JP6417890B2 - High-strength concrete composition and method for producing high-strength concrete hardened body - Google Patents
High-strength concrete composition and method for producing high-strength concrete hardened body Download PDFInfo
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- 239000011372 high-strength concrete Substances 0.000 title claims description 47
- 239000000203 mixture Substances 0.000 title claims description 42
- 238000004519 manufacturing process Methods 0.000 title claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
- 239000004568 cement Substances 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 24
- 239000003638 chemical reducing agent Substances 0.000 claims description 19
- 229910021487 silica fume Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 229910000831 Steel Inorganic materials 0.000 claims description 6
- 239000002518 antifoaming agent Substances 0.000 claims description 6
- 239000010959 steel Substances 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- 230000032683 aging Effects 0.000 claims 1
- 238000001723 curing Methods 0.000 description 47
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000004567 concrete Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000002893 slag Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000013007 heat curing Methods 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 235000019738 Limestone Nutrition 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000011362 coarse particle Substances 0.000 description 3
- 239000006028 limestone Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229910001111 Fine metal Inorganic materials 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229910000863 Ferronickel Inorganic materials 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000009614 chemical analysis method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Description
本発明は、高強度コンクリート組成物及び高強度コンクリート硬化体の製造方法に関する。 The present invention relates to a high-strength concrete composition and a method for producing a high-strength concrete hardened body.
近年、構造部材の軽量化、鉄筋使用量の削減などの要求に伴い、２００Ｎ／ｍｍ２程度の圧縮強度が得られるような超高強度材料が提案されている。これらの材料では、セメント、ポゾラン質微粉末、骨材及び高性能減水剤が使用されており、熱養生によって超高強度化が図られている。また、これらに金属繊維や有機繊維を添加することによって、高いじん性やひび割れ抑制機能を付与することが提案されている（特許文献１〜３参照）。
例えば、上記の材料よりもさらに圧縮強度の高い材料が得られれば、柱部材の受け持つ荷重をさらに増大することができるため、構造物における柱の数を減らすことができ、その結果、構造物の居住空間をさらに広げられるとともに、設計や意匠性の自由度がさらに高まることが考えられる。
In recent years, an ultra-high-strength material capable of obtaining a compressive strength of about 200 N / mm 2 has been proposed in accordance with demands for reducing the weight of structural members and reducing the amount of reinforcing bars used. In these materials, cement, pozzolanic fine powder, aggregate, and a high-performance water reducing agent are used, and ultrahigh strength is achieved by heat curing. In addition, it has been proposed to impart high toughness and crack suppression function by adding metal fibers and organic fibers to these (see Patent Documents 1 to 3).
For example, if a material having a higher compressive strength than the above-mentioned material is obtained, the load of the column member can be further increased, so that the number of columns in the structure can be reduced. It is conceivable that the living space can be further expanded and the degree of freedom in design and design is further increased.
コンクリート組成物の高強度化を図る場合、その水／結合材比をより小さくする方法が一般的に執られるが、結合材の化学反応をより促進するために、蒸気養生などの加熱養生がとられることがある。また、更なる高強度化のため、コンクリート中の空隙を極力小さくする目的で、遠心成型や加圧成型が行われることもある。また、これらの方法を組み合わせた、オートクレーブ養生やヒートプレス養生をすることで、さらに高い圧縮強度が得られることが分かっている。 In order to increase the strength of a concrete composition, a method of reducing the water / binder ratio is generally adopted. However, in order to further promote the chemical reaction of the binder, heat curing such as steam curing is required. May be. In order to further increase the strength, centrifugal molding or pressure molding may be performed for the purpose of reducing the voids in the concrete as much as possible. It has also been found that higher compressive strength can be obtained by combining these methods with autoclave curing and heat press curing.
しかしながら、これらの製造方法は、大掛かりな設備が必要であるため、容易に実施できるものではない。
そこで、本発明は、従来の技術にくらべて、大掛かりかつ特殊な製造設備を必要とせず、より高強度である高強度コンクリート組成物及び高強度コンクリート硬化体の製造方法を提供することを目的とする。
However, these manufacturing methods are not easy to implement because they require large-scale equipment.
Therefore, an object of the present invention is to provide a high-strength concrete composition and a method for producing a high-strength hardened concrete body, which are higher in strength and do not require large-scale and special production equipment, as compared with the conventional technology. To do.
本発明者らは、上記課題を解決すべく鋭意検討した結果、セメントと、無機質微粉末と、細骨材と、粗骨材と、減水剤及び消泡剤とを組み合わせ、さらに、微小な金属微粉末を混入することによって、高強度化が実現できることを見出し、本発明に至った。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have combined cement, inorganic fine powder, fine aggregate, coarse aggregate, water reducing agent and antifoaming agent, and a fine metal. The inventors have found that high strength can be realized by mixing fine powder, and have reached the present invention.
