JP6776165B2 - Laminated film manufacturing method and laminated film manufacturing equipment - Google Patents
Laminated film manufacturing method and laminated film manufacturing equipment Download PDFInfo
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- JP6776165B2 JP6776165B2 JP2017063205A JP2017063205A JP6776165B2 JP 6776165 B2 JP6776165 B2 JP 6776165B2 JP 2017063205 A JP2017063205 A JP 2017063205A JP 2017063205 A JP2017063205 A JP 2017063205A JP 6776165 B2 JP6776165 B2 JP 6776165B2
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- 238000004519 manufacturing process Methods 0.000 title claims description 67
- 239000007788 liquid Substances 0.000 claims description 182
- 239000011248 coating agent Substances 0.000 claims description 62
- 238000000576 coating method Methods 0.000 claims description 62
- 239000007789 gas Substances 0.000 claims description 62
- 238000007789 sealing Methods 0.000 claims description 53
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 39
- 239000012530 fluid Substances 0.000 claims description 34
- 230000007246 mechanism Effects 0.000 claims description 29
- 229910052757 nitrogen Inorganic materials 0.000 claims description 17
- 239000002346 layers by function Substances 0.000 claims description 13
- 238000007664 blowing Methods 0.000 claims description 10
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 5
- 230000007723 transport mechanism Effects 0.000 claims description 5
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 3
- 239000010410 layer Substances 0.000 claims description 2
- 230000032258 transport Effects 0.000 claims 3
- 238000013461 design Methods 0.000 description 13
- 230000001105 regulatory effect Effects 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- -1 polyethylene terephthalate Polymers 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229920002284 Cellulose triacetate Polymers 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 2
- 239000011112 polyethylene naphthalate Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940105570 ornex Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C3/00—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
- B05C3/18—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material only one side of the work coming into contact with the liquid or other fluent material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C3/00—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
- B05C3/02—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C5/00—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
- B05C5/02—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work
- B05C5/0245—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work for applying liquid or other fluent material to a moving work of indefinite length, e.g. to a moving web
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C5/00—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
- B05C5/02—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work
- B05C5/0254—Coating heads with slot-shaped outlet
- B05C5/0258—Coating heads with slot-shaped outlet flow controlled, e.g. by a valve
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/40—Distributing applied liquids or other fluent materials by members moving relatively to surface
Landscapes
- Coating Apparatus (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
本発明は、ローラで連続搬送されるフィルムに機能液の液溜まりを用いて、フィルム上に機能層を備えた積層フィルムを製造する積層フィルムの製造方法および製造装置に関する。 The present invention relates to a method and an apparatus for producing a laminated film for producing a laminated film having a functional layer on the film by using a pool of functional liquid on a film continuously conveyed by a roller.
フィルム上への機能液の塗布幅を制御するには、ギーザーやダイなど高価で精密な液供給設備を用いる必要があった。また、粘度の低い塗布液の幅制御には、コーティング用のローラ両端部にテフロン(登録商標)などの樹脂を物理的に押し付け、ピン止め効果を用いる方法などが採用されていた。 In order to control the coating width of the functional liquid on the film, it was necessary to use an expensive and precise liquid supply facility such as a gieser or a die. Further, in order to control the width of the coating liquid having a low viscosity, a method of physically pressing a resin such as Teflon (registered trademark) against both ends of a roller for coating and using a pinning effect has been adopted.
特許文献1、2には、バッキングローラとドクタローラ間に機能液の液溜めを設け、バッキングローラを通過するフィルム上に液溜め内の機能液を塗布するローラ塗布装置が開示されている。そして、特許文献2には、液溜めの両脇を仕切って塗布幅を規制するサイドプレートと後端を仕切るバックプレートから構成され、液溜め領域を規定するダム部材が提案されている。 Patent Documents 1 and 2 disclose a roller coating device in which a liquid reservoir of a functional liquid is provided between a backing roller and a doctor roller, and the functional liquid in the liquid reservoir is applied onto a film passing through the backing roller. Further, Patent Document 2 proposes a dam member that is composed of a side plate that partitions both sides of a liquid reservoir to regulate the coating width and a back plate that partitions the rear end, and defines a liquid reservoir area.
積層フィルムの生産に際して、フィルム上もしくはフィルム間に設けられる機能層の塗布幅を制御することは、製品幅の一定化による生産効率の向上を図るためには、重要な課題である。特許文献2に記載のサイドプレートを有するダム部材を用いれば塗布幅を規制することが可能と考えられる。 In the production of laminated films, controlling the coating width of the functional layer provided on or between the films is an important issue in order to improve the production efficiency by keeping the product width constant. It is considered that the coating width can be regulated by using the dam member having the side plate described in Patent Document 2.
しかし、固定配置されたダム部材に対し、ローラを回転させてフィルムを搬送するため、ダム部材とフィルムあるいはローラとの間には隙間を設ける必然性がある。したがって、このような隙間から機能液が漏れ出てしまい、機能液のロスが生じる恐れがある。粘度の低い機能液程この問題は顕著であり、機能液の流出が抑えられない場合には、塗布膜の有効幅内においてもその端部で膜厚が薄くなるなどの問題が生じる恐れもある。 However, since the film is conveyed by rotating the roller with respect to the fixedly arranged dam member, it is necessary to provide a gap between the dam member and the film or the roller. Therefore, the functional liquid may leak from such a gap, resulting in loss of the functional liquid. This problem is more pronounced for functional liquids with lower viscosities, and if the outflow of functional liquid cannot be suppressed, problems such as thinning of the film thickness at the edges may occur even within the effective width of the coating film. ..
本発明は、上記事情に鑑みてなされたものであって、機能液の塗布幅を制御し、塗布膜の膜厚を均一に維持でき、かつ機能液のロスを抑制することが可能な積層フィルムの製造方法および積層フィルム製造装置を提供することを目的とする。 The present invention has been made in view of the above circumstances, and is a laminated film capable of controlling the coating width of the functional liquid, maintaining a uniform film thickness of the coating film, and suppressing loss of the functional liquid. It is an object of the present invention to provide a manufacturing method and a laminated film manufacturing apparatus.
本発明の積層フィルムの製造方法は、フィルムの一面に機能液の液溜まりを接触させた状態でフィルムを搬送してフィルムの一面に機能液を塗布することにより、フィルムとフィルムの一面に形成された機能液の塗布膜からなる機能層とを備えた積層フィルムを製造する積層フィルムの製造方法であって、
液溜まりのフィルム幅方向の両端位置を規定するシール部材を、機能液の塗布幅に合わせて配置し、シール部材のフィルム幅方向の外側から液溜まりに流体圧を加えることにより、シール部材の周辺からの機能液の流出を抑制しつつ、機能液による塗布膜を形成する積層フィルムの製造方法である。
In the method for producing a laminated film of the present invention, a film is formed on one surface of a film by transporting the film in a state where a pool of functional liquid is in contact with one surface of the film and applying the functional liquid to one surface of the film. It is a manufacturing method of a laminated film for manufacturing a laminated film including a functional layer composed of a coating film of a functional liquid.
Sealing members that define the positions of both ends of the liquid pool in the film width direction are arranged according to the application width of the functional liquid, and fluid pressure is applied to the liquid pool from the outside of the sealing member in the film width direction to surround the sealing member. This is a method for producing a laminated film that forms a coating film with a functional liquid while suppressing the outflow of the functional liquid from the water.
液溜まりに加えられる流体圧は、動圧であっても静圧であってもよい。 The fluid pressure applied to the liquid pool may be dynamic pressure or static pressure.
