JP6488235B2 - 水溶性切削油剤原液組成物、切削油剤組成物および切削加工方法 - Google Patents
水溶性切削油剤原液組成物、切削油剤組成物および切削加工方法 Download PDFInfo
- Publication number
- JP6488235B2 JP6488235B2 JP2015541554A JP2015541554A JP6488235B2 JP 6488235 B2 JP6488235 B2 JP 6488235B2 JP 2015541554 A JP2015541554 A JP 2015541554A JP 2015541554 A JP2015541554 A JP 2015541554A JP 6488235 B2 JP6488235 B2 JP 6488235B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- mass
- cutting fluid
- oil
- stock solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 93
- 239000002173 cutting fluid Substances 0.000 title claims description 63
- 238000005520 cutting process Methods 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 21
- 239000011550 stock solution Substances 0.000 claims description 50
- -1 amine compound Chemical class 0.000 claims description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
- 239000002480 mineral oil Substances 0.000 claims description 35
- 235000010446 mineral oil Nutrition 0.000 claims description 33
- 239000000956 alloy Substances 0.000 claims description 16
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 125000003118 aryl group Chemical group 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- 229910000831 Steel Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 239000010959 steel Substances 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 claims description 7
- 238000007865 diluting Methods 0.000 claims description 3
- 239000003921 oil Substances 0.000 description 34
- 239000000839 emulsion Substances 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 14
- 238000010079 rubber tapping Methods 0.000 description 13
- 150000001412 amines Chemical class 0.000 description 12
- 238000010790 dilution Methods 0.000 description 11
- 239000012895 dilution Substances 0.000 description 11
- 238000004945 emulsification Methods 0.000 description 11
- 239000010730 cutting oil Substances 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 7
- 239000002199 base oil Substances 0.000 description 7
- 239000006071 cream Substances 0.000 description 7
- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- KKFDCBRMNNSAAW-UHFFFAOYSA-N 2-(morpholin-4-yl)ethanol Chemical compound OCCN1CCOCC1 KKFDCBRMNNSAAW-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Natural products C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- XZKLXPPYISZJCV-UHFFFAOYSA-N 1-benzyl-2-phenylimidazole Chemical compound C1=CN=C(C=2C=CC=CC=2)N1CC1=CC=CC=C1 XZKLXPPYISZJCV-UHFFFAOYSA-N 0.000 description 3
- OISVCGZHLKNMSJ-UHFFFAOYSA-N 2,6-dimethylpyridine Chemical compound CC1=CC=CC(C)=N1 OISVCGZHLKNMSJ-UHFFFAOYSA-N 0.000 description 3
- KZTWONRVIPPDKH-UHFFFAOYSA-N 2-(piperidin-1-yl)ethanol Chemical compound OCCN1CCCCC1 KZTWONRVIPPDKH-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 125000003944 tolyl group Chemical group 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- FBHPRUXJQNWTEW-UHFFFAOYSA-N 1-benzyl-2-methylimidazole Chemical compound CC1=NC=CN1CC1=CC=CC=C1 FBHPRUXJQNWTEW-UHFFFAOYSA-N 0.000 description 2
- AXWLKJWVMMAXBD-UHFFFAOYSA-N 1-butylpiperidine Chemical compound CCCCN1CCCCC1 AXWLKJWVMMAXBD-UHFFFAOYSA-N 0.000 description 2
- VTDIWMPYBAVEDY-UHFFFAOYSA-N 1-propylpiperidine Chemical compound CCCN1CCCCC1 VTDIWMPYBAVEDY-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 150000002460 imidazoles Chemical class 0.000 description 2
- 239000008235 industrial water Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
- 150000004885 piperazines Chemical class 0.000 description 2
- 150000003053 piperidines Chemical class 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 150000003217 pyrazoles Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- SZQCPPRPWDXLMM-UHFFFAOYSA-N 1,4-dimethylpyrazole Chemical compound CC=1C=NN(C)C=1 SZQCPPRPWDXLMM-UHFFFAOYSA-N 0.000 description 1
- KKKDZZRICRFGSD-UHFFFAOYSA-N 1-benzylimidazole Chemical compound C1=CN=CN1CC1=CC=CC=C1 KKKDZZRICRFGSD-UHFFFAOYSA-N 0.000 description 1
- AKFHFMMKMUJLBU-UHFFFAOYSA-N 1-benzylimidazole-2-carbaldehyde Chemical compound O=CC1=NC=CN1CC1=CC=CC=C1 AKFHFMMKMUJLBU-UHFFFAOYSA-N 0.000 description 1
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 1
- BBYSGWAYRRMWOW-UHFFFAOYSA-N 1-hexylpiperidine Chemical compound CCCCCCN1CCCCC1 BBYSGWAYRRMWOW-UHFFFAOYSA-N 0.000 description 1
- OQJRUUUFRQCENE-UHFFFAOYSA-N 1-octylpiperidine Chemical compound CCCCCCCCN1CCCCC1 OQJRUUUFRQCENE-UHFFFAOYSA-N 0.000 description 1
- XLXCHZCQTCBUOX-UHFFFAOYSA-N 1-prop-2-enylimidazole Chemical compound C=CCN1C=CN=C1 XLXCHZCQTCBUOX-UHFFFAOYSA-N 0.000 description 1
- RXMTUVIKZRXSSM-UHFFFAOYSA-N 2,2-diphenylethanamine Chemical compound C=1C=CC=CC=1C(CN)C1=CC=CC=C1 RXMTUVIKZRXSSM-UHFFFAOYSA-N 0.000 description 1
- MLPPKQBLCUWNFM-UHFFFAOYSA-N 2-butyl-n,n-dimethylaniline Chemical compound CCCCC1=CC=CC=C1N(C)C MLPPKQBLCUWNFM-UHFFFAOYSA-N 0.000 description 1
- SMDUHNYZAXWZHE-UHFFFAOYSA-N 2-butyl-n-(2-butylphenyl)-n-methylaniline Chemical compound CCCCC1=CC=CC=C1N(C)C1=CC=CC=C1CCCC SMDUHNYZAXWZHE-UHFFFAOYSA-N 0.000 description 1
- SGLADJJYQDGSEJ-UHFFFAOYSA-N 2-ethyl-n,n-dimethylaniline Chemical compound CCC1=CC=CC=C1N(C)C SGLADJJYQDGSEJ-UHFFFAOYSA-N 0.000 description 1
- LWXRTBMZPHXSJG-UHFFFAOYSA-N 2-ethyl-n-(2-ethylphenyl)-n-methylaniline Chemical compound CCC1=CC=CC=C1N(C)C1=CC=CC=C1CC LWXRTBMZPHXSJG-UHFFFAOYSA-N 0.000 description 1
- AMSDWLOANMAILF-UHFFFAOYSA-N 2-imidazol-1-ylethanol Chemical compound OCCN1C=CN=C1 AMSDWLOANMAILF-UHFFFAOYSA-N 0.000 description 1
- XWKFPIODWVPXLX-UHFFFAOYSA-N 2-methyl-5-methylpyridine Natural products CC1=CC=C(C)N=C1 XWKFPIODWVPXLX-UHFFFAOYSA-N 0.000 description 1
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 1
- WFCSWCVEJLETKA-UHFFFAOYSA-N 2-piperazin-1-ylethanol Chemical compound OCCN1CCNCC1 WFCSWCVEJLETKA-UHFFFAOYSA-N 0.000 description 1
- LLEASVZEQBICSN-UHFFFAOYSA-N 2-undecyl-1h-imidazole Chemical compound CCCCCCCCCCCC1=NC=CN1 LLEASVZEQBICSN-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- KISZTEOELCMZPY-UHFFFAOYSA-N 3,3-diphenylpropylamine Chemical compound C=1C=CC=CC=1C(CCN)C1=CC=CC=C1 KISZTEOELCMZPY-UHFFFAOYSA-N 0.000 description 1
- SESYNEDUKZDRJL-UHFFFAOYSA-N 3-(2-methylimidazol-1-yl)propanenitrile Chemical compound CC1=NC=CN1CCC#N SESYNEDUKZDRJL-UHFFFAOYSA-N 0.000 description 1
- BVYPJEBKDLFIDL-UHFFFAOYSA-N 3-(2-phenylimidazol-1-yl)propanenitrile Chemical compound N#CCCN1C=CN=C1C1=CC=CC=C1 BVYPJEBKDLFIDL-UHFFFAOYSA-N 0.000 description 1
- GZYBSURBYCLNSM-UHFFFAOYSA-N 3-anilinopropan-1-ol Chemical compound OCCCNC1=CC=CC=C1 GZYBSURBYCLNSM-UHFFFAOYSA-N 0.000 description 1
- MAAQGZFMFXQVOG-UHFFFAOYSA-N 4,4-diphenylbutan-1-amine Chemical compound C=1C=CC=CC=1C(CCCN)C1=CC=CC=C1 MAAQGZFMFXQVOG-UHFFFAOYSA-N 0.000 description 1
- ZGPMXJWYRKMUHY-UHFFFAOYSA-N 4-anilinobutan-1-ol Chemical compound OCCCCNC1=CC=CC=C1 ZGPMXJWYRKMUHY-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- AZPXDSUNECZBHK-UHFFFAOYSA-N 6,6-diphenylhexan-1-amine Chemical compound C=1C=CC=CC=1C(CCCCCN)C1=CC=CC=C1 AZPXDSUNECZBHK-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical compound N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- DSSKLTAHHALFRW-UHFFFAOYSA-N N-cyclohexylpiperidine Chemical compound C1CCCCC1N1CCCCC1 DSSKLTAHHALFRW-UHFFFAOYSA-N 0.000 description 1
- HTLZVHNRZJPSMI-UHFFFAOYSA-N N-ethylpiperidine Chemical compound CCN1CCCCC1 HTLZVHNRZJPSMI-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010727 cylinder oil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical group C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003269 fluorescent indicator Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Substances C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- LHTGBZMVHWJBQB-UHFFFAOYSA-N n,2-diethylaniline Chemical compound CCNC1=CC=CC=C1CC LHTGBZMVHWJBQB-UHFFFAOYSA-N 0.000 description 1
- IZXSYSCLCVFUOB-UHFFFAOYSA-N n,2-dimethyl-n-(2-methylphenyl)aniline Chemical compound C=1C=CC=C(C)C=1N(C)C1=CC=CC=C1C IZXSYSCLCVFUOB-UHFFFAOYSA-N 0.000 description 1
- GUAWMXYQZKVRCW-UHFFFAOYSA-N n,2-dimethylaniline Chemical compound CNC1=CC=CC=C1C GUAWMXYQZKVRCW-UHFFFAOYSA-N 0.000 description 1
- RQYIRYHWLJKUOM-UHFFFAOYSA-N n,2-dipropylaniline Chemical compound CCCNC1=CC=CC=C1CCC RQYIRYHWLJKUOM-UHFFFAOYSA-N 0.000 description 1
- JDEJGVSZUIJWBM-UHFFFAOYSA-N n,n,2-trimethylaniline Chemical compound CN(C)C1=CC=CC=C1C JDEJGVSZUIJWBM-UHFFFAOYSA-N 0.000 description 1
- CFKKRWVLPRUDFI-UHFFFAOYSA-N n,n-dimethyl-2-propylaniline Chemical compound CCCC1=CC=CC=C1N(C)C CFKKRWVLPRUDFI-UHFFFAOYSA-N 0.000 description 1
- VRUKENOGLFMZNY-UHFFFAOYSA-N n-cyclohexyl-n-phenylaniline Chemical compound C1CCCCC1N(C=1C=CC=CC=1)C1=CC=CC=C1 VRUKENOGLFMZNY-UHFFFAOYSA-N 0.000 description 1
- ZNPPAGQASKRWNT-UHFFFAOYSA-N n-methyl-2-propyl-n-(2-propylphenyl)aniline Chemical compound CCCC1=CC=CC=C1N(C)C1=CC=CC=C1CCC ZNPPAGQASKRWNT-UHFFFAOYSA-N 0.000 description 1
- DYFFAVRFJWYYQO-UHFFFAOYSA-N n-methyl-n-phenylaniline Chemical compound C=1C=CC=CC=1N(C)C1=CC=CC=C1 DYFFAVRFJWYYQO-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002918 oxazolines Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- 239000010723 turbine oil Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/48—Heterocyclic nitrogen compounds the ring containing both nitrogen and oxygen
- C10M133/50—Morpholines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/06—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic nitrogen-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
- C10M2215/224—Imidazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
- C10M2215/226—Morpholines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/24—Emulsion properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
このことからもわかるように、水溶性切削油に求められる性能は冷却性、すなわちそれを活かした加工性である。もし冷却性が不十分であると、加工時に熱が除去されず被削材が工具に溶着して加工不良となる場合がある。また、水溶性切削油剤を安定して使用するために、乳化安定度や耐腐敗性も重視される。乳化安定度が不十分であると、油剤が水と油分に分離してしまい、設計通りの性能を得ることができないだけでなく、切削された金属の摩耗粉が凝集して材料に付着する場合もある。こうなると後工程での除去が必要となるため生産性が低下してしまうこととなる。耐腐敗性も重要な性能で、水を多く含んだ水溶性切削油は菌やカビが繁殖しやすく、腐敗すると性能が低下したり、その臭気により作業環境を大幅に低下させたりすることとなる。
[1]原液組成物全量を基準として、0.3質量%以上7.0質量%以下の芳香族3級アミン類および複素環式3級アミン類から選ばれる少なくとも1種のアミン化合物と、0.1質量%以上5.0質量%以下の水と、70質量%以上98質量%以下の鉱油と、を含有する水溶性切削油剤原液組成物。
[2]前記鉱油中の芳香族成分が10質量%以上である、[1]に記載の水溶性切削油剤原液組成物。
[3]前記複素環式3級アミン類がジモルホリンまたはN−エチルモルホリンである、[1]または[2]に記載の水溶性切削油剤原液組成物。
[4][1]〜[3]のいずれかに記載の水溶性切削油剤原液組成物を水により5倍以上50倍以下に希釈してなる水溶性切削油剤組成物。
[5][4]に記載の水溶性切削油剤組成物を用いて、アルミニウムその合金、銅およびその合金並びに鋼から選ばれる少なくとも1種の金属を含む被削材を切削する、切削加工方法。
本発明の第1実施形態に係る水溶性切削油剤組成物(以下、単に「原液組成物」ともいう。)は、原液組成物全量を基準として、0.3質量%以上7.0質量%以下の芳香族3級アミン類および複素環式3級アミン類から選ばれる少なくとも1種のアミン化合物と、0.1質量%以上5.0質量%以下の水と、70質量%以上98質量%以下の鉱油と、を含有する。
一方、鉱油の含有量は、水溶性切削油剤原液組成物全量基準で98質量%以下であり、93質量%以下が好ましく、90質量%以下が最も好ましい。
鉱油の含有量が上記の範囲内であると、優れた乳化安定度を得ることができる。
一方、鉱油の粘度は150mm2/sec以下が好ましく、100mm2/sec以下がより好ましく、80mm2/sec以下が最も好ましい。粘度が上記の上限値を超えると乳化安定度を損なうおそれがある。
本発明の第2実施形態に係る水溶性切削油剤組成物は、原液組成物全量を基準として、0.3質量%以上7.0質量%以下の芳香族3級アミン類および複素環式3級アミン類から選ばれる少なくとも1種のアミン化合物と、0.1質量%以上5.0質量%以下の水と、70質量%以上98質量%以下の鉱油と、を含有する水溶性切削油剤原液組成物を、水により5倍以上50倍以下に希釈してなる。なお、本実施形態における水溶性切削油剤原液組成物は、上記第1実施形態に係る水溶性切削油剤原液組成物と同様であり、ここでは重複する説明を省略する。
本発明の第3実施形態に係る切削加工方法は、原液組成物全量を基準として、0.3質量%以上7.0質量%以下の芳香族3級アミン類および複素環式3級アミン類から選ばれる少なくとも1種のアミン化合物と、0.1質量%以上5.0質量%以下の水と、70質量%以上98質量%以下の鉱油と、を含有する水溶性切削油剤原液組成物を、水により5倍以上50倍以下に希釈してなる水溶性切削油剤組成物を用いて、アルミニウムその合金、銅およびその合金並びに鋼から選ばれる少なくとも1種の金属を含む被削材を切削する工程を備える。なお、本実施形態における水溶性切削油剤原液組成物および水溶性切削油剤組成物は、それぞれ上記第1実施形態に係る水溶性切削油剤原油組成物および上記第2実施形態に係る水溶性切削油剤組成物と同様であり、ここでは重複する説明を省略する。
実施例1〜27および比較例1〜10においては、それぞれ以下に示すアミン化合物A1〜A10、鉱油B1〜B8、その他の添加剤C1〜C5、ならびに水(アメリカ硬度64)を用いて、表1〜4に示す組成を有する水溶性切削油剤原液組成物を調製した。
A1:トリ(メチルフェニル)アミン
A2:N,N’−ジメチル−4−アミノピリジン
A3:1−ベンジル−2−フェニルイミダゾール
A4:ピラゾール
A5:ジモルホリン
A6:4−(2−ヒドロキシエチル)モルホリン
A7:N−エチルモルホリン
A8:N,N’−ジメチルピペラジン
A9:N−(2−ヒドロキシエチル)ピペリジン
A10:トリエタノールアミン
B1:鉱油(40℃における動粘度24mm2/sec、芳香族分12質量%)
B2:鉱油(40℃における動粘度22mm2/sec、芳香族分22質量%)
B3:鉱油(40℃における動粘度93mm2/sec、芳香族分14質量%)
B4:鉱油(40℃における動粘度3.4mm2/sec、芳香族分12質量%)
B5:鉱油(40℃における動粘度144mm2/sec、芳香族分14質量%)
B6:鉱油(40℃における動粘度27mm2/sec、芳香族分6.7質量%)
B7:鉱油(40℃における動粘度1.2mm2/sec、芳香族分13質量%)
B8:鉱油(40℃における動粘度162mm2/sec、芳香族分14質量%)
C1:ナトリウムスルホネート
C2:オレイン酸カリウム
C3:ポリエチレングリコール(平均重合度12)
C4:ポリエチレングリコール(平均重合度4.5)のオレイン酸モノエステル
C5:シリコーンオイル
JIS K2241 乳化安定度試験に準拠して評価を行った。ただし、希釈水は水道水(アメリカ硬度64)を使用した。また、希釈倍率は10倍(原液濃度10%)とし乳化後24時間での油層とクリーム層の合計で評価した。なお、実施例27では希釈倍率を50倍(2%)(体積比。カッコ内の数値は切削油剤組成物全量基準での原液組成物の含有量を意味する。)として同様に評価を行った。本試験における評価基準は以下のとおりである。得られた結果を表1〜4に示す。
A;油層とクリーム層の合計が1mL未満
B:油層とクリーム層の合計が1mL以上2mL未満
C:油層とクリーム層の合計が2mL以上3mL未満
D:油層とクリーム層の合計が3mL以上4mL未満
E:油層とクリーム層の合計が4mL以上5mL未満
F:油層とクリーム層の合計が5mL以上
水道水(アメリカ硬度64)を用いて原液組成物を20倍に希釈して油剤組成物を調製した。次に、油剤組成物300mLに種菌(需要家で使用され腐敗した油剤、総菌数107個/mL以上)15gを添加し、30℃にて60回転/分で撹拌した。7日後に油剤の総菌数を三愛石油(株)三愛バイオチェッカーTTCにて測定した。基準油としてJX日鉱日石エネルギー(株)ユニソルブルEM−L(20倍希釈)についても同様の試験を行い、総菌数を比較した。なお、実施例27では原液組成物を50倍(2%)(体積比。カッコ内の数値は切削油剤組成物全量基準での原液組成物の含有量を意味する。)に希釈した油剤組成物として同様に評価を行った。本試験における評価基準は以下のとおりである。得られた結果を表1〜4に示す。
A:総菌数が基準油よりも少ない
B:総菌数が基準油と同等
C:総菌数が基準油よりも多い
転造タップによるタッピング評価試験によりタッピングエネルギー効率(TEE)を求めることにより評価した。
材料はアルミニウム(AC8A)で行った。
工具はOSG社製 B−NRT B M8(ピッチ1.25)を用い、7.4mmの下穴に対し回転数360回転/分、送り速度9m/分で加工評価を実施した。
なお、基準油はJX日鉱日石エネルギー(株)ユニソルブルEM−Lとし、基準油、評価油ともに水道水にて20倍に希釈したものを使用した。
タッピングエネルギー効率とは基準油のタッピングエネルギー(加工時のトルク積分値)を評価油のタッピングエネルギーで割った値であり、下記式:
(タッピングエネルギー効率、%)=(基準油のタッピングエネルギー/試験油のタッピングエネルギー)×100
により定義される。タッピングエネルギー効率が100を超える油剤組成物は、基準油よりも加工性が良いことになる。本試験における評価基準は以下のとおりである。得られた結果を表1〜4に示す。
A:タッピングエネルギー効率が110以上
B:タッピングエネルギー効率が110未満105以上
C:タッピングエネルギー効率が105未満95以上
D:タッピングエネルギー効率が95未満
Claims (4)
- 原液組成物全量を基準として、
0.3質量%以上7.0質量%以下の芳香族3級アミン類および複素環式3級アミン類から選ばれる少なくとも1種のアミン化合物と、
0.1質量%以上5.0質量%以下の水と、
80質量%以上98質量%以下の鉱油と、を含有し、
前記鉱油中の芳香族分が10質量%以上であり、
前記鉱油の40℃における動粘度が5mm 2 /sec以上150mm 2 /sec以下である、水溶性切削油剤原液組成物。 - 前記複素環式3級アミン類がジモルホリンまたはN−エチルモルホリンである、請求項1に記載の水溶性切削油剤原液組成物。
- 請求項1又は2に記載の水溶性切削油剤原液組成物を水により5倍以上50倍以下(体積比)に希釈してなる、水溶性切削油剤組成物。
- 請求項3に記載の水溶性切削油剤組成物を用いて、アルミニウムその合金、銅およびその合金並びに鋼から選ばれる少なくとも1種の金属を含む被削材を切削する、切削加工方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013209985 | 2013-10-07 | ||
JP2013209985 | 2013-10-07 | ||
PCT/JP2014/076569 WO2015053192A1 (ja) | 2013-10-07 | 2014-10-03 | 水溶性切削油剤原液組成物、切削油剤組成物および切削加工方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2015053192A1 JPWO2015053192A1 (ja) | 2017-03-09 |
JP6488235B2 true JP6488235B2 (ja) | 2019-03-20 |
Family
ID=52813008
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015541554A Active JP6488235B2 (ja) | 2013-10-07 | 2014-10-03 | 水溶性切削油剤原液組成物、切削油剤組成物および切削加工方法 |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP6488235B2 (ja) |
CN (1) | CN105612247B (ja) |
SG (1) | SG11201602660WA (ja) |
TW (1) | TWI649416B (ja) |
WO (1) | WO2015053192A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102062341B1 (ko) * | 2017-06-01 | 2020-01-03 | 영창케미칼 주식회사 | 절삭유 조성물 및 그를 이용한 절삭방법 |
WO2018221972A2 (ko) * | 2017-06-01 | 2018-12-06 | 영창케미칼 주식회사 | 절삭유 조성물 |
CN112940833A (zh) * | 2021-02-09 | 2021-06-11 | 上海应用技术大学 | 一种长寿环保切削液及其制备方法 |
JP2023063105A (ja) * | 2021-10-22 | 2023-05-09 | Eneos株式会社 | 水溶性加工油組成物、及び、金属加工方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62292896A (ja) * | 1986-06-12 | 1987-12-19 | Idemitsu Kosan Co Ltd | 水系潤滑剤用添加剤 |
JP2510233B2 (ja) * | 1988-02-05 | 1996-06-26 | 協同油脂株式会社 | 水溶性金属加工油剤 |
JPH02242892A (ja) * | 1989-03-16 | 1990-09-27 | Yushiro Chem Ind Co Ltd | 抗菌性水溶性切削油剤 |
JPH04214796A (ja) * | 1990-12-14 | 1992-08-05 | Yushiro Chem Ind Co Ltd | 水溶性切研削用油剤 |
JP5291292B2 (ja) * | 2007-02-01 | 2013-09-18 | 協同油脂株式会社 | 金属加工用油剤及び金属加工方法 |
-
2014
- 2014-10-03 JP JP2015541554A patent/JP6488235B2/ja active Active
- 2014-10-03 SG SG11201602660WA patent/SG11201602660WA/en unknown
- 2014-10-03 WO PCT/JP2014/076569 patent/WO2015053192A1/ja active Application Filing
- 2014-10-03 CN CN201480055102.1A patent/CN105612247B/zh active Active
- 2014-10-07 TW TW103134933A patent/TWI649416B/zh active
Also Published As
Publication number | Publication date |
---|---|
WO2015053192A1 (ja) | 2015-04-16 |
SG11201602660WA (en) | 2016-05-30 |
TW201518496A (zh) | 2015-05-16 |
CN105612247A (zh) | 2016-05-25 |
CN105612247B (zh) | 2018-07-24 |
JPWO2015053192A1 (ja) | 2017-03-09 |
TWI649416B (zh) | 2019-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101104831B (zh) | 微乳化型不锈钢切削液 | |
EP2928992B1 (en) | Additive compositions and industrial process fluids | |
CN103215115B (zh) | 一种用于金属加工的水溶性高效微乳切削液 | |
EP3394230B1 (en) | Metalworking fluid | |
CN106118834A (zh) | 一种使用寿命长的铝合金切削液及其制备方法 | |
JP6488235B2 (ja) | 水溶性切削油剤原液組成物、切削油剤組成物および切削加工方法 | |
CN106281616A (zh) | 一种铝合金切削加工用长寿命低泡乳化液 | |
CN105670738A (zh) | 一种防锈乳化型金属切削液 | |
CN105154187A (zh) | 一种可替代油品的乳化液及其制备方法 | |
CN107502437B (zh) | 一种用于不锈钢半合成型水溶性切削液及其制备方法 | |
CN111909770A (zh) | 全合成高润滑金属加工液、其制备方法及用途 | |
CN107446681A (zh) | 一种微乳化型水溶性金属切削液及其制备方法 | |
CN104403769A (zh) | 一种多功能切削液及其制备方法 | |
CN108517251A (zh) | 一种水性环保切削液及制备方法 | |
CN108949332B (zh) | 一种汽车空调滤清器盖板的环保型攻丝液的制备方法及环保型攻丝液 | |
KR101794618B1 (ko) | 물에 대한 용해성 및 윤활성이 우수한 수용성 절삭유 | |
CN103351914A (zh) | 一种水溶性切削液 | |
CN106221882A (zh) | 一种防锈切削液 | |
JP2011074186A (ja) | 水溶性金属加工油剤 | |
US11396708B2 (en) | Water soluble metalworking concentrate | |
JP4005204B2 (ja) | 超硬合金用水溶性切削研削油剤 | |
JP4480981B2 (ja) | 水溶性金属加工油剤組成物 | |
CN107573994A (zh) | 一种具有防锈效果的金属切削油 | |
JP2006265409A (ja) | 水溶性金属加工液 | |
CZ306189B6 (cs) | Způsob modifikace průmyslově dodávané chladicí a/nebo mazací procesní kapaliny užívané v průběhu třískového obrábění kovových materiálů |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170627 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180814 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180926 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190205 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190225 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6488235 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |