JP6342920B2 - タイヤの高剛性配合物 - Google Patents
タイヤの高剛性配合物 Download PDFInfo
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- JP6342920B2 JP6342920B2 JP2015556603A JP2015556603A JP6342920B2 JP 6342920 B2 JP6342920 B2 JP 6342920B2 JP 2015556603 A JP2015556603 A JP 2015556603A JP 2015556603 A JP2015556603 A JP 2015556603A JP 6342920 B2 JP6342920 B2 JP 6342920B2
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- Prior art keywords
- acid hydrazide
- resin
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- hydrazide
- hydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000001875 compounds Chemical class 0.000 title claims description 12
- 239000000203 mixture Substances 0.000 claims description 63
- 238000009472 formulation Methods 0.000 claims description 30
- 229920005989 resin Polymers 0.000 claims description 30
- 239000011347 resin Substances 0.000 claims description 30
- 239000006229 carbon black Substances 0.000 claims description 22
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 14
- 230000003014 reinforcing effect Effects 0.000 claims description 9
- 229920000307 polymer substrate Polymers 0.000 claims description 7
- 229920001971 elastomer Polymers 0.000 claims description 5
- 229920001568 phenolic resin Polymers 0.000 claims description 5
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 4
- 239000005062 Polybutadiene Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000012763 reinforcing filler Substances 0.000 claims description 4
- 239000005060 rubber Substances 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 4
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 claims description 3
- HPTJCEPNQHYWIH-UHFFFAOYSA-N 3-hydroxy-n-(4-methylpentan-2-ylideneamino)naphthalene-2-carboxamide Chemical compound C1=CC=C2C=C(O)C(C(=O)NN=C(C)CC(C)C)=CC2=C1 HPTJCEPNQHYWIH-UHFFFAOYSA-N 0.000 claims description 3
- 244000043261 Hevea brasiliensis Species 0.000 claims description 3
- 239000011324 bead Substances 0.000 claims description 3
- 229920003052 natural elastomer Polymers 0.000 claims description 3
- 229920001194 natural rubber Polymers 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- QZSVNPLDWQDBSW-UHFFFAOYSA-N 2-hydroxy-n-(4-methylpentan-2-ylideneamino)benzamide Chemical compound CC(C)CC(C)=NNC(=O)C1=CC=CC=C1O QZSVNPLDWQDBSW-UHFFFAOYSA-N 0.000 claims description 2
- RFBJJDYPYULWCO-UHFFFAOYSA-N 2-hydroxy-n-(propan-2-ylideneamino)benzamide Chemical compound CC(C)=NNC(=O)C1=CC=CC=C1O RFBJJDYPYULWCO-UHFFFAOYSA-N 0.000 claims description 2
- RSRDAGPXJWNKES-UHFFFAOYSA-N 3-hydroxy-n-(pentan-2-ylideneamino)naphthalene-2-carboxamide Chemical compound C1=CC=C2C=C(O)C(C(=O)NN=C(C)CCC)=CC2=C1 RSRDAGPXJWNKES-UHFFFAOYSA-N 0.000 claims description 2
- BJBFLNKKGYKDFG-UHFFFAOYSA-N 3-hydroxy-n-(propan-2-ylideneamino)naphthalene-2-carboxamide Chemical compound C1=CC=C2C=C(O)C(C(=O)NN=C(C)C)=CC2=C1 BJBFLNKKGYKDFG-UHFFFAOYSA-N 0.000 claims description 2
- 229920003049 isoprene rubber Polymers 0.000 claims description 2
- NLCUJGHQAINACX-UHFFFAOYSA-N n-(2,6-dimethylheptan-4-ylideneamino)-3-hydroxynaphthalene-2-carboxamide Chemical compound C1=CC=C2C=C(O)C(C(=O)NN=C(CC(C)C)CC(C)C)=CC2=C1 NLCUJGHQAINACX-UHFFFAOYSA-N 0.000 claims description 2
