JP6286415B2 - 排ガスの乾式浄化のためのアルカリ土類金属カーボネートおよびアルカリ土類金属水酸化物を含有する材料の活性化 - Google Patents
排ガスの乾式浄化のためのアルカリ土類金属カーボネートおよびアルカリ土類金属水酸化物を含有する材料の活性化 Download PDFInfo
- Publication number
- JP6286415B2 JP6286415B2 JP2015502380A JP2015502380A JP6286415B2 JP 6286415 B2 JP6286415 B2 JP 6286415B2 JP 2015502380 A JP2015502380 A JP 2015502380A JP 2015502380 A JP2015502380 A JP 2015502380A JP 6286415 B2 JP6286415 B2 JP 6286415B2
- Authority
- JP
- Japan
- Prior art keywords
- alkaline earth
- earth metal
- metal hydroxide
- material containing
- metal carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000463 material Substances 0.000 title claims description 118
- 229910052784 alkaline earth metal Inorganic materials 0.000 title claims description 83
- -1 alkaline earth metal carbonates Chemical class 0.000 title claims description 76
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 title claims description 76
- 230000004913 activation Effects 0.000 title claims description 48
- 238000000746 purification Methods 0.000 title description 19
- 238000000034 method Methods 0.000 claims description 35
- 238000010438 heat treatment Methods 0.000 claims description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 12
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 12
- 239000010459 dolomite Substances 0.000 claims description 12
- 229910000514 dolomite Inorganic materials 0.000 claims description 12
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052815 sulfur oxide Inorganic materials 0.000 claims description 11
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 9
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 9
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 9
- 239000000920 calcium hydroxide Substances 0.000 claims description 9
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 9
- 239000004571 lime Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 6
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 238000001994 activation Methods 0.000 description 46
- 239000007789 gas Substances 0.000 description 39
- 239000002250 absorbent Substances 0.000 description 36
- 230000002745 absorbent Effects 0.000 description 36
- 238000010521 absorption reaction Methods 0.000 description 16
- 230000001965 increasing effect Effects 0.000 description 9
- 235000011116 calcium hydroxide Nutrition 0.000 description 8
- 239000000356 contaminant Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 150000001342 alkaline earth metals Chemical class 0.000 description 7
- 239000003344 environmental pollutant Substances 0.000 description 7
- 231100000719 pollutant Toxicity 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 6
- 239000012925 reference material Substances 0.000 description 6
- 235000019738 Limestone Nutrition 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000006028 limestone Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000011575 calcium Substances 0.000 description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 150000002148 esters Chemical group 0.000 description 3
- 238000007725 thermal activation Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 229910052790 beryllium Inorganic materials 0.000 description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical group OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/508—Sulfur oxides by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/606—Carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/304—Linear dimensions, e.g. particle shape, diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/83—Solid phase processes with moving reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4806—Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12162517.2A EP2644267B2 (de) | 2012-03-30 | 2012-03-30 | Aktivierung eines Erdalkalicarbonat und Erdalkalihydroxid enthaltenden Materials für die trockene Rauchgasreinigung |
| EP12162517.2 | 2012-03-30 | ||
| PCT/EP2013/056904 WO2013144367A1 (de) | 2012-03-30 | 2013-04-02 | Aktivierung eines erdalkalicarbonat und erdalkalihydroxid enthaltenden materials für die trockene rauchgasreinigung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015526263A JP2015526263A (ja) | 2015-09-10 |
| JP6286415B2 true JP6286415B2 (ja) | 2018-02-28 |
Family
ID=48040257
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015502380A Active JP6286415B2 (ja) | 2012-03-30 | 2013-04-02 | 排ガスの乾式浄化のためのアルカリ土類金属カーボネートおよびアルカリ土類金属水酸化物を含有する材料の活性化 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20150157977A1 (cs) |
| EP (1) | EP2644267B2 (cs) |
| JP (1) | JP6286415B2 (cs) |
| BR (1) | BR112014023593B1 (cs) |
| DK (1) | DK2644267T4 (cs) |
| ES (1) | ES2656018T5 (cs) |
| NO (1) | NO2644267T3 (cs) |
