JP7032142B2 - 熱処理温度の変化で加工性又は透光性の調節が可能な結晶化ガラスの製造方法 - Google Patents
熱処理温度の変化で加工性又は透光性の調節が可能な結晶化ガラスの製造方法 Download PDFInfo
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- JP7032142B2 JP7032142B2 JP2018002835A JP2018002835A JP7032142B2 JP 7032142 B2 JP7032142 B2 JP 7032142B2 JP 2018002835 A JP2018002835 A JP 2018002835A JP 2018002835 A JP2018002835 A JP 2018002835A JP 7032142 B2 JP7032142 B2 JP 7032142B2
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/012—Tempering or quenching glass products by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/831—Preparations for artificial teeth, for filling teeth or for capping teeth comprising non-metallic elements or compounds thereof, e.g. carbon
- A61K6/833—Glass-ceramic composites
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/831—Preparations for artificial teeth, for filling teeth or for capping teeth comprising non-metallic elements or compounds thereof, e.g. carbon
- A61K6/836—Glass
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/831—Preparations for artificial teeth, for filling teeth or for capping teeth comprising non-metallic elements or compounds thereof, e.g. carbon
- A61K6/838—Phosphorus compounds, e.g. apatite
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B32/00—Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
- C03B32/02—Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
- C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
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- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Ceramic Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Health & Medical Sciences (AREA)
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- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
- Dental Prosthetics (AREA)
- Dental Preparations (AREA)
Description
Claims (6)
- SiO260~83重量%、
Li2O10~15重量%、
核形成剤の役割を行うP2O52~6重量%、
ガラス転移温度と軟化点を増加させ、ガラスの化学的耐久性を増大させるAl2O31~5重量%、
ガラスの軟化点を増加させるSrO0.1~3重量%、
ZnO0.1~2重量%、
着色剤(colorant)1~5重量%;及び
ガラスの熱膨張係数を増加させるNa2OとK2Oとの混合物2.5~6重量%を含むガラス組成物を480乃至800℃で1次熱処理して、30乃至500nmのリチウムジシリケートと、結晶相をX線回折分析したときに回折角2 thetaが22度近傍と27度近傍でピークを示すシリカ結晶相を主結晶相として含み、
加工後に2次熱処理の温度によって透過性が調節されることを特徴とする、シリカ結晶相を含む結晶化ガラス。 - SiO260~83重量%、
Li2O10~15重量%、
核形成剤の役割を行うP2O52~6重量%、
ガラス転移温度と軟化点を増加させ、ガラスの化学的耐久性を増大させるAl2O31~5重量%、
ガラスの軟化点を増加させるSrO0.1~3重量%、
ZnO0.1~2重量%、
着色剤(colorant)1~5重量%、及び
ガラスの熱膨張係数を増加させるNa2OとK2Oとの混合物2.5~6重量%を含むガラス組成物を480乃至800℃で1次熱処理し、
前記1次熱処理によって、30乃至500nmのリチウムジシリケートと結晶相をX線回折分析したときに回折角2 thetaが22度近傍と27度近傍でピークを示すシリカ結晶相が生成される特徴とする、シリカ結晶相を含む結晶化ガラスの製造方法。 - 前記1次熱処理の後、
780乃至880℃で2次熱処理を行い、
前記2次熱処理の温度によって透光性が調節されることを特徴とする請求項2に記載のシリカ結晶相を含む結晶化ガラスの製造方法。 - 前記リチウムジシリケート結晶相及びシリカ結晶相の大きさは0.3~5.5μmであることを特徴とする請求項3に記載のシリカ結晶相を含む結晶化ガラスの製造方法。
- 前記リチウムジシリケート結晶相及びシリカ結晶相の高い半透明度(high translucency)は780~820℃、中間半透明度(medium translucency)は821~840℃、低い半透明度(low translucency)は841~860℃及び中間透明度(medium opacity)は861~880℃であり、
維持時間は1分乃至2時間であることを特徴とする請求項3に記載のシリカ結晶相を含む結晶化ガラスの製造方法。 - 前記リチウムジシリケート結晶相及びシリカ結晶相の光透過率は550nmで55%乃至27%であることを特徴とする請求項5に記載のシリカ結晶相を含む結晶化ガラスの製造方法。
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KR1020170028705A KR101975548B1 (ko) | 2017-03-07 | 2017-03-07 | 열처리 온도의 변화로 가공성 또는 투광성 조절이 가능한 결정화 유리 제조 방법 |
KR10-2017-0028705 | 2017-03-07 |
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KR102228118B1 (ko) * | 2019-02-12 | 2021-03-16 | 주식회사 하스 | 결정화 유리를 포함하는 치과용 복합체 |
US20220183803A1 (en) * | 2019-03-29 | 2022-06-16 | Gc Corporation | Method of producing block for dental prostheses, and method of producing dental prosthesis |
US20220183802A1 (en) * | 2019-03-29 | 2022-06-16 | Gc Corporation | Block for dental prostheses |
