JP6429242B2 - 有機変性シリコーンポリマーおよびそれを含むハイドロゲル - Google Patents
有機変性シリコーンポリマーおよびそれを含むハイドロゲル Download PDFInfo
- Publication number
- JP6429242B2 JP6429242B2 JP2015501696A JP2015501696A JP6429242B2 JP 6429242 B2 JP6429242 B2 JP 6429242B2 JP 2015501696 A JP2015501696 A JP 2015501696A JP 2015501696 A JP2015501696 A JP 2015501696A JP 6429242 B2 JP6429242 B2 JP 6429242B2
- Authority
- JP
- Japan
- Prior art keywords
- prepolymer
- silicone
- group
- hydrogen
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 0 CC[C@](C)C=*CCOCC*C(CCC1)C1C1OC1C Chemical compound CC[C@](C)C=*CCOCC*C(CCC1)C1C1OC1C 0.000 description 3
- RNSUMEWJRVJVQX-UHFFFAOYSA-N CC(C(OC(CCC(CCS(C)(O[Si](C)(C)C)O[Si+](C)(C)O[Si+](C)(C)C)C1)C1O)=O)=C Chemical compound CC(C(OC(CCC(CCS(C)(O[Si](C)(C)C)O[Si+](C)(C)O[Si+](C)(C)C)C1)C1O)=O)=C RNSUMEWJRVJVQX-UHFFFAOYSA-N 0.000 description 1
- QGOAVYUHMIPPOD-UHFFFAOYSA-N CC(C)C1=CCCC1C Chemical compound CC(C)C1=CCCC1C QGOAVYUHMIPPOD-UHFFFAOYSA-N 0.000 description 1
- SODBREMAILNAOJ-UHFFFAOYSA-N CCC(C)C[N](C)(O[N](C)(C)C)O[N](C)(C)O[N](C)(C)C Chemical compound CCC(C)C[N](C)(O[N](C)(C)C)O[N](C)(C)O[N](C)(C)C SODBREMAILNAOJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
- C08F283/124—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to polysiloxanes having carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2210/00—Compositions for preparing hydrogels
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B2207/00—Coding scheme for general features or characteristics of optical elements and systems of subclass G02B, but not including elements and systems which would be classified in G02B6/00 and subgroups
- G02B2207/109—Sols, gels, sol-gel materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Eyeglasses (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Silicon Polymers (AREA)
- Dispersion Chemistry (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261614262P | 2012-03-22 | 2012-03-22 | |
| US61/614,262 | 2012-03-22 | ||
| PCT/US2013/029302 WO2013142052A2 (en) | 2012-03-22 | 2013-03-06 | Organo-modified silicone polymers and hydrogels comprising the same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015523415A JP2015523415A (ja) | 2015-08-13 |
| JP2015523415A5 JP2015523415A5 (OSRAM) | 2017-11-16 |
| JP6429242B2 true JP6429242B2 (ja) | 2018-11-28 |
Family
ID=49223438
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015501698A Active JP6227625B2 (ja) | 2012-03-22 | 2013-03-06 | 有機変性シリコーンポリマー |
| JP2015501696A Active JP6429242B2 (ja) | 2012-03-22 | 2013-03-06 | 有機変性シリコーンポリマーおよびそれを含むハイドロゲル |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015501698A Active JP6227625B2 (ja) | 2012-03-22 | 2013-03-06 | 有機変性シリコーンポリマー |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9944742B2 (OSRAM) |
| EP (2) | EP2838955A4 (OSRAM) |
