JP6786214B2 - マグネシウム合金、その製造方法およびその使用 - Google Patents
マグネシウム合金、その製造方法およびその使用 Download PDFInfo
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- JP6786214B2 JP6786214B2 JP2015518992A JP2015518992A JP6786214B2 JP 6786214 B2 JP6786214 B2 JP 6786214B2 JP 2015518992 A JP2015518992 A JP 2015518992A JP 2015518992 A JP2015518992 A JP 2015518992A JP 6786214 B2 JP6786214 B2 JP 6786214B2
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- weight
- implant
- alloy
- magnesium
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- 229910000861 Mg alloy Inorganic materials 0.000 title claims description 33
- 238000004519 manufacturing process Methods 0.000 title description 12
- 239000007943 implant Substances 0.000 claims description 72
- 229910045601 alloy Inorganic materials 0.000 claims description 58
- 239000000956 alloy Substances 0.000 claims description 58
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 51
- 239000011777 magnesium Substances 0.000 claims description 44
- 239000012535 impurity Substances 0.000 claims description 35
- 229910052742 iron Inorganic materials 0.000 claims description 33
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 32
- 229910052749 magnesium Inorganic materials 0.000 claims description 32
- 239000011159 matrix material Substances 0.000 claims description 31
- 239000002245 particle Substances 0.000 claims description 28
- 229910052748 manganese Inorganic materials 0.000 claims description 23
- 229910052710 silicon Inorganic materials 0.000 claims description 21
- 239000002244 precipitate Substances 0.000 claims description 18
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 229910052802 copper Inorganic materials 0.000 claims description 17
- 229910052759 nickel Inorganic materials 0.000 claims description 17
- 229910052790 beryllium Inorganic materials 0.000 claims description 14
- 229910052793 cadmium Inorganic materials 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 12
- 229910052738 indium Inorganic materials 0.000 claims description 11
- 229910052726 zirconium Inorganic materials 0.000 claims description 11
- 229910052718 tin Inorganic materials 0.000 claims description 10
- 229910052727 yttrium Inorganic materials 0.000 claims description 10
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 7
- 150000002910 rare earth metals Chemical class 0.000 claims description 7
- 229910052745 lead Inorganic materials 0.000 claims description 4
- 230000000399 orthopedic effect Effects 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000004053 dental implant Substances 0.000 claims description 2
- 210000005036 nerve Anatomy 0.000 claims description 2
- 229910017706 MgZn Inorganic materials 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 238000005260 corrosion Methods 0.000 description 26
- 230000007797 corrosion Effects 0.000 description 26
- 239000000463 material Substances 0.000 description 26
- 239000011701 zinc Substances 0.000 description 26
- 239000011572 manganese Substances 0.000 description 24
- 238000000034 method Methods 0.000 description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 18
- 239000010949 copper Substances 0.000 description 17
- 230000008569 process Effects 0.000 description 16
- 239000006104 solid solution Substances 0.000 description 16
- 238000005275 alloying Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 12
- 210000001519 tissue Anatomy 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 11
- 230000002526 effect on cardiovascular system Effects 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 6
- 230000035882 stress Effects 0.000 description 6
- 238000000137 annealing Methods 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 239000011265 semifinished product Substances 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 230000002792 vascular Effects 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 210000000056 organ Anatomy 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000005292 vacuum distillation Methods 0.000 description 3
- 229910018137 Al-Zn Inorganic materials 0.000 description 2
- 229910018573 Al—Zn Inorganic materials 0.000 description 2
- 206010002329 Aneurysm Diseases 0.000 description 2
- 208000037408 Device failure Diseases 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 206010061218 Inflammation Diseases 0.000 description 2