すなわち、本発明は、セメントと、無機質微粉末と、水と、細骨材と、粗骨材と、減水剤と、消泡剤と、金属微粉末とを含む高強度コンクリート組成物であって、前記セメントは、Ｃ３Ｓを１０．０質量％〜７０．０質量％及びＣ２Ｓを１０．０質量％〜７０．０質量％含有し、前記無機質微粉末はシリカフュームを含む高強度コンクリート組成物を提供する。このような高強度コンクリート組成物は、従来にない、非常に高い圧縮強度を発現することができる。
また、本発明は前記高強度コンクリート組成物を、１５〜２５℃の気中で１日間〜５日間養生を行う前養生工程と、２０〜６０℃の水中または気中で１日間〜７日間養生を行う一次養生工程と、８０℃〜２００℃の水中または気中で１日間〜２１日間養生を行う二次養生工程とを含む、高強度コンクリート硬化体の製造方法を提供する。
また、本発明は、更に、８０℃〜２００℃の気中で１〜２１日間養生を行う三次養生工程を含む、高強度コンクリート硬化体の製造方法を提供する。
このような高強度コンクリート硬化体の製造方法によれば、従来にない、非常に高い圧縮強度を有す高強度コンクリート硬化体を製造することができる。
That is, the present invention is a high-strength concrete composition comprising cement, inorganic fine powder, water, fine aggregate, coarse aggregate, water reducing agent, antifoaming agent, and metal fine powder. The cement contains C 3 S in an amount of 10.0% to 70.0% by mass and C 2 S in an amount of 10.0% to 70.0% by mass, and the inorganic fine powder contains silica fume. A composition is provided. Such a high-strength concrete composition can express a very high compressive strength that has not existed before.
The present invention also includes a pre-curing step for curing the high-strength concrete composition in the air at 15 to 25 ° C. for 1 to 5 days, and curing for 1 to 7 days in water or air at 20 to 60 ° C. There is provided a method for producing a high-strength concrete hardened body comprising a primary curing step of performing a curing step and a secondary curing step of curing for 1 to 21 days in water or in the air at 80 ° C to 200 ° C.
Moreover, this invention provides the manufacturing method of a high-strength concrete hardened | cured material including the tertiary curing process which further cures for 1 to 21 days in the air of 80 to 200 degreeC.
According to such a method for producing a high-strength concrete cured body, an unprecedented high-strength concrete cured body having a very high compressive strength can be produced.
本発明によれば、特殊な養生方法をとらなくとも、高い圧縮強度を持つ高強度コンクリート組成物及び高強度コンクリート硬化体の製造方法を提供することができる。 According to the present invention, it is possible to provide a high-strength concrete composition having a high compressive strength and a method for producing a high-strength concrete hardened body without taking a special curing method.
以下、本発明に係る高強度コンクリート組成物及び高強度コンクリート硬化体の製造方法好適な実施形態について説明するが、本発明は以下の実施形態に限定されるものではない。 Hereinafter, preferred embodiments of a method for producing a high-strength concrete composition and a high-strength concrete hardened body according to the present invention will be described, but the present invention is not limited to the following embodiments.
（高強度コンクリート組成物）
本実施形態の高強度コンクリート組成物は、セメントと、無機質微粉末としてシリカフュームと、水と、細骨材と、粗骨材と、減水剤と、消泡剤と、金属微粉末とを含むものである。
(High-strength concrete composition)
The high-strength concrete composition of the present embodiment includes cement, silica fume as inorganic fine powder, water, fine aggregate, coarse aggregate, water reducing agent, antifoaming agent, and metal fine powder. .