- DGHXOUMYRXAXMJ-UHFFFAOYSA-N n-(butan-2-ylideneamino)-2-hydroxybenzamide Chemical compound CCC(C)=NNC(=O)C1=CC=CC=C1O DGHXOUMYRXAXMJ-UHFFFAOYSA-N 0.000 claims description 2
- CFMUQRHQUYZLQW-UHFFFAOYSA-N n-(butan-2-ylideneamino)-3-hydroxynaphthalene-2-carboxamide Chemical compound C1=CC=C2C=C(O)C(C(=O)NN=C(C)CC)=CC2=C1 CFMUQRHQUYZLQW-UHFFFAOYSA-N 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 229920003051 synthetic elastomer Polymers 0.000 claims description 2
- 239000005061 synthetic rubber Substances 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- ZPFKRQXYKULZKP-UHFFFAOYSA-N butylidene Chemical group [CH2+]CC[CH-] ZPFKRQXYKULZKP-UHFFFAOYSA-N 0.000 claims 1
- 235000019241 carbon black Nutrition 0.000 description 19
- 238000005096 rolling process Methods 0.000 description 9
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- JVNPYFYZMKEHQZ-UHFFFAOYSA-N 2-hydroxy-n-(pentan-2-ylideneamino)benzamide Chemical compound CCCC(C)=NNC(=O)C1=CC=CC=C1O JVNPYFYZMKEHQZ-UHFFFAOYSA-N 0.000 description 1
- XSXYESVZDBAKKT-UHFFFAOYSA-N 2-hydroxybenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1O XSXYESVZDBAKKT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/24—Derivatives of hydrazine
- C08K5/25—Carboxylic acid hydrazides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34922—Melamine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C2001/005—Compositions of the bead portions, e.g. clinch or chafer rubber or cushion rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
(第1混合段階)
混合する前に、230−270リットルの接線式回転ミキサーに、架橋可能なポリマー基材と、カーボンブラックの一部(配合物に用いる総量の50〜70%)とを、66〜72%の充填率まで装填した。
第1段階からの混合物に、カーボンブラックの残りと、メチレンアクセプター化合物と、ヒドラジン由来樹脂(必要ならば)を加えた。前記ミキサーを40〜60rpmの速度で操作し、得られた混合物を温度130〜150℃に達したところで取り出した。
第2段階からの混合物に、硬化剤と、必要ならばメチレンドナー化合物とを、充填率63〜67%まで加えた。
Claims (7)
- 架橋可能な不飽和鎖のポリマー基材と、補強性充填材と、硬化剤と、を含むタイヤの構造部品の配合物であって、
該配合物は、補強性樹脂混合物を含み、該補強性樹脂混合物は、(a)メチレンドナー化合物と組み合わされたメチレンアクセプター樹脂と、(b)ヒドラジド由来樹脂と、を含み、
前記補強性充填材は、窒素吸着で測定した表面積(N 2 SA)が100〜150m2/gのカーボンブラック20〜80重量%及び窒素吸着で測定した表面積(N 2 SA)が33〜49m2/gのカーボンブラック80〜20重量%の混合物を含み、
前記補強性樹脂混合物を2〜20phr、前記カーボンブラックを合計で20〜70phr含むことを特徴とする、配合物。 - 前記メチレンアクセプター樹脂が、フェノール−ホルムアルデヒド樹脂であり、前記メチレンドナー化合物が、ヘキサメトキシメチルメラミンであることを特徴とする、請求項1に記載の配合物。
- 前記補強性樹脂混合物は、フェノール−ホルムアルデヒド樹脂を20〜80重量%、ヒドラジド由来樹脂を20〜80重量%含むことを特徴とする、請求項2に記載の配合物。
- 前記ヒドラジド由来樹脂は、2−ヒドロキシ−N’−(1−メチルエチリデン)−3−ナフトエ酸ヒドラジド、2−ヒドロキシ−N’−(1−メチルプロピリデン)−3−ナフトエ酸ヒドラジド、2−ヒドロキシ−N’−(1−メチルブチリデン)−3−ナフトエ酸ヒドラジド、2−ヒドロキシ−N’−(1,3−ジメチルブチリデン)−3−ナフトエ酸ヒドラジド、2−ヒドロキシ−N’−(2,6−ジメチル−4−ヘプチリデン)−3−ナフトエ酸ヒドラジド、N’−(1−メチルエチリデン)−サリチル酸ヒドラジド、N’−(1−メチルプロピリデン)−サリチル酸ヒドラジド、N’−(1−メチルブチリデン)−サリチル酸ヒドラジド、N’−(1,3−ジメチルブチリデン)−サリチル酸ヒドラジド、及びN’−(2,6−ジメチル−4−ヘプチリデン)−サリチル酸ヒドラジドを含む群から選択されることを特徴とする、請求項1〜3のいずれかに記載の配合物。
- 前記架橋可能な不飽和鎖のポリマー基材は、天然ゴム40〜80phrと、ブタジエンゴム、スチレン−ブタジエンゴム、及びイソプレンゴムを含む群の中の合成ゴム20〜60phrと、を含むことを特徴とする、請求項1〜4のいずれかに記載の配合物。
- 請求項1〜5のいずれかに記載の配合物から作られたタイヤの構造部品であって、
トレッドアンダーレイヤー、トレッドベース、ビードフィラー、摩耗ゴムストリップ、及びサイドウォールを含む群に属することを特徴とする、構造部品。 - 請求項6に記載の構造部品を備えるタイヤ。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITRM2013A000071 | 2013-02-08 | ||
IT000071A ITRM20130071A1 (it) | 2013-02-08 | 2013-02-08 | Mescola ad elevata rigidezza per pneumatici |
PCT/IB2014/058871 WO2014122623A1 (en) | 2013-02-08 | 2014-02-08 | Tyre high-stiffness compound |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016507625A JP2016507625A (ja) | 2016-03-10 |