- 206010057469 Vascular stenosis Diseases 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 210000004204 blood vessel Anatomy 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 229910052729 chemical element Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000012377 drug delivery Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000001727 in vivo Methods 0.000 description 2
- 230000004054 inflammatory process Effects 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 239000006166 lysate Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 230000008733 trauma Effects 0.000 description 2
- 229910001020 Au alloy Inorganic materials 0.000 description 1
- 208000010392 Bone Fractures Diseases 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 229910000684 Cobalt-chrome Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010017076 Fracture Diseases 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 208000012659 Joint disease Diseases 0.000 description 1
- 229910018643 Mn—Si Inorganic materials 0.000 description 1
- 208000029578 Muscle disease Diseases 0.000 description 1
- 208000031481 Pathologic Constriction Diseases 0.000 description 1
- 208000000491 Tendinopathy Diseases 0.000 description 1
- 208000023835 Tendon disease Diseases 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 210000000748 cardiovascular system Anatomy 0.000 description 1
- 208000015100 cartilage disease Diseases 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000010952 cobalt-chrome Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003353 gold alloy Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000004881 precipitation hardening Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000036262 stenosis Effects 0.000 description 1
- 208000037804 stenosis Diseases 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000003356 suture material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 210000002435 tendon Anatomy 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 231100000701 toxic element Toxicity 0.000 description 1
- 238000002054 transplantation Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 208000019553 vascular disease Diseases 0.000 description 1
- 210000005166 vasculature Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C23/00—Alloys based on magnesium
- C22C23/04—Alloys based on magnesium with zinc or cadmium as the next major constituent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
- A61L27/02—Inorganic materials
- A61L27/04—Metals or alloys
- A61L27/047—Other specific metals or alloys not covered by A61L27/042 - A61L27/045 or A61L27/06
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
- A61L27/50—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
- A61L27/58—Materials at least partially resorbable by the body
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C23/00—Alloys based on magnesium
- C22C23/02—Alloys based on magnesium with aluminium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/06—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of magnesium or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Transplantation (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dermatology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Inorganic Chemistry (AREA)
- Materials For Medical Uses (AREA)
- Powder Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Dental Preparations (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261664229P | 2012-06-26 | 2012-06-26 | |
US61/664,229 | 2012-06-26 | ||
PCT/EP2013/062876 WO2014001191A1 (en) | 2012-06-26 | 2013-06-20 | Magnesium alloy, method for the production thereof and use thereof |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019080609A Division JP2019148012A (ja) | 2012-06-26 | 2019-04-22 | マグネシウム合金、その製造方法およびその使用 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015528052A JP2015528052A (ja) | 2015-09-24 |
JP6786214B2 true JP6786214B2 (ja) | 2020-11-18 |
Family
ID=48652113
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015518992A Active JP6786214B2 (ja) | 2012-06-26 | 2013-06-20 | マグネシウム合金、その製造方法およびその使用 |
JP2019080609A Pending JP2019148012A (ja) | 2012-06-26 | 2019-04-22 | マグネシウム合金、その製造方法およびその使用 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2019080609A Pending JP2019148012A (ja) | 2012-06-26 | 2019-04-22 | マグネシウム合金、その製造方法およびその使用 |
Country Status (12)
Country | Link |
---|---|
US (1) | US10895000B2 (de) |
EP (1) | EP2864514B1 (de) |
JP (2) | JP6786214B2 (de) |
KR (1) | KR102246885B1 (de) |
CN (1) | CN104284993B (de) |
AU (1) | AU2013283577A1 (de) |
CA (1) | CA2869458C (de) |
ES (1) | ES2796371T3 (de) |
HK (1) | HK1200881A1 (de) |
RU (2) | RU2017138378A (de) |
SG (1) | SG11201406024QA (de) |
