JP7141911B2 - Deodorant for textile products and method for deodorizing and improving texture of textile products - Google Patents
Deodorant for textile products and method for deodorizing and improving texture of textile products Download PDFInfo
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Description
本発明は、衣類、繊維製品に付着した悪臭に対して好適に使用される繊維製品用消臭剤及び繊維製品の消臭・風合い改善方法に関する。 TECHNICAL FIELD The present invention relates to a deodorant for textile products that is suitably used for bad odors adhering to clothing and textile products, and a method for deodorizing and improving the texture of textile products.
タバコ、焼き肉、ペットなどの臭いは、衣類や繊維製品に付着して悪臭を発する。しかし、一般的に使用されている消臭剤は代表的な悪臭とされるアンモニア、トリメチルアミン、硫化水素、メチルメルカプタン、イソ吉草酸などには効果があっても、タバコ臭や焼き肉臭等の複合悪臭に対しては性能的に十分とは言い難い。 Smells from cigarettes, grilled meat, pets, etc. adhere to clothing and textile products, giving off bad odors. However, although commonly used deodorants are effective against typical bad odors such as ammonia, trimethylamine, hydrogen sulfide, methyl mercaptan, and isovaleric acid, they are effective against complex odors such as cigarette odors and grilled meat odors. It is difficult to say that the performance is sufficient for bad odors.
そこで、衣類、繊維製品に付着したタバコ、焼き肉、ペットなどの臭いを効果的に消臭する繊維製品用消臭剤として、特許文献１には、柿抽出物を０．０１～５．０重量％と、乳酸ナトリウムを０．１～２．０重量％含有することを特徴とする繊維製品用消臭剤組成物および繊維製品の消臭方法が開示されている。また、繰り返し使用しても衣類、繊維製品の風合いを悪化させないことも記載されている。 Therefore, as a deodorant for textile products that effectively deodorizes the odors of cigarettes, grilled meat, pets, etc. attached to clothing and textile products, Patent Document 1 discloses 0.01 to 5.0 weight of persimmon extract. %, and 0.1 to 2.0% by weight of sodium lactate. It also states that the texture of clothes and textile products is not deteriorated even after repeated use.
一方、洗濯を繰り返すことによって衣服の織構造が緩んだり繊維が傷んだりしてハリやコシが衰えると、外観が悪くなり着用時の感触も悪くなるという問題があった。綿や合成繊維等の衣服のハリやコシを向上させる手法としては、糊剤等を用いて高分子で繊維表面をコートする手法が一般的に知られているが、これらの方法においては、塗布量が不均一化して局部的に製膜した場合にゴワつきが生じたり外観を損なったりしてしまう。 On the other hand, repeated washing loosens the woven structure of the clothes and damages the fibers, resulting in a loss of tension and stiffness, which causes problems such as deterioration of the appearance and feeling of wearing. As a technique for improving the firmness and stiffness of clothes such as cotton and synthetic fibers, it is generally known to coat the fiber surface with a polymer using a sizing agent or the like. If the amount becomes non-uniform and the film is formed locally, it will become stiff or the appearance will be damaged.
そこで、特許文献２には、重合度２ないし３のオリゴ糖から選ばれる少なくとも１種を含有し、処理後に乾燥するだけの操作で良好なハリやコシを付与し、かつ、ゴワつき感を生じさせない繊維の風合い改善剤および繊維製品用仕上げ剤が開示されている。 Therefore, in Patent Document 2, at least one selected from oligosaccharides having a degree of polymerization of 2 to 3 is contained, and good elasticity and stiffness are imparted by simply drying after treatment, and a stiff feeling is produced. Disclosed are fabric hand improvers and textile finishes that do not dry out.
しかしながら、繊維製品の消臭処理と風合いの改善処理の両方を行いたい場合、特許文献１のような消臭剤組成物と特許文献２のような風合い改善剤とを個別に準備して処理する必要がある。そのため、処理工程数やコストが増加するという問題点があった。 However, when it is desired to perform both deodorizing treatment and texture improving treatment of textile products, a deodorant composition as in Patent Document 1 and a texture improving agent as in Patent Document 2 are separately prepared and treated. There is a need. Therefore, there is a problem that the number of processing steps and costs increase.
本発明は、上記問題点に鑑み、繊維製品に付着したタバコ臭、汗臭、尿臭、ペット臭、焼き肉臭等の種々の悪臭を効果的に消臭するとともに、繊維の風合い改善処理も同時に行うことができる繊維製品用消臭剤および繊維製品の消臭・風合い改善方法を提供することを目的とする。 In view of the above problems, the present invention effectively deodorizes various odors such as tobacco odor, sweat odor, urine odor, pet odor, and grilled meat odor adhering to textile products, and simultaneously improves the texture of textiles. It is an object of the present invention to provide a deodorant for textile products and a method for deodorizing and improving the texture of textile products.
上記目的を達成するために本発明は、（Ａ）消臭成分・剛軟度付与成分として炭酸水素ナトリウムと、（Ｂ）消臭成分・剛軟度調整成分として植物抽出物と、（Ｃ）水と、を含有し、前記炭酸水素ナトリウムの配合量が０．０５質量％以上０．１５質量％以下である繊維製品用消臭剤である。 In order to achieve the above object, the present invention comprises (A) sodium hydrogen carbonate as a deodorizing component and a bending resistance imparting component, (B) a plant extract as a deodorizing component and a bending resistance adjusting component, and (C). and water, and the sodium hydrogen carbonate content is 0.05% by mass or more and 0.15% by mass or less .
また本発明は、上記構成の繊維製品用消臭剤において、前記植物抽出物が、サトウキビ抽出物、柿抽出物、イチョウ抽出物、イチジク抽出物、レンギョウ抽出物から選ばれた１種以上であることを特徴としている。 Further, according to the present invention, in the deodorant for textile products having the above constitution, the plant extract is one or more selected from sugarcane extract, persimmon extract, ginkgo biloba extract, fig extract, and forsythia extract. It is characterized by
また本発明は、上記構成の繊維製品用消臭剤において、前記炭酸水素ナトリウムと前記植物抽出物の配合比が１：０．５～１：５であることを特徴としている。 Further, according to the present invention, in the textile product deodorant having the above constitution, the mixing ratio of the sodium hydrogen carbonate and the plant extract is 1:0.5 to 1:5.
