JP6358799B2 - 吸収式ヒートポンプのための作動媒体 - Google Patents
吸収式ヒートポンプのための作動媒体 Download PDFInfo
- Publication number
- JP6358799B2 JP6358799B2 JP2013538135A JP2013538135A JP6358799B2 JP 6358799 B2 JP6358799 B2 JP 6358799B2 JP 2013538135 A JP2013538135 A JP 2013538135A JP 2013538135 A JP2013538135 A JP 2013538135A JP 6358799 B2 JP6358799 B2 JP 6358799B2
- Authority
- JP
- Japan
- Prior art keywords
- working medium
- refrigerant
- ionic liquid
- ethyl
- heat pump
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000010521 absorption reaction Methods 0.000 title claims description 51
- 239000002608 ionic liquid Substances 0.000 claims description 55
- 239000003507 refrigerant Substances 0.000 claims description 55
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 150000002892 organic cations Chemical class 0.000 claims description 21
- 239000006096 absorbing agent Substances 0.000 claims description 17
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 claims description 14
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims description 14
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 5
- XIYUIMLQTKODPS-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;acetate Chemical compound CC([O-])=O.CC[N+]=1C=CN(C)C=1 XIYUIMLQTKODPS-UHFFFAOYSA-M 0.000 claims description 4
- QLKGUVGAXDXFFW-UHFFFAOYSA-M 2-hydroxyethyl(trimethyl)azanium;acetate Chemical compound CC([O-])=O.C[N+](C)(C)CCO QLKGUVGAXDXFFW-UHFFFAOYSA-M 0.000 claims description 4
- HQWOEDCLDNFWEV-UHFFFAOYSA-M diethyl phosphate;1-ethyl-3-methylimidazol-3-ium Chemical compound CC[N+]=1C=CN(C)C=1.CCOP([O-])(=O)OCC HQWOEDCLDNFWEV-UHFFFAOYSA-M 0.000 claims description 4
- ZQUXGQXJZVCUDD-UHFFFAOYSA-M 1,3-dimethylimidazol-1-ium;acetate Chemical compound CC([O-])=O.CN1C=C[N+](C)=C1 ZQUXGQXJZVCUDD-UHFFFAOYSA-M 0.000 claims description 3
- JUJGLVPPDJTGCT-UHFFFAOYSA-M 1,3-dimethylimidazol-1-ium;propanoate Chemical compound CCC([O-])=O.CN1C=C[N+](C)=C1 JUJGLVPPDJTGCT-UHFFFAOYSA-M 0.000 claims description 3
- BMQZYMYBQZGEEY-UHFFFAOYSA-M 1-ethyl-3-methylimidazolium chloride Chemical compound [Cl-].CCN1C=C[N+](C)=C1 BMQZYMYBQZGEEY-UHFFFAOYSA-M 0.000 claims description 3
- WTKUDOCGUOSPGV-UHFFFAOYSA-M dimethyl phosphate;1-ethyl-3-methylimidazol-3-ium Chemical compound COP([O-])(=O)OC.CC[N+]=1C=CN(C)C=1 WTKUDOCGUOSPGV-UHFFFAOYSA-M 0.000 claims description 3
- FHDQNOXQSTVAIC-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;chloride Chemical compound [Cl-].CCCCN1C=C[N+](C)=C1 FHDQNOXQSTVAIC-UHFFFAOYSA-M 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
- -1 aliphatic alcohols Chemical class 0.000 description 27
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 20
- 239000002594 sorbent Substances 0.000 description 18
- 150000001450 anions Chemical class 0.000 description 15
