JP6847393B2 - 改良されたレオロジー特性を有するポリシロキサン−ポリカーボネートブロック共縮合物 - Google Patents
改良されたレオロジー特性を有するポリシロキサン−ポリカーボネートブロック共縮合物 Download PDFInfo
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- JP6847393B2 JP6847393B2 JP2016549292A JP2016549292A JP6847393B2 JP 6847393 B2 JP6847393 B2 JP 6847393B2 JP 2016549292 A JP2016549292 A JP 2016549292A JP 2016549292 A JP2016549292 A JP 2016549292A JP 6847393 B2 JP6847393 B2 JP 6847393B2
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- Prior art keywords
- polysiloxane
- siloxane
- polycarbonate block
- polycarbonate
- carbonate
- Prior art date
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- 229920000515 polycarbonate Polymers 0.000 title claims description 125
- 239000004417 polycarbonate Substances 0.000 title claims description 125
- 229920001400 block copolymer Polymers 0.000 title claims description 49
- -1 Polysiloxane Polymers 0.000 claims description 106
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 78
- 238000000034 method Methods 0.000 claims description 56
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 238000009826 distribution Methods 0.000 claims description 15
- 229920001296 polysiloxane Polymers 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- 238000005809 transesterification reaction Methods 0.000 claims description 13
- 238000000386 microscopy Methods 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- 238000004630 atomic force microscopy Methods 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 2
- 125000001118 alkylidene group Chemical group 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 150000007942 carboxylates Chemical group 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 44
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 30
- 239000003054 catalyst Substances 0.000 description 30
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 28
- 239000000203 mixture Substances 0.000 description 24
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 20
- 230000008569 process Effects 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 19
- 239000000047 product Substances 0.000 description 19
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 description 18
- 239000000155 melt Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 14
- 239000000654 additive Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 13
- 239000004594 Masterbatch (MB) Substances 0.000 description 12
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 10
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 230000002829 reductive effect Effects 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 8
- 229910052783 alkali metal Inorganic materials 0.000 description 8
- 229910017053 inorganic salt Inorganic materials 0.000 description 8