本発明の積層フィルムの製造方法においては、液溜まりの液面を窒素雰囲気下に置いて塗布膜を形成してもよい。 In the method for producing a laminated film of the present invention, the liquid surface of the liquid pool may be placed under a nitrogen atmosphere to form a coating film.
本発明の積層フィルムの製造方法においては、上記流体圧を、窒素ガスにより生じさせてもよい。 In the method for producing a laminated film of the present invention, the fluid pressure may be generated by nitrogen gas.
本発明の積層フィルム製造装置は、フィルムを搬送する搬送機構と、
搬送されているフィルムの一面に接触させて設けられる機能液の液溜まりと、
液溜まりのフィルム幅方向の両端位置を規定するシール部材と、
シール部材のフィルム幅方向の外側から液溜まりに流体圧を加える圧力付与機構とを備えた積層フィルム製造装置である。
The laminated film manufacturing apparatus of the present invention includes a transport mechanism for transporting a film and
A pool of functional liquid that is provided in contact with one side of the film being conveyed,
A seal member that defines the positions of both ends of the liquid pool in the film width direction,
It is a laminated film manufacturing apparatus provided with a pressure applying mechanism for applying a fluid pressure to a liquid pool from the outside in the film width direction of the sealing member.
本発明の積層フィルム製造装置は、圧力付与機構が、シール部材のフィルム幅方向の外側から液溜まりに向けて気体を吹き付ける気体供給部を備え、気体を吹き付けることにより液溜まりに流体圧を加える構成であってもよい。 The laminated film manufacturing apparatus of the present invention has a configuration in which the pressure applying mechanism includes a gas supply unit that blows gas from the outside of the sealing member in the film width direction toward the liquid pool, and applies fluid pressure to the liquid pool by blowing the gas. It may be.
本発明の積層フィルム製造装置は、圧力付与機構が、シール部材のフィルム幅方向の外側に隣接するバッファ室を画成するバッファ室画成部材を備え、バッファ室を介して液溜まりに流体圧を加える構成であってもよい。 In the laminated film manufacturing apparatus of the present invention, the pressure applying mechanism includes a buffer chamber defining member that defines a buffer chamber adjacent to the outside in the film width direction of the sealing member, and applies fluid pressure to the liquid pool through the buffer chamber. It may be a configuration to be added.
本発明の積層フィルム製造装置は、バッファ室内に向けて、バッファ室画成部材のフィルム幅方向の外側から気体を吹き付ける気体供給部を備え、バッファ室内に気体を吹き付けることにより、バッファ室を介して液溜まりに流体圧を加える構成であってもよい。 The laminated film manufacturing apparatus of the present invention includes a gas supply unit that blows gas from the outside of the buffer chamber drawing member in the film width direction toward the buffer chamber, and by blowing gas into the buffer chamber, the gas is blown through the buffer chamber. It may be configured to apply fluid pressure to the liquid pool.
本発明の積層フィルム製造装置は、バッファ室のフィルム幅方向の外側に隣接する加圧室を画成する加圧室画成部材と、加圧室に気体を供給する気体供給部とを備え、バッファ室内に、加圧室から供給された気体による圧力が加えられることにより、バッファ室を介して液溜まりに流体圧を加える構成であってもよい。 The laminated film manufacturing apparatus of the present invention includes a pressure chamber defining member that defines a pressure chamber adjacent to the outside in the film width direction of the buffer chamber, and a gas supply unit that supplies gas to the pressure chamber. By applying the pressure of the gas supplied from the pressurizing chamber to the buffer chamber, the fluid pressure may be applied to the liquid pool through the buffer chamber.
本発明の積層フィルム製造装置において、気体供給部が窒素を供給するものであることが好ましい。 In the laminated film manufacturing apparatus of the present invention, it is preferable that the gas supply unit supplies nitrogen.
本発明の積層フィルム製造装置においては、液溜まりの上方空間を覆うカバー部材と、上方空間に窒素を供給する窒素供給機構を備えていてもよい。 The laminated film manufacturing apparatus of the present invention may include a cover member that covers the space above the liquid pool and a nitrogen supply mechanism that supplies nitrogen to the space above.
本発明の積層フィルム製造装置においては、液溜まりに接触するローラを備え、ローラは表面に凹版または凸版を有していてもよい。 The laminated film manufacturing apparatus of the present invention may include a roller that comes into contact with a liquid pool, and the roller may have an intaglio or a letterpress on its surface.
本発明の積層フィルムの製造方法および製造装置によれば、シール部材により所望の塗布幅に規制された液溜まりからフィルムに機能液を塗布するので、所望の有効幅において均一な膜厚の塗布膜を形成することができる。また、シール部材のフィルム幅方向の外側から液溜まりに対して流体圧を加えることにより、フィルム幅方向に漏れ出す機能液を抑制することができ、機能液のロスを抑えることができる。 According to the method and apparatus for producing a laminated film of the present invention, the functional liquid is applied to the film from a liquid pool regulated to a desired coating width by a sealing member, so that a coating film having a uniform film thickness in a desired effective width is applied. Can be formed. Further, by applying a fluid pressure to the liquid pool from the outside in the film width direction of the sealing member, the functional liquid leaking in the film width direction can be suppressed, and the loss of the functional liquid can be suppressed.
以下、本発明の実施形態について図面を用いて説明するが、本発明はこれに限られるものではない。なお、視認しやすくするため、図面中の各構成要素の縮尺等は実際のものとは適宜変えてある。 Hereinafter, embodiments of the present invention will be described with reference to the drawings, but the present invention is not limited thereto. The scale of each component in the drawing is appropriately changed from the actual one in order to make it easier to see.
<積層フィルム製造装置>
図1は、本発明の第1の実施形態の積層フィルム製造装置の一例の概略構成図である。図2は図1の積層フィルム製造装置100の塗布部103の拡大図、図3は塗布部103の一部構成を示す図である。
<Laminated film manufacturing equipment>
FIG. 1 is a schematic configuration diagram of an example of a laminated film manufacturing apparatus according to the first embodiment of the present invention. FIG. 2 is an enlarged view of the coating portion 103 of the laminated film manufacturing apparatus 100 of FIG. 1, and FIG. 3 is a diagram showing a partial configuration of the coating portion 103.
積層フィルム製造装置100は、支持体として用いられる樹脂フィルムなどのフィルム10をロール状態にて支持し、繰り出す送出機101と、フィルム状のワークを搬送するための複数の図示しないガイドローラと、各処理工程を経て形成された積層フィルムをロール状に巻き取る巻取機104を備えており、送出機101、ガイドローラおよび巻取機104によりフィルムを搬送する搬送機構が構成されている。 The laminated film manufacturing apparatus 100 includes a feeder 101 that supports and feeds a film 10 such as a resin film used as a support in a roll state, and a plurality of guide rollers (not shown) for conveying a film-like work. A winder 104 for winding a laminated film formed through a processing step in a roll shape is provided, and a transport mechanism for transporting the film by a feeder 101, a guide roller, and a winder 104 is configured.
積層フィルム製造装置100は、送出機101と巻取機104との間に、フィルム10の一面10aに機能液21を塗布して塗布膜20Mを形成する塗布部103と、フィルム10の一面に形成された塗布膜20Mを硬化させて機能層20を形成する硬化処理部105とを備えている。 The laminated film manufacturing apparatus 100 is formed on one surface of the film 10 and a coating portion 103 that coats the functional liquid 21 on one surface 10a of the film 10 to form a coating film 20M between the feeder 101 and the winder 104. It is provided with a curing treatment unit 105 that cures the coated coating film 20M to form a functional layer 20.
