JP6802164B2 - 硬化性部分フッ素化ポリマー組成物 - Google Patents
硬化性部分フッ素化ポリマー組成物 Download PDFInfo
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- JP6802164B2 JP6802164B2 JP2017532105A JP2017532105A JP6802164B2 JP 6802164 B2 JP6802164 B2 JP 6802164B2 JP 2017532105 A JP2017532105 A JP 2017532105A JP 2017532105 A JP2017532105 A JP 2017532105A JP 6802164 B2 JP6802164 B2 JP 6802164B2
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- 0 *=CCC1C(O)=CC=CC1 Chemical compound *=CCC1C(O)=CC=CC1 0.000 description 2
- XTNOZVGIZUQGED-UHFFFAOYSA-N C=C(Cc(cccc1)c1O)N Chemical compound C=C(Cc(cccc1)c1O)N XTNOZVGIZUQGED-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/244—Stepwise homogeneous crosslinking of one polymer with one crosslinking system, e.g. partial curing
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08K5/00—Use of organic ingredients
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- C08K5/05—Alcohols; Metal alcoholates
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/19—Quaternary ammonium compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2323/28—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/20—Homopolymers or copolymers of hexafluoropropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
(i)炭素−炭素二重結合を含む、又は部分フッ素化された非晶性フルオロポリマー鎖内で炭素−炭素二重結合を形成し得る、部分フッ素化された非晶性フルオロポリマーであって、臭素、ヨウ素、及びニトリルを実質的に含まない、部分フッ素化された非晶性フルオロポリマー;及び
(ii)少なくとも1個のオレフィン系水素を有する末端オレフィンを含む硬化剤、を含む。
「a」、「an」、及び「the」は互換可能に使用され、1又はそれよりも多くを意味する。
「及び/又は」は、表記される場合のいずれか又は両方が生じ得ること、例えば、A及び/又はBは、(A及びB)、及び(A又はB)を含むことを示すために使用される。
「主鎖」は、ポリマーの主要部となる連続鎖を指す。
「架橋」は、2つの予め形成されたポリマー鎖を、化学結合又は化学基を用いて連結することを指す。
「硬化部位」は、架橋に関与し得る官能基を指す。
「共重合」は、モノマーが一緒に重合されてポリマー主鎖を形成することを指す。
「ポリマー」は、多数(例えば、数百〜)の共重合したモノマーユニットから構成された、高分子量(例えば、10,000超、20,000超、50,000超、又は更には100,000グラム/モル超)の巨大分子を指す。
同様にして、本明細書において、端点による範囲の引用は、範囲内に包含される全ての数を含む(例えば、1〜10は、1.4、1.9、2.33、5.75、9.98などを含む)。
CX1X2=CX3−R(I)
式中、X1、X2、及びX3は、独立して、H、Cl、及びFから選択され、X1、X2、及びX3のうちの少なくとも1つはHであり;Rは、一価の基である。
(i)炭素−炭素二重結合を含む、又は部分フッ素化された非晶性フルオロポリマー鎖内で炭素−炭素二重結合を形成し得る、部分フッ素化された非晶性フルオロポリマーであって、臭素、ヨウ素、及びニトリルを実質的に含まない、部分フッ素化された非晶性フルオロポリマー;及び
(ii)少なくとも1個のオレフィン系水素を有する末端オレフィンを含む硬化剤、を含む、硬化性部分フッ素化ポリマー組成物。
実施形態1〜18のいずれか一態様に記載の硬化性部分フッ素化ポリマー組成物を提供することと、
硬化性部分フッ素化ポリマー組成物を硬化させることと、を含む、部分フッ素化されたエラストマーの製造方法。
実施例
Oリング成形及び圧縮永久歪み
Claims (10)
- (i)炭素−炭素二重結合を含む、又は部分フッ素化された非晶性フルオロポリマー鎖内で炭素−炭素二重結合を形成し得る、部分フッ素化された非晶性フルオロポリマーであって、臭素、ヨウ素、及びニトリルを実質的に含まない、部分フッ素化された非晶性フルオロポリマー;及び
(ii)少なくとも1個のオレフィン系水素を有する末端オレフィンを含む硬化剤、を含み、前記硬化剤が、フェノール基及び非芳香族オレフィン系アルコールのうち少なくとも1つを含む、硬化性部分フッ素化ポリマー組成物。 - 前記硬化剤が、フェノール基を含む、請求項1に記載の硬化性部分フッ素化ポリマー組成物。
- 前記硬化剤が、非芳香族オレフィン系アルコールを含む、請求項1又は2のいずれかに記載の硬化性部分フッ素化ポリマー組成物。
- 前記部分フッ素化された非晶性フルオロポリマーが、(i)VDF及びHFPが隣接して共重合したユニット;(ii)VDF及び酸性水素原子を有するフッ素化コモノマーが共重合したユニット;(iii)TFE及び酸性水素原子を有するフッ素化コモノマーが共重合したユニット;並びに(iv)これらの組み合わせ、を含む、請求項1〜3のいずれか一項に記載の硬化性部分フッ素化ポリマー組成物。