また本発明は、（Ａ）消臭成分・剛軟度付与成分として炭酸水素ナトリウムと、（Ｂ）消臭成分・剛軟度調整成分として植物抽出物と、（Ｃ）水と、を含有する繊維製品用消臭剤を、繊維製品に５～１００ｇ／ｍ2噴霧した後、乾燥することを特徴とする繊維製品の消臭・風合い改善方法である。 Further, the present invention contains (A) sodium hydrogen carbonate as a deodorizing component and a bending resistance imparting component, (B) a plant extract as a deodorizing component and a bending resistance adjusting component, and (C) water. A method for deodorizing and improving the texture of textile products, characterized by spraying 5 to 100 g/m 2 of a deodorant for textile products onto textile products and then drying the product.
また本発明は、上記構成の繊維製品の消臭・風合い改善方法において、前記繊維製品用消臭剤を噴霧し、乾燥させた前記繊維製品を、ＪＩＳ Ｌ１０９６に記載の４５°カンチレバー法にて測定したときの剛軟度の増加率が１１０％～１４５％であることを特徴としている。 The present invention also provides the method for deodorizing and improving the texture of textile products having the above configuration, wherein the textile product is sprayed with the deodorant for textile products, dried, and measured by the 45° cantilever method described in JIS L1096. It is characterized in that the rate of increase in bending resistance is 110% to 145%.
また本発明は、上記構成の繊維製品の消臭・風合い改善方法において、前記植物抽出物が、サトウキビ抽出物、柿抽出物、イチョウ抽出物、イチジク抽出物、レンギョウ抽出物から選ばれた１種以上であることを特徴としている。 Further, according to the present invention, in the method for deodorizing and improving the texture of textile products having the above configuration, the plant extract is one selected from sugarcane extract, persimmon extract, ginkgo biloba extract, fig extract, and forsythia extract. It is characterized by the above.
また本発明は、上記構成の繊維製品の消臭・風合い改善方法において、前記炭酸水素ナトリウムの配合量が０．０５質量％以上０．１５質量％以下であることを特徴としている。 Further, according to the present invention, in the method for deodorizing and improving texture of textile products having the above configuration, the content of sodium hydrogen carbonate is 0.05% by mass or more and 0.15% by mass or less.
また本発明は、上記構成の繊維製品の消臭・風合い改善方法において、前記炭酸水素ナトリウムと前記植物抽出物の配合比が１：０．５～１：５であることを特徴としている。 Further, according to the present invention, in the method for deodorizing and improving the texture of textile products having the above configuration, the mixing ratio of the sodium hydrogen carbonate and the plant extract is 1:0.5 to 1:5.
また本発明は、上記構成の繊維製品の消臭・風合い改善方法において、前記繊維製品が、ポリエステル繊維製であることを特徴としている。 Further, according to the present invention, in the method for deodorizing and improving the texture of a textile product having the above configuration, the textile product is made of polyester fiber.
本発明の第１の構成によれば、（Ａ）消臭成分・剛軟度付与成分として炭酸水素ナトリウムと、（Ｂ）消臭成分・剛軟度調整成分として植物抽出物と、（Ｃ）水と、を含有することにより、タバコ臭、汗臭に対して消臭効果のある炭酸水素ナトリウムと、尿臭、ペット臭に対して消臭効果のある植物抽出物の相乗効果によって幅広い悪臭を効果的に消臭可能な繊維製品用消臭剤となる。また、炭酸水素ナトリウムが繊維製品に対する剛軟度付与成分として作用するとともに、植物抽出物が炭酸水素ナトリウムの剛軟度付与性能を調整する剛軟度調整成分として作用するため、繊維製品に適度なハリやコシを与えることができる。また、炭酸水素ナトリウムの配合量を０．０５質量％以上０．１５質量％以下とすることにより、タバコ臭、汗臭に対する十分な消臭効果を有し、且つ繊維製品に対する適度な剛軟度付与効果が得られる繊維製品用消臭剤となる。 According to the first configuration of the present invention, (A) sodium hydrogen carbonate as a deodorizing component and a bending resistance imparting component, (B) a plant extract as a deodorizing component and a bending resistance adjusting component, and (C) By containing water, the synergistic effect of sodium bicarbonate, which has a deodorizing effect against cigarette odors and sweat odors, and plant extracts, which have a deodorizing effect against urine odors and pet odors, eliminates a wide range of bad odors. It becomes a deodorant for textile products that can effectively deodorize. In addition, since sodium hydrogen carbonate acts as a bending resistance imparting component for textile products, and the plant extract acts as a bending resistance adjusting component that adjusts the bending resistance imparting performance of sodium hydrogen carbonate, it is suitable for textile products. It can give firmness and firmness. In addition, by setting the amount of sodium hydrogencarbonate to 0.05% by mass or more and 0.15% by mass or less, it has a sufficient deodorant effect against cigarette odor and sweat odor, and has an appropriate bending resistance for textile products. It becomes a deodorant for textile products that can obtain the imparting effect.
また、本発明の第２の構成によれば、上記第１の構成の繊維製品用消臭剤において、植物抽出物としてサトウキビ抽出物、柿抽出物、イチョウ抽出物、イチジク抽出物、レンギョウ抽出物から選ばれた１種以上を用いることにより、尿臭、ペット臭に対する消臭効果が高く剛軟度調整性能にも優れた繊維製品用消臭剤となる。 According to the second aspect of the present invention, in the deodorant for textile products of the first aspect, the plant extracts include sugarcane extract, persimmon extract, ginkgo biloba extract, fig extract, and forsythia extract. By using one or more selected from the above, a deodorant for textile products having a high deodorizing effect against urine odor and pet odor and excellent bending resistance adjusting performance can be obtained.
また、本発明の第３の構成によれば、上記第１又は第２の構成の繊維製品用消臭剤において、炭酸水素ナトリウムと植物抽出物の配合比を１：０．５～１：５とすることにより、尿臭、ペット臭に対する消臭効果および剛軟度調整効果が必要十分であり、安全性やコスト面においても優れた繊維製品用消臭剤となる。 Further, according to the third configuration of the present invention, in the deodorant for textile products of the first or second configuration, the mixing ratio of sodium hydrogen carbonate and the plant extract is 1:0.5 to 1:5. As a result, the deodorizing effect against urine odor and pet odor and the bending resistance adjusting effect are necessary and sufficient, and the deodorant for textile products is excellent in terms of safety and cost.
