JP6353991B1 - Adhesive composition, sealing sheet, and sealing body - Google Patents

Abstract

The present invention is an adhesive composition containing (A) component: modified polyolefin resin, and (B) component: polyfunctional epoxy compound, and the amount of outgas is 20 ° C. for 20 minutes with respect to the solid content. When measured, the amount of outgas per 1 cm 3 of solid content is 20 mg or less, a sealing sheet having an adhesive layer formed using this adhesive composition, and encapsulation It is a sealing body formed by sealing a stationary object with the sealing sheet. According to the present invention, it is easy to form into a sheet and has a low outgas adhesive composition, a sealing sheet having a low outgas adhesive layer formed using this adhesive composition, and A sealing body is provided in which an object to be sealed is sealed with the sealing sheet.

Description

  The present invention relates to an adhesive composition that is easy to be molded into a sheet and has a low outgassing property, a sealing sheet having a low outgassing adhesive layer formed by using this adhesive composition, and an encapsulant It is related with the sealing body by which a stationary thing is sealed with the said sealing sheet.

In recent years, organic EL elements have attracted attention as light-emitting elements that can emit light with high luminance by low-voltage direct current drive.
However, the organic EL element has a problem that light emission characteristics such as light emission luminance, light emission efficiency, and light emission uniformity are likely to deteriorate with time.
As a cause of the problem of the deterioration of the light emission characteristics, it has been considered that oxygen, moisture and the like enter the inside of the organic EL element to deteriorate the electrode and the organic layer. For this reason, it has been practiced to seal the organic EL element using a sealing material to prevent the entry of oxygen and moisture.
Moreover, when sealing an organic EL element using a sealing material, when an outgas generate | occur | produces from a sealing material, since an organic EL element will be deteriorated, the development of the low outgassing sealing material has been performed.

For example, Patent Document 1 describes a sealing composition containing a specific cationic curable compound, a photocationic polymerization initiator, and an azole compound.
Patent Document 1 also describes that the cured product of the sealing composition has low outgassing and moisture resistance.

WO2015 / 111525

Patent Document 1 describes that a low outgassing sealing composition can be obtained by using an azole compound as a curing retarder.
However, according to the study by the present inventors, the cause of outgas generation in the sealing material is not only the curing retarder, and therefore further investigation is necessary to obtain a lower outgassing sealing material. I understood.

  The present invention has been made in view of the above circumstances, and is easily formed into a sheet shape and has a low outgassing adhesive composition, and a low outgassing adhesive formed using this adhesive composition. It aims at providing the sealing sheet which has a sealing sheet which has an agent layer, and a to-be-sealed material is sealed with the said sealing sheet.

  As a result of intensive studies to solve the above problems, the present inventors have found that an adhesive composition containing a modified polyolefin resin and a polyfunctional epoxy compound is suitable as a material for forming a low-outgas sealing material. As a result, the present invention has been completed.

Thus, according to the present invention, the following adhesive compositions (1) to (9), the sealing sheets (10) to (13), and the sealing bodies (14) and (15) are provided. .
(1) An adhesive composition containing the following component (A) and component (B), the solid content of which is 1 cm ³ when the outgas amount is measured at 120 ° C. for 20 minutes. An adhesive composition, wherein the amount of pergassing is 20 mg or less.
(A) component: modified polyolefin resin (B) component: polyfunctional epoxy compound (2) The adhesive composition according to (1), wherein the component (A) is an acid-modified polyolefin resin.
(3) The adhesive composition according to (1) or (2), wherein the content of the component (B) is 25 to 200 parts by mass with respect to 100 parts by mass of the component (A).
(4) The adhesive composition according to any one of (1) to (3), further comprising the following component (C).
Component (C): Tackifier having a softening point of 80 ° C. or higher (5) The content of the component (C) is 1 to 200 parts by mass with respect to 100 parts by mass of the component (A), (4) The adhesive composition described in 1.
(6) The adhesive composition according to any one of (1) to (5), further comprising the following component (D).
Component (D): Imidazole-based curing catalyst (7) Adhesion according to (6), wherein the content of component (D) is 0.1 to 10 parts by mass with respect to 100 parts by mass of component (A). Agent composition.
(8) The adhesive composition according to any one of (1) to (7), further comprising the following component (E):
(E) Component: Silane coupling agent (9) Adhesion according to (8), wherein the content of component (E) is 0.01 to 10 parts by mass with respect to 100 parts by mass of component (A). Agent composition.
(10) A sealing sheet comprising two release films and an adhesive layer sandwiched between these release films, wherein the adhesive layer is any one of (1) to (9) A sealing sheet that is formed using an adhesive composition.
(11) A sealing sheet comprising a release film, a gas barrier film, and an adhesive layer sandwiched between the release film and the gas barrier film, wherein the adhesive layer is any one of (1) to (9) A sealing sheet formed using the adhesive composition according to claim 1.
(12) The sealing sheet according to (11), wherein the gas barrier film is a metal foil, a resin film, or thin film glass.
(13) The sealing sheet according to any one of (10) to (12), wherein the adhesive layer has a thickness of 5 to 25 μm.
(14) A sealed body in which an object to be sealed is sealed with the sealing sheet according to any one of (10) to (13).
(15) The sealed body according to (14), wherein the object to be sealed is an organic EL element, an organic EL display element, a liquid crystal display element, or a solar cell element.

  According to the present invention, it is easy to form into a sheet and has a low outgas adhesive composition, a sealing sheet having a low outgas adhesive layer formed using this adhesive composition, and A sealing body is provided in which an object to be sealed is sealed with the sealing sheet.

Hereinafter, the present invention will be described in detail by dividing it into 1) an adhesive composition, 2) a sealing sheet, and 3) a sealing body.
As used herein, “low outgassing” refers to release even when the solid content of the adhesive composition (or the adhesive layer formed from the adhesive composition) is placed in a high temperature environment. The characteristic of the adhesive composition or adhesive layer that the amount of outgas produced is small.

1) Adhesive composition The adhesive composition of this invention is an adhesive composition containing the following (A) component and (B) component, Comprising: On the conditions for 120 degreeC and 20 minutes about the solid content When the outgas amount is measured, the outgas amount per 1 cm ³ of the solid content is 20 mg or less.
(A) component: modified polyolefin resin (B) component: polyfunctional epoxy compound

The modified polyolefin resin is a polyolefin resin having a functional group introduced therein.
The polyolefin resin is a polymer containing a repeating unit derived from an olefin monomer. The polyolefin resin may be a homopolymer consisting of only one type of repeating unit derived from an olefinic monomer or a copolymer consisting of two or more types of repeating units derived from an olefinic monomer. A copolymer comprising a repeating unit derived from a monomer and a repeating unit derived from another monomer copolymerizable with the olefin monomer (other monomers other than the olefin monomer) There may be.