セメントの鉱物組成は、Ｃ３Ｓ量が１０．０〜７０．０質量％、Ｃ２Ｓ量が１０．０〜７０．０質量％、Ｃ３Ａ量が７．０質量％以下、Ｃ４ＡＦ量が５．０〜１５．０質量％である。Ｃ３Ｓ量は、好ましくは１１．０〜６８．０質量％、より好ましくは１２．０〜６０．０質量％であり、更に好ましくは１３．０〜４０．０質量％、最も好ましくは１５．０〜２５．０質量％である。Ｃ３Ｓ量が１０．０質量％未満では圧縮強度が低くなる傾向があり、７０．０質量％を超えると加熱養生後の圧縮強度が低くなる傾向がある。Ｃ２Ｓ量は、好ましくは１２．０〜６５．０質量％、より好ましくは１５．０〜６２．０質量％であり、更に好ましくは５５．０〜６３．０質量％である。Ｃ２Ｓ量が１０．０質量％未満では、特に加熱養生後の圧縮強度が低くなる傾向がある。Ｃ３Ａ量は好ましくは７．０質量％以下であり、より好ましくは４．５質量％以下であり、更に好ましくは４．０質量％以下である。Ｃ３Ａ量が５．０％を超えると、十分な流動性が得られなくなる。Ｃ４ＡＦ量は、好ましくは６．０〜１５．０質量％、より好ましくは７．０〜１５．０質量％であり、更に好ましくは８．０〜１０．０質量％である。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。 As for the mineral composition of the cement, the amount of C 3 S is 10.0 to 70.0% by mass, the amount of C 2 S is 10.0 to 70.0% by mass, the amount of C 3 A is 7.0% by mass or less, C 4 The AF amount is 5.0 to 15.0% by mass. The amount of C 3 S is preferably 11.0 to 68.0% by mass, more preferably 12.0 to 60.0% by mass, still more preferably 13.0 to 40.0% by mass, and most preferably 15 0.0-25.0% by mass. If the amount of C 3 S is less than 10.0% by mass, the compressive strength tends to be low, and if it exceeds 70.0% by mass, the compressive strength after heat curing tends to be low. The amount of C 2 S is preferably 12.0 to 65.0 mass%, more preferably 15.0 to 62.0 mass%, and further preferably 55.0 to 63.0 mass%. When the amount of C 2 S is less than 10.0% by mass, the compressive strength particularly after heat curing tends to be low. The amount of C 3 A is preferably 7.0% by mass or less, more preferably 4.5% by mass or less, and further preferably 4.0% by mass or less. When the amount of C 3 A exceeds 5.0%, sufficient fluidity cannot be obtained. The amount of C 4 AF is preferably 6.0 to 15.0% by mass, more preferably 7.0 to 15.0% by mass, and still more preferably 8.0 to 10.0% by mass. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
セメントのブレーン比表面積は、好ましくは２５００〜４８００ｃｍ２／ｇ、より好ましくは２８００〜４５００ｃｍ２／ｇ、更に好ましくは３０００〜４２００ｃｍ２／ｇであり、特に好ましくは３１００〜３９００ｃｍ２／ｇである。セメントのブレーン比表面積が２５００ｃｍ２／ｇ未満では高強度コンクリート組成物の強度が低くなる傾向があり、４８００ｃｍ２／ｇを超えると低水セメント比での流動性が低下する傾向にある。 The brane specific surface area of the cement is preferably 2500 to 4800 cm 2 / g, more preferably 2800 to 4500 cm 2 / g, still more preferably 3000 to 4200 cm 2 / g, and particularly preferably 3100 to 3900 cm 2 / g. When the brane specific surface area of the cement is less than 2500 cm 2 / g, the strength of the high-strength concrete composition tends to be low, and when it exceeds 4800 cm 2 / g, the fluidity at the low water cement ratio tends to decrease.
本実施形態に係るセメントの製造にあたっては、通常のセメントと特に異なる操作を行う必要はない。上記セメントは、石灰石、珪石、スラグ、石炭灰、建設発生土、高炉ダスト等の原料の調合を目標とする鉱物組成に応じて変え、実機キルンで焼成した後、得られたクリンカーに石膏を加えて所定の粒度に粉砕することによって製造することができる。焼成するキルンには、一般的なＮＳＰキルンやＳＰキルン等を使用することができ、粉砕には一般的なボールミル等の粉砕機が使用可能である。また、必要に応じて、２種以上のセメントを混合することもできる。 In manufacturing the cement according to the present embodiment, it is not necessary to perform an operation different from that of normal cement. The cement is changed according to the target mineral composition such as limestone, silica, slag, coal ash, construction generated soil, blast furnace dust, etc., fired in the actual kiln, gypsum added to the obtained clinker And can be manufactured by pulverizing to a predetermined particle size. A general NSP kiln, SP kiln, or the like can be used for the kiln to be fired, and a general pulverizer such as a ball mill can be used for pulverization. Moreover, 2 or more types of cement can also be mixed as needed.
シリカフュームは、金属シリコン、フェロシリコン、電融ジルコニア等を製造する際に発生する排ガス中のダストを集塵して得られる副産物であり、主成分は、アルカリ溶液中で溶解する非晶質のＳｉＯ２である。
シリカフュームのＢＥＴ比表面積は、好ましくは１０〜３０ｍ２／ｇ、より好ましくは１３〜２８ｍ２／ｇ、更に好ましくは１４〜２６ｍ２／ｇ、特に好ましくは１５〜２４ｍ２／ｇである。このようなシリカフュームを用いることで、高強度コンクリート組成物の高い圧縮強度及び高い流動性を確保しやすくなる。
Silica fume is a by-product obtained by collecting dust in the exhaust gas generated when producing metal silicon, ferrosilicon, fused zirconia, etc., and the main component is amorphous SiO dissolved in an alkaline solution. 2 .