また、本発明の第４の構成によれば、（Ａ）消臭成分・剛軟度付与成分として炭酸水素ナトリウムと、（Ｂ）消臭成分・剛軟度調整成分として植物抽出物と、（Ｃ）水と、を含有する繊維製品用消臭剤を、繊維製品に５～１００ｇ／ｍ2噴霧した後、乾燥することにより、タバコ臭、汗臭、尿臭、ペット臭等を効果的に消臭することができ、且つ、繊維製品に適度なハリやコシを付与することができる繊維製品の消臭・風合い改善方法となる。 Further, according to the fourth configuration of the present invention, (A) sodium hydrogen carbonate as a deodorizing component and a bending resistance imparting component, (B) a plant extract as a deodorizing component and a bending resistance adjusting component, ( C) After spraying 5 to 100 g/m 2 of a textile product deodorant containing water on the textile product, it is dried to effectively eliminate tobacco odor, sweat odor, urine odor, pet odor, etc. To provide a method for deodorizing and improving the texture of textile products, capable of deodorizing and imparting appropriate firmness and stiffness to the textile products.
また、本発明の第５の構成によれば、上記第４の構成の繊維製品の消臭・風合い改善方法において、繊維製品用消臭剤を噴霧し、乾燥させた繊維製品を、ＪＩＳ Ｌ１０９６に記載の４５°カンチレバー法にて測定したときの剛軟度の増加率を１１０％～１４５％の範囲とすることにより、繊維製品に付与されるハリやコシをゴワつきの発生しない適切な範囲とすることができる。 Further, according to the fifth configuration of the present invention, in the method for deodorizing and improving the texture of textile products of the fourth configuration, the textile product deodorant is sprayed and dried, and the textile product is dried according to JIS L1096. By setting the rate of increase in bending resistance when measured by the described 45° cantilever method to the range of 110% to 145%, the tension and stiffness imparted to the textile product are set to an appropriate range that does not cause stiffening. be able to.
また、本発明の第６の構成によれば、上記第４又は第５の構成の繊維製品の消臭・風合い改善方法において、植物抽出物としてサトウキビ抽出物、柿抽出物、イチョウ抽出物、イチジク抽出物、レンギョウ抽出物から選ばれた１種以上を用いることにより、尿臭、ペット臭に対する消臭効果が高く剛軟度調整性能にも優れた繊維製品の消臭・風合い改善方法となる。 According to a sixth aspect of the present invention, in the method for deodorizing and improving the texture of textile products of the fourth or fifth aspect, the plant extracts include sugarcane extract, persimmon extract, ginkgo biloba extract, and fig. By using one or more selected from extracts and forsythia extracts, a method for deodorizing and improving the texture of textile products, which has a high deodorizing effect against urine odor and pet odor and is excellent in bending resistance adjusting performance, is provided.
また、本発明の第７の構成によれば、上記第４乃至第６の構成の繊維製品の消臭・風合い改善方法において、炭酸水素ナトリウムの配合量を０．０５質量％以上０．１５質量％以下とすることにより、タバコ臭、汗臭に対する十分な消臭効果を有し、且つ繊維製品に対する適度な剛軟度付与効果が得られる繊維製品の消臭・風合い改善方法となる。 Further, according to the seventh configuration of the present invention, in the method for deodorizing and improving the texture of textile products of the fourth to sixth configurations, the amount of sodium hydrogen carbonate compounded is 0.05% by mass or more and 0.15% by mass. % or less, a method for deodorizing and improving the texture of textile products, which has a sufficient deodorizing effect against tobacco odor and sweat odor and imparts an appropriate bending resistance to textile products.
また、本発明の第８の構成によれば、上記第７の構成の繊維製品の消臭・風合い改善方法において、炭酸水素ナトリウムと植物抽出物の配合比を１：０．５～１：５とすることにより、タバコ臭、汗臭、尿臭、ペット臭等に対する消臭効果および剛軟度調整効果が必要十分であり、安全性やコスト面においても優れた繊維製品の消臭・風合い改善方法となる。 Further, according to the eighth configuration of the present invention, in the method for deodorizing and improving the texture of textile products of the seventh configuration, the mixing ratio of sodium hydrogen carbonate and the plant extract is 1:0.5 to 1:5. As a result, the deodorant effect and the bending resistance adjustment effect against tobacco odor, sweat odor, urine odor, pet odor, etc. are necessary and sufficient, and the deodorant and texture improvement of textile products excellent in terms of safety and cost. method.
また、本発明の第９の構成によれば、上記第４乃至第８のいずれかの構成の繊維製品の消臭・風合い改善方法において、対象となる繊維製品をポリエステル繊維製とすることにより、特に良好な剛軟度付与効果が得られる繊維製品の消臭・風合い改善方法となる。 Further, according to the ninth configuration of the present invention, in the method for deodorizing and improving the texture of a textile product according to any one of the fourth to eighth configurations, by making the target textile product made of polyester fiber, It is a method for deodorizing and improving the texture of textile products that can obtain a particularly good effect of imparting bending resistance.
以下、本発明の繊維製品用消臭剤について詳細に説明する。本発明の繊維製品用消臭剤は、（Ａ）消臭成分・剛軟度付与成分としての炭酸水素ナトリウムと、（Ｂ）消臭成分・剛軟度調整成分としての植物抽出物と、を（Ｃ）水に混合して水溶液としたものである。 The deodorant for textile products of the present invention will be described in detail below. The deodorant for textile products of the present invention comprises (A) sodium hydrogen carbonate as a deodorizing component and a bending resistance imparting component, and (B) a plant extract as a deodorizing component and a bending resistance adjusting component. (C) It is mixed with water to form an aqueous solution.
本発明の繊維製品用消臭剤に（Ａ）消臭成分・剛軟度付与成分として配合される炭酸水素ナトリウムは、タバコ臭、汗臭に対する優れた消臭効果を有する。また炭酸水素ナトリウムは、繊維製品に対してハリやコシを付与する性質を有する。この性質を利用して、本発明では炭酸水素ナトリウムを消臭成分として配合するとともに、繊維製品にハリやコシを付与する剛軟度付与剤として配合している。従来、炭酸水素ナトリウムが消臭効果を有することは知られていたが、繊維製品の剛軟度付与剤として作用することは、本発明者らによって初めて発見された知見である。 Sodium bicarbonate, which is blended as (A) the deodorizing component/bending stiffness imparting component in the deodorant for textile products of the present invention, has an excellent deodorizing effect against tobacco odor and sweat odor. In addition, sodium hydrogen carbonate has the property of imparting firmness and stiffness to textile products. Taking advantage of this property, in the present invention, sodium bicarbonate is blended as a deodorizing component and as a bending resistance-imparting agent that imparts firmness and stiffness to textile products. Although it has been known that sodium bicarbonate has a deodorant effect, it was discovered by the present inventors for the first time that it acts as an agent for imparting bending resistance to textile products.