The olefin monomer is preferably an α-olefin having 2 to 8 carbon atoms, more preferably ethylene, propylene, 1-butene, isobutylene, or 1-hexene, and further preferably ethylene or propylene.
Examples of other monomers copolymerizable with the olefin monomer include vinyl acetate, (meth) acrylic acid ester, and styrene. Here, (meth) acrylic acid represents the meaning of acrylic acid or methacrylic acid (the same applies hereinafter).

  Examples of polyolefin resins include very low density polyethylene (VLDPE), low density polyethylene (LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), linear low density polyethylene, polypropylene (PP), and ethylene-propylene. Polymer, olefin elastomer (TPO), ethylene-vinyl acetate copolymer (EVA), ethylene- (meth) acrylic acid copolymer, ethylene- (meth) acrylic acid ester copolymer, etc. It is not limited to.

The modified polyolefin resin can be obtained by subjecting a polyolefin resin as a precursor to a modification treatment using a modifier.
The modifier used for the modification treatment of the polyolefin resin is a compound having a functional group in the molecule, that is, a group that can contribute to a crosslinking reaction described later.
Functional groups include carboxyl groups, carboxylic anhydride groups, carboxylic ester groups, hydroxyl groups, epoxy groups, amide groups, ammonium groups, nitrile groups, amino groups, imide groups, isocyanate groups, acetyl groups, thiol groups, ether groups. Thioether group, sulfone group, phosphoric acid group, nitro group, urethane group, halogen atom and the like. Among these, a carboxyl group, a carboxylic anhydride group, a carboxylic ester group, a hydroxyl group, an ammonium group, an amino group, an imide group, and an isocyanate group are preferable, a carboxylic anhydride group and an alkoxysilyl group are more preferable, and a carboxylic anhydride Physical groups are particularly preferred.
The compound having a functional group may have two or more kinds of functional groups in the molecule.

  Examples of modified polyolefin resins include acid-modified polyolefin resins and silane-modified polyolefin resins. Among these, an acid-modified polyolefin resin is preferable from the viewpoint of obtaining the superior effect of the present invention.

  The acid-modified polyolefin resin refers to a resin obtained by graft modification with an acid to a polyolefin resin. For example, a polyolefin resin may be reacted with an unsaturated carboxylic acid to introduce a carboxyl group (graft modification). In the present specification, the unsaturated carboxylic acid includes the concept of carboxylic anhydride, and the carboxyl group includes the concept of carboxylic anhydride group.

Examples of the unsaturated carboxylic acid to be reacted with the polyolefin resin include maleic acid, fumaric acid, itaconic acid, citraconic acid, glutaconic acid, tetrahydrophthalic acid, aconitic acid, maleic anhydride, itaconic anhydride, glutaconic anhydride, citraconic anhydride, Examples thereof include aconitic anhydride, norbornene dicarboxylic acid anhydride, and tetrahydrophthalic acid anhydride.
These can be used alone or in combination of two or more. Among these, maleic anhydride is preferable because an adhesive composition having better adhesive strength can be easily obtained.

  The amount of the unsaturated carboxylic acid to be reacted with the polyolefin resin is preferably 0.1 to 5 parts by mass, more preferably 0.2 to 3 parts by mass, and still more preferably 0.2 to 100 parts by mass with respect to 100 parts by mass of the polyolefin resin. 1.0 part by mass. The adhesive composition containing the acid-modified polyolefin resin thus obtained is more excellent in adhesive strength.

  In the present invention, a commercially available product may be used as the acid-modified polyolefin resin. Examples of commercially available products include Admer (registered trademark) (manufactured by Mitsui Chemicals), Unistor (registered trademark) (manufactured by Mitsui Chemicals), BondyRam (manufactured by Polyram), orevac (registered trademark) (manufactured by ARKEMA), Modic (registered trademark) (manufactured by Mitsubishi Chemical Corporation) and the like.

  A silane-modified polyolefin resin refers to a resin obtained by graft modification with an unsaturated silane compound to a polyolefin resin. The silane-modified polyolefin resin has a structure in which an unsaturated silane compound is graft copolymerized with a polyolefin resin as a main chain. Although it does not specifically limit as a silane modified polyolefin resin, A silane modified polyethylene resin and a silane modified ethylene-vinyl acetate copolymer are mentioned. Of these, silane-modified polyethylene resins such as silane-modified low-density polyethylene, silane-modified ultra-low-density polyethylene, and silane-modified linear low-density polyethylene are preferable.

As the unsaturated silane compound to be reacted with the polyolefin resin, a vinyl silane compound is preferable. Vinyl silane compounds include vinyl trimethoxy silane, vinyl triethoxy silane, vinyl tripropoxy silane, vinyl triisopropoxy silane, vinyl tributoxy silane, vinyl tripentyloxy silane, vinyl triphenoxy silane, vinyl tribenzyloxy silane, vinyl tri Examples include methylenedioxysilane, vinyltriethylenedioxysilane, vinylpropionyloxysilane, vinyltriacetoxysilane, and vinyltricarboxysilane. These can be used individually by 1 type or in combination of 2 or more types.
As a condition for graft polymerization of the unsaturated silane compound to the polyolefin resin as the main chain, a known conventional method of graft polymerization may be employed.

  The amount of the unsaturated silane compound to be reacted with the polyolefin resin is preferably 0.1 to 10 parts by mass, particularly preferably 0.3 to 7 parts by mass, with respect to 100 parts by mass of the polyolefin resin. Is preferably 0.5 to 5 parts by mass. When the amount of the unsaturated silane compound to be reacted is in the above range, the adhesive composition containing the resulting silane-modified polyolefin resin is more excellent in adhesive strength.

  In the present invention, a commercially available product can also be used as the silane-modified polyolefin resin. Commercially available products include, for example, Linklon (registered trademark) (manufactured by Mitsubishi Chemical Corporation), among others, low density polyethylene-based linklon, linear low-density polyethylene-based linkron, and ultra-low-density polyethylene-based. Of these, Rincron of ethylene-vinyl acetate copolymer system can be preferably used.

