JP6360068B2 - 熱老化耐性エチレン酢酸ビニルコポリマー組成物およびその製造方法 - Google Patents
熱老化耐性エチレン酢酸ビニルコポリマー組成物およびその製造方法 Download PDFInfo
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- JP6360068B2 JP6360068B2 JP2015545794A JP2015545794A JP6360068B2 JP 6360068 B2 JP6360068 B2 JP 6360068B2 JP 2015545794 A JP2015545794 A JP 2015545794A JP 2015545794 A JP2015545794 A JP 2015545794A JP 6360068 B2 JP6360068 B2 JP 6360068B2
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- Prior art keywords
- vinyl acetate
- ethylene vinyl
- polyamide
- composition
- blend
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 373
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- 239000005038 ethylene vinyl acetate Substances 0.000 title claims description 135
- 238000000034 method Methods 0.000 title claims description 36
- 230000008569 process Effects 0.000 title claims description 17
- 230000032683 aging Effects 0.000 title description 18
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- 239000004952 Polyamide Substances 0.000 claims description 243
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- 239000000806 elastomer Substances 0.000 claims description 166
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- 150000002978 peroxides Chemical class 0.000 claims description 83
- 239000000178 monomer Substances 0.000 claims description 51
- 238000002844 melting Methods 0.000 claims description 45
- 230000008018 melting Effects 0.000 claims description 45
- 239000003795 chemical substances by application Substances 0.000 claims description 41
- 238000002156 mixing Methods 0.000 claims description 39
- 229920001577 copolymer Polymers 0.000 claims description 30
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 24
- 239000005977 Ethylene Substances 0.000 claims description 23
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 18
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- 238000002425 crystallisation Methods 0.000 claims description 10
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- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 6
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 claims 3
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 claims 3
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- 125000004432 carbon atom Chemical group C* 0.000 description 18
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- 239000004953 Aliphatic polyamide Substances 0.000 description 5
- XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 description 5
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- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 241001441571 Hiodontidae Species 0.000 description 4
- 229920003346 Levapren® Polymers 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- UJAWGGOCYUPCPS-UHFFFAOYSA-N 4-(2-phenylpropan-2-yl)-n-[4-(2-phenylpropan-2-yl)phenyl]aniline Chemical compound C=1C=C(NC=2C=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C=CC=1C(C)(C)C1=CC=CC=C1 UJAWGGOCYUPCPS-UHFFFAOYSA-N 0.000 description 3
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- 125000005907 alkyl ester group Chemical group 0.000 description 3
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- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
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- 125000004093 cyano group Chemical group *C#N 0.000 description 1
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- JMLPVHXESHXUSV-UHFFFAOYSA-N dodecane-1,1-diamine Chemical compound CCCCCCCCCCCC(N)N JMLPVHXESHXUSV-UHFFFAOYSA-N 0.000 description 1
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 1
- ZMUCVNSKULGPQG-UHFFFAOYSA-N dodecanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCCCC(O)=O ZMUCVNSKULGPQG-UHFFFAOYSA-N 0.000 description 1
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- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 description 1
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
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- TUWYJOPPRPXZQX-UHFFFAOYSA-N tetradecane-2,3-dione Chemical compound CCCCCCCCCCCC(=O)C(C)=O TUWYJOPPRPXZQX-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0853—Ethene vinyl acetate copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
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| US61/733,081 | 2012-12-04 | ||
| PCT/US2013/072954 WO2014089136A1 (en) | 2012-12-04 | 2013-12-04 | Heat aging resistant ethylene vinyl acetate copolymer composition and process for its production |
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| JP2016520666A JP2016520666A (ja) | 2016-07-14 |
| JP2016520666A5 JP2016520666A5 (enExample) | 2016-12-28 |
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| WO (1) | WO2014089136A1 (enExample) |
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| US20140072789A1 (en) * | 2012-09-12 | 2014-03-13 | E I Du Pont De Nemours And Company | Heat aging resistant ethylene vinyl acetate copolymer composition and process for its production |
| US9062193B2 (en) * | 2012-12-04 | 2015-06-23 | E. I. Du Pont De Nemours And Company | Heat aging resistant ethylene vinyl acetate copolymer composition and process for its production |
| US20150140246A1 (en) * | 2013-11-20 | 2015-05-21 | E I Du Pont De Nemours And Company | Heat resistant ethylene vinyl acetate copolymer composition and process for its production |
| WO2015084336A1 (en) * | 2013-12-04 | 2015-06-11 | E. I. Du Pont De Nemours And Company | Heat resistant ethylene vinyl acetate copolymer composition and process for its production |
| CN104788799B (zh) * | 2015-04-21 | 2017-06-16 | 江苏德威新材料股份有限公司 | 环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法 |
| BR112018009918B1 (pt) * | 2015-12-02 | 2020-09-01 | Toyobo Co., Ltd | Composição de resina poliamida reforçada com fibra de vidro, e produto moldado para uso no interior do veículo ou no exterior do veículo |
| CN106349685A (zh) * | 2016-08-26 | 2017-01-25 | 宁波市青湖弹性体科技有限公司 | 一种高耐油的充电桩无卤阻燃tpu线缆料及其制备方法 |
| WO2019043625A1 (en) * | 2017-09-01 | 2019-03-07 | 3M Innovative Properties Company | COLD STRETCHED POLYOLEFIN COPOLYMER CORD FOR EAR PLUGS |
| CN111492002A (zh) | 2017-12-21 | 2020-08-04 | 阿朗新科德国有限责任公司 | 具有改进的热空气耐受性的固化hnbr产品 |
| US11518971B2 (en) * | 2018-11-27 | 2022-12-06 | Research Triangle Institute | Method and apparatus for spatial control of cellular growth |
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| US2933480A (en) | 1959-06-17 | 1960-04-19 | Du Pont | Sulfur vulcanizable unsaturated elastomeric interpolymers of monoolefins and diolefins |
| US3965055A (en) | 1972-09-21 | 1976-06-22 | Uniroyal Inc. | Free curing rubber composition |
| US4174358A (en) | 1975-05-23 | 1979-11-13 | E. I. Du Pont De Nemours And Company | Tough thermoplastic nylon compositions |
| GB1603205A (en) | 1977-04-12 | 1981-11-18 | Raychem Ltd | Polymer compositions |
| US4310638A (en) | 1980-08-20 | 1982-01-12 | Monsanto Company | Nylon modified acrylic copolymer rubber |
| DE3403576A1 (de) | 1984-02-02 | 1985-08-08 | Basf Ag, 6700 Ludwigshafen | Elastomere thermoplastische formmassen und deren herstellung |
| FR2580656B1 (fr) | 1985-04-23 | 1987-09-11 | Charbonnages Ste Chimique | Compositions thermoplastiques multiphases et articles obtenus |
| JPS6431866A (en) * | 1987-07-27 | 1989-02-02 | Unitika Ltd | Resin composition |
| US5591798A (en) | 1988-04-11 | 1997-01-07 | Advanced Elastomer Systems, L.P. | High temperature stable, low solvent swelling thermoplastic elastomer compositions |
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2013
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- 2013-12-04 CN CN201380063860.3A patent/CN104837919B/zh active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| CN104837919A (zh) | 2015-08-12 |
| US20170066916A9 (en) | 2017-03-09 |
| CN104837919B (zh) | 2018-01-30 |
| US9062193B2 (en) | 2015-06-23 |
| EP2928960A1 (en) | 2015-10-14 |
| JP2016520666A (ja) | 2016-07-14 |
| US20140155552A1 (en) | 2014-06-05 |
| US9650508B2 (en) | 2017-05-16 |
| US20150247030A1 (en) | 2015-09-03 |
| WO2014089136A1 (en) | 2014-06-12 |
| ES2664334T3 (es) | 2018-04-19 |
| EP2928960B1 (en) | 2018-01-31 |
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