炭酸水素ナトリウムによる剛軟度付与効果が期待できる繊維としては、ポリエステル、ナイロン、レーヨン等の合成繊維が挙げられる。後述する実施例に示すように、特にポリエステル繊維に対して高い剛軟度付与効果を有する。 Synthetic fibers such as polyester, nylon, and rayon are examples of fibers in which sodium bicarbonate can be expected to impart bending resistance. As shown in the examples described later, it has a high bending resistance imparting effect particularly to polyester fibers.
炭酸水素ナトリウムの配合量が少なすぎると剛軟度付与効果が十分でなくなり、多すぎると剛軟度付与効果が強くなり過ぎてしまう。後述の実施例において示すように、炭酸水素ナトリウムの配合量は繊維製品用消臭剤全体に対して０．０５質量％以上０．１５質量％以下とすることが好ましい。 If the amount of sodium hydrogencarbonate is too small, the effect of imparting bending resistance will be insufficient, and if it is too large, the effect of imparting bending resistance will be too strong. As shown in Examples below, the amount of sodium bicarbonate to be blended is preferably 0.05% by mass or more and 0.15% by mass or less with respect to the entire deodorant for textile products.
本発明の繊維製品用消臭剤に（Ｂ）消臭成分・剛軟度調整成分として配合される植物抽出物は、植物由来の成分が悪臭を不揮発性化・中和・分解する効果と、植物由来の香気成分で悪臭をマスキングする効果とがあり、両方の相乗効果により消臭すると考えられる。特に、尿臭、ペット臭、焼き肉臭等に対する優れた消臭効果を有する。また植物抽出物は、炭酸水素ナトリウムによって繊維製品に付与される剛軟度を緩和する性質を有する。この性質を利用して、本発明では植物抽出物を消臭成分として配合するとともに、繊維製品のハリやコシを調整する剛軟度調整剤として配合している。従来、植物抽出物が消臭効果を有することは知られていたが、繊維製品の剛軟度調整剤として作用することは、本発明者らによって初めて発見された知見である。 The plant extract blended as (B) the deodorizing component and the bending resistance adjusting component in the deodorant for textile products of the present invention has the effect that the plant-derived component devolatizes, neutralizes, and decomposes bad odors, It is thought that the synergistic effect of both of the plant-derived aromatic components is to mask offensive odors, resulting in deodorization. In particular, it has an excellent deodorant effect against urine odor, pet odor, grilled meat odor, and the like. Plant extracts also have the property of reducing the bending resistance imparted to textiles by sodium bicarbonate. Taking advantage of this property, in the present invention, the plant extract is blended as a deodorizing component and as a bending resistance adjuster for adjusting the firmness and stiffness of textile products. Although it has been conventionally known that plant extracts have a deodorant effect, the inventors of the present invention have discovered for the first time that plant extracts act as bending resistance modifiers for textile products.
上記の植物抽出物としては、サトウキビ、柿、イチョウ、イチジク、レンギョウ、茶、竹、カタバミ、ドクダミ、ツガ、クロマツ、カラマツ、アカマツ、キリ、ヒイラギ、モクセイ、ライラック、キンモクセイ、フキ、ツワブキ、クリ、ハンノキ、コナラ、ザクロ、ゼンマイ、タニウツギ、カキノキ、オオバコ、ヨモギ、ヤマモミジ、サルスベリ、シロバナハギ、アセビ、シダ、ヤマナラシ、コバノトネリコ等の抽出物が挙げられる。これらの中でも、特にサトウキビ抽出物、柿抽出物、イチョウ抽出物、イチジク抽出物、レンギョウ抽出物が好ましい。上記の植物抽出物は単独で用いても良いし、２種以上を混合して用いても良い。 The above plant extracts include sugarcane, persimmon, ginkgo, fig, forsythia, tea, bamboo, oxalis, Houttuynia cordata, hemlock, black pine, larch, Japanese red pine, paulownia, holly, osmanthus, lilac, osmanthus, butterbur, Japanese silverberry, chestnut, Extracts of alder, konara, pomegranate, fern, weigela, persimmon, plantain, mugwort, mountain maple, crape myrtle, white tang, Japanese juniper, fern, aspen, ash, and the like. Among these, sugarcane extract, persimmon extract, ginkgo biloba extract, fig extract, and forsythia extract are particularly preferred. The above plant extracts may be used alone, or two or more of them may be mixed and used.
サトウキビ抽出物としては、（１）サトウキビを圧搾して得られた圧搾汁を原料として、合成吸着剤樹脂に通液、吸着した成分を回収する樹脂分離により得られる水溶性の不揮発性成分を主成分としたもの、（２）サトウキビの圧搾汁を濃縮する際に得られる揮発性成分を樹脂に吸着分離することにより得られる画分からなるもの、（３）サトウキビを圧搾した際に得られるバガスから熱水抽出することにより得られる水溶性成分からなるもの、（４）サトウキビの圧搾汁を原料として、クロマト分離を行うことにより得られる不揮発性成分からなり、サトウキビ抽出物（１）とは組成の異なるものが挙げられる。このうち、消臭効果の観点からサトウキビ抽出物（２）が好ましい。サトウキビ抽出物としては、例えば三井製糖（株）製の「ＭＳＸ－２４５」を使用することができる。 The sugarcane extract consists mainly of water-soluble non-volatile components obtained by resin separation in which (1) pressed juice obtained by squeezing sugarcane is passed through a synthetic adsorbent resin and the adsorbed components are recovered. (2) A fraction obtained by adsorbing and separating volatile components obtained when concentrating sugarcane juice on a resin, (3) Bagasse obtained when sugarcane is pressed (4) Consisting of water-soluble components obtained by hot water extraction; There are different ones. Among these, the sugarcane extract (2) is preferable from the viewpoint of the deodorant effect. As the sugarcane extract, for example, "MSX-245" manufactured by Mitsui Sugar Co., Ltd. can be used.
柿抽出物としては、柿の未熟実の搾汁又は搾汁から糖分を除去した無糖搾汁液、またはそれらの脱水濃縮物が挙げられる。柿抽出物として、例えばリリース科学工業（株）製の「パンシルＦＧ－６０」を使用することができる。 Persimmon extracts include juice from unripe persimmons, sugar-free juice obtained by removing sugar from the juice, and dehydrated concentrates thereof. As the persimmon extract, for example, “Pancil FG-60” manufactured by Release Science Industry Co., Ltd. can be used.