図2および図3に示すように、塗布部103には、搬送されているフィルム10の一面10aに接触させて設けられる機能液21の液溜まり22と、液溜まり22のフィルム幅方向の両端位置を規定する1対のシール部材32と、各シール部材32のフィルム幅方向の外側から液溜まり22に流体圧を加える圧力付与機構40とを備えている。本積層フィルム製造装置100における塗布部103では、フィルム10は表面1aに凹凸を有する型ローラ1とローラ2との間を搬送されるように構成されており、型ローラ1とローラ2によってフィルムが挟持される位置上のローラ2にラップされたフィルム10と型ローラ1との間に、液溜まり22が設けられている。 As shown in FIGS. 2 and 3, the coating portion 103 has a liquid pool 22 of the functional liquid 21 provided in contact with one surface 10a of the film 10 being conveyed, and positions of both ends of the liquid pool 22 in the film width direction. A pair of sealing members 32 and a pressure applying mechanism 40 for applying fluid pressure to the liquid pool 22 from the outside in the film width direction of each sealing member 32 are provided. In the coating portion 103 of the laminated film manufacturing apparatus 100, the film 10 is configured to be conveyed between the mold roller 1 and the roller 2 having irregularities on the surface 1a, and the film is transferred by the mold roller 1 and the roller 2. A liquid pool 22 is provided between the film 10 wrapped around the roller 2 on the sandwiched position and the mold roller 1.
1対のシール部材32は、機能液21の塗布幅よりも長い支持板34に、塗布幅Wの間隔で平行に支持されている。塗布幅Wは積層フィルムの所望の有効幅に設定されている。支持板34は、シール部材32を所定位置に配置支持するものであり、この支持板34とシール部材32とが一体化されて塗布幅規制部材30が構成されている。 The pair of sealing members 32 are supported in parallel by the support plate 34, which is longer than the coating width of the functional liquid 21, at intervals of the coating width W. The coating width W is set to a desired effective width of the laminated film. The support plate 34 arranges and supports the seal member 32 at a predetermined position, and the support plate 34 and the seal member 32 are integrated to form the coating width regulating member 30.
図4に、塗布幅規制部材30の斜視図を示す。
図4に示すように、シール部材32はフィルム幅方向に幅Lを有する。また、シール部材32の型ローラ1に沿って配置される面32aはローラ1の曲面に沿った曲面を有し、ローラ2にラップされるフィルム10に沿って配置される面32bはローラ2の曲面に沿った曲面を有する。
FIG. 4 shows a perspective view of the coating width regulating member 30.
As shown in FIG. 4, the seal member 32 has a width L in the film width direction. Further, the surface 32a arranged along the mold roller 1 of the sealing member 32 has a curved surface along the curved surface of the roller 1, and the surface 32b arranged along the film 10 wrapped by the roller 2 is the roller 2. It has a curved surface along the curved surface.
図3に示すように、支持板34は、液溜まり22の上方空間25を覆うカバー部材を兼ねている。支持板34とシール部材32、型ローラ1およびフィルム10で囲まれた空間は液溜まり室を構成している。支持板34には、液溜まり22に機能液21を供給する機能液供給ノズル用口34a、液溜まり22の液面を検出する液面センサ用口34b、液溜まり22の上方空間25への窒素パージを行うための窒素供給ノズル用口34cおよび液溜まり22の上方空間25中の酸素濃度を測定する酸素濃度センサ用口34dが設けられている。上方空間25への窒素パージにより液溜まり22の液面を窒素雰囲気下に置くことができる。ここで、機能液供給ノズル用口、窒素供給ノズル用口の個数と位置は、機能液の物性や量、あるいは窒素供給量などに応じて適宜設定することができる。また、機能液温度や雰囲気の状態を計測するための各種センサ用の口を適宜設置することもできる。 As shown in FIG. 3, the support plate 34 also serves as a cover member that covers the space 25 above the liquid pool 22. The space surrounded by the support plate 34, the sealing member 32, the mold roller 1, and the film 10 constitutes a liquid pool chamber. The support plate 34 has a functional liquid supply nozzle port 34a for supplying the functional liquid 21 to the liquid pool 22, a liquid level sensor port 34b for detecting the liquid level of the liquid pool 22, and oxygen to the space 25 above the liquid pool 22. A nitrogen supply nozzle port 34c for purging and an oxygen concentration sensor port 34d for measuring the oxygen concentration in the space 25 above the liquid pool 22 are provided. By purging the nitrogen in the upper space 25, the liquid level of the liquid pool 22 can be placed in a nitrogen atmosphere. Here, the number and position of the functional liquid supply nozzle port and the nitrogen supply nozzle port can be appropriately set according to the physical properties and amount of the functional liquid, the nitrogen supply amount, and the like. In addition, ports for various sensors for measuring the temperature of the functional liquid and the state of the atmosphere can be appropriately installed.
なお、ここでは、支持板34がカバー部材として設けられているが、液溜まり22の液面の雰囲気制御を行う必要がない場合には、カバー部材である必要はない。その場合には、塗布幅規制部材30は、支持板34に代えて、例えば、支持棒によって1対のシール部材32を支持する構成であってもよい。また、塗布幅規制部材30は、両端のシール部材32を共通の支持板により支持する構成に限らず、それぞれをフィルムの幅方向両側から別個に支持する形態であってもよい。 Although the support plate 34 is provided as a cover member here, it does not need to be a cover member when it is not necessary to control the atmosphere of the liquid level of the liquid pool 22. In that case, the coating width regulating member 30 may have a configuration in which, for example, a pair of sealing members 32 are supported by a support rod instead of the support plate 34. Further, the coating width regulating member 30 is not limited to the configuration in which the sealing members 32 at both ends are supported by a common support plate, and each may be separately supported from both sides in the width direction of the film.
積層フィルム製造中は固定配置されるシール部材32に対して、型ローラ1、ローラ2は回転し、その回転に伴ってフィルム10は搬送される。したがって、図2に示すように、この型ローラ1、ローラ2の回転およびフィルム10の搬送を妨げないようにシール部材32は、型ローラ1およびフィルム10と一定の間隔を持って配置される。そのため、シール部材32(の面32a)と型ローラ1との隙間c1、シール部材32(の面32b)とフィルム10との隙間c2およびシール部材32の下端32cとフィルム10がローラ2と接触する位置までの隙間c3は必然的に生じる。これらのシール部材32の周辺の隙間c1〜c3からは、液溜まり22からの機能液21の漏れが生じ得るため、その間隔は小さい方が好ましく、フィルム10がラップされるローラ2の表面とシール部材32の面32bの間隔はフィルム10の膜厚程度とすることが好ましい。一方で、シール部材32の下端32cは先細り形状となりフィルム10に接触するとフィルム10に傷をつけるため、フィルムに接触しないように配置する必要があり、隙間c3は最も大きくなってしまう。さらに隙間c3は液溜まり22の下端に位置するため、機能液21による液圧が生じる。したがって、シール部材32の周辺のうち、この隙間c3から最も機能液21の液漏れが生じやすい。 During the production of the laminated film, the mold roller 1 and the roller 2 rotate with respect to the seal member 32 which is fixedly arranged, and the film 10 is conveyed along with the rotation. Therefore, as shown in FIG. 2, the sealing member 32 is arranged at a constant distance from the mold roller 1 and the film 10 so as not to interfere with the rotation of the mold roller 1 and the roller 2 and the transportation of the film 10. Therefore, the seal member 32 (surface 32a) of the gap c 1 between the mold roller 1, the sealing member 32 (surface 32b) of the lower end 32c and the film 10 of the gap c 2 and the sealing member 32 between the film 10 and the roller 2 clearance c 3 position to the contacting inevitably occur. Since the functional liquid 21 may leak from the liquid pool 22 from the gaps c 1 to c 3 around these sealing members 32, it is preferable that the distance between them is small, and the surface of the roller 2 on which the film 10 is wrapped is wrapped. The distance between the surface 32b of the seal member 32 and the surface 32b of the seal member 32 is preferably about the thickness of the film 10. On the other hand, since the lower end 32c of the seal member 32 damaging the film 10 in contact with the film 10 becomes tapered, must be placed so as not to contact the film, the gap c 3 becomes highest. Further, since the gap c 3 is located at the lower end of the liquid pool 22, the hydraulic pressure due to the functional liquid 21 is generated. Therefore, of the periphery of the sealing member 32, leakage of the most functional fluid 21 from the gap c 3 is likely to occur.