- 238000005260 corrosion Methods 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- IDFANOPDMXWIOP-UHFFFAOYSA-O dimethyl(pentyl)azanium Chemical compound CCCCC[NH+](C)C IDFANOPDMXWIOP-UHFFFAOYSA-O 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000007872 degassing Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229910001369 Brass Inorganic materials 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000001449 anionic compounds Chemical class 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 229910001412 inorganic anion Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical class N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- NILDVBKEQHKFLO-UHFFFAOYSA-M 1,3-diethylimidazol-1-ium;diethyl phosphate Chemical compound CCOP([O-])(=O)OCC.CCN1C=C[N+](CC)=C1 NILDVBKEQHKFLO-UHFFFAOYSA-M 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- WCPLIVGFHVMPRG-UHFFFAOYSA-M 1-butyl-1-methylpyrrolidin-1-ium;acetate Chemical compound CC([O-])=O.CCCC[N+]1(C)CCCC1 WCPLIVGFHVMPRG-UHFFFAOYSA-M 0.000 description 2
- SUZSCMCVEGBGHA-UHFFFAOYSA-N 1-butyl-4-methylpiperidin-1-ium;acetate Chemical compound CC([O-])=O.CCCC[NH+]1CCC(C)CC1 SUZSCMCVEGBGHA-UHFFFAOYSA-N 0.000 description 2
- LRRVBLSOIBDURC-UHFFFAOYSA-M 1-butylpyridin-1-ium;acetate Chemical compound CC([O-])=O.CCCC[N+]1=CC=CC=C1 LRRVBLSOIBDURC-UHFFFAOYSA-M 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- LMKUDAHQVXSELX-UHFFFAOYSA-M 1-methylpyridin-1-ium;acetate Chemical compound CC([O-])=O.C[N+]1=CC=CC=C1 LMKUDAHQVXSELX-UHFFFAOYSA-M 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- HPYNZHMRTTWQTB-UHFFFAOYSA-N 2,3-dimethylpyridine Chemical compound CC1=CC=CN=C1C HPYNZHMRTTWQTB-UHFFFAOYSA-N 0.000 description 2
- JGVSZDFHWNPMMA-UHFFFAOYSA-M 2-hydroxyacetate;2-hydroxyethyl(trimethyl)azanium Chemical compound OCC([O-])=O.C[N+](C)(C)CCO JGVSZDFHWNPMMA-UHFFFAOYSA-M 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910001060 Gray iron Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical class C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical class C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical class N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- XLJMAIOERFSOGZ-UHFFFAOYSA-N cyanic acid Chemical compound OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical class C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 150000002891 organic anions Chemical class 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- BBDSPKMOLMUQSV-UHFFFAOYSA-M 1,1-dimethylpyrrolidin-1-ium;acetate Chemical compound CC([O-])=O.C[N+]1(C)CCCC1 BBDSPKMOLMUQSV-UHFFFAOYSA-M 0.000 description 1
- HMIJTIBXFUDKFV-UHFFFAOYSA-M 1,3-diethylimidazol-1-ium;dimethyl phosphate Chemical compound COP([O-])(=O)OC.CCN1C=C[N+](CC)=C1 HMIJTIBXFUDKFV-UHFFFAOYSA-M 0.000 description 1
- WOKQGMYCUGJNIJ-UHFFFAOYSA-M 1,3-dimethylimidazol-1-ium;methyl sulfate Chemical compound COS([O-])(=O)=O.CN1C=C[N+](C)=C1 WOKQGMYCUGJNIJ-UHFFFAOYSA-M 0.000 description 1
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 description 1
- POKOASTYJWUQJG-UHFFFAOYSA-M 1-butylpyridin-1-ium;chloride Chemical compound [Cl-].CCCC[N+]1=CC=CC=C1 POKOASTYJWUQJG-UHFFFAOYSA-M 0.000 description 1
- NZTSXIYKZKXSHJ-UHFFFAOYSA-L 1-ethyl-3-methylimidazol-3-ium;ethyl phosphate Chemical compound CCOP([O-])([O-])=O.CCN1C=C[N+](C)=C1.CCN1C=C[N+](C)=C1 NZTSXIYKZKXSHJ-UHFFFAOYSA-L 0.000 description 1
- VRFOKYHDLYBVAL-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;ethyl sulfate Chemical compound CCOS([O-])(=O)=O.CCN1C=C[N+](C)=C1 VRFOKYHDLYBVAL-UHFFFAOYSA-M 0.000 description 1
