JP6599367B2 - ガス拡散電極を用いて二酸化炭素を電気化学的に還元するための方法及びシステム - Google Patents

ガス拡散電極を用いて二酸化炭素を電気化学的に還元するための方法及びシステム Download PDF

Info

Publication number
JP6599367B2
JP6599367B2 JP2016569872A JP2016569872A JP6599367B2 JP 6599367 B2 JP6599367 B2 JP 6599367B2 JP 2016569872 A JP2016569872 A JP 2016569872A JP 2016569872 A JP2016569872 A JP 2016569872A JP 6599367 B2 JP6599367 B2 JP 6599367B2
Authority
JP
Japan
Prior art keywords
catholyte
anolyte
cathode
anode
stream
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2016569872A
Other languages
English (en)
Japanese (ja)
Other versions
JP2017521555A5 (enExample
JP2017521555A (ja
Inventor
カッキュール,ジェリー・ジェイ
ラッカラジュ,プラサード
ティーミー,カイル
Original Assignee
アヴァンティウム・ノレッジ・センター・ベスローテン・フェンノートシャップ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2014/046555 external-priority patent/WO2015195149A1/en
Application filed by アヴァンティウム・ノレッジ・センター・ベスローテン・フェンノートシャップ filed Critical アヴァンティウム・ノレッジ・センター・ベスローテン・フェンノートシャップ
Priority claimed from US14/726,061 external-priority patent/US10329676B2/en
Priority claimed from PCT/US2015/033378 external-priority patent/WO2015184388A1/en
Publication of JP2017521555A publication Critical patent/JP2017521555A/ja
Publication of JP2017521555A5 publication Critical patent/JP2017521555A5/ja
Application granted granted Critical
Publication of JP6599367B2 publication Critical patent/JP6599367B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C25B11/032—Gas diffusion electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/083—Separating products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/13—Organo-metallic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
JP2016569872A 2014-05-29 2015-05-29 ガス拡散電極を用いて二酸化炭素を電気化学的に還元するための方法及びシステム Active JP6599367B2 (ja)

Applications Claiming Priority (11)

Application Number Priority Date Filing Date Title
US201462004544P 2014-05-29 2014-05-29
US62/004,544 2014-05-29
US201462014465P 2014-06-19 2014-06-19
US62/014,465 2014-06-19
PCT/US2014/046555 WO2015195149A1 (en) 2014-06-19 2014-07-14 Integrated process for co-production of carboxylic acids and halogen products from carbon dioxide
USPCT/US2014/046555 2014-07-14
US201562108407P 2015-01-27 2015-01-27
US62/108,407 2015-01-27
US14/726,061 2015-05-29
US14/726,061 US10329676B2 (en) 2012-07-26 2015-05-29 Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode
PCT/US2015/033378 WO2015184388A1 (en) 2014-05-29 2015-05-29 Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode

Publications (3)

Publication Number Publication Date
JP2017521555A JP2017521555A (ja) 2017-08-03
JP2017521555A5 JP2017521555A5 (enExample) 2018-07-05
JP6599367B2 true JP6599367B2 (ja) 2019-10-30

Family

ID=57483085

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2016569872A Active JP6599367B2 (ja) 2014-05-29 2015-05-29 ガス拡散電極を用いて二酸化炭素を電気化学的に還元するための方法及びシステム

Country Status (2)

Country Link
JP (1) JP6599367B2 (enExample)
CA (1) CA2950294C (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023525988A (ja) * 2020-05-20 2023-06-20 ユニバーシティー オブ デラウェア 電気化学的に駆動される二酸化炭素セパレータ

