CA2950294C - Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode - Google Patents

Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode Download PDF

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Publication number
CA2950294C
CA2950294C CA2950294A CA2950294A CA2950294C CA 2950294 C CA2950294 C CA 2950294C CA 2950294 A CA2950294 A CA 2950294A CA 2950294 A CA2950294 A CA 2950294A CA 2950294 C CA2950294 C CA 2950294C
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Canada
Prior art keywords
anode
cathode
anolyte
catholyte
alkali metal
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CA2950294A
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English (en)
French (fr)
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CA2950294A1 (en
Inventor
Jerry J. Kaczur
Prasad Lakkaraju
Kyle Teamey
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Avantium Knowledge Centre BV
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Avantium Knowledge Centre BV
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Priority claimed from PCT/US2014/046555 external-priority patent/WO2015195149A1/en
Application filed by Avantium Knowledge Centre BV filed Critical Avantium Knowledge Centre BV
Priority claimed from US14/726,061 external-priority patent/US10329676B2/en
Priority claimed from PCT/US2015/033378 external-priority patent/WO2015184388A1/en
Publication of CA2950294A1 publication Critical patent/CA2950294A1/en
Application granted granted Critical
Publication of CA2950294C publication Critical patent/CA2950294C/en
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/24—Halogens or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
    • C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/03—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form perforated or foraminous
    • C25B11/031—Porous electrodes
    • C25B11/032—Gas diffusion electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/083—Separating products
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/13—Organo-metallic compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
CA2950294A 2014-05-29 2015-05-29 Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode Active CA2950294C (en)

Applications Claiming Priority (11)

Application Number Priority Date Filing Date Title
US201462004544P 2014-05-29 2014-05-29
US62/004,544 2014-05-29
US201462014465P 2014-06-19 2014-06-19
US62/014,465 2014-06-19
PCT/US2014/046555 WO2015195149A1 (en) 2014-06-19 2014-07-14 Integrated process for co-production of carboxylic acids and halogen products from carbon dioxide
USPCT/US14/46555 2014-07-14
US201562108407P 2015-01-27 2015-01-27
US62/108,407 2015-01-27
US14/726,061 2015-05-29
US14/726,061 US10329676B2 (en) 2012-07-26 2015-05-29 Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode
PCT/US2015/033378 WO2015184388A1 (en) 2014-05-29 2015-05-29 Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode

Publications (2)

Publication Number Publication Date
CA2950294A1 CA2950294A1 (en) 2015-12-03
CA2950294C true CA2950294C (en) 2022-07-19

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2950294A Active CA2950294C (en) 2014-05-29 2015-05-29 Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode

Country Status (2)

Country Link
JP (1) JP6599367B2 (enExample)
CA (1) CA2950294C (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
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US12286716B2 (en) 2018-01-22 2025-04-29 Twelve Benefit Corporation System and method for carbon dioxide reactor control
US12577690B2 (en) 2021-12-08 2026-03-17 Twelve Benefit Corporation Systems and methods for ethylene production
US12595572B2 (en) 2018-04-25 2026-04-07 The University Of British Columbia Systems and methods for electrochemical generation of syngas and other useful chemicals

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WO2017112900A1 (en) * 2015-12-22 2017-06-29 Avantium Holding B.V. System and method for the co-production of oxalic acid and acetic acid
WO2019051609A1 (en) * 2017-09-14 2019-03-21 The University Of British Columbia SYSTEMS AND METHODS FOR ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE
JP6845114B2 (ja) * 2017-09-20 2021-03-17 株式会社東芝 二酸化炭素電解装置および二酸化炭素電解方法
DE102018202337A1 (de) * 2018-02-15 2019-08-22 Linde Aktiengesellschaft Elektrochemische Herstellung eines Gases umfassend CO mit Zwischenkühlung des Elektrolytstroms
JP6813526B2 (ja) 2018-03-16 2021-01-13 株式会社東芝 二酸化炭素の電解セルと電解装置
JP6813525B2 (ja) 2018-03-16 2021-01-13 株式会社東芝 二酸化炭素の電解セルと電解装置
EP3626861A1 (de) * 2018-09-18 2020-03-25 Covestro Deutschland AG Elektrolysezelle, elektrolyseur und verfahren zur reduktion von co2
US11193212B2 (en) 2018-09-25 2021-12-07 Sekisui Chemical Co., Ltd. Synthetic method and synthetic system
US10811711B2 (en) 2018-11-20 2020-10-20 University Of Delaware Electrochemical devices and fuel cell systems
ES2909402T3 (es) * 2019-05-27 2022-05-06 Covestro Deutschland Ag Procedimiento de reciclaje de residuos de material de poliuretano para la fabricación de materias primas químicas para la fabricación de isocianatos y poliuretanos
EP3805429A1 (de) * 2019-10-08 2021-04-14 Covestro Deutschland AG Verfahren und elektrolysevorrichtung zur herstellung von chlor, kohlenmonoxid und gegebenenfalls wasserstoff
KR102232536B1 (ko) * 2019-10-15 2021-03-25 한국조선해양 주식회사 가스확산전극을 이용한 이산화탄소 및 평형수 처리장치
KR102305659B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 통합 공정 기반 이산화탄소 광물화 장치 및 방법
KR102305660B1 (ko) * 2019-11-26 2021-09-30 한국에너지기술연구원 무기 폐기물을 이용한 통합 공정 기반 이산화탄소 광물화 장치 및 방법
KR102305656B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 저전력 통합공정 기반 이산화탄소 광물화 장치 및 방법
KR102305657B1 (ko) * 2019-11-26 2021-09-29 한국에너지기술연구원 무기 폐기물을 이용한 저전력 통합공정 기반 이산화탄소 광물화 장치 및 방법
KR102279080B1 (ko) * 2019-12-11 2021-07-16 부경대학교 산학협력단 염수 전기분해를 이용한 이산화탄소 전환 방법 및 시스템
WO2021236979A1 (en) 2020-05-20 2021-11-25 University Of Delaware Et Al. Electrochemically driven carbon dioxide separator
CN114452822A (zh) * 2020-11-09 2022-05-10 鼎佳能源股份有限公司 二氧化碳回收产生一氧化碳再利用系统
CA3208601A1 (en) * 2021-01-21 2022-07-28 Zishuai ZHANG Methods and apparatus for performing electrolytic conversion
CN113120866B (zh) * 2021-03-31 2022-04-22 中南大学 一种利用二氧化硫制备单质硫的方法
CN114318383A (zh) * 2022-01-25 2022-04-12 山东中教金源精密仪器有限公司 一种气固液三相界面光电催化反应池
CN114772682B (zh) * 2022-03-31 2023-07-25 北京化工大学 金基修饰电极、氯甘油的去除方法及其用途
CN115337933B (zh) * 2022-07-11 2024-03-22 华东理工大学 一种高效光催化还原co2的锡掺杂带有氧空位的四氧化三钴材料的制备方法及其应用
CN116231176A (zh) * 2023-03-02 2023-06-06 中国华能集团清洁能源技术研究院有限公司 一种利用空气源的移动式金属-二氧化碳电池系统
JP7743847B2 (ja) * 2023-03-06 2025-09-25 株式会社豊田中央研究所 二酸化炭素還元装置および人工光合成装置
WO2024250018A1 (en) * 2023-06-02 2024-12-05 Hunt Energy Enterprises, L.L.C. System, apparatus, and method to create synthetic fuel
CN119332256A (zh) * 2024-09-18 2025-01-21 万华化学集团股份有限公司 一种草酸的制备方法

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12286716B2 (en) 2018-01-22 2025-04-29 Twelve Benefit Corporation System and method for carbon dioxide reactor control
US12320022B2 (en) 2018-01-22 2025-06-03 Twelve Benefit Corporation System and method for carbon dioxide reactor control
US12595572B2 (en) 2018-04-25 2026-04-07 The University Of British Columbia Systems and methods for electrochemical generation of syngas and other useful chemicals
US12577690B2 (en) 2021-12-08 2026-03-17 Twelve Benefit Corporation Systems and methods for ethylene production

Also Published As

Publication number Publication date
JP6599367B2 (ja) 2019-10-30
CA2950294A1 (en) 2015-12-03
JP2017521555A (ja) 2017-08-03

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