- HZKDSQCZNUUQIF-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;hydrogen sulfate Chemical compound OS([O-])(=O)=O.CCN1C=C[N+](C)=C1 HZKDSQCZNUUQIF-UHFFFAOYSA-M 0.000 description 1
- GQUDFUNCZROOCL-UHFFFAOYSA-L 1-ethyl-3-methylimidazol-3-ium;methyl phosphate Chemical compound COP([O-])([O-])=O.CC[N+]=1C=CN(C)C=1.CC[N+]=1C=CN(C)C=1 GQUDFUNCZROOCL-UHFFFAOYSA-L 0.000 description 1
- BXSDLSWVIAITRQ-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCN1C=C[N+](C)=C1 BXSDLSWVIAITRQ-UHFFFAOYSA-M 0.000 description 1
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 description 1
- QAIGYXWRIHZZAA-UHFFFAOYSA-M 1-methylpyridin-1-ium;chloride Chemical compound [Cl-].C[N+]1=CC=CC=C1 QAIGYXWRIHZZAA-UHFFFAOYSA-M 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- BKMMTJMQCTUHRP-UHFFFAOYSA-N 2-aminopropan-1-ol Chemical compound CC(N)CO BKMMTJMQCTUHRP-UHFFFAOYSA-N 0.000 description 1
- NRGGMCIBEHEAIL-UHFFFAOYSA-N 2-ethylpyridine Chemical compound CCC1=CC=CC=N1 NRGGMCIBEHEAIL-UHFFFAOYSA-N 0.000 description 1
- LCFKURIJYIJNRU-UHFFFAOYSA-N 2-methylhexan-1-ol Chemical compound CCCCC(C)CO LCFKURIJYIJNRU-UHFFFAOYSA-N 0.000 description 1
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 1
- BODRLKRKPXBDBN-UHFFFAOYSA-N 3,5,5-Trimethyl-1-hexanol Chemical compound OCCC(C)CC(C)(C)C BODRLKRKPXBDBN-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- KKUKTXOBAWVSHC-UHFFFAOYSA-N Dimethylphosphate Chemical compound COP(O)(=O)OC KKUKTXOBAWVSHC-UHFFFAOYSA-N 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Natural products OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- 229910018119 Li 3 PO 4 Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Chemical class C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical class C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 description 1
- WCZVZNOTHYJIEI-UHFFFAOYSA-N cinnoline Chemical class N1=NC=CC2=CC=CC=C21 WCZVZNOTHYJIEI-UHFFFAOYSA-N 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 description 1
- URSLCTBXQMKCFE-UHFFFAOYSA-N dihydrogenborate Chemical compound OB(O)[O-] URSLCTBXQMKCFE-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 1
- KKUKTXOBAWVSHC-UHFFFAOYSA-M dimethyl phosphate Chemical compound COP([O-])(=O)OC KKUKTXOBAWVSHC-UHFFFAOYSA-M 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Chemical class CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Chemical class C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate Chemical compound [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- CTAPFRYPJLPFDF-UHFFFAOYSA-N isoxazole Chemical compound C=1C=NOC=1 CTAPFRYPJLPFDF-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- LFSXCDWNBUNEEM-UHFFFAOYSA-N phthalazine Chemical class C1=NN=CC2=CC=CC=C21 LFSXCDWNBUNEEM-UHFFFAOYSA-N 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229910052717 sulfur Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- MRYQZMHVZZSQRT-UHFFFAOYSA-M tetramethylazanium;acetate Chemical compound CC([O-])=O.C[N+](C)(C)C MRYQZMHVZZSQRT-UHFFFAOYSA-M 0.000 description 1