イチョウ抽出物、イチジク抽出物、レンギョウ抽出物としては、例えばイチョウ抽出物、イチジク抽出物、レンギョウ抽出物の混合物を含むパナソニック化成（株）製の「スーパーピュリエールＡ－１００」を使用することができる。 As the ginkgo biloba extract, fig extract, and forsythia extract, for example, "Super Puriere A-100" manufactured by Panasonic Chemicals Co., Ltd. containing a mixture of ginkgo biloba extract, fig extract, and forsythia extract can be used. can.
植物抽出物の配合量が少なすぎると消臭効果および剛軟度調整効果が十分でなく、多すぎると非常に高価なものになり、汎用性がなくなってしまう。後述の実施例において示すように、植物抽出物の配合量は炭酸水素ナトリウム：植物抽出物＝１：０．５～１：５となるように配合することが好ましい。 If the amount of the plant extract is too small, the deodorant effect and the bending resistance adjusting effect will be insufficient, and if it is too large, the product will be very expensive and will lose versatility. As shown in Examples below, it is preferable that the blending ratio of the plant extract is sodium hydrogen carbonate:plant extract=1:0.5 to 1:5.
本発明には、必要に応じてエタノールを配合しても良い。本発明の繊維製品用消臭剤に加えられるエタノールとしては、例えば発酵エタノール、合成エタノール等が挙げられ、変性剤が添加されていても良い。変性剤としては、例えばメタノール、アセトアルデヒド、プロピオン酸エチル、食品用フレーバー等が挙げられ、中でも食品用フレーバーが好適に用いられる。 In the present invention, ethanol may be blended as necessary. Examples of ethanol added to the deodorant for textile products of the present invention include fermented ethanol, synthetic ethanol, and the like, and a denaturant may be added. Modifiers include, for example, methanol, acetaldehyde, ethyl propionate, food flavors, etc. Among them, food flavors are preferably used.
本発明の繊維製品用消臭剤には、必要に応じて界面活性剤を配合することができる。本発明の繊維製品用消臭剤に配合される界面活性剤としては、アニオン界面活性剤、カチオン界面活性剤、ノニオン界面活性剤、両性界面活性剤のいずれも好適に用いられる。アニオン界面活性剤の例としては、例えば脂肪酸石けん、アルキルベンゼンスルホン酸塩、直鎖アルキルベンゼンスルホン酸塩、アルキル硫酸塩、α―オレフィンスルホン酸塩、アルキルリン酸エステル塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、ポリオキシエチレンアルキルエーテルリン酸塩などが挙げられる。 The deodorant for textile products of the present invention may optionally contain a surfactant. Any of an anionic surfactant, a cationic surfactant, a nonionic surfactant and an amphoteric surfactant can be suitably used as the surfactant to be blended in the deodorant for textile products of the present invention. Examples of anionic surfactants include fatty acid soaps, alkylbenzene sulfonates, linear alkylbenzene sulfonates, alkyl sulfates, α-olefin sulfonates, alkyl phosphate salts, polyoxyethylene alkyl ether sulfates, Polyoxyethylene alkylphenyl ether sulfates, polyoxyethylene alkyl ether phosphates, and the like.
カチオン界面活性剤の例としては、ラウリルトリメチルアンモニウムクロリド、塩化ベンザルコニウム等の第４級アンモニウム塩が挙げられる。 Examples of cationic surfactants include quaternary ammonium salts such as lauryltrimethylammonium chloride and benzalkonium chloride.
ノニオン界面活性剤の例としては、例えばポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレン高級脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ヤシ油脂肪酸ジエタノールアミド、ポリオキシエチレンポリオキシプロピレンアルキルエーテル、脂肪酸アルカノールアミド、アルキルアミンオキシドなどが挙げられる。 Examples of nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene alkylphenyl ethers, polyoxyethylene higher fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene glycerin fatty acid esters, and polyoxyethylene hydrogenated castor oil. , coconut oil fatty acid diethanolamide, polyoxyethylene polyoxypropylene alkyl ether, fatty acid alkanolamide, alkylamine oxide and the like.
両性界面活性剤の例としては、ベタイン型界面活性剤が挙げられる。具体的には、ラウリル－Ｎ，Ｎ－ジメチル酢酸ベタイン、ラウリルアミドプロピル－Ｎ，Ｎ－ジメチル酢酸ベタイン、ヤシアルキルアミドプロピル－Ｎ，Ｎ－ジメチルヒドロキシプロピルスルホベタイン等が挙げられる。 Examples of amphoteric surfactants include betaine-type surfactants. Specific examples include lauryl-N,N-dimethylacetate betaine, laurylamidopropyl-N,N-dimethylacetate betaine, coconutalkylamidopropyl-N,N-dimethylhydroxypropylsulfobetaine and the like.
本発明の繊維製品用消臭剤は、水系タイプであり、溶媒としては主に水が用いられる。水としては、イオン交換水や逆浸透膜水等の精製水や、通常の水道水や工業用水、海洋深層水等が挙げられる。 The deodorant for textile products of the present invention is of a water-based type, and water is mainly used as a solvent. Examples of water include purified water such as ion-exchanged water and reverse osmosis membrane water, normal tap water, industrial water, deep sea water, and the like.
更に、本発明の繊維製品用消臭剤には、その他の成分として、必要に応じて、無機抗菌剤、有機抗菌剤、防藻剤、防錆剤、溶剤、キレート剤、香料、消臭成分等を、本発明の効果を損なわない範囲で配合することにより、抗菌効果、防藻効果、防錆効果、洗浄効果、芳香性、消臭性等を付与するようにしてもよい。 Furthermore, the deodorant for textile products of the present invention may optionally contain other components such as an inorganic antibacterial agent, an organic antibacterial agent, an anti-algae agent, an anti-rust agent, a solvent, a chelating agent, a fragrance, and a deodorant component. etc. may be added within a range that does not impair the effects of the present invention to impart antibacterial effects, anti-algae effects, anti-corrosion effects, cleaning effects, fragrant properties, deodorant properties, and the like.
こうして得られた本発明の繊維製品用消臭剤を、繊維製品に対してトリガースプレー又はエアゾールスプレーでスプレーすることにより消臭効果、風合い改善効果を得ることができる。好ましくは繊維製品用消臭剤を繊維製品１平方メートル当たり５ｇから１００ｇをスプレーすることが望ましい。５ｇ以下であると十分な消臭効果、風合い改善効果が認められず、１００ｇ以上では対象物が完全に濡れてしまい乾燥に時間がかかるとともに消臭効率や風合い改善効果も良くない。 The thus obtained deodorant for textile products of the present invention can be sprayed on textile products with a trigger spray or an aerosol spray to obtain a deodorizing effect and an effect of improving texture. Preferably, 5 to 100 g of textile deodorant is sprayed per square meter of textile. If the amount is less than 5 g, no sufficient deodorant effect or texture improvement effect is observed, and if the amount is more than 100 g, the object will be completely wet, and drying will take a long time.