  Modified polyolefin-type resin can be used individually by 1 type or in combination of 2 or more types.

The number average molecular weight (Mn) of the modified polyolefin resin is not particularly limited, but is preferably 10,000 to 2,000,000, more preferably 20,000 to 1,500, from the viewpoint of obtaining the better effect of the present invention. More preferably, it is 000.
The number average molecular weight (Mn) of the modified polyolefin resin can be obtained as a standard polystyrene equivalent value by performing gel permeation chromatography using tetrahydrofuran as a solvent.

  The content of the modified polyolefin resin is not particularly limited, but from the viewpoint of obtaining the better effect of the present invention, the total amount of the modified polyolefin resin and the following component (B) determines the solid content of the adhesive composition. As a reference, 30% by mass or more is preferable, and 50% by mass or more is more preferable.

(B) component: Multifunctional epoxy compound The adhesive composition of this invention contains a polyfunctional epoxy compound as (B) component.
Since the adhesive composition of the present invention contains a polyfunctional epoxy compound, the cured product has excellent water vapor barrier properties.

  The polyfunctional epoxy compound refers to a compound having at least two epoxy groups in the molecule.

Examples of epoxy compounds having two or more epoxy groups include bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, bisphenol S diglycidyl ether, brominated bisphenol A diglycidyl ether, brominated bisphenol F diglycidyl ether, and brominated bisphenol S. Diglycidyl ether, novolac type epoxy resin (for example, phenol novolac type epoxy resin, cresol novolac type epoxy resin, brominated phenol novolac type epoxy resin), hydrogenated bisphenol A diglycidyl ether, hydrogenated bisphenol F diglycidyl ether, Hydrogenated bisphenol S diglycidyl ether, pentaerythritol polyglycidyl ether, 1,6-hexanediol diglycidyl ether, Oxahydrophthalic acid diglycidyl ester, neopentyl glycol diglycidyl ether, trimethylolpropane polyglycidyl ether, 2,2-bis (3-glycidyl-4-glycidyloxyphenyl) propane, dimethyloltricyclodecane diglycidyl ether, etc. Can be mentioned.
These polyfunctional epoxy compounds can be used individually by 1 type or in combination of 2 or more types.

  The lower limit of the weight average molecular weight of the polyfunctional epoxy compound is preferably 1,000, more preferably 1,200. The upper limit of the weight average molecular weight of the polyfunctional epoxy compound is preferably 5,000, more preferably 4,500. By using an adhesive composition having a polyfunctional epoxy compound having a weight average molecular weight of 1,000 or more, a lower outgassing sealing material can be formed. The adhesive composition having a polyfunctional epoxy compound having a weight average molecular weight of 5,000 or less is excellent in fluidity, and can sufficiently fill the unevenness caused by the unevenness of the surface of the object to be sealed and the thickness of the object to be sealed ( Excellent ruggedness followability).

  The epoxy equivalent of the polyfunctional epoxy compound is preferably 100 g / eq or more and 500 g / eq or less, more preferably 150 g / eq or more and 300 g / eq or less. By using an adhesive composition having an epoxy equivalent of 100 g / eq or more and 500 g / eq or less of the polyfunctional epoxy compound, it is possible to form a lower outgassing sealing material.

  The content of the polyfunctional epoxy compound in the adhesive composition of the present invention is preferably 25 to 200 parts by mass, more preferably 50 to 150 parts by mass with respect to 100 parts by mass of the component (A). Hardened | cured material of the adhesive composition in which content of a polyfunctional epoxy compound exists in this range is excellent by water vapor | steam barrier property.

The adhesive composition of this invention may contain components other than the said (A) component and (B) component.
As components other than (A) component and (B) component, the following (C) component, (D) component, and (E) component are mentioned.
Component (C): Tackifier having a softening point of 80 ° C. or higher (D) Component: Imidazole-based curing catalyst (E) component: Silane coupling agent

Component (C): Tackifier having a softening point of 80 ° C. or higher The adhesive composition containing the component (B) has a low storage elastic modulus before curing and is excellent in unevenness followability. However, such an adhesive composition may be difficult to maintain a certain shape and difficult to be formed into a sheet shape. In such a case, the moldability can be improved by containing the component (C).

Examples of tackifiers include rosin resins such as polymerized rosin, polymerized rosin ester, and rosin derivatives; terpene resins such as polyterpene resins, aromatic modified terpene resins and hydrides thereof, and terpene phenol resins; coumarone and indene resins; aliphatic Petroleum resins such as petroleum resins, aromatic petroleum resins and their hydrides, aliphatic / aromatic copolymer petroleum resins; low molecular weight polymers of styrene or substituted styrene; α-methylstyrene monopolymer resins, α -Methylstyrene / styrene copolymer resin, styrene monomer / aliphatic monomer copolymer resin, styrene monomer / α-methylstyrene / aliphatic monomer copolymer resin, styrene monomer monopolymer resin, Styrene resin such as styrene monomer / aromatic monomer copolymer resin; and the like. Among these, a styrene resin is preferable, and a styrene monomer / aliphatic monomer copolymer resin is more preferable.
These tackifiers can be used singly or in combination of two or more.

  The softening point of the tackifier is 80 ° C. or higher. The adhesive composition which is excellent in the adhesiveness at the time of high temperature is obtained because the softening point of a tackifier is 80 degreeC or more. Moreover, the workability | operativity at the time of shape | molding an adhesive composition in a sheet form improves.

  When the adhesive composition of the present invention contains a tackifier having a softening point of 80 ° C. or higher, the content is preferably 1 to 200 parts by mass with respect to 100 parts by mass of the component (A). Preferably it is 10-150 mass parts. If there are too few tackifiers having a softening point of 80 ° C. or higher, it may be difficult to form the adhesive composition into a sheet. On the other hand, when there are too many tackifiers whose softening point is 80 degreeC or more, there exists a possibility that an adhesive bond layer may become weak.

Component (D): Imidazole-based curing catalyst The imidazole-based curing catalyst is a compound having an imidazole skeleton, and has an action of catalyzing the curing reaction of the adhesive composition.
Examples of imidazole curing catalysts include 2-methylimidazole, 2-phenylimidazole, 2-undecylimidazole, 2-heptadecylimidazole, 2-ethyl-4-methylimidazole, 2-phenyl-4-methylimidazole, and 2-phenyl. Examples include -4-methyl-5-hydroxymethylimidazole, 2-phenyl-4,5-dihydroxymethylimidazole and the like. Among these, 2-ethyl-4-methylimidazole is preferable.
These imidazole-based curing catalysts can be used singly or in combination of two or more.