- WWIYWFVQZQOECA-UHFFFAOYSA-M tetramethylazanium;formate Chemical compound [O-]C=O.C[N+](C)(C)C WWIYWFVQZQOECA-UHFFFAOYSA-M 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Sorption Type Refrigeration Machines (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10190356 | 2010-11-08 | ||
| EP10190356.5 | 2010-11-08 | ||
| PCT/EP2011/069402 WO2012062656A1 (de) | 2010-11-08 | 2011-11-04 | Arbeitsmedium für absorptionswärmepumpen |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016225187A Division JP2017036914A (ja) | 2010-11-08 | 2016-11-18 | 吸収式ヒートポンプのための作動媒体 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013543965A JP2013543965A (ja) | 2013-12-09 |
| JP2013543965A5 JP2013543965A5 (enExample) | 2017-01-12 |
| JP6358799B2 true JP6358799B2 (ja) | 2018-07-18 |
Family
ID=43760011
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013538135A Expired - Fee Related JP6358799B2 (ja) | 2010-11-08 | 2011-11-04 | 吸収式ヒートポンプのための作動媒体 |
| JP2016225187A Pending JP2017036914A (ja) | 2010-11-08 | 2016-11-18 | 吸収式ヒートポンプのための作動媒体 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016225187A Pending JP2017036914A (ja) | 2010-11-08 | 2016-11-18 | 吸収式ヒートポンプのための作動媒体 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20130219949A1 (enExample) |
| EP (1) | EP2638123B1 (enExample) |
| JP (2) | JP6358799B2 (enExample) |
| KR (1) | KR101404833B1 (enExample) |
| CN (1) | CN103189466B (enExample) |
| BR (1) | BR112013007941A2 (enExample) |
| CA (1) | CA2817264C (enExample) |
| MY (1) | MY153070A (enExample) |
| PH (1) | PH12013500344A1 (enExample) |
| SG (1) | SG188955A1 (enExample) |
| WO (1) | WO2012062656A1 (enExample) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2088389B1 (de) * | 2008-02-05 | 2017-05-10 | Evonik Degussa GmbH | Absorptionskältemaschine |
| EP2087930A1 (de) * | 2008-02-05 | 2009-08-12 | Evonik Degussa GmbH | Verfahren zur Absorption eines flüchtigen Stoffes in einem flüssigen Absorptionsmittel |
| DE102009000543A1 (de) | 2009-02-02 | 2010-08-12 | Evonik Degussa Gmbh | Verfahren, Absorptionsmedien und Vorrichtung zur Absorption von CO2 aus Gasmischungen |
| DE102009047564A1 (de) | 2009-12-07 | 2011-06-09 | Evonik Degussa Gmbh | Arbeitsmedium für eine Absorptionskältemaschine |
| DE102011077377A1 (de) | 2010-11-12 | 2012-05-16 | Evonik Degussa Gmbh | Verfahren zur Absorption von sauren Gasen aus Gasmischungen |
| PH12014500533A1 (en) | 2011-11-14 | 2014-04-21 | Evonik Degussa Gmbh | Method and device for the separation of acidic gases from a gas mixture |
| DE102012200907A1 (de) | 2012-01-23 | 2013-07-25 | Evonik Industries Ag | Verfahren und Absorptionsmedium zur Absorption von CO2 aus einer Gasmischung |
| WO2013113461A1 (en) * | 2012-02-02 | 2013-08-08 | Vtu Holding Gmbh | Ionic liquids for cooling in high temperature environment |
| DE102012207509A1 (de) | 2012-05-07 | 2013-11-07 | Evonik Degussa Gmbh | Verfahren zur Absorption von CO2 aus einer Gasmischung |
| EP2735820A1 (de) * | 2012-11-21 | 2014-05-28 | Evonik Industries AG | Absorptionswärmepumpe und Sorptionsmittel für eine Absorptionswärmepumpe umfassend Methansulfonsäure |
| CN104592942B (zh) * | 2014-12-24 | 2017-11-24 | 巨化集团技术中心 | 一种阻燃型制冷剂及其制备方法 |
| DE102015212749A1 (de) | 2015-07-08 | 2017-01-12 | Evonik Degussa Gmbh | Verfahren zur Entfeuchtung von feuchten Gasgemischen |