圧力付与機構40は、シール部材32のフィルム幅方向の外側から液溜まり22に向けて気体42を吹き付ける気体供給部としてのエアブロー装置41から構成されている。このエアブロー装置41は空気あるいは窒素ガスなどの圧縮気体のタンクを備え、ノズルから圧縮気体を放出するものである。気体42は、圧縮空気でもよいが、機能液が酸化しやすい等の制約がある場合は窒素ガス、アルゴンガスなどが好ましい。その場合はコストの観点から窒素ガスが特に好ましい。 The pressure applying mechanism 40 is composed of an air blow device 41 as a gas supply unit that blows a gas 42 toward the liquid pool 22 from the outside of the seal member 32 in the film width direction. The air blow device 41 includes a tank for a compressed gas such as air or nitrogen gas, and discharges the compressed gas from a nozzle. The gas 42 may be compressed air, but nitrogen gas, argon gas, or the like is preferable when there are restrictions such as the functional liquid being easily oxidized. In that case, nitrogen gas is particularly preferable from the viewpoint of cost.
エアブロー装置41は、シール部材32のフィルム幅方向外側から、シール部材32の下端32c側の隙間c3に向けて気体42を吹き付ける。隙間c3に気体42を吹き付けることにより、シール部材32の下端32cの隙間c3から気体42を液溜まり22に送り込んで液溜まり22に対して流体圧を加え、この隙間c3から機能液21がフィルム幅方向外側に漏れ出るのを防ぐことができる。 Air blow device 41, the film width direction outside of the sealing member 32, blowing air 42 toward the lower end 32c side of the gap c 3 of the sealing member 32. By blowing gas 42 into the gap c 3, the fluid pressure applied to the liquid reservoir 22 is fed into the gap c 3 of the lower end 32c of the seal member 32 gas 42 to the liquid reservoir 22, the functional liquid from the gap c 3 21 Can be prevented from leaking to the outside in the film width direction.
既述の通り、シール部材32の下端32cの隙間c3において、液溜まり22からフィルム幅方向外側に機能液21が漏れ出やすい構造となっている。したがって、エアブロー装置41は、シール部材32の周辺の隙間全体に対して気体42を吹き付けてもよいが、最も機能液21が漏れ出やすい隙間c3に気体42を吹き付ける構成が好ましい。 As described above, in the gap c 3 of the lower end 32c of the seal member 32, and has a prone structures leakage of the functional fluid 21 from the liquid reservoir 22 in the film width direction outside. Accordingly, the air blow device 41 may be sprayed gas 42 for the entire clearance near the sealing member 32, but the configuration of blowing gas 42 into prone gap c 3 leaks most functional fluid 21 is preferred.
塗布部103において、塗布幅規制部材30には、図3に示すように、液溜まり22に機能液21を供給する機能液供給ノズル52、液溜まり22の液面を検出する液面センサ54、液溜まり22の上方空間25への窒素パージを行うための窒素供給ノズル56、および上方空間25の酸素濃度を測定するための酸素濃度センサ58がセットされる。機能液供給ノズル52は機能液を供給するためのポンプPに接続される。窒素供給機構の一部をなす窒素供給ノズル56は、図示しない配管により窒素供給装置に接続される。 In the coating unit 103, as shown in FIG. 3, the coating width regulating member 30 includes a functional liquid supply nozzle 52 that supplies the functional liquid 21 to the liquid pool 22, and a liquid level sensor 54 that detects the liquid level of the liquid pool 22. A nitrogen supply nozzle 56 for purging the nitrogen in the upper space 25 of the liquid pool 22 and an oxygen concentration sensor 58 for measuring the oxygen concentration in the upper space 25 are set. The functional liquid supply nozzle 52 is connected to a pump P for supplying the functional liquid. The nitrogen supply nozzle 56, which forms part of the nitrogen supply mechanism, is connected to the nitrogen supply device by a pipe (not shown).
硬化処理部105は、機能液の塗布膜を硬化させる活性エネルギーを塗布膜に与えることができる構成を有していればよく、例えば、機能液が光重合性組成物である場合には、UV光を照射するUV照射装置であり、機能液が熱重合性組成物である場合には、ヒータなどの加熱装置である。 The curing treatment unit 105 may have a structure capable of applying active energy for curing the coating film of the functional liquid to the coating film. For example, when the functional liquid is a photopolymerizable composition, UV It is a UV irradiation device that irradiates light, and when the functional liquid is a thermopolymerizable composition, it is a heating device such as a heater.
<積層フィルムの製造方法>
上記構成の積層フィルム製造装置100を用いた積層フィルムの製造方法について説明する。
支持体であるフィルム10として、PET(ポリエチレンテレフタレート)、TAC(トリアセチルセルロース)およびPEN(ポリエチレンナフタレート)などの樹脂フィルムを用いる。機能液21としては、粘度10〜10,000mPa・sのアクリル樹脂などの樹脂組成物を適用することができる。
<Manufacturing method of laminated film>
A method for manufacturing a laminated film using the laminated film manufacturing apparatus 100 having the above configuration will be described.
As the film 10 as the support, resin films such as PET (polyethylene terephthalate), TAC (triacetyl cellulose) and PEN (polyethylene naphthalate) are used. As the functional liquid 21, a resin composition such as an acrylic resin having a viscosity of 10 to 10,000 mPa · s can be applied.
送出機101から繰り出されたフィルム10は塗布部103に搬送され、塗布部103において、フィルム10の一面10aが機能液21の液溜まり22に接触されるように搬送され、フィルム10の一面10aに機能液21が塗布される。このとき、シール部材32が、機能液21の塗布幅に合わせて配置されており、エアブロー装置41によりシール部材32のフィルム幅方向の外側から液溜まり22に気体42が吹き付けられることにより、液溜まり22に流体圧が加えられて、シール部材32の周辺からの機能液21の流出が抑制されつつ、機能液21による塗布膜20Mが形成される。 The film 10 unwound from the delivery machine 101 is conveyed to the coating unit 103, and in the coating unit 103, one surface 10a of the film 10 is conveyed so as to be in contact with the liquid pool 22 of the functional liquid 21, and is conveyed to the one surface 10a of the film 10. The functional liquid 21 is applied. At this time, the seal member 32 is arranged according to the coating width of the functional liquid 21, and the gas 42 is sprayed onto the liquid pool 22 from the outside of the seal member 32 in the film width direction by the air blow device 41, so that the liquid pool is collected. A fluid pressure is applied to 22 to form a coating film 20M by the functional liquid 21 while suppressing the outflow of the functional liquid 21 from the periphery of the sealing member 32.