BET specific surface area of silica fume is preferably 10 to 30 m 2 / g, more preferably 13~28m 2 / g, more preferably 14~26m 2 / g, particularly preferably 15~24m 2 / g. By using such silica fume, it becomes easy to ensure high compressive strength and high fluidity of the high-strength concrete composition.
本実施形態の高強度コンクリート組成物において、セメントと無機質微粉末の合計量を基準として、シリカフュームを、好ましくは５〜３５質量％、より好ましくは７〜３０質量％、更に好ましくは８〜２７質量％、特に好ましくは９〜２３質量％含む。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。 In the high-strength concrete composition of the present embodiment, silica fume is preferably 5 to 35% by mass, more preferably 7 to 30% by mass, and still more preferably 8 to 27% by mass, based on the total amount of cement and inorganic fine powder. %, Particularly preferably 9 to 23% by mass. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
細骨材としては、特に制限されないが、川砂、陸砂、海砂、砕砂、珪砂、石灰石骨材、高炉スラグ細骨材、フェロニッケルスラグ細骨材、銅スラグ細骨材、電気炉酸化スラグ細
骨材等を使用することができる。なお、細骨材の粒度は、１０ｍｍふるいを全部通り、５
ｍｍふるいを８５質量％以上通過するものが好ましい。
粗骨材としては、特に制限されないが、砂利、砕石、石灰石骨材、高炉スラグ粗骨材等を使用することができる。なお、粗骨材の粒度は、５ｍｍの篩いに８５質量％以上とどまるものが好ましい。
The fine aggregate is not particularly limited, but river sand, land sand, sea sand, crushed sand, quartz sand, limestone aggregate, blast furnace slag fine aggregate, ferronickel slag fine aggregate, copper slag fine aggregate, electric furnace oxidation slag Fine aggregates can be used. The fine aggregate has a particle size of 5 mm through the 10 mm sieve.
It is preferable to pass through a mm sieve by 85% by mass or more.
Although it does not restrict | limit especially as a coarse aggregate, Gravel, a crushed stone, a limestone aggregate, a blast furnace slag coarse aggregate, etc. can be used. The coarse aggregate preferably has a particle size of 85% by mass or more on a 5 mm sieve.
減水剤としては、リグニン系、ナフタレンスルホン酸系、アミノスルホン酸系、ポリカルボン酸系の減水剤、高性能減水剤、高性能ＡＥ減水剤等を使用することができる。低水セメント比での流動性確保の観点から、減水剤として、ポリカルボン酸系の減水剤、高性能減水剤又は高性能ＡＥ減水剤を用いることが好ましく、ポリカルボン酸系の高性能減水剤を用いることがより好ましい。本実施形態に係る高強度コンクリート組成物は、セメントと無機質微粉末の合量１００質量部に対して、減水剤を好ましくは１．０〜６．０質量部、より好ましくは１．５〜５．０質量部、更に好ましくは１．８〜４．５質量部、特に好ましくは２．２〜４．０質量部含む。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。 As the water reducing agent, lignin-based, naphthalenesulfonic acid-based, aminosulfonic acid-based, polycarboxylic acid-based water reducing agents, high-performance water reducing agents, high-performance AE water reducing agents, and the like can be used. From the viewpoint of ensuring fluidity at a low water cement ratio, it is preferable to use a polycarboxylic acid-based water reducing agent, a high-performance water reducing agent or a high-performance AE water reducing agent as the water reducing agent, and a polycarboxylic acid-based high-performance water reducing agent. It is more preferable to use The high-strength concrete composition according to the present embodiment is preferably 1.0 to 6.0 parts by mass, more preferably 1.5 to 5 parts by weight of the water reducing agent with respect to 100 parts by mass of the total amount of cement and inorganic fine powder. 0.0 part by mass, more preferably 1.8 to 4.5 parts by mass, particularly preferably 2.2 to 4.0 parts by mass. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
また、セメントと無機質微粉末の合量１００質量部に対して、水を好ましくは９〜２０質量部、より好ましくは９．５〜１８質量部、更に好ましくは１０．０〜１６質量部、特に好ましくは１０．５〜１４．０質量部含む。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。 The amount of water is preferably 9 to 20 parts by weight, more preferably 9.5 to 18 parts by weight, still more preferably 10.0 to 16 parts by weight, especially 100 parts by weight of the total amount of cement and inorganic fine powder. Preferably it contains 10.5 to 14.0 parts by mass. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
消泡剤としては、特殊非イオン配合型界面活性剤、ポリアルキレン誘導体、疎水性シリカ、ポリエーテル系等が挙げられる。この場合、セメントと無機質微粉末の合量１００質量部に対して、消泡剤を好ましくは０．０１〜２．０質量部、より好ましくは０．１〜１．０質量部、更に好ましくは０．２〜０．５質量部含む。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。 Examples of antifoaming agents include special nonionic compounding surfactants, polyalkylene derivatives, hydrophobic silica, and polyethers. In this case, the defoamer is preferably 0.01 to 2.0 parts by weight, more preferably 0.1 to 1.0 parts by weight, and still more preferably, with respect to 100 parts by weight of the total amount of cement and inorganic fine powder. Including 0.2 to 0.5 parts by mass. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