  By using an adhesive composition containing an imidazole-based curing catalyst, a cured product having excellent adhesiveness can be easily obtained even at high temperatures.

  When the adhesive composition of the present invention contains an imidazole-based curing catalyst, the content thereof is preferably 0.1 to 10 parts by mass, more preferably 0.2 to 100 parts by mass of the component (A). -5 parts by mass. The cured product of the adhesive composition having an imidazole-based curing catalyst content within this range has excellent adhesiveness even at high temperatures.

(E) Component: Silane Coupling Agent A silane coupling agent is an organosilicon compound having simultaneously a functional group reactively bonded to an organic material and a functional group reactively bonded to an inorganic material (hydrolyzable group) in the molecule. .
As the silane coupling agent, a known silane coupling agent can be used, and among them, an organosilicon compound having at least one alkoxysilyl group in the molecule is preferable.
Examples of the silane coupling agent include polymerizable unsaturated group-containing silicon compounds such as vinyltrimethoxysilane, vinyltriethoxysilane, and methacryloxypropyltrimethoxysilane; 3-glycidoxypropyltrimethoxysilane, 2- (3,4 -Epoxycyclohexyl) silicon compound having an epoxy structure such as ethyltrimethoxysilane; 3-aminopropyltrimethoxysilane, N- (2-aminoethyl) -3-aminopropyltrimethoxysilane, N- (2-aminoethyl) An amino group-containing silicon compound such as -3-aminopropylmethyldimethoxysilane; 3-chloropropyltrimethoxysilane; 3-isocyanatopropyltriethoxysilane;
These silane coupling agents can be used alone or in combination of two or more.

  By using an adhesive composition containing a silane coupling agent, it becomes easy to obtain a cured product having better adhesive strength in a normal temperature (15 ° C. to 30 ° C.) and high temperature (40 ° C. to 100 ° C.) environment.

  In the case where the adhesive composition of the present invention contains a silane coupling agent, the content is preferably based on 100 parts by mass of the component (A) from the viewpoint of obtaining a cured product having further excellent adhesive strength. It is 0.01-10 mass parts, More preferably, it is 0.02-5 mass parts.

The adhesive composition of the present invention may contain a solvent.
Solvents include aromatic hydrocarbon solvents such as benzene and toluene; ester solvents such as ethyl acetate and butyl acetate; ketone solvents such as acetone, methyl ethyl ketone, and methyl isobutyl ketone; n-pentane, n-hexane, and n- And aliphatic hydrocarbon solvents such as heptane; alicyclic hydrocarbon solvents such as cyclopentane, cyclohexane, and methylcyclohexane;
These solvents can be used alone or in combination of two or more.
The content of the solvent can be appropriately determined in consideration of coating properties and the like.

The adhesive composition of the present invention may contain other components as long as the effects of the present invention are not hindered.
Examples of other components include additives such as ultraviolet absorbers, antistatic agents, light stabilizers, antioxidants, resin stabilizers, fillers, pigments, extenders and softeners.
These can be used alone or in combination of two or more.
When the adhesive composition of this invention contains these additives, the content can be suitably determined according to the objective.

  The adhesive composition of the present invention can be prepared by appropriately mixing and stirring predetermined components according to a conventional method.

The adhesive composition of the present invention, the on solids 120 ° C., as measured outgas amount in for 20 minutes, and the outgas amount of the total solid content 1 cm ² is 20mg or less, preferably 18 mg, 15 mg or less Is more preferably 10 mg or less, and most preferably 8 mg or less. Although there is no lower limit in particular, it is usually 0.1 mg or more. In this specification, solid content means the solid part remove | excluding volatile substances, such as a solvent, from an adhesive composition.
Moreover, a low outgassing adhesive layer can be more easily formed by using a polyfunctional epoxy compound having a weight average molecular weight of 1,000 to 5,000.

  The amount of outgas for the solid content of the adhesive composition is, for example, a film with a sheet-like adhesive obtained by coating the adhesive composition of the present invention on a base film (or a release film) and drying it. Using as a test piece, it can be measured according to the method described in Examples.

  An adhesive composition with a small outgas amount can be efficiently obtained by using a relatively high molecular weight polyfunctional epoxy compound.

  The adhesive composition of the present invention is easy to be formed into a sheet and has low outgassing properties. For this reason, the adhesive composition of this invention is used suitably when forming a sealing material.

2) Sealing sheet The sealing sheet of this invention is the following sealing sheet ((alpha)) or sealing sheet ((beta)).
Sealing sheet (α): a sealing sheet comprising two release films and an adhesive layer sandwiched between these release films, wherein the adhesive layer uses the adhesive composition of the present invention. A sealing sheet (β): a sealing sheet comprising a release film, a gas barrier film, and an adhesive layer sandwiched between the release film and the gas barrier film The adhesive layer is formed by using the adhesive composition of the present invention. These sealing sheets represent a state before use. When using the sealing sheet of the present invention, the release film is usually peeled off.

[Sealing sheet (α)]
The release film constituting the sealing sheet (α) functions as a support in the manufacturing process of the sealing sheet (α) and protects the adhesive layer until the sealing sheet (α) is used. Functions as a sheet.

A conventionally well-known thing can be utilized as a peeling film. For example, what has the peeling layer by which the peeling process was carried out with the release agent on the base material for peeling films is mentioned.
As the substrate for the release film, paper substrates such as glassine paper, coated paper, and high-quality paper; laminated paper obtained by laminating a thermoplastic resin such as polyethylene on these paper substrates; polyethylene terephthalate resin, polybutylene terephthalate resin, Examples thereof include plastic films such as polyethylene naphthalate resin, polypropylene resin, and polyethylene resin.
Examples of the release agent include rubber elastomers such as silicone resins, olefin resins, isoprene resins, and butadiene resins, long chain alkyl resins, alkyd resins, and fluorine resins.

  The two release films in the sealing sheet (α) may be the same or different, but the two release films preferably have different release forces. By making the peeling force of two peeling films different, the process of peeling a peeling film initially can be performed more efficiently.

Although the thickness of the adhesive bond layer of a sealing sheet ((alpha)) is not specifically limited, It is preferable that it is 5-25 micrometers, and it is more preferable that it is 10-20 micrometers.
Thus, although the adhesive layer is very thin, since this adhesive layer is formed by the adhesive composition of the present invention, it is excellent in uneven follow-up and sufficiently adheres to the unevenness of the adherend. Can be filled.

