JP6713087B2 - Resin film forming method and resin film forming apparatus - Google Patents

Resin film forming method and resin film forming apparatus Download PDF

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JP6713087B2
JP6713087B2 JP2019501331A JP2019501331A JP6713087B2 JP 6713087 B2 JP6713087 B2 JP 6713087B2 JP 2019501331 A JP2019501331 A JP 2019501331A JP 2019501331 A JP2019501331 A JP 2019501331A JP 6713087 B2 JP6713087 B2 JP 6713087B2
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film
substrate
mask
resin
resin material
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JPWO2018155421A1 (en
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信 青代
信 青代
健介 清
健介 清
高橋 明久
明久 高橋
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Ulvac Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/16Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/10Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C9/00Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
    • B05C9/08Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation
    • B05C9/12Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying liquid or other fluent material and performing an auxiliary operation the auxiliary operation being performed after the application
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    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
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    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
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    • C23C14/042Coating on selected surface areas, e.g. using masks using masks
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    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
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    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
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    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
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    • C23C14/5806Thermal treatment
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    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58After-treatment
    • C23C14/5873Removal of material
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00Electroluminescent light sources
    • H05B33/02Details
    • H05B33/04Sealing arrangements, e.g. against humidity
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    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12Chemical modification
    • C08J7/123Treatment by wave energy or particle radiation

Description

本発明は、減圧雰囲気において、マスク上に形成された樹脂材料膜を容易に除去できる、樹脂膜の形成方法および樹脂膜の成膜装置に関する。
本願は、2017年2月21日に日本に出願された特願2017−030321号に基づき優先権を主張し、その内容をここに援用する。
The present invention relates to a resin film forming method and a resin film forming apparatus capable of easily removing a resin material film formed on a mask in a reduced pressure atmosphere.
The present application claims priority based on Japanese Patent Application No. 2017-030321 filed in Japan on February 21, 2017, the contents of which are incorporated herein by reference.

高分子有機物からなる樹脂膜の製法としては、蒸着重合法や紫外線硬化法が広く用いられている。この2つの製法は何れも、減圧された処理槽内に低分子の有機物ガスを導入し、被処理体上に供給された樹脂材料が重合反応を起し、高分子の樹脂膜を被処理体の表面上に形成する方法であり、被処理体の表面に対する樹脂膜のカバレッジ(被覆率)が良いという特長がある。特許文献1には、これに適した成膜装置が開示されている。 A vapor deposition polymerization method and an ultraviolet curing method are widely used as a method for producing a resin film made of a high molecular organic material. In both of these two manufacturing methods, a low-molecular organic gas is introduced into a depressurized processing tank, the resin material supplied onto the object to be processed undergoes a polymerization reaction, and a polymer resin film is applied to the object to be processed. It is a method of forming on the surface of, and has a feature that the coverage (coverage) of the resin film on the surface of the object to be processed is good. Patent Document 1 discloses a film forming apparatus suitable for this.

図7は、従来の樹脂膜の形成方法を示すフローチャートであり、メタルマスクMYを用いて樹脂膜の代表例としてアクリル樹脂膜Fを形成する場合を示す。
まず、基板Sに対して無機保護膜形成などの前処理を施した後、成膜室内へ基板Sを移動する(SY1、SY2)。
FIG. 7 is a flowchart showing a conventional method of forming a resin film, showing a case where an acrylic resin film F is formed as a representative example of the resin film using the metal mask MY.
First, after performing a pretreatment such as forming an inorganic protective film on the substrate S, the substrate S is moved into the film forming chamber (SY1, SY2).

成膜室内(減圧雰囲気)において、図8〜図11に示すように、所望の開口部を設けたメタルマスクMYを基板Sの被成膜面上に配置する(SY3)。これにより、開口部の位置にある基板Sの被成膜面は、図8に示すように、露呈された状態となる。
次に、図9に示すように、メタルマスクMYを介して、樹脂材料膜の代表例としてアクリル材料膜fを基板Sの上に形成する(SY4)。アクリル材料膜fは、基板Sを被覆する部位f1と、メタルマスクMYを被覆する部位f2と、から構成される。
In the film formation chamber (reduced pressure atmosphere), as shown in FIGS. 8 to 11, a metal mask MY having a desired opening is arranged on the film formation surface of the substrate S (SY3). As a result, the film formation surface of the substrate S at the position of the opening is exposed as shown in FIG.
Next, as shown in FIG. 9, an acrylic material film f as a representative example of the resin material film is formed on the substrate S through the metal mask MY (SY4). The acrylic material film f is composed of a portion f1 that covers the substrate S and a portion f2 that covers the metal mask MY.

次いで、図10に示すように、アクリル材料膜fに紫外線(UV)を照射して、アクリル材料膜fを硬化してアクリル樹脂膜Fを形成する(SY5)。その後、図11に示すように、メタルマスクMYを矢印の方向へ移動させることにより、メタルマスクMYを基板Sから剥離する(SY6)。メタルマスクMYは、一回の成膜後、もしくは、基板を入れ替えて複数回使用された(複数回の成膜が行われた)後、クリーニングされて、再使用される。 Next, as shown in FIG. 10, the acrylic material film f is irradiated with ultraviolet rays (UV) to cure the acrylic material film f to form an acrylic resin film F (SY5). Then, as shown in FIG. 11, by moving the metal mask MY in the direction of the arrow, the metal mask MY is separated from the substrate S (SY6). The metal mask MY is cleaned and reused after one-time film formation or after being used a plurality of times by exchanging substrates (a plurality of film formations have been performed).

従来、メタルマスクMY上に堆積されたアクリル樹脂膜Fの除去は、アクリル樹脂膜の成膜装置の内部から外部へメタルマスクMYを取り外して、ウェットエッチング処理を行う方法により行われていた。したがって、減圧雰囲気にある成膜装置の内部において、マスク上に形成されたアクリル樹脂膜を容易に除去できる、アクリル樹脂膜の形成方法およびアクリル樹脂膜の成膜装置の開発が期待されていた。 Conventionally, the removal of the acrylic resin film F deposited on the metal mask MY has been performed by a method of removing the metal mask MY from the inside of the acrylic resin film forming apparatus to the outside and performing a wet etching process. Therefore, it has been expected to develop an acrylic resin film forming method and an acrylic resin film forming apparatus capable of easily removing the acrylic resin film formed on the mask inside the film forming apparatus in a reduced pressure atmosphere.

日本国特許第4112702号公報Japanese Patent No. 4112702

本発明は、上述した事情に鑑みてなされたもので、メタルマスクに樹脂膜が形成されず、メタルマスクを成膜装置から取り出してクリーニングせずに繰り返し使用できる、樹脂膜の形成方法および樹脂膜の成膜装置を提供することを目的とする。減圧雰囲気にある成膜装置の内部において、マスク上に樹脂膜が形成されない樹脂膜の形成方法および樹脂膜の成膜装置を提供することを目的とする。 The present invention has been made in view of the above-mentioned circumstances, and a resin film forming method and a resin film in which a resin film is not formed on a metal mask and the metal mask can be repeatedly used without taking out from the film forming apparatus and cleaning. It is an object of the present invention to provide a film forming apparatus of the above. An object of the present invention is to provide a resin film forming method and a resin film forming apparatus in which a resin film is not formed on a mask inside a film forming apparatus in a reduced pressure atmosphere.