なお、本発明は上述した実施形態に限定されるものではなく、請求項に示した範囲で種々の変更が可能であり、異なる実施形態にそれぞれ開示された技術的手段を適宜組み合わせて得られる実施形態についても本発明の技術的範囲に含まれる。以下、実施例により本発明の効果について更に具体的に説明するが、本発明はこれらの実施例に制約されるものではない。 In addition, the present invention is not limited to the above-described embodiments, and various modifications are possible within the scope of the claims, and implementations obtained by appropriately combining technical means disclosed in different embodiments. The form is also included in the technical scope of the present invention. EXAMPLES Hereinafter, the effects of the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples.
[試験液の調製]
（Ａ）消臭成分・剛軟度付与成分として、炭酸水素ナトリウム（和光純薬工業社製）、（Ｂ）消臭成分・剛軟度調整成分として、サトウキビ抽出物（ＭＳＸ－２４５、三井製糖社製）、柿抽出物（パンシルＦＧ－６０、リリース科学工業社製）、イチョウ、イチジク、レンギョウ抽出物の混合物（スーパーピュリエールＡ－１００、パナソニック化成社製）を表１、表２に示す配合割合（質量％）で配合し、（Ｃ）イオン交換水を加えて１００重量％として試験液（本発明１～１７）を得た。
[Preparation of test solution]
(A) Sodium bicarbonate (manufactured by Wako Pure Chemical Industries, Ltd.) as a deodorizing component and bending resistance imparting component, (B) Sugarcane extract (MSX-245, Mitsui Sugar Co., Ltd.) as a deodorizing component and bending resistance adjusting component Co., Ltd.), persimmon extract (Pancil FG-60, Release Science Industry Co., Ltd.), ginkgo biloba, fig, and forsythia extract mixture (Super Puriere A-100, Panasonic Chemical Co., Ltd.) are shown in Tables 1 and 2. They were blended at a blending ratio (% by mass), and (C) ion-exchanged water was added to make 100% by weight to obtain test solutions (Inventions 1 to 17).
（Ａ）消臭成分・剛軟度付与成分として、炭酸水素ナトリウム、炭酸水素カリウム、炭酸ナトリウム、乳酸ナトリウム（以上、和光純薬工業社製）、（Ｂ）消臭成分・剛軟度調整成分として、サトウキビ抽出物（ＭＳＸ－２４５、三井製糖社製）、柿抽出物（パンシルＦＧ－６０、リリース科学工業社製）、イチョウ、イチジク、レンギョウ抽出物の混合物（スーパーピュリエールＡ－１００、パナソニック化成社製）を表３、表４に示す配合割合（質量％）で配合し、（Ｃ）イオン交換水を加えて１００重量％として試験液（比較例１～１８）を得た。 (A) Deodorizing component/bending stiffness imparting component: sodium hydrogen carbonate, potassium hydrogen carbonate, sodium carbonate, sodium lactate (manufactured by Wako Pure Chemical Industries, Ltd.), (B) deodorizing component/bending stiffness adjusting component As, sugar cane extract (MSX-245, manufactured by Mitsui Sugar Co., Ltd.), persimmon extract (Pancil FG-60, manufactured by Release Science Industry Co., Ltd.), ginkgo biloba, fig, forsythia extract mixture (Super Puriere A-100, Panasonic (manufactured by Kasei Co., Ltd.) was blended at the blending ratio (% by mass) shown in Tables 3 and 4, and (C) ion-exchanged water was added to make 100% by weight to obtain test solutions (Comparative Examples 1 to 18).
［消臭効果の確認試験］
タバコ臭、汗臭または尿臭を付着させた綿布（５×５ｃｍ）に、本発明、比較例の試験液をトリガースプレーで２０ｃｍの距離から３回スプレー（付着量約０．０７ｇ）し、１０００ｍＬの三角フラスコに入れ、直後及び６０分後に８人のパネラーによって官能評価を行った。
[Confirmation test of deodorant effect]
A test solution of the present invention or a comparative example was sprayed 3 times from a distance of 20 cm with a trigger spray (attachment amount: about 0.07 g) on a cotton cloth (5 x 5 cm) to which tobacco odor, sweat odor or urine odor was attached, and 1000 mL. Immediately after and 60 minutes later, sensory evaluation was carried out by eight panelists.
評価基準としては、タバコ臭、汗臭または尿臭を感じない場合を○、タバコ臭、汗臭または尿臭とわかるが弱い場合を△、タバコ臭、汗臭または尿臭と明らかにわかる場合を×とした。 The evaluation criteria were as follows: ○ when no odor of tobacco, sweat or urine was detected; △ when recognizable but weak odor of tobacco, sweat or urine; and when clearly recognizable as odor of tobacco, sweat or urine. x.
［剛軟度増加率の測定試験］
ポリエステル布（テトロンタフタ布：厚さ０．１０ｍｍ、坪量約６０ｇ／ｍ2、東レ社製）の試験片（２ｃｍ×１５ｃｍ）５枚に本発明、比較例の試験液をトリガースプレーで２０ｃｍの距離から３回スプレー（付着量約０．０８ｇ）し、乾燥させた。乾燥後の試験片の剛軟度をＪＩＳ Ｌ１０９６に記載の４５°カンチレバー法により測定した。具体的には、水平の台の一端が４５°の斜面をもつ測定器の上に各試験片を置き、適当な方法で水平の台の上を緩やかに滑らせた。そして、試験片の一端が自重と自身の柔らかさにより４５°の斜面に接触した時点で、試験片が移動した長さ（ｍｍ）を測定し、その平均値を剛軟度とした。そして、試験液を塗布する前の布に対する剛軟度の増加率を算出した。
[Measurement test of bending resistance increase rate]
Five test pieces (2 cm × 15 cm) of polyester cloth (Tetoron taffeta cloth: thickness 0.10 mm, basis weight about 60 g/m 2 , manufactured by Toray Industries, Inc.) were sprayed with the test solutions of the present invention and the comparative example to 20 cm by trigger spraying. It was sprayed three times from a distance (approximately 0.08 g coverage) and allowed to dry. The bending resistance of the dried test piece was measured by the 45° cantilever method described in JIS L1096. Specifically, each test piece was placed on a measuring instrument having a 45° slope at one end of a horizontal platform, and gently slid over the horizontal platform by an appropriate method. Then, when one end of the test piece touched the 45° slope due to its own weight and its own softness, the length (mm) of movement of the test piece was measured, and the average value was taken as the bending resistance. Then, the rate of increase in bending resistance relative to the cloth before applying the test solution was calculated.