- 前記硬化性組成物が、助剤を実質的に含まない、請求項1〜4のいずれか一項に記載の硬化性部分フッ素化ポリマー組成物。
- 有機オニウム化合物を更に含む、請求項1〜5のいずれか一項に記載の硬化性部分フッ素化ポリマー組成物。
- 酸受容体を更に含む、請求項1〜6のいずれか一項に記載の硬化性部分フッ素化ポリマー組成物。
- 請求項1〜8のいずれか一項に記載の硬化した組成物を含む物品。
- 部分フッ素化されたエラストマーの製造方法であって、
請求項1〜8のいずれか一項に記載の硬化性部分フッ素化ポリマー組成物を準備することと、
前記硬化性部分フッ素化ポリマー組成物を硬化させることと、を含む、方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB201422777 | 2014-12-19 | ||
GB1422777.1 | 2014-12-19 | ||
PCT/US2015/065933 WO2016100421A1 (en) | 2014-12-19 | 2015-12-16 | Curable partially fluorinated polymer compositions |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2017538023A JP2017538023A (ja) | 2017-12-21 |
JP2017538023A5 JP2017538023A5 (ja) | 2019-02-07 |
JP6802164B2 true JP6802164B2 (ja) | 2020-12-16 |
Family
ID=56127500
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017532105A Active JP6802164B2 (ja) | 2014-12-19 | 2015-12-16 | 硬化性部分フッ素化ポリマー組成物 |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP3234011A4 (ja) |
JP (1) | JP6802164B2 (ja) |
KR (1) | KR20170099947A (ja) |
CN (1) | CN107109012A (ja) |
CA (1) | CA2971219A1 (ja) |
MX (1) | MX2017008046A (ja) |
WO (1) | WO2016100421A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20220251338A1 (en) * | 2019-08-23 | 2022-08-11 | 3M Innovative Properties Company | Curable Fluoropolymer Compositions Comprising a Compound Containing a Phthalonitrile and an Olefinic Bond and Cured Articles Therefrom |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102448558B1 (ko) * | 2016-12-28 | 2022-09-28 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 규소-함유 할로겐화 탄성중합체 |
JP6859455B2 (ja) | 2017-05-19 | 2021-04-14 | スリーエム イノベイティブ プロパティズ カンパニー | ポリフルオロ化アリルエーテルの製造方法及びその方法に関連する化合物 |
WO2019126298A1 (en) | 2017-12-22 | 2019-06-27 | 3M Innovative Properties Company | Peroxide-cured halogenated elastomers having a silicon-containing superficial layer |
US11919984B2 (en) | 2018-02-19 | 2024-03-05 | 3M Innovative Properties Company | Blends of crosslinking agents for fluoroelastomers |
WO2019239288A1 (en) | 2018-06-12 | 2019-12-19 | 3M Innovative Properties Company | Fluorinated polymer coating compositions and articles therefrom |
WO2024090559A1 (ja) * | 2022-10-27 | 2024-05-02 | ダイキン工業株式会社 | フッ素ゴム架橋用組成物および成形品 |
JP2024064171A (ja) * | 2022-10-27 | 2024-05-14 | ダイキン工業株式会社 | フッ素ゴム架橋用組成物および成形品 |
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US3507844A (en) * | 1965-08-03 | 1970-04-21 | Aviat Uk | Fluoroelastomer sealants |
GB1144163A (en) * | 1965-08-03 | 1969-03-05 | Mini Of Technology | Improvements in or relating to fluorocarbon elastomers |
JP3058556B2 (ja) * | 1994-04-19 | 2000-07-04 | 株式会社トウペ | 高耐熱性ゴム組成物 |
IT1286042B1 (it) * | 1996-10-25 | 1998-07-07 | Ausimont Spa | O-rings da fluoroelastomeri vulcanizzabili per via ionica |
US6087406A (en) * | 1997-03-12 | 2000-07-11 | Dyneon Llc | Recycle of vulcanized fluorinated elastomers |