本発明の第1態様に係る樹脂膜の形成方法は、マスク本体が金属材料からなり所定の開口部を備えたマスクを用い、減圧雰囲気において、基板上に樹脂膜を形成する方法であって、減圧雰囲気において、冷却された支持台に載置された前記基板(被成膜面)と接するように前記マスクを設けて、該マスクを介して気化した樹脂材料を供給し該基板上で凝縮させ、該基板上に液体の樹脂材料膜を形成する第1工程(工程α)と、前記基板から前記マスクを剥離する第2工程(工程β)と、前記マスク上の樹脂材料膜を熱処理し、該樹脂材料膜を蒸発する第3工程(工程γ)と、前記基板上に残存した樹脂材料膜にUV光を照射し、該樹脂材料膜を硬化して樹脂膜を形成する第4工程(工程δ)と、を順に備える。
本発明の第1態様に係る樹脂膜の形成方法においては、前記第3工程における熱処理は、加熱装置を用いた前記マスクに対する加熱昇温であってもよい。
本発明の第1態様に係る樹脂膜の形成方法においては、前記第3工程における熱処理は、前記マスクが前記支持台から離れたことによる自然昇温によって行われてもよい。
本発明の第1態様に係る樹脂膜の形成方法においては、前記第3工程における熱処理においては、前記マスクが前記支持台から離され、加熱されたチャンバもしくはシャワープレートからの輻射熱により加熱されてもよい。
A method of forming a resin film according to a first aspect of the present invention is a method of forming a resin film on a substrate in a reduced pressure atmosphere using a mask whose mask body is made of a metal material and has a predetermined opening. In a depressurized atmosphere, the mask is provided so as to come into contact with the substrate (deposition surface) placed on a cooled support, and the vaporized resin material is supplied through the mask and condensed on the substrate. A first step (step α) of forming a liquid resin material film on the substrate, a second step (step β) of peeling the mask from the substrate, and a heat treatment of the resin material film on the mask, A third step (step γ) of evaporating the resin material film, and a fourth step (step of irradiating the resin material film remaining on the substrate with UV light to cure the resin material film to form a resin film) δ) and are provided in order.
In the method for forming a resin film according to the first aspect of the present invention, the heat treatment in the third step may be heating and temperature rise for the mask using a heating device.
In the method for forming a resin film according to the first aspect of the present invention, the heat treatment in the third step may be performed by a natural temperature rise due to the mask being separated from the support table.
In the resin film forming method according to the first aspect of the present invention, in the heat treatment in the third step, the mask may be separated from the support table and heated by radiant heat from a heated chamber or shower plate. Good.

本発明の第2態様に係る樹脂膜の成膜装置は、マスク本体が金属材料からなり所定の開口部を備えたマスクを用い、減圧雰囲気において、基板上に樹脂膜を形成する装置であって、樹脂膜の材料である気化した樹脂材料を基板上に供給し、凝縮させて樹脂材料膜を形成する時に、前記基板を零度以下の温度帯域に保つ温度制御装置を内蔵する該基板の支持部と、前記樹脂材料膜に対してUV光を照射する前に、前記支持部に載置された状態にある該基板から前記マスクを剥離して、該マスク上の樹脂材料膜を熱処理する機構と、前記樹脂材料膜にUV光を照射して硬化させ、樹脂膜を形成するUV照射装置と、を備える。
本発明の第2態様に係る樹脂膜の成膜装置においては、前記樹脂材料膜を熱処理する機構が、前記マスクの温度増加を促す加熱装置であってもよい。
本発明の第2態様に係る樹脂膜の成膜装置においては、前記樹脂材料膜を熱処理する機構が、前記マスクを支持台から離間させる移動装置であってもよい。
本発明の第2態様に係る樹脂膜の成膜装置においては、前記樹脂材料膜を熱処理する機構が、前記基板を収容するチャンバの加熱装置であってもよい。
A film forming apparatus for a resin film according to a second aspect of the present invention is an apparatus for forming a resin film on a substrate in a depressurized atmosphere using a mask whose main body is made of a metal material and has a predetermined opening. A support portion for the substrate, which has a temperature control device for keeping the substrate in a temperature range of zero degrees or less when the vaporized resin material that is the material of the resin film is supplied onto the substrate and condensed to form the resin material film. And a mechanism for, before irradiating the resin material film with UV light, peeling the mask from the substrate placed on the supporting portion and heat treating the resin material film on the mask. And a UV irradiation device that forms a resin film by irradiating the resin material film with UV light to cure the resin material film.
In the resin film forming apparatus according to the second aspect of the present invention, the mechanism for heat-treating the resin material film may be a heating device for promoting the temperature increase of the mask.
In the resin film forming apparatus according to the second aspect of the present invention, the mechanism for heat-treating the resin material film may be a moving device that separates the mask from the support base.
In the resin film forming apparatus according to the second aspect of the present invention, the mechanism for heat-treating the resin material film may be a heating device for a chamber that houses the substrate.

本発明の態様に係る樹脂膜の形成方法は、第3工程において、基板上に形成した樹脂材料膜にUV光を照射する前に、零度以下の温度帯域にある支持台に載置された状態にある該基板から前記マスクを剥離して、該マスク上の樹脂材料膜を熱処理し、該樹脂材料膜を蒸発する。これにより、減圧雰囲気にある成膜室内にて、樹脂材料膜を形成する毎に、マスク上を覆う樹脂材料膜は全てマスクから除去される。このため、その後、UV照射してもマスク上には樹脂膜は形成されない。ゆえに、樹脂膜を除去するために、従来は必須であったクリーニング作業、すなわち、樹脂膜の成膜装置の内部から外部へマスクを取り外して、ウェットエッチング処理などを行う作業は、本発明の態様によれば基本的に不要となる。
ゆえに、本発明の態様は、マスクを用いた樹脂膜の形成において、低コスト化および作業の簡単化を図ることが可能な、樹脂膜の形成方法をもたらす。
In the method of forming a resin film according to the aspect of the present invention, in the third step, before the resin material film formed on the substrate is irradiated with UV light, the resin material film is placed on a support table in a temperature range of zero degrees or less. The mask is peeled off from the substrate at, the resin material film on the mask is heat-treated, and the resin material film is evaporated. As a result, every time the resin material film is formed in the deposition chamber in the reduced pressure atmosphere, the resin material film covering the mask is completely removed from the mask. Therefore, even if UV irradiation is performed thereafter, the resin film is not formed on the mask. Therefore, in order to remove the resin film, the cleaning operation that has been indispensable in the past, that is, the operation of removing the mask from the inside of the film forming apparatus for the resin film to the outside and performing the wet etching process, etc. is an aspect of the present invention. According to, it is basically unnecessary.
Therefore, the aspect of the present invention provides a method for forming a resin film that can reduce the cost and simplify the work in forming the resin film using a mask.