- ZLLNYWQSSYUXJM-UHFFFAOYSA-M tetraphenylphosphanium;phenoxide Chemical compound [O-]C1=CC=CC=C1.C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 ZLLNYWQSSYUXJM-UHFFFAOYSA-M 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 150000004714 phosphonium salts Chemical class 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 150000001491 aromatic compounds Chemical class 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- 229930185605 Bisphenol Natural products 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical group CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- RLGQACBPNDBWTB-UHFFFAOYSA-N cetyltrimethylammonium ion Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)C RLGQACBPNDBWTB-UHFFFAOYSA-N 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000012760 heat stabilizer Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 150000004679 hydroxides Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000012744 reinforcing agent Substances 0.000 description 3
- 238000010079 rubber tapping Methods 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- CJWNFAKWHDOUKL-UHFFFAOYSA-N 2-(2-phenylpropan-2-yl)phenol Chemical compound C=1C=CC=C(O)C=1C(C)(C)C1=CC=CC=C1 CJWNFAKWHDOUKL-UHFFFAOYSA-N 0.000 description 2
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 2
- NFAOATPOYUWEHM-UHFFFAOYSA-N 2-(6-methylheptyl)phenol Chemical compound CC(C)CCCCCC1=CC=CC=C1O NFAOATPOYUWEHM-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- XHASMJXNUHCHBL-UHFFFAOYSA-N 4-(1-phenylethyl)phenol Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=CC=C1 XHASMJXNUHCHBL-UHFFFAOYSA-N 0.000 description 2
- BRPSWMCDEYMRPE-UHFFFAOYSA-N 4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=C(O)C=C1 BRPSWMCDEYMRPE-UHFFFAOYSA-N 0.000 description 2
- ODJUOZPKKHIEOZ-UHFFFAOYSA-N 4-[2-(4-hydroxy-3,5-dimethylphenyl)propan-2-yl]-2,6-dimethylphenol Chemical compound CC1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=C(C)C=2)=C1 ODJUOZPKKHIEOZ-UHFFFAOYSA-N 0.000 description 2
- PVFQHGDIOXNKIC-UHFFFAOYSA-N 4-[2-[3-[2-(4-hydroxyphenyl)propan-2-yl]phenyl]propan-2-yl]phenol Chemical compound C=1C=CC(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 PVFQHGDIOXNKIC-UHFFFAOYSA-N 0.000 description 2
- ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 2
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical group [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- 229920004142 LEXAN™ Polymers 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000012963 UV stabilizer Substances 0.000 description 2
- VLVUZJNSDUWQOO-UHFFFAOYSA-N [2-(4-phenylphenyl)phenyl] hydrogen carbonate Chemical compound OC(=O)OC1=CC=CC=C1C1=CC=C(C=2C=CC=CC=2)C=C1 VLVUZJNSDUWQOO-UHFFFAOYSA-N 0.000 description 2
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 125000004423 acyloxy group Chemical group 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000000089 atomic force micrograph Methods 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 2