US6803435B2 (en) * | 2002-07-18 | 2004-10-12 | 3M Innovative Properties Company | Curable fluoropolymers containing bromine groups having improved compression set |
CN100558774C (zh) * | 2004-06-10 | 2009-11-11 | 杜邦特性弹性体有限责任公司 | 接枝含氟弹性体 |
US7253236B2 (en) * | 2004-06-10 | 2007-08-07 | Dupont Performance Elastomers L.L.C. | Grafted fluoroelastomers |
EP1634895B1 (en) * | 2004-09-09 | 2008-11-05 | 3M Innovative Properties Company | Fluoropolymer for making a fluoroelastomer |
FR2934274B1 (fr) * | 2008-07-25 | 2013-01-11 | Hutchinson | Composition de caoutchouc pour structure multicouches, telle qu'un raccord pour systeme d'admission d'air de turbocompresseur, cette structure et ce systeme |
CN102549060B (zh) * | 2009-07-31 | 2016-01-20 | 3M创新有限公司 | 含有多元醇化合物的含氟聚合物组合物及其制备方法 |
WO2013023983A1 (en) * | 2011-08-17 | 2013-02-21 | Solvay Specialty Polymers Italy S.P.A. | Milling process |
JP2016524012A (ja) * | 2013-06-24 | 2016-08-12 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | フルオロエラストマー組成物 |
WO2015098338A1 (ja) * | 2013-12-27 | 2015-07-02 | 日本バルカー工業株式会社 | フッ素ゴム組成物、並びに架橋ゴム成形体及びその製造方法 |
US10668257B2 (en) * | 2014-10-16 | 2020-06-02 | W. L. Gore & Associates, Inc. | Blow molded composite devices and methods |
WO2016100420A1 (en) * | 2014-12-19 | 2016-06-23 | 3M Innovative Properties Company | Curable partially fluorinated polymer compositions |
-
2015
- 2015-12-16 EP EP15870930.3A patent/EP3234011A4/en not_active Withdrawn
- 2015-12-16 CA CA2971219A patent/CA2971219A1/en not_active Abandoned
- 2015-12-16 MX MX2017008046A patent/MX2017008046A/es unknown
- 2015-12-16 CN CN201580069383.0A patent/CN107109012A/zh active Pending
- 2015-12-16 WO PCT/US2015/065933 patent/WO2016100421A1/en active Application Filing
- 2015-12-16 KR KR1020177019629A patent/KR20170099947A/ko unknown
- 2015-12-16 JP JP2017532105A patent/JP6802164B2/ja active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20220251338A1 (en) * | 2019-08-23 | 2022-08-11 | 3M Innovative Properties Company | Curable Fluoropolymer Compositions Comprising a Compound Containing a Phthalonitrile and an Olefinic Bond and Cured Articles Therefrom |
US11499032B2 (en) * | 2019-08-23 | 2022-11-15 | 3M Innovative Properties Company | Curable fluoropolymer compositions comprising a compound containing a phthalonitrile and an olefinic bond and cured articles therefrom |
Also Published As
Publication number | Publication date |
---|---|
MX2017008046A (es) | 2017-12-11 |
CA2971219A1 (en) | 2016-06-23 |
EP3234011A4 (en) | 2018-08-01 |
KR20170099947A (ko) | 2017-09-01 |
EP3234011A1 (en) | 2017-10-25 |
WO2016100421A1 (en) | 2016-06-23 |
CN107109012A (zh) | 2017-08-29 |
JP2017538023A (ja) | 2017-12-21 |
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