The adhesive layer of the sealing sheet (α) preferably has thermosetting properties. The adhesive layer having thermosetting property is extremely excellent in adhesive strength after curing.
The conditions for thermosetting the adhesive layer are not particularly limited.
The heating temperature is usually 80 to 200 ° C, preferably 90 to 150 ° C.
The heating time is usually 30 minutes to 12 hours, preferably 1 to 6 hours.

The peel adhesive strength at 23 ° C. of the adhesive layer after the curing treatment is usually 1 to 100 N / 25 mm, preferably 10 to 50 N / 25 mm, and the peel adhesive strength at 85 ° C. is usually 1 to 100 N. / 25 mm, preferably 5 to 50 N / 25 mm.
The peel adhesive strength is measured according to the method described in the examples.
The water vapor permeability of the adhesive layer after the curing treatment is usually 0.1 to 200 g / m ² / day, preferably 1 to 150 g / m ² / day.

  The manufacturing method of a sealing sheet ((alpha)) is not specifically limited. For example, a sealing sheet ((alpha)) can be manufactured using a well-known casting method. More specifically, by using a known method, the adhesive composition of the present invention is applied to the release-treated surface of the release film, and the resulting coating film is dried to form an adhesive layer with a release film. The sealing sheet ((alpha)) can be obtained by manufacturing and then stacking another release film on the adhesive layer.

Examples of the method for applying the adhesive composition include spin coating, spray coating, bar coating, knife coating, roll coating, blade coating, die coating, and gravure coating.
The drying conditions for drying the coating film are not particularly limited. For example, the drying temperature is 80 to 150 ° C., and the drying time is 30 seconds to 5 minutes.

[Sealing sheet (β)]
Examples of the release film and the adhesive layer constituting the sealing sheet (β) are the same as those shown as the release film and the adhesive layer constituting the sealing sheet (α).
The gas barrier film which comprises a sealing sheet ((beta)) will not be specifically limited if it is a film which has a moisture barrier property.

The gas barrier film preferably has a water vapor transmission rate of 0.1 g / m ² / day or less in an environment of a temperature of 40 ° C. and a relative humidity of 90% (hereinafter abbreviated as “90% RH”). It is more preferable that it is 0.05 g / m ² / day or less, and it is more preferable that it is 0.005 g / m ² / day or less.
The gas barrier film has a water vapor transmission rate of 0.1 g / m ² / day or less in an environment of 40 ° C. and 90% RH, so that oxygen or oxygen can be contained inside the organic EL element formed on the transparent substrate. It is possible to effectively suppress the penetration of moisture and the like and the deterioration of the electrode and the organic layer.
The transmittance of water vapor and the like of the gas barrier film can be measured using a known gas permeability measuring device.

  Examples of the gas barrier film include metal foil, resin film, and thin film glass. Among these, a resin film is preferable, and a gas barrier film having a base material and a gas barrier layer is more preferable.

  Examples of the metal of the metal foil include metal materials such as copper, nickel, and aluminum; alloy materials such as stainless steel and aluminum alloys; and the like.

The components and composition of the thin film glass are not particularly limited, but alkali-free borosilicate glass is preferable in terms of obtaining more stable flexibility.
As the thin film glass, the thin film glass may be used as a simple substance, or a metal foil such as an aluminum foil or a resin film laminated or laminated on the thin film glass may be used.
Moreover, as thin film glass, what has the flexibility which thickness is about 10-200 micrometers is preferable.

Examples of the resin component constituting the base material of the gas barrier film include polyimide, polyamide, polyamideimide, polyphenylene ether, polyether ketone, polyether ether ketone, polyolefin, polyester, polycarbonate, polysulfone, polyether sulfone, polyphenylene sulfide, and polyphenylene sulfide. Examples include arylate, acrylic resin, cycloolefin polymer, aromatic polymer, polyurethane polymer, and the like.
Although there is no restriction | limiting in particular in the thickness of a base material, From a viewpoint of the ease of handling, Preferably it is 0.5-500 micrometers, More preferably, it is 1-200 micrometers, More preferably, it is 5-100 micrometers.

  A material etc. will not be specifically limited if a gas barrier layer can provide desired gas barrier property. Examples of the gas barrier layer include an inorganic film and a layer obtained by subjecting a layer containing a polymer compound to a modification treatment. Among these, since a layer having a small thickness and excellent gas barrier properties can be efficiently formed, the gas barrier layer includes a gas barrier layer made of an inorganic film and a gas barrier layer obtained by subjecting a layer containing a polymer compound to a modification treatment. preferable.

The inorganic film is not particularly limited, and examples thereof include an inorganic vapor deposition film.
Examples of the inorganic vapor deposition film include vapor deposition films of inorganic compounds and metals.
As the raw material for the vapor-deposited film of the inorganic compound, inorganic oxides such as silicon oxide, aluminum oxide, magnesium oxide, zinc oxide, indium oxide and tin oxide; inorganic nitrides such as silicon nitride, aluminum nitride and titanium nitride; inorganic carbides; Inorganic sulfides; inorganic oxynitrides such as silicon oxynitride; inorganic oxide carbides; inorganic nitride carbides; inorganic oxynitride carbides and the like.
Examples of the raw material for the metal vapor deposition film include aluminum, magnesium, zinc, and tin.
It is done.

Examples of the method for forming the inorganic film include a vacuum deposition method, an EB deposition method, a sputtering method, an ion plating method, a lamination method, a plasma vapor deposition method (CVD method), and the like.
Although the thickness of an inorganic film is suitably selected by the kind and structure of an inorganic material, it is 1-500 normally, Preferably, it is 2-300 nm.

In a gas barrier layer obtained by ion implantation into a layer containing a polymer compound (hereinafter sometimes referred to as “polymer layer”), the polymer compound used is a silicon-containing polymer such as polyorganosiloxane or polysilazane compound. Compound, polyimide, polyamide, polyamideimide, polyphenylene ether, polyether ketone, polyether ether ketone, polyolefin, polyester, polycarbonate, polysulfone, polyethersulfone, polyphenylene sulfide, polyarylate, acrylic resin, cycloolefin polymer, aromatic System polymers and the like. These polymer compounds can be used alone or in combination of two or more.
Among these, from the viewpoint of forming a gas barrier layer having excellent gas barrier properties, silicon-containing polymer compounds are preferable, and polysilazane compounds are more preferable.