| DE102016106234B4 (de) * | 2016-04-06 | 2022-03-03 | Fahrenheit Gmbh | Adsorptionswärmepumpe und Verfahren zum Betreiben einer Adsorptionswärmepumpe |
| JP2019517654A (ja) * | 2016-05-26 | 2019-06-24 | 矢崎総業株式会社 | 吸収式冷凍機におけるグアニジニウム系イオン液体 |
| US10168080B2 (en) * | 2016-05-26 | 2019-01-01 | Yazaki Corporation | Eutectic mixtures of ionic liquids in absorption chillers |
| EP3257843A1 (en) | 2016-06-14 | 2017-12-20 | Evonik Degussa GmbH | Method of preparing a high purity imidazolium salt |
| DE102016210481B3 (de) | 2016-06-14 | 2017-06-08 | Evonik Degussa Gmbh | Verfahren zum Reinigen einer ionischen Flüssigkeit |
| DE102016210484A1 (de) * | 2016-06-14 | 2017-12-14 | Evonik Degussa Gmbh | Verfahren zur Entfeuchtung von feuchten Gasgemischen |
| DE102016210478A1 (de) * | 2016-06-14 | 2017-12-14 | Evonik Degussa Gmbh | Verfahren zur Entfeuchtung von feuchten Gasgemischen |
| EP3257568B1 (de) | 2016-06-14 | 2019-09-18 | Evonik Degussa GmbH | Verfahren zur entfeuchtung von feuchten gasgemischen mit ionischen flüssigkeiten |
| DE102016210483A1 (de) | 2016-06-14 | 2017-12-14 | Evonik Degussa Gmbh | Verfahren und Absorptionsmittel zur Entfeuchtung von feuchten Gasgemischen |
| JP6729453B2 (ja) * | 2017-03-07 | 2020-07-22 | 株式会社デンソー | 熱媒体用基材、並びにそれを用いた熱輸送システムおよびヒートポンプシステム |
| KR102482452B1 (ko) | 2017-09-28 | 2022-12-29 | 삼성디스플레이 주식회사 | 유기 재료 정제 조성물 및 이를 이용한 유기 재료 정제 방법 |
| JP7054874B2 (ja) * | 2018-08-23 | 2022-04-15 | パナソニックＩｐマネジメント株式会社 | 液体吸湿材料を用いた調湿システムおよびこれを備える空気調和装置 |
| JP7054876B2 (ja) * | 2018-08-23 | 2022-04-15 | パナソニックＩｐマネジメント株式会社 | 液体吸湿材料を用いた調湿システムおよびこれを備える空気調和装置 |
| JP7054875B2 (ja) * | 2018-08-23 | 2022-04-15 | パナソニックＩｐマネジメント株式会社 | 液体吸湿材料を用いた調湿システムおよびこれを備える空気調和装置 |
| JP7054873B2 (ja) * | 2018-08-23 | 2022-04-15 | パナソニックＩｐマネジメント株式会社 | 液体吸湿材料を用いた調湿システムおよびこれを備える空気調和装置、並びに、調湿システム用液体吸湿材料 |
| WO2020114576A1 (en) | 2018-12-04 | 2020-06-11 | Evonik Operations Gmbh | Process for dehumidifying moist gas mixtures |
| EP3757189A1 (en) * | 2019-06-26 | 2020-12-30 | Evonik Operations GmbH | Use of ionic liquids as coolants for vehicle engines, motors and batteries |
| KR102524486B1 (ko) * | 2021-09-24 | 2023-04-20 | 고려대학교 산학협력단 | 흡수식 에너지 저장 및 냉난방 동시 활용 시스템 |
| EP4282890A1 (de) | 2022-05-25 | 2023-11-29 | Evonik Operations GmbH | Herstellung von polyurethanschaum unter verwendung von ionischen flüssigkeiten |
| EP4282892A1 (de) | 2022-05-25 | 2023-11-29 | Evonik Operations GmbH | Herstellung von polyurethanschaum unter verwendung von katalysatoren auf basis ionischer flüssigkeiten |
| CN116790225A (zh) * | 2023-06-14 | 2023-09-22 | 东方电气集团东方锅炉股份有限公司 | 一种低温热源驱动下的吸收式制冷工质对 |
| CN119924302A (zh) * | 2023-11-03 | 2025-05-06 | 中国石油天然气股份有限公司 | 增强杀菌缓蚀剂配伍性的助剂和杀菌缓蚀剂及其应用 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3276217A (en) | 1965-11-09 | 1966-10-04 | Carrier Corp | Maintaining the effectiveness of an additive in absorption refrigeration systems |
| US3609087A (en) | 1968-02-01 | 1971-09-28 | American Gas Ass Inc The | Secondary alcohol additives for lithium bromide-water absorption refrigeration system |
| US3580759A (en) * | 1968-06-25 | 1971-05-25 | Borg Warner | Heat transfer additives for absorbent solutions |