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017112900A1 (en) * 2015-12-22 2017-06-29 Avantium Holding B.V. System and method for the co-production of oxalic acid and acetic acid
WO2019051609A1 (en) * 2017-09-14 2019-03-21 The University Of British Columbia SYSTEMS AND METHODS FOR ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE
JP6845114B2 (ja) * 2017-09-20 2021-03-17 株式会社東芝 二酸化炭素電解装置および二酸化炭素電解方法
US12320022B2 (en) 2018-01-22 2025-06-03 Twelve Benefit Corporation System and method for carbon dioxide reactor control
DE102018202337A1 (de) * 2018-02-15 2019-08-22 Linde Aktiengesellschaft Elektrochemische Herstellung eines Gases umfassend CO mit Zwischenkühlung des Elektrolytstroms
JP6813526B2 (ja) 2018-03-16 2021-01-13 株式会社東芝 二酸化炭素の電解セルと電解装置
JP6813525B2 (ja) 2018-03-16 2021-01-13 株式会社東芝 二酸化炭素の電解セルと電解装置
US12006580B2 (en) 2018-04-25 2024-06-11 The University Of British Columbia Systems and methods for electrochemical generation of syngas and other useful chemicals
EP3626861A1 (de) * 2018-09-18 2020-03-25 Covestro Deutschland AG Elektrolysezelle, elektrolyseur und verfahren zur reduktion von co2
US11193212B2 (en) 2018-09-25 2021-12-07 Sekisui Chemical Co., Ltd. Synthetic method and synthetic system
US10811711B2 (en) 2018-11-20 2020-10-20 University Of Delaware Electrochemical devices and fuel cell systems
ES2909402T3 (es) * 2019-05-27 2022-05-06 Covestro Deutschland Ag Procedimiento de reciclaje de residuos de material de poliuretano para la fabricación de materias primas químicas para la fabricación de isocianatos y poliuretanos
EP3805429A1 (de) * 2019-10-08 2021-04-14 Covestro Deutschland AG Verfahren und elektrolysevorrichtung zur herstellung von chlor, kohlenmonoxid und gegebenenfalls wasserstoff
KR102232536B1 (ko) * 2019-10-15 2021-03-25 한국조선해양 주식회사 가스확산전극을 이용한 이산화탄소 및 평형수 처리장치
KR102305659B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 통합 공정 기반 이산화탄소 광물화 장치 및 방법
KR102305660B1 (ko) * 2019-11-26 2021-09-30 한국에너지기술연구원 무기 폐기물을 이용한 통합 공정 기반 이산화탄소 광물화 장치 및 방법
KR102305656B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 저전력 통합공정 기반 이산화탄소 광물화 장치 및 방법
KR102305657B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 무기 폐기물을 이용한 저전력 통합공정 기반 이산화탄소 광물화 장치 및 방법
KR102279080B1 (ko) * 2019-12-11 2021-07-16 부경대학교 산학협력단 염수 전기분해를 이용한 이산화탄소 전환 방법 및 시스템
CN114452822A (zh) * 2020-11-09 2022-05-10 鼎佳能源股份有限公司 二氧化碳回收产生一氧化碳再利用系统
CA3208601A1 (en) * 2021-01-21 2022-07-28 Zishuai ZHANG Methods and apparatus for performing electrolytic conversion
CN113120866B (zh) * 2021-03-31 2022-04-22 中南大学 一种利用二氧化硫制备单质硫的方法
EP4444939A2 (en) 2021-12-08 2024-10-16 Twelve Benefit Corporation Systems and methods for ethylene production
CN114318383A (zh) * 2022-01-25 2022-04-12 山东中教金源精密仪器有限公司 一种气固液三相界面光电催化反应池
CN114772682B (zh) * 2022-03-31 2023-07-25 北京化工大学 金基修饰电极、氯甘油的去除方法及其用途
CN115337933B (zh) * 2022-07-11 2024-03-22 华东理工大学 一种高效光催化还原co2的锡掺杂带有氧空位的四氧化三钴材料的制备方法及其应用
CN116231176A (zh) * 2023-03-02 2023-06-06 中国华能集团清洁能源技术研究院有限公司 一种利用空气源的移动式金属-二氧化碳电池系统
JP7743847B2 (ja) * 2023-03-06 2025-09-25 株式会社豊田中央研究所 二酸化炭素還元装置および人工光合成装置
WO2024250018A1 (en) * 2023-06-02 2024-12-05 Hunt Energy Enterprises, L.L.C. System, apparatus, and method to create synthetic fuel
CN119332256A (zh) * 2024-09-18 2025-01-21 万华化学集团股份有限公司 一种草酸的制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE81982T1 (de) * 1981-12-11 1983-09-29 The British Petroleum Co. P.L.C., Sunbury-On-Thames, Middlesex Elektrochemische organische synthese.
JPH0693485A (ja) * 1992-09-10 1994-04-05 Tanaka Kikinzoku Kogyo Kk 二酸化炭素の還元方法
JPH07258877A (ja) * 1994-03-23 1995-10-09 Tanaka Kikinzoku Kogyo Kk ガスの電解還元方法
US20120171583A1 (en) * 2010-12-30 2012-07-05 Liquid Light, Inc. Gas phase electrochemical reduction of carbon dioxide
US20130034489A1 (en) * 2011-02-14 2013-02-07 Gilliam Ryan J Electrochemical hydroxide system and method using fine mesh cathode
JP6083531B2 (ja) * 2011-03-18 2017-02-22 国立大学法人長岡技術科学大学 二酸化炭素の還元固定化システム、二酸化炭素の還元固定化方法、及び有用炭素資源の製造方法
KR20150055033A (ko) * 2012-09-14 2015-05-20 리퀴드 라이트 인코포레이티드 이산화탄소의 전기화학적 환원을 위한 방법 및 고 표면적 전극
KR20150056627A (ko) * 2012-09-19 2015-05-26 리퀴드 라이트 인코포레이티드 이산화탄소로부터 카복실산을 생산하기 위한 통합 공정
KR20160040614A (ko) * 2013-07-31 2016-04-14 아쿠아하이드렉스 프로프라이어터리 리미티드 기체 확산 전극(들)을 가지는 전기-합성 또는 전기-에너지 전지
WO2015035521A1 (en) * 2013-09-12 2015-03-19 Mantra Energy Alternatives Ltd Membrane-less reactor for the electro-reduction of carbon dioxide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2023525988A (ja) * 2020-05-20 2023-06-20 ユニバーシティー オブ デラウェア 電気化学的に駆動される二酸化炭素セパレータ
EP4153344A4 (en) * 2020-05-20 2024-07-10 University of Delaware ELECTROCHEMICALLY DRIVEN CARBON DIOXIDE SEPARATOR
JP7767312B2 (ja) 2020-05-20 2025-11-11 ユニバーシティー オブ デラウェア 電気化学的に駆動される二酸化炭素セパレータ