  A polysilazane compound is a polymer compound having a repeating unit containing a —Si—N— bond (silazane bond) in the molecule. Specifically, the formula (1)

The compound which has a repeating unit represented by these is preferable. The number average molecular weight of the polysilazane compound to be used is not particularly limited, but is preferably 100 to 50,000.

In said formula (1), n represents arbitrary natural numbers.
Rx, Ry, and Rz each independently represent a hydrogen atom, an unsubstituted or substituted alkyl group, an unsubstituted or substituted cycloalkyl group, an unsubstituted or substituted alkenyl group, unsubstituted or substituted Represents a non-hydrolyzable group such as an aryl group having a group or an alkylsilyl group; Among these, as Rx, Ry, and Rz, a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or a phenyl group is preferable, and a hydrogen atom is particularly preferable. Examples of the polysilazane compound having a repeating unit represented by the formula (1) include inorganic polysilazanes in which Rx, Ry, and Rz are all hydrogen atoms, and organic polysilazanes in which at least one of Rx, Ry, and Rz is not a hydrogen atom. It may be.

  The polysilazane compounds can be used alone or in combination of two or more. In the present invention, a modified polysilazane compound can also be used as the polysilazane compound. In the present invention, as the polysilazane compound, a commercially available product as a glass coating material or the like can be used as it is.

The polymer layer may contain other components in addition to the above-described polymer compound as long as the object of the present invention is not impaired. Examples of other components include curing agents, other polymers, anti-aging agents, light stabilizers, and flame retardants.
The content of the polymer compound in the polymer layer is preferably 50% by mass or more and more preferably 70% by mass or more because a gas barrier layer having better gas barrier properties can be obtained.

The thickness of the polymer layer is not particularly limited, but is preferably in the range of 50 to 300 nm, more preferably 50 to 200 nm.
In the present invention, a sealing sheet having a sufficient gas barrier property can be obtained even if the thickness of the polymer layer is nano-order.

  As a method for forming a polymer layer, for example, a layer forming solution containing at least one polymer compound, optionally other components, a solvent, and the like is used as a known method such as a spin coater, a knife coater, a gravure coater, or the like. There is a method in which an apparatus is used for coating and the resulting coating film is appropriately dried to form.

Examples of the polymer layer modification treatment include ion implantation treatment, plasma treatment, radiation irradiation treatment, heat treatment and the like, and treatment for changing the bonding structure of the polymer layer is preferable. These processes can be performed alone or in combination of two or more.
The ion implantation process is a method of modifying the polymer layer by implanting ions into the polymer layer, as will be described later.
The plasma treatment is a method for modifying the polymer layer by exposing the polymer layer to plasma. For example, plasma treatment can be performed according to a method described in Japanese Patent Application Laid-Open No. 2012-106421.
The radiation irradiation treatment is a method for modifying the polymer layer by irradiating the polymer layer with radiation. The radiation preferably has a short wavelength with a high effect of changing the bonding structure of the polymer layer, and it is preferable to use ultraviolet rays, particularly vacuum ultraviolet rays. For example, vacuum ultraviolet light modification treatment can be performed according to the method described in JP2013-226757A.
Among these, the ion implantation treatment is preferable because the gas barrier layer can be efficiently modified to the inside without roughening the surface of the polymer layer and more excellent in gas barrier properties.

As ions implanted into the polymer layer, ions of rare gases such as argon, helium, neon, krypton, and xenon; ions such as fluorocarbon, hydrogen, nitrogen, oxygen, carbon dioxide, chlorine, fluorine, and sulfur;
Ions of alkane gases such as methane and ethane; Ions of alkene gases such as ethylene and propylene; Ions of alkadiene gases such as pentadiene and butadiene; Ions of alkyne gases such as acetylene; Benzene, toluene, etc. Ions of aromatic hydrocarbon gases such as: ions of cycloalkane gases such as cyclopropane; ions of cycloalkene gases such as cyclopentene; ions of metals; ions of organosilicon compounds;
These ions can be used alone or in combination of two or more.
Among these, ions of rare gases such as argon, helium, neon, krypton, and xenon are preferable because ions can be more easily implanted and a gas barrier layer having particularly excellent gas barrier properties can be obtained.

  The method for implanting ions is not particularly limited. For example, there are a method of irradiating ions accelerated by an electric field (ion beam), a method of injecting ions in plasma (ion of plasma generation gas), etc., and a gas barrier layer can be easily obtained. A method of implanting ions is preferred. In the plasma ion implantation method, for example, plasma is generated in an atmosphere containing a plasma generation gas, and a negative high voltage pulse is applied to a layer into which ions are implanted, whereby ions (positive ions) in the plasma are ionized. Can be performed by injecting into the surface portion of the layer to be injected.

The manufacturing method of a sealing sheet ((beta)) is not specifically limited. For example, in the manufacturing method of the sealing sheet (α) described above, the sealing sheet (β) can be manufactured by replacing one of the release films with a gas barrier film.
Moreover, after manufacturing a sealing sheet ((alpha)), the sealing sheet ((beta)) is manufactured by peeling the one peeling film and sticking the exposed adhesive bond layer and a gas-barrier film. You can also. In this case, when the sealing sheet (α) has two release films having different release forces, it is preferable to release the release film having the smaller release force from the viewpoint of handleability.

  As described above, the adhesive layer of the sealing sheet of the present invention has low outgassing properties. For this reason, when an organic EL element is sealed, the deterioration can be suppressed.

3) Sealing body The sealing body of the present invention is formed by sealing an object to be sealed with the sealing sheet of the present invention.
The sealing body of the present invention includes, for example, a transparent substrate, an element (an object to be sealed) formed on the transparent substrate, and a sealing material for sealing the element. The sealing material is an adhesive layer of the sealing sheet of the present invention.

The transparent substrate is not particularly limited, and various substrate materials can be used. In particular, it is preferable to use a substrate material having a high visible light transmittance. In addition, a material having a high blocking performance for blocking moisture and gas to enter from the outside of the element and having excellent solvent resistance and weather resistance is preferable. Specifically, transparent inorganic materials such as quartz and glass; polyethylene terephthalate, polyethylene naphthalate, polycarbonate, polystyrene, polyethylene, polypropylene, polyphenylene sulfide, polyvinylidene fluoride, acetyl cellulose, brominated phenoxy, aramids, polyimides, Examples thereof include transparent plastics such as polystyrenes, polyarylates, polysulfones, and polyolefins, and the gas barrier film described above.
The thickness of the transparent substrate is not particularly limited, and can be appropriately selected in consideration of light transmittance and performance for blocking the inside and outside of the element.