本発明の態様に係る樹脂膜の成膜装置は、減圧雰囲気において、樹脂材料膜の形成時に、前記基板を零度以下の温度帯域に保つ温度制御装置を内蔵する該基板の支持部と、前記樹脂材料膜に対してUV光を照射する前に、前記支持部に載置された状態にある該基板から前記マスクを剥離して、該マスク上の樹脂材料膜を熱処理する機構と、を備えている。これにより、減圧雰囲気にある成膜室内にて、樹脂材料膜を形成する毎に、マスク上を覆う樹脂材料膜はマスクから除去できる。ゆえに、本発明によれば、樹脂膜の成膜装置の内部から外部へマスクを取り外して、ウェットエッチング処理などを行う作業が基本的に不要となる。
また、本発明の成膜装置では、樹脂膜を形成する一連の作業の中で毎回、マスクから樹脂材料膜が除去されるので、次に樹脂膜を形成する際には、クリーンな状態のマスクを利用できる。
ゆえに、本発明の態様に係る樹脂膜の成膜装置は、マスクを用いた樹脂膜の形成において、低コスト化および作業の簡単化を図ることが可能な、樹脂膜の成膜装置をもたらす。
A film forming apparatus for a resin film according to an aspect of the present invention, in a reduced pressure atmosphere, when a resin material film is formed, a support unit for the substrate, which incorporates a temperature control device for maintaining the substrate in a temperature range of zero degrees or less, and the resin. A mechanism for, before irradiating the material film with UV light, peeling the mask from the substrate placed on the supporting portion and heat-treating the resin material film on the mask. There is. Thus, the resin material film covering the mask can be removed from the mask each time the resin material film is formed in the film forming chamber in the reduced pressure atmosphere. Therefore, according to the present invention, the work of removing the mask from the inside of the film forming apparatus for the resin film to the outside and performing wet etching is basically unnecessary.
Further, in the film forming apparatus of the present invention, since the resin material film is removed from the mask every time during the series of operations for forming the resin film, when the resin film is formed next time, the mask in a clean state is used. Is available.
Therefore, the resin film forming apparatus according to the aspect of the present invention provides a resin film forming apparatus capable of reducing cost and simplifying work in forming a resin film using a mask.

このような樹脂膜の用途としては、例えば、有機ELディスプレイやフレキシブルディスプレイの封止膜に好適に用いられる。 As the application of such a resin film, for example, it is suitably used as a sealing film for an organic EL display or a flexible display.

本発明の実施形態に係るアクリル樹脂膜の形成方法を示すフローチャートである。6 is a flowchart showing a method for forming an acrylic resin film according to an embodiment of the present invention. 図1において、マスクを基板に配置した状態を示す断面図である。It is sectional drawing which shows the state which has arrange|positioned the mask on the board|substrate in FIG. マスクを介し基板にアクリル材料膜を形成した状態を示す断面図である。It is sectional drawing which shows the state which formed the acrylic material film on the board|substrate through the mask. UV照射前に、基板からマスクを剥離した状態を示す断面図である。It is sectional drawing which shows the state which peeled the mask from the board|substrate before UV irradiation. マスク上のアクリル材料膜を熱処理し、蒸発した状態を示す断面図である。It is sectional drawing which shows the state which heat-processed the acrylic material film on a mask, and was evaporated. 基板上のアクリル材料膜にUV照射し、硬化した状態を示す断面図である。It is sectional drawing which shows the state which UV-irradiated the acrylic material film|membrane on a board|substrate, and hardened. 基板上のアクリル材料膜にUV照射し、硬化した状態を示す断面図である。It is sectional drawing which shows the state which UV-irradiated the acrylic material film|membrane on a board|substrate, and hardened. 従来のアクリル樹脂膜の形成方法を示すフローチャートである。It is a flowchart which shows the formation method of the conventional acrylic resin film. 図7において、マスクを基板に配置する前の断面図である。FIG. 8 is a cross-sectional view before placing the mask on the substrate in FIG. 7. マスクを介し基板にアクリル材料膜を形成した状態を示す断面図である。It is sectional drawing which shows the state which formed the acrylic material film on the board|substrate through the mask. アクリル材料膜にUV照射し、硬化した状態を示す断面図である。FIG. 3 is a cross-sectional view showing a state where the acrylic material film is irradiated with UV and cured. UV照射後、基板からマスクを剥離した状態を示す断面図である。It is sectional drawing which shows the state which peeled the mask from the board|substrate after UV irradiation. 本発明の実施形態に係るアクリル樹脂膜の成膜装置の一例を示す模式図である。It is a schematic diagram which shows an example of the film-forming apparatus of the acrylic resin film which concerns on embodiment of this invention.

以下、本発明の一実施形態に係る樹脂膜の形成方法と、この樹脂膜の形成において有効な構成を備えたマスクを、図面に基づいて説明する。樹脂膜の一例として、アクリル樹脂を例示する。 Hereinafter, a method for forming a resin film according to an embodiment of the present invention and a mask having a configuration effective in forming the resin film will be described with reference to the drawings. An acrylic resin is illustrated as an example of the resin film.

<アクリル樹脂膜の形成方法>
図1は、本発明の一実施形態に係るアクリル樹脂膜の作製工程を示すフローチャートであり、アクリル樹脂膜の形成方法は、工程SB1〜工程SB8の8つの工程から構成される。
工程SB1〜工程SB2は基板の前処理と基板移動に関する作業である。工程SB3〜工程SB7は、アクリル材料膜を形成する前にメタルマスクを基板に配置、アクリル材料膜の形成、メタルマスクを基板から剥離、メタルマスクのみ加熱(メタルマスク上のアクリル材料を蒸発)、基板上のアクリル材料膜にUV照射してアクリル樹脂膜の形成、の各作業であり、成膜室内(減圧雰囲気)において行われる。工程SB8は成膜室外へ基板移動である。
<Method of forming acrylic resin film>
FIG. 1 is a flow chart showing a process for producing an acrylic resin film according to an embodiment of the present invention, and a method for forming an acrylic resin film includes eight steps SB1 to SB8.
Steps SB1 to SB2 are operations related to pretreatment of the substrate and movement of the substrate. In steps SB3 to SB7, a metal mask is placed on the substrate before the acrylic material film is formed, the acrylic material film is formed, the metal mask is peeled from the substrate, only the metal mask is heated (evaporation of the acrylic material on the metal mask), These are the respective operations of irradiating the acrylic material film on the substrate with UV to form an acrylic resin film, and are performed in a film forming chamber (reduced pressure atmosphere). Step SB8 is to move the substrate to the outside of the film forming chamber.

ゆえに、本発明の実施形態によれば、従来の製法においては必須であった、アクリル樹脂膜の成膜装置の内部から外部へマスクを取り外して、マスクに付着したアクリル樹脂を除去するためのウェットエッチング処理などを行う作業が不要となる。このため、マスクを用いたアクリル樹脂膜の形成において、低コスト化および作業の簡単化を図ることが可能となる。 Therefore, according to the embodiment of the present invention, the wet process for removing the acrylic resin adhering to the mask by removing the mask from the inside to the outside of the acrylic resin film forming apparatus, which is essential in the conventional manufacturing method. It is not necessary to perform an etching process or the like. Therefore, in the formation of the acrylic resin film using the mask, the cost can be reduced and the work can be simplified.