KR102246195B1 (ko) * | 2019-05-29 | 2021-04-29 | 주식회사 하스 | 절삭가공을 위한 치과용 벌크 블록 및 그 제조방법 |
KR102446072B1 (ko) * | 2020-09-28 | 2022-09-23 | 주식회사 하스 | 절삭가공을 위한 치과용 벌크 블록 및 그 제조방법 |
KR102446071B1 (ko) | 2020-09-28 | 2022-09-22 | 주식회사 하스 | 절삭가공을 위한 치과용 벌크 블록 및 그 제조방법 |
EP4349299A1 (en) | 2021-05-28 | 2024-04-10 | Hass Co., Ltd. | Dental bulk block to be cut and manufacturing method therefor |
JP2024519122A (ja) | 2021-05-28 | 2024-05-08 | ハス カンパニー リミテッド | 切削加工のための歯科用バルクブロック及びその製造方法 |
EP4349300A1 (en) | 2021-05-28 | 2024-04-10 | Hass Co., Ltd. | Dental bulk block for cutting machining and manufacturing method therefor |
KR102542448B1 (ko) | 2021-06-15 | 2023-06-07 | 주식회사 하스 | 치과용 벌크 블록 및 그 제조방법 |
KR102519286B1 (ko) | 2021-07-26 | 2023-04-10 | 주식회사 하스 | 치과용 벌크 블록 및 그 제조방법 |
KR102642739B1 (ko) * | 2021-07-26 | 2024-03-04 | 주식회사 하스 | 글라스 세라믹 기판의 제조방법 및 이로부터 제조된 글라스 세라믹 기판 |
CN114524616B (zh) * | 2022-03-01 | 2024-02-06 | 山东国瓷功能材料股份有限公司 | 具有不同透光度的二硅酸锂玻璃陶瓷坯体及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015173394A1 (de) | 2014-05-16 | 2015-11-19 | Ivoclar Vivadent Ag | Glaskeramik mit sio2 als hauptkristallphase |
JP2016514078A (ja) | 2013-02-12 | 2016-05-19 | イフォクレール ヴィヴァデント アクチェンゲゼルシャフトIvoclar Vivadent AG | 歯科用の素材 |
JP2016522134A (ja) | 2013-04-15 | 2016-07-28 | イフォクレール ヴィヴァデント アクチェンゲゼルシャフトIvoclar Vivadent AG | 酸化セシウムを含有する、ケイ酸リチウムガラスセラミックおよびケイ酸リチウムガラス |
EP3135641A1 (de) | 2015-08-25 | 2017-03-01 | Ivoclar Vivadent AG | Lithiumsilikat-tiefquarz-glaskeramik |
US20170057865A1 (en) | 2015-08-26 | 2017-03-02 | Hass Co., Ltd. | Dental glass-ceramics block bonded with abutment and preparation method thereof |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3416033B2 (ja) * | 1996-09-05 | 2003-06-16 | 株式会社オハラ | 磁気ヘッド用結晶化ガラス基板およびその製造方法 |
JP2000086289A (ja) | 1998-09-10 | 2000-03-28 | Ngk Insulators Ltd | 結晶化ガラスの核形成剤、結晶化ガラス、磁気ディスク基板および磁気ディスク |
EP1396237A1 (en) | 2002-09-05 | 2004-03-10 | Elephant Dental B.V. | Strengthened ceramic restoration |
BRPI0300644B8 (pt) * | 2003-02-20 | 2022-04-26 | Fundacao Univ Federal De Sao Carlos | Processo de preparação de biosilicatos particulados, bioativos e reabsorvíveis, composições para preparar ditos biosilicatos e biosilicatos particulados bioativos e reabsorvíveis. |
KR101262121B1 (ko) * | 2010-12-27 | 2013-05-14 | 주식회사 하스 | 치아용 고강도 결정화유리의 제조방법 |
US9371249B2 (en) * | 2012-05-04 | 2016-06-21 | Ivoclar Vivadent Ag | Lithium disilicate-apatite glass-ceramic |
FR2990690B1 (fr) * | 2012-05-15 | 2016-01-01 | Eurokera | Vitroceramiques de quartz-beta, transparentes, essentiellement incolores et non diffusantes; articles en lesdites vitroceramiques; verres precurseurs |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016514078A (ja) | 2013-02-12 | 2016-05-19 | イフォクレール ヴィヴァデント アクチェンゲゼルシャフトIvoclar Vivadent AG | 歯科用の素材 |
JP2016522134A (ja) | 2013-04-15 | 2016-07-28 | イフォクレール ヴィヴァデント アクチェンゲゼルシャフトIvoclar Vivadent AG | 酸化セシウムを含有する、ケイ酸リチウムガラスセラミックおよびケイ酸リチウムガラス |
WO2015173394A1 (de) | 2014-05-16 | 2015-11-19 | Ivoclar Vivadent Ag | Glaskeramik mit sio2 als hauptkristallphase |
EP3135641A1 (de) | 2015-08-25 | 2017-03-01 | Ivoclar Vivadent AG | Lithiumsilikat-tiefquarz-glaskeramik |
US20170057865A1 (en) | 2015-08-26 | 2017-03-02 | Hass Co., Ltd. | Dental glass-ceramics block bonded with abutment and preparation method thereof |
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JP2018145084A (ja) | 2018-09-20 |
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KR101975548B9 (ko) | 2022-10-21 |
CN108117263A (zh) | 2018-06-05 |
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