  Examples of the object to be sealed include an organic EL element, an organic EL display element, a liquid crystal display element, and a solar cell element.

The manufacturing method of the sealing body of this invention is not specifically limited. For example, after the adhesive layer of the sealing sheet of the present invention is stacked on the object to be sealed, the adhesive layer of the sealing sheet and the object to be sealed are bonded by heating.
Subsequently, the sealing body of this invention can be manufactured by hardening this adhesive bond layer.

There are no particular restrictions on the bonding conditions for bonding the adhesive layer of the sealing sheet and the object to be sealed. Adhesion temperature is 23-100 degreeC, for example, Preferably it is 40-80 degreeC. This adhesion treatment may be performed while applying pressure.
As the curing conditions for curing the adhesive layer, the conditions described above can be used.

The sealing body of the present invention is formed by sealing an object to be sealed with the sealing sheet of the present invention.
Therefore, in the sealed body of the present invention, the performance of the object to be sealed is maintained for a long time.

Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to the following examples.
Unless otherwise indicated, the part and% in each example are based on mass. Moreover, the weight average molecular weight (Mw) of the modified polyolefin resin and the polyfunctional epoxy compound is a value measured by the following method.
<Weight average molecular weight of modified polyolefin resin (Mw)>
The weight average molecular weight (Mw) of the modified polyolefin resin was measured using a gel permeation chromatograph (GPC) apparatus (product name “HLC-8320” manufactured by Tosoh Corporation) under the following conditions. The value converted into the weight average molecular weight was used.
(Measurement condition)
・ Measurement sample: Tetrahydrofuran solution with a modified polyolefin resin concentration of 1 mass% ・ Column: Two “TSK gel Super HM-H” and one “TSK gel Super H2000” (both manufactured by Tosoh Corporation), sequentially connected -Column temperature: 40 ° C
・ Developing solvent: Tetrahydrofuran ・ Flow rate: 0.60 mL / min
<Weight average molecular weight of polyfunctional epoxy compound (Mw)>
The weight average molecular weight (Mw) of the polyfunctional epoxy compound was measured under the following conditions using a gel permeation chromatograph (GPC) apparatus (product name “HLC-8320” manufactured by Tosoh Corporation), and a plurality of weight average molecular weights were observed. Among the peaks having the largest area, the weight average molecular weight of the standard polystyrene corresponding to the retention time of the peak top is converted.
(Measurement condition)
・ Measurement sample: Tetrahydrofuran solution with a polyfunctional epoxy compound concentration of 1 mass% ・ Column: Two “TSK gel Super HM-H” and one “TSK gel Super H2000” (both manufactured by Tosoh Corporation), sequentially connected -Column temperature: 40 ° C
・ Developing solvent: Tetrahydrofuran ・ Flow rate: 0.60 mL / min

[Example 1]
100 parts of acid-modified polyolefin resin (α-olefin polymer, manufactured by Mitsui Chemicals, trade name: Unistor H-200, weight average molecular weight: 52,000), polyfunctional epoxy compound (1) (bisphenol A diglycidyl ether) , Manufactured by Mitsubishi Chemical Corporation, trade name: YL980, epoxy equivalent 180-190 g / eq, molecular weight: 2,400, 100 parts, tackifier (styrene monomer aliphatic monomer copolymer, softening point 95 ° C., Mitsui Chemicals) 50 parts by company, product name: FTR6100), and 1 part by imidazole-based curing catalyst (manufactured by Shikoku Kasei Co., Ltd., trade name: Curesol 2E4MZ, 2-ethyl-4-methylimidazole) are dissolved in methyl ethyl ketone, and the solid content concentration is 30 % Adhesive composition 1 was prepared.
The adhesive composition 1 was applied onto a release-treated surface of a release film (product name: SP-PET382150, manufactured by Lintec Corporation), and the resulting coating film was dried at 100 ° C. for 2 minutes to bond with a thickness of 12 μm. An agent layer was formed, and the release treatment surface of another release film (manufactured by Lintec Corporation, trade name: SP-PET 381031) was bonded thereon to obtain a sealing sheet 1.

[Example 2]
In Example 1, as a polyfunctional epoxy compound, polyfunctional epoxy compound (2) (hydrogenated bisphenol A diglycidyl ether, manufactured by Mitsubishi Chemical Corporation, trade name: YX8000, epoxy equivalent 205 g / eq, weight average molecular weight: 1,400 ) Was used in the same manner as in Example 1 except that a sealing sheet 2 was obtained.

Example 3
In Example 1, the polyfunctional epoxy compound (3) (hydrogenated bisphenol A diglycidyl ether, manufactured by Mitsubishi Chemical Corporation, trade name: YX8034, epoxy equivalent 270 g / eq, weight average molecular weight: 3,200) ) Was used in the same manner as in Example 1 except that a sealing sheet 3 was obtained.

Example 4
In Example 1, as the polyfunctional epoxy compound, polyfunctional epoxy compound (4) (hydrogenated bisphenol A diglycidyl ether, manufactured by Mitsubishi Chemical Corporation, trade name: YX8040, epoxy equivalent 1100 g / eq, weight average molecular weight: 4,200 ) Was used in the same manner as in Example 1 except that a sealing sheet 4 was obtained.

[Comparative Example 1]
In Example 1, as a polyfunctional epoxy compound, polyfunctional epoxy compound (5) (hydrogenated bisphenol A diglycidyl ether, manufactured by Kyoeisha Chemical Co., Ltd., trade name: Epolite 4000, epoxy equivalent of 215 to 245 g / eq, weight average molecular weight: 800) was used in the same manner as in Example 1 to obtain a sealing sheet 5.

[Comparative Example 2]
In Example 1, as the polyfunctional epoxy compound, polyfunctional epoxy compound (6) (hydrogenated bisphenol A diglycidyl ether, manufactured by ADEKA, trade name: Adeka Resin, EP-4080E, epoxy equivalent 215 g / eq, molecular weight: 800) A sealing sheet 6 was obtained in the same manner as in Example 1 except that was used.

The following tests were done about the sealing sheets 1-6 obtained in Examples 1-4 and Comparative Examples 1-2.
[Low outgassing evaluation test]
One release film of the sealing sheet obtained in Examples or Comparative Examples is peeled off, and this sealing sheet is placed on the glass plate so that the exposed adhesive layer faces the glass plate. Bonded at ℃.
Subsequently, what peeled off the remaining peeling film was used as a measurement sample, outgas was generated on 120 degreeC and the conditions for 20 minutes, and the generation amount was quantified.
The amount of outgas generated was quantified using a gas chromatograph mass spectrometer (GCMS-QP2010, manufactured by Shimadzu Corporation), and a column using 5% -Diphenyl-95% Dimethylpolysiloxane (HP-5 ms). At this time, a calibration curve was prepared using toluene.

[Evaluation test of organic EL elements]
Using a glass substrate on which an indium tin oxide (ITO) film (thickness: 100 nm, sheet resistance: 50Ω / □) was formed as an anode, an organic EL device was produced by the following method.
On the ITO film of the glass substrate, N, N′-bis (naphthalen-1-yl) -N, N′-bis (phenyl) -benzidine) (manufactured by Luminescence Technology) was 0.1 to 0.2 nm / A hole transport layer having a thickness of 50 nm is formed by vapor deposition at a rate of 30 minutes, and then, tris (8-hydroxy-quinolinate) aluminum (manufactured by Luminesence Technology) is 0.1 to 0. Evaporation was performed at a rate of 2 nm / min to form a light emitting layer having a thickness of 50 nm. On the light emitting layer, lithium fluoride (LiF) (manufactured by High Purity Chemical Laboratory) was deposited at a rate of 0.1 nm / min to form an electron injection layer having a thickness of 4 nm, and then on the electron injection layer Then, aluminum (Al) (manufactured by High Purity Chemical Research Laboratories) was vapor-deposited at a rate of 0.1 nm / min to form a cathode having a thickness of 100 nm to obtain an organic EL device. In addition, all the vacuum degrees at the time of vapor deposition were 1 * 10 <^-4> Pa or less.

One release film of each of the sealing sheets 1 to 6 obtained in Examples and Comparative Examples was peeled off, and the exposed adhesive layer was stacked on the metal foil film, and these were adhered at 40 ° C. using a heat laminator. Next, the other release film was peeled off, and the exposed adhesive layer was stacked so as to cover the organic EL element formed on the glass substrate, and these were adhered at 40 ° C. using a heat laminator. Subsequently, it heated at 100 degreeC for 2 hours, the adhesive bond layer was hardened, and the bottom emission type electronic device with which the organic EL element was sealed was obtained.
The electronic device was allowed to stand for 240 hours in an environment of 85 ° C. and a relative humidity of 85%, and then the organic EL element was activated to measure the area of the dark spot (non-light emitting portion).
The expansion ratio of the dark spot based on the area of the dark spot of the electronic device before being left in an environment of 85 ° C. and 85% relative humidity was calculated and evaluated according to the following criteria.
<Standard>
○: Dark spot enlargement ratio is less than 150% ×: Dark spot enlargement ratio is 150% or more The evaluation results are shown in Table 1.

Table 1 shows the following.
The sealing sheets of Examples 1 to 4 have low outgassing properties and are excellent in evaluation tests of organic EL elements.
On the other hand, the sealing sheets of Comparative Examples 1 and 2 generate a large amount of outgas and are inferior in the evaluation test of the organic EL element.

Claims (18)

A sealing sheet comprising two release films and an adhesive layer sandwiched between these release films,
The adhesive layer is an adhesive composition containing the following component (A) and component (B), and the solid content is measured when the outgas amount is measured at 120 ° C. for 20 minutes. An encapsulating sheet formed using an adhesive composition, wherein the amount of outgas per 1 cm ³ per minute is 20 mg or less .
Component (A): Modified polyolefin resin
(B) component: polyfunctional epoxy compound A release film, a gas barrier film, and an adhesive layer sandwiched between the release film and the gas barrier film,
The adhesive layer is an adhesive composition containing the following component (A) and component (B), and the solid content is measured when the outgas amount is measured at 120 ° C. for 20 minutes. An encapsulating sheet formed using an adhesive composition, wherein the amount of outgas per 1 cm ³ per minute is 20 mg or less.
Component (A): Modified polyolefin resin
(B) component: polyfunctional epoxy compound The sealing sheet according to claim 1 or 2 , wherein the component (A) is an acid-modified polyolefin resin. The sealing sheet in any one of Claims 1-3 whose content of the said (B) component is 25-200 mass parts with respect to 100 mass parts of said (A) components. The sealing sheet according to any one of claims 1 to 4 , wherein the adhesive composition further contains the following component (C).
Component (C): A tackifier having a softening point of 80 ° C or higher. The encapsulating sheet according to claim 5 , wherein the content of the component (C) is 1 to 200 parts by mass with respect to 100 parts by mass of the component (A). The sealing sheet according to any one of claims 1 to 6 , wherein the adhesive composition further contains the following component (D).
(D) Component: Imidazole-based curing catalyst The encapsulating sheet according to claim 7 , wherein the content of the component (D) is 0.1 to 10 parts by mass with respect to 100 parts by mass of the component (A). The sealing sheet according to any one of claims 1 to 8 , wherein the adhesive composition further contains the following component (E).
(E) component: Silane coupling agent The encapsulating sheet according to claim 9 , wherein the content of the component (E) is 0.01 to 10 parts by mass with respect to 100 parts by mass of the component (A). The sealing sheet according to claim 1, wherein the two release films have different release forces. It is used for manufacturing the sealing sheet which consists of a peeling film, a gas-barrier film, and the adhesive layer pinched | interposed into the said peeling film and a gas-barrier film, It is in any one of Claim 1, 3-11 Sealing sheet. The sealing sheet according to any one of claims 2 to 12, wherein the gas barrier film is a metal foil, a resin film, or a thin film glass. The sealing sheet in any one of Claims 1-13 whose thickness of an adhesive bond layer is 5-25 micrometers. The sealing sheet in any one of Claims 1-14 used for sealing the to-be-sealed thing chosen from an organic EL element, an organic EL display element, a liquid crystal display element, and a solar cell element. The sealing body by which a to-be-sealed thing is sealed with the sealing sheet in any one of Claims 1-15 . The sealing body according to claim 16 , wherein the object to be sealed is an organic EL element, an organic EL display element, a liquid crystal display element, or a solar cell element. The sealed body according to claim 16, comprising a step of bonding the adhesive layer of the sealing sheet and the object to be sealed by heating the adhesive layer after being stacked on the object to be sealed. Manufacturing method.