| JPS606779A (ja) * | 1983-06-27 | 1985-01-14 | Sanyo Electric Co Ltd | 吸収冷凍機用の組成物 |
| JPH01198679A (ja) * | 1987-10-16 | 1989-08-10 | Kawasaki Heavy Ind Ltd | 吸収冷凍機用吸収液 |
| JPH076704B2 (ja) * | 1988-01-20 | 1995-01-30 | 矢崎総業株式会社 | 吸収冷凍機の吸収液 |
| JP2512095B2 (ja) * | 1988-08-12 | 1996-07-03 | 株式会社日立製作所 | 冷熱発生方法 |
| US5390509A (en) * | 1991-11-27 | 1995-02-21 | Rocky Research | Triple effect absorption cycle apparatus |
| JP3013673B2 (ja) * | 1993-11-12 | 2000-02-28 | 株式会社日立製作所 | 吸収冷凍機 |
| JPH07139839A (ja) * | 1993-11-19 | 1995-06-02 | Sekiyu Sangyo Kasseika Center | 吸収式冷温水機の吸収促進剤 |
| JPH09104862A (ja) * | 1995-02-27 | 1997-04-22 | Asahi Glass Co Ltd | 吸収冷凍機用組成物および吸収冷凍機 |
| DE29516319U1 (de) * | 1995-10-14 | 1996-02-01 | ABSOTECH Energiesparsysteme GmbH & Co. KG, 83646 Bad Tölz | Absorptionswärmetransformationsanlage mit Zusatzkomponenten zur Steigerung der Nutzleistung bzw. Erweiterung der Grenzen für die Antriebs-, Nutz- oder Kühltemperaturen |
| JP2002098449A (ja) * | 2000-09-22 | 2002-04-05 | Mitsubishi Heavy Ind Ltd | 吸収冷凍機 |
| JP2002228291A (ja) * | 2001-01-30 | 2002-08-14 | Kawasaki Thermal Engineering Co Ltd | 吸収冷凍機 |
| DE102004024967A1 (de) * | 2004-05-21 | 2005-12-08 | Basf Ag | Neue Absorptionsmedien für Absorptionswärmepumpen, Absorptionskältemaschinen und Wärmetransformatoren |
| US8715521B2 (en) * | 2005-02-04 | 2014-05-06 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquid as working fluid |
| DE102005028451B4 (de) | 2005-06-17 | 2017-02-16 | Evonik Degussa Gmbh | Verfahren zum Transport von Wärme |
| US8506839B2 (en) * | 2005-12-14 | 2013-08-13 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquids and water as working fluids |
| EP2129737B1 (en) * | 2007-04-03 | 2012-10-17 | E. I. Du Pont de Nemours and Company | Heat transfer systems using mixtures of polyols and ionic liquids |
| JP2008267667A (ja) * | 2007-04-18 | 2008-11-06 | Hitachi Building Systems Co Ltd | 吸収式冷温水機用吸収液および吸収式冷温水機 |
| EP2087930A1 (de) | 2008-02-05 | 2009-08-12 | Evonik Degussa GmbH | Verfahren zur Absorption eines flüchtigen Stoffes in einem flüssigen Absorptionsmittel |
| EP2093278A1 (de) | 2008-02-05 | 2009-08-26 | Evonik Goldschmidt GmbH | Performance-Additive zur Verbesserung der Benetzungseigenschaften von ionischen Flüssigkeiten auf festen Oberflächen |
| EP2087931A3 (de) * | 2008-02-05 | 2011-08-31 | Evonik Goldschmidt GmbH | Entschäumung von ionischen Flüssigkeiten |
| EP2088389B1 (de) * | 2008-02-05 | 2017-05-10 | Evonik Degussa GmbH | Absorptionskältemaschine |
| KR20110095282A (ko) * | 2008-11-07 | 2011-08-24 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 작동 유체로서 이온성 화합물 및/또는 비이온성 흡수제를 이용하는 흡수 사이클 |
| CN102449101A (zh) * | 2009-03-31 | 2012-05-09 | 纳幕尔杜邦公司 | 溴化锂/水吸收循环系统中的离子化合物 |
| EP2246651A2 (de) * | 2009-04-27 | 2010-11-03 | Basf Se | Absorptionswärmepumpen, Absorptionskältemaschinen und Absorptionswärmetransformatoren auf Basis EMIM-acetat / Methanol |
| DE102009047564A1 (de) * | 2009-12-07 | 2011-06-09 | Evonik Degussa Gmbh | Arbeitsmedium für eine Absorptionskältemaschine |
| EP2380941A1 (de) * | 2010-04-20 | 2011-10-26 | Evonik Degussa GmbH | Absorptionswärmepumpe mit Sorptionsmittel umfassend ein Lithiumsalz und ein organisches Salz mit gleichem Anion |
-
2011
- 2011-11-04 EP EP11778629.3A patent/EP2638123B1/de not_active Not-in-force
- 2011-11-04 KR KR1020137014601A patent/KR101404833B1/ko not_active Expired - Fee Related
- 2011-11-04 SG SG2013016167A patent/SG188955A1/en unknown
- 2011-11-04 MY MYPI2013000868 patent/MY153070A/en unknown
- 2011-11-04 PH PH1/2013/500344A patent/PH12013500344A1/en unknown
- 2011-11-04 US US13/883,573 patent/US20130219949A1/en not_active Abandoned
- 2011-11-04 JP JP2013538135A patent/JP6358799B2/ja not_active Expired - Fee Related
- 2011-11-04 BR BR112013007941A patent/BR112013007941A2/pt not_active IP Right Cessation
- 2011-11-04 CA CA2817264A patent/CA2817264C/en not_active Expired - Fee Related
- 2011-11-04 WO PCT/EP2011/069402 patent/WO2012062656A1/de not_active Ceased
- 2011-11-04 CN CN201180051909.4A patent/CN103189466B/zh not_active Expired - Fee Related
-
2016
- 2016-11-18 JP JP2016225187A patent/JP2017036914A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CA2817264C (en) | 2016-12-13 |
| HK1187070A1 (zh) | 2014-03-28 |
| CA2817264A1 (en) | 2012-05-18 |
| CN103189466B (zh) | 2016-01-06 |
| JP2017036914A (ja) | 2017-02-16 |
| KR20130100349A (ko) | 2013-09-10 |
| BR112013007941A2 (pt) | 2016-06-14 |
| WO2012062656A1 (de) | 2012-05-18 |
| SG188955A1 (en) | 2013-05-31 |
| EP2638123A1 (de) | 2013-09-18 |
| JP2013543965A (ja) | 2013-12-09 |
| PH12013500344A1 (en) | 2013-03-25 |
| KR101404833B1 (ko) | 2014-06-09 |
| MY153070A (en) | 2014-12-31 |
| EP2638123B1 (de) | 2016-08-31 |
| CN103189466A (zh) | 2013-07-03 |
| US20130219949A1 (en) | 2013-08-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6358799B2 (ja) | 吸収式ヒートポンプのための作動媒体 | |
| JP6161717B2 (ja) | 吸収式ヒートポンプ、並びにメタンスルホン酸を含有する、吸収式ヒートポンプ用の吸収剤 | |
| US8069687B2 (en) | Working media for refrigeration processes | |
| JP5479611B2 (ja) | 吸収式冷凍機用作動媒体 | |
| US20170321101A1 (en) | Refrigeration System With Dual Refrigerants and Liquid Working Fluids | |
| JP5748794B2 (ja) | 吸収式ヒートポンプの動作方法 | |
| JP2013543965A5 (enExample) | ||
| JP2012522872A (ja) | 温度調整装置 | |
| JP2012522963A (ja) | 温度調整装置 | |
| JP2022517053A (ja) | 吸収式冷凍機における吸収剤として使用するためのイオン液体添加剤 | |
| HK1187070B (en) | Working medium for absorption heat pumps | |
| JP2012522964A (ja) | 温度調整装置 | |
| HK1174050A (en) | Operating medium for an absorption refrigeration device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140618 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140707 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20140918 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150330 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20160719 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20161118 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20161129 |
|
| A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20170203 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180220 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20180619 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 6358799 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |