JP6448621B2 - セキュリティ要素、及びその製造方法 - Google Patents
セキュリティ要素、及びその製造方法 Download PDFInfo
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- JP6448621B2 JP6448621B2 JP2016514345A JP2016514345A JP6448621B2 JP 6448621 B2 JP6448621 B2 JP 6448621B2 JP 2016514345 A JP2016514345 A JP 2016514345A JP 2016514345 A JP2016514345 A JP 2016514345A JP 6448621 B2 JP6448621 B2 JP 6448621B2
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- coating
- liquid crystal
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- resin
- security element
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- 229920002521 macromolecule Polymers 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 239000000434 metal complex dye Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910001511 metal iodide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- WAAGUMJODZOKDE-UHFFFAOYSA-N methyl 2-(4-benzoylphenoxy)acetate Chemical compound C1=CC(OCC(=O)OC)=CC=C1C(=O)C1=CC=CC=C1 WAAGUMJODZOKDE-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- IZRZMBCKGLWYSC-UHFFFAOYSA-N n'-(2-aminoethyl)ethane-1,2-diamine;2-methylprop-2-enamide Chemical compound CC(=C)C(N)=O.CC(=C)C(N)=O.CC(=C)C(N)=O.NCCNCCN IZRZMBCKGLWYSC-UHFFFAOYSA-N 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- BYJPRUDFDZPCBH-UHFFFAOYSA-N n-[2-(2-hydroxyethoxy)ethyl]prop-2-enamide Chemical compound OCCOCCNC(=O)C=C BYJPRUDFDZPCBH-UHFFFAOYSA-N 0.000 description 1
- YQCFXPARMSSRRK-UHFFFAOYSA-N n-[6-(prop-2-enoylamino)hexyl]prop-2-enamide Chemical compound C=CC(=O)NCCCCCCNC(=O)C=C YQCFXPARMSSRRK-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000004843 novolac epoxy resin Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003606 oligomerizing effect Effects 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 238000009304 pastoral farming Methods 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 230000002165 photosensitisation Effects 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 238000002198 surface plasmon resonance spectroscopy Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/148—Transitory