以下では、図1のフローチャートに示した各工程(工程SB1〜工程SB8)について、図2〜図6Bを用いて詳細に説明する。
図2は、本発明の実施形態において用いるメタルマスクMBを基板Sに配置した状態を示す断面図である。図3は、メタルマスクMBを介し基板Sにアクリル材料膜fを形成した状態を示す断面図である。図4は、アクリル材料膜fを形成した後、UV照射前に、基板SからメタルマスクMBを剥離した状態を示す断面図である。図5は、マスクMB上のアクリル材料膜f2を蒸発させた後、基板S上のアクリル材料膜f1にUV照射し、アクリル材料膜f1を硬化しアクリル樹脂膜F1を形成した状態を示す断面図である。
Hereinafter, each step (step SB1 to step SB8) shown in the flowchart of FIG. 1 will be described in detail with reference to FIGS. 2 to 6B.
FIG. 2 is a sectional view showing a state in which the metal mask MB used in the embodiment of the present invention is arranged on the substrate S. FIG. 3 is a cross-sectional view showing a state in which the acrylic material film f is formed on the substrate S via the metal mask MB. FIG. 4 is a cross-sectional view showing a state where the metal mask MB is peeled from the substrate S after the acrylic material film f is formed and before UV irradiation. FIG. 5 is a cross-sectional view showing a state in which after the acrylic material film f2 on the mask MB is evaporated, the acrylic material film f1 on the substrate S is irradiated with UV to cure the acrylic material film f1 and form the acrylic resin film F1. Is.

メタルマスクMBのマスク本体は、例えば、インバー材やステンレススティール等の金属材料から構成される。マスク本体に設けた所定の開口部Wを通して基板Sに気化したアクリル材料を供給し、基板S上で凝縮させることにより、基板S上にアクリル材料膜fを形成するために用いられる。これにより、マスクMBの場合は基本的に、成膜時にマスク本体が存在した領域には基板S上にアクリル樹脂膜は形成されず、開口部Wが存在した領域には基板S上にアクリル樹脂膜は形成される。 The mask body of the metal mask MB is made of, for example, a metal material such as Invar material or stainless steel. It is used to form an acrylic material film f on the substrate S by supplying the vaporized acrylic material to the substrate S through a predetermined opening W provided in the mask body and condensing it on the substrate S. Accordingly, in the case of the mask MB, basically, the acrylic resin film is not formed on the substrate S in the region where the mask body was present at the time of film formation, and the acrylic resin film was formed on the substrate S in the region where the opening W was present. The film is formed.

基板Sは、発光素子などが形成され、無機材料などの保護膜が形成される。この一連の作業が基板の前処理(工程SB1)である。次に、前処理を終えた基板を、メタルマスクMBが予め配置された成膜室内へ移動する(工程SB2)。 On the substrate S, a light emitting element and the like are formed, and a protective film such as an inorganic material is formed. This series of operations is a substrate pretreatment (step SB1). Next, the substrate which has undergone the pretreatment is moved into the film forming chamber in which the metal mask MB is previously arranged (step SB2).

基板が移動した成膜室内は、真空排気装置により減圧雰囲気にされている。この減圧雰囲気において、基板Sは樹脂材料の凝縮温度以下、例えば、零度以下の温度帯域にある支持台に載置された後、前記基板の被成膜面と接するようにメタルマスクMBを配置する(工程SB3)。このメタルマスクMBを介して気化したアクリル材料を供給し、基板S上で凝縮させ、該基板S上にアクリル材料膜fを形成する(工程SB4)。工程SB3と工程SB4が工程αであり、成膜室内(減圧雰囲気)にて行われる。ここで、零度以下の温度帯域とは、使用されるアクリル材料の気化温度によって決まる数値である。好ましくは零度(0℃)以下であり、例えば、−30℃〜0℃程度の範囲である。 The film forming chamber in which the substrate has moved is evacuated by a vacuum exhaust device. In this depressurized atmosphere, the substrate S is placed on a support table in a temperature range below the condensation temperature of the resin material, for example, below 0 degree, and then a metal mask MB is arranged so as to come into contact with the film formation surface of the substrate. (Step SB3). The vaporized acrylic material is supplied through the metal mask MB and condensed on the substrate S to form an acrylic material film f on the substrate S (step SB4). Step SB3 and step SB4 are step α and are performed in the film forming chamber (reduced pressure atmosphere). Here, the temperature zone below zero degree is a numerical value determined by the vaporization temperature of the acrylic material used. It is preferably zero degrees (0° C.) or less, for example, in the range of about −30° C. to 0° C.

次に、図4に示すように、アクリル材料膜fにUV光を照射することなく、アクリル材料膜fの形成を終えたメタルマスクMBを、基板Sから矢印の方向に剥離する(工程SB5)。このとき、メタルマスクMBは、その上面を覆うようにアクリル材料膜f2が付着した状態にある。UV光を照射していないので、メタルマスクMBの上面を覆うアクリル材料膜f2は、未硬化の状態にある。これが工程βであり、成膜室内(減圧雰囲気)にて行われる。 Next, as shown in FIG. 4, the metal mask MB on which the acrylic material film f has been formed is peeled from the substrate S in the direction of the arrow without irradiating the acrylic material film f with UV light (step SB5). .. At this time, the metal mask MB is in a state in which the acrylic material film f2 is attached so as to cover the upper surface thereof. Since it is not irradiated with UV light, the acrylic material film f2 covering the upper surface of the metal mask MB is in an uncured state. This is step β, and is performed in the film forming chamber (reduced pressure atmosphere).

次に、図5に示すように、支持台及び支持台に載置された基板は加熱せず、メタルマスクMBのみ加熱する。ここで、「メタルマスクMBのみ加熱」とは、基板や基板を載置する支持台は昇温させず、メタルマスク上のアクリル材料膜f2を昇温させ、該アクリル材料膜f2を蒸発することを意味する(工程γ)。
この加熱は、メタルマスクMB上のアクリル材料膜f2を熱処理する機構により行われる。
本発明の実施形態において、アクリル材料膜f2を熱処理する機構としては、メタルマスクMBの温度増加を促す加熱装置、及び、メタルマスクMBを支持台から離間させる移動装置、の何れか一方、若しくは組み合わせが好適に用いられる。
Next, as shown in FIG. 5, the support and the substrate placed on the support are not heated, but only the metal mask MB is heated. Here, "heating only the metal mask MB" means elevating the acrylic material film f2 on the metal mask and evaporating the acrylic material film f2 without raising the temperature of the substrate or the support on which the substrate is placed. Means (step γ).
This heating is performed by a mechanism for heat-treating the acrylic material film f2 on the metal mask MB.
In the embodiment of the present invention, as a mechanism for heat-treating the acrylic material film f2, one of a heating device that promotes a temperature increase of the metal mask MB and a moving device that separates the metal mask MB from the support base, or a combination thereof. Is preferably used.

