JP6636040B2 - 接着剤組成物 - Google Patents
接着剤組成物 Download PDFInfo
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- JP6636040B2 JP6636040B2 JP2017549738A JP2017549738A JP6636040B2 JP 6636040 B2 JP6636040 B2 JP 6636040B2 JP 2017549738 A JP2017549738 A JP 2017549738A JP 2017549738 A JP2017549738 A JP 2017549738A JP 6636040 B2 JP6636040 B2 JP 6636040B2
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- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000004018 acid anhydride group Chemical group 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- IIYWTFLFMVZQET-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3.C1C(C2)CC3CC1CC2C3 IIYWTFLFMVZQET-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 description 1
- LBDSXVIYZYSRII-IGMARMGPSA-N alpha-particle Chemical compound [4He+2] LBDSXVIYZYSRII-IGMARMGPSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- OOULUYZFLXDWDQ-UHFFFAOYSA-L barium perchlorate Chemical compound [Ba+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O OOULUYZFLXDWDQ-UHFFFAOYSA-L 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- QDVNNDYBCWZVTI-UHFFFAOYSA-N bis[4-(ethylamino)phenyl]methanone Chemical compound C1=CC(NCC)=CC=C1C(=O)C1=CC=C(NCC)C=C1 QDVNNDYBCWZVTI-UHFFFAOYSA-N 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 150000001669 calcium Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- 239000006059 cover glass Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate group Chemical group [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- GCSJLQSCSDMKTP-UHFFFAOYSA-N ethenyl(trimethyl)silane Chemical compound C[Si](C)(C)C=C GCSJLQSCSDMKTP-UHFFFAOYSA-N 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229910000373 gallium sulfate Inorganic materials 0.000 description 1
- SBDRYJMIQMDXRH-UHFFFAOYSA-N gallium;sulfuric acid Chemical compound [Ga].OS(O)(=O)=O SBDRYJMIQMDXRH-UHFFFAOYSA-N 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- AHAREKHAZNPPMI-UHFFFAOYSA-N hexa-1,3-diene Chemical compound CCC=CC=C AHAREKHAZNPPMI-UHFFFAOYSA-N 0.000 description 1
- DWYKRMTVNUXSIM-UHFFFAOYSA-N hexane-1,6-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OCCCCCCO DWYKRMTVNUXSIM-UHFFFAOYSA-N 0.000 description 1
- 230000005525 hole transport Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- OTLDLKLSNZMTTA-UHFFFAOYSA-N octahydro-1h-4,7-methanoindene-1,5-diyldimethanol Chemical compound C1C2C3C(CO)CCC3C1C(CO)C2 OTLDLKLSNZMTTA-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- AOLPZAHRYHXPLR-UHFFFAOYSA-I pentafluoroniobium Chemical compound F[Nb](F)(F)(F)F AOLPZAHRYHXPLR-UHFFFAOYSA-I 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 125000003748 selenium group Chemical class *[Se]* 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YRGLXIVYESZPLQ-UHFFFAOYSA-I tantalum pentafluoride Chemical compound F[Ta](F)(F)(F)F YRGLXIVYESZPLQ-UHFFFAOYSA-I 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- HDUMBHAAKGUHAR-UHFFFAOYSA-J titanium(4+);disulfate Chemical compound [Ti+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HDUMBHAAKGUHAR-UHFFFAOYSA-J 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0075—Antistatics
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
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Description
本出願は、2015年03月24日付け韓国特許出願第10−2015−0040742号に基づく優先権の利益を主張し、当該韓国特許出願の文献に開示されたすべての内容は、本明細書の一部として含まれる。
技術分野
本出願は、接着剤組成物、これを含む有機電子装置及び前記有機電子装置の製造方法に関する。
R=Ji/J60×100
T=V0.5/V5
常温で樹脂成分として、オレフィン系樹脂であるポリイソブチレン樹脂(PIB、Daelim、Mn=2,400g/mol)及び硬化性化合物である脂環族エポキシ樹脂(KUKDO化学、ST−4100D)を70:30(PIB:ST−4100D)の重量比率で混合容器に投入した。硬化剤としてイミダゾール系硬化剤(Shikoku、2P4MHZ)を樹脂成分100重量部に対して5重量部投入した。なお、水分吸着剤としてカルシウムオキシド(CaO、Aldrich)を前記樹脂成分100重量部に対して20重量部をさらに容器に投入した。
前記混合容器をPlanetary mixer(クラボウ、KK−250s)を利用して均一な組成物溶液を製造した。
常温で樹脂成分として、オレフィン系樹脂であるポリイソブチレン樹脂(PIB、Daelim、Mn=2,400g/m)及び硬化性化合物であるポリブタジエンジアクリレート(sartomer、CN307)を70:30(PIB:CN307)の重量の比率で混合容器に投入した。引き続いて、ラジカル開始剤として2、2−ジメトキシ−1、2−ジフェニルエタン−1−オン(Irgacure 651、Ciba)を前記樹脂成分100重量部に対して約1重量部を前記容器に投入した。なお、水分吸着剤としてカルシウムオキシド(CaO、Aldrich)を前記樹脂成分100重量部に対して20重量部をさらに容器に投入した。
前記混合容器をPlanetary mixer(クラボウ、KK−250s)を利用して均一な組成物溶液を製造した。
常温で樹脂成分として、オレフィン系樹脂であるポリイソブチレン樹脂(PIB、Daelim、Mn=2,400g/mol)及び硬化性化合物である脂環族エポキシ樹脂(KUKDO化学、ST−4100D)及びポリブタジエンジアクリレート(sartomer、CN307)を60:20:20(PIB:ST−4100D:CN307)の重量比率で混合容器に投入した。引き続いて、ラジカル開始剤として2、2−ジメトキシ−1、2−ジフェニルエタン−1−オン(Irgacure 651、Ciba)を前記樹脂成分100重量部に対して約1重量部を前記容器に投入し、硬化剤としてイミダゾール系硬化剤(Shikoku、2P4MHZ)を樹脂成分100重量部に対して5重量部投入した。なお、水分吸着剤としてカルシウムオキシド(CaO、Aldrich)を前記樹脂成分100重量部に対して20重量部をさらに容器に投入した。
前記混合容器をPlanetary mixer(クラボウ、KK−250s)を利用して均一な組成物溶液を製造した。
オレフィン系樹脂であるポリイソブチレン樹脂(PIB、Daelim、Mn=2,400g/mol)及び硬化性化合物である脂環族エポキシ樹脂(KUKDO化学、ST−4100D)を90:10(PIB:ST−4100D)の重量比率で混合容器に投入したことを除いて、実施例1と同一の方法で接着剤組成物を製造した。
オレフィン系樹脂であるポリイソブチレン樹脂(PIB、Daelim、Mn=2,400g/mol)及び硬化性化合物である脂環族エポキシ樹脂(KUKDO化学、ST−4100D)を50:50(PIB:ST−4100D)の重量比率で混合容器に投入したことを除いて、実施例1と同一の方法で接着剤組成物を製造した。
オレフィン系樹脂であるポリイソブチレン樹脂(PIB、Daelim、Mn=2,400g/m)及び硬化性化合物であるポリブタジエンジアクリレート(sartomer、CN307)を90:10(PIB:CN307)の重量の比率で混合容器に投入したことを除いて、実施例2と同一の方法で接着剤組成物を製造した。
オレフィン系樹脂であるポリイソブチレン樹脂(PIB、Daelim、Mn=2,400g/m)及び硬化性化合物であるポリブタジエンジアクリレート(sartomer、CN307)を40:60(PIB:CN307)の重量の比率で混合容器に投入したことを除いて、実施例2と同一の方法で接着剤組成物を製造した。