images, i.e. images only visible from certain viewing angles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/328—Diffraction gratings; Holograms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/364—Liquid crystals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/373—Metallic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
- C09D101/16—Esters of inorganic acids
- C09D101/18—Cellulose nitrate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- Engineering & Computer Science (AREA)
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- Crystallography & Structural Chemistry (AREA)
- Finance (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Business, Economics & Management (AREA)
- Accounting & Taxation (AREA)
- Medicinal Chemistry (AREA)
- Credit Cards Or The Like (AREA)
- Laminated Bodies (AREA)
- Holo Graphy (AREA)
- Polarising Elements (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Diffracting Gratings Or Hologram Optical Elements (AREA)
Description
a)基材
b)前記基材の少なくとも一部にある、少なくとも1種の液晶化合物を含有する被覆、
この被覆は、前記基材が透明若しくは半透明であれば、前記基材の裏側に適用されているか、又は
前記基材が透明、半透明、反射性、又は不透明であれば、表側に適用されており、
c)前記液晶化合物を含有する被覆の少なくとも一部に、又は前記液晶化合物を含有する被覆が、前記基材の裏側に配置されている場合には、前記基材に直接、さらなる被覆、
を有するセキュリティ要素であり、
前記さらなる被覆は、フレーク形状の遷移金属粒子を含有し、この遷移金属粒子は最長の辺の長さの寸法が5nm〜1000nm、好ましくは5nm〜600nm、特に10nm〜500nmであり、かつその厚さが2nm〜100nm、好ましくは2〜40nm、特に4〜30nmである。
a)透明、半透明、反射性、若しくは不透明の基材、
b)前記基材の少なくとも一部にある、少なくとも1種の液晶化合物を含有する被覆、
c)前記液晶化合物を含有する被覆の少なくとも一部にあるさらなる被覆、このさらなる被覆は、フレーク形状の遷移金属粒子を含有し、この遷移金属粒子は最長の辺の長さの寸法が5nm〜1000nm、好ましくは5nm〜600nm、特に10nm〜500nmであり、かつその厚さが2nm〜100nm、好ましくは2〜40nm、特に4〜30nmである。
具体的な例は、ビス(2,4,6−トリメチルベンゾイル)−フェニルホスフィンオキシド(lrgacure(登録商標)819)、2,4,6−トリメチルベンゾイル−ジフェニル−ホスフィンオキシド(Darocur(登録商標)TPO)、エチル(2,4,6−トリメチルベンゾイルフェニル)ホスフィン酸エステル、(2,4,6−トリメチルベンゾイル)−2,4−ジペントキシフェニルホスフィンオキシド、ビス(2,6−ジメトキシベンゾイル)−2,4,4−トリメチルペンチルホスフィンオキシドである。
