JP6326163B1 - 樹脂洗浄剤 - Google Patents
樹脂洗浄剤 Download PDFInfo
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- JP6326163B1 JP6326163B1 JP2017044051A JP2017044051A JP6326163B1 JP 6326163 B1 JP6326163 B1 JP 6326163B1 JP 2017044051 A JP2017044051 A JP 2017044051A JP 2017044051 A JP2017044051 A JP 2017044051A JP 6326163 B1 JP6326163 B1 JP 6326163B1
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- JP
- Japan
- Prior art keywords
- resin
- polyester resin
- cleaning
- acid anhydride
- anhydride group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920005989 resin Polymers 0.000 title claims abstract description 36
- 239000011347 resin Substances 0.000 title claims abstract description 36
- 229920001225 polyester resin Polymers 0.000 claims abstract description 30
- 239000004645 polyester resin Substances 0.000 claims abstract description 30
- 125000004018 acid anhydride group Chemical group 0.000 claims abstract description 22
- 238000000465 moulding Methods 0.000 claims abstract description 17
- 238000004140 cleaning Methods 0.000 claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 239000012459 cleaning agent Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000000155 melt Substances 0.000 claims description 6
- 238000006664 bond formation reaction Methods 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 239000008188 pellet Substances 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- 239000003599 detergent Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 229920005992 thermoplastic resin Polymers 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- -1 polypropylene Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000011342 resin composition Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229920001634 Copolyester Polymers 0.000 description 2
- 229920003354 Modic® Polymers 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 125000006158 tetracarboxylic acid group Chemical group 0.000 description 2
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- OLQWMCSSZKNOLQ-UHFFFAOYSA-N 3-(2,5-dioxooxolan-3-yl)oxolane-2,5-dione Chemical compound O=C1OC(=O)CC1C1C(=O)OC(=O)C1 OLQWMCSSZKNOLQ-UHFFFAOYSA-N 0.000 description 1
- VQVIHDPBMFABCQ-UHFFFAOYSA-N 5-(1,3-dioxo-2-benzofuran-5-carbonyl)-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)=O)=C1 VQVIHDPBMFABCQ-UHFFFAOYSA-N 0.000 description 1
- JVERADGGGBYHNP-UHFFFAOYSA-N 5-phenylbenzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(=O)O)=CC(C=2C=CC=CC=2)=C1C(O)=O JVERADGGGBYHNP-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 241000083869 Polyommatus dorylas Species 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- STZIXLPVKZUAMV-UHFFFAOYSA-N cyclopentane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCC1(C(O)=O)C(O)=O STZIXLPVKZUAMV-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 125000006159 dianhydride group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- MEZLKOACVSPNER-GFCCVEGCSA-N selegiline Chemical compound C#CCN(C)[C@H](C)CC1=CC=CC=C1 MEZLKOACVSPNER-GFCCVEGCSA-N 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- YXZRCLVVNRLPTP-UHFFFAOYSA-J turquoise blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].NC1=NC(Cl)=NC(NC=2C=C(NS(=O)(=O)C3=CC=4C(=C5NC=4NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)NC=4NC(=C6C=C(C=CC6=4)S([O-])(=O)=O)NC=4[N-]C(=C6C=CC(=CC6=4)S([O-])(=O)=O)N5)C=C3)C(=CC=2)S([O-])(=O)=O)=N1 YXZRCLVVNRLPTP-UHFFFAOYSA-J 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Moulds For Moulding Plastics Or The Like (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