- MHFGNKMUCULCRW-UHFFFAOYSA-N bis(4-phenylphenyl) carbonate Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1OC(=O)OC(C=C1)=CC=C1C1=CC=CC=C1 MHFGNKMUCULCRW-UHFFFAOYSA-N 0.000 description 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- NKOPSNSLUIFZFO-UHFFFAOYSA-N carbonic acid;2-methoxybenzoic acid Chemical compound OC(O)=O.COC1=CC=CC=C1C(O)=O.COC1=CC=CC=C1C(O)=O NKOPSNSLUIFZFO-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
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- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- VURFVHCLMJOLKN-UHFFFAOYSA-N diphosphane Chemical compound PP VURFVHCLMJOLKN-UHFFFAOYSA-N 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
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- 150000004820 halides Chemical class 0.000 description 2
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- 150000002431 hydrogen Chemical class 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 238000000399 optical microscopy Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 229940086560 pentaerythrityl tetrastearate Drugs 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
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- OSWMMVUHYHQYCV-UHFFFAOYSA-N tetrabenzylazanium Chemical compound C=1C=CC=CC=1C[N+](CC=1C=CC=CC=1)(CC=1C=CC=CC=1)CC1=CC=CC=C1 OSWMMVUHYHQYCV-UHFFFAOYSA-N 0.000 description 1
- SBCUXVQZGCKZET-UHFFFAOYSA-N tetrabenzylphosphanium Chemical compound C=1C=CC=CC=1C[P+](CC=1C=CC=CC=1)(CC=1C=CC=CC=1)CC1=CC=CC=C1 SBCUXVQZGCKZET-UHFFFAOYSA-N 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- MRYQZMHVZZSQRT-UHFFFAOYSA-M tetramethylazanium;acetate Chemical compound CC([O-])=O.C[N+](C)(C)C MRYQZMHVZZSQRT-UHFFFAOYSA-M 0.000 description 1
- CZMILNXHOAKSBR-UHFFFAOYSA-N tetraphenylazanium Chemical compound C1=CC=CC=C1[N+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 CZMILNXHOAKSBR-UHFFFAOYSA-N 0.000 description 1
- USFPINLPPFWTJW-UHFFFAOYSA-N tetraphenylphosphonium Chemical compound C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 USFPINLPPFWTJW-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- GRAKJTASWCEOQI-UHFFFAOYSA-N tridodecylphosphane Chemical compound CCCCCCCCCCCCP(CCCCCCCCCCCC)CCCCCCCCCCCC GRAKJTASWCEOQI-UHFFFAOYSA-N 0.000 description 1
- DMEUUKUNSVFYAA-UHFFFAOYSA-N trinaphthalen-1-ylphosphane Chemical compound C1=CC=C2C(P(C=3C4=CC=CC=C4C=CC=3)C=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 DMEUUKUNSVFYAA-UHFFFAOYSA-N 0.000 description 1
- KJFAJLYXKTVJDA-UHFFFAOYSA-N trioctadecylphosphane Chemical compound CCCCCCCCCCCCCCCCCCP(CCCCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCCCC KJFAJLYXKTVJDA-UHFFFAOYSA-N 0.000 description 1
- ITHPEWAHFNDNIO-UHFFFAOYSA-N triphosphane Chemical compound PPP ITHPEWAHFNDNIO-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- IUURMAINMLIZMX-UHFFFAOYSA-N tris(2-nonylphenyl)phosphane Chemical compound CCCCCCCCCC1=CC=CC=C1P(C=1C(=CC=CC=1)CCCCCCCCC)C1=CC=CC=C1CCCCCCCCC IUURMAINMLIZMX-UHFFFAOYSA-N 0.000 description 1