Also Published As

Publication number Publication date
CA2950294C (en) 2022-07-19
CA2950294A1 (en) 2015-12-03
JP2017521555A (ja) 2017-08-03

Similar Documents

Publication Publication Date Title
US11131028B2 (en) Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode
EP3149228B1 (en) Method for electrochemical reduction of carbon dioxide employing a gas diffusion electrode
JP2017521555A (ja) ガス拡散電極を用いて二酸化炭素を電気化学的に還元するための方法及びシステム
EP2898117B1 (en) Integrated process for producing oxalic acid from carbon dioxide
US8691069B2 (en) Method and system for the electrochemical co-production of halogen and carbon monoxide for carbonylated products
EP2898118B1 (en) A method and system for the electrochemical co-production of halogen and carbon monoxide for carbonylated products
US20130292257A1 (en) Integrated Process for Producing Carboxylic Acids from Carbon Dioxide
EP2935654B1 (en) Method for production of oxalic acid and oxalic acid reduction products
US20190017183A1 (en) System and Method for the Co-Production of Oxalic Acid and Acetic Acid
JP7688798B2 (ja) 電解セル、電解槽およびco2還元方法
WO2017118712A1 (en) Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion anode
JP2015533944A (ja) 二酸化炭素を電気化学的に還元するための方法及び高表面積電極
EP3157897B1 (en) Integrated process for co-production of carboxylic acids and halogen products from carbon dioxide
Theußl et al. Technological advances in the electroreduction of CO2 to HCOOH: the impact of catalyst, gas diffusion electrode, and cell design
CARBON Kaczur et al.

Legal Events

Date Code Title Description
A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20170725

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20170725

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180525

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20180525

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20181115

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20181120

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20190219

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20190419

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20190517

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20190905

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20191002

R150 Certificate of patent or registration of utility model

Ref document number: 6599367

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250