具体的な例は、Darocur(登録商標)BP(=ベンゾフェノン)、Lamberti社製のEsacure TZT(登録商標)(2,4,6−トリメチルベンゾフェノンと4−メチルベンゾフェノンとの混合物)、4−フェニルベンゾフェノン、4−メトキシベンゾフェノン、4,4’−ジメトキシベンゾフェノン、4,4’−ジメチルベンゾフェノン、4,4’−ジクロロベンゾフェノン、4,4’−ジメチルアミノベンゾフェノン、4,4’−ジエチルアミノベンゾフェノン、4−メチルベンゾフェノン、2,4,6−トリメチルベンゾフェノン、4−(4−メチルチオフェニル)ベンゾフェノン、3,3’−ジメチル−4−メトキシベンゾフェノン、メチル−2−ベンゾイルベンゾエート、4−(2−ヒドロキシエチルチオ)ベンゾフェノン、4−(4−トルイルチオ)ベンゾフェノン、4−ベンゾイル−N,N,N−トリメチルベンゼンメタンアミニウムクロリド、2−ヒドロキシ−3−(4−ベンゾイルフェノキシ)−N,N,N−トリメチル−1−プロパンアミニウムクロリド一水和物、4−(13−アクリロイル−1,4,7,10,13−ペンタオキサトリデシル)ベンゾフェノン、4−ベンゾイル−N,N−ジメチル−N−[2−(1−オキソ−2−プロペニル)オキシ]エチルベンゼンメタンアミニウムクロリド、[4−(2−ヒドロキシ−エチルスルファニル)−フェニル]−(4−イソプロピルフェニル)−メタノン、ビフェニル−[4−(2−ヒドロキシ−エチルスルファニル)−フェニル]−メタノン、ビフェニル−4−イル−フェニル−メタノン、ビフェニル−4−イル−p−トルイル−メタノン、ビフェニル−4−イル−m−トルイル−メタノン、[4−(2−ヒドロキシ−エチルファニル)−フェニル]−p−トルイル−メタノン、[4−(2−ヒドロキシエチルスルファニル)−フェニル]−(4−イソプロピル−フェニル)−メタノン、[4−(2−ヒドロキシ−エチルスルファニル)−フェニル]−(4−メトキシ−フェニル)−メタノン、1−(4−ベンゾイル−フェノキシ)−プロパン−2−オン、[4−(2−ヒドロキシ−エチルスルファニル)−フェニル]−(4−フェノキシ−フェニル)−メタノン、3−(4−ベンゾイル−フェニル)−2−ジメチルアミノ−2−メチル−1−フェニル−プロパン−1−オン、(4−クロロ−フェニル)−(4−オクチルスルファニル−フェニル)−メタノン、(4−クロロ−フェニル)−(4−ドデシルスルファニル−フェニル)−メタノン、(4−ブロモ−フェニル)−(4−オクチルスルファニル−フェニル)−メタノン、(4−ドデシルスルファニル−フェニル)−(4−メトキシ−フェニル)−メタノン、(4−ベンゾイル−フェノキシ)酢酸メチルエステル、ビフェニル−[4−(2−ヒドロキシ−エチルスルファニル)−フェニル]−メタノン、1−[4−(4−ベンゾイルフェニルスルファニル)フェニル]−2−メチル−2−(4−メチルフェニルスルホニル)プロパン−1−オン(Lamberti社製のEsacure(登録商標)1001)である。
・N,N,N−トリブチル−1−ブタンアミニウムブチルトリフェニルボレート(120307-06-4)
・N−エチル−N−[4−[1,5,5−トリス[4−(ジエチルアミノ)フェニル]−2,4−ペンタジエン−1−イリデン]−2,5−シクロヘキサジエン−1−イリデン]−エタンアミニウムブチルトリフェニルボレート(141714-54-7)
・N,N,N−トリメチル−メタンアミニウム、ブチルトリフェニルボレート(117522-01-7)
・N,N,N−トリブチル−1−ブタンアミニウム、ブチルトリ−1−ナフタレニルボレート(219125-19-6)
・N,N,N−トリブチル−1−ブタンアミニウム、トリス(3−フルオロフェニル)ヘキシルボレート(191726-69-9)
・N,N,N−トリブチル−1−ブタンアミニウム、トリス(3−フルオロフェニル)(フェニルメチル)ボレート(199127-03-2)
・ジメチル−(2−オキソ−2−フェニルエチル)−スルホニウム、ブチルトリフェニルボレート(153148-27-7)
・N,N,N−トリブチル−1−ブタンアミニウム、トリス(5−フルオロ−2−メチルフェニル)ヘキシルボレート(225107-27-7)
・1−ヘプチル−2−[3−(1−ヘプチル−1,3−ジヒドロ−3,3−ジメチル−2H−インドール−2−イリデン)−1−プロペン−1−イル]−3,3−ジメチル−3H−インドリウム、ブチルトリフェニルボレート(17522-03-9)
・ブチルトリフェニルボレート、リチウム(65859-86-1)。
中圧水銀アークは、スペクトル出力を変えるため、金属ハロゲン化物を少量で取り込むことにより修正する。
・鉄ドープしたもの、スペクトル出力は、350〜450nmにシフト
・ガリウムドープしたもの、紫外線をごく僅かに放出、紫、及び青のスペクトル領域における放出(金属ヨウ化物により水銀アークを以下の波長(nm)でドープすることにより予測されたさらなる紫外線:ガリウム(Ga)403、417、及び鉄(Fe)358、372、374/5、382、386、388)、及び焦点反射型ダイオードアレイ(FRDA)システム(igb-tech GmbH)、例えば約400nmの放射ピークを有するFRDA 202である。マルチスペクトルランプも使用できる。