前記メタルマスクMBの温度増加(昇温)を促す加熱装置とは、例えば、メタルマスクMBに直接的に接触させるヒータや、メタルマスクMBに間接的に照射するランプなどが挙げられる。加熱装置を用いる場合は、メタルマスクMBを覆うアクリル材料膜f2(f)に対して、単位時間当たりに加える熱量を自在に制御できる利点がある。加熱装置においては、例えば、アクリル材料膜fを構成する物質の蒸発温度に応じた、温度増加プロファイルを採用することにより、メタルマスクMBを覆うアクリル材料膜f2は、液体から気体へ相転移が生じるため、メタルマスクMBからアクリル材料膜f2が除去される。その際、基板S上に残存するアクリル材料膜f1は何ら影響を受けない。メタルマスクMBの温度を上昇させる場合は、基板Sの温度に影響を与えないように、基板Sから離して加熱されることが好ましい。 Examples of the heating device that promotes the temperature increase (temperature increase) of the metal mask MB include a heater that directly contacts the metal mask MB, a lamp that indirectly irradiates the metal mask MB, and the like. When the heating device is used, there is an advantage that the amount of heat applied per unit time to the acrylic material film f2(f) covering the metal mask MB can be freely controlled. In the heating device, for example, the acrylic material film f2 covering the metal mask MB undergoes a phase transition from liquid to gas by adopting a temperature increase profile corresponding to the evaporation temperature of the substance forming the acrylic material film f. Therefore, the acrylic material film f2 is removed from the metal mask MB. At that time, the acrylic material film f1 remaining on the substrate S is not affected at all. When increasing the temperature of the metal mask MB, it is preferable to heat the substrate S away from the substrate S so as not to affect the temperature of the substrate S.

前記メタルマスクMBを支持台から離間させる移動装置とは、減圧雰囲気において稼働できる、昇降ピン、ロボットハンド、吸着装置手段などが挙げられる。本発明の実施形態においては、アクリル材料膜fの形成中にある基板Sは、零度以下の温度帯域にある支持台に載置された状態にあるため、基板S上に形成されたアクリル材料膜fの温度も零度以下の温度帯域に保たれる。アクリル材料膜を構成する物質としては、例えば、零度以上の温度で蒸発する物質を採用する。これにより、メタルマスクMBを支持台から離間させるだけで、メタルマスクMBを覆うアクリル材料膜f2は、液体から気体へ相転移が生じるため、メタルマスクMBからアクリル材料膜f2が除去される。その際、基板S上に残存するアクリル膜F1は何ら影響を受けない。
特に、成膜装置のチャンバや、基板Sに対向して配置されるシャワープレートは、アクリル材料が付着しないように加熱されている。このため、メタルマスクMBは、冷却されている基板Sから離すだけで、周辺のチャンバやシャワープレートからの輻射熱で加熱される。
Examples of the moving device that separates the metal mask MB from the support include a lifting pin, a robot hand, and a suction device means that can operate in a reduced pressure atmosphere. In the embodiment of the present invention, since the substrate S on which the acrylic material film f is being formed is placed on the support table in the temperature range of 0° C. or less, the acrylic material film formed on the substrate S. The temperature of f is also kept in the temperature range of zero degrees or lower. As the substance forming the acrylic material film, for example, a substance that evaporates at a temperature of zero degree or higher is adopted. As a result, the acrylic material film f2 covering the metal mask MB undergoes a phase transition from liquid to gas simply by separating the metal mask MB from the support, so that the acrylic material film f2 is removed from the metal mask MB. At that time, the acrylic film F1 remaining on the substrate S is not affected at all.
In particular, the chamber of the film forming apparatus and the shower plate arranged to face the substrate S are heated so that the acrylic material does not adhere thereto. Therefore, the metal mask MB is heated by the radiant heat from the peripheral chamber and the shower plate only by separating it from the cooled substrate S.

つまり、本発明の実施形態における「アクリル材料膜f2を熱処理する機構」は、アクリル材料膜を構成する物質を蒸発させる機構である。これにより、成膜室内(減圧雰囲気)にて、メタルマスクMBを覆うアクリル材料膜f2を、メタルマスクMBから容易に除去できる。
以上が工程γであり、成膜室内(減圧雰囲気)にて行われる。ゆえに、このアクリル材料膜f2が除去されたメタルマスクMBは、成膜室外に取り出すことなく、次の成膜バッチにおいて新たな基板上に配置し、新たなアクリル膜の形成に供することが可能となる。
That is, the “mechanism for heat-treating the acrylic material film f2” in the embodiment of the present invention is a mechanism for evaporating the substance forming the acrylic material film. Thus, the acrylic material film f2 covering the metal mask MB can be easily removed from the metal mask MB in the film forming chamber (reduced pressure atmosphere).
The above is the process γ, which is performed in the film forming chamber (reduced pressure atmosphere). Therefore, the metal mask MB from which the acrylic material film f2 has been removed can be placed on a new substrate in the next film forming batch without being taken out of the film forming chamber, and can be used for forming a new acrylic film. Become.

次いで、図6Aに示すように、工程δにおいては、基板S上に残存したアクリル材料膜f1(f)にUV光を照射し、該アクリル材料膜f1を硬化してアクリル樹脂膜Fを形成する(工程SB7)。この工程は、成膜室内(減圧雰囲気)にて行われる。その際に、先に基板S上から剥離したメタルマスクMBを覆っていたアクリル材料膜f2は、前述した工程γにおいてメタルマスクMB上から蒸発しており、工程δを行う際には、メタルマスクMB上にはアクリル材料膜f2は存在しない。ゆえに、メタルマスクMB上にアクリル樹脂膜は形成されない。 Next, as shown in FIG. 6A, in step δ, the acrylic material film f1(f) remaining on the substrate S is irradiated with UV light to cure the acrylic material film f1 to form an acrylic resin film F. (Step SB7). This step is performed in the film forming chamber (reduced pressure atmosphere). At that time, the acrylic material film f2 covering the metal mask MB previously peeled from the substrate S is evaporated from above the metal mask MB in the above step γ, and when the step δ is performed, the metal mask is removed. The acrylic material film f2 does not exist on the MB. Therefore, the acrylic resin film is not formed on the metal mask MB.

<アクリル樹脂膜の成膜装置>
図12は、上述した本発明の実施形態に係るメタルマスクMBを用い、基板Sに樹脂材料を供給することにより、該基板S上に液体の樹脂材料膜を形成し、樹脂材料膜を重合して樹脂膜を形成する成膜装置100の一構成例である。以下では、樹脂材料膜の一例であるアクリル樹脂膜を成膜する場合について詳述する。
成膜装置100は、内部空間が減圧可能なチャンバ110と、気化した樹脂材料をチャンバ110(処理室)に供給する気化器300と、を有する。
<Acrylic resin film forming device>
FIG. 12 shows that a liquid resin material film is formed on the substrate S by supplying the resin material to the substrate S by using the metal mask MB according to the above-described embodiment of the present invention, and the resin material film is polymerized. 1 is a configuration example of a film forming apparatus 100 that forms a resin film by using the above. Hereinafter, a case of forming an acrylic resin film, which is an example of the resin material film, will be described in detail.
The film forming apparatus 100 includes a chamber 110 whose internal space can be decompressed, and a vaporizer 300 which supplies the vaporized resin material to the chamber 110 (processing chamber).

チャンバ110の内部空間は、後述するように、上部空間107、下部空間108から構成されている。
チャンバ110には、不図示の真空排気装置(真空排気手段、真空ポンプ等)が接続され、真空排気装置は、チャンバ110の内部空間が真空雰囲気となるように、内部空間のガスを排気できるように構成されている。
The inner space of the chamber 110 is composed of an upper space 107 and a lower space 108, as will be described later.
An unillustrated vacuum exhaust device (vacuum exhaust means, vacuum pump, etc.) is connected to the chamber 110, and the vacuum exhaust device is capable of exhausting gas in the internal space of the chamber 110 so that the internal space becomes a vacuum atmosphere. Is configured.

チャンバ110の内部空間には、図12に示すように、シャワープレート105が配されており、チャンバ110内においてシャワープレート105より上側が上部空間107を構成する。チャンバ110の最上部には、紫外光を透過可能な部材からなる天板120が設けられ、天板120の上側には紫外光の照射装置122(UV照射装置)が配されている。ここで、シャワープレート105も紫外光を透過可能な部材で形成することにより、照射装置122から天板120を通過して上部空間107へ導入された紫外光は、さらにシャワープレート105を通過し、シャワープレート105の下側に位置する下部空間108へ進行可能となる。これにより、後述する基板S上に形成されたアクリル材料膜に対して、成膜後に紫外光を照射し、アクリル材料膜(樹脂材料膜)を硬化させ、アクリル樹脂膜(樹脂膜)を形成することが可能とされている。 As shown in FIG. 12, a shower plate 105 is arranged in the internal space of the chamber 110, and the upper side of the shower plate 105 in the chamber 110 constitutes an upper space 107. A top plate 120 made of a member capable of transmitting ultraviolet light is provided at the top of the chamber 110, and an ultraviolet light irradiation device 122 (UV irradiation device) is arranged above the top plate 120. Here, the shower plate 105 is also formed of a member capable of transmitting ultraviolet light, so that the ultraviolet light that has passed through the top plate 120 from the irradiation device 122 and is introduced into the upper space 107 further passes through the shower plate 105, It is possible to proceed to the lower space 108 located below the shower plate 105. Thereby, the acrylic material film formed on the substrate S, which will be described later, is irradiated with ultraviolet light after the film formation to cure the acrylic material film (resin material film) to form an acrylic resin film (resin film). It is possible.

基板Sの被成膜面上に配置されたメタルマスクMAの開口部(不図示)を通じて、気化された樹脂材料が基板Sに付着する。その際、本発明の一実施形態に係る製造装置においては、基板Sの温度が、基板Sを載置するステージ102に内蔵された冷却装置102aにより、樹脂材料の凝縮温度以下に制御されているので、凝縮した液体のアクリル材料膜が基板S上に形成可能とされている。
ゆえに、本発明の一実施形態に係る製造装置100においては、基板Sを載置する支持台であるステージ102が、基板Sを零度以下の温度帯域に保持することが好ましい。
The vaporized resin material adheres to the substrate S through the opening (not shown) of the metal mask MA arranged on the film formation surface of the substrate S. At that time, in the manufacturing apparatus according to the embodiment of the present invention, the temperature of the substrate S is controlled to be equal to or lower than the condensation temperature of the resin material by the cooling device 102a built in the stage 102 on which the substrate S is mounted. Therefore, the condensed liquid acrylic material film can be formed on the substrate S.
Therefore, in the manufacturing apparatus 100 according to the embodiment of the present invention, it is preferable that the stage 102, which is a support table on which the substrate S is placed, holds the substrate S in a temperature range of 0 degrees or less.

なお、図12に示した成膜装置100は、本発明の実施形態の一例である。基板Sを載置する支持台であるステージ102が、基板Sを冷却保持する、温度制御装置である冷却装置102aを内蔵していれば、他の構成が採用されてもよい。
例えば、気化された樹脂材料が基板Sに向けて面内均一に拡散可能とされているならば、チャンバ110の内部空間にシャワープレート105を配置する必要はない。
The film forming apparatus 100 shown in FIG. 12 is an example of the embodiment of the present invention. Other configurations may be adopted as long as the stage 102, which is a support table on which the substrate S is placed, has a built-in cooling device 102a that is a temperature control device that cools and holds the substrate S.
For example, if the vaporized resin material can be uniformly diffused in the surface toward the substrate S, it is not necessary to dispose the shower plate 105 in the internal space of the chamber 110.

チャンバ110には、不図示の加熱装置が配されている。上部空間107及び下部空間108を構成するチャンバ110の内壁面の温度は、樹脂材料の露点温度以上、好ましくは40〜250℃程度となるように設定可能であり、加熱装置によって制御される。 The chamber 110 is provided with a heating device (not shown). The temperature of the inner wall surface of the chamber 110 forming the upper space 107 and the lower space 108 can be set to be equal to or higher than the dew point temperature of the resin material, preferably about 40 to 250° C., and controlled by the heating device.

チャンバ110内においてシャワープレート105より下側に位置する下部空間108には、アクリル樹脂膜が形成される基板Sを載置するステージ102(基板保持部)が配されている。 In the lower space 108 located below the shower plate 105 in the chamber 110, the stage 102 (substrate holding portion) on which the substrate S on which the acrylic resin film is formed is placed is arranged.

ステージ102においては、表面に基板が配置されるべき位置が予め定められている。ステージ102は、その表面が露出された状態で、チャンバ110内に配置されている。符号Sは基板ステージ102の表面の所定位置に配置された基板を示している。ステージ102には、基板Sを冷却する基板冷却装置102aが設けられる。 In the stage 102, the position where the substrate is to be placed on the surface is predetermined. The stage 102 is arranged in the chamber 110 with its surface exposed. Reference symbol S indicates a substrate arranged at a predetermined position on the surface of the substrate stage 102. The stage 102 is provided with a substrate cooling device 102 a that cools the substrate S.

基板冷却装置102aは、ステージ102内部に冷媒を供給してステージ102上面の基板Sを冷却する。具体的には、基板Sの温度が基板Sを載置するステージ102(基板保持部)に内蔵された冷却装置102aにより制御され、樹脂材料の気化温度以下、好ましくは零度(0℃)以下、例えば、−30℃〜0℃程度に制御される。 The substrate cooling device 102a supplies a coolant into the stage 102 to cool the substrate S on the upper surface of the stage 102. Specifically, the temperature of the substrate S is controlled by the cooling device 102a built in the stage 102 (substrate holding unit) on which the substrate S is mounted, and is equal to or lower than the vaporization temperature of the resin material, preferably equal to or lower than 0° C. For example, it is controlled at about -30°C to 0°C.

ステージ102の上側位置には、ステージ102の全面に対してシャワープレート105が設けられる。シャワープレート105は、多数の貫通孔の設けられた石英等の紫外線透過材料からなる板状部材で構成され、チャンバ110の内部空間を上空間と下空間とに分割している。 A shower plate 105 is provided above the stage 102 on the entire surface of the stage 102. The shower plate 105 is composed of a plate-shaped member made of an ultraviolet ray transmitting material such as quartz and provided with a large number of through holes, and divides the internal space of the chamber 110 into an upper space and a lower space.

下部空間108には、図示しないマスクが設けられ、このマスクの位置は、成膜時において所定の位置に設定可能である。下部空間108には、図示しないマスクの昇降機構が設けられる。 A mask (not shown) is provided in the lower space 108, and the position of this mask can be set to a predetermined position during film formation. In the lower space 108, a mask lifting mechanism (not shown) is provided.

チャンバ110の上部空間107は、配管112(樹脂材料供給管)およびバルブ112Vを介して気化器300と連通している。この樹脂材料供給管112を介してチャンバ110の上部空間107に対して、気化された樹脂材料は供給可能である。 The upper space 107 of the chamber 110 communicates with the vaporizer 300 via a pipe 112 (resin material supply pipe) and a valve 112V. The vaporized resin material can be supplied to the upper space 107 of the chamber 110 via the resin material supply pipe 112.

樹脂材料供給管112(第一配管)のバルブ112Vよりも気化器300に近い位置には、バルブ113Vを有する樹脂材料迂回管113(第二配管)の一端が接続されている。樹脂材料迂回管113(第二配管)の他端は、排気管114を介して外部に接続されており、樹脂材料迂回管113を通じてガスが排気可能である。 One end of a resin material bypass pipe 113 (second pipe) having a valve 113V is connected to a position of the resin material supply pipe 112 (first pipe) closer to the vaporizer 300 than the valve 112V. The other end of the resin material bypass pipe 113 (second pipe) is connected to the outside via an exhaust pipe 114, and gas can be exhausted through the resin material bypass pipe 113.

バルブ112Vおよびバルブ113Vの開閉駆動は、制御部400によって制御される。制御部400は、気化器300からの気化した樹脂材料をチャンバ110内へ供給する成膜状態と、気化器300からの気化した樹脂材料を外部に排気してチャンバ110内への供給しない非成膜状態と、を切り替え可能に制御する。 Opening/closing drive of the valve 112V and the valve 113V is controlled by the control unit 400. The control unit 400 supplies the vaporized resin material from the vaporizer 300 into the chamber 110, and the control unit 400 exhausts the vaporized resin material from the vaporizer 300 to the outside and does not supply the vaporized resin material into the chamber 110. The film state and the film state are controlled to be switchable.

バルブ112V、バルブ113V、及び制御部400は、チャンバ110の内部に樹脂材料を供給する、或いは、チャンバ110の外部に樹脂材料を排気する選択機能を有する切替部を構成している。 The valve 112V, the valve 113V, and the control unit 400 configure a switching unit that has a selection function of supplying a resin material to the inside of the chamber 110 or exhausting the resin material to the outside of the chamber 110.

気化器300は、チャンバ110に対して気化された樹脂材料を供給可能とする。図12に示すように、気化器300は、気化槽130と、吐出部132と、樹脂材料原料容器150と、を有する。 The vaporizer 300 can supply the vaporized resin material to the chamber 110. As shown in FIG. 12, the vaporizer 300 includes a vaporization tank 130, a discharge part 132, and a resin material raw material container 150.

気化槽130は、図12に示すように、液状の樹脂材料を気化するための内部空間を備え、内部空間の上方には、液状の樹脂材料を噴霧する吐出部132が配されている。気化槽130は、略円筒状に形成されるが、他の断面形状とされることもできる。気化槽130は、その内面が、例えば、SUSやアルミニウム等からなることができる。 As shown in FIG. 12, the vaporization tank 130 has an internal space for vaporizing the liquid resin material, and a discharge part 132 for spraying the liquid resin material is arranged above the internal space. The vaporization tank 130 is formed in a substantially cylindrical shape, but may have another cross-sectional shape. The inner surface of the vaporization tank 130 can be made of, for example, SUS or aluminum.

吐出部132には、樹脂材料原料容器150にバルブ140Vを介して接続された樹脂材料液供給管140の一端と、窒素ガス等とされるキャリアガスを供給するキャリアガス供給管130Gと、が接続されている。樹脂材料液供給管140の他端は、樹脂材料原料容器150に接続されるとともに、樹脂材料原料容器150内に貯留された液状の樹脂材料の内部に位置している。 One end of the resin material liquid supply pipe 140 connected to the resin material raw material container 150 via the valve 140V and a carrier gas supply pipe 130G for supplying a carrier gas such as nitrogen gas are connected to the discharge part 132. Has been done. The other end of the resin material liquid supply pipe 140 is connected to the resin material raw material container 150 and is located inside the liquid resin material stored in the resin material raw material container 150.

樹脂材料原料容器150には、窒素ガス等とされる材料液供給用の加圧ガス供給管150Gが接続され、樹脂材料原料容器150の内圧を上昇させて加圧した液状の樹脂材料は、樹脂材料液供給管140へと送液可能となっている。 A pressurized gas supply pipe 150G for supplying a material liquid such as nitrogen gas is connected to the resin material raw material container 150, and the liquid resin material pressurized by increasing the internal pressure of the resin material raw material container 150 is a resin. Liquid can be sent to the material liquid supply pipe 140.

吐出部132は、樹脂材料液供給管140から供給された液状の樹脂材料をキャリアガスとともに気化槽130の内部空間に噴霧するよう構成されている。吐出部132は、気化槽130の頂部略中央位置に設けられている。 The discharge part 132 is configured to spray the liquid resin material supplied from the resin material liquid supply pipe 140 into the internal space of the vaporization tank 130 together with the carrier gas. The discharge part 132 is provided at a substantially central position of the top of the vaporization tank 130.

気化槽130には、図12に示すように、気化槽130の下側位置に加温部135が設けられる。加温部135は、内部空間を上空間と下空間とに分割するように配置され、加温部135より上方に気化空間が形成され、下方に貯留部が形成される。 As shown in FIG. 12, the vaporization tank 130 is provided with a heating unit 135 at a position below the vaporization tank 130. The heating unit 135 is arranged so as to divide the internal space into an upper space and a lower space, a vaporization space is formed above the heating unit 135, and a storage unit is formed below the heating space.

加温部135は、吐出部132より下方位置に設けられ、吐出部132から噴霧された液状の樹脂材料を加熱して気化させるものである。 The heating unit 135 is provided below the discharge unit 132, and heats and vaporizes the liquid resin material sprayed from the discharge unit 132.

樹脂材料原料容器150の内圧を上昇させて、樹脂材料液供給管140から供給された液状の樹脂材料を、吐出部132からキャリアガスとともに気化槽130の内部空間に噴霧する。このとき、吐出部132に供給される樹脂材料およびキャリアガスをさらに加温することもできる。 The internal pressure of the resin material raw material container 150 is increased, and the liquid resin material supplied from the resin material liquid supply pipe 140 is sprayed from the discharge part 132 together with the carrier gas into the internal space of the vaporization tank 130. At this time, the resin material and the carrier gas supplied to the discharge part 132 can be further heated.

吐出部132からキャリアガスとともに気化槽130の内部空間に噴霧された樹脂材料は、加温された気化槽130の内部において気化する。 The resin material sprayed from the discharge unit 132 into the internal space of the vaporization tank 130 together with the carrier gas is vaporized inside the heated vaporization tank 130.

樹脂材料の気化が定常的に行われている間に、制御部400により、バルブ112Vを開状態として、チャンバ110にガスが流入可能な状態とするとともに、バルブ113Vを閉状態とする。すると、樹脂材料迂回管113(第二配管)は、ガスが流入できない状態となる。これにより、チャンバ110に気化した樹脂材料が供給され、成膜処理を行うことが可能となる。 During the steady vaporization of the resin material, the control unit 400 opens the valve 112V so that gas can flow into the chamber 110 and closes the valve 113V. Then, the resin material bypass pipe 113 (second pipe) is in a state in which gas cannot flow. As a result, the vaporized resin material is supplied to the chamber 110, and the film forming process can be performed.