JP6342920B2 true JP6342920B2 (ja) | 2018-06-13 |
Family
ID=48014211
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015556603A Active JP6342920B2 (ja) | 2013-02-08 | 2014-02-08 | タイヤの高剛性配合物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20150368445A1 (ja) |
EP (1) | EP2954001B1 (ja) |
JP (1) | JP6342920B2 (ja) |
CN (1) | CN104981507B (ja) |
IT (1) | ITRM20130071A1 (ja) |
RU (1) | RU2647038C2 (ja) |
WO (1) | WO2014122623A1 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180134494A1 (en) * | 2015-06-22 | 2018-05-17 | Bridgestone Corporation | Rubber composition, laminate and conveyor belt |
CN105906864B (zh) * | 2016-06-30 | 2017-08-25 | 肇庆骏鸿实业有限公司 | 一种增加胎侧硬度的汽车轮胎胎侧胶 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5430087A (en) * | 1993-09-02 | 1995-07-04 | Hydril Company | Carbon black pair with different particle size and improved rubber stock |
US5426147A (en) * | 1994-05-03 | 1995-06-20 | Cabot Corporation | Low permeability rubber compositions |
US5798405A (en) * | 1997-03-20 | 1998-08-25 | The Goodyear Tire & Rubber Company | Tire with tread of rubber composition containing two different carbon blacks |
CN1362918A (zh) * | 2000-02-02 | 2002-08-07 | 米其林技术公司 | 包含苯乙烯/丁二烯乳液共聚物的轮胎胎面 |
ES2234780T3 (es) * | 2000-09-01 | 2005-07-01 | Bridgestone Corporation | Composicion de caucho y cubierta neumatica robusta que utiliza la composicion de caucho. |
JP5032725B2 (ja) * | 2000-09-01 | 2012-09-26 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた重荷重用空気入りタイヤ |
US20040182486A1 (en) * | 2003-01-30 | 2004-09-23 | Carlo Bernard | Agricultural or industrial tire with reinforced rubber composition |
JP2007191611A (ja) * | 2006-01-20 | 2007-08-02 | Bridgestone Corp | 変性ポリブタジエンゴム配合ゴム組成物及びタイヤ |
EP1876203B1 (en) * | 2006-07-06 | 2011-05-18 | Sumitomo Rubber Industries, Ltd. | Rubber composition and tire using same |
IT1396782B1 (it) * | 2009-11-18 | 2012-12-14 | Bridgestone Corp | Mescola per pneumatici con migliorata resistenza al rotolamento. |
JP5377454B2 (ja) * | 2010-10-21 | 2013-12-25 | 住友ゴム工業株式会社 | バンドトッピング用ゴム組成物、ブレーカーエッジストリップ用ゴム組成物、及び空気入りタイヤ |
JP5232254B2 (ja) * | 2011-01-17 | 2013-07-10 | 住友ゴム工業株式会社 | ビードエイペックス用ゴム組成物及び空気入りタイヤ |
JP5779257B2 (ja) * | 2011-01-19 | 2015-09-16 | ブリヂストン アメリカズ タイヤ オペレイションズ エルエルシー | キャッププライゴム組成物 |
-
2013
- 2013-02-08 IT IT000071A patent/ITRM20130071A1/it unknown
-
2014
- 2014-02-08 WO PCT/IB2014/058871 patent/WO2014122623A1/en active Application Filing
- 2014-02-08 RU RU2015138129A patent/RU2647038C2/ru active
- 2014-02-08 JP JP2015556603A patent/JP6342920B2/ja active Active
- 2014-02-08 CN CN201480008193.3A patent/CN104981507B/zh not_active Expired - Fee Related
- 2014-02-08 US US14/765,923 patent/US20150368445A1/en not_active Abandoned
- 2014-02-08 EP EP14710977.1A patent/EP2954001B1/en not_active Not-in-force
Also Published As
Publication number | Publication date |
---|---|
RU2015138129A (ru) | 2017-03-21 |
ITRM20130071A1 (it) | 2014-08-09 |
WO2014122623A1 (en) | 2014-08-14 |
US20150368445A1 (en) | 2015-12-24 |
CN104981507B (zh) | 2017-10-13 |
RU2647038C2 (ru) | 2018-03-13 |
JP2016507625A (ja) | 2016-03-10 |
EP2954001B1 (en) | 2017-01-04 |
EP2954001A1 (en) | 2015-12-16 |
CN104981507A (zh) | 2015-10-14 |
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