[風合い改善効果についての評価試験]
前記[剛軟度増加率の測定試験]にて用いた測定後の試験布および同サイズの未処理布について、５名の評価者の触感の比較による評価を行った。評価基準は、未処理布との差が感じられない場合、あるいはゴワツキを感じた場合を×とし、適度なコシのある触感を感じた場合を○とし、全員の評価結果を平均したものを最終評価とした。消臭効果、剛軟度増加率の測定結果、風合い改善効果の評価試験結果を試験液の配合と併せて表１～表４に示す。
[Evaluation test on texture improvement effect]
The test cloth after the measurement used in the above [measurement test of bending resistance increase rate] and the untreated cloth of the same size were evaluated by comparing the tactile sensations of five evaluators. The evaluation criteria were as follows: when there was no difference from the untreated cloth, or when the cloth felt stiff; was evaluated. Tables 1 to 4 show the deodorant effect, measurement results of bending resistance increase rate, and evaluation test results of hand feeling improvement effect together with the composition of the test solution.
表１、表２に示すように、炭酸水素ナトリウムを０．０５～０．１５質量％配合し、サトウキビ抽出物、柿抽出物、またはイチョウ、イチジク、レンギョウ抽出物の混合物を炭酸水素ナトリウムに対する配合比が１：０．５～１：５となるように配合した本発明１～１７では、タバコ臭、汗臭、尿臭のいずれに対しても優れた消臭効果を示した。また、乾燥後の試験片の剛軟度増加率がいずれも１１０％～１４５％の範囲となり、適度なハリやコシが付与されて風合いが改善された。 As shown in Tables 1 and 2, 0.05 to 0.15% by mass of sodium hydrogen carbonate is blended, and a mixture of sugarcane extract, persimmon extract, or ginkgo biloba, fig, and forsythia extract is added to sodium hydrogen carbonate. Inventions 1 to 17, which were blended at a ratio of 1:0.5 to 1:5, exhibited excellent deodorant effects against cigarette odor, sweat odor, and urine odor. In addition, the rate of increase in bending resistance of the test pieces after drying was in the range of 110% to 145%, and the feel was improved by imparting appropriate firmness and stiffness.
これに対し、表３、表４に示すように、炭酸水素ナトリウムのみを配合した比較例１では、尿臭に対する消臭効果がなく、乾燥後の試験片の剛軟度増加率も１４５％を超えてしまいゴワつきが発生した。また、サトウキビ抽出物、柿抽出物、植物抽出物のみを配合した比較例２～４では、タバコ臭、汗臭に対する消臭効果が十分でなく、乾燥後の試験片の剛軟度増加率も１１０％未満となり風合い改善効果も認められなかった。 On the other hand, as shown in Tables 3 and 4, in Comparative Example 1 containing only sodium bicarbonate, there was no deodorizing effect on urine odor, and the bending resistance increase rate of the test piece after drying was 145%. It was exceeded, and stiffness occurred. In addition, in Comparative Examples 2 to 4, in which only sugarcane extract, persimmon extract, and plant extract were blended, the deodorant effect against tobacco odor and sweat odor was not sufficient, and the bending resistance increase rate of the test piece after drying was low. The result was less than 110%, and no feeling improvement effect was observed.
また、炭酸水素ナトリウムに対するサトウキビ抽出物、柿抽出物の配合比を１：０．２５とした比較例５、６では尿臭に対する消臭効果が十分でなく、乾燥後の試験片の剛軟度増加率も１４５％を超えてしまいゴワつきが発生した。炭酸水素ナトリウムの配合量を０．２質量％とした比較例７～１０では、サトウキビ抽出物の配合量に関係なく乾燥後の試験片の剛軟度増加率が１４５％を超えてしまいゴワつきが発生した。一方、炭酸水素ナトリウムの配合量を０．０５質量％未満とした比較例１１、１２では、タバコ臭、汗臭、尿臭に対する消臭効果は認められたが乾燥後の試験片の剛軟度増加率が１１０％未満となり風合い改善効果が認められなかった。 In addition, in Comparative Examples 5 and 6, in which the blending ratio of sugarcane extract and persimmon extract to sodium hydrogen carbonate was 1:0.25, the deodorizing effect against urine odor was not sufficient, and the bending resistance of the test piece after drying was The increase rate exceeded 145%, and stiffening occurred. In Comparative Examples 7 to 10 in which the amount of sodium bicarbonate was 0.2% by mass, the rate of increase in bending resistance of the test piece after drying exceeded 145% regardless of the amount of sugarcane extract. There has occurred. On the other hand, in Comparative Examples 11 and 12 in which the amount of sodium bicarbonate was less than 0.05% by mass, the deodorant effect against cigarette odor, sweat odor, and urine odor was observed, but the bending resistance of the test piece after drying was The rate of increase was less than 110%, and no improvement in texture was observed.
また、炭酸水素ナトリウムに代えて炭酸水素カリウムを配合した比較例１３、１４では、サトウキビ抽出物の配合の有無に係わらずタバコ臭、汗臭、尿臭に対する消臭効果が十分ではなく、乾燥後の試験片の剛軟度増加率も１１０％未満となり風合い改善効果も認められなかった。また、炭酸水素ナトリウムに代えて炭酸ナトリウムを配合した比較例１５、１６では、試験片の剛軟度増加率が１１４％、１１９％となり風合い改善効果は認められたが、汗臭、尿臭に対する消臭効果が認められなかった。さらに、炭酸水素ナトリウムに代えて乳酸ナトリウムを配合した比較例１７、１８では、サトウキビ抽出物の配合の有無に係わらずタバコ臭、汗臭、尿臭に対する消臭効果が十分ではなく、乾燥後の試験片の剛軟度増加率も１１０％未満となり風合い改善効果も認められなかった。 In addition, in Comparative Examples 13 and 14, in which potassium hydrogen carbonate was blended instead of sodium hydrogen carbonate, the deodorant effect against tobacco odor, sweat odor, and urine odor was not sufficient regardless of the presence or absence of the sugarcane extract. The rate of increase in bending resistance of the test piece was less than 110%, and no effect of improving hand feeling was observed. In addition, in Comparative Examples 15 and 16 in which sodium carbonate was blended instead of sodium hydrogencarbonate, the bending resistance increase rate of the test piece was 114% and 119%, and the effect of improving the texture was recognized, but the sweat odor and urine odor No deodorant effect was observed. Furthermore, in Comparative Examples 17 and 18, in which sodium lactate was blended instead of sodium bicarbonate, the deodorant effect against cigarette odor, sweat odor, and urine odor was not sufficient regardless of the presence or absence of the sugarcane extract. The rate of increase in bending resistance of the test piece was less than 110%, and no effect of improving hand feeling was observed.