| PL (1) | PL2644267T5 (cs) |
| PT (1) | PT2644267T (cs) |
| WO (1) | WO2013144367A1 (cs) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL246429A0 (en) * | 2016-06-19 | 2016-09-29 | Yeda Res & Dev | A method for removing sulfur from furnace gas |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2252710A1 (de) † | 1972-10-27 | 1974-05-02 | Ver Kesselwerke Ag | Verfahren zur entfernung von salzsaeure (hcl) aus den rauchgasen von verbrennungseinrichtungen aller art |
| US4061593A (en) † | 1977-01-26 | 1977-12-06 | General Motors Corporation | Stabilization of calcium oxide sulfate trapping materials |
| DE3230472A1 (de) † | 1982-08-16 | 1984-02-16 | Deutsche Kommunal-Anlagen Miete GmbH, 8000 München | Verfahren und vorrichtung zum reinigen von pyrolysegasen |
| CN85105415A (zh) † | 1985-07-16 | 1985-12-20 | 北京工业大学 | 可治理多种酸气的吸附剂 |
| US5219536A (en) † | 1990-07-16 | 1993-06-15 | Board Of Trustees Operating Michigan State University | Composite clay materials for removal of sox from gas streams |
| JP3381948B2 (ja) * | 1992-12-02 | 2003-03-04 | 鈴木工業株式会社 | 高活性酸化カルシウム多孔質体の製造方法 |
| DE4307007A1 (de) † | 1993-03-05 | 1994-09-08 | Ic Umwelt & Und Anlagentechnik | Verfahren und Vorrichtung zur Trockenreinigung von heißen Gasen |
| DE19521808A1 (de) * | 1995-06-16 | 1996-12-19 | Rheinische Kalksteinwerke | Granulat auf Basis von Erdalkalikarbonaten mit ab- und adsorptiven Substanzen |
| BE1009692A3 (fr) † | 1995-10-19 | 1997-07-01 | Lhoist Rech & Dev Sa | PARTICULES DE Ca(OH)2. |
| JP3634795B2 (ja) † | 2001-11-29 | 2005-03-30 | 株式会社日本触媒 | 窒素酸化物および/または硫黄酸化物の吸着剤 |
| US7314847B1 (en) † | 2004-10-21 | 2008-01-01 | The United States Of America As Represented By The United States Department Of Energy | Regenerable sorbents for CO2 capture from moderate and high temperature gas streams |
| JP2006169062A (ja) † | 2004-12-17 | 2006-06-29 | Ube Material Industries Ltd | 酸化カルシウム含有多孔質粒状物 |
| KR101270921B1 (ko) * | 2005-03-30 | 2013-06-03 | 다이요 닛산 가부시키가이샤 | 칼슘 및/또는 마그네슘을 함유하는 다공질 입자로이루어지는 입상물 |
| CA2605176A1 (en) * | 2005-04-19 | 2006-10-26 | Carmeuse North America Services, Inc. | Method for producing activated lime for removal of acid gases from a combustion gas |
| JP5286480B2 (ja) † | 2007-08-31 | 2013-09-11 | 一般財団法人石炭エネルギーセンター | 粒子状のCa(OH)2の製造方法及びそれを用いたガス吸収方法又はガス回収方法 |
| DE102008041530A1 (de) † | 2008-08-25 | 2010-03-04 | Dirk Dombrowski | Verfahren und Abgasanlage zur Reinigung SOx-haltiger Abgase, insbesondere von Schiffsbrennkraftmaschinen |
| JP5217819B2 (ja) † | 2008-09-12 | 2013-06-19 | 旭硝子株式会社 | ハロゲン系ガスの除去剤およびハロゲン系ガスの除去方法 |
| UA44170U (ru) † | 2009-03-24 | 2009-09-25 | Инна Вячеславовна Питак | Способ получения активного оксида магния |
| DE102009045278B4 (de) * | 2009-10-02 | 2011-12-15 | Dirk Dombrowski | Mineralisches, granuliertes Entschwefelungsmittel auf Basis von Calciumhydroxid, Verfahren zu seiner Herstellung sowie seine Verwendung |
| US8999278B2 (en) † | 2010-03-11 | 2015-04-07 | The Board Of Trustees Of The University Of Illinois | Method and apparatus for on-site production of lime and sorbents for use in removal of gaseous pollutants |
| DE102011112657B4 (de) † | 2011-09-06 | 2015-02-12 | Fels-Werke Gmbh | Gasabsorptionsgranulat sowie seine Verwendung |
| DE102011113034C5 (de) † | 2011-09-06 | 2017-03-16 | Fels-Werke Gmbh | Gasabsorptionsgranulat sowie Verfahren zu seiner Herstellung |
-
2012
- 2012-03-30 ES ES12162517T patent/ES2656018T5/es active Active
- 2012-03-30 NO NO12162517A patent/NO2644267T3/no unknown
- 2012-03-30 PL PL12162517T patent/PL2644267T5/pl unknown
- 2012-03-30 PT PT121625172T patent/PT2644267T/pt unknown
- 2012-03-30 DK DK12162517.2T patent/DK2644267T4/da active
- 2012-03-30 EP EP12162517.2A patent/EP2644267B2/de active Active
-
2013
- 2013-04-02 JP JP2015502380A patent/JP6286415B2/ja active Active
- 2013-04-02 BR BR112014023593A patent/BR112014023593B1/pt active IP Right Grant
- 2013-04-02 US US14/388,429 patent/US20150157977A1/en not_active Abandoned
- 2013-04-02 WO PCT/EP2013/056904 patent/WO2013144367A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP2644267B2 (de) | 2021-01-20 |
| US20150157977A1 (en) | 2015-06-11 |
| PT2644267T (pt) | 2018-01-19 |
| DK2644267T3 (en) | 2018-01-15 |
| DK2644267T4 (da) | 2021-04-12 |
| ES2656018T3 (es) | 2018-02-22 |
| PL2644267T5 (pl) | 2021-05-31 |
| PL2644267T3 (pl) | 2018-04-30 |
| JP2015526263A (ja) | 2015-09-10 |
| WO2013144367A9 (de) | 2013-12-19 |
| ES2656018T5 (es) | 2021-10-26 |
| WO2013144367A1 (de) | 2013-10-03 |
| EP2644267A1 (de) | 2013-10-02 |
| BR112014023593A2 (pt) | 2017-06-27 |
| BR112014023593B1 (pt) | 2019-12-10 |
| EP2644267B1 (de) | 2017-11-08 |
| NO2644267T3 (cs) | 2018-04-07 |
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