金属微粉末は、カットスチールウール及び／又は鉄粉等を使用することができる。カットスチールウールとはスチールウールを短く切断したものを意味する。またスチールウールとは鉄の非常に細い線を綿状に固めた物で、研磨用のたわしとして使用されることがある。
金属微粉末の形状は、直径が好ましくは５μｍ〜５００μｍ、より好ましくは１０μｍ〜４２０μｍ、更に好ましくは１５μｍ〜４００μｍ、特に好ましくは２０μｍ〜３８０μｍである。長さは好ましくは５μｍ〜５．０ｍｍ、より好ましくは２０μｍ〜４．０ｍｍ、更に好ましくは３０μｍ〜３．８ｍｍ、特に好ましくは５０μｍ〜３．５ｍｍである。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。
As the metal fine powder, cut steel wool and / or iron powder or the like can be used. Cut steel wool means steel wool cut into short pieces. Steel wool is a product in which very thin wires of iron are hardened in a cotton form, and is sometimes used as a scrubbing brush.
The shape of the metal fine powder is preferably 5 μm to 500 μm in diameter, more preferably 10 μm to 420 μm, still more preferably 15 μm to 400 μm, and particularly preferably 20 μm to 380 μm. The length is preferably 5 μm to 5.0 mm, more preferably 20 μm to 4.0 mm, still more preferably 30 μm to 3.8 mm, and particularly preferably 50 μm to 3.5 mm. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
（高強度コンクリート硬化体の製造方法）
本実施形態の高強度コンクリート硬化体の製造方法は、上記高強度コンクリート組成物を、１５〜２５℃の気中で１日間〜５日間養生を行う前養生工程と、２０〜６０℃の水中または気中で１日間〜７日間養生を行う一次養生工程と、８０℃〜２００℃の水中または気中で１日間〜２１日間養生を行う二次養生工程とを含む。
前養生工程は、好ましくは１６〜２４℃、より好ましくは１７〜２３℃、更に好ましくは１８〜２２℃、特に好ましくは１９〜２１℃の気中で、好ましくは１.５〜４日間、より好ましくは２.０〜３.５日間、更に好ましくは２．５〜３．３日間養生を行う。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。
(Manufacturing method of high-strength concrete hardened body)
The manufacturing method of the high-strength concrete hardened | cured material of this embodiment is the pre-curing process which cures the said high-strength concrete composition in the air of 15-25 degreeC for 1 day-5 days, and 20-20 degreeC water or A primary curing process in which the curing is performed in the air for 1 day to 7 days, and a secondary curing process in which the curing is performed in water at 80 ° C. to 200 ° C. or in the air for 1 to 21 days.
The pre-curing step is preferably 16 to 24 ° C., more preferably 17 to 23 ° C., still more preferably 18 to 22 ° C., particularly preferably 19 to 21 ° C., preferably 1.5 to 4 days. The curing is preferably performed for 2.0 to 3.5 days, and more preferably for 2.5 to 3.3 days. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
一次養生工程は、好ましくは２３〜５５℃、より好ましくは２５〜５０℃、更に好ましくは２８〜４８℃、特に好ましくは３０〜４５℃の水中で、好ましくは１〜７日間、より好ましくは１．５〜６日間、更に好ましくは１．８〜５日間、特に好ましくは２．０〜４．５日間養生を行う。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。 The primary curing step is preferably 23 to 55 ° C, more preferably 25 to 50 ° C, still more preferably 28 to 48 ° C, particularly preferably 30 to 45 ° C in water, preferably 1 to 7 days, more preferably 1 Curing is carried out for 5 to 6 days, more preferably 1.8 to 5 days, particularly preferably 2.0 to 4.5 days. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
二次養生工程は、好ましくは８０〜２００℃、より好ましくは８３〜１９０℃、更に好ましくは８５〜１８５℃、特に好ましくは９０〜１８０℃の水中または気中で、好ましくは１〜２１日間、より好ましくは３〜１９日間、更に好ましくは５〜１７日間、特に好ましくは７〜１５日間養生を行う。水中の場合、温水、気中の場合、蒸気養生装置、オートクレーブ、乾燥機などが使用出来る。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。 The secondary curing step is preferably 80 to 200 ° C, more preferably 83 to 190 ° C, still more preferably 85 to 185 ° C, particularly preferably 90 to 180 ° C in water or in the air, preferably 1 to 21 days. More preferably 3 to 19 days, still more preferably 5 to 17 days, particularly preferably 7 to 15 days. In water, warm water, in the air, steam curing devices, autoclaves, dryers, etc. can be used. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
本実施形態の高強度コンクリート硬化体の製造方法は、更に、８０℃〜２００℃の気中で１日間〜２１日間養生を行う三次養生工程で行っても良い。
三次養生工程は、好ましくは８０〜２００℃、より好ましくは８３〜１９０℃、更に好ましくは８５〜１８５℃、特に好ましくは９０〜１８０℃の気中で、好ましくは１〜２１日間、より好ましくは３〜１９日間、更に好ましくは５〜１７日間、特に好ましくは７〜１５日間養生を行う。
水中の場合、温水、気中の場合、蒸気養生装置、オートクレーブ、乾燥機などが使用出来る。三次養生工程では、水中よりも気中養生の方が、強度増進の観点からより好ましい。以上の範囲であれば、高い圧縮強度及び高い流動性を十分に確保出来る。
The manufacturing method of the high-strength concrete hardening body of this embodiment may be further performed in a tertiary curing process in which curing is performed in the air at 80 ° C. to 200 ° C. for 1 day to 21 days.