以上の結果から、炭酸水素ナトリウムの配合量を０．０５質量％以上０．１５質量％以下とし、サトウキビ抽出物、柿抽出物、またはイチョウ、イチジク、レンギョウ抽出物の混合物を炭酸水素ナトリウムに対し１：０．５～１：５の配合比で配合することで、タバコ臭、汗臭、尿臭に対して優れた消臭効果を有し、且つ、処理後の繊維製品の風合い改善効果も得られることが確認された。 From the above results, the amount of sodium hydrogen carbonate is set to 0.05% by mass or more and 0.15% by mass or less, and a mixture of sugarcane extract, persimmon extract, or ginkgo biloba, fig, and forsythia extract is added to sodium hydrogen carbonate. By blending at a blending ratio of 1:0.5 to 1:5, it has an excellent deodorizing effect against cigarette odor, sweat odor, and urine odor, and also has an effect of improving the texture of textile products after treatment. confirmed to be obtained.
［繊維製品用消臭剤の作製］
消臭成分・剛軟度付与成分として炭酸水素ナトリウムを０．１質量％、消臭成分・剛軟度調整成分としてサトウキビ抽出物（ＭＳＸ－２４５、三井製糖社製）を０．１質量％、カチオン性界面活性剤としてニッサンカチオンＦ２－５０Ｒ（塩化ベンザルコニウム５０％含有、日油社製）０．２質量％、９５度エタノールを５質量％、香料（フローラル系）を０．０１質量％加えたものに、最終的にバランスとして精製水を加えて１００質量％に調製し、よく混合して繊維製品用消臭剤を作製した。
[Preparation of deodorant for textile products]
0.1% by mass of sodium bicarbonate as a deodorizing component/bending property imparting component, 0.1% by mass of sugarcane extract (MSX-245, manufactured by Mitsui Sugar Co., Ltd.) as a deodorizing component/bending property adjusting component, Nissan cation F2-50R (containing 50% benzalkonium chloride, manufactured by NOF Corporation) as a cationic surfactant 0.2% by mass, 5% by mass of 95° ethanol, and 0.01% by mass of fragrance (floral type) Purified water was finally added to the added material as a balance to adjust the concentration to 100% by mass, and the mixture was thoroughly mixed to prepare a deodorant for textile products.
作製された繊維製品用消臭剤を、トリガースプレー（１回の吐出量が約０．７ｃｃ）を用いてタバコ臭、汗臭、尿臭の付着したポリエステル製の繊維製品に適量噴霧した結果、いずれの臭気もほとんど消臭した。さらに、繊維製品に適度なハリやコシを付与することができ、風合いも改善された。 As a result of spraying an appropriate amount of the produced deodorant for textiles on polyester textiles with tobacco odor, sweat odor, and urine odor using a trigger spray (one discharge amount is about 0.7 cc), Almost all odors were eliminated. Furthermore, it was possible to impart appropriate tension and stiffness to the textile product, and the texture was also improved.
本発明は、繊維製品に付着したタバコ臭、汗臭、尿臭、ペット臭等の種々の悪臭に対して顕著な消臭効果を有し、且つ、消臭と同時に繊維製品にハリやコシも付与することができる繊維製品用消臭剤として好適に用いられる。 INDUSTRIAL APPLICABILITY The present invention has a remarkable deodorizing effect on various bad odors such as tobacco odor, sweat odor, urine odor and pet odor adhering to textile products, and at the same time deodorizes and gives firmness and elasticity to textile products. It is suitably used as a deodorant for textile products that can be applied.
Claims (9)
（Ｂ）消臭成分・剛軟度調整成分として植物抽出物と、
（Ｃ）水と、
を含有し、前記炭酸水素ナトリウムの配合量が０．０５質量％以上０．１５質量％以下であることを特徴とする繊維製品用消臭剤。 (A) Sodium hydrogen carbonate as a deodorizing component and a bending resistance imparting component;
(B) a plant extract as a deodorizing component and a bending resistance adjusting component;
(C) water;
A deodorant for textile products , characterized in that the content of sodium hydrogen carbonate is 0.05% by mass or more and 0.15% by mass or less .
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP3090951B2 (en) | 1994-08-12 | 2000-09-25 | ザ、プロクター、エンド、ギャンブル、カンパニー | Composition for reducing odor impression on non-living surfaces |
| JP2003095905A (en) | 2001-09-27 | 2003-04-03 | Nagase & Co Ltd | Deodorant for oral cavity |
| JP2004049889A (en) | 2002-05-30 | 2004-02-19 | Shiseido Co Ltd | Deodorant composition |
| JP2005143770A (en) | 2003-11-14 | 2005-06-09 | Katayama Chem Works Co Ltd | Industrial deodorant |
| JP2009530014A (en) | 2006-03-22 | 2009-08-27 | 高砂香料工業株式会社 | Deodorant composition |
| JP2019099546A (en) | 2017-12-07 | 2019-06-24 | 株式会社カミノ | Deodorant and bactericidal agent |
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| JP3090951B2 (en) | 1994-08-12 | 2000-09-25 | ザ、プロクター、エンド、ギャンブル、カンパニー | Composition for reducing odor impression on non-living surfaces |
| JP2003095905A (en) | 2001-09-27 | 2003-04-03 | Nagase & Co Ltd | Deodorant for oral cavity |
| JP2004049889A (en) | 2002-05-30 | 2004-02-19 | Shiseido Co Ltd | Deodorant composition |
| JP2005143770A (en) | 2003-11-14 | 2005-06-09 | Katayama Chem Works Co Ltd | Industrial deodorant |
| JP2009530014A (en) | 2006-03-22 | 2009-08-27 | 高砂香料工業株式会社 | Deodorant composition |
| JP2019099546A (en) | 2017-12-07 | 2019-06-24 | 株式会社カミノ | Deodorant and bactericidal agent |
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