| JP (2) | JP6227625B2 (OSRAM) |
| KR (2) | KR20140134715A (OSRAM) |
| CN (2) | CN104955878B (OSRAM) |
| AU (1) | AU2013235656A1 (OSRAM) |
| CA (1) | CA2868170A1 (OSRAM) |
| IN (2) | IN2014MN01867A (OSRAM) |
| WO (2) | WO2013142052A2 (OSRAM) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104955878B (zh) | 2012-03-22 | 2018-08-17 | 莫门蒂夫性能材料股份有限公司 | 有机基-改性的有机硅聚合物 |
| JP6257653B2 (ja) * | 2013-02-06 | 2018-01-10 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | (メタ)アクリロキシ含有トリシロキサン、シロキサン含有ポリマー、およびそれらによる生物医学用具 |
| JP2015078333A (ja) * | 2013-10-18 | 2015-04-23 | 日華化学株式会社 | 硬化性オルガノ変性シリコーン及びその製造方法、並びにコーティング剤及び積層体 |
| JP6037453B2 (ja) * | 2013-11-14 | 2016-12-07 | 信越化学工業株式会社 | 眼科デバイス製造用モノマー |
| US9296764B2 (en) * | 2013-12-10 | 2016-03-29 | Momentive Performance Materials Inc. | Hydrophilic silicone composition |
| US9851472B2 (en) * | 2015-03-27 | 2017-12-26 | Momentive Performance Materials Inc. | Silicone-based hydrophilic copolymer and hydrogel compositions comprising the same |
| FR3062209B1 (fr) | 2017-01-25 | 2021-08-27 | Commissariat Energie Atomique | Detecteur optique de particules |
| CN110494519B (zh) * | 2017-02-16 | 2021-10-26 | 莫门蒂夫性能材料股份有限公司 | 经离子改性的有机硅、组合物和由其形成的医疗器材 |
| TWI626253B (zh) * | 2017-05-25 | 2018-06-11 | 晶碩光學股份有限公司 | 水溶性矽高聚物、矽水膠組成物、矽水膠鏡片及其製造方法 |
| CN107260655B (zh) * | 2017-06-09 | 2021-03-09 | 金陵科技学院 | 一种维生素e改性的硅基水凝胶隐形眼镜载药体系及其制备方法 |
| WO2019020542A1 (en) * | 2017-07-26 | 2019-01-31 | Byk-Chemie Gmbh | POLYMER COMPRISING POLYETHER AND POLYSILOXANE SEGMENTS |
| KR102255536B1 (ko) | 2017-11-30 | 2021-05-25 | 주식회사 엘지에너지솔루션 | 젤 폴리머 전해질용 조성물, 이로부터 제조되는 젤 폴리머 전해질 및 이를 포함하는 리튬 이차 전지 |
| WO2020252772A1 (en) | 2019-06-21 | 2020-12-24 | Dow Silicones Corporation | Method for producing thixotropic curable silicone composition |
| JP7495434B2 (ja) | 2019-06-21 | 2024-06-04 | ダウ シリコーンズ コーポレーション | 熱伝導性シリコーン組成物 |
| EP4056262A4 (en) * | 2019-11-05 | 2023-11-22 | LG Household & Health Care Ltd. | Biodegradable microcapsule and method for manufacturing same |
| JP7681610B2 (ja) | 2020-02-23 | 2025-05-22 | ダウ シリコーンズ コーポレーション | 光硬化性シリコーン組成物及びその硬化物 |
| CN114103281B (zh) * | 2021-11-24 | 2024-01-19 | 四川中烟工业有限责任公司 | 一种保湿的三层材料及其制备方法 |
| CN114103320B (zh) * | 2021-11-24 | 2024-01-19 | 四川中烟工业有限责任公司 | 一种保湿三层材料对雪茄烟微环境湿度调控方面的用途 |
| CN114015053A (zh) * | 2021-12-03 | 2022-02-08 | 郝建强 | 紫外线固化有机硅离型剂 |
| CN115490805B (zh) * | 2022-09-30 | 2023-08-18 | 郑州轻工业大学 | 一种基于氧化还原反应引发的水凝胶 |
| WO2024242750A1 (en) * | 2023-05-23 | 2024-11-28 | Dow Global Technologies Llc | Silicone - (meth)acrylate - polyether copolymer and synthesis method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| NL128305C (OSRAM) | 1963-09-11 | |||
| AT251910B (de) | 1964-07-02 | 1967-01-25 | Ceskoslovenska Akademie Ved | Verfahren zur Herstellung von weichen, biegsamen Kontaktlinsen |