a)少なくとも1種の液晶化合物を含有する基材の少なくとも一部に被覆を堆積させる工程、この被覆は、前記基材が透明、又は半透明である場合、前記基材の裏側に適用されているか、又は
前記基材が透明、半透明、反射性、又は不透明である場合、表側に適用されており、
b)液晶化合物を含有する被覆の少なくとも一部に、又は液晶化合物を含有する被覆が、前記基材の裏側に配置されている場合には、前記基材に直接、さらに被覆する工程、
を有する上記セキュリティ要素の製造方法であり、
さらなる被覆は、フレーク形状の遷移金属粒子を含有し、この遷移金属粒子は最長の辺の長さの寸法が5nm〜1000nm、好ましくは5nm〜600nm、特に10nm〜500nmであり、前記遷移金属粒子は厚さが2nm〜100nm、好ましくは2〜40nm、特に4〜30nmである。
この製造は、国際公開第2011/064162号(WO2011/064162)の例1に従って行う。この析出物を、選択したいずれかの溶媒(水、メタノール、エチルアセテート、シクロヘキサノン、メトキシプロパノールを含む)に分散させ、銀フレークを20%含有する分散液を得る。
この製造は、国際公開第2011/064162号(WO2011/064162)の例5に従って行う。この析出物を、選択したいずれかの溶媒(水、メタノール、エチルアセテート、シクロヘキサノン、メトキシプロパノールを含む)に分散させ、銀フレークを20%含有する分散液を得る。
液晶被覆を欧州特許第1078975号明細書(EP 1 0789 75 B1)の例1に従って、二軸延伸ポリエステルテレフタレート(PET)基材上に作製する。最適化された色彩効果を有するコレステリック被覆材料を使用する。被覆の厚さは、3.0μmである。カラーフロップは、キラル化合物の量次第である。
青・金のインク作製:ニトロセルロース(DHX 3/5 IPA、固体分70%(Nobel Enterprises、英国))を、250mlのガラス瓶内の酢酸エチル(Brenntag社製で純度99〜100%)71.4gにゆっくりと添加し、室温で完全に溶解するまで穏やかに撹拌する。それから固体含分の測定を行い、酢酸エチルの量を、ワニス調製物中で固体含分が19.6%の値になるよう調整する。メタリックインク調製のための一般的な手順:銀顔料分散液10.0g(酢酸エチル中で得られる顔料粒子の19.6%)を、顔料対結合剤の比が1:1になるような割合で、上記ワニス10gに添加する。得られた分散液をDispermatで800rpmで10分間撹拌し、ワイヤーバー1で被覆したメタリックインク(湿潤塗膜で6ミクロン)を液晶で被覆されたフィルム上に得て、空気乾燥させる。
・黒色に重ねた印刷面での測定
・白色に重ねた印刷面での測定
・黒色に重ねた裏面での測定
・白色に重ねた裏面での測定
青・金のインクは、例1と同様に製造する。このインクをワイヤーバー1により、例1に示した液晶で被覆したフィルムに被覆し(6ミクロンの湿潤フィルム)、空気乾燥させる。
・黒色に重ねた印刷面での測定
・白色に重ねた印刷面での測定
・黒色に重ねた裏面での測定
・白色に重ねた裏面での測定
反射時に緑色で、透過時にマゼンダのメタリックコーティングを、二軸配向性PETフィルム(Lumirror)上の緑〜青の液晶被覆に被覆する。
400nm〜1700nm、角度0°及び45°での透過時の測定、400nm〜1020nmについてはZeiss MCS 501の分析光度計で、1020nm〜1700nmについてはZiess MCR 511分光光度計で行う。
角度0°及び45°で400nm〜1700nmにおける透過性の測定
・黒色に重ねた印刷面での測定
・白色に重ねた印刷面での測定
・黒色に重ねた裏面での測定
・白色に重ねた裏面での測定
Claims (13)
- 以下のa)、b)、及びc):
a)透明、又は半透明な基材、
b)前記基材の少なくとも一部にある、少なくとも1種の液晶化合物を含有する被覆、
前記被覆は、
前記基材の裏側に適用されているか、又は表側に適用されており、
c)前記液晶化合物を含有する被覆の少なくとも一部に、又は前記液晶化合物を含有する被覆を前記基材の裏側に配置する場合には前記基材に直接、さらなる被覆、
を有するセキュリティ要素であって、
前記さらなる被覆は、フレーク形状の遷移金属粒子を有し、当該遷移金属粒子の最長の辺の長さの寸法が5nm〜1000nmであり、前記遷移金属粒子の厚さが2nm〜100nmであり、
前記金属がCu及びAgから選択される、前記セキュリティ要素。 - 以下のa)、b)、及びc):
a)透明、又は半透明な基材、
b)前記基材の少なくとも一部にある、少なくとも1種の液晶化合物を含有する被覆、
前記被覆は、前記基材の裏側に適用されており、および
c)前記基材に直接、さらなる被覆、
を有する、請求項1に記載のセキュリティ要素。 - 前記基材、前記液晶化合物を含有する被覆、前記金属粒子を含有するさらなる被覆、又はこれらのうち2つ若しくは3つがさらに、エンボス加工された表面レリーフマイクロ構造、特に光学可変イメージ(光学可変デバイス:OVD)を有する、請求項1または2に記載のセキュリティ要素。
- 前記形状の遷移金属粒子は、最長の辺の長さの寸法が5〜1000nmであり、厚さが2〜100nmであり、六角形状、及び/又は三角形状、及び/又は切欠を有する三角形状のプリズムを有し、当該プリズムが、前記形状の遷移金属粒子の合計数の20%超となる、請求項1から3までのいずれか1項に記載のセキュリティ要素。
- 構成要素c)の被覆が、ニトロセルロース、エチルセルロース、酢酸セルロース、セルロースアセテートプロピオネート(CAP)、セルロースアセテートブチレート(CAB)、アルコール可溶性プロピオネート(ASP)、塩化ビニル、酢酸ビニルコポリマー、酢酸ビニル、ビニル樹脂、アクリル酸樹脂、ポリウレタン樹脂、ポリアミド樹脂、ロジンエステル樹脂、炭化水素樹脂、アルデヒド樹脂、ケトン樹脂、ウレタン樹脂、ポリエチレンテレフタレート樹脂、テルペンフェノール樹脂、ポリオレフィン樹脂、シリコーン樹脂、セルロース樹脂、ポリアミド樹脂、ポリエステル樹脂、及びロジンエステル樹脂から成る群から選択される結合剤を含有するか、又は、
構成要素c)の被覆が、少なくとも1種のエチレン系不飽和モノマー及び/又はオリゴマー、並びに少なくとも1種の光開始剤を含有する光重合性組成物である、
請求項1から4までのいずれか1項に記載のセキュリティ要素。 - 前記基材が、ガラス、プラスチック、若しくは紙、又はこれらの混合物を含有する、請求項1から5までのいずれか1項に記載のセキュリティ要素。
- 前記液晶化合物が、光開始剤の存在下で紫外線の照射により重合/架橋されたオリゴマー又はポリマーである、請求項1から6までのいずれか1項に記載のセキュリティ要素。
- 以下の工程a)及びb):
a)基材の少なくとも一部に、少なくとも1種の液晶化合物を含有する被覆を堆積させる工程、前記被覆は、前記基材の裏側に適用されており、又は表側に適用されており、
b)前記液晶化合物を含有する被覆の少なくとも一部に、又は前記液晶化合物を含有する被覆が前記基材の裏側に配置されていれば、前記基材に直接、さらに被覆する工程、
を有する、請求項1のセキュリティ要素を製造するための方法であって、
さらなる被覆は、フレーク形状の遷移金属粒子を含有し、当該遷移金属粒子の最長の辺の長さの寸法は5nm〜1000nmであり、前記遷移金属粒子の厚さは2nm〜100nmであり、
前記金属がCu及びAgから選択される、前記方法。 - 液晶化合物を含有する被覆である構成要素a)の厚さが、乾燥状態又は硬化状態で0.1μm〜100μmである、請求項8に記載の方法。
- 金属粒子を含有する被覆である構成要素b)の厚さが、乾燥状態又は硬化状態で0.2μm〜50μmである、請求項8に記載の方法。
- 製造された前記セキュリティ要素が、見た角度に応じて色を変える、請求項8に記載の方法。
- 紙幣、クレジットカード、認証文書、例えば旅券、IDカード、運転免許証、若しくはその他の確認文書、医薬用衣類、ソフトウェア、コンパクトディスク、タバコの包装、及びその他の製品、又は偽造若しくは模造されやすい包装を包含する、請求項1から7までのいずれか1項に記載のセキュリティ要素を有するセキュリティ製品。
- 有価文書、権利文書、認証文書、セキュリティベル、又はブランド品について偽造若しくは複製を防止するための、請求項1から7までのいずれか1項に記載のセキュリティ要素の使用。
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AU2014270602A1 (en) | 2015-12-10 |
CN105392851B (zh) | 2018-09-11 |
CN105392851A (zh) | 2016-03-09 |
RU2015154519A (ru) | 2017-06-22 |
RU2663063C2 (ru) | 2018-08-01 |
BR112015028902A2 (pt) | 2017-07-25 |
AU2014270602B2 (en) | 2017-07-13 |
US10252561B2 (en) | 2019-04-09 |
JP2016531016A (ja) | 2016-10-06 |
WO2014187750A1 (en) | 2014-11-27 |
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