JP6703593B2 - ジイソブテンのＰｄ触媒ヒドロキシカルボニル化の方法：酢酸／ジイソブテン比 - Google Patents

ジイソブテンのＰｄ触媒ヒドロキシカルボニル化の方法：酢酸／ジイソブテン比 Download PDF

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Publication number
JP6703593B2
JP6703593B2 JP2018238250A JP2018238250A JP6703593B2 JP 6703593 B2 JP6703593 B2 JP 6703593B2 JP 2018238250 A JP2018238250 A JP 2018238250A JP 2018238250 A JP2018238250 A JP 2018238250A JP 6703593 B2 JP6703593 B2 JP 6703593B2
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diisobutene
acetic acid
addition
mol
bar
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JP2018238250A
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Japanese (ja)
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JP2019112400A5 (OSRAM
JP2019112400A (ja
Inventor
サン，ルイ
ククミエルクジク，ペーター
ドン，カイウ
ジャックステル，ラルフ
ベラー，マティアス
フランケ，ロベルト
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Evonik Operations GmbH
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Evonik Operations GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/126—Acids containing more than four carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0202—Polynuclearity
    • B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2018238250A 2017-12-21 2018-12-20 ジイソブテンのＰｄ触媒ヒドロキシカルボニル化の方法：酢酸／ジイソブテン比 Expired - Fee Related JP6703593B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17209362.7A EP3502087B1 (de) 2017-12-21 2017-12-21 Verfahren zur pd-katalysierten hydroxycarbonylierung von diisobuten: verhältnis essigsäure/diisobuten
EP17209362.7 2017-12-21

Publications (3)

Publication Number Publication Date
JP2019112400A JP2019112400A (ja) 2019-07-11
JP2019112400A5 JP2019112400A5 (OSRAM) 2020-05-07
JP6703593B2 true JP6703593B2 (ja) 2020-06-03

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JP2018238250A Expired - Fee Related JP6703593B2 (ja) 2017-12-21 2018-12-20 ジイソブテンのＰｄ触媒ヒドロキシカルボニル化の方法：酢酸／ジイソブテン比

Country Status (11)

Country Link
US (1) US10519090B2 (OSRAM)
EP (1) EP3502087B1 (OSRAM)
JP (1) JP6703593B2 (OSRAM)
KR (1) KR102145214B1 (OSRAM)
CN (1) CN109942398B (OSRAM)
CA (1) CA3028189C (OSRAM)
ES (1) ES2807545T3 (OSRAM)
MX (1) MX383693B (OSRAM)
MY (1) MY197949A (OSRAM)
TW (1) TWI790332B (OSRAM)
ZA (1) ZA201808494B (OSRAM)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2785564T3 (es) * 2017-12-21 2020-10-07 Evonik Degussa Gmbh Procedimiento para la conversión directa de diisobuteno en un ácido carboxílico
PL3842411T3 (pl) 2019-12-17 2023-10-02 Evonik Operations Gmbh Ester trimetylowy kwasu 3,3',3''-(cykloheksano-1,2,4-triylo)tripropionowego

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2709438C3 (de) * 1977-03-04 1980-01-17 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von C6. bis C20 Alkylcarbonsäuren
ZA965990B (en) * 1995-07-17 1997-02-24 Shell Int Research Process for the continuous carbonylation of olefins.
DE102004055252A1 (de) * 2004-11-16 2006-05-24 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von aliphatischen geradkettigen und ß-alkylverzweigten Carbonsäuren
CN106397484A (zh) * 2015-07-23 2017-02-15 赢创德固赛有限公司 用于烷氧基羰基化的丁基‑桥连的二膦配体
CN106187735B (zh) * 2016-07-07 2019-04-09 河北华旭化工有限公司 二异丁烯羰基合成特戊酸和2,2,4,4-四甲基戊酸的方法

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Publication number Publication date
ES2807545T3 (es) 2021-02-23
EP3502087B1 (de) 2020-06-24
ZA201808494B (en) 2019-09-25
MX383693B (es) 2025-03-14
US20190194113A1 (en) 2019-06-27
EP3502087A1 (de) 2019-06-26
CA3028189A1 (en) 2019-06-21
KR20190075836A (ko) 2019-07-01
TW201930249A (zh) 2019-08-01
JP2019112400A (ja) 2019-07-11
MY197949A (en) 2023-07-25
US10519090B2 (en) 2019-12-31
CN109942398A (zh) 2019-06-28
CN109942398B (zh) 2022-09-20
TWI790332B (zh) 2023-01-21
MX2018015527A (es) 2019-06-24
CA3028189C (en) 2021-01-12
KR102145214B1 (ko) 2020-08-18

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