ;及び
vi. 前記照射された熱硬化性樹脂基材を成形するステップ; - i. 予備成形された硬化済み熱硬化性樹脂基材を用意するステップ;
ii. 閉鎖温度制御環境を用意するステップであって、選択された前記閉鎖温度制御環境は、前記予備成形された硬化済み熱硬化性樹脂基材と化学的に反応しないステップ;
iii. 前記予備成形された硬化済み熱硬化性樹脂基材を前記閉鎖温度制御環境内に入れ
るステップ;
iv. 電磁放射線の供給源を用意するステップ;
v. 前記閉鎖温度制御環境内の前記予備成形された硬化済み熱硬化性樹脂基材を照射するステップ;及び
vi. 前記照射された熱硬化性樹脂基材を再成形するステップ
を含む、予備成形された硬化済み熱硬化性樹脂基材をリサイクルする方法。
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PCT/GB2018/050790 WO2018172799A1 (en) | 2017-03-24 | 2018-03-26 | Method of shaping a cured thermosetting resin |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001342290A (ja) | 2000-06-05 | 2001-12-11 | Mitsubishi Electric Corp | 熱硬化性樹脂の分解方法及び分解装置 |
JP2015036394A (ja) | 2013-08-12 | 2015-02-23 | 学校法人君が淵学園 | 不飽和ポリエステルの解重合方法、およびその解重合方法を用いた不飽和ポリエステルの原料の回収方法 |
CN104827687A (zh) | 2014-02-10 | 2015-08-12 | 现代汽车欧洲技术中心有限公司 | 用于制造纤维增强的热固性复合材料的方法和设备 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5028358A (en) * | 1989-04-17 | 1991-07-02 | Blum Ronald D | Method for molding and curing plastic lenses |
JP3156159B2 (ja) | 1990-10-12 | 2001-04-16 | 株式会社クラレ | Frp補強筋の曲げ加工方法およびその装置 |
JP3309296B2 (ja) * | 1993-10-29 | 2002-07-29 | 清水建設株式会社 | 熱硬化性廃プラスチックと廃ポリスチレンとからなる成形物及びその製造法 |
JPH07144327A (ja) * | 1993-11-22 | 1995-06-06 | Tokyo Inst Of Technol | 熱硬化性廃プラスチックを利用するための処理方法及びそのための装置 |
US5770143A (en) * | 1996-07-03 | 1998-06-23 | Board Of Trustees Operating Michigan State University | Method for liquid thermosetting resin molding using radiofrequency wave heating |
ITMI980960A1 (it) | 1998-05-04 | 1999-11-04 | Colmec S P A | Motodo ed apparecchiatura di reticolazione mista a bagno di sali fusi per profili estrusi |
DE10026761C1 (de) * | 2000-05-30 | 2002-01-10 | Daimler Chrysler Ag | Verfahren zur Wiederverwertung von Faserverbundwerkstoffen |
JP2002154162A (ja) * | 2000-11-17 | 2002-05-28 | Honda Motor Co Ltd | 超音波を利用した樹脂成形方法 |
JP2002264221A (ja) * | 2001-03-14 | 2002-09-18 | Minolta Co Ltd | 三次元造形装置、および三次元造形方法 |
KR100468324B1 (ko) * | 2001-11-15 | 2005-01-27 | 경상대학교산학협력단 | 감마선을 이용한 폐고무 재활용 방법 및 재활용제품 |
JP2004033387A (ja) | 2002-07-02 | 2004-02-05 | Kuraray Co Ltd | 医療用易減容性プラスチック成形品 |
NL1023563C2 (nl) | 2003-05-28 | 2004-11-30 | Dsm Ip Assets Bv | Thermohardend materiaal; werkwijze en installatie voor het vervormen van een al dan niet uitgehard thermohardend materiaal. |
US7837911B2 (en) * | 2004-01-26 | 2010-11-23 | Sabic Innovative Plastics Ip B.V. | Methods of forming a layered article |
KR100569417B1 (ko) * | 2004-08-13 | 2006-04-07 | 현대자동차주식회사 | 마이크로웨이브를 이용한 폐고무분말의 연속식표면개질장치와 이를 이용한 표면개질방법 |
GB2453308B (en) | 2007-10-03 | 2012-07-25 | Acell Group Ltd | Composite products |
CA3009693C (en) | 2008-10-20 | 2020-06-30 | Acell Industries Limited | Composite product with surface effect |
GB2464540B (en) | 2008-10-20 | 2013-03-13 | Acell Group Ltd | Patterned composite product |
DK2523798T3 (en) | 2010-01-12 | 2017-02-13 | Vestas Wind Sys As | Method for connecting composite parts with a thermoset matrix |
EP2576193B1 (fr) | 2010-05-31 | 2017-06-21 | Arkema France | Resines et composites thermodurs epoxy acides pouvant etre faconnes a chaud et recycles |
US20120282421A1 (en) | 2011-05-04 | 2012-11-08 | Toyota Motor Europe Nv/Sa | Method for heating a fiber-reinforced polymer |
WO2014025360A1 (en) | 2012-08-10 | 2014-02-13 | Empire Technology Development Llc | Microwave dipolar heating of energetic polymers for carbon fiber-matrix separation |
-
2017
- 2017-03-24 GB GB1704750.7A patent/GB2560768B/en active Active
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001342290A (ja) | 2000-06-05 | 2001-12-11 | Mitsubishi Electric Corp | 熱硬化性樹脂の分解方法及び分解装置 |
JP2015036394A (ja) | 2013-08-12 | 2015-02-23 | 学校法人君が淵学園 | 不飽和ポリエステルの解重合方法、およびその解重合方法を用いた不飽和ポリエステルの原料の回収方法 |
CN104827687A (zh) | 2014-02-10 | 2015-08-12 | 现代汽车欧洲技术中心有限公司 | 用于制造纤维增强的热固性复合材料的方法和设备 |
US20150224683A1 (en) | 2014-02-10 | 2015-08-13 | Hyundai Motor Europe Technical Center Gmbh | Method and apparatus for manufacturing a fiber-reinforced thermoset article |
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AR111142A1 (es) | 2019-06-05 |
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CA3057563A1 (en) | 2018-09-27 |
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BR112019019851A2 (pt) | 2020-04-22 |
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