CN106470970B - 用于制备二苯基甲烷系列的二胺和多胺的方法 - Google Patents

用于制备二苯基甲烷系列的二胺和多胺的方法 Download PDF

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CN106470970B
CN106470970B CN201580034183.1A CN201580034183A CN106470970B CN 106470970 B CN106470970 B CN 106470970B CN 201580034183 A CN201580034183 A CN 201580034183A CN 106470970 B CN106470970 B CN 106470970B
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reactor
aniline
plant
aminal
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CN106470970A (zh
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T.克瑙夫
S.韦尔肖芬
K-G.格鲁纳
V.哈特耶斯
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Covestro Deutschland AG
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/78—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton from carbonyl compounds, e.g. from formaldehyde, and amines having amino groups bound to carbon atoms of six-membered aromatic rings, with formation of methylene-diarylamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02—Separation of non-miscible liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/12—Molecular distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/02—Treatment of water, waste water, or sewage by heating
    • C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82—Purification; Separation; Stabilisation; Use of additives
    • C07C209/86—Separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/49—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton
    • C07C211/50—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring having at least two amino groups bound to the carbon skeleton with at least two amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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    • B01J2219/00004—Scale aspects
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    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00191—Control algorithm
    • B01J2219/00222—Control algorithm taking actions
    • B01J2219/00225—Control algorithm taking actions stopping the system or generating an alarm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
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    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201580034183.1A 2014-06-24 2015-06-22 用于制备二苯基甲烷系列的二胺和多胺的方法 Active CN106470970B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14173580.3 2014-06-24
EP14173580 2014-06-24
PCT/EP2015/063934 WO2015197527A1 (de) 2014-06-24 2015-06-22 Verfahren zur herstellung von di- und polyaminen der diphenylmethanreihe

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CN106470970A CN106470970A (zh) 2017-03-01
CN106470970B true CN106470970B (zh) 2019-11-12

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US (1) US10689322B2 (enExample)
EP (1) EP3160934B1 (enExample)
JP (1) JP6742922B2 (enExample)
KR (1) KR20170023987A (enExample)
CN (1) CN106470970B (enExample)
HU (1) HUE058168T2 (enExample)
PT (1) PT3160934T (enExample)
SA (1) SA516380563B1 (enExample)
WO (1) WO2015197527A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018114771A1 (de) 2016-12-22 2018-06-28 Covestro Deutschland Ag Verfahren zur herstellung von di- und polyaminen der diphenylmethanreihe
EP3558926B1 (de) 2016-12-22 2021-01-20 Covestro Intellectual Property GmbH & Co. KG Verfahren zur herstellung von di- und polyaminen der diphenylmethanreihe
WO2018114767A1 (de) 2016-12-22 2018-06-28 Covestro Deutschland Ag Verfahren zur herstellung von di- und polyaminen der diphenylmethanreihe bei unterschiedlichen produktionskapazitäten
CN110072840B (zh) * 2016-12-22 2022-09-09 科思创德国股份有限公司 在不同生产能力下生产二苯基甲烷系列的二胺和多胺的方法
WO2022106685A1 (de) 2020-11-23 2022-05-27 Covestro Deutschland Ag Destillationseinheit und verfahren zur trennung eines flüssigen stoffgemisches in 2 bis 6 flüssige produktströme unterschiedlicher zusammensetzung
US11542223B1 (en) * 2022-07-21 2023-01-03 Covestro Llc Process for preparing di- and polyamines of the diphenyl methane series
CN120965498B (zh) * 2025-03-31 2026-07-31 浙江新和成股份有限公司 Mda的制备方法和制备装置、mdi的制备方法和制备装置
CN121288744B (zh) * 2025-12-11 2026-06-16 山东华鲁恒升化工股份有限公司 一种集成反应器及制备二苯基甲烷系列胺的反应系统

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EP0283757A1 (en) * 1987-02-26 1988-09-28 The Dow Chemical Company Am improved process for polymeric MDA, recycle of finished polymeric MDA
US4914236A (en) * 1987-05-01 1990-04-03 Bayer Aktiengesellschaft Process for the preparation of multinuclear aromatic polyamines
US4924028A (en) * 1988-04-12 1990-05-08 Bayer Aktiengesellschaft Process for the production of polynuclear aromatic polyamines
CN1721389A (zh) * 2004-07-05 2006-01-18 拜尔材料科学股份公司 在低质子化程度下制备二苯基甲烷系列多胺的方法
CN101801910A (zh) * 2007-09-19 2010-08-11 亨茨曼国际有限公司 用于生产二苯基甲烷系列的二-和多胺的工艺
WO2012088671A1 (zh) * 2010-12-29 2012-07-05 烟台万华聚氨酯股份有限公司 一种快速混合反应器及其应用

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Publication number Priority date Publication date Assignee Title
EP0283757A1 (en) * 1987-02-26 1988-09-28 The Dow Chemical Company Am improved process for polymeric MDA, recycle of finished polymeric MDA
US4914236A (en) * 1987-05-01 1990-04-03 Bayer Aktiengesellschaft Process for the preparation of multinuclear aromatic polyamines
US4924028A (en) * 1988-04-12 1990-05-08 Bayer Aktiengesellschaft Process for the production of polynuclear aromatic polyamines
CN1721389A (zh) * 2004-07-05 2006-01-18 拜尔材料科学股份公司 在低质子化程度下制备二苯基甲烷系列多胺的方法
CN101801910A (zh) * 2007-09-19 2010-08-11 亨茨曼国际有限公司 用于生产二苯基甲烷系列的二-和多胺的工艺
WO2012088671A1 (zh) * 2010-12-29 2012-07-05 烟台万华聚氨酯股份有限公司 一种快速混合反应器及其应用

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SA516380563B1 (ar) 2021-03-04
PT3160934T (pt) 2022-04-20
WO2015197527A1 (de) 2015-12-30
KR20170023987A (ko) 2017-03-06
HUE058168T2 (hu) 2022-07-28
JP2017520559A (ja) 2017-07-27
US20170137367A1 (en) 2017-05-18
EP3160934B1 (de) 2022-01-26
EP3160934A1 (de) 2017-05-03
CN106470970A (zh) 2017-03-01
JP6742922B2 (ja) 2020-08-19
US10689322B2 (en) 2020-06-23

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