切替部の駆動によって、即ち、制御部400によって、バルブ112V及びバルブ113Vの開閉状態を切替えるだけで、チャンバ110に対する有機材料の供給と、樹脂材料迂回管113(第二配管)に対する有機材料の供給とを選択することができる。このため、チャンバ110に供給する気化した樹脂材料の供給量を安定化できるため、成膜レートが変動することを防止して、膜特性の優れた樹脂材料膜を安定して形成することが可能となる。さらに、チャンバ110における基板の入れ替え時、および、マスクの位置合わせ時に、チャンバ110に樹脂材料を導入せずに、樹脂材料の気化を継続して行うことができるので、蒸気発生の停止/開始を繰り返すことなく、蒸気の発生レートを概ね一定にすることができる。 The organic material is supplied to the chamber 110 and the organic material bypass pipe 113 (second pipe) is supplied only by switching the open/closed states of the valve 112V and the valve 113V by driving the switching unit, that is, by the control unit 400. You can choose and. Therefore, the supply amount of the vaporized resin material supplied to the chamber 110 can be stabilized, so that the film formation rate can be prevented from varying and a resin material film having excellent film characteristics can be stably formed. Becomes Furthermore, since the resin material can be continuously vaporized without introducing the resin material into the chamber 110 when the substrates are replaced in the chamber 110 and the mask is aligned, the vapor generation can be stopped/started. The steam generation rate can be made substantially constant without repetition.

成膜装置100は、例えば、気化温度40℃〜250℃程度とされる紫外線硬化型のアクリル樹脂とされる樹脂材料の成膜と、成膜された樹脂材料の硬化のための紫外線照射とを同一のチャンバ110内で可能とするように構成されている。これにより、何れの処理工程も同一の装置構成で行うことが可能となり、生産性を向上させることができる。 The film forming apparatus 100 performs, for example, film formation of a resin material which is an ultraviolet curable acrylic resin having a vaporization temperature of about 40° C. to 250° C., and ultraviolet irradiation for curing the film formed resin material. It is configured so as to be possible in the same chamber 110. As a result, it is possible to perform all processing steps with the same device configuration, and it is possible to improve productivity.

本発明は、樹脂膜の形成方法と、樹脂の形成において有効な構成を備えた製造装置に広く適用可能である。本発明は、例えば、有機ELディスプレイやフレキシブルディスプレイの封止膜として樹脂膜を作製する場合に好適に用いられる。 INDUSTRIAL APPLICABILITY The present invention can be widely applied to a method for forming a resin film and a manufacturing apparatus having a configuration effective in forming a resin. INDUSTRIAL APPLICABILITY The present invention is suitably used, for example, when a resin film is produced as a sealing film for organic EL displays and flexible displays.

f(f1、f2) アクリル材料膜(樹脂材料膜)、F(F1、F2) アクリル樹脂膜(樹脂膜)、MB メタルマスク、S 基板 W 開口部。 f (f1, f2) Acrylic material film (resin material film), F (F1, F2) Acrylic resin film (resin film), MB metal mask, S substrate W opening.

Claims (8)

マスク本体が金属材料からなり所定の開口部を備えたマスクを用い、減圧雰囲気において、基板上に樹脂膜を形成する方法であって、
減圧雰囲気において、冷却された支持台に載置された前記基板と接するように前記マスクを設けて、該マスクを介して気化した樹脂材料を供給し該基板上で凝縮させ、該基板上に液体の樹脂材料膜を形成する第1工程と、
前記基板から前記マスクを剥離する第2工程と、
前記マスク上の樹脂材料膜を熱処理し、該樹脂材料膜を蒸発する第3工程と、
前記基板上に残存した樹脂材料膜にUV光を照射し、該樹脂材料膜を硬化して樹脂膜を形成する第4工程と、
を順に備える、
樹脂膜の形成方法。
A method of forming a resin film on a substrate in a reduced pressure atmosphere, using a mask having a predetermined opening in a mask body made of a metal material,
In a depressurized atmosphere, the mask is provided so as to come into contact with the substrate placed on a cooled support, and the vaporized resin material is supplied through the mask to condense on the substrate and liquid on the substrate. A first step of forming a resin material film of
A second step of peeling the mask from the substrate,
A third step of heat-treating the resin material film on the mask to evaporate the resin material film;
A fourth step of irradiating the resin material film remaining on the substrate with UV light to cure the resin material film to form a resin film;
In order,
Method for forming resin film.
前記第3工程における熱処理は、加熱装置を用いた前記マスクに対する加熱昇温である、
請求項1に記載の樹脂膜の形成方法。
The heat treatment in the third step is heating and heating of the mask using a heating device.
The method for forming a resin film according to claim 1.
前記第3工程における熱処理は、前記マスクが前記支持台から離れたことによる自然昇温によって行われる、
請求項1に記載の樹脂膜の形成方法。
The heat treatment in the third step is performed by a natural temperature rise due to the mask being separated from the support table.
The method for forming a resin film according to claim 1.
前記第3工程における熱処理においては、前記マスクが前記支持台から離され、加熱されたチャンバもしくはシャワープレートからの輻射熱により加熱される、
請求項1に記載の樹脂膜の形成方法。
In the heat treatment in the third step, the mask is separated from the support table and heated by radiant heat from a heated chamber or shower plate,
The method for forming a resin film according to claim 1.
マスク本体が金属材料からなり所定の開口部を備えたマスクを用い、減圧雰囲気において、基板上に樹脂膜を形成する装置であって、
樹脂膜の材料である気化した樹脂材料を基板上に供給し、凝縮させて樹脂材料膜を形成する時に、前記基板を零度以下の温度帯域に保つ温度制御装置を内蔵する該基板の支持部と、
前記樹脂材料膜に対してUV光を照射する前に、前記支持部に載置された状態にある該基板から前記マスクを剥離して、該マスク上の樹脂材料膜を熱処理する機構と、
前記樹脂材料膜にUV光を照射して硬化させ、樹脂膜を形成するUV照射装置と、を備える、
樹脂膜の成膜装置。
An apparatus for forming a resin film on a substrate in a reduced pressure atmosphere, using a mask whose mask body is made of a metal material and has a predetermined opening,
When a vaporized resin material, which is a material of a resin film, is supplied onto a substrate and condensed to form a resin material film, a support portion for the substrate that incorporates a temperature control device that keeps the substrate in a temperature range of zero degrees or less. ,
A mechanism for, before irradiating the resin material film with UV light, peeling off the mask from the substrate placed on the supporting portion and heat treating the resin material film on the mask;
A UV irradiation device that irradiates the resin material film with UV light to cure the resin material film to form a resin film.
Deposition equipment for resin film.
前記樹脂材料膜を熱処理する機構が、前記マスクの温度増加を促す加熱装置である、
請求項5に記載の樹脂膜の成膜装置。
The mechanism for heat-treating the resin material film is a heating device for promoting the temperature increase of the mask,
The resin film forming apparatus according to claim 5.
前記樹脂材料膜を熱処理する機構が、前記マスクを支持台から離間させる移動装置である、
請求項5に記載の樹脂膜の成膜装置。
A mechanism for heat-treating the resin material film is a moving device that separates the mask from a support.
The resin film forming apparatus according to claim 5.
前記樹脂材料膜を熱処理する機構が、前記基板を収容するチャンバの加熱装置である、
請求項5に記載の樹脂膜の成膜装置。
The mechanism for heat-treating the resin material film is a heating device for a chamber that houses the substrate,
The resin film forming apparatus according to claim 5.
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