The tertiary curing step is preferably 80 to 200 ° C, more preferably 83 to 190 ° C, still more preferably 85 to 185 ° C, particularly preferably 90 to 180 ° C, preferably 1 to 21 days, more preferably Curing is performed for 3 to 19 days, more preferably 5 to 17 days, particularly preferably 7 to 15 days.
In water, warm water, in the air, steam curing devices, autoclaves, dryers, etc. can be used. In the tertiary curing process, air curing is more preferable than water from the viewpoint of strength enhancement. If it is the above range, high compressive strength and high fluidity | liquidity can fully be ensured.
以下、実施例、参考例及び比較例を挙げて本発明の内容をより具体的に説明する。なお、本発明は下記実施例に限定されるものではない。 Hereinafter, the contents of the present invention will be described more specifically with reference to Examples , Reference Examples and Comparative Examples. In addition, this invention is not limited to the following Example.
［使用材料の準備］
実施例、参考例及び比較例のモルタル組成物を作製するために、以下に示す材料を準備した。
[Preparation of materials used]
In order to prepare the mortar compositions of Examples , Reference Examples and Comparative Examples, the following materials were prepared.
（１）セメント：
使用した２種類のセメントの化学成分を、ＪＩＳ Ｒ ５２０２−２０１０「セメントの化学分析方法」に従い測定し、鉱物組成を下記のボーグ式により算出した。得られたセメントの鉱物組成を表１に示す。
(1) Cement:
The chemical components of the two types of cement used were measured according to JIS R 5202-2010 “Cement chemical analysis method”, and the mineral composition was calculated by the following Borg equation. The mineral composition of the obtained cement is shown in Table 1.
Ｃ３Ｓ量＝（４．０７×ＣａＯ）−（７．６０×ＳｉＯ２）−（６．７２×Ａｌ２Ｏ３）−（１．４３×Ｆｅ２Ｏ３）−（２．８５×ＳＯ３）
Ｃ２Ｓ量＝（２．８７×ＳｉＯ２）−（０．７５４×Ｃ３Ｓ）
Ｃ３Ａ量＝（２．６５×Ａｌ２Ｏ３）−（１．６９×Ｆｅ２Ｏ３）
Ｃ４ＡＦ量＝３．０４×Ｆｅ２Ｏ３
C 3 S amount = (4.07 × CaO) − (7.60 × SiO 2 ) − (6.72 × Al 2 O 3 ) − (1.43 × Fe 2 O 3 ) − (2.85 × SO 3 )
C 2 S amount = (2.87 × SiO 2 ) − (0.754 × C 3 S)
C 3 A amount = (2.65 × Al 2 O 3 ) − (1.69 × Fe 2 O 3 )
C 4 AF amount = 3.04 × Fe 2 O 3
（２）シリカフューム
（Ａ）シリカフュームＡ：密度２．２ｇ／ｃｍ３，ＢＥＴ比表面積２２．８ｍ２／ｇ
(2) Silica fume (A) Silica fume A: density 2.2 g / cm 3 , BET specific surface area 22.8 m 2 / g
（４）細骨材：砕砂：密度２．６２ｇ／ｃｍ３、粗粒率２．８０ (4) Fine aggregate: Crushed sand: Density 2.62 g / cm 3 , coarse particle ratio 2.80
（５）粗骨材
（Ａ）砕石１３０５（安山岩）：密度２．６２ｇ／ｃｍ３、粗粒率２．８０、吸水率２．５質量％
（Ｂ）砕石１３０５（硬質砂岩）：絶乾密度２．６５g／ｃｍ３、粗粒率６．５１、吸水率０．６１質量％
(5) Coarse aggregate (A) Crushed stone 1305 (andesite): density 2.62 g / cm 3 , coarse particle ratio 2.80, water absorption 2.5 mass%
(B) Crushed stone 1305 (hard sandstone): absolutely dry density 2.65 g / cm 3 , coarse particle ratio 6.51 and water absorption 0.61% by mass
（６）減水剤：ポリカルボン酸系高性能減水剤（固形分濃度２５質量％）
（７）消泡剤：特殊非イオン配合型界面活性剤
（８）金属微紛末：
カットスチールウール：日本スチールウール社製、直径２０〜３０μｍ、長さ０．１〜３ｍｍ、密度７．８５ｇ／ｃｍ３
（９）練混ぜ水（Ｗ）：上水道水
(6) Water reducing agent: polycarboxylic acid-based high-performance water reducing agent (solid content concentration 25% by mass)