| US4197266A (en) | 1974-05-06 | 1980-04-08 | Bausch & Lomb Incorporated | Method for forming optical lenses |
| US4084459A (en) | 1977-03-07 | 1978-04-18 | Bausch & Lomb Incorporated | Method and apparatus for lens turning |
| US4260725A (en) | 1979-12-10 | 1981-04-07 | Bausch & Lomb Incorporated | Hydrophilic contact lens made from polysiloxanes which are thermally bonded to polymerizable groups and which contain hydrophilic sidechains |
| AU546039B2 (en) * | 1982-05-08 | 1985-08-08 | Menicon Co., Ltd | Oxygen permeable hard contact lens |
| US4450264A (en) * | 1982-08-09 | 1984-05-22 | Polymatic Investment Corp., N.V. | Siloxane-containing polymers and contact lenses therefrom |
| HK1001563A1 (en) * | 1990-11-27 | 1998-06-26 | Bausch & Lomb Incorporated | Surface-active macromonomers |
| US5352714A (en) | 1991-11-05 | 1994-10-04 | Bausch & Lomb Incorporated | Wettable silicone hydrogel compositions and methods for their manufacture |
| US5336797A (en) * | 1992-12-30 | 1994-08-09 | Bausch & Lomb Incorporated | Siloxane macromonomers |
| TW328535B (en) | 1993-07-02 | 1998-03-21 | Novartis Ag | Functional photoinitiators and their manufacture |
| US6013711A (en) | 1997-06-18 | 2000-01-11 | Ck Witco Corporation | Hydrophilic polysiloxane compositions |
| US5981669A (en) | 1997-12-29 | 1999-11-09 | Bausch & Lomb Incorporated | Silicone-containing prepolymers and low water materials |
| US5998498A (en) | 1998-03-02 | 1999-12-07 | Johnson & Johnson Vision Products, Inc. | Soft contact lenses |
| US6207782B1 (en) | 1998-05-28 | 2001-03-27 | Cromption Corporation | Hydrophilic siloxane latex emulsions |
| WO2001044861A1 (en) | 1999-12-16 | 2001-06-21 | Asahikasei Aime Co., Ltd. | Soft contact lens capable of being worn for a long period |
| JP5242876B2 (ja) | 2000-03-24 | 2013-07-24 | ノバルティス アーゲー | 架橋結合性または重合性プレポリマー |
| CN101467093B (zh) * | 2006-06-15 | 2010-10-06 | 库柏维景国际控股公司 | 可湿性硅氧水凝胶隐形眼镜以及相关组合物和方法 |
| EP2129513B1 (en) * | 2007-03-22 | 2016-08-03 | Novartis AG | Prepolymers with dangling polysiloxane-containing polymer chains |
| US8044111B2 (en) | 2007-11-30 | 2011-10-25 | Novartis Ag | Actinically-crosslinkable silicone-containing block copolymers |
| US7934830B2 (en) * | 2007-12-03 | 2011-05-03 | Bausch & Lomb Incorporated | High water content silicone hydrogels |
| US8030363B2 (en) * | 2008-01-25 | 2011-10-04 | Momentive Performance Materials Inc. | Polyorganosiloxane demulsifier compositions and methods of making the same |
| WO2010038242A2 (en) * | 2008-10-03 | 2010-04-08 | Momentive Performance Materials Inc. | Hydrophilic silicone monomers, process for their preparation and thin films containing the same |
| EP3598181B1 (en) * | 2008-11-13 | 2021-06-23 | Alcon Inc. | Vinylic monomer and prepolymer comprising same |