- 238000000825 ultraviolet detection Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
- C08G77/448—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences containing polycarbonate sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
- C08G64/186—Block or graft polymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
Description
(A)式(1)のポリシロキサンブロック:
R1はH、Cl、Br又はC1〜C4−アルキル、好ましくはH又はメチル、特に好ましくはHであり、
R2及びR3はそれぞれ互いに独立して、アリール、C1〜C10−アルキル及びC1〜C10−アルキルアリールから選択され、好ましくはR2及びR3はメチルであり、
Xは単結合、−CO−、−O−、C1〜C6−アルキレン、C2〜C5−アルキリデン、C5〜C12−シクロアルキリデン、又はC6〜C12−アリーレンであり、これらはヘテロ原子を含むさらなる芳香族環に縮合されていてもよく、Xは好ましくは単結合、C1〜C5−アルキレン、C2〜C5−アルキリデン、C5〜C12−シクロアルキリデン、−O−又は−CO−であり、Xはより好ましくは単結合、イソプロピリデン、C5〜C12−シクロアルキリデン又は酸素であり、最も好ましくはイソプロピリデンであり、
nは1〜500、好ましくは10〜400、特に好ましくは10〜100、最も好ましくは20〜60の数であり、
mは1〜10、好ましくは1〜6、特に好ましくは2〜5の数であり、
pは0または1であり、
n掛けるmの値は、好ましくは12〜400、より好ましくは15〜200である〕、ならびに
(B)式(2)の繰り返し単位を有するポリカーボネートブロック:
ZはC1〜C8アルキリデン、S、SO2又は単結合であり、
R4及びR5は、相互に独立に、置換されているか又は置換されていないC1〜C18アルキル部分、ハロゲン又はH、好ましくはメチル、エチル、プロピル、ブチル、フェニル、Cl、Br、特に好ましくはHであり;
r及びsは相互に独立して0、1、又は2である]
を含む。
ここで、
フェニル環は、置換されていないか又は独立してC1〜C8−アルキル及び/又はハロゲン、好ましくはC1又はC4−アルキル、より好ましくはメチルにより一又は二置換されており、
Xは単結合、C1〜C6−アルキレン、C2〜C5−アルキリデン又はC5〜C6−シクロアルキリデン、好ましくは単結合又はC1〜C4−アルキレン、また特に好ましくはイソプロピリデンであり、
構造単位(I)〜(IV)中の−−−により示す結合は、それぞれカルボキシレート基の各部分であり、
且つここで、
構造単位(I)〜(IV)の量は合計して、50〜2000ppm、好ましくは60〜1500、より好ましくは70〜1200ppm、最も好ましくは80〜850ppmである(加水分解後にポリシロキサン−ポリカーボネートブロック共縮合物に基づいて決定する)。
の反応により調製される。また、繰り返し単位p、q、n及びmの整数も上記の通り定義される。
Dは、6〜30個の炭素原子を有する芳香族残基であり、1個以上の置換されていてもよい芳香族環を含み、ここで、芳香族環は、脂肪族残基又はアルキルアリール基又はヘテロ原子ブリッジにより接続されていてよい]に由来する構造を含む。
R6及びR7は互いに独立し、H、C1〜C18−アルキル−、C1〜C18−アルコキシ、例えばCl又はBrのようなハロゲン、もしくは置換されていてもよいアリール−又はアラルキル、好ましくはH又はC1〜C12−アルキル、より好ましくはH又はC1〜C8−アルキル、また最も好ましくはH又はメチルであり、且つ、
Xは単結合、−CO−、−O−、C1−〜C6−アルキレン、C2〜C5−アルキリデン、C5〜C12−シクロアルキリデン又はC6〜C12−アリーレンであり、これらはヘテロ原子を含むさらなる芳香族環に縮合されていてもよく、Xは好ましくは単結合、C1〜C5−アルキレン、 C2〜C5−アルキリデン、−O−又は−CO−であり、Xはより好ましくは単結合、イソプロピリデン又は酸素であり、最も好ましくはイソプロピリデンである]による残基である。
R,R’及びR”は、同一であるか又は異なった、それぞれ独立して水素、直鎖状又は分岐鎖状C1〜C34−アルキル,C7〜C34−アルキルアリール又はC6〜C34−アリールであり、
Rはさらに−COO−R’’’であってもよく、ここでR’’’は水素、直鎖状又は分岐鎖状C1〜C34−アルキル,C7〜C34−アルキルアリール又はC6〜C34−アリールである]。
R4−7は同一であるか又は異なった、置換されていてもよいC1〜C10−アルキル, C6〜C14−アリール,C7〜C15−アリールアルキル又はC5〜C6−シクロアルキルラジカル,好ましくはメチル又はC6〜C14−アリール,より好ましくはメチル又はフェニルであり、また
X−は水酸化物、硫酸塩、硫酸水素塩、炭酸水素塩、炭酸塩、ハロゲン化物、好ましくは塩化物、及びアルコキシド又は式−OR8のアロキシド、[ここでR8は置換されていてもよいC6〜C14−アリール,C7〜C15−アリールアルキル,C5〜C6−シクロアルキル又はC1〜C20−アルキルラジカル,好ましくはフェニルである]の群から選択された陰イオンである]のホスホニウム塩である。
R0はアリール,C1〜C10−アルキル又はC1〜C10−アルキルアリールであり、
R2及びR3は、同一であるか又は異なった、それぞれ互いに独立し、アリール、C1〜C10−アルキル及びC1〜C10−アルキルアリールから選択され、好ましくはR2及びR3は両方共メチルであり、また、
nは1〜500,好ましくは10〜400,特に好ましくは10〜100,最も好ましくは20〜60,の数である]であり、
ここで式(4)の化合物及び芳香族化合物は、芳香族化合物中のフェノール系ヒドロキシル基と式(4)の化合物中のアシルオキシ基の比が2.0未満になるようなモル比で反応する。