オレフィン系樹脂であるポリイソブチレン樹脂(PIB、Daelim、Mn=2,400g/mol)と硬化性化合物である脂環族エポキシ樹脂(KUKDO化学、ST−4100D)及びポリブタジエンジアクリレート(sartomer、CN307)を50:20:30(PIB:ST−4100D:CN307)の重量比率で混合容器に投入したことを除いて、実施例3と同一の方法で接着剤組成物を製造した。
1.粘弾性の比率(Viscoelastic Ratio、R)
実施例及び比較例の接着剤組成物を硬化させて、8mmの直径及び200μmの厚さを有する試験片で製造した。
R=Ji/J60×100
実施例及び比較例の接着剤組成物の相溶性を下記のように評価した。製造された接着剤組成物を容器に25℃で3日間放置した後、相分離の可否を観察した。前記組成物で相分離が全然発生しない場合、○、部分的に相分離が発生した場合、△、2つの層に相分離が発生した場合、×で表示した。
実施例及び比較例の接着剤組成物の水分遮断特性を照射するために、カルシウムテストを進行した。具体的には、100mm×100mmサイズのガラス基板上にカルシウム(Ca)を5mm×5mmのサイズ及び100nmの厚さで7個(7 spot)蒸着し、実施例及び比較例の接着剤組成物をディスペンサーを使用してカルシウム蒸着部から3mm間隔で周縁部(周辺部)に塗布した後に、カバーガラスを各カルシウム蒸着箇所に積層した後、接着剤組成物の幅が3mmとなるように押圧した。その後、実施例1、比較例1及び比較例2は、100℃オーブンで3時間熱を加えて前記接着剤組成物を硬化し、実施例2、比較例3及び4は、前記接着剤組成物にUV−A領域帯の波長範囲を有する光を5J/cm2の光量で照射して硬化し、実施例3及び比較例5は、前記接着剤組成物にUV−A領域帯の波長範囲を有する光を5J/cm2の光量で照射した後、100℃オーブンで3時間熱を加えて接着剤組成物を硬化した。その後、11mm×11mmのサイズに封止されたカルシウム(Ca)試験片をそれぞれ切断した。得られた試験片を恒温恒湿チャンバで85℃の温度及び85%R.H.の環境に放置した後、水分浸透による酸化反応によってカルシウムが透明になり始めた時点を評価し、下記表1に示す。
実施例及び比較例で製造した接着剤組成物を0.7T Soda−lime glassに塗布した後、同一のガラスで積層して試験片を製造した。実施例1、比較例1及び比較例2は、100℃オーブンで3時間熱を加えて前記接着剤組成物を硬化し、実施例2、比較例3及び4は、前記接着剤組成物にUV−A領域帯の波長範囲を有する光を5J/cm2の光量で照射して硬化し、実施例3及び比較例5は、前記接着剤組成物にUV−A領域帯の波長範囲を有する光を5J/cm2の光量で照射した後、100℃オーブンで3時間熱を加えて接着剤組成物を硬化した。
10 側面封止層
11 前面封止層
21 基板
22 カバー基板
23 有機電子素子
Claims (13)
- 重量平均分子量が10万以下のオレフィン系樹脂及び硬化性化合物が、それぞれ55重量部〜85重量部及び15重量部〜45重量部で含まれ、さらに水分吸着剤が、オレフィン系樹脂100重量部に対して5〜100重量部で含まれる、下記一般式1による粘弾性の比率(R)が34%〜40%の範囲内にある有機電子素子封止用接着剤組成物:
[一般式1]
R=Ji/J60×100
前記一般式1でJiは、前記接着剤組成物を硬化させて、8mmの直径及び200μmの厚さである円形の試験片に製造し、前記試験片をARES(Advanced Rheometric Expansion System)にローディングし、100℃で200gの軸方向力で5000Paの応力を1分間加えたとき、前記軸方向力を加えた時点での変形係数を意味し、前記J60は、前記軸方向力を加えた時点から1分が経過した時点での変形係数を意味する。 - オレフィン系樹脂の透湿度が、50g/m2・day以下である、請求項1に記載の接着剤組成物。
- 硬化性化合物は、熱硬化性樹脂または光硬化性化合物を含む、請求項2に記載の接着剤組成物。
- 熱硬化性樹脂は、熱硬化性官能基を1つ以上含む樹脂である、請求項3に記載の接着剤組成物。
- 熱硬化性官能基は、エポキシ基、イソシアネート基、ヒドロキシ基、カルボキシル基またはアミド基を含む、請求項4に記載の接着剤組成物。
- 光硬化性化合物は、多官能性の活性エネルギー線重合性化合物を含む、請求項3に記載の接着剤組成物。
- 硬化剤または開始剤を含む、請求項3に記載の接着剤組成物。
- オレフィン系樹脂は、反応性官能基を少なくとも1つ以上有する、請求項2に記載の接着剤組成物。
- 水分吸着剤がP2O5、Li2O、Na2O、BaO、CaO、MgO、Li2SO4、Na2SO4、CaSO4、MgSO4、CoSO4、Ga2(SO4)3、Ti(SO4)2、NiSO4、CaCl2、MgCl2、SrCl2、YCl3、CuCl2、CsF、TaF5、NbF5、LiBr、CaBr2、CeBr3、SeBr4、VBr3、MgBr2、BaI2、MgI2、Ba(ClO4)2及びMg(ClO4)2よりなる群から選択された1つ以上である、請求項1から8のいずれか一項に記載の接着剤組成物。
- 無機フィラーをさらに含む、請求項2に記載の接着剤組成物。
- 基板と、基板上に形成された有機電子素子と、前記基板の周縁部上に前記有機電子素子の側面を取り囲むように形成され、請求項1に記載の接着剤組成物を含む側面封止層と、を含む有機電子装置。
- 有機電子素子の前面をカバーする前面封止層をさらに含み、前記前面封止層及び側面封止層は、同一平面上に存在する、請求項11に記載の有機電子装置。
- 上部に有機電子素子が形成された基板の周縁部上に請求項1に記載の接着剤組成物を前記有機電子素子の側面を取り囲むように塗布する段階と、前記接着剤組成物に光を照射する段階と、前記接着剤組成物に熱を加える段階と、を含む有機電子装置の製造方法。
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