| JP5684798B2 (ja) * | 2009-05-22 | 2015-03-18 | ノバルティス アーゲー | 化学線架橋性シロキサン含有コポリマー |
| CA2760747C (en) | 2009-05-22 | 2016-12-13 | Novartis Ag | Actinically-crosslinkable siloxane-containing copolymers |
| TWI401263B (zh) | 2009-12-31 | 2013-07-11 | Far Eastern New Century Corp | 增進聚矽氧水膠潤濕性之共聚物、包含其之聚矽氧水膠組成物及由此製得之眼用物件 |
| US10391179B2 (en) * | 2011-03-21 | 2019-08-27 | Momentive Performance Materials Inc. | Organomodified carbosiloxane monomers containing compositions and uses thereof |
| CN102303713B (zh) | 2011-09-02 | 2013-09-25 | 浙江双友物流器械股份有限公司 | 一种快速绞紧器 |
| CN104955878B (zh) * | 2012-03-22 | 2018-08-17 | 莫门蒂夫性能材料股份有限公司 | 有机基-改性的有机硅聚合物 |
-
2013
- 2013-03-06 CN CN201380024460.1A patent/CN104955878B/zh active Active
- 2013-03-06 AU AU2013235656A patent/AU2013235656A1/en not_active Abandoned
- 2013-03-06 EP EP13763479.6A patent/EP2838955A4/en active Pending
- 2013-03-06 KR KR20147029338A patent/KR20140134715A/ko not_active Withdrawn
- 2013-03-06 WO PCT/US2013/029302 patent/WO2013142052A2/en not_active Ceased
- 2013-03-06 EP EP13764947.1A patent/EP2828338A4/en active Pending
- 2013-03-06 JP JP2015501698A patent/JP6227625B2/ja active Active
- 2013-03-06 IN IN1867MUN2014 patent/IN2014MN01867A/en unknown
- 2013-03-06 CA CA2868170A patent/CA2868170A1/en not_active Abandoned
- 2013-03-06 JP JP2015501696A patent/JP6429242B2/ja active Active
- 2013-03-06 IN IN1866MUN2014 patent/IN2014MN01866A/en unknown
- 2013-03-06 WO PCT/US2013/029316 patent/WO2013142055A2/en not_active Ceased
- 2013-03-06 KR KR20147029400A patent/KR20140143194A/ko not_active Withdrawn
- 2013-03-06 CN CN201380024477.7A patent/CN105518058B/zh active Active
-
2014
- 2014-09-22 US US14/492,378 patent/US9944742B2/en active Active
- 2014-09-22 US US14/492,646 patent/US9890234B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| AU2013235656A1 (en) | 2014-10-09 |
| US9944742B2 (en) | 2018-04-17 |
| KR20140134715A (ko) | 2014-11-24 |
| WO2013142055A2 (en) | 2013-09-26 |
| CA2868170A1 (en) | 2013-09-26 |
| CN105518058A (zh) | 2016-04-20 |
| EP2838955A4 (en) | 2016-07-13 |
| KR20140143194A (ko) | 2014-12-15 |
| EP2828338A2 (en) | 2015-01-28 |
| JP6227625B2 (ja) | 2017-11-08 |
| CN104955878A (zh) | 2015-09-30 |
| CN104955878B (zh) | 2018-08-17 |
| EP2828338A4 (en) | 2016-04-06 |
| JP2015523415A (ja) | 2015-08-13 |
| US20150011671A1 (en) | 2015-01-08 |
| WO2013142052A3 (en) | 2015-05-28 |
| US9890234B2 (en) | 2018-02-13 |
| IN2014MN01866A (OSRAM) | 2015-07-03 |
| EP2838955A2 (en) | 2015-02-25 |
| US20150011788A1 (en) | 2015-01-08 |
| JP2015522661A (ja) | 2015-08-06 |
| WO2013142055A3 (en) | 2015-06-18 |
| WO2013142052A2 (en) | 2013-09-26 |
| CN105518058B (zh) | 2019-03-26 |
| IN2014MN01867A (OSRAM) | 2015-07-03 |
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