(7) Antifoaming agent: Special nonionic compound type surfactant (8) Fine metal powder:
Cut steel wool: manufactured by Nippon Steel Wool Co., Ltd., diameter 20-30 μm, length 0.1-3 mm, density 7.85 g / cm 3
(9) Mixing water (W): Tap water
［高強度コンクリート組成物の作製］
高強度コンクリート組成物の作製を、表３の配合組成に基づき、以下の通りに行った。
[Production of high-strength concrete composition]
A high-strength concrete composition was produced as follows based on the composition shown in Table 3.
セメント、シリカフューム消泡剤及び細骨材をモルタルミキサに加え、減水剤を含む練混ぜ水をミキサ内に投入して１０分間撹拌し、その後、粗骨材をミキサに投入して１分３０秒間攪拌し、コンクリート組成物を作製した。なお、実施例１及び参考例２〜４では、金属微紛末を更に投入して、高強度コンクリート組成物を作製した。 Cement, silica fume defoamer and fine aggregate are added to the mortar mixer, mixing water containing a water reducing agent is put into the mixer and stirred for 10 minutes, and then the coarse aggregate is put into the mixer for 1 minute 30 seconds. Stir to produce a concrete composition. In Example 1 and Reference Examples 2 to 4 , metal fine powder was further added to produce a high-strength concrete composition.
［養生方法］
練り混ぜた高強度コンクリート組成物は、型枠に充填後、２０℃、湿度約７０％の気中で３日間養生（前養生工程）後、脱型し、４０℃の水中で３日の一次養生の工程を実施した。その後、二次養生として、９８℃の温水中で７日間養生し、更に、その後、三次養生として、７日間、９８℃の乾燥機で乾燥させた。これらの養生を行い、高強度コンクリート硬化体を作製した。
[Curing method]
Kneaded high-strength concrete composition, after filling into the mold, is cured for 3 days (pre-curing process) in the atmosphere of 20 ° C and humidity of about 70%, then demolded, and primary in 40 ° C water for 3 days A curing process was carried out. Then, as a secondary curing, curing was performed in 98 ° C. warm water for 7 days, and then as a tertiary curing, drying was performed with a 98 ° C. dryer for 7 days. These curings were performed to produce a high-strength concrete hardened body.
［高強度コンクリート組成物の評価］
（１）フレッシュ性状
（試験方法）
比較例１〜３並びに実施例１及び参考例２〜４の配合で作製した高強度コンクリート組成物を用いて、スランプフローを測定した。スランプフローは、ＪＩＳ Ａ １１５０−２００７「コンクリートのスランプフロー試験方法」に準じて測定した。
[Evaluation of high-strength concrete composition]
(1) Fresh properties (test method)
By using high-strength concrete compositions prepared in Comparative Examples 1-3 and Examples 1 and Reference Example 2-4 formulations were measured slump flow. The slump flow was measured according to JIS A 1150-2007 “Concrete slump flow test method”.
（２）強度試験
ＪＩＳ Ａ １１３２−２００６「コンクリートの強度試験用供試体の作り方」に準じて５ｃｍ×１０ｃｍの円柱供試体を作製し、ＪＩＳ Ａ １１０８−２００６「コンクリートの圧縮強度試験方法」に準じて高強度コンクリート硬化体の圧縮強度試験を実施した。
(2) Strength test According to JIS A 1132-2006 “How to make a specimen for concrete strength test”, a 5 cm × 10 cm cylindrical specimen is prepared and according to JIS A 1108-2006 “Concrete compressive strength test method”. The compressive strength test of the high strength concrete hardened body was carried out.
（評価結果）
表４に、スランプフローおよび圧縮強度試験結果を示す。
(Evaluation results)
Table 4 shows the slump flow and compressive strength test results.
比較例１〜３のように，金属微紛末を用いない場合，三次養生後の圧縮強度は約２４０〜２６０Ｎ／ｍｍ２程度であった。
これに対して、実施例１のように、金属微紛末を混入することによって、特に三次養生時の強度の増大量が大きくなり、三次養生後に２８９Ｎ／ｍｍ２と高い圧縮強度が得られた。
参考例２〜３のように、セメント種類を変えた場合にも、三次養生後で２７０Ｎ／ｍｍ２以上の高い圧縮強度が得られた。
参考例４は、参考例３に対して水結合材比を１質量％程低下させたものであるが、強度は若干増大した。
When the metal fine powder powder was not used as in Comparative Examples 1 to 3, the compressive strength after tertiary curing was about 240 to 260 N / mm 2 .
On the other hand, as in Example 1, by adding metal fine powder powder, the amount of increase in strength particularly during tertiary curing was increased, and a high compressive strength of 289 N / mm 2 was obtained after tertiary curing. .
As in Reference Examples 2 to 3, even when the cement type was changed, a high compressive strength of 270 N / mm 2 or more was obtained after tertiary curing.
In Reference Example 4, the water binder ratio was reduced by about 1% by mass compared to Reference Example 3, but the strength was slightly increased.
また、表４に示すように、二次養生の水中養生後に三次養生の気中養生を施すと、非常に高い圧縮強度が得られた。セメントの養生は、一般的に水中で十分に水和させることが重要とされているが、実施例及び参考例の結果からは、寧ろ、ある程度水中養生した後は気中養生した方が良いことが示唆されている。シリカフュームを低水セメント比で使用したコンクリートでは、シリカフュームの水和を十分に行わせることが重要で、気中養生の場合、硬化体の微細な空隙への蒸気の浸透などが起こり易く水和が進行するような現象が起こっていると推察される。 Moreover, as shown in Table 4, when the air curing of the tertiary curing was performed after the water curing of the secondary curing, a very high compressive strength was obtained. In general, it is important for cement to be sufficiently hydrated in water. However, from the results of Examples and Reference Examples , it is better to cure in air after curing to some extent. Has been suggested. In concrete using silica fume at a low water cement ratio, it is important to fully hydrate the silica fume. In the case of air curing, hydration tends to occur due to the penetration of steam into fine voids in the cured body. It is inferred that there is a phenomenon that progresses.
Claims (10)
前記セメントは、Ｃ３Ｓを１０．０質量％〜２５．０質量％及びＣ２Ｓを５５．０質量％〜７０．０質量％含有することを特徴とする高強度コンクリート組成物。 A high-strength concrete composition comprising cement, silica fume , water, fine aggregate, coarse aggregate, water reducing agent, antifoaming agent, and metal fine powder,
The cement, C 3 S 10.0 wt% to 25.0 wt% and C 2 S with high-strength concrete composition characterized Rukoto that Yusuke containing 55.0 wt% 70.0 wt%.
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| JP7068655B2 (en) * | 2018-06-08 | 2022-05-17 | 住友大阪セメント株式会社 | High-strength concrete composition and high-strength concrete hardened body |
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| JPS59102849A (en) * | 1982-12-01 | 1984-06-14 | 電気化学工業株式会社 | Super high strength cement hardened body |
| JPS62207752A (en) * | 1986-03-10 | 1987-09-12 | 電気化学工業株式会社 | High strength hydraulic composition |
| US4780141A (en) * | 1986-08-08 | 1988-10-25 | Cemcom Corporation | Cementitious composite material containing metal fiber |
| JPH07291765A (en) * | 1994-04-21 | 1995-11-07 | Nippon Steel Corp | Aging method of cement molding |
| JP2001270762A (en) * | 2000-03-29 | 2001-10-02 | Taiheiyo Cement Corp | Grouting mortar composition for prepacked concrete |
| JP4558569B2 (en) * | 2005-04-18 | 2010-10-06 | 電気化学工業株式会社 | Ultra high strength fiber reinforced cement composition, ultra high strength fiber reinforced mortar or concrete, and ultra high strength cement admixture |
| JP5592307B2 (en) * | 2010-05-18 | 2014-09-17 | 大成建設株式会社 | Method for producing high-strength concrete and concrete member |
| JP6022747B2 (en) * | 2011-01-14 | 2016-11-09 | 株式会社大林組 | High strength mortar composition |
| JP5702608B2 (en) * | 2011-01-14 | 2015-04-15 | 株式会社大林組 | High strength mortar composition |
| JP6205843B2 (en) * | 2013-05-24 | 2017-10-04 | 宇部興産株式会社 | High-strength cement paste composition and method for producing high-strength cement paste hardened body |
| JP6530890B2 (en) * | 2013-06-17 | 2019-06-12 | 宇部興産株式会社 | High strength cement mortar composition and method of producing hardened high strength cement mortar |
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