Ra,Rb,Rc及びRdは、同一であるか異なった、C1〜C10−アルキル,C6〜C14−アリール,C7〜C15−アリールアルキル又はC5〜C6−シクロアルキル,好ましくはメチル又はC6〜C14−アリール,より好ましくはメチル又はフェニルであってよく,またY−は水酸化物、硫酸塩、硫酸水素塩、炭酸水素塩、炭酸塩又はハロゲン化物、好ましくは塩化物、又はアルコキシド又は式−OReのアロキシド[ここでReはC6〜C14−アリール,C7〜C15−アリールアルキル又はC5〜C6−シクロアルキル、好ましくはフェニルであってよい]のような陰イオンであってよい]。
融成物体積流量(MVR)は、他の条件が記載されていない限り、ISO 1133(300℃、1.2kg)により測定する。
相対的溶液粘度(ηrel、eta relとも呼ばれる)は、ジクロロメタン中、濃度5g/l、25℃で、ウベローデ粘度計で測定した。
シロキサン成分の配合特性は、光顕微鏡検査により検査する。大量(マイクロメートル領域の、又はそれより大きな)のシリコーン油の存在は、シリコーン成分の物理的配合の指針である。ブロック共縮合物は存在しない。もし、対照的に、シリコーン領域の平均サイズが1μm未満であった場合、ブロック共重合体の存在が推定される。
シロキサンドメインの分布は、原子力顕微鏡及び光顕微鏡により分析された。(The siloxane domain distribution was analysed by by using atomforce microscopy and light microscopy.)それぞれのサンプルの射出成型試験バー(80x10x4mm)を、液体窒素温度で超ミクロトームを使用して中央で切断した。サンプルを作製し、AFM画像を、流動方向を見て撮影した(射出成型部分の流動方向)。画像を、周辺状態(25 °C,相対的湿度30%)で、且つ穏やかな断続的な接触モード又はタッピングモード(tapping mode)で記録した。典型的なバネ定数が2.8Nm−1、共振周波数が約75kHzのタッピングモードのカンチレバー(ナノ世界の先端プローブ)をスキャニングに使用した。タッピング力を、設定時の振幅及び自由大気下での振幅の比で制御した。スキャン速度を、画像の品質により、1Hzの範囲で調整した。表面構造を取得するために、様相のコントラスト及び高さの画像を2.5μmx2.5μmの領域で記録した。AFMにBruker D3100顕微鏡を使用した。粒子は、オリンパスソフトイメージングソルーションズ(Olympus SIS)(Olympus Soft Imaging Solutions GmbH, 48149, Muenster, Germany)の画像評価手段により、明/暗のコントラストで、自動的に分析された。映された領域に等しい円の直径により粒子の直径を測定した。1μmより大きいシロキサンドメインを評価するために、Zeiss Axioplan 2光顕微鏡を使用した。AFM画像で記載したようにサイズ分布を分析した。光顕微鏡で評価された領域は約(例)735000μm2、及びAFMで評価された領域は約6.25μm2であった。AFM−領域及び光顕微鏡検査との領域の表面比率を利用して、粒子の領域サイズの分布を再計算した。
本発明による共縮合物の合成に使用されたポリカーボネート(PC): Bayer MaterialScienceから市販のフェノール系末端基を有する直鎖状ビスフェノールAポリカーボネートであり、融成物体積流量59−62cm3/10min(ISO 1033により、300℃、1.2kg負荷で測定)にて使用される。このポリカーボネートは、紫外線安定剤、離型剤又は熱安定剤のような添加剤を一切含んでいない。ポリカーボネートは、独国特許第102008019503号に記載されている様に、メルトエステル交換反応により調製した。このポリカーボネートは、約600ppmのフェノール末端基含有量を有する。
使用されるシロキサンは、式(1a)(即ち、R1 =H,R2,R3=メチル,p= 0)のヒドロキノン−末端ポリジメチルシロキサンであり、ここでn=30、またm=3であり、ヒドロキシ含有量8.8mgKOH/g、粘度753mPas(23°C)を有する。
使用する触媒は、Rhein Chemie Rheinau GmbH(Mannheim, Germany)から市販のテトラフェニルホスホニウムフェノキシドのマスターバッチ形態である。テトラフェニルホスホニウムフェノキシドは、フェノールとの共結晶形態で使用し、テトラフェニルホスホニウムフェノキシド約70%を含む。以下に記載する量は、Rhein Chemieから得た物質に基づく(フェノールとの共結晶として)。
Makrolon(登録商標)2808:Bayer MaterialScienceから市販の、ビスフェノールAを基剤とし、フェノールを末端基とする直鎖状ポリカーボネート、MVR9.5。(Linear polycarbonate from Bayer 材料Science based on bisphenol A with phenol as end group with an MVR of 9.5. (for)
Lexan(登録商標)EXL 1414T:Sabic Innovative Plasticsから市販の、ビスフェノールAを基剤とする、直鎖状シロキサン含有ブロック共縮合物、MVR7.3、界面プロセスにより調製。
Lexan(登録商標)EXL 9330: Sabic Innovative Plasticsから市販の、ビスフェノールAを基剤とし、難燃剤を含んでなる直鎖状シロキサン含有ブロック共縮合物、MVR8.8、界面プロセスにより調製。
ビスフェノールA2185g(9.57 mol)及び水酸化ナトリウム1687 g(42.16 mol)を水25リットルにいれた、窒素掃気した溶液に塩化メチレン25リットルを添加する。シロキサン成分(上記参照のこと)115g(ビスフェノールAの量に対して約5重量%)を添加する。pH12.5〜13.5及び20℃で、ホスゲン1896g(19.17mol)を通す。pHが12.5を下回るのを防ぐため、ホスゲン化の際に30%水酸化ナトリウム溶液を添加する。ホスゲン化が完了し、そして窒素掃気の後、ジクロロメタン2リットルに溶解させた4−tert.−ブチルフェノール(米国Sigma−Aldrichの技術水準)65.4g(0.43mol)を添加する。10分間撹拌し、ジクロロメタン0.5リットルに溶解させたN−エチルピペリジン11g(0.1mol)を添加し、撹拌を1時間継続する。水相を分離した後、有機相をリン酸で酸性化し、蒸留水で中性に、無塩に洗浄する。溶剤をクロロベンゼンで置き換えた後、生成物を290℃及び80回転/min、0.1mbarで通気押出機により押出し、造粒機により造粒した。
本発明によるブロック共重合体は、図1に示された配置で製造される。
機械的試験を行うために、楔形幾何学的構造を有する試験バーを、射出成形により調製した。
Claims (14)
- (A)式(1)のポリシロキサンブロック
R1はH、Cl、Br又はC1〜C4−アルキル、好ましくはH又はメチル、特に好ましくはHであり、
R2及びR3は同一か又は異なっていてもよく、それぞれ互いに独立して、アリール、C1〜C10−アルキル及びC1〜C10−アルキルアリールから選択され、好ましくはR2及びR3はメチルであり、
Xは単結合、−CO−、−O−、C1〜C6−アルキレン、C2〜C5−アルキリデン、C5〜C12−シクロアルキリデン、又はC6〜C12−アリーレンであり、これらはヘテロ原子を含むさらなる芳香族環に縮合されていてもよく、Xは好ましくは単結合、C1〜C5−アルキレン、C2〜C5−アルキリデン、C5〜C12−シクロアルキリデン、−O−又は−CO−であり、Xはより好ましくは単結合、イソプロピリデン、C5〜C12−シクロアルキリデン又は酸素であり、最も好ましくはイソプロピリデンであり、nは1〜500、好ましくは10〜400、特に好ましくは10〜100、最も好ましくは20〜60の数であり、
mは1〜10、好ましくは1〜6、特に好ましくは2〜5の数であり、
pは0又は1であり、
n掛けるmの値が、好ましくは12及び400の間、より好ましくは15及び200の間である]、ならびに
(B)式(2)の繰り返し単位を有するポリカーボネートブロック:
ZはC1〜C8アルキリデン、S、SO2又は単結合であり、
R4及びR5は、相互に独立に、置換されているか又は置換されていないC1〜C18アルキル部分、ハロゲン又はH、好ましくはメチル、エチル、プロピル、ブチル、フェニル、Cl、Br、特に好ましくはHであり、
r及びsは相互に独立して0、1又は2である]
を含んでなるポリシロキサン−ポリカーボネートブロック共縮合物であって、
以下の構造(I)〜(IV):
フェニル環は、置換されていないか、又は独立してC1〜C8−アルキル及び/又はハロゲン、好ましくはC1〜C4−アルキル、より好ましくはメチルにより一又は二置換されており、
Xは単結合、C1〜C6−アルキレン、C2〜C5−アルキリデン又はC5〜C6−シクロアルキリデン、好ましくは単結合又はC1〜C4−アルキレン、特に好ましくはイソプロピリデンであり、
構造単位(I)〜(IV)中の−−−により示される結合は、それぞれカルボキシレート基の部分である]
の少なくとも1種、好ましくは2種以上を含み、
シロキサンドメインの総数に対して0.01%〜2.5%のシロキサンドメインの直径が、原子間力顕微鏡検査及び光顕微鏡検査により測定された場合に200nm〜1μmであるシロキサンドメイン分布(シロキサンドメインの直径)を有する、ポリシロキサン−ポリカーボネートブロック共縮合物。 - シロキサンドメインの総数に対して0.01%〜1.5%のシロキサンドメインの直径が、原子間力顕微鏡検査及び光顕微鏡検査により測定された場合に200nm〜1μmであるシロキサンドメイン分布(シロキサンドメインの直径)を有する、請求項1に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- シロキサンドメインの総数に対して0.01%〜1.5%のシロキサンドメインの平均サイズ(直径)が、原子間力顕微鏡検査及び光顕微鏡検査により測定された場合に200nmを超える平均シロキサンドメインサイズ(シロキサンドメインの直径)を有し、且つ、1μmを超える直径を有する粒子(シロキサンドメイン)を、シロキサンドメインの総数に対して0.00001%〜0.05%の量で含む、請求項1又は2に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- 原子間力顕微鏡検査及び光顕微鏡検査により測定された場合における200nm〜1μmのシロキサンドメイン分布(シロキサンドメインの直径)が、シロキサンドメインの総数に対して0.03%〜1.0%の範囲内である、請求項1〜3のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- 少なくとも1μmの直径を有するシロキサンドメインを含む、請求項1〜4のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- 構造単位(I)〜(IV)の量が合計が50〜2000ppm、好ましくは60〜1500ppm、より好ましくは70〜1200ppm、最も好ましくは80〜850ppm(加水分解後に決定された、ポリシロキサン−ポリカーボネートブロック共縮合物に対する数値)である、請求項1〜5のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- R1がHであり、pが1であり、Xがイソプロピリデンである、請求項1〜6のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- R2及びR3がメチルである、請求項1〜7のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- nが10〜100の数であり、mが2〜5の数である、請求項1〜8のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- ナトリウム含有量が0.1ppm〜1000ppmの範囲内である、請求項1〜9のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物。
- 成形品の製造のための、請求項1〜10のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物の使用。
- 請求項1〜10のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物を含んでなる、成形品又は押出成形物。
- 請求項1〜10のいずれか一項に記載のポリシロキサン−ポリカーボネートブロック共縮合物を製造する方法であって、連続的メルトエステル交換反応法が用いられる、方法。
- 前記連続的メルトエステル交換反応法が、反応性の加圧法または反応性ブレンド法を使用するものである、請求項13に記載の方法。
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