先に説明した通り、エアブロー装置41により、シール部材32の下端32c側の隙間c3に対して気体42が吹き付けられることにより、下端32cの隙間c3から気体42が侵入して液溜まり22に流体圧を加え、液溜まり22からフィルム幅外側への機能液21の流出を抑制することができる。 As described above, the air blow device 41, sealed by the gas 42 is blown against the lower end 32c side of the gap c 3 members 32, the fluid in the liquid reservoir 22 by a gas 42 entering from the gaps c3 of the lower end 32c A pressure can be applied to suppress the outflow of the functional liquid 21 from the liquid pool 22 to the outside of the film width.
その後、硬化処理部105において、フィルム10上に形成された塗布膜20Mに、フィルム10の他面側からUV照射がなされて塗布膜20Mが硬化され機能層20が形成される。 After that, in the curing treatment unit 105, the coating film 20M formed on the film 10 is irradiated with UV from the other surface side of the film 10 to cure the coating film 20M and form the functional layer 20.
上記工程を経てフィルム10の一面10aに機能層20が積層されてなる積層フィルムが形成され、巻取機104によりロール状に巻き取られる。 Through the above steps, a laminated film in which the functional layer 20 is laminated on one surface 10a of the film 10 is formed, and the film is wound into a roll by the winder 104.
本積層フィルム製造装置100および製造方法によれば、シール部材32により所望の塗布幅に規制された液溜まり22からフィルム10に機能液21を塗布するので、所望の有効幅において均一な膜厚の塗布膜を形成することができる。また、液溜まり22に対してフィルム幅方向から流体圧を加えることにより、フィルム幅方向に漏れ出す機能液を抑制することができ、機能液のロスを抑えることができる。 According to the laminated film manufacturing apparatus 100 and the manufacturing method, the functional liquid 21 is applied to the film 10 from the liquid pool 22 regulated to the desired coating width by the sealing member 32, so that the functional liquid 21 has a uniform film thickness in the desired effective width. A coating film can be formed. Further, by applying the fluid pressure to the liquid pool 22 from the film width direction, the functional liquid leaking in the film width direction can be suppressed, and the loss of the functional liquid can be suppressed.
本積層フィルム製造装置100において、シール部材32のフィルム幅方向の幅Lは、隙間c1、c2におけるシール部材32とローラ1もしくはフィルム10との間隔をtとしたとき、L/t≧10の関係にあることが好ましい。間隔tに対してシール部材32の幅Lを十分大きくすることにより、機能液21がシール部材32を超えてフィルム幅方向外側に漏れ出るのを抑制することが可能となる。 In the laminated film manufacturing apparatus 100, the width L of the film width direction of the seal member 32, when the distance between the seal member 32 and the roller 1 or film 10 in the gap c 1, c 2 and the t, L / t ≧ 10 It is preferable that there is a relationship of. By sufficiently increasing the width L of the seal member 32 with respect to the interval t, it is possible to prevent the functional liquid 21 from leaking beyond the seal member 32 to the outside in the film width direction.
シール部材32の材料は特に制限されるものではないが、ナイロン、ニューライト、テフロン(登録商標)等が好適に用いられる。シール部材32の材料は機能液21に対する接触角が大きい方が好ましく、接触角80°以上であることが特に好ましい。 The material of the sealing member 32 is not particularly limited, but nylon, new light, Teflon (registered trademark) and the like are preferably used. The material of the sealing member 32 preferably has a large contact angle with the functional liquid 21, and particularly preferably has a contact angle of 80 ° or more.
本製造装置100においては、凹凸パターンを有する表面1aを備えた型ローラ1を備えており、液溜まり22において、この表面1aの凹部に入り込み、型ローラ1とローラ2とのフィルムニップ位置でその凹部に閉じ込められた機能液21がフィルム10上に転写される。そのため、フィルム10の一面10aに形成される塗布膜20Mは、型ローラ1の表面凹凸に沿った凹凸パターン状に形成され、製造される積層フィルムは、このようなパターン形成された塗布膜が硬化されてなるパターン状の機能層をフィルム10上に備えたものとなる。 The manufacturing apparatus 100 includes a mold roller 1 having a surface 1a having a concavo-convex pattern, and in the liquid pool 22, the mold roller 1 enters the recess of the surface 1a and is located at a film nip position between the mold roller 1 and the roller 2. The functional liquid 21 confined in the recess is transferred onto the film 10. Therefore, the coating film 20M formed on one surface 10a of the film 10 is formed in an uneven pattern along the surface unevenness of the mold roller 1, and in the manufactured laminated film, such a patterned coating film is cured. A patterned functional layer formed on the film 10 is provided.
なお、表面に凹凸を有する型ローラは、凹版表面を備えたものであっても、凸版表面を備えたものであってもよい。他方、フィルム上に一様な機能層を形成する場合には、型ローラに代え表面に凹凸を有していないローラを用いてもよい。 The mold roller having an uneven surface may be provided with an intaglio surface or a letterpress surface. On the other hand, when forming a uniform functional layer on the film, a roller having no unevenness on the surface may be used instead of the mold roller.
上記製造装置100における具体的な装置の寸法および機能液の一例をあげる。
型ローラ1として、直径φ350mm、面長800mmであり、表面にμmオーダーの凹凸が刻まれているローラを用いる。ローラ2として、直径φ110mm、面長800mmを用いる。そして、型ローラ1とローラ2とは、両者の最近接位置において0〜100μmの間隔で設置する。このとき、塗布速度(搬送速度)は0.5〜5m/分程度とする。
機能液21としては、例えば、TMPTA(トリメチロールプロパントリアクリレート)(ダイセル・オルネクス社製)を99質量部、重合開始剤であるイルガキュアTPO(BASF社製)1質量部を混合して得られる粘度100mPa・sの樹脂組成物を用いる。
このとき、硬化処理部105はUV照射装置であり、例えば、空冷式メタルハライドランプ(アイグラフィックス社製)500mW/cm2を備える。そして、300mJ/cm2で紫外線を塗布膜に照射する。上記仕様により樹脂フィルム上に型ローラの凹凸に応じたパターン状に形成されたアクリル層からなる機能層を備えた積層フィルムを製造することができる。
An example of specific device dimensions and functional liquid in the manufacturing device 100 will be given.
As the mold roller 1, a roller having a diameter of φ350 mm and a surface length of 800 mm and having irregularities on the order of μm is used. As the roller 2, a diameter of 110 mm and a surface length of 800 mm are used. Then, the mold roller 1 and the roller 2 are installed at intervals of 0 to 100 μm at the positions closest to each other. At this time, the coating speed (conveying speed) is about 0.5 to 5 m / min.
As the functional liquid 21, for example, a viscosity obtained by mixing 99 parts by mass of TMPTA (trimethylolpropane triacrylate) (manufactured by Daicel Ornex) and 1 part by mass of Irgacure TPO (manufactured by BASF) as a polymerization initiator. A resin composition of 100 mPa · s is used.
At this time, the curing treatment unit 105 is a UV irradiation device, and includes, for example, an air-cooled metal halide lamp (manufactured by Eye Graphics) 500 mW / cm 2 . Then, the coating film is irradiated with ultraviolet rays at 300 mJ / cm 2 . According to the above specifications, it is possible to manufacture a laminated film having a functional layer composed of an acrylic layer formed on a resin film in a pattern corresponding to the unevenness of a mold roller.
<積層フィルム製造装置の設計変更例>
図5に設計変更例の積層フィルム製造装置110の構成の概略構成図を示す。図1の積層フィルム製造装置100と同一要素には同一の符号を付し、詳細な説明を省略する。
<Example of design change of laminated film manufacturing equipment>
FIG. 5 shows a schematic configuration diagram of the configuration of the laminated film manufacturing apparatus 110 of the design change example. The same elements as those of the laminated film manufacturing apparatus 100 of FIG. 1 are designated by the same reference numerals, and detailed description thereof will be omitted.
設計変更例の積層フィルム製造装置110は、機能層20を第1および第2のフィルム10、12で挟んだサンドイッチ状の積層フィルムを製造する製造装置であり、既述の積層フィルム製造装置100の構成に加え、第2のフィルム12をロール状態にて支持し、繰り出す送出機102を備えている。そして、塗布部103において、第1のフィルム10と第2のフィルム12との間に液溜まり22が設けられて、塗布膜20Mを第1および第2のフィルムで挟持して搬送する構成となっている。本構成においては、型ローラ1に代えて、表面に凹凸を有していないローラ3が備えられている。本製造装置110によって製造される積層フィルムは、第1のフィルム10、機能層20および第2のフィルム12からなる。 The laminated film manufacturing apparatus 110 of the design modification example is a manufacturing apparatus for producing a sandwich-shaped laminated film in which the functional layer 20 is sandwiched between the first and second films 10 and 12, and is the laminated film manufacturing apparatus 100 described above. In addition to the configuration, a transmitter 102 that supports the second film 12 in a rolled state and feeds it out is provided. Then, in the coating unit 103, a liquid pool 22 is provided between the first film 10 and the second film 12, and the coating film 20M is sandwiched between the first and second films and conveyed. ing. In this configuration, instead of the mold roller 1, a roller 3 having no unevenness on the surface is provided. The laminated film produced by the manufacturing apparatus 110 includes a first film 10, a functional layer 20, and a second film 12.
このように、液溜まり22は、フィルムとローラとの間に限らず、フィルムとフィルムの間に形成することも可能であり、製造装置100、110いずれの構成であっても、同様のシール部材32と圧力付与機構40を備えることにより、均一な塗布膜の形成および機能液のロスを抑制する効果を同様に得ることができる。 As described above, the liquid pool 22 can be formed not only between the films but also between the films, and the same sealing member can be formed regardless of the configuration of the manufacturing apparatus 100 or 110. By providing the 32 and the pressure applying mechanism 40, the effect of forming a uniform coating film and suppressing the loss of the functional liquid can be similarly obtained.
上記実施形態の製造装置100、110において、圧力付与機構40はエアブロー装置41から構成されているが、圧力付与機構40は上記構成に限るものではない。以下に、圧力付与機構40の設計変更例について説明する。 In the manufacturing devices 100 and 110 of the above embodiment, the pressure applying mechanism 40 is composed of the air blow device 41, but the pressure applying mechanism 40 is not limited to the above configuration. An example of design modification of the pressure applying mechanism 40 will be described below.
<圧力付与機構の設計変更例1>
図6に圧力付与機構40の設計変更例1の構成を示す。図6のように、本例においては圧力付与機構40が、シール部材32のフィルム幅方向外側に隣接するバッファ室44を画成するバッファ室画成部材45と、バッファ室44内に向かってバッファ室画成部材45のフィルム幅方向の外側から気体42を吹き付ける気体供給部であるエアブロー装置41を備えている。バッファ室画成部材45は塗布幅規制部材30の支持板34にシール部材32と共に支持される。バッファ室画成部材45はシール部材32とほぼ同一の形状を有し、ローラ1、2に沿った曲面を備えている。シール部材32とバッファ室画成部材45の間隔は、バッファ室44を所望の容量とする距離で適宜定めればよい。図6においては、機能液21がバッファ室44に相当量漏れ出して充満する態様を示したが、これに限られず、液溜まり22からシール部材32とフィルム10の隙間を漏れ出てくる機能液に気体42の圧力が加えられる構成であればよい。
<Example of design change 1 of pressure application mechanism>
FIG. 6 shows the configuration of the design modification example 1 of the pressure applying mechanism 40. As shown in FIG. 6, in this example, the pressure applying mechanism 40 has a buffer chamber defining member 45 that defines a buffer chamber 44 adjacent to the outside in the film width direction of the sealing member 32, and a buffer toward the inside of the buffer chamber 44. It is provided with an air blow device 41 which is a gas supply unit for blowing a gas 42 from the outside of the chamber image forming member 45 in the film width direction. The buffer chamber defining member 45 is supported by the support plate 34 of the coating width regulating member 30 together with the seal member 32. The buffer chamber drawing member 45 has substantially the same shape as the sealing member 32, and has curved surfaces along the rollers 1 and 2. The distance between the seal member 32 and the buffer chamber defining member 45 may be appropriately determined at a distance that makes the buffer chamber 44 a desired capacity. FIG. 6 shows a mode in which a considerable amount of the functional liquid 21 leaks into the buffer chamber 44 and fills the buffer chamber 44, but the present invention is not limited to this, and the functional liquid leaks from the liquid pool 22 through the gap between the sealing member 32 and the film 10. The structure may be such that the pressure of the gas 42 is applied to the gas 42.
このようなバッファ室44を備えた場合、バッファ室44を介して液溜まり22に流体圧を加えることができる。バッファ室44内において気体42が吹き付けられた機能液21はバッファ室と液溜まり22に連通するシール部材32の下端32cの隙間c3に押し戻され、液溜まり22に対して流体圧を加える。このようにバッファ室44内に漏れ出た機能液21が液溜まり22に流体圧を加えることにより機能液21の液溜まり22からの流出を抑制することができる。 When such a buffer chamber 44 is provided, a fluid pressure can be applied to the liquid pool 22 via the buffer chamber 44. Functional fluid 21 the gas 42 is blown in the buffer chamber 44 is pushed back into the gap c 3 of the lower end 32c of the sealing member 32 which communicates with the buffer chamber and the liquid reservoir 22, is added a fluid pressure to the liquid reservoir 22. By applying the fluid pressure to the liquid pool 22 for the functional liquid 21 leaking into the buffer chamber 44 in this way, the outflow of the functional liquid 21 from the liquid pool 22 can be suppressed.
図3に示したように、バッファ室を備えず、シール部材32の外側からシール部材32の下端32c側の隙間c3に気体を吹き付ける構成では、液溜まり22に気体42が侵入し、液溜まり22に気泡42aが発生することがある。気泡42aの多くは液溜まり上の空間へと浮き上がっていくが、それら気泡42aの一部が液溜まり22の機能液中に含まれた状態で塗布されると、塗布膜20M中に気泡が生じ、積層フィルムとしての品質の低下を引き起こす場合がある。 As shown in FIG. 3, in a configuration in which a buffer chamber is not provided and gas is blown from the outside of the seal member 32 into the gap c 3 on the lower end 32 c side of the seal member 32, the gas 42 invades the liquid pool 22 and the liquid pool Bubbles 42a may be generated in 22. Most of the bubbles 42a float up into the space above the liquid pool, but when a part of the bubbles 42a is applied in the functional liquid of the liquid pool 22, bubbles are generated in the coating film 20M. , May cause deterioration of the quality of the laminated film.
本構成のように、バッファ室44を設け、バッファ室44に対してバッファ室画成部材45のフィルム幅方向外側から気体を吹き付けて、バッファ室画成部材45の下端から気体をバッファ室44内の、液溜まり側から漏れ出た機能液に気体による圧力を加える構成であれば、気体42の気泡42aはバッファ室44内で液面に浮き上がっていくため、シール部材のフィルム幅方向内側の液溜まり22側に気泡42aが侵入するのを抑制することができ、積層フィルムの品質を担保することができる。なお、バッファ室画成部材45には、エア抜きとなる開口が一部に設けられていることが好ましい。
なお、図3に示す構成であっても、機能液の粘度と気体による圧力とのバランスにより、機能液中にほとんど気泡が入り込まないように制御することは可能であり、粘度と圧力を調整することにより、十分に良好な品質の積層フィルムを製造することが可能である。
As in this configuration, the buffer chamber 44 is provided, gas is blown onto the buffer chamber 44 from the outside in the film width direction of the buffer chamber defining member 45, and gas is blown into the buffer chamber 44 from the lower end of the buffer chamber defining member 45. However, if the functional liquid leaking from the liquid pool side is configured to apply pressure by gas, the bubbles 42a of the gas 42 float up to the liquid surface in the buffer chamber 44, so that the liquid inside the sealing member in the film width direction is applied. It is possible to suppress the invasion of the air bubbles 42a into the pool 22 side, and it is possible to ensure the quality of the laminated film. It is preferable that the buffer chamber defining member 45 is partially provided with an opening for bleeding air.
Even with the configuration shown in FIG. 3, it is possible to control so that almost no bubbles enter the functional liquid by the balance between the viscosity of the functional liquid and the pressure due to the gas, and the viscosity and the pressure are adjusted. This makes it possible to produce a laminated film of sufficiently good quality.
<圧力付与機構の設計変更例2>
図7に圧力付与機構40の設計変更例2の構成を示す。図7のように、本例においては圧力付与機構40が、シール部材32のフィルム幅方向外側にバッファ室44を画成するバッファ室画成部材45と、バッファ室44のさらにフィルム幅方向外側に隣接して加圧室48を画成する加圧室画成部材49と、液溜まり22からバッファ室44に漏れ出た機能液21に、バッファ室画成部材45のフィルム幅方向の外側から気体42を加圧室48に供給する気体供給部であるエアブロー装置41を備えている。本例においては、エアブロー装置41は、外部から気体を吹き付けるのではなく、ノズルが加圧室画成部材49に設けられた供給口49aに差し込まれて、加圧室48に気体42に供給する。但し、加圧室48への気体42の供給方法として、加圧室画成部材49の下端の隙間に、フィルム幅方向外側から気体を吹き付けるようにしても構わない。設計変更例1と同様にバッファ室44を備えているので、バッファ室44を介して液溜まり22に流体圧を加えることができる。
<Example 2 of design change of pressure application mechanism>
FIG. 7 shows the configuration of the design modification example 2 of the pressure applying mechanism 40. As shown in FIG. 7, in this example, the pressure applying mechanism 40 defines the buffer chamber 44 outside the film width direction of the sealing member 32, and further to the outside of the buffer chamber 44 in the film width direction. A gas is added to the pressure chamber defining member 49 that defines the pressurizing chamber 48 adjacently and the functional liquid 21 that leaks from the liquid pool 22 to the buffer chamber 44 from the outside of the buffer chamber defining member 45 in the film width direction. It is provided with an air blow device 41 which is a gas supply unit that supplies 42 to the pressurizing chamber 48. In this example, the air blow device 41 does not blow the gas from the outside, but the nozzle is inserted into the supply port 49a provided in the pressurizing chamber drawing member 49 to supply the gas 42 to the pressurizing chamber 48. .. However, as a method of supplying the gas 42 to the pressurizing chamber 48, the gas may be sprayed from the outside in the film width direction into the gap at the lower end of the pressurizing chamber imaging member 49. Since the buffer chamber 44 is provided as in the design change example 1, the fluid pressure can be applied to the liquid pool 22 via the buffer chamber 44.
図8に、本例の圧力付与機構の一部構成を備える塗布幅規制部材30の斜視図を示す。図8に示すように、バッファ室画成部材45は塗布幅規制部材30の支持板34にシール部材32と共に支持される。同様に、加圧室画成部材49も支持板34に支持される。バッファ室画成部材45および加圧室画成部材49は、シール部材32とほぼ同一の形状を有し、ローラ1、2に沿った曲面を備えている。シール部材32とバッファ室画成部材45の間隔は、バッファ室44を所望の容量とする距離で適宜定めればよく、バッファ室画成部材45と加圧室画成部材49の間隔は、加圧室48を所望の容量とする距離で適宜定めればよい。
なお、シール部材32と加圧室48との間にはバッファ室44を1つのみならず、複数備えていてもよい。
FIG. 8 shows a perspective view of the coating width regulating member 30 including a partial configuration of the pressure applying mechanism of this example. As shown in FIG. 8, the buffer chamber defining member 45 is supported by the support plate 34 of the coating width regulating member 30 together with the seal member 32. Similarly, the pressurizing chamber drawing member 49 is also supported by the support plate 34. The buffer chamber defining member 45 and the pressurizing chamber defining member 49 have substantially the same shape as the sealing member 32, and have curved surfaces along the rollers 1 and 2. The distance between the seal member 32 and the buffer chamber defining member 45 may be appropriately determined at a distance that allows the buffer chamber 44 to have a desired capacity, and the distance between the buffer chamber defining member 45 and the pressure chamber defining member 49 is added. The pressure chamber 48 may be appropriately determined at a distance having a desired capacity.
It should be noted that not only one buffer chamber 44 but also a plurality of buffer chambers 44 may be provided between the seal member 32 and the pressurizing chamber 48.
本例においては、図7に示すように、加圧室48に気体42が供給されて加圧室48内は加圧され、隣接するバッファ室44内に加圧室48で加圧された気体42の圧力が加えられる。バッファ室44に加えられた気体による圧力は直接もしくは間接的にシール部材32側から漏れ出た機能液21に加えられる。そして、バッファ室44内において気体42による圧力が加えられた機能液21はシール部材32との連通部に押し戻され、液溜まり22に対して流体圧を加える。このようにバッファ室44内に漏れ出た機能液21による流体圧により機能液21の液溜まり22からの流出を抑制することができる。 In this example, as shown in FIG. 7, the gas 42 is supplied to the pressurizing chamber 48, the inside of the pressurizing chamber 48 is pressurized, and the gas pressurized in the adjacent buffer chamber 44 by the pressurizing chamber 48. Forty-two pressures are applied. The pressure due to the gas applied to the buffer chamber 44 is directly or indirectly applied to the functional liquid 21 leaking from the sealing member 32 side. Then, the functional liquid 21 to which the pressure of the gas 42 is applied in the buffer chamber 44 is pushed back to the communication portion with the seal member 32, and the fluid pressure is applied to the liquid pool 22. The fluid pressure of the functional liquid 21 leaking into the buffer chamber 44 in this way can suppress the outflow of the functional liquid 21 from the liquid pool 22.
1 型ローラ
1a 型ローラの表面
2 ローラ
10、12 フィルム
10a フィルムの表面
20 機能層
20M 塗布膜
21 機能液
22 液溜まり
25 液溜まりの上方空間
30 塗布幅規制部材
32 シール部材
32a、32b シール部材の面
32c シール部材の下端
34 支持板
34a 機能液供給ノズル用口
34b 液面センサ用口
34c 窒素供給ノズル用口
34d 酸素濃度測定口
40 圧力付与機構
41 エアブロー装置
42 気体
42a 気泡
44 バッファ室
45 バッファ室画成部材
48 加圧室
49 加圧室画成部材
49a 供給口
52 機能液供給ノズル
54 液面センサ
56 窒素供給ノズル
58 酸素濃度センサ
100、110 積層フィルム製造装置
101、102 送出機
103 塗布部
104 巻取機
105 硬化処理部
110 製造装置
1 type roller 1a type roller surface 2 roller 10, 12 film 10a film surface 20 functional layer 20M coating film 21 functional liquid 22 liquid pool 25 upper space of liquid pool 30 coating width regulating member 32 sealing member 32a, 32b Surface 32c Lower end of seal member 34 Support plate 34a Functional liquid supply nozzle port 34b Liquid level sensor port 34c Nitrogen supply nozzle port 34d Oxygen concentration measurement port 40 Pressure application mechanism 41 Air blower 42 Gas 42a Bubbles 44 Buffer room 45 Buffer room Drawing member 48 Pressurizing chamber 49 Pressurizing chamber Drawing member 49a Supply port 52 Functional liquid supply nozzle 54 Liquid level sensor 56 Nitrogen supply nozzle 58 Oxygen concentration sensor 100, 110 Laminated film manufacturing equipment 101, 102 Transmitter 103 Coating unit 104 Winding machine 105 Hardening processing unit 110 Manufacturing equipment
Claims (12)
前記液溜まりのフィルム幅方向の両端位置を規定するシール部材を、前記機能液の塗布幅に合わせて、かつ、前記シール部材の一つの面を前記フィルムの前記一面に対向させて配置し、該シール部材の前記フィルム幅方向の外側から前記液溜まりに流体圧を加えることにより、前記シール部材の周辺からの前記機能液の流出を抑制しつつ、前記機能液による塗布膜を形成する積層フィルムの製造方法であり、
前記シール部材の前記フィルム幅方向の幅Lが、前記一つの面と前記フィルムの前記一面との間隔tに対して、L/t≧10を満たす積層フィルムの製造方法。 The function formed on the film and the one surface of the film by transporting the film in a state where the liquid pool of the functional liquid is in contact with one surface of the film and applying the functional liquid to the one surface of the film. A method for producing a laminated film, which is a method for producing a laminated film having a functional layer composed of a liquid coating film.
The sealing members that define the positions of both ends of the liquid pool in the film width direction are arranged so as to match the coating width of the functional liquid and one surface of the sealing member faces the one surface of the film. A laminated film that forms a coating film with the functional liquid while suppressing the outflow of the functional liquid from the periphery of the sealing member by applying a fluid pressure to the liquid pool from the outside in the film width direction of the sealing member . It is a manufacturing method,
A method for producing a laminated film in which the width L of the sealing member in the film width direction satisfies L / t ≧ 10 with respect to the distance t between the one surface and the one surface of the film.
搬送されているフィルムの一面に接触させて設けられる機能液の液溜まりと、
前記液溜まりのフィルム幅方向の両端位置を規定するシール部材と、
該シール部材の前記フィルム幅方向の外側から前記液溜まりに流体圧を加える圧力付与機構とを備え、
前記シール部材は、該シール部材の一つの面を前記フィルムの前記一面に対向させて配置され、
前記シール部材の前記フィルム幅方向の幅Lが、前記シール部材と前記フィルムの前記一面との間隔tに対して、L/t≧10を満たす積層フィルム製造装置。 A transport mechanism that transports the film and
A pool of functional liquid that is provided in contact with one side of the film being conveyed,
A seal member that defines the positions of both ends of the liquid pool in the film width direction,
A pressure applying mechanism for applying a fluid pressure to the liquid pool from the outside of the sealing member in the film width direction is provided .
The sealing member is arranged so that one surface of the sealing member faces the one surface of the film.
A laminated film manufacturing apparatus in which the width L of the sealing member in the film width direction satisfies L / t ≧ 10 with respect to the distance t between the sealing member and the one surface of the film.
搬送されているフィルムの一面に接触させて設けられる機能液の液溜まりと、
前記液溜まりのフィルム幅方向の両端位置を規定するシール部材と、
該シール部材の前記フィルム幅方向の外側から前記液溜まりに流体圧を加える圧力付与機構とを備え、
前記圧力付与機構が、前記シール部材の前記フィルム幅方向の外側に隣接するバッファ室を画成するバッファ室画成部材を備え、前記バッファ室に気体を供給することにより、前記シール部材と前記フィルムの前記一面との間から前記バッファ室に流出した前記機能液に前記気体の圧力を加え、前記流出した機能液を介して前記液溜まりに前記流体圧を加える積層フィルム製造装置。 A transport mechanism that transports the film and
A pool of functional liquid that is provided in contact with one side of the film being conveyed,
A seal member that defines the positions of both ends of the liquid pool in the film width direction,
A pressure applying mechanism for applying a fluid pressure to the liquid pool from the outside of the sealing member in the film width direction is provided.
The pressure applying mechanism includes a buffer chamber defining member that defines a buffer chamber adjacent to the outside of the sealing member in the film width direction, and supplies gas to the buffer chamber to supply the sealing member and the film. A laminated film manufacturing apparatus that applies the pressure of the gas to the functional liquid that has flowed out from the one surface to the buffer chamber, and applies the fluid pressure to the liquid pool through the outflowing functional liquid .
前記バッファ室内に前記気体を吹き付けることにより、前記バッファ室を介して前記液溜まりに前記流体圧を加える請求項6記載の積層フィルム製造装置。 A gas supply unit for blowing gas from the outside of the buffer chamber drawing member in the film width direction toward the buffer chamber is provided.
The laminated film manufacturing apparatus according to claim 6, wherein the fluid pressure is applied to the liquid pool through the buffer chamber by blowing the gas into the buffer chamber.
前記バッファ室内に、前記加圧室から供給された前記気体による圧力が加えられることにより、前記バッファ室を介して前記液溜まりに前記流体圧を加える請求項6記載の積層フィルム製造装置。 A pressurizing chamber defining member for defining a pressurizing chamber adjacent to the outside in the film width direction of the buffer chamber, and a gas supply unit for supplying gas to the pressurizing chamber are provided.
The laminated film manufacturing apparatus according to claim 6, wherein the fluid pressure is applied to the liquid pool through the buffer chamber by applying a pressure from the gas supplied from the pressurizing chamber into the buffer chamber.
搬送されているフィルムの一面に接触させて設けられる機能液の液溜まりと、
前記液溜まりのフィルム幅方向の両端位置を規定するシール部材と、
該シール部材の前記フィルム幅方向の外側から前記液溜まりに流体圧を加える圧力付与機構とを備え、
前記圧力付与機構が、前記シール部材の前記フィルム幅方向の外側に隣接するバッファ室を画成するバッファ室画成部材と、前記バッファ室内に向けて、前記バッファ室画成部材の前記フィルム幅方向の外側から気体を吹き付ける気体供給部とを備え、
前記バッファ室内に前記気体を吹き付けることにより、前記バッファ室を介して前記液溜まりに前記流体圧を加える積層フィルム製造装置。 A transport mechanism that transports the film and
A pool of functional liquid that is provided in contact with one side of the film being conveyed,
A seal member that defines the positions of both ends of the liquid pool in the film width direction,
A pressure applying mechanism for applying a fluid pressure to the liquid pool from the outside of the sealing member in the film width direction is provided.
The pressure applying mechanism defines a buffer chamber defining a buffer chamber adjacent to the outside in the film width direction of the sealing member, and a film width direction of the buffer chamber defining member toward the buffer chamber. Equipped with a gas supply unit that blows gas from the outside of the
Wherein by blowing the gas into the buffer chamber, the fluid pressure was added Ru product layer film manufacturing apparatus to reservoir the liquid through the buffer chamber.
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PCT/JP2018/004945 WO2018179932A1 (en) | 2017-03-28 | 2018-02-13 | Method for manufacturing laminated film and device for manufacturing laminated film |
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