WO (1) | WO2014001191A1 (de) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2640700C2 (ru) | 2012-06-26 | 2018-01-11 | Биотроник Аг | Магниевый сплав, способ его производства и использования |
SG11201406024QA (en) | 2012-06-26 | 2014-10-30 | Biotronik Ag | Magnesium alloy, method for the production thereof and use thereof |
ES2797498T3 (es) | 2012-06-26 | 2020-12-02 | Biotronik Ag | La invención se refiere a un implante hecho de una aleación de magnesio y a un método para la producción del mismo |
CA2867773C (en) | 2012-06-26 | 2022-10-25 | Biotronik Ag | Magnesium-aluminum-zinc alloy, method for the production thereof and use thereof |
CN104233123B (zh) * | 2014-08-26 | 2017-05-03 | 盐城市鑫洋电热材料有限公司 | 一种Mg‑Al‑Cd‑Zn系增强镁基合金及其制备方法 |
EP2992925B1 (de) | 2014-09-04 | 2022-09-07 | BIOTRONIK SE & Co. KG | Intravaskuläre elektrodenleitung und intravaskuläre stimulationsvorrichtung damit |
CN104233029B (zh) * | 2014-09-24 | 2016-04-27 | 中南大学 | 一种高强度可降解镁合金及制备方法 |
US11147874B2 (en) | 2015-06-15 | 2021-10-19 | Boston Scientific Scimed, Inc. | Devices and methods for therapeutic heat treatment |
CN105886804B (zh) * | 2016-05-16 | 2017-10-17 | 扬州大学 | 一种高性能镁锌系合金的制备方法 |
RU2615930C1 (ru) * | 2016-06-16 | 2017-04-11 | Юлия Алексеевна Щепочкина | Магниевый припой |
CN107587020B (zh) * | 2016-07-08 | 2019-10-22 | 中国科学院金属研究所 | 一种高导热镁合金及其制备方法 |
WO2018083998A1 (ja) * | 2016-11-02 | 2018-05-11 | 国立大学法人 熊本大学 | 生体吸収性医療機器及びその製造方法 |
CN108070762A (zh) * | 2016-11-17 | 2018-05-25 | 比亚迪股份有限公司 | 一种变形镁合金及其制备方法 |
CN106868369A (zh) * | 2017-03-17 | 2017-06-20 | 扬州大学 | 一种单相过饱和固溶体镁锌合金的制备方法 |
CN107142431B (zh) * | 2017-06-01 | 2018-09-11 | 哈尔滨工业大学 | 一种az80a镁合金锻坯挤压多向锻造复合工艺提高强度的方法 |
CN107217185B (zh) * | 2017-06-03 | 2021-02-12 | 西南医科大学 | 一种可降解医学植入物 |
EP3415651A1 (de) * | 2017-06-14 | 2018-12-19 | Heraeus Deutschland GmbH & Co. KG | Verfahren zur herstellung eines passivierten produkts |
CN108502007A (zh) * | 2018-03-12 | 2018-09-07 | 张纪校 | 一种镁合金婴儿推车 |
USD903393S1 (en) | 2019-04-03 | 2020-12-01 | Enfant Terrible Design AB | Sun canopy |
CN109913723A (zh) * | 2019-04-08 | 2019-06-21 | 常熟理工学院 | 骨缺损修复用的梯度多孔镁合金材料及压铸装置 |
US11697869B2 (en) | 2020-01-22 | 2023-07-11 | Heraeus Deutschland GmbH & Co. KG | Method for manufacturing a biocompatible wire |
WO2022152585A1 (en) | 2021-01-15 | 2022-07-21 | Biotronik Se & Co. Kg | Implantable medical device |
WO2022152587A1 (en) | 2021-01-15 | 2022-07-21 | Biotronik Se & Co. Kg | Medical implant, particularly in form of an implantable intracardiac pacemaker, comprising a rotatable anchoring device to allow extraction of the encapsulated medical implant |
WO2022152586A1 (en) | 2021-01-15 | 2022-07-21 | Biotronik Se & Co. Kg | Implantable medical device |
WO2022152470A1 (en) | 2021-01-15 | 2022-07-21 | Biotronik Se & Co. Kg | A medical implant anchoring element with improved characteristics for implantation and retention |
CN114045409B (zh) * | 2021-11-16 | 2022-11-15 | 湖南华翔医疗科技有限公司 | 一种骨科修复植入物及其制备方法 |
CN116407687A (zh) * | 2021-12-31 | 2023-07-11 | 四川大学 | 一种表面改性的多孔铁基支架及其制备方法和应用 |
CN115505858B (zh) * | 2022-09-29 | 2023-05-09 | 上海交通大学 | 一种镁稀土合金大型复杂构件的热处理方法 |
CN118516594B (zh) * | 2024-07-22 | 2024-10-01 | 广东省科学院新材料研究所 | 一种Mg17Al12相增强镁基复合材料及其制备方法 |
Family Cites Families (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US102A (en) * | 1861-08-13 | Whole | ||
US692A (en) * | 1838-04-14 | Improvement in machines for mowing and cutting grass and grain | ||
US3320055A (en) | 1964-08-19 | 1967-05-16 | Dow Chemical Co | Magnesium-base alloy |
CH672417A5 (de) | 1987-06-17 | 1989-11-30 | Sulzer Ag | |
JPH0247238A (ja) | 1988-08-08 | 1990-02-16 | Nippon Telegr & Teleph Corp <Ntt> | 制振合金およびその製造方法 |
US5055254A (en) | 1989-10-05 | 1991-10-08 | Timminco Limited | Magnesium-aluminum-zinc alloy |
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EP2864514B1 (de) | 2020-04-29 |
ES2796371T3 (es) | 2020-11-26 |
CA2869458A1 (en) | 2014-01-03 |
KR102246885B1 (ko) | 2021-05-03 |
WO2014001191A1 (en) | 2014-01-03 |
JP2015528052A (ja) | 2015-09-24 |
JP2019148012A (ja) | 2019-09-05 |
HK1200881A1 (en) | 2015-08-14 |
RU2017138378A (ru) | 2019-02-11 |
SG11201406024QA (en) | 2014-10-30 |
BR112014032618A2 (pt) | 2017-06-27 |
EP2864514A1 (de) | 2015-04-29 |
CN104284993A (zh) | 2015-01-14 |
AU2013283577A1 (en) | 2014-10-09 |
RU2015102168A (ru) | 2016-08-20 |
US20150119995A1 (en) | 2015-04-30 |
RU2647951C2 (ru) | 2018-03-21 |
CA2869458C (en) | 2021-04-06 |
CN104284993B (zh) | 2017-06-23 |
KR20150023311A (ko) | 2015-03-05 |
US10895000B2 (en) | 2021-01-19 |
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