「(A)ポリプロピレン100質量部に対して、
(B)(A)成分と相溶化しない熱可塑性樹脂0〜50質量部、
(C)(A)成分及び(B)成分を相溶化させるための熱可塑性樹脂0.5〜50質量部、及び
(D)アニオン界面活性剤から選ばれる1種以上とノニオン界面活性剤から選ばれる1種以上を含む界面活性剤混合物0.5〜15質量部を含有する洗浄用の熱可塑性樹脂組成物。」
ポリエステル樹脂(三菱化学製商品「NOVAPEX」G2グレード(固有粘度:0.59dL/g)100重量部に酸無水物基含有ポリマー(三菱化学社製の「ダイヤカナル30」)1重量部を加え、混合機で予備混合した後、以下に記載の要領で押出機で混練し、射出成形し、ペレット形状の樹脂洗浄剤を得た。ペレットの大きさは、直径3mm、長さ3mmであった。なお、比較用に酸無水物基含有ポリマーを含有しないポリエステル樹脂ペレットも製造した。
押出機;(株)池貝社製「PCM45」(スクリュー径46mm)
射出条件;スクリュー回転数184rpm
温度条件;300℃
(射出成形条件)
射出成型機;(株)名機製作所製「M−100C」
射出条件;スクリュー回転数80rpm、射出速度50%、射出圧10MPA、背圧0MPA
温度条件;290℃
前記と同じ条件を採用した着色ポリエステル樹脂ペレットの製造工程における押出機と射出成型機の洗浄を行った。着色ポリエステル樹脂ペレットの製造においては、前記と同一のポリエステル樹脂と、これに対して10重量%の樹脂用着色剤(日本ピグメント社製のポリエステル用マスターバッチターコイズブルー)とを使用した。
Claims (1)
- 原料樹脂としてポリエステル樹脂を使用する成形加工機器内部の洗浄に使用する樹脂洗浄剤であって、酸無水物基を有する化合物と基材ポリエステル樹脂との溶融混合処理で得られるエステル結合形成反応物から成ることを特徴とする樹脂洗浄剤。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017044051A JP6326163B1 (ja) | 2017-03-08 | 2017-03-08 | 樹脂洗浄剤 |
CN201880010871.8A CN110268016B (zh) | 2017-02-14 | 2018-01-25 | 树脂清洗剂和聚酯树脂的熔融成型方法 |
KR1020197023049A KR20190111982A (ko) | 2017-02-14 | 2018-01-25 | 수지 세정제 및 폴리에스테르 수지의 용융 성형 방법 |
PCT/JP2018/002226 WO2018150837A1 (ja) | 2017-02-14 | 2018-01-25 | 樹脂洗浄剤およびポリエステル樹脂の溶融成形方法 |
TW107104470A TW201840704A (zh) | 2017-02-14 | 2018-02-08 | 樹脂洗淨劑及聚酯樹脂之熔融成形方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017044051A JP6326163B1 (ja) | 2017-03-08 | 2017-03-08 | 樹脂洗浄剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP6326163B1 true JP6326163B1 (ja) | 2018-05-16 |
JP2018145352A JP2018145352A (ja) | 2018-09-20 |
Family
ID=62143865
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017044051A Active JP6326163B1 (ja) | 2017-02-14 | 2017-03-08 | 樹脂洗浄剤 |
Country Status (1)
Country | Link |
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JP (1) | JP6326163B1 (ja) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59124999A (ja) * | 1983-01-05 | 1984-07-19 | 大日精化工業株式会社 | 成形機の洗浄剤組成物 |
JP2008146822A (ja) * | 2007-12-20 | 2008-06-26 | Sony Corp | 電子機器 |
JP2010125663A (ja) * | 2008-11-26 | 2010-06-10 | Asahi Kasei Chemicals Corp | 洗浄剤 |
JP2011021156A (ja) * | 2009-07-17 | 2011-02-03 | Nitto Denko Corp | 金型洗浄剤組成物および金型洗浄材、ならびにそれを用いた金型のクリーニング方法 |
-
2017
- 2017-03-08 JP JP2017044051A patent/JP6326163B1/ja active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59124999A (ja) * | 1983-01-05 | 1984-07-19 | 大日精化工業株式会社 | 成形機の洗浄剤組成物 |
JP2008146822A (ja) * | 2007-12-20 | 2008-06-26 | Sony Corp | 電子機器 |
JP2010125663A (ja) * | 2008-11-26 | 2010-06-10 | Asahi Kasei Chemicals Corp | 洗浄剤 |
JP2011021156A (ja) * | 2009-07-17 | 2011-02-03 | Nitto Denko Corp | 金型洗浄剤組成物および金型洗浄材、ならびにそれを用いた金型のクリーニング方法 |
Also Published As
Publication number | Publication date |
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JP2018145352A (ja) | 2018-09-20 |
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