JP6438411B2 - 刺激緩和ポリマーおよびその使用 - Google Patents

Info

Publication number

JP6438411B2

JP6438411B2 JP2015549491A JP2015549491A JP6438411B2 JP 6438411 B2 JP6438411 B2 JP 6438411B2 JP 2015549491 A JP2015549491 A JP 2015549491A JP 2015549491 A JP2015549491 A JP 2015549491A JP 6438411 B2 JP6438411 B2 JP 6438411B2

Authority

JP

Japan

Prior art keywords

vinyl

meth

acrylate

composition

monomer

Prior art date

2012-12-20

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Fee Related

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• 229920000642 polymer Polymers 0.000 title claims description 174
• 230000000116 mitigating effect Effects 0.000 title description 2
• 239000000203 mixture Substances 0.000 claims description 284
• 239000000178 monomer Substances 0.000 claims description 261
• -1 2-ethylhexyl Chemical group 0.000 claims description 133
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 125
• 239000004094 surface-active agent Substances 0.000 claims description 108
• 238000004140 cleaning Methods 0.000 claims description 92
• 125000000217 alkyl group Chemical group 0.000 claims description 87
• 238000000034 method Methods 0.000 claims description 79
• 239000003945 anionic surfactant Substances 0.000 claims description 57
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 47
• 239000000047 product Substances 0.000 claims description 40
• 229920002554 vinyl polymer Polymers 0.000 claims description 37
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
• 239000002280 amphoteric surfactant Substances 0.000 claims description 32
• 239000001257 hydrogen Substances 0.000 claims description 28
• 229910052739 hydrogen Inorganic materials 0.000 claims description 28
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 25
• 229920001223 polyethylene glycol Polymers 0.000 claims description 22
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 21
• 239000003381 stabilizer Substances 0.000 claims description 20
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 19
• 238000007046 ethoxylation reaction Methods 0.000 claims description 19
• 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 18
• 239000002202 Polyethylene glycol Substances 0.000 claims description 16
• 239000007788 liquid Substances 0.000 claims description 16
• 206010040880 Skin irritation Diseases 0.000 claims description 15
• 231100000475 skin irritation Toxicity 0.000 claims description 15
• 239000011734 sodium Substances 0.000 claims description 15
• 229910052708 sodium Inorganic materials 0.000 claims description 15
• 229940083542 sodium Drugs 0.000 claims description 15
• 229920001567 vinyl ester resin Polymers 0.000 claims description 15
• 150000003254 radicals Chemical class 0.000 claims description 14
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
• WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 12
• 239000003599 detergent Substances 0.000 claims description 12
• 239000004815 dispersion polymer Substances 0.000 claims description 12
• 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
• 230000008569 process Effects 0.000 claims description 11
• XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 10
• 230000036556 skin irritation Effects 0.000 claims description 10
• 206010015946 Eye irritation Diseases 0.000 claims description 9
• 125000002947 alkylene group Chemical group 0.000 claims description 9
• 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 9
• CMDXMIHZUJPRHG-UHFFFAOYSA-N ethenyl decanoate Chemical compound CCCCCCCCCC(=O)OC=C CMDXMIHZUJPRHG-UHFFFAOYSA-N 0.000 claims description 9
• 231100000013 eye irritation Toxicity 0.000 claims description 9
• 150000002734 metacrylic acid derivatives Polymers 0.000 claims description 9
• HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims description 9
• 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 9
• 239000002453 shampoo Substances 0.000 claims description 9
• 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 9
• 125000003118 aryl group Chemical group 0.000 claims description 8
• 150000002148 esters Chemical class 0.000 claims description 8
• 229920001577 copolymer Polymers 0.000 claims description 7
• WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 claims description 7
• TVFJAZCVMOXQRK-UHFFFAOYSA-N ethenyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OC=C TVFJAZCVMOXQRK-UHFFFAOYSA-N 0.000 claims description 7
• MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 claims description 7
• GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 claims description 7
• UJRIYYLGNDXVTA-UHFFFAOYSA-N ethenyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OC=C UJRIYYLGNDXVTA-UHFFFAOYSA-N 0.000 claims description 7
• LZWYWAIOTBEZFN-UHFFFAOYSA-N ethenyl hexanoate Chemical compound CCCCCC(=O)OC=C LZWYWAIOTBEZFN-UHFFFAOYSA-N 0.000 claims description 7
• NWJTZFZQVYJIHU-UHFFFAOYSA-N ethenyl nonanoate Chemical compound CCCCCCCCC(=O)OC=C NWJTZFZQVYJIHU-UHFFFAOYSA-N 0.000 claims description 7
• AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 claims description 7
• BLZSRIYYOIZLJL-UHFFFAOYSA-N ethenyl pentanoate Chemical compound CCCCC(=O)OC=C BLZSRIYYOIZLJL-UHFFFAOYSA-N 0.000 claims description 7
• UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims description 7
• WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 6
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
• 239000007795 chemical reaction product Substances 0.000 claims description 6
• GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical group CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 6
• IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 claims description 6
• RASNHPFIOGUOOT-UHFFFAOYSA-N ethenyl 6-methylheptanoate Chemical compound CC(C)CCCCC(=O)OC=C RASNHPFIOGUOOT-UHFFFAOYSA-N 0.000 claims description 6
• 229920005862 polyol Polymers 0.000 claims description 6
• FYRWKWGEFZTOQI-UHFFFAOYSA-N 3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propan-1-ol Chemical group C=CCOCC(CO)(COCC=C)COCC=C FYRWKWGEFZTOQI-UHFFFAOYSA-N 0.000 claims description 5
• 239000004971 Cross linker Substances 0.000 claims description 5
• 150000003863 ammonium salts Chemical class 0.000 claims description 5
• MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims description 5
• 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
• MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical group CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 5
• 229940043264 dodecyl sulfate Drugs 0.000 claims description 5
• 125000002819 montanyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
• 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
• 150000003077 polyols Chemical class 0.000 claims description 5
• 239000000344 soap Substances 0.000 claims description 5
• 125000001424 substituent group Chemical group 0.000 claims description 5
• 125000003545 alkoxy group Chemical group 0.000 claims description 4
• 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 4
• 239000003431 cross linking reagent Substances 0.000 claims description 4
• SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical class CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 4
• 230000001815 facial effect Effects 0.000 claims description 4
• 125000005843 halogen group Chemical group 0.000 claims description 4
• 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
• 239000011541 reaction mixture Substances 0.000 claims description 4
• 125000005504 styryl group Chemical group 0.000 claims description 4
• 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 3
• FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical class ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 3
• 229940073507 cocamidopropyl betaine Drugs 0.000 claims description 3
• KVMGZRHAVFZQQJ-UHFFFAOYSA-N ethenyl 2-methylhexanoate Chemical compound CCCCC(C)C(=O)OC=C KVMGZRHAVFZQQJ-UHFFFAOYSA-N 0.000 claims description 3
• 230000003020 moisturizing effect Effects 0.000 claims description 3
• 229920000223 polyglycerol Polymers 0.000 claims description 3
• 229940014800 succinic anhydride Drugs 0.000 claims description 3
• 125000000524 functional group Chemical group 0.000 claims description 2
• 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
• 238000009472 formulation Methods 0.000 description 34
• 230000002209 hydrophobic effect Effects 0.000 description 32
• 125000004432 carbon atom Chemical group C* 0.000 description 31
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 28
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 27
• 239000002736 nonionic surfactant Substances 0.000 description 27
• 238000006116 polymerization reaction Methods 0.000 description 26
• 125000000129 anionic group Chemical group 0.000 description 24
• 239000011324 bead Substances 0.000 description 23
• 239000002904 solvent Substances 0.000 description 22
• 239000000463 material Substances 0.000 description 18
• 210000003491 skin Anatomy 0.000 description 18
• 238000012360 testing method Methods 0.000 description 17
• 210000001519 tissue Anatomy 0.000 description 17
• 229910052757 nitrogen Inorganic materials 0.000 description 15
• 239000000243 solution Substances 0.000 description 15
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
• 239000002253 acid Substances 0.000 description 14
• 239000003795 chemical substances by application Substances 0.000 description 14
• 239000000523 sample Substances 0.000 description 14
• 239000003995 emulsifying agent Substances 0.000 description 13
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 12
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
• 150000001875 compounds Chemical class 0.000 description 12
• 229940008099 dimethicone Drugs 0.000 description 12
• 239000004205 dimethyl polysiloxane Substances 0.000 description 12
• 235000013870 dimethyl polysiloxane Nutrition 0.000 description 12
• 239000003999 initiator Substances 0.000 description 12
• 230000007794 irritation Effects 0.000 description 12
• 239000002245 particle Substances 0.000 description 12
• 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 12
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 11
• 230000003110 anti-inflammatory effect Effects 0.000 description 11
• 229930195733 hydrocarbon Natural products 0.000 description 11
• 229910052700 potassium Inorganic materials 0.000 description 11
• 239000011591 potassium Substances 0.000 description 11
• 229960003975 potassium Drugs 0.000 description 11
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
• GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 10
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 10
• 235000014113 dietary fatty acids Nutrition 0.000 description 10
• 229930195729 fatty acid Natural products 0.000 description 10
• 239000000194 fatty acid Substances 0.000 description 10
• 239000006254 rheological additive Substances 0.000 description 10
• 239000004215 Carbon black (E152) Substances 0.000 description 9
• DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 9
• 150000004665 fatty acids Chemical class 0.000 description 9
• 150000002430 hydrocarbons Chemical class 0.000 description 9
• 230000000622 irritating effect Effects 0.000 description 9
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 9
• 150000003839 salts Chemical class 0.000 description 9
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 8
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
• MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
• 239000002585 base Substances 0.000 description 8
• 239000006185 dispersion Substances 0.000 description 8
• 238000012674 dispersion polymerization Methods 0.000 description 8
• 239000003960 organic solvent Substances 0.000 description 8
• 229940059574 pentaerithrityl Drugs 0.000 description 8
• 229920000058 polyacrylate Polymers 0.000 description 8
• 229920001451 polypropylene glycol Polymers 0.000 description 8
• 239000007787 solid Substances 0.000 description 8
• OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 7
• GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 7
• 239000013543 active substance Substances 0.000 description 7
• 125000003342 alkenyl group Chemical group 0.000 description 7
• 150000001412 amines Chemical class 0.000 description 7
• 125000002091 cationic group Chemical group 0.000 description 7
• 239000012530 fluid Substances 0.000 description 7
• 230000005484 gravity Effects 0.000 description 7
• 150000002431 hydrogen Chemical class 0.000 description 7
• 239000002609 medium Substances 0.000 description 7
• 239000003094 microcapsule Substances 0.000 description 7
• 238000006386 neutralization reaction Methods 0.000 description 7
• 230000003287 optical effect Effects 0.000 description 7
• ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 6
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
• ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical group CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 6
• QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical group C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 6
• 229910052783 alkali metal Inorganic materials 0.000 description 6
• 125000003277 amino group Chemical group 0.000 description 6
• 229920001400 block copolymer Polymers 0.000 description 6
• 238000006243 chemical reaction Methods 0.000 description 6
• 230000003749 cleanliness Effects 0.000 description 6
• 239000002537 cosmetic Substances 0.000 description 6
• DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 6
• 229920001519 homopolymer Polymers 0.000 description 6
• 239000004615 ingredient Substances 0.000 description 6
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
• 239000013642 negative control Substances 0.000 description 6
• 238000002360 preparation method Methods 0.000 description 6
• 229920005604 random copolymer Polymers 0.000 description 6
• 230000009467 reduction Effects 0.000 description 6
• 150000003467 sulfuric acid derivatives Chemical class 0.000 description 6
• 239000000725 suspension Substances 0.000 description 6
• 239000002562 thickening agent Substances 0.000 description 6
• RMTFNDVZYPHUEF-XZBKPIIZSA-N 3-O-methyl-D-glucose Chemical compound O=C[C@H](O)[C@@H](OC)[C@H](O)[C@H](O)CO RMTFNDVZYPHUEF-XZBKPIIZSA-N 0.000 description 5
• 229910052774 Proactinium Inorganic materials 0.000 description 5
• 229920002125 Sokalan® Polymers 0.000 description 5
• NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
• 235000001014 amino acid Nutrition 0.000 description 5
• 229940024606 amino acid Drugs 0.000 description 5
• 239000012736 aqueous medium Substances 0.000 description 5
• 150000001768 cations Chemical class 0.000 description 5
• 239000003638 chemical reducing agent Substances 0.000 description 5
• 150000002170 ethers Chemical class 0.000 description 5
• 150000002978 peroxides Chemical class 0.000 description 5
• 239000013641 positive control Substances 0.000 description 5
• 235000019333 sodium laurylsulphate Nutrition 0.000 description 5
• JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 4
• GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 4
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