JP6742922B2 - ジフェニルメタン系ジアミンおよびポリアミンの製造方法 - Google Patents

ジフェニルメタン系ジアミンおよびポリアミンの製造方法 Download PDF

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JP6742922B2
JP6742922B2 JP2016575013A JP2016575013A JP6742922B2 JP 6742922 B2 JP6742922 B2 JP 6742922B2 JP 2016575013 A JP2016575013 A JP 2016575013A JP 2016575013 A JP2016575013 A JP 2016575013A JP 6742922 B2 JP6742922 B2 JP 6742922B2
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reactor
aniline
plant
aminal
formaldehyde
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JP2017520559A (ja
JP2017520559A5 (enExample
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トーマス、クナーフ
シュテファン、ベルスホーフェン
クラウス−ゲルト、グリュナー
フォルカー、ハルティエス
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Covestro Deutschland AG
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/78—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton from carbonyl compounds, e.g. from formaldehyde, and amines having amino groups bound to carbon atoms of six-membered aromatic rings, with formation of methylene-diarylamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02—Separation of non-miscible liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/12—Molecular distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/02—Treatment of water, waste water, or sewage by heating
    • C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82—Purification; Separation; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82—Purification; Separation; Stabilisation; Use of additives
    • C07C209/84—Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82—Purification; Separation; Stabilisation; Use of additives
    • C07C209/86—Separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00222—Control algorithm taking actions
    • B01J2219/00225—Control algorithm taking actions stopping the system or generating an alarm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277—Apparatus
    • B01J2219/00452—Means for the recovery of reactants or products
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/38—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2016575013A 2014-06-24 2015-06-22 ジフェニルメタン系ジアミンおよびポリアミンの製造方法 Active JP6742922B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14173580 2014-06-24
EP14173580.3 2014-06-24
PCT/EP2015/063934 WO2015197527A1 (de) 2014-06-24 2015-06-22 Verfahren zur herstellung von di- und polyaminen der diphenylmethanreihe

Publications (3)

Publication Number Publication Date
JP2017520559A JP2017520559A (ja) 2017-07-27
JP2017520559A5 JP2017520559A5 (enExample) 2018-08-02
JP6742922B2 true JP6742922B2 (ja) 2020-08-19

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JP2016575013A Active JP6742922B2 (ja) 2014-06-24 2015-06-22 ジフェニルメタン系ジアミンおよびポリアミンの製造方法

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Country Link
US (1) US10689322B2 (enExample)
EP (1) EP3160934B1 (enExample)
JP (1) JP6742922B2 (enExample)
KR (1) KR20170023987A (enExample)
CN (1) CN106470970B (enExample)
HU (1) HUE058168T2 (enExample)
PT (1) PT3160934T (enExample)
SA (1) SA516380563B1 (enExample)
WO (1) WO2015197527A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110291063B (zh) * 2016-12-22 2022-07-05 科思创德国股份有限公司 在不同的生产能力下制备二苯基甲烷系列的二胺和多胺的方法
US10626078B2 (en) 2016-12-22 2020-04-21 Covestro Deutschland Ag Method of producing diamines and polyamines of the diphenylmethane series at different production capacities
EP3558926B1 (de) 2016-12-22 2021-01-20 Covestro Intellectual Property GmbH & Co. KG Verfahren zur herstellung von di- und polyaminen der diphenylmethanreihe
CN110088078B (zh) * 2016-12-22 2022-09-09 科思创德国股份有限公司 生产二苯基甲烷系列的二胺和多胺的方法
WO2022106685A1 (de) 2020-11-23 2022-05-27 Covestro Deutschland Ag Destillationseinheit und verfahren zur trennung eines flüssigen stoffgemisches in 2 bis 6 flüssige produktströme unterschiedlicher zusammensetzung
US11542223B1 (en) * 2022-07-21 2023-01-03 Covestro Llc Process for preparing di- and polyamines of the diphenyl methane series

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Publication number Priority date Publication date Assignee Title
DE844896C (de) 1944-04-04 1952-09-15 Bayer Ag Verfahren zur Herstellung von organischen Isocyanaten
US3297759A (en) * 1964-01-13 1967-01-10 Upjohn Co Continuous process for producing mixtures of methylene-bridged polyphenyl polyamines
US3517062A (en) * 1966-08-05 1970-06-23 Mobay Chemical Corp Process for the preparation of substantially pure 4,4'-diaminodiphenylmethane
GB1228495A (enExample) * 1968-11-25 1971-04-15 Ici Ltd
US3954867A (en) * 1969-10-20 1976-05-04 Funk Jr Bernard D Continuous process for preparing methylene dianilines
US4290110A (en) * 1979-11-08 1981-09-15 Phillips Petroleum Co. Temperature control for a reactor
US4792624A (en) * 1987-02-26 1988-12-20 The Dow Chemical Company Process for polymeric MDA, recycle of finished polymeric MDA
DE3714606A1 (de) 1987-05-01 1988-11-10 Bayer Ag Verfahren zur herstellung von mehrkernigen aromatischen polyaminen
DE3812083A1 (de) * 1988-04-12 1989-10-26 Bayer Ag Verfahren zur herstellung von mehrkernigen aromatischen polyaminen
JP2825604B2 (ja) 1990-04-11 1998-11-18 三井化学株式会社 メチレン架橋されたポリアリールアミンの製造方法
US5286760A (en) 1992-10-09 1994-02-15 Miles, Inc. Process for reducing impurity levels in methylene diphenyamines
DE19804915A1 (de) 1998-02-07 1999-08-12 Basf Ag Verfahren zur Herstellung von Methylendi(phenylamin) und Methylendi(phenylisocyanat)
DE19817691A1 (de) 1998-04-21 1999-10-28 Basf Ag Verfahren zur Herstellung von Mischungen aus Diphenylmehandiisocyanaten und Polyphenylen-polymethylen-polyisocyanaten mit vermindertem Gehalt an chlorierten Nebenprodukten und verminderter Jodfarbzahl
DE10006452A1 (de) 2000-02-14 2001-08-16 Bayer Ag Verfahren zur Herstellung von Diaminodiphenylmethanen
DE10031540A1 (de) * 2000-06-28 2002-01-10 Basf Ag Verfahren zur Herstellung eines aromatischen Polyamingemisches
DE102004032416A1 (de) 2004-07-05 2006-02-02 Bayer Materialscience Ag Verfahren zur Herstellung von Polyaminen der Diphenylmethanreihe bei niedriger Protonierung
DE102004052370A1 (de) 2004-10-28 2006-05-04 Bayer Materialscience Ag Verfahren zur Herstellung von Di- und Polyaminen der Diphenylmethanreihe
US7414149B2 (en) * 2004-11-22 2008-08-19 Rohm And Haas Company Non-routine reactor shutdown method
DE102006004047A1 (de) 2006-01-28 2007-08-02 Bayer Materialscience Ag Verfahren zur Herstellung von Di- und Polyaminen der Diphenylmethanreihe
DE102006004041A1 (de) 2006-01-28 2007-08-02 Bayer Materialscience Ag Verfahren zur Herstellung von Di- und Polyaminen der Diphenylmethanreihe
EP2039676A1 (en) * 2007-09-19 2009-03-25 Huntsman International Llc Process for the production of di-and polyamines of the diphenylmethane series
DE102008015123A1 (de) 2008-03-20 2009-09-24 Bayer Materialscience Ag Verfahren zur Herstellung von Di- und Polyaminen der Diphenylmethanreihe
WO2012088671A1 (zh) * 2010-12-29 2012-07-05 烟台万华聚氨酯股份有限公司 一种快速混合反应器及其应用

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Publication number Publication date
EP3160934B1 (de) 2022-01-26
US20170137367A1 (en) 2017-05-18
EP3160934A1 (de) 2017-05-03
HUE058168T2 (hu) 2022-07-28
CN106470970A (zh) 2017-03-01
SA516380563B1 (ar) 2021-03-04
JP2017520559A (ja) 2017-07-27
WO2015197527A1 (de) 2015-12-30
US10689322B2 (en) 2020-06-23
CN106470970B (zh) 2019-11-12
PT3160934T (pt) 2022-04-20
KR